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1.
Deuterium, oxygen-18 and chloride were analyzed for 84 samples from deep and shallow wells, precipitation and the river White Nile to investigate groundwater recharge/discharge relations in the semi-arid central Sudan. Spatial and vertical variation in isotopic signature and chloride concentration in the groundwater show similar patterns and indicate local recharge and evaporative discharge. Progressive decrease in isotopic composition along the regional groundwater flow path demonstrates aquifer continuity down the NW–SE recharge-discharge path. Isotope-heavy recharged water progressively mixes with lighter older groundwater formed during cooler and humid conditions in the late Pleistocene. However, evaporative fractionation in the flow path’s final reach in the southeast re-enriches the isotopic composition and suggests evaporative loss of groundwater as the plausible discharge mechanism. Chloride concentration increases down the gradient from the recharge area and reaches its peak in the discharge zones indicating: lack of recharge from direct infiltration down the gradient, evaporation and prolonged rock/water interaction. Head differences and increased isotopic concentration in the vicinity of the White Nile suggest recharge from the river from subsurface flow. Reduced chloride content and relatively heavier isotopic composition in the deep groundwater beneath the wadi of Khor Abu Habil indicate recharge from the streambed into the deep aquifer.  相似文献   

2.
Stable isotope data, a dissolved gas tracer study, groundwater age dating, and geochemical modeling were used to identify and characterize the effects of introducing low-TDS recharge water in a shallow aerobic aquifer affected by a managed aquifer recharge project in California’s San Joaquin Valley. The data all consistently point to a substantial degree of mixing of recharge water from surface ponds with ambient groundwater in a number of nearby wells screened at depths above 60 m below ground surface. Groundwater age data indicate that the wells near the recharge ponds sample recently recharged water, as delineated by stable O and C isotope data as well as total dissolved solids, in addition to much older groundwater in various mixing proportions. Where the recharge water signature is present, the specific geochemical interactions between the recharge water and the aquifer material appear to include ion exchange reactions (comparative enrichment of affected groundwater with Na and K at the expense of Ca and Mg) and the desorption of oxyanion-forming trace elements (As, V, and Mo), possibly in response to the elevated pH of the recharge water.  相似文献   

3.
In the region between Mersin and Tarsus cities, located along the Mediterranean Sea coast in southern Turkey, the demand for groundwater has increased dramatically as the available surface water supplies have already been developed. Fundamental information is required to characterize the existing groundwater system in this area in order to establish a sustainable groundwater-use policy. For this purpose, hydrochemical and environmental isotopic data were collected and integrated with available geological and hydrogeological information to develop a conceptual model of the system. Results, backed up mainly by depleted stable isotope composition and infinitesimal tritium content, suggest that most of the groundwater along the coastal zone is supplied by the neighboring mountain belt while local precipitation has also contributes to aquifer recharge. The validation of the conceptual perspective by a steady-state numerical groundwater flow model reveals that about 90% of the recharge to the aquifer system is supplied by the deep flow of karstic groundwater fed from the Taurus Mountains. Monitoring of changes in the recharge regime of the mountain sector seems to be critical in establishing future groundwater use policies.  相似文献   

4.
The hydrodynamic groundwater data and stable isotopes of water have been used jointly for better understanding of upward leakage and mixing processes in the Djerid aquifer system (southwestern Tunisia). The aquifer system is composed of the upper unconfined Plio-Quaternary (PQ) aquifer, the intermediate (semi-)confined Complex Terminal (CT) aquifer and the deeper confined Continental Intercalaire (CI) aquifer. A total of 41 groundwater samples from the CT and PQ aquifers were collected during June 2001. The stable isotope composition of waters establishes that the CT deep groundwater (depleted as compared to present Nefta local rainfall) is ancient water recharged during late Quaternary time. The relatively recent water in the shallow PQ aquifer is composed of mixed water resulting from upward leakage and sporadic meteoric recharge. In order to characterize the meteoric input signal for PQ in the study area, rainfall water samples were collected during 4 years (2000–2003) at the Nefta meteorological station. Weighted mean values of isotopic contents with respect to rainfall amounts have been computed. Despite the short collection period in the study area, results agree with those found in Beni Abbes (southwestern Algerian Sahara) by Fontes on 9 years of rainfall surveillance. Stable isotopic relationships provide clear evidence of shallow PQ aquifer replenishment by deep CT groundwater. The 18O/upward leakage rate allowed the identification of distinctive PQ waters related to CT aquifer configuration (confined in the western part of the study area, semi-permeable in the eastern part). These trends were confirmed by the relation 18O/TDS. The isotope balance model indicated a contribution of up to 75% of the deep CT groundwater to the upper PQ aquifer in the western study area, between Nefta and Hazoua.  相似文献   

