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1.
Wetlands often form the transition zone between upland soils and watershed streams, however, stream–wetland interactions and hydrobiogeochemical processes are poorly understood. We measured changes in stream nitrogen (N) through one riparian wetland and one beaver meadow in the Archer Creek watershed in the Adirondack Mountains of New York State, USA from 1 March to 31 July 1996. In the riparian wetland we also measured changes in groundwater N. Groundwater N changed significantly from tension lysimeters at the edge of the peatland to piezometer nests within the peatland. Mean N concentrations at the peatland perimeter were 1·5, 0·5 and 18·6 µmol L?1 for NH4+, NO3? and DON (dissolved organic nitrogen), respectively, whereas peatland groundwater N concentration was 56·9, 1·5 and 31·6 µmol L?1 for NH4+, NO3? and DON, respectively. The mean concentrations of stream water N species at the inlet to the wetlands were 1·5, 10·1 and 16·9 µmol L?1 for NH4+, NO3? and DON, respectively and 1·6, 28·1 and 8·4 µmol L?1 at the wetland outlet. Although groundwater total dissolved N (TDN) concentrations changed more than stream water TDN through the wetlands, hydrological cross‐sections for the peatland showed that wetland groundwater contributed minimally to stream flow during the study period. Therefore, surface water N chemistry was affected more by in‐stream N transformations than by groundwater N transformations because the in‐stream changes, although small, affected a much greater volume of water. Stream water N input–output budgets indicated that the riparian peatland retained 0·16 mol N ha?1 day?1 of total dissolved N and the beaver meadow retained 0·26 mol N ha?1 day?1 during the study period. Nitrate dominated surface water TDN flux from the wetlands during the spring whereas DON dominated during the summer. This study demonstrates that although groundwater N changed significantly in the riparian peatland, those changes were not reflected in the stream. Consequently, although in‐stream changes of N concentrations were less marked than those in groundwater, they had a greater effect on stream water chemistry—because wetland groundwater contributed minimally to stream flow. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

2.
Canada's post‐mined oil sands will have a higher concentration of salts compared with freshwater peatlands that dominate the landscape. While rare, naturally occurring saline wetlands do exist in Alberta's Boreal Plains and may function as analogues for reclamation, however, little is known about their hydrology. This paper investigates the geochemical and hydrologic characteristics of a natural saline‐spring peatland in Alberta's oil sands region. The fen is located within a saline groundwater discharge area connected to the erosional edge of the Grand Rapids Formation. Na+ (195–25,680 mgl?1) and Cl? (1785–56,249 mg l?1) were the dominant salts, and the fen transitioned sharply to freshwater along its margins because in part of subsurface mineral ridges that restricted shallow groundwater exchange. Salinity decreased from hypersaline to brackish along the local groundwater flow path but no active spring outlets were observed over the two‐year study. Vertical groundwater discharge was minimal because of the very low permeability of the underlying sediments. Subsurface storage was exceeded during periods of high flow, resulting in flooding and surface runoff that was enhanced by the ephemerally connected pond network. These findings have implications for reclamation, as mechanisms such as subsurface mineral ridges may function as effective saline groundwater‐control structures in the post‐mined environment. Incorporating saline wetlands into regional monitoring networks will help to better quantify natural discharge, which has implications for belowground wastewater storage related to in situ bitumen extraction. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

3.
The proposed harvesting of previously undeveloped forests in north coastal British Columbia requires an understanding of hydrological responses. Hydrometric and isotopic techniques were used to examine the hydrological linkages between meteoric inputs to the surface‐groundwater system and runoff response patterns of a forest‐peatland complex. Quickflow accounted for 72–91% of peak storm discharge. The runoff ratio was lowest for open peatland areas with thick organic horizons (0·02–0·05) due to low topographic gradients and many surface depressions capable of retaining surface water. Runoff ratio increased comparatively for ephemeral surface seep flows (0·06–0·40) and was greatest in steeply sloping forest communities with more permeable soils (0·33–0·69). The dominant mechanism for runoff generation was saturated shallow subsurface flow. Groundwater fluxes from the organic horizon of seeps (1·70–1·72 m3 day?1 m?1) were an important component of quickflow. The homogeneous δ2H? δ18O composition of groundwater indicated attenuation of the seasonal rainfall signal by mixing during recharge. The positive correlation (r2 = 0·64 and 0·38, α = 0·05) between slope index and δ18O values in groundwater suggests that the spatial pattern in the δ18O composition along the forest‐peatland complex is influenced by topography and provides evidence that topographic indices may be used to predict groundwater residence time. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

