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1.
In the frame of the R&D activities performed on the Boom Clay for assessing the suitability of deep clayey formations for radioactive waste disposal, the transferability of the scientific results obtained on the Boom Clay in Mol to the whole Campine Basin is investigated. Boreholes were drilled at different locations (e.g. Mol, Doel, Essen) and cores were sampled over the entire thickness of the Boom Clay formation on which the migration parameters for iodide and tritiated water (HTO) are determined.At Essen, the transport parameters in the Boom Clay can be considered as homogeneous in the range from 159 m to 241 m Below Drilling Table. The average hydraulic conductivity is (5.4 ± 1.7) × 10−12 m/s. The average ηR value for iodide is 0.25 ± 0.03 and 0.42 ± 0.05 for HTO. For HTO, this high value is mainly due to a higher value in the Putte Member (0.46 ± 0.03) compared to the other members (0.39 ± 0.02). The apparent diffusion coefficient is (1.3 ± 0.1) × 10−10 m2/s for HTO and (1.1 ± 0.2) × 10−10 m2/s for iodide. The expected effect of ionic strength (increasing with depth) on the ηR value of iodide is of the same size as the measurement error, what might explain why it was not observed.On a lateral (horizontal) level, the hydraulic conductivity at the Essen-1 borehole (5.4 × 10−12 m/s) lies between that of Boom Clay in Mol-1 (2.5 × 10−12 m/s) and that of Boom Clay in Doel-2b (1.4 × 10−11 m/s). For iodide, the higher ηR value in Essen-1 and Doel-2b (ηR ≈ 0.25) than in Mol-1 (ηR ≈ 0.16) can partly be explained by a higher ionic strength of the pore water. Apart from the Putte Member at Essen-1, the HTO porosities of the Terhagen Member and the Transition zone in Essen are in the range of the average porosities observed in Mol and Doel (ηR ≈ 0.37–0.39). For both iodide and HTO, the value of the apparent diffusion coefficient Dapp is similar in Mol-1 and in Doel-2b, with a clearly higher value for HTO than for iodide. In Essen-1, the apparent diffusion coefficients for iodide and HTO are nearly equal, and slightly smaller than the iodide value in Mol-1/Doel-2b. Accordingly, the HTO apparent diffusion coefficient is considerably smaller in Essen-1 than in Mol-1/Doel-2b.  相似文献   

2.
《Journal of Geodynamics》2007,43(1):170-186
Stratigraphic and sedimentological studies indicate that Iceland has experienced over 20 glaciations during the last 4–5 Myr, in reasonable agreement with the number of glaciations reconstructed from the ∂18O record in deep-sea sediment. The pattern of glacial erosion was to a large part controlled by constructive volcanic processes resulting in increased topographic relief after 2.5 Myr. Between 2.5 and 0.5 Ma valleys up to 400 m deep were excavated into the Tertiary basalts of eastern and south Iceland with an average erosion rate of 10–20 cm ka−1. During the last 0.5 million years rates of erosion increased to 50–175 cm ka−1, with an additional 200 to over 1000 m of valley excavation. Previous estimates of the rate of landscape erosion during the Holocene vary widely, from 5 to 70,000 cm ka−1. We present new studies that define the rates of landscape denudation during the major part of the Holocene (the last 10,200 years): one based on the Iceland shelf sediment record, the other from the sediment record in the glacier-fed lake, Hvítárvatn. Both studies indicate average Holocene erosion rates of about 5 cm ka−1 similar to our erosion rate estimate for 4–5 Ma old strata that has not been subjected to regional glaciation.  相似文献   