5.
Sources of groundwater recharge to the Badain Jaran Desert in China have been investigated using geochemical and isotopic techniques. Stable isotope compositions (δ18O and δ2H) of shallow groundwater and surface water from oasis lakes evolve from a starting composition considerably depleted compared to local unsaturated zone moisture, confirming inferences from chloride mass balance that direct infiltration of precipitation is not a volumetrically important source of recharge to the shallow aquifer in the study area. Shallow phreatic and deeper confined groundwater bodies appear unconnected based on chemical composition and radiocarbon activities. Hydrogeologic evidence points toward a bordering mountain range (Yabulai) as a likely recharge zone, which is consistent with tracer results. A mean residence time in the range of 1–2 ka for the desert’s southeastern margin is inferred from radiocarbon. These results reveal that some replenishment to the desert aquifer is occurring but at a rate much lower than previously suggested, which is relevant for water resources planning in this ecologically sensitive area.  相似文献   

6.
Stable isotopes (δ18O, δ2H and 13C) and radioactivity (3H, 14C) have been used in conjunction with chemical data to evaluate the processes generating the chemical composition, reconstruct the origin of the water and groundwater residence time. The Aleppo basin is comprised of two main limestone aquifers: the first one is unconfined of Paleogene age and the second is confined of Upper Cretaceous age. The chemical data indicate that the dissolution of minerals and evaporation are the main processes controlling groundwater mineralization. The groundwater from the two aquifers is characterized by distinctive stable isotope signatures. This difference in water isotopes is interpreted in terms of difference origin and recharge period. Fresh and brackish shallow groundwater were mostly recharged during the Holocene period. The presence of 3H in several groundwater samples of this aquifer gives evidence that groundwater recharge is going on. Brackish water of the deep confined aquifer has depleted stable isotope composition and very low 14C activity that indicates recharge during the late Pleistocene cold period.  相似文献   

7.
The major ion hydrochemistry, sodium absorption ratio (SAR), sodium percentage, and isotopic signatures of Hammamet-Nabeul groundwaters were used to identify the processes that control the mineralization, irrigation suitability, and origin of different water bodies. This investigation highlights that groundwater mineralization is mainly influenced by water-rock interaction and pollution by the return flow of irrigation water. The comparison of groundwater quality with irrigation suitability standards proves that most parts of groundwater are unacceptable for irrigation and this long-term practice may result in a significant increase of the salinity and alkalinity in the soils. Based on isotopic signatures, the shallow aquifer groundwater samples were classified into (i) waters with depleted δ18O and δ2H contents, highlighting recharge by modern precipitation, and (ii) waters with enriched stable isotope contents, reflecting the significance of recharge by contaminated water derived from the return flow of evaporated irrigation waters. The deep-aquifer groundwater samples were also classified into (i) waters with relatively enriched isotope contents derived from modern recharge and mixed with shallow-aquifer groundwater and (ii) waters with depleted stable isotope contents reflecting a paleoclimatic origin. Tritium data permit to identify three origins of recharge, i.e., contemporaneous, post-nuclear, and pre-nuclear. Carbon-14 activities demonstrate the existence of old paleoclimatic recharge related to the Holocene and Late Pleistocene humid periods.  相似文献   

8.
This paper gives an account of the implementation of hydrochemical and isotopic techniques to identify and explain the processes that govern solute exchange in two groundwater-dependent shallow lakes in the Southeastern Pampa Plain of Argentina. Water samples (lakes, streams, spring water and groundwater) for hydrochemical and stable isotopic determination were collected and the main physical–chemical parameters were measured. The combination of stable isotope data with hydrogeochemical techniques was used for the identification of sources and preferential recharge areas to these aquatic ecosystems which allowed the explanation of the lake water origin. The hydrochemical processes which explain Los Padres Lake water chemistry are evaporation from groundwater, CO2 input, calcite dissolution, Na+ release by Ca2+ and Mg2+ exchange, and sulfate reduction. The model that best aligns with La Brava Lake hydrochemical constraints includes: mixing, CO2 and calcite dissolution, cationic exchange with Na+ release and Mg2+ adsorption, and to a lesser extent, Ca/Na exchange. This model suggests that the fractured aquifer contribution to this water body is greater than 50 %. An isotopic-specific fingerprint for each lake was identified, finding a higher evaporation rate for La Brava Lake compared to Los Padres Lake. Isotopic data demonstrate the importance of these shallow lakes as recharge areas to the regional aquifer, becoming areas of high groundwater vulnerability. The Tandilia Range System, considered in many hydrogeological studies as the impermeable bedrock of the Pampean aquifer, acts as a fissured aquifer in this area, contributing to low salinity waters and with a fingerprint similar to groundwater isotopic composition.  相似文献   