4.
Alan R. Hill 《水文研究》1990,4(2):121-130
Groundwater cation concentrations in relation to hydrologic flow paths were studied in the riparian forest zone of a small headwater catchment near Toronto, Ontario. Groundwater entering the riparian zone from uplands showed significant differences in cation concentrations between slope-foot and near-stream locations. Mean Ca, Mg, K, and Na concentrations in shallow groundwater at the upland perimeter of the riparian forest were 65-0, 11-2, 0-7, and 1-8 mg L?1 respectively. Mean Ca, Mg, K, and Na concentrations in deep groundwater flowing upwards through glacial sands beneath the riparian zone were 52-1, 15-1, 1-3, and 2-6 mg L?1 respectively. Shallow groundwater emerged as slope-foot springs producing surface rivulets which crossed the riparian zone to the streams. Deep groundwater flowed upward through organic soils into the rivulets and also discharged directly to the streams as bed and bank seepage. Springs had higher Ca concentrations and lower Mg, K, and Na values than rivulets entering the streams. Conversely, Mg, K, and Na concentrations were higher and Ca concentrations were lower in bank seeps in comparison to rivulets. These results suggest that differences in cation concentrations in groundwater entering the streams result from initial contrast in the chemistry of shallow and deep groundwater rather than from the effects of riparian soils and vegetation.  相似文献   

5.
Waterborne carbon (C) export from terrestrial ecosystems is a potentially important flux for the net catchment C balance and links the biogeochemical C cycling of terrestrial ecosystems to their downstream aquatic ecosystems. We have monitored hydrology and stream chemistry over 3 years in ten nested catchments (0.6–15.1 km2) with variable peatland cover (0%–22%) and groundwater influence in subarctic Sweden. Total waterborne C export, including dissolved and particulate organic carbon (DOC and POC) and dissolved inorganic carbon (DIC), ranged between 2.8 and 7.3 g m–2 year–1, representing ~10%–30% of catchment net ecosystem exchange of CO2. Several characteristics of catchment waterborne C export were affected by interacting effects of peatland cover and groundwater influence, including magnitude and timing, partitioning into DOC, POC, and DIC and chemical composition of the exported DOC. Waterborne C export was greater during the wetter years, equivalent to an average change in export of ~2 g m–2 year–1 per 100 mm of precipitation. Wetter years led to a greater relative increase in DIC export than DOC export due to an inferred relative shift in dominance from shallow organic flow pathways to groundwater sources. Indices of DOC composition (SUVA254 and a250/a365) indicated that DOC aromaticity and average molecular weight increased with catchment peatland cover and decreased with increased groundwater influence. Our results provide examples on how waterborne C export and DOC composition might be affected by climate change. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

