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海水氧化镁(烧结后亦称海水镁砂)具有纯度高、成份稳定,既可制得高质量产品,生产中又易于配料等优点,因而是炼钢炉碱性耐火材料的优良原料。 当用石灰乳以海水沉淀镁时,因Mg(OH)_2胶体带正电荷,海水中硼呈B(OH)_4-负离子,由于静电吸引,将硼一起吸附下来;若海水中硼全部被Mg(OH)_2胶体吸附,可使MgO中的硼含量达到0.7％(以B_2O_3计)。Byrne和Kestor指出,海水中B(OH)_4-负离子有部分与Na~+,Mg~(2+),Ca~(2+)等形成络合物NaB(OH)_4,MgB(OH)_4~+,CaB(OH)~+,它们不带电荷或 相似文献
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维生素B_(12)(C_(63)H_(90)CoN_(14)O_(14)P)又名钴胺素,是一种含钴的有机化合物。在动物的肝脏、肌肉、乳品、蛋黄和某些贝类中含量丰富。许多海洋生物能利用海水中的痕量钴来合成B_(12)。我国有关水产部门曾对毛蚶体内B_(12)的提取进行过研究,测得每克毛蚶鲜肉中含有B_(12)O.65—O.85微克。~(60)Co是海洋放射性 相似文献
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日本的海水化学资源提取技术研究 总被引：3，自引：0，他引：3
海水化学资源例如铀、锂提取技术已进入海水现场小规模试验。以纤维状偕胺肟类化合物为吸附材料 ,每公斤吸附剂的提铀量为 1 g。添加质量分数为 2 0 %聚氯乙烯的尖晶石型锰氧化物粒状海水提锂吸附剂 ,每克吸附剂的提铀量为 1 8mg。浮体式吸铀装置可用于深海作业。流动床或船舶提锂系统 ,可规模化海水提锂。吸锂剂的脱附以及脱锂液的浓缩分离已初步达到小型生产的程度。用吸附法从海水中提取的碳酸锂纯度达 99%以上 ,海水锂回收率为 2 7%。 相似文献
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沙滩水体中溶解性石油烃的降解及吸附研究 总被引：2，自引：0，他引：2
以海水体系和海水-砂体系作为对比,研究了沙滩水体中溶解性石油烃的降解及吸附作用。实验结果表明,1d内海水中石油浓度的降低主要是由于砂的快速吸附作用,3d以后生物对石油烃的降解作用逐渐占据优势。两种体系中降烃菌数量及石油浓度的变化曲线表明,砂对油的快速吸附显著降低了海水中石油污染物的浓度,使得海水含砂体系中石油降解菌的数量远高于海水体系。海水中石油污染物的降解符合一级动力学模式,当含砂体系中砂的粒径不同时,石油污染物降解的半衰期可由海水体系的31.9d缩短到22.4d和19.5d。系统中砂的存在有利于海水中石油污染物的去除,有约20%的石油污染物被吸附到砂上,然而这种去除是物理去除。 相似文献
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镁砂是冶金工业和其他高温工业部门不可缺少的耐火材料,为了综合利用海水资源,特别是卤水资源,中国科学院海洋研究所,承担了山东省科委下达的“地下卤水提取镁砂的技术研究”任务。该所的科研人员,三年来经过数百次反复试验研究,终于提取出高纯镁砂,氧化镁含量达99.9％,而且无硼,超额完成了任务,山东省科委,日前在青岛召开了技术鉴定会。专家们一致认为:技术路线先进,工艺流程简便可行,该方法有用海水代淡水配氨水 相似文献
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本文研究了表面活性剂对氢氧化镁吸附硼的影响,对不同类型的表面活性剂,不同的加入方式以及不同的加入量等进行了试验,并试验了在表面活性剂存在下,pH值对吸硼量的影响。阴离子表面活性剂——十二烷基硫酸钠的加入 可以减少Mg(OH)_2对硼的吸附;十二烷基硫酸钠加入的顺序对Mg(OH)_2吸硼没有影响,这表明Mg(OH)_2吸硼是可逆的;在十二烷基硫酸钠的存在下,最大吸硼量时的pH为10.3。 相似文献
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研究用交流示波极谱测定海水中钾的方法。海水试样用NaOH调节pH约12,加入过量四苯硼化钠标准溶液,用微孔滤膜(或滤纸)过滤沉淀。收集游液,用TI(Ⅰ)标准溶液滴定过量的四苯基硼离子。方法回收率为99.5％。测定结果与四苯硼化钾重量法结果一致。海水中共存离子不干扰测定,并可用于海水及多种盐溶液中钾的测定。本法因其简便、快速、准确而易于推广。 相似文献
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Recently carbon dioxide fluxes between sea water and air have been measured in many coastal seas to clarify whether the coastal seas are source or sink of CO2. In this study behavior of CO2 within the water column was studied in a semi-enclosed coastal sea: the Seto Inland Sea, Japan. It was found that seasonal formation of hypoxic water mass is highly related to CO2 dynamics in coastal seas. Bacterial remineralization of organic matter consumes dissolved oxygen (DO) and releases dissolved CO2 in the bottom water when summertime thermal stratification develops. The CO2 accumulates within the low DO bottom water (hypoxic water) and causes increasing of carbonic acid content which results in low pH. Concentrations of dissolved CO2 and pH are highly correlated with DO concentration. The summertime low DO and acidification (low pH) occur in the lower layer every year. The accumulated CO2 during the summer season is dispersed to the atmosphere at the beginning of mixing season. 相似文献