9.
Overexploitation of shallow aquifers on the Syrian coast, north of Latakia (Damsarkho) for irrigation and tourism has caused an intrusion of seawater. The seawater intrusion into this aquifer has been presented by a three-dimensional finite element model using the FEFLOW numerical code. This conceptual model is based on field and laboratory data collected during the period 1966–2003. Meteoric infiltration and flows from the adjoining carbonate aquifer recharge the aquifer; natural outflow occurs through a diffuse flow into the sea; and artificial outflow occurs through intensive extraction of groundwater from wells. Water exchanges in the aquifer occur naturally (leakage) and artificially (multi-screened wells). The model was calibrated for transient conditions. The model helped establish that seawater intrusion is essentially due to withdrawals near the coast during the irrigation season and that it mainly occurs in the Damsarkho plain. The effects of hypothetical aquifer exploitation were assessed in terms of salt budget.  相似文献   

10.
Groundwater resources protection and aquifer recovery in China   总被引：7，自引：0，他引：7  
The groundwater resources in China and especially the northern part represent a vital water resource. Both the shallow and deep aquifers are highly overexploited in a large area of north China. The heavy overexploitation of groundwater resources is causing major environmental damage. To protect groundwater resources, several technical feasibility studies were performed. Artificial recharge using floodwater and wastewater was tried. Surface spreading systems are applicable in many areas of the Yellow River basin and Hai River basin. Deep aquifer injections were undertaken in the urban area. A far better strategy is to reduce the extraction of groundwater, especially to stop or slow down land subsidence and seawater intrusion. To address the problem of falling groundwater levels and aquifer recovery, there is a need reduce groundwater extraction and artificial recharge.  相似文献   

11.
海河流域地下水资源保护   总被引：8，自引：2，他引：8  
地下水资源在海河流域至关重要的资源。海河平原的浅层和深层含水层大面积处于严重超采状态。地下水资源的的过量开采造成了严重环境问题。为了保护地下水资源，评价了可行的技术。利用洪水和废水进行人工回灌已进行了试验。在很多地区可以应用地表回灌系统，城市地区实施深层含水层的回灌。更好地策略是减少地下水的抽取量，特别是为了减缓地面沉降和海水入侵。应该联合运用减少地下水抽水量和人工回灌，以解决地下水位持续下降和含水层恢复的问题。  相似文献   

12.
Salinization in coastal aquifers is usually related to both seawater intrusion and water–rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl?, Na+, Ca2+, Mg2+ and SO 4 2– ), as well as the isotopic content and ratios (2H, 18O, 87Sr/86Sr and 13C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.  相似文献   

13.
Korba aquifer is one of the most typical examples of overexploited coastal aquifer in the Mediterranean countries. In fact, from 1985, a considerable piezometric level drop, water salinization, and seawater intrusion were registered in the aquifer. In December 2008, Tunisian authorities initiated a general plan to groundwater management in order to augment groundwater resources, restore the piezometric levels, and improve water quality. The plan consists of artificial recharge of groundwater used treated wastewater through three infiltration basins. During the first 4 years (from December 2008 to December 2012), 1.41 Mm3 of treated wastewater was injected to the Korba aquifer. This study presents a hydrogeological assessment of groundwater evolution during the recharge processes. In this study, 32 piezometric and chemical surveys of 70 piezometers and observed wells are used to present hydrogeological investigation and water quality evolution of wastewater reuse through artificial recharge in Korba coastal aquifer. The piezometric evolution maps are used to specify the positive effect in groundwater level that exceeding 1.5 m in some regions. The interpretation of salinity evolution maps are used to indicate the improving of groundwater quality.  相似文献   

14.
《Applied Geochemistry》2002,17(8):1047-1060
Due to the scarcity of water resources in semiarid sedimentary basins, hill reservoirs are often constructed to recharge groundwater and limit runoff induced water loss. The impact of such reservoirs on groundwater chemistry is investigated in the aquifers of the El Gouazine watershed, Central Tunisia. Three groundwater types are recognised, Ca–HCO3, Na–Cl and Ca–SO4. The strong similarity between host rock and groundwater chemistries indicates significant rock–water interaction. A flowpath, along which the chemical composition of the groundwater evolves, can be identified using the contrast in stable isotope signature between upstream and downstream groundwater. Shallow upstream groundwater is recharged by the infiltration of rainwater with the rate of recharge strongly linked to the permeability of the host lithology. Calcium and HCO3 are supplied to an alluvial aquifer from a more rapidly recharged limestone aquifer with the concentration of Ca and HCO3 ions decreasing by dilution. The alluvial aquifer is also enriched in Ca and SO4 during the downstream flow of groundwater through gypsiferous materials. There is evidence of mixing between meteoric groundwater and evaporated reservoir water. Below the reservoir and partly responsible for reservoir leakage is a sandy aquifer, formed by weathering and erosion of a sandstone host which also supplies water to the alluvial aquifer.  相似文献   