6.
Biologically mediated redox processes in the riparian zone, like denitrification, can have substantially beneficial impacts on stream water quality. The extent of these effects, however, depends greatly on the hydrological boundary conditions. The impact of hydrological processes on a wetland's nitrogen sink capacity was investigated in a forested riparian fen which is drained by a first‐order perennial stream. Here, we analysed the frequency distributions and time‐series of pH and nitrogen, silica, organic carbon and oxygen concentrations in throughfall, soil solution, groundwater and stream water, and the groundwater levels and stream discharges from a 3‐year period. During baseflow conditions, the stream was fed by discharging shallow, anoxic groundwater and by deep, oxic groundwater. Whereas the latter delivered considerable amounts of nitrogen (～0·37 mg l?1) to the stream, the former was almost entirely depleted of nitrogen. During stormflow, near‐surface runoff in the upper 30 cm soil layer bypassed the denitrifying zone and added significant amounts to the nitrogen load of the stream. Nitrate‐nitrogen was close to 100% of deep groundwater and stream‐water nitrogen concentration. Stream‐water baseflow concentrations of nitrate, dissolved carbon and silica were about 1·6 mg l?1, 4 mg l?1 and 7·5 mg l?1 respectively, and >3 mg l?1, >10 mg l?1 and <4 mg l?1 respectively during discharge peaks. In addition to that macroscale bypassing effect, there was evidence for a corresponding microscale effect: Shallow groundwater sampled by soil suction cups indicated complete denitrification and lacked any seasonal signal of solute concentration, which was in contrast to piezometer samples from the same depth. Moreover, mean solute concentration in the piezometer samples resembled more that of suction‐cup samples from shallower depth than that of the same depth. We conclude that the soil solution cups sampled to a large extent the immobile soil‐water fraction. In contrast, the mobile fraction that was sampled by the piezometers exhibited substantially shorter residence time, thus being less exposed to denitrification, but predominating discharge of that layer to the stream. Consequently, assessing the nitrogen budget based on suction‐cup data tended to overestimate the nitrogen consumption in the riparian wetland. These effects are likely to become more important with the increased frequency and intensity of rainstorms that are expected due to climate change. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

7.
From 2011 to 2019, mercury (Hg) stores and fluxes were studied in the small forested catchment Lesní potok (LES) in the central Czech Republic using the watershed mass balance approach together with internal measurements. Mean input fluxes of Hg via open bulk deposition, beech throughfall and spruce throughfall during the periodwere 2.9, 3.9 and 7.6 μg m−2 year−1, respectively. These values were considerably lower than corresponding deposition Hg fluxes reported in the early years of the 21st century from catchments in Germany. Current bulk precipitation inputs at unimpacted Czech mountainous sites were lower than those in Germany. The largest Hg inputs to the catchment were via litterfall, averaging 22.6 and 17.8 μg m−2 year−1 for beech and spruce stands. The average Hg input, based on the sum of mean litterfall and throughfall deposition, was 23.0 μg m−2 year−1, compared to the estimated Hg output in runoff of 0.5 μg m−2 year−1, which is low compared to other reported values. Thus, only ~2% of Hg input is exported in stream runoff. Stream water Hg was only weakly related to dissolved organic carbon (DOC) but both concentrations were positively correlated with water temperature. The estimated total soil Hg pool averaged 47.5 mg m−2, only 4% of which was in the O-horizon. Thus Hg in the O-horizon pool represents 72 years of deposition at the current input flux and 3800 years of export at the current runoff flux. Age-dating by 14C suggested that organic soil contains Hg from recent deposition, while mineral soil at 40–80 cm depth contained 4400-year old carbon, suggesting the soil had accumulated atmospheric Hg inputs through millennia to reach the highest soil Hg pool of the soil profile. These findings suggest that industrial era intensification of the Hg cycle is superimposed on a slower-paced Hg cycle during most of the Holocene.  相似文献   

8.
Runoff generated from large storm events, such as hurricanes, is expected to transport large quantities of suspended sediment. Observations of suspended-sediment loads transported during Hurricane Hugo in the Lago Loìza (Lake Loiza) basin, Puerto Rico, indicate that loads were lower than expected. In the two main tributaries that enter Lago Loìza, Rio Grande de Loìza and Rio Gurabo, 99 600 tonnes of suspended sediment was transported by 58·2 × 106 m3 of runoff in a 48 h period. The storm-average suspended-sediment concentration in the Río Grande de Loìza for Hurricane Hugo was 2290 mgl−1, the second lowest for the 12 storms that have been monitored at this site. In Río Gurabo the storm-average suspended-sediment concentration was 1420 mgl−1, the sixth lowest recorded out of 15 monitored storms. In Quebrada Salvatierra, a small tributary to Río Grande de Loìza, suspended-sediment concentrations were as low as 33 mgl−1 during the peak runoff of 20 m3 s−1. Normally the suspended-sediment concentrations at this discharge are 3000 mgl−1. Hurricane force winds seem to be the most important factor contributing to the lower than expected suspended-sediment loads in the Lago Loìza basin. The high winds caused vegetation and debris to be dislodged and displaced. Debris accumulated on hillslopes and in small channels, blocked bridges and formed debris dams. These dams caused local backwater effects that reduced stream velocities and decreased suspended-sediment loads.  相似文献   

