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1.
Degassing during magma ascent in the Mule Creek vent (USA)   总被引：1，自引：1，他引：1  
 The structures and textures of the rhyolite in the Mule Creek vent (New Mexico, USA) indicate mechanisms by which volatiles escape from silicic magma during eruption. The vent outcrop is a 300-m-high canyon wall comprising a section through the top of a feeder conduit, vent and the base of an extrusive lava dome. Field relations show that eruption began with an explosive phase and ended with lava extrusion. Analyses of glass inclusions in quartz phenocrysts from the lava indicate that the magma had a pre-eruptive dissolved water content of 2.5–3.0 wt% and, during eruption, the magma would have been water-saturated over the vertical extent of the present outcrop. However, the vesicularity of the rhyolite is substantially lower than that predicted from closed-system models of vesiculation under equilibrium conditions. At a given elevation in the vent, the volume fraction of primary vesicles in the rhyolite increases from zero close to the vent margin to values of 20–40 vol.% in the central part. In the centre the vesicularity increases upward from approximately 20 vol.% at 300 m below the canyon rim to approximately 40 vol.% at 200 m, above which it shows little increase. To account for the discrepancy between observed vesicularity and measured water content, we conclude that gas escaped during ascent, probably beginning at depths greater than exposed, by flow through the vesicular magma. Gas escape was most efficient near the vent margin, and we postulate that this is due both to the slow ascent of magma there, giving the most time for gas to escape, and to shear, favouring bubble coalescence. Such shear-related permeability in erupting magma is supported by the preserved distribution of textures and vesicularity in the rhyolite: Vesicles are flattened and overlapping near the dense margins and become progressively more isolated and less deformed toward the porous centre. Local zones have textures which suggest the coalescence of bubbles to form permeable, collapsing foams, implying the former existence of channels for gas migration. Local channelling of gas into the country rocks is suggested by the presence of sub-horizontal syn-eruptive rhyolitic tuffisite veins which depart from the vent margin and invade the adjacent country rock. In the central part of the vent, similar local channelling of gas is indicated by steep syn-eruption tuffisite veins which cut the rhyolite itself. We conclude that the suppression of explosive eruption resulted from gas separation from the ascending magma and vent structure by shear-related porous flow and channelling of gas through tuffisite veins. These mechanisms of gas loss may be responsible for the commonly observed transition from explosive to effusive behaviour during the eruption of silicic magma. Received: 24 May 1995 / Accepted: 13 March 1996  相似文献   

2.
The eruption of the Pelagatos scoria cone in the Sierra Chichinautzin monogenetic field near the southern suburbs of Mexico City occurred less than 14,000 years ago. The eruption initiated at a fissure with an effusive phase that formed a 7-km-long lava flow, and continued with a phase of alternating and/or simultaneous explosive and effusive activity that built a 50-m-high scoria cone on the western end of the fissure and formed a compound lava flow-field near the vent. The eruption ended with the emplacement of a short lava flow that breached the cone and was accompanied by weak explosions at the crater. Products consist of a microlite-rich high-Mg basaltic andesite. Samples were analyzed to determine the magma’s initial properties as well as the effects of degassing-induced crystallization on eruptive style. Although distal ash fallout deposits from this eruption are not preserved, a recent quarry exposes a large section of the scoria cone. Detailed study of exposed layers allows us to elucidate the mode of cone-building activity. Petrological and textural data, combined with models calibrated by experimental work and melt-inclusion analyses of similar magmas elsewhere, indicate that the magma was initially hot (>1,200°C), gas-rich (up to 5 wt.% H2O), crystal-poor (~10 vol.% Fo90 olivine phenocrysts) and thus poorly viscous (40–80 Pa s). During the early phase, low magma ascent velocity at the fissure vent allowed low-viscosity magma to degas and crystallize during ascent, producing lava flows with elevated crystal contents at T < 1,100°C, and blocky surfaces. Later, the closure of the fissure by cooling dikes focused the magma flow at a narrow section of the fissure. This led to an increased magma ascent velocity. Rapid and shallow degassing (<3 km deep) triggered ~40 vol.% microlite crystallization. Limited times for gas-escape and higher magma viscosity (6 × 105–4 × 106 Pa s) drove strong explosions of highly (60–80 vol.%) and finely vesicular magma. Coarse clasts broke on landing, which implies brittle behavior due to complete solidification. This requires sufficient time to cool and in turn implies ejection heights of over 1 km, which is much higher than “normal” Strombolian activity. Hence, magma viscosity significantly impacts eruption style at monogenetic volcanoes because it affects the kinetics of shallow degassing. The long-lasting eruptions of Jorullo and Paricutin, which produced similar magmas in western México, were more explosive. This can be related to higher magma fluxes and total erupted volumes. Implications of this study are important because basaltic andesites are commonly erupted to form monogenetic scoria cones of the Trans-Mexican Volcanic Belt.  相似文献   