15.
Anthropogenic pressure influences the two-way interactions between shallow aquifers and coastal lagoons. Aquifer overexploitation may lead to seawater intrusion, and aquifer recharge from rainfall plus irrigation may, in turn, increase the groundwater discharge into the lagoon. We analyse the evolution, since the 1950s up to the present, of the interactions between the Campo de Cartagena Quaternary aquifer and the Mar Menor coastal lagoon (SE Spain). This is a very heterogeneous and anisotropic detrital aquifer, where aquifer–lagoon interface has a very irregular geometry. Using electrical resistivity tomography, we clearly identified the freshwater–saltwater transition zone and detected areas affected by seawater intrusion. Severity of the intrusion was spatially variable and significantly related to the density of irrigation wells in 1950s–1960s, suggesting the role of groundwater overexploitation. We distinguish two different mechanisms by which water from the sea invades the land: (a) horizontal advance of the interface due to a wide exploitation area and (b) vertical rise (upconing) caused by local intensive pumping. In general, shallow parts of the geophysical profiles show higher electrical resistivity associated with freshwater mainly coming from irrigation return flows, with water resources mostly from deep confined aquifers and imported from Tagus river, 400 km north. This indicates a likely reversal of the former seawater intrusion process.  相似文献   

16.
The Korba aquifer on the east coast of Cape Bon has been overexploited since the 1960s with a resultant reversal of the hydraulic gradient and a degradation of the quality due to seawater intrusion. In 2008 the authorities introduced integrated water resources planning based on a managed aquifer recharge with treated wastewater. Water quality monitoring was implemented in order to determine the different system components and trace the effectiveness of the artificial recharge. Groundwater samples taken from recharge control piezometers and surrounding farm wells were analyzed for their chemical contents, for their B isotopes, a proven tracer of groundwater salinization and domestic sewage, and their carbamazepine content, an anti-epileptic known to pass through wastewater treatment and so recognized as a pertinent tracer of wastewater contamination. The system equilibrium was permanently disturbed by the different temporal dynamics of continuous processes such as cation exchange, and by threshold processes linked to oxidation–reduction conditions. The B isotopic compositions significantly shifted back-and-forth due to mixing with end-members of various origin. Under the variable contribution of meteoric recharge, the Plio-Quaternary groundwater (δ11B of 35–40.6‰, a mean B concentration of 30 μmol/L, no carbamazepine, n = 7) was subject to seawater intrusion that induced a high δ11B level (δ11B of 41.5–48.0‰, a mean B concentration of 36 μmol/L, and n = 8). Fresh groundwater (δ11B of 19.89‰, B concentration of 2.8 μmol/L, no carbamazepine) was detected close to the recharge site and may represent the deep Miocene pole which feeds the upper Plio-Quaternary aquifer. The managed recharge water (δ11B of 10.67–13.8‰, n = 3) was brackish and of poor quality with a carbamazepine content showing a large short term variability with an average daily level of 328 ± 61 ng/L. A few piezometers in the vicinity of the recharge site gradually acquired a B isotopic composition close to the wastewater signature and showed an increasing carbamazepine content (from 20 to 910 ng/L). The combination of B isotopic signatures with B and carbamazepine contents is a useful tool to assess sources and mixing of treated wastewaters in groundwaters. Effluent quality needs to be greatly improved before injection to prevent further degradation of groundwater quality.  相似文献   

17.
The Wadi Watir delta, in the arid Sinai Peninsula, Egypt, contains an alluvial aquifer underlain by impermeable Precambrian basement rock. The scarcity of rainfall during the last decade, combined with high pumping rates, resulted in degradation of water quality in the main supply wells along the mountain front, which has resulted in reduced groundwater pumping. Additionally, seawater intrusion along the coast has increased salinity in some wells. A three-dimensional (3D) groundwater flow model (MODFLOW) was calibrated using groundwater-level changes and pumping rates from 1982 to 2009; the groundwater recharge rate was estimated to be 1.58?×?106 m3/year. A variable-density flow model (SEAWAT) was used to evaluate seawater intrusion for different pumping rates and well-field locations. Water chemistry and stable isotope data were used to calculate seawater mixing with groundwater along the coast. Geochemical modeling (NETPATH) determined the sources and mixing of different groundwaters from the mountainous recharge areas and within the delta aquifers; results showed that the groundwater salinity is controlled by dissolution of minerals and salts in the aquifers along flow paths and mixing of chemically different waters, including upwelling of saline groundwater and seawater intrusion. Future groundwater pumping must be closely monitored to limit these effects.  相似文献   