9.
The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay‐rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two‐year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 1·10?7 to 3·10?9 m.s?1) and does not form a hydraulic barrier. Moreover, the vertical hydraulic gradients are downward between the peat and the sand aquifer, leading to high flows of groundwater through the clay layer (20–48% of the precipitation). The observed hydric deficit of the peatland results from a combination of dry climatic conditions during the study period and groundwater extraction. The climatic effect is mainly expressed through drying out of the peatland, while the anthropogenic effect leads to an enhancement of the climatic effect on a global scale, and a modification of fluxes at a local scale. The drying out of the peatland can lead to its mineralisation, which thus gives rise to environmental impacts. The protection of such wetlands in the context of climate change should take account of anthropogenic pressures by considering the wetland‐aquifer interaction. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

10.
Dissolved organic carbon export from a cutover and restored peatland   总被引：1，自引：0，他引：1  
High demand for horticultural peat has increased peatland drainage and peat extraction in Canada. The hydrology and carbon cycling of these cutover peatlands is greatly altered, necessitating active restoration efforts to permit the regeneration of Sphagnum mosses and the re‐establishment of natural peatland function. The effect of peatland extraction and restoration on the export of dissolved organic carbon (DOC) was examined for three successive seasons (May to October, 1999 to 2001) at two different sites (cutover and restored) in eastern Québec. A shift towards higher DOC concentrations was observed following peatland extraction (maximum: 182·6 mg L?1) and concentrations remained high post‐restoration (maximum: 191·0 mg L?1). The cutover site exported more DOC than the restored site in all three study seasons. The highest exports occurred during the wettest year (1999), with cutover and restored site export of 10·3 and 4·8 g m?2, respectively. In 2000, 8·5 g C m?2 was released from the cutover site, while the restored site released less than half that amount (3·4 g C m?2). In 2001, the restored site released about the same amount of DOC as in the previous year (3·5 g C m?2), while the cutover site load dropped to 6·2 g C m?2. Both sites were net exporters of DOC in all years. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

11.
The mid‐ to high‐boreal forest in Canada occupies the discontinuous permafrost zone, and is often underlain by glaciolacustrine sediments mantled by a highly porous organic mat. The result is a poorly drained landscape dominated by wetlands. Frost‐table dynamics and surface storage conditions help to control runoff contributions from various landscape elements, hydrological linkages between these elements, and basin streamflow during spring snowmelt. Runoff components and pathways in a forested peatland basin were assessed during two spring snowmelts with contrasting input and basin conditions. Runoff from relatively intense melt (up to 16 mm day?1) on slopes with limited soil thawing combined with large pre‐melt storage in surface depressions to produce high flows composed primarily of meltwater (78% of the 0·29 m3 s?1 peak discharge) routed over wetland surfaces and through permeable upper peat layers. Melt intensity was less in the subsequent year (maximum of 10 mm day?1) and active layer development was relatively greater (0·2 m deeper at the end of spring melt), resulting in less slope runoff. Coupling of reduced slope contributions with lower storage levels in basin wetlands led to relatively subdued streamflows dominated by older water (73% of the 0·09 m3 s?1 peak discharge) routed through less‐permeable deeper peat layers and mineral soil. Interannual differences in runoff conditions provide important insight for the development of distributed hydrological models for boreal forest basins and into potential influences on biogeochemical cycling in this landscape under a warming climate. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