3.
The 1875 rhyolitic eruption of Askja volcano in Iceland was a complex but well-documented silicic explosive eruption. Eyewitness chronologies, coupled with examination of very proximal exposures and historical records of distal deposit thickness, provide an unusual opportunity for study of Plinian and phreatoplinian eruption and plume dynamics. The ∼ 17 hour-long main eruption was characterized by abrupt and reversible shifts in eruption style, e.g., from ‘wet’ to ‘dry’ eruption conditions, and transitions from fall to flow activity. The main eruption began with a ‘dry’ subplinian phase (B), followed by a shift to a very powerful phreatoplinian ‘wet’ eruptive phase (C1). A shift from sustained ‘wet’ activity to the formation of ‘wet’ pyroclastic density currents followed with the C2 pyroclastic density currents, which became dryer with time. Severe ground shaking accompanied a migration in vent position and the onset of the intense ‘dry’ Plinian phase (D). Each of the fall units can be modeled using the segmented exponential thinning method (Bonadonna et al. 1998), and three to five segments have been recognized on a semilog plot of thickness vs. area1/2. The availability of very proximal and far-distal thickness data in addition to detailed observations taken during this eruption has enabled calculations of eruption parameters such as volumes, intensities and eruption column heights. This comprehensive dataset has been used here to assess the bias of volume calculations when proximal and distal data are missing, and to evaluate power-law and segmented exponential thinning methods using limited datasets.  相似文献   

4.
Fragmentation of magma during Plinian volcanic eruptions   总被引：2，自引：0，他引：2  
 The ratio of the volume of vesicles (gas) to that of glass (liquid) in pumice clasts (V G /V L ) reflects the degassing and dynamic history experienced by a magma during an explosive eruption. V G /V L in pumices from a large number of Plinian eruption deposits is shown here to vary by two orders of magnitude, even between pumices at a given level in a deposit. These variations in V G /V L do not correlate with crystallinity or initial water content of the magmas or their eruptive intensities, despite large ranges in these variables. Gas volume ratios of pumices do, however, vary systematically with magma viscosity estimated at the point of fragmentation, and we infer that pumices do not quench at the level of fragmentation but undergo some post-fragmentary evolution. On the timescale of Plinian eruptions, pumices with viscosities <109 Pa s can expand after fragmentation, as long as their bubbles retain gas, at a rate inversely proportional to their viscosity. Once the bubbles connect to form a permeable network and lose their gas, expansion halts and pumices with viscosities <105 Pa s can collapse under the action of surface tension. Textural evidence from bubble sizes and shapes in pumices indicates that both expansion and collapse have taken place. The magnitudes of expansion and collapse, therefore, depend critically on the timing of bubble connectivity relative to the final moment of quenching. We propose that bubbles in different pumices become connected at different times throughout the time span between fragmentation and quenching. After accounting for these effects, we derive new information on the fragmentation process from two characteristics of pumices. The most important is a relatively constant minimum value of V G /V L of ∼1.78 (64 vol.% vesicularity) in all samples with viscosities >105 Pa s. This value is independent of magma composition and thus reflects a property of the eruptive mechanism. The other characteristic is that highly expanded pumices (>85 vol.% vesicularities) are common, which argues against overpressure in bubbles as a mechanism for fragmenting magma. We suggest that magma fragments when it reaches a vesicularity of ∼64 vol.%, but only if sheared sufficiently strongly. The intensity of shear varies as a function of velocity in the conduit, which is related to overpressure in the chamber, so that changes in overpressure with time are important in controlling the common progression from explosive to effusive activity at volcanoes. Received: 19 April 1995 / Accepted: 3 April 1996  相似文献   