18.
High water demand for domestic use in Douala with over 3 million inhabitants is met mainly by shallow groundwater. Field measurements and water sampling in January 2015 were carried out to examine the major controls on the groundwater composition and spatial view of ions in the water, timing of recharge and link between the recharge process and quality of the water. Fifty-two water samples were analysed for major ions and stable hydrogen and oxygen isotopes. Low pH values (3.61–6.92) in the groundwater indicated an acidic aquifer; thus, prone to acidification. The dominant water type was Na–Cl. Nitrate, which exceeded the WHO guide value of 50 mg/l in 22% of the groundwater, poses a health problem. Mass ratios of Cl?/Br? in the water ranged from 54 to 3249 and scattered mostly along the mixing lines between dilute waters, septic-tank effluent and domestic sewage. A majority of the samples, especially the high NO3 ? shallow wells, clustered around the septic-tank effluent-end-member indicating high contamination by seepage from pit latrines; hence, vulnerable to pollution. Stable isotopes in the groundwater indicated its meteoric origin and rapid infiltration after rainfall. The δ18O values showed narrow ranges and overlaps in rivers, springs, open wells and boreholes. These observations depict hydraulic connectivity, good water mixing and a homogeneous aquifer system mainly receiving local direct uniform areal recharge from rainfall. The rapid and diffused recharge favours the leaching of effluent from the pit toilets into the aquifer; hence, the high NO3 ? and Cl? in shallow wells. Silicate weathering, ion exchange and leaching of waste from pit toilets are the dominant controls on the groundwater chemistry. Drilling of deep boreholes is highly recommended for good-quality water supply. However, due the hydraulic connection to the shallow aquifer, geochemical modelling of future effects of such an exploitation of the deeper aquifer should support groundwater management and be ahead of the field actions.  相似文献   

19.
Greece is dependent on groundwater resources for its water supply. The main aquifers are within carbonate rocks (karstic aquifers) and coarse grained Neogene and Quaternary deposits (porous aquifers). The use of groundwater resources has become particularly intensive in coastal areas during the last decades with the intense urbanization, tourist development and irrigated land expansion. Sources of groundwater pollution are the seawater intrusion due to over-exploitation of coastal aquifers, the fertilizers from agricultural activities and the disposal of untreated wastewater in torrents or in old pumping wells. In the last decades the total abstractions from coastal aquifers exceed the natural recharge; so the aquifer systems are not used safely. Over-exploitation causes a negative water balance, triggering seawater intrusion. Seawater intrusion phenomena are recorded in coastal aquifer systems. Nitrate pollution is the second major source of groundwater degradation in many areas in Greece. The high levels of nitrate are probably the result of over-fertilization and the lack of sewage systems in some urban areas.  相似文献   

20.
A shallow unconfined low-lying coastal aquifer in southern Finland surrounded by the Baltic Sea is vulnerable to changes in groundwater recharge, sea-level rise and human activities. Assessment of the intrinsic vulnerability of groundwater under climate scenarios was performed for the aquifer area by utilising the results of a published study on the impacts of climate change on groundwater recharge and sea-level rise on groundwater–seawater interaction. Three intrinsic vulnerability mapping methods, the aquifer vulnerability index (AVI), a modified SINTACS and GALDIT, were applied and compared. According to the results, the degree of groundwater vulnerability is greatly impacted by seasonal variations in groundwater recharge during the year, and also varies depending on the climate-change variability in the long term. The groundwater is potentially highly vulnerable to contamination from sources on the ground surface during high groundwater recharge rates after snowmelt, while a high vulnerability to seawater intrusion could exist when there is a low groundwater recharge rate in dry season. The AVI results suggest that a change in the sea level will have an insignificant impact on groundwater vulnerability compared with the results from the modified SINTACS and GALDIT. The modified SINTACS method could be used as a guideline for the groundwater vulnerability assessment of glacial and deglacial deposits in inland aquifers, and in combination with GALDIT, it could provide a useful tool for assessing groundwater vulnerability to both contamination from sources on the ground surface and to seawater intrusion for shallow unconfined low-lying coastal aquifers under future climate-change conditions.  相似文献   

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