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Interest in factors controlling lacustrine source rock deposition has increased over the last few decades because this type of deposits contain significant petroleum resources. Generally, tectonic subsidence and climate are the two root causes as they control the accommodation potential, water column properties and sources of organic matter. In this study, coupling organic geochemical and elemental geochemical data, two potential source rocks, i.e., the Eocene Wenchang Formation (E2w) and Oligocene Enping Formation (E3e) were investigated. Two models were finally raised to explain deposition of the two set of source rocks according to their paleoclimatic and tectonic properties. The source rock potential shows a strong heterogeneity. The second member of the Eocene Wenchang Formation (E2w2) is characterized by high organic matter content and oil-prone kerogen type. In contrast, the first member of the Eocene Wenchang Formation (E2w1) and the Oligocene Enping formation (E3e) are characterized by low organic matter content and gas-prone kerogen type. The primary productivity and depositional environment exhibit notable differences between the two potential source rocks horizons and show an obvious variation from the depocenter to the slope and can be best explained by the coevolution of tectonic subsidence and climate. During the E2w depositional stage, low sediment supply led to mudstone deposited in deep lacustrine environment and resulted in underfilled lake basin. The low water inflow provided little terrigenous organic matter (low bicadinane, perylene and floranthene contents) and oxygen. Besides, the low area/depth ratio impeded the water circulation, thus resulted in shallow thermocline and anoxic-suboxic bottom environment (abundant dibenzothiophene and high C35/C3122S hopane ratios). Therefore abundant algae, which contributed to the high amorphous organic matter (AOM) content, can be preserved. The warm and wet climate (high Mn/Mg ratios) gave birth to autochthonous organism, such as dinoflagellates and Pavlova gyrans (abundant 4-methyl sterane). During the E3e depositional stage, the sufficient sedimentary supply resulted in expanding, shallow lacustrine and swamp environment. The higher area/depth ratio and high sediment supply made environment unstable and can be strongly influenced by external environment (broader range of Mn/Mg ratios). Enough terrigenous organic matter (TOM) was transported to the slope but little to the depocenter. The slightly hot and dry climate (low Mn/Mg ratios) led to decreasing autochthonous organism and evaporation environment. The shallow water depth and relative dry climate resulted in saline, suboxic-dysoxic acid bottom environment. The co-variation of organic and inorganic indexes indicates the combination is a valid method in reconstructing source rock depositional models. 相似文献
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-The i. r. spectra of Na4 [UO2 (CO3)3], Na [UO2 (OH)3] and the surface species of uranium on HTO underthe condition of flowing natural seawater and concentrated seawater (NaCl-NaHCO3-U) were recorded, with the bands of urany! of surface species obtained and the finding that iigands of surface species besides HTO are mainly water and OH, and there are some CO32- groups under the condition of natural seawater. Some relations between the complex properties and the j. r. spectroscopic characters for uranyl complexes were studied, and the transferred change quantity of surface complex was calculated.Structure models for surface species of adsorption are herein presented and the mechanism for uranium adsorption is deduced. 相似文献