3.
The Loncopué Trough is located in the hinterland Andean zone between 36°30′ and 39°S. It constitutes a topographic low bounded by normal faults and filled by lavas and sediments less than 5 Ma old. Reprocessed seismic lines show wedge-like depocenters up to 1700 m deep associated with high-angle faults, correlated with the 27–17 Ma Cura Mallín basin deposits, and buried beneath Pliocene to Quaternary successions and Late Miocene foreland sequences. The southern Central Andes seem to have been under extension in the hinterland zone some 27 Ma ago and again at approximately 5 Ma ago. This last extensional period could have been the product of slab steepening after a shallow subduction cycle in the area, although other alternatives are discussed. Orogenic wedge topography, altered by the first extensional stage in the area, was recovered through Late Miocene inversion, and was associated with foreland sequences. However, since the last extension (<5 Ma) the Andes have not recovered their characteristic contractional behavior that controlled past orogenic growth.  相似文献   

4.
The aim of this paper concerns Miocene igneous activity in the Alboran Sea and Peri-Alboran area (northern Morocco, western Algeria and Betic Cordilleras in Spain), considering its age and its location with regard to major tectonics structures.We have compiled previous K-Ar isotopic ages of lavas and plutonic boulders and intrusives with an error of ±1σ and completed this set by a new K-Ar isotopic age for andesitic tuffites from Alboran Island. Geochemistry of most of these samples has been considered after previous analyses completed with new data for Spain magmatism. These two sets of data allow us to place the magmatic activity within the regional stratigraphy and tectonics and their chronological framework of the three major tectonic phases of the Maghrebian orogen, at 17 Ma (Burdigalian), 15 Ma (Langhian) and 9 Ma (Tortonian). Petro-geochemical characteristics are compared through time and geographical locations. A major goal of this coupled approach is to help the elaboration of possible geodynamical processes.As an application, we present the case study of the Dellys, Djinet and Thenia region (east of Algiers) where the successive magmatic events between 19.4 ± 1 and 11.6 ± 0.5 Ma are closely related to the local tectonics and sedimentation.The Peri-Alboran igneous activity is placed in a multidisciplinary framework. Timing of activity is defined according to the ages of the neighbouring sedimentary units and the K-Ar ages of igneous rocks.In Spain, the Cabo de Gata-Carboneras magmatic province displays late Oligocene and early Miocene leucogranitic dikes, dated from 24.8 ± 1.3 to 18.1 ± 1.2 Ma; three following andesitic to rhyolitic events took place around 15.1 ± 0.8 to 14.0 ± 0.7 Ma, 11.8 ± 0.6 to 9.4 ± 0.4 Ma, 8.8 ± 0.4 to 7.9 ± 0.4 Ma; this last event displays also granitic rocks. Lamproitic magmas dated between 8.4 ± 0.4 and 6.76 ± 0.04 Ma were emplaced after the Tortonian phase.In Morocco, after the complex building of the Ras Tarf volcanic edifice, major calc-alkaline to shoshonitic volcanoes were built between 9.0 ± 0.5 and 4.8 ± 0.5 Ma, in particular the large Gourougou volcanic complex. Near Oujda, volcanic activity of alkaline affinity leads to multiple emissions of basalts throughout Pliocene times until the beginning of Pleistocene, between 6.2 ± 0.3 and 1.5 ± 0.1 Ma.In the Alboran domain, an age of 19.7 ± 0.8 Ma is reported (this study) for the andesitic tuffites that form the emergent part of the Alboran Island. This age is comparable to that of the Algerian tuffites and cherts “silexites” and the Malaga ones in Spain. Younger activity, completely separated from the previous one, forms the low-K basaltic andesitic dikes from Alboran Island, dated between 9.1 ± 0.5 and 7.5 ± 0.3 Ma. Along the Alboran Ridge both low-K and high-K andesites to dacites were emitted in the estimated range of 10.7–8.7 Ma. Low-K and high-K andesites to dacites sampled at ODP sites 977 and 978 into the East Alboran Basin, are dated between 12.1 ± 0.2 and 9.3 ± 0.1 Ma.We propose to relate with the Trans-Alboran lineament only the post-Tortonian igneous activity younger than 9 Ma.  相似文献   