5.
Critical to understanding explosive eruptions is establishing how accurately representative pyroclasts are of processes during magma vesiculation and fragmentation. Here, we present data on densities, and vesicle size and number characteristics, for representative pyroclasts from six silicic eruptions of contrasting size and style from Raoul volcano (Kermadec arc). We use these data to evaluate histories of bubble nucleation, coalescence, and growth in explosive eruptions and to provide comparisons with pumiceous dome carapace material. Density/vesicularity distributions show a scarcity of pyroclasts with ～65–75 % vesicularity; however, pyroclasts closest to this vesicularity range have the highest bubble number density (BND) values regardless of eruptive intensity or style. Clasts with vesicularities greater than this 65–75 % “pivotal” vesicularity range have decreasing BNDs with increasing vesicularities, interpreted to reflect continuing bubble growth and coalescence. Clasts with vesicularities less than the pivotal range have BNDs that decrease with decreasing vesicularity and preserve textures indicative of processes such as stalling and open system degassing prior to vesiculation in a microlite-rich magma, or vesiculation during slow ascent of degassing magma. Bubble size distributions (BSDs) and BNDs show variations consistent with 65–75 % representing the vesicularity at which vesiculating magma is most likely to undergo fragmentation, consistent with the closest packing of spheres. We consider that the observed vesicularity range may reflect the development of permeability in the magma through shearing as it flows through the conduit. These processes can act in concert with multiple nucleation events, generating a situation of heterogeneous bubble populations that permit some regions of the magma to expand and bubbles to coalesce with other regions in which permeable networks are formed. Fragmentation preserves the range in vesicularity seen as well as any post-fragmentation/pre-quenching expansion which may have occurred. We demonstrate that differing density pyroclasts from a single eruption interval can have widely varying BND values corresponding to the degree of bubble maturation that has occurred. The modal density clasts (the usual targets for vesicularity studies) have likely undergone some degree of bubble maturation and are therefore may not be representative of the magma at the onset of fragmentation.  相似文献   

6.
The largest natrocarbonatite lava flow eruption ever documented at Oldoinyo Lengai, NW Tanzania, occurred from March 25 to April 5, 2006, in two main phases. It was associated with hornito collapse, rapid extrusion of lava covering a third of the crater and emplacement of a 3-km long compound rubbly pahoehoe to blocky aa-like flow on the W flank. The eruption was followed by rapid enlargement of a pit crater. The erupted natrocarbonatite lava has high silica content (3% SiO2). The eruption chronology is reconstructed from eyewitness and news media reports and Moderate Resolution Imaging Spectroradiometer (MODIS) satellite data, which provide the most reliable evidence to constrain the eruption’s onset and variations in activity. The eruption products were mapped in the field and the total erupted lava volume estimated at 9.2 ± 3.0 × 105 m3. The event chronology and field evidence are consistent with vent construct instability causing magma mixing and rapid extrusion from shallow reservoirs. It provides new insights into and highlights the evolution of the shallow magmatic system at this unique natrocarbonatite volcano.  相似文献   

7.
Bubble growth in rhyolitic melts: experimental and numerical investigation   总被引：2，自引：0，他引：2  
 Bubble growth controlled by mass transfer of water from hydrated rhyolitic melts at high pressures and temperatures was studied experimentally and simulated numerically. Rhyolitic melts were hydrated at 150 MPa, 780–850  °C to uniform water content of 5.5–5.3 wt%. The pressure was then dropped and held constant at 15–145 MPa. Upon the drop bubbles nucleated and were allowed to grow for various periods of time before final, rapid quenching of the samples. The size and number density of bubbles in the quenched glasses were recorded. Where number densities were low and run duration short, bubble sizes were in accord with the growth model of Scriven (1959) for solitary bubbles. However, most results did not fit this simple model because of interaction between neighboring bubbles. Hence, the growth model of Proussevitch et al. (1993), which accounts for finite separation between bubbles, was further developed and used to simulate bubble growth. The good agreement between experimental data, numerical simulation, and analytical solutions enables accurate and reliable examination of bubble growth from a limited volume of supersaturated melt. At modest supersaturations bubble growth in hydrated silicic melts (3–6 wt% water, viscosity 104–106 Pa·s) is diffusion controlled. Water diffusion is fast enough to maintain steady-state concentration gradient in the melt. Viscous resistance is important only at the very early stage of growth (t<1 s). Under the above conditions growth is nearly parabolic, R2=2Dtρm(C0–Cf)/ρg until the bubble approaches its final size. In melts with low water content, viscosity is higher and maintains pressure gradients in the melt. Growth may be delayed for longer times, comparable to time scales of melt ascent during eruptions. At high levels of supersaturation, advection of hydrated melt towards the growing bubble becomes significant. Our results indicate that equilibrium degassing is a good approximation for modeling vesiculation in melts with high water concentrations (C0>3 wt%) in the region above the nucleation level. When the melt accelerates and water content decreases, equilibrium can no longer be maintained between bubbles and melt. Supersaturation develops in melt pockets away from bubbles and new bubbles may nucleate. Further acceleration and increase in viscosity cause buildup of internal pressure in the bubbles and may eventually lead to fragmentation of the melt. Received: 19 June 1995 / Accepted: 27 December 1995  相似文献   