12.
The lake without any outlet (11 ha, 55000 m3, zmax 2,25 m) has a weak thermal stratification with maximum surface temperatures of 32.5 °C. The annual variation of temperature and depth of visibility is unimodal, with the maxima or minima in August. Phytoplankton consists mainly of Cyanophyceae. The primary production determined by the light-dark bottle technique (oxygen method) varies in the annual variation between 0.3… 0.5 g m?2 d?1 C (winter) and 3.4… 4.6 g m?2 d?1 C (summer); as the annual means of 1975 and 1976 there were found 1.9 and 2.4 g m?2 d?1 C, resp., gross production at a utilization of 0.42… 2.85% of the radiation energy. The chemism is a well-buffered hydrogen-carbonate water (pH 8.1… 9.0) with 74… 90 mg/1 Na and 20.5… 31.5 mg/1 K and with a good nutrient supply (20… 40 μg/1 PO4—P and 100… 240 μg/1 NO3—N) at the same time.  相似文献   

13.
A hydrological investigation was conducted in a small headwater peatland located in the Experimental Lakes Area, north-western Ontario, Canada, to determine the subsurface and surface flow paths within the peatland, and between the peatland and an adjacent forested upland during baseflow and storm flow conditions. Distinct zones of groundwater recharge and discharge were observed within the peatland. These zones are similar to those found in much larger flow systems even though the peatland was only influenced by local groundwater flow. Groundwater emerging in seeps and flowing beneath the peatland sustained the surface wetness of the peatland and maintained a constant baseflow. The response of the peatland stream to summer rain events was controlled by peatland water table position when the basin was dry and antecedent moisture storage on the uplands when the basin was wet. The magnitude and timing of peak runoff during wet conditions were controlled by the degree of hydrological connectivity between the surrounding upland terrain and the peatland. © 1998 John Wiley & Sons, Ltd.  相似文献   

14.
To ascertain the influence of hydrological boundary conditions on acidity fluxes in lakes influenced by acid mine drainage, acidity budgets were developed for two sediments in areas of differential groundwater inflow (approx. 1 L m?2 d?1 and 10 L m?2 d?1). In both sediments iron was deposited as schwertmannite leading to iron(III) enriched sediments (3.9…6.2 mmol g?1, referred to dry weight). Compared to the surface water, the inflowing groundwater had higher pH (4.5 vs. 3), ferrous iron (6…20 mmol L?1 vs. 0.8…2.0 mmol L?1), and sulfate (5…60 mmol L?1 vs. 8…13 mmol L?1) concentrations. The inflow changed the sediment pore water chemistry and triggered a further increase in pH to above 5.5. In both sediments acidity generation in the surface water (10…30 mol m?2 a?1) strongly prevailed over acidity consumption in the sediments (> ?0.6 mol m?2 a?1). With advective groundwater inflow, however, more acidity was consumed due to TRIS formation (?0.12 mol m?2 a?1 vs. ?0.017 mol m?2 a?1), iron carbonate burial (upper estimate: ?0.14 mol m?2 a?1 vs. ?0.022 mol m?2 a?1), and unspecific ferrous iron retention (?0.39 mol m?2 a?1 vs. ?0.08 mol m?2 a?1). Also, less acidity was generated due to schwertmannite transformation (?2.4 mol m?2 a?1 vs. ?0.11 mol m?2 a?1). The acidity balance of internal processes in the sediment with groundwater inflow was negative, whereas it was positive in the other sediment. The study demonstrates that in acidic and iron rich lakes the hydrological boundary conditions strongly affect geochemical processes as subsumed in acidity fluxes.  相似文献   