5.
Investigations to understand linkages among climate, erosion and weathering are central to quantifying landscape evolution. We approach these linkages through synthesis of regolith data for granitic terrain compiled with respect to climate, geochemistry, and denudation rates for low sloping upland profiles. Focusing on Na as a proxy for plagioclase weathering, we quantified regolith Na depletion, Na mass loss, and the relative partitioning of denudation to physical and chemical contributions. The depth and magnitude of regolith Na depletion increased continuously with increasing water availability, except for locations with mean annual temperature < 5 °C that exhibited little Na depletion, and locations with physical erosion rates < 20 g m? 2 yr? 1 that exhibited deep and complete regolith Na depletion. Surface Na depletion also tended to decrease with increasing physical erosion. Depth-integrated Na mass loss and regolith depth were both three orders of magnitude greater in the fully depleted, low erosion rate sites relative to other locations. These locations exhibited strong erosion-limitation of Na chemical weathering rates based on correlation of Na chemical weathering rate to total Na denudation. Sodium weathering rates in cool locations with positive annual water balance were strongly correlated to total Na denudation and precipitation, and exhibited an average apparent activation energy (Ea) of 69 kJ mol? 1 Na. The remaining water-limited locations exhibited kinetic limitation of Na weathering rates with an Ea of 136 kJ mol? 1 Na, roughly equivalent to the sum of laboratory measures of Ea and dissolution reaction enthalpy for albite. Water availability is suggested as the dominant factor limiting rate kinetics in the water-limited systems. Together, these data demonstrate marked transitions and nonlinearity in how climate and tectonics correlate to plagioclase chemical weathering and Na mass loss.  相似文献   

6.
In the central Western Alps, a combined structural, petrological and 40Ar–39Ar geochronological study of the Modane-Aussois and Southern Vanoise units yields important constraints on the timing of deformation and exhumation of the Briançonnais zone. These data help to decipher the respective roles of oceanic subduction, continental subduction and collision in the burial and exhumation of the main units through time. In the Modane-Aussois unit top to the NW thrusting (D1) was followed by top to the east shearing (D2) interpreted by some as normal faulting and by others as backthrusting. Pseudosection calculations imply that D1 deformation occurred at 1.0 ± 0.1 GPa and 350 ± 30 °C. Analysis of chlorite–phengite pairs yield P–T estimates between 0.15 and 0.65 GPa and between 220 and 350 °C for the D2 event. Phengites along the D1 schistosity (sample M80) yields an 40Ar–39Ar age of 37.12 ± 0.39 Ma, while D2 phengites yield ages of 35.42 ± 0.38 (sample M173) and 31.60 ± 0.33 Ma (sample M196). It was not possible to test whether these ages are altered by excess argon or not. Our interpretation is that the D1/D2 transition occurred at ∼37 Ma at the beginning of decompression, and that D2 lasted until at least ∼32 Ma. Pseudosection calculation suggests that the Southern Vanoise unit was buried at 1.6 ± 0.2 GPa and 500–540 °C. D1 deformation occurred during exhumation until 0.7–10.5 GPa and 370 ± 30 °C. Published ages suggest that D1 deformation possibly started at ∼50 Ma and lasted until ∼37 Ma. D2 deformations started at P–T conditions close to that recorded in Modane-Aussois unit and lasted until 0.2 ± 0.1 GPa and 280 ± 30 °C at ∼28 Ma. The gap of 0.6 ± 0.3 GPa and 150 ± 130 °C between peak metamorphic conditions in the two units was concealed by thrusting of the South Vanoise unit on top of the Modane-Aussois unit during D1 Deformation. Top to the east deformation (D2) affects both units and is interpreted as backthrusting.Based on these data, we propose a geodynamic reconstruction where the oceanic subduction of the Piedmont unit until ∼50 Ma, is followed by its exhumation at the time of continental subduction of the continental Southern Vanoise unit until ∼45 Ma. The Southern Vanoise is in turn underthrusted by the Modane-Aussois unit until ∼37 Ma (D1). Between 37 and 31 Ma the Modane-Aussois and Southern Vanoise units exhume together during backthrusting to the east (D2). This corresponds to the collision stage and to the activation of the Penninic Thrust. In the ∼50 Ma to ∼31 Ma time period the main thrusts propagated westward as the tectonic context switched from oceanic to continental subduction and finally to collision. During each stage, external units are buried while internal ones are exhumed.  相似文献   