8.
Plinian/ignimbrite activity stopped briefly and abruptly 16 and 45 h after commencement of the 1912 Novarupta eruption defining three episodes of explosive volcanism before finally giving way after 60 h to effusion of lava domes. We focus here on the processes leading to the termination of the second and third of these three episodes. Early erupted pumice from both episodes show a very similar range in bulk vesicularity, but the modal values markedly decrease and the vesicularity range widens toward the end of Episode III. Clasts erupted at the end of each episode represent textural extremes; at the end of Episode II, clasts have very thin glass walls and a predominance of large bubbles, whereas at the end of Episode III, clasts have thick interstices and more small bubbles. Quantitatively, all clasts have very similar vesicle size distributions which show a division in the bubble population at 30 μm vesicle diameter and cumulative number densities ranging from 107–109 cm–3. Patterns seen in histograms of volume fraction and the trends in the vesicle size data can be explained by coalescence signatures superimposed on an interval of prolonged nucleation and free growth of bubbles. Compared to experimental data for bubble growth in silicic melts, the high 1912 number densities suggest homogeneous nucleation was a significant if not dominant mechanism of bubble nucleation in the dacitic magma. The most distinct clast populations occurred toward the end of Plinian activity preceding effusive dome growth. Distributions skewed toward small sizes, thick walls, and teardrop vesicle shapes are indicative of bubble wall collapse marking maturation of the melt and onset of processes of outgassing. The data suggest that the superficially similar pauses in the 1912 eruption which marked the ends of episodes II and III had very different causes. Through Episode III, the trend in vesicle size data reflects a progressive shift in the degassing process from rapid magma ascent and coupled gas exsolution to slower ascent with partial open-system outgassing as a precursor to effusive dome growth. No such trend is visible in the Episode II clast assemblages; we suggest that external changes involving failure of the conduit/vent walls are more likely to have effected the break in explosive activity at 45 h.  相似文献   

9.
 During the 1944 eruption of Vesuvius a sudden change occurred in the dynamics of the eruptive events, linked to variations in magma composition. K-phonotephritic magmas were erupted during the effusive phase and the first lava fountain, whereas the emission of strongly porphyritic K-tephrites took place during the more intense fountain. Melt inclusion compositions (major and volatile elements) highlight that the magmas feeding the eruption underwent differentiation at different pressures. The K-tephritic volatile-rich melts (up to 3 wt.% H2O, 3000 ppm CO2, and 0.55 wt.% Cl) evolved to reach K-phonotephritic compositions by crystallization of diopside and forsteritic olivine at total fluid pressure higher than 300 MPa. These magmas fed a very shallow reservoir. The low-pressure differentiation of the volatile-poor K-phonotephritic magmas (H2O<1 wt.%) involved mixing, open-system degassing, and crystallization of leucite, salite, and plagioclase. The eruption was triggered by intrusion of a volatile-rich magma batch that rose from a depth of 11–22 km into the shallow magma chamber. The first phase of the eruption represents the partial emptying of the shallow reservoir, the top of which is within the volcanic edifice. The newly arrived magma mixed with that resident in the shallow reservoir and forced the transition from the effusive to the lava fountain phase of the eruption. Received: 14 September 1998 / Accepted: 10 January 1999  相似文献   

10.
Lava balloons—peculiar products of basaltic submarine eruptions   总被引：1，自引：1，他引：0  
Between December 1998 and April 2001, a submarine basaltic eruption occurred west of Terceira Island, Azores (Portugal) in water depths between 300 and 1,000?m. Physical evidence for the eruption was provided by the periodic occurrence of hot lava “balloons” floating on the sea surface. The balloons consisted of a large gas-filled cavity surrounded by a thin shell (a few centimetres thick). The shells of the collected balloons are composed of two layers, termed the outer layer and the inner layer, defined by different bubble number density, bubble sizes and crystal content. The inner layer is further divided into three sublayers defined by more subtle differences in vesicularity. The outer layer is glassy, golden-coloured and highly porous. It shows signs of fluidal deformation and late-stage extension cracks. Interstitial glass contains 0.29?wt% H2O and CO2 is below detection. Melt inclusions contain up to 1.18?wt% H2O and 1,500?ppm CO2 (from different inclusions). Cooling rates of the outermost glass of the outer layer are found to be as high as 1,259?K/s. During ascent of low viscosity magma to the ocean floor, volatiles, dominated by CO2, exsolved from the magma (melt + crystals). The buoyancy of the vapour phase that accumulated below a thin crust on lava ponded at the vent caused bulging and ultimately cracking of the crust. This allowed large bubbles (central cavity) surrounded by a film of vesicular magma (balloon shell) to leak into the water column. On contact with the seawater, the outermost part of the outer layer of the shell hyperquenched. If an entirely closed shell was produced during detachment, the trapped gas inside allowed buoyant rise. Only balloons with the right balance of physical properties (e.g. size and bulk density) rose all the way to the sea surface.  相似文献   