15.
Discharge in mountain streams may be a mixture of snowmelt, water from surface runoff, and deep return flow through valley bottom alluvia. We used δ18O and δ2H, solute concentrations, and 222Rn to determine water sources of a headwater stream located at the McDonald Creek watershed, Glacier National Park, USA, during summer recession flow period. We analysed minimal water isotope ranges of ?17.6‰ to ?16.5‰ and ?133‰ to ?121‰ for δ18O and δ2H, respectively, potentially due to dominance of snow‐derived water in the stream. Likewise, solute concentrations measured in the stream through the watershed showed minimal variation with little indication of subsurface water input into the stream. However, we observed 222Rn activities in the stream that ranged from 39 to 2646 Bq/m3 with the highest value measured in middle of the watershed associated with channel constriction corresponding to changes in local orientation of underlying rocks. Downstream from this point, 222Rn activity decreased from 581 to 117 Bq/m3 in a series of punctuated steps associated with small rapids and waterfalls that we hypothesized to cause radon degassing with a maximum predicted loss of 427 Bq/m3 along a 400 m distance. Based on mass balance calculations using 222Rn activity values, streamflow, and channel characteristics, we estimated that groundwater contributed between 0.3% and 29% of total flow. Overall, we estimated a 5.9% of groundwater contribution integrated for stream reach measured at McDonald Creek during recession flow period. Finally, a lower mean hyporheic flux of 14 m3/day was estimated compared to the groundwater flux of 70 710 m3/day. These assessments highlight the potential for radon as a conservative tracer that can be used to estimate subsurface water contribution in mountain streams within a complex geologic setting. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

16.
The objective of this paper is to quantify, and enable the prediction of, sediment delivery and water pollution impacts from a spectrum of forest roads. Ten 100–200 m long sections of forest road were selected to incorporate a wide range of the key physical site factors that are likely to affect the rate of sediment generation. Each road section was permanently instrumented for 1 year to measure rainfall and runoff continuously. Suspended load, bedload, and traffic were integrated measurements over 2‐ to 3‐week site‐service intervals. Total annual sediment load (normalized for slope) varied about 25‐fold, from 216 mg m?2 per millimetre of rain for a high‐quality gravel surfaced road with minimal traffic to 5373 mg m?2 per millimetre of rain for an unsurfaced road on an erodible subsoil with moderate light‐vehicle traffic. For the seven gravel‐surfaced roads in this study, truck traffic (axles/week) explained 97% of the variation in annual sediment delivery (per unit of rainfall) from the road. Equations are proposed that allow annual sediment delivery rates to be estimated when net rainfall, road slope, road area, and truck traffic are known. Roads produce runoff rapidly and were found to deliver sediment for about the same duration as rainfall is falling, in this study varying between 5 and 10% of the time. The patterns of sediment delivery measured from the experimental roads (frequency, duration, and intensity) in this study are similar to levels that have been shown to alter the composition of in‐stream macroinvertebrate communities in small (e.g. <10 l s?1), clean, mountain streams. However, in larger well‐mixed streams (e.g. >500 l s?1), dilution is sufficient to prevent concentrations reaching critical levels that are likely to result in biological impacts. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

17.
Entrapped gas bubbles in peat can alter the buoyancy, storativity, void ratio and expansion/contraction properties of the peat. Moreover, when gas bubbles block water‐conducting pores they can significantly reduce saturated hydraulic conductivity and create zones of over‐pressuring, perhaps leading to an alteration in the magnitude and direction of groundwater flow and solute transport. Some previous researches have demonstrated that these zones of over‐pressuring are not observed by the measurements of pore‐water pressures using open‐pipe piezometers in peat; rather, they are only observed with pressure transducers sealed in the peat. In has been hypothesized that open‐pipe piezometers vent entrapped CH4 to the atmosphere and thereby do not permit the natural development of zones of entrapped gas. Here we present findings of the study to investigate whether piezometers vent subsurface CH4 to the atmosphere and whether the presence of piezometers alters the subsurface concentration of dissolved CH4. We measured the flux of methane venting from the piezometers and also determined changes in pore‐water CH4 concentration at a rich fen in southern Ontario and a poor fen in southern Quebec, in the summer of 2004. Seasonally averaged CH4 flux from piezometers was 1450 and 37·8‐mg CH4 m?2 d?1 at the southern Ontario site and Quebec site, respectively. The flux at the Ontario site was two orders of magnitude greater than the diffusive flux at the site. CH4 pore‐water concentrations were significantly lower in open piezometers than in water taken from sealed samplers at both the Ontario and Quebec sites. The flux of CH4 from piezometers decreased throughout the season suggesting that CH4 venting through the piezometer exceeded the rate of methanogenesis in the peat. Consequently we conclude that piezometers may alter the gas dynamics of some peatlands. We suggest that less‐invasive techniques (e.g. buried pressure transducers, tracer experiments) are needed for the accurate measurement of pore‐water pressures and hydraulic conductivity in peatlands with a large entrapped gas component. Furthermore, we argue that caution must be made in interpreting results from previous peatland hydrology studies that use these traditional methods. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