7.
The Late Jurassic Kimmeridge Clay Formation (KCF) is an economically important, organic-rich source rock of Kimmeridgian–Early Tithonian age. The main rock types of the KCF in Dorset, UK, include grey to black laminated shale, marl, coccolithic limestone, and dolostone, which occur with an obvious cyclicity at astronomical timescales. In this study, we examine two high-resolution borehole records (Swanworth Quarry 1 and Metherhills 1) obtained as part of a Rapid Global Geological Events (RGGE) sediment drilling project. Datasets examined were total organic carbon (TOC), and borehole wall microconductivity by Formation Microscanner (FMS). Our intent is to assess the rhythmicity of the KCF with respect to the astronomical timescale, and to discuss the results with respect to other key Late Jurassic geological processes. Power spectra of the untuned data reveal a hierarchy of cycles throughout the KCF with ～ 167 m, ～ 40 m, 9.1 m, 3.8 m and 1.6 m wavelengths. Tuning the ～ 40 m cycles to the 405-kyr eccentricity cycle shows the presence of all the astronomical parameters: eccentricity, obliquity, and precession index. In particular, ～ 100-kyr and 405-kyr eccentricity cycles are strongly expressed in both records. The 405-kyr eccentricity cycle corresponds to relative sea-level changes inferred from sequence stratigraphy. Intervals with elevated TOC are associated with strong obliquity forcing. The 405-kyr-tuned duration of the lower KCF (Kimmeridgian Stage) is 3.47 Myr, and the upper KCF (early part of the Tithonian Stage, elegans to fittoni ammonite zones) is 3.32 Myr. Two other chronologies test the consistency of this age model by tuning ～ 8–10 m cycles to 100-kyr (short eccentricity), and ～ 3–5 m cycles to 36-kyr (Jurassic obliquity). The ‘obliquity-tuned’ chronology resolves an accumulation history for the KCF with a variation that strongly resembles that of Earth's orbital eccentricity predicted for 147.2 Ma to 153.8 Ma. There is evidence for significant non-deposition (up to 1 million years) in the lowermost KCF (baylei–mutabilis zones), which would indicate a Kimmeridgian/Oxfordian boundary age of 154.8 Ma. This absolute calibration allows assignment of precise numerical ages to zonal boundaries, sequence surfaces, and polarity chrons of the lower M-sequence.  相似文献   

8.
This study reconstructs the late stages in the exhumation history of a nappe derived from the Meliatic accretionary wedge in the Western Carpathians by means of zircon and apatite (U-Th)/He dating. The Meliatic accretionary wedge formed due to the closure of the Neotethyan Triassic–Jurassic Meliata–Hallstatt Ocean in the Late Jurassic. The studied fragments of the blueschist-bearing Meliatic Bôrka Nappe were metamorphosed at low-temperature and high- to medium-pressure conditions at ca. 160–150 Ma and included into the accretionary wedge. The time of the accretionary wedge formation constrains the beginning of the Bôrka Nappe northward thrusting over the Gemeric Unit of the evolving Central Western Carpathians (CWC) orogenic wedge. The zircon (U-Th)/He data on four samples recorded three evolutionary stages: (i) cooling through the ∼180 °C isotherm at 130–120 Ma related to starting collapse of the accretionary wedge, following exhumation of the high-pressure slices in the Meliatic accretionary wedge; (ii) postponed exhumation and cooling of some fragments through the ∼180 °C isotherm from 115 to 95 Ma due to ongoing collapse of this wedge; and (iii) cooling from 80 to 65 Ma, postdating the thrusting (∼100–80 Ma) of the Bôrka Nappe slices during the Late Cretaceous compression related to formation of the CWC orogenic wedge. The third stage already documents cooling of the Meliatic Bôrka Nappe slices in the CWC orogenic wedge. The apatite (U-Th)/He data may indicate cooling of a Bôrka Nappe slice to near-surface temperatures at ∼65 Ma. The younger AHe age clusters indicate that at least one, or possibly two, reheating events could have occurred in the longer interval from ∼40 to ∼10 Ma during the Oligocene–Miocene. These were related to sedimentary burial and/or the magmatism as documented in other parts of the CWC.  相似文献   