11.
Hawaiian eruptions are characterized by fountains of gas and ejecta, sustained for hours to days that reach tens to hundreds of meters in height. Quantitative analysis of the pyroclastic products from the 1959 eruption of Kīlauea Iki, Kīlauea volcano, Hawai‘i, provides insights into the processes occurring during typical Hawaiian fountaining activity. This short-lived but powerful eruption contained 17 fountaining episodes and produced a cone and tephra blanket as well as a lava lake that interacted with the vent and fountain during all but the first episode of the eruption, the focus of this paper. Microtextural analysis of Hawaiian fountaining products from this opening episode is used to infer vesiculation processes within the fountain and shallow conduit. Vesicle number densities for all clasts are high (106–107 cm−3). Post-fragmentation expansion of bubbles within the thermally-insulated fountain overprints the pre-fragmentation bubble populations, leading to a reduction in vesicle number density and increase in mean vesicle size. However, early quenched rims of some clasts, with vesicle number densities approaching 107 cm−3, are probably a valid approximation to magma conditions near fragmentation. The extent of clast evolution from low vesicle-to-melt ratio and corresponding high vesicle number density to higher vesicle-to-melt ratio and lower vesicle-number density corresponds to the length of residence time within the fountain.  相似文献   

12.
The August 1991 eruptions of Hudson volcano produced ~2.7 km3 (dense rock equivalent, DRE) of basaltic to trachyandesitic pyroclastic deposits, making it one of the largest historical eruptions in South America. Phase 1 of the eruption (P1, April 8) involved both lava flows and a phreatomagmatic eruption from a fissure located in the NW corner of the caldera. The paroxysmal phase (P2) began several days later (April 12) with a Plinian-style eruption from a different vent 4 km to the south-southeast. Tephra from the 1991 eruption ranges in composition from basalt (phase 1) to trachyandesite (phase 2), with a distinct gap between the two erupted phases from 54–60 wt% SiO2. A trend of decreasing SiO2 is evident from the earliest part of the phase 2 eruption (unit A, 63–65 wt% SiO2) to the end (unit D, 60–63 wt% SiO2). Melt inclusion data and textures suggest that mixing occurred in magmas from both eruptive phases. The basaltic and trachyandesitic magmas can be genetically related through both magma mixing and fractional crystallization processes. A combination of observed phase assemblages, inferred water content, crystallinity, and geothermometry estimates suggest pre-eruptive storage of the phase 2 trachyandesite at pressures between ~50–100 megapascal (MPa) at 972 ± 26°C under water-saturated conditions (log fO2 –10.33 (±0.2)). It is proposed that rising P1 basaltic magma intersected the lower part of the P2 magma storage region between 2 and 3 km depth. Subsequent mixing between the two magmas preferentially hybridized the lower part of the chamber. Basaltic magma continued advancing towards the surface as a dyke to eventually be erupted in the northwestern part of the Hudson caldera. The presence of tachylite in the P1 products suggests that some of the magma was stalled close to the surface (<0.5 km) prior to eruption. Seismicity related to magma movement and the P1 eruption, combined with chamber overpressure associated with basalt injection, may have created a pathway to the surface for the trachyandesite magma and subsequent P2 eruption at a different vent 4 km to the south-southeast. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

13.
The 1960 Kapoho lavas of Kilauea’s east rift zone contain 1–10 cm xenoliths of olivine gabbro, olivine gabbro-norite, and gabbro norite. Textures are poikilitic (ol+sp+cpx in pl) and intergranular (cpx+pl±ol±opx). Poikilitic xenoliths, which we interpret as cumulates, have the most primitive mineral compositions, Fo82.5, cpx Mg# 86.5, and An80.5. Many granular xenoliths (ol and noritic gabbro) contain abundant vesicular glass that gives them intersertal, hyaloophitic, and overall ‘open’ textures to suggest that they represent ‘mush’ and ‘crust’ of a magma crystallization environment. Their phase compositions are more evolved (Fo80–70, cpx Mg# 82–75, and An73–63) than those of the poikilitic xenoliths. Associated glass is basaltic, but evolved (MgO 5 wt%; TiO2 3.7–5.8 wt%). The gabbroic xenolith mineral compositions fit existing fractional crystallization models that relate the origins of various Kilauea lavas to one another. FeO/MgO crystal–liquid partitioning is consistent with the poikilitic ol-gabbro assemblage forming as a crystallization product from Kilauea summit magma with ∼8 wt% MgO that was parental to evolved lavas on the east rift zone. For example, least squares calculations link summit magmas to early 1955 rift-zone lavas (∼5 wt% MgO) through ∼28–34% crystallization of the ol+sp+cpx+pl that comprise the poikilitic ol-gabbros. The other ol-gabbro assemblages and the olivine gabbro-norite assemblages crystallized from evolved liquids, such as represented by the early 1955 and late 1955 lavas (∼6.5 wt% MgO) of the east rift zone. The eruption of 1960 Kapoho magmas, then, scoured the rift-zone reservoir system to entrain portions of cumulate and solidification zones that had coated reservoir margins during crystallization of prior east rift-zone magmas. Received: January 7, 1993/Accepted: November 23, 1993  相似文献   