18.
A two‐dimensional variable‐density groundwater flow and transport model was developed to provide a conceptual understanding of past and future conditions of nitrate (NO3) transport and estimate groundwater nitrate flux to the Gulf of Mexico. Simulation results show that contaminant discharge to the coast decreases as the extent of saltwater intrusion increases. Other natural and/or artificial surface waters such as navigation channels may serve as major sinks for contaminant loading and act to alter expected transport pathways discharging contaminants to other areas. Concentrations of NO3 in the saturated zone were estimated to range between 30 and 160 mg?L?1 as NO3. Relatively high hydraulic vertical gradients and mixing likely play a significant role in the transport processes, enhancing dilution and contaminant migration to depth. Residence times of NO3 in the deeper aquifers vary from 100 (locally) to about 300 years through the investigated aquifer system. NO3 mass fluxes from the shallow aquifers (0 to 5.7 × 104 mg?m?2?day?1) were primarily directed towards the navigation channel, which intersects and captures a portion of the shallow groundwater flow/discharge. Direct NO3 discharge to the sea (i.e. Gulf of Mexico) from the shallow aquifer was very low (0 to 9.0 × 101 mg · m?2?day?1) compared with discharge from the deeper aquifer system (0 to 8.2 × 103 mg?m?2?day?1). Both model‐calibrated and radiocarbon tracer‐determined contaminant flux estimates reveal similar discharge trends, validating the use of the model for density‐dependent flow conditions. The modelling approach shows promise to evaluate contaminant and nutrient loading for similar coastal regions worldwide. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

19.
Analytical modelling of heat transport was used to address effects of uncertainty in thermal conductivity on groundwater–surface water exchange. In situ thermal conductivities and temperature profiles were measured in a coastal lagoon bed where groundwater is known to discharge. The field site could be divided into three sediment zones where significant spatial changes in thermal conductivity on metre to centimetre scale show that spatial variability connected to the sediment properties must be considered. The application of a literature‐based bulk thermal conductivity of 1.84 Wm?1 °C?1, instead of field data that ranged from 0.62 to 2.19 W m?1 °C?1, produced a mean overestimation of 2.33 cm d?1 that, considering the low fluxes of the study area, represents an 89% increase and up to a factor of 3 in the most extreme cases. Incorporating the uncertainty due to sediment heterogeneities leads to an irregular trend of the flux distribution from the shore towards the lagoon. The natural variability of the thermal conductivity associated with changes in the sediment composition resulted in a mean variation of ±0.66 cm d?1 in fluxes corresponding to a change of ±25.4%. The presence of organic matter in the sediments, a common situation in the near‐shore areas of surface water bodies, is responsible for the decrease of thermal conductivity. The results show that the natural variability of sediment thermal conductivity is a parameter to be considered for low flux environments, and it contributes to a better understanding of groundwater–surface water interactions in natural environments. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

20.
Danube river water samples were saturated with mineral oil, and then the primary production (gross) was determined by means of the light-dark bottle method (oxygen) in situ at depths of 0.1… 1.5 m in comparison with untreated samples. Samples were exposed for half a solar day alternately during the first and second half-days. Investigations carried out between March and October for periods of 14 days showed a mean production of 2.56 g · m?2d?1 O2, which was reduced by 36% due to 12.6 mg/l hydrocarbons. Production decreases with the water depth from 6.2 to 0.9 mg · l?1d?1 02, whereas the inhibition by hydrocarbons increases from 31 to 41%.  相似文献   

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