9.
The brittle/ductile transition is a major rheologic boundary in the crust yet little is known about how or if rates of tectonic processes are influenced by this boundary. In this study we examine the slip history of the large-scale Naxos/Paros extensional fault system (NPEFS), Cyclades, Greece, by comparing published slip rates for the ductile crust with new thermochronological constraints on slip rates in the brittle regime. Based on apatite and zircon fission-track (AFT and ZFT) and (U–Th)/He dating we observe variable slip rates across the brittle/ductile transition on Naxos. ZFT and AFT ages range from 11.8 ± 0.8 to 9.7 ± 0.8 Ma and 11.2 ± 1.6 to 8.2 ± 1.2 Ma and (U–Th)/He zircon and apatite ages are between 10.4 ± 0.4 to 9.2 ± 0.3 Ma and 10.7 ± 1.0 to 8.9 ± 0.6 Ma, respectively. On Paros, ZFT and AFT ages range from 13.1 ± 1.4 Ma to 11.1 ± 1.0 Ma and 12.7 ± 2.8 Ma to 10.5 ± 2.0 Ma while the (U–Th)/He zircon ages are slightly younger between 8.3 ± 0.4 Ma and 9.8 ± 0.3 Ma. All ages consistently decrease northwards in the direction of hanging wall transport. Most of our new thermochronological results and associated thermal modeling more strongly support the scenario of an identical fault dip and a constant or slightly accelerating slip rate of ∼ 6–8 km Myr− 1 on the NPEFS across the brittle/ductile transition. Even the intrusion of a large granodiorite body into the narrowing fault zone at ∼ 12 Ma on Naxos does not seem to have affected the thermal structure of the area in a way that would significantly disturb the slip rate. The data also show that the NPEFS accomplished a minimum total offset of ∼ 50 km between ∼ 16 and 8 Ma.  相似文献   

10.
In Switzerland the geological storage in the Opalinus Clay formation is the preferred option for the disposal of spent fuel (SF) and high-level radioactive waste (HLW). The waste will be encapsulated in steel canisters and emplaced into long tunnels that are backfilled with bentonite. Due to uncertainties in the depth of the repository and the associated stress state, a concrete liner might be used for support of emplacement tunnels.Numerical reactive transport calculations are presented that investigate the influence of a concrete liner on the adjacent barrier materials, namely bentonite and Opalinus Clay. The geochemical setup was tailored to the specific materials foreseen in the Swiss repository concept, namely MX-80 bentonite, low-pH concrete (ESDRED) and Opalinus Clay. The heart of the bentonite model is a new conceptual approach for representing thermodynamic properties of montmorillonite which is formulated as a multi-component solid solution comprised of several end-members.The presented calculations provide information on the extent of pH fronts, on the sequence and extent of mineral phase transformations, and on porosity changes on cement–clay interfaces. It was found that the thickness of the zone containing significant mineralogical alterations is at most a few tens of centimeters thick in both the bentonite and the Opalinus Clay adjacent to the liner. Near both interfaces, bentonite–concrete liner and concrete liner–Opalinus Clay, the precipitation of minerals causes a reduction in the porosity. The effect is more pronounced and faster at the concrete liner–Opalinus Clay interface. The simulations reveal that significant pH-changes (i.e. pH > 9) in bentonite and Opalinus Clay are limited to small zones, less than 10 cm thick at the end of the simulations. It is not to be expected that the zone of elevated pH will extend much further at longer times.  相似文献   