14.
 Fragmentation, or the "coming apart" of magma during a plinian eruption, remains one of the least understood processes in volcanology, although assumptions about the timing and mechanisms of fragmentation are key parameters in all existing eruption models. Despite evidence to the contrary, most models assume that fragmentation occurs at a critical vesicularity (volume percent vesicles) of 75–83%. We propose instead that the degree to which magma is fragmented is determined by factors controlling bubble coalescence: magma viscosity, temperature, bubble size distribution, bubble shapes, and time. Bubble coalescence in vesiculating magmas creates permeability which serves to connect the dispersed gas phase. When sufficiently developed, permeability allows subsequent exsolved and expanded gas to escape, thus preserving a sufficiently interconnected region of vesicular magma as a pumice clast, rather than fully fragmenting it to ash. For this reason pumice is likely to preserve information about (a) how permeability develops and (b) the critical permeability needed to insure clast preservation. We present measurements and calculations that constrain the conditions (vesicularity, bubble size distribution, time, pressure difference, viscosity) necessary for adequate permeability to develop. We suggest that magma fragments explosively to ash when and where, in a heterogeneously vesiculating magma, these conditions are not met. Both the development of permeability by bubble wall thinning and rupture and the loss of gas through a permeable network of bubbles require time, consistent with the observation that degree of fragmentation (i.e., amount of ash) increases with increasing eruption rate. Received: 5 July 1995 / Accepted: 27 December 1995  相似文献   

15.
 The 1963 eruption of Gunung Agung produced 0.95 km3 dense rock equivalent (DRE) of olivine±hornblende-bearing, weakly phyric, basaltic andesite tephra and lava. Evidence for magma mixing in the eruptive products includes whole-rock compatible and incompatible trace element trends, reverse and complex compositional zoning of mineral phases, disequilibrium mineral assemblages, sieve-textured plagioclase phenocrysts, and augite rims on reversely zoned orthopyroxene. Basalt magma mixed with pre-existing andesite magma shortly before eruption to yield basaltic andesite with a temperature of 1040–1100  °C at an assumed pressure of 2 kb, f O2>NNO, and an average melt volatile content (H2O±CO2) of 4.3 wt.%. Magma-mixing end members may have provided some of the S and Cl emitted in the eruption. Glass inclusions in phenocrysts contain an average of 650 ppm S and 3130 ppm Cl as compared with 70 ppm and 2220 ppm, respectively, in the matrix glass. Maximum S and Cl contents of glass inclusions approach 1800 and 5000 ppm, respectively. Application of the petrologic method to products of the 1963 eruption for estimating volatile release yields of 2.5×1012 g (Mt) of SO2 and 3.4 Mt of Cl released from the 0.65 km3 of juvenile tephra which contributed to stratospheric injection of H2SO4 aerosols on 17 March and 16 May, when eruption column heights exceeded 20 km above sea level. An independent estimate of SO2 release from atmospheric aerosol loading (11–12 Mt) suggests that approximately 7 Mt of SO2 was injected into the stratosphere. The difference between the two estimates can be most readily accounted for by the partitioning of S, as well as some Cl, from the magma into a water-rich vapor phase which was released upon eruption. For other recent high-S-release eruptions of more evolved and oxidized magmas (El Chichón, Pinatubo), the petrologic method gives values two orders of magnitude less than independent estimates of SO2 emissions. Results from this study of the Agung 1963 magma and its volatile emissions, and from related studies on eruptions of more mafic magmas, suggest that SO2 emissions from eruptions of higher-S-solubility magma may be more reliably estimated by the petrologic method than may those from more-evolved magma eruptions. Received: 29 June 1994 / Accepted: 25 April 1996  相似文献   