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Resulting from the rising levels of atmospheric carbon, ocean acidification has become a global problem. It has significant impacts on the development, survival, growth and physiology of marine organisms. Therefore, a highprecision sensor is urgently needed to measure the pH of sea-water. Iridium wire with a diameter of 0.25 mm is used as the substrate, and an Ir/Ir(OH)_x pH electrode is prepared by a one-step electrochemical method in a Li OH solution at the room temperature. A scanning electron microscope(SEM) observation reveals that it is coated with nanoscale particles. In laboratory tests, the electrode exhibits a very promising pH response, with an ideal Nernst slope(56.14–59.52), fast response, good stability and long life-span in tested pH buffer solutions. For a sea trial,four pH electrodes and one Ag/Ag Cl reference electrode are integrated with a self-made chemical sensor, and a profile detection of nearly 70 m is implemented near Newport Harbor, California on August 3, 2015. The results reflect that the pH value measured by the sensor is very close to the data given by Sea-Bird 911 plus CTD, with a difference value ranging from 0.000 075 to 0.064 719. And the sensor shows a better data matching degree in 0–40m water depth. In addition, the high precision and accuracy of the sensor make it possible to use in the ocean observation field. 相似文献
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Silver determinations in the sea-water around Monaco were carried out using a procedure consisting of preconcentration of silver with lead sulfide, followed by dithizone extraction and spectrophotometric mono-colour measurement of silver-dithizonate. The average concentration of silver in the surface sea-water around Monaco was found to be 0.14Μg Ag/l. It was also concluded that observed variations of silver content in seawater were not related to the fresh water run-off from the neighbouring coast. This suggests that the variations have to be attributed to some other factor or a combination of factors. On the basis of the observed values of the silver content of the Var River water, an upper limit of silver supply by fresh waters into the sea-area around Monaco is estimated to be 2.3Μg Ag per liter of fresh water. Considering the mixing of the fresh water with sea-water, an increase of up to 0.09Μg Ag/l in the sea-water might be expected. The fact that the increase of silver in the sea-water was not observed in connection with the fresh-water mixing suggests that some effective removal process of silver may be in operation at the immediate vicinity of the injection of fresh-water into the sea. 相似文献
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A new set of empirical formulas for the production rate and the number concentration of sea-water droplets on the sea surface are proposed, synthesizing past observation data of sea-salt particles in the sea and water droplets in wind-wave tanks. A new levelz
c
is introduced as the effective wind-sea surface where seawater droplets are produced. The new formulas are expressed in linear functions in logarithmic scales ofu*2/v
p
, a parameter to describe overall conditions of airsea boundary processes, whereu
* is the friction velocity of air,v the kinematic viscosity of air and
p
the peak angular frequency of wind-wave part of wave spectra. A model of coexistence of spray droplets and suspended particles near the sea surface is proposed. As for the independent parameter, a comparison between the uses ofu*2/v
p
and ofu
*
3 which was the traditional way of parameterization excluding wave measure, shows that the advantage of usingu*2/v
p
is statistically significant with a confidence limit 89% in F-test. 相似文献