16.
Phase equilibrium experiments were performed to determine the pre-eruptive conditions of the phonolitic magma responsible for the last eruption (about 1,150 yr B.P.) of Teide volcano. The Lavas Negras phonolite contains 30 to 40 wt% of phenocrysts, mainly anorthoclase, diopside, and magnetite. We have investigated pressures from 100 to 250 MPa, temperatures from 750 to 925°C, water contents from 1.3 to 10 wt%, at an oxygen fugacity (fO2) of 1 log unit above the Ni-NiO solid buffer. Comparison of the natural and experimental phase proportions and compositions indicates that the phonolite was stored at 900 ± 20°C, 150 ± 50 MPa, 3 ± 0.5 wt% dissolved H2O in the melt. The fO2 was probably close to the fayalite-magnetite-quartz solid buffer judging from results of other experimental studies. These conditions constrain the magma storage depth at about 5 ± 1 km below current summit of Teide volcano. Given that the island has not suffered any major structural or topographic changes since the Lavas Negras eruption, any remaining magma from this event should still be stored at such depth and probably with a similar thermal and rheological state.  相似文献   

17.
Mount Etna volcano erupted almost simultaneously on its northeastern and southern flanks between October 27 and November 3, 2002. The eruption on the northeastern flank lasted for 8 days, while on the southern flank it continued for 3 months. The northeastern flank eruption was characterized by the opening of a long eruptive fracture system between 2,900 and 1,900 m.a.s.l. A detailed survey indicates that the fractures’ direction shifted during the opening from N10W (at the NE Crater, 2,900 m) to N45E (at its lowest portion, 1,900 m) and that distinct magma groups were erupted at distinct fracture segments. Based on their petrological features, three distinct groups of rocks have been identified. The first group, high-potassium porphyritic (HKP), is made up of porphyritic lavas with a Porphyritic Index (P.I.) of 20–32 and K2O content higher than 2 wt%. The second group is represented by lavas and tephra with low modal phenocryst abundance (P.I. < 20) named here oligo-phyric (low-phyric), and K2O content higher than 2 wt% (HKO, high-potassium oligophyric). The third group, low-potassium oligophyric (LKO), consists of tephra with oligophyric texture (P.I. < 20) but K2O content < 2 wt%. K-rich magmas (HKP and HKO) are similar to the magma erupted on the southern flank, and geochemical variations within these groups can be accounted for by a variable degree of fractionation from a single parent magma. The K-poor magma (LKO), erupted only in the upper segment of the fracture, cannot be placed on the same liquid line of descent of the HK groups, and it is similar to the magmas that fed the activity of Etna volcano prior to the eruption of 1971. This is the first time since then that a magma of this composition has been documented at Mt. Etna, thus providing a strong indication for the existence of distinct batches of magma whose rise and differentiation are independent from the main conduit system. The evolution of this eruption provides evidence that the NE Rift plays a very active role in the activity of Mt. Etna volcano, and that its extensional tectonics allows the intrusion and residence of magma bodies at various depths, which can therefore differentiate independently from the main open conduit system.  相似文献   

18.
The previously poorly documented 26–16.6 ka interval of pyroclastic volcanism from Tongariro Volcano is marked by three distal lapilli fall units (Rt1-3) exposed in ring-plain deposits. The distal Rt1-3 units are tentatively correlated to proximal scoria deposits on the upper slopes of North Crater based on their dispersal patterns, petrography and geochemistry. Lapilli in each of the Rt1-3 deposits are characterised by variable groundmass crystallinity, vesicularity and colour within individual clasts. Matrix glasses are mostly microlite-free, and compositionally diverse across the deposits (SiO2 = 62–75 wt%), with wide composition ranges occurring within single clasts. The glasses represent different melts that were mingled and mixed shortly before eruption; a finding supported by widely variable Fe–Ti oxide equilibrium temperature estimates (∼830–1,200°C). Ranges of 30–160°C (typically 70°C) occur within individual clasts. Some clinopyroxene crystals display Mg-rich (∼Mg #88) rim zones around homogeneous low-Mg (∼Mg #68) cores, with abrupt transition zones. This zoning is interpreted as resulting from the injection of a more mafic melt into a stagnating, resident magma. Crystal-melt equilibria indicate that several episodes of mafic intrusion occurred, to produce hybrid melts with zoned crystals forming isolated ponds within the resident magma. Variable mixing from the percolation of melts and the coalescence of melt ponds would explain the wide range of melt compositions and equilibrium temperatures observed in the ejecta. The magma heterogeneity was preserved by quenching on prompt eruption, with much of the short-duration chaotic mixing of melts and crystals occurring in the conduit. The Rt1-3 eruptions were from an open magmatic system consisting of one or more long-lived stagnant crystal mush zones, from which eruptions were rapidly triggered by new injections of mafic magmas from greater depths. A similar pattern of magmatic dynamics was observed in the much smaller 1995 eruptions of the neighbouring Ruapehu Volcano.  相似文献   

19.
Tofua Island is the largest emergent mafic volcano within the Tofua arc, Tonga, southwest Pacific. The volcano is dominated by a distinctive caldera averaging 4 km in diameter, containing a freshwater lake in the south and east. The latest paroxysmal (VEI 5–6) explosive volcanism includes two phases of activity, each emplacing a high-grade ignimbrite. The products are basaltic andesites with between 52 wt.% and 57 wt.% SiO2. The first and largest eruption caused the inward collapse of a stratovolcano and produced the ‘Tofua’ ignimbrite and a sub-circular caldera located slightly northwest of the island’s centre. This ignimbrite was deposited in a radial fashion over the entire island, with associated Plinian fall deposits up to 0.5 m thick on islands >40 km away. Common sub-rounded and frequently cauliform scoria bombs throughout the ignimbrite attest to a small degree of marginal magma–water interaction. The common intense welding of the coarse-grained eruptive products, however, suggests that the majority of the erupted magma was hot, water-undersaturated and supplied at high rates with moderately low fragmentation efficiency and low levels of interaction with external water. We propose that the development of a water-saturated dacite body at shallow (<6 km) depth resulted in failure of the chamber roof to cause sudden evacuation of material, producing a Plinian eruption column. Following a brief period of quiescence, large-scale faulting in the southeast of the island produced a second explosive phase believed to result from recharge of a chemically distinct magma depleted in incompatible elements. This similar, but smaller eruption, emplaced the ‘Hokula’ Ignimbrite sheet in the northeast of the island. A maximum total volume of 8 km3 of juvenile material was erupted by these events. The main eruption column is estimated to have reached a height of ∼12 km, and to have produced a major atmospheric injection of gas, and tephra recorded in the widespread series of fall deposits found on coral islands 40–80 km to the east (in the direction of regional upper-tropospheric winds). Radiocarbon dating of charcoal below the Tofua ignimbrite and organic material below the related fall units imply this eruption sequence occurred post 1,000 years BP. We estimate an eruption magnitude of 2.24 × 1013 kg, sulphur release of 12 Tg and tentatively assign this eruption to the AD 1030 volcanic sulphate spike recorded in Antarctic ice sheet records.  相似文献   

20.
 The 1783–1784 Laki tholeiitic basalt fissure eruption in Iceland was one of the greatest atmospheric pollution events of the past 250 years, with widespread effects in the northern hemisphere. The degassing history and volatile budget of this event are determined by measurements of pre-eruption and residual contents of sulfur, chlorine, and fluorine in the products of all phases of the eruption. In fissure eruptions such as Laki, degassing occurs in two stages: by explosive activity or lava fountaining at the vents, and from the lava as it flows away from the vents. Using the measured sulfur concentrations in glass inclusions in phenocrysts and in groundmass glasses of quenched eruption products, we calculate that the total accumulative atmospheric mass loading of sulfur dioxide was 122 Mt over a period of 8 months. This volatile release is sufficient to have generated ∼250 Mt of H2SO4 aerosols, an amount which agrees with an independent estimate of the Laki aerosol yield based on atmospheric turbidity measurements. Most of this volatile mass (∼60 wt.%) was released during the first 1.5 months of activity. The measured chlorine and fluorine concentrations in the samples indicate that the atmospheric loading of hydrochloric acid and hydrofluoric acid was ∼7.0 and 15.0 Mt, respectively. Furthermore, ∼75% of the volatile mass dissolved by the Laki magma was released at the vents and carried by eruption columns to altitudes between 6 and 13 km. The high degree of degassing at the vents is attributed to development of a separated two-phase flow in the upper magma conduit, and implies that high-discharge basaltic eruptions such as Laki are able to loft huge quantities of gas to altitudes where the resulting aerosols can reside for months or even 1–2 years. The atmospheric volatile contribution due to subsequent degassing of the Laki lava flow is only 18 wt.% of the total dissolved in the magma, and these emissions were confined to the lowest regions of the troposphere and therefore important only over Iceland. This study indicates that determination of the amount of sulfur degassed from the Laki magma batch by measurements of sulfur in the volcanic products (the petrologic method) yields a result which is sufficient to account for the mass of aerosols estimated by other methods. Received: 30 May 1995 / Accepted: 19 April 1996  相似文献   

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