11.
Located on the margin of the west Alboran basin, the Gibraltar Arc (Betic-Rif mountain belt) displays post-Pliocene vertical movements evidenced by uplifted marine sedimentary basins and marine terraces. Quantification of vertical movements is an important clue to understand the origin of present-day relief generation in the Betic-Rif mountain chain together with the causes of the Messinian Salinity Crisis. In this paper, we present the results of a pluridisciplinary study combining an analysis of low temperature thermochronology and Pliocene basins evolution to constrain the exhumation history and surface uplift of internals units of the Rif belt (Northern Morocco). The mean (U-Th)/He apatite ages obtained from 11 samples are comprised between 14.1 and 17.8 Ma and display a wide dispersion, which could be explained by a great variability of apatite chemistries in the analyzed samples. No correlations between altitude and age have been found along altitudinal profile suggesting a rapid exhumation during this period. Thermal modeling using our (U-Th)/He apatite ages and geochronological data previously obtained in the same area (40Ar/39Ar and K/Ar data on biotite, zircon and apatite fission track) allow us to propose a cooling history. The rocks suffered a rapid cooling at 60–100 °C/Ma between 22.5 and 19 Ma, then cooled to temperatures around 40 °C between 19 and 18 Ma. They were re-heated at around 110 °C between 18 and 15 Ma then rapidly cooled and exhumed to reach the surface temperature at around 13 Ma. The re-heating could be related to a renewal in thrusting and burying of the inner zones. Between 15 and 13 Ma the cooling resumed at a rate of 50 °C/Ma indicating an exhumation rate of 0.8 mm/y considering an average 40 °C/km geothermal gradient. This exhumation may be linked to the extension in the Alboran Sea. Otherwise biostratigraphic and sedimentological analysis of Pliocene basins of the internal Rif provided informations on the more recent events and vertical movements. Pliocene deposits of the Rifian coast represent the passive infilling of palaeo-rias between 5.33 and 3.8 Ma. The whole coastal area was uplifted at slow average rates (0.01–0.03 mm/y) in relation with a northeastward tilting of 0.2–0.3° since the Lower-Pliocene. A late Pliocene to present extensional tectonics associated to uplift has been identified all along the coastal ranges of the Internal Zone of the Rif chain. This extension was coeval with the major late Pliocene to Pleistocene extensional episode of the Alboran Sea and appears to be still active nowadays. No significant late Messinian uplift was evidenced, thus calling into question the geodynamic models relating the closure of the marine gateways and the MSC to slab roll back.  相似文献   

12.
New Late Cretaceous paleomagnetic results from the Okhotsk-Chukotka Volcanic Belt in the Kolyma-Omolon Composite Terrane yield stable and consistent remanent directions. The Late Cretaceous (86–81 Ma) ignimbrites from the Kholchan and Ola suites were sampled at 19 sites in the Magadan area (60.4° N, 151.0° E). We isolated the characteristic paleomagnetic directions from 16 sampled sites using an alternating field demagnetization procedure. The primary nature of these directions is ascertained by dual polarities and positive fold tests. A tilt-corrected mean direction (D = 42.8°, I = 84.7°, k = 46.0, α95 = 10.0°) yields a paleomagnetic pole of 66.7° N, 168.5° E (A95 = 18.8°) which appears almost identical to the 90–67 Ma pole reported from the Lake El’gygytgyn area of the Okhotsk-Chukotka Volcanic Belt (Chukotka Terrane). This consistency suggests that the Kolyma-Omolon Composite Terrane and Chukotka Terrane has acted as a single tectonic unit since 80 Ma without any significant internal deformation. Accordingly, we calculate a combined 80 Ma characteristic paleomagnetic pole (Long. = 164.7° E, Lat. = 68.0°, A95 = 10.9°, N = 12) for the Kolyma-Omolon-Chukotka Block which falls 16.5–17.5° south of the same age poles from Europe and East Asia. We ascribe this discrepancy in pole positions to tectonic activity in the area and infer a southward displacement of 1640 ± 1380 km for the Kolyma-Omolon-Chukotka Block with respect to the North American and Eurasian blocks since 80 Ma; more than 260 km of it is attributed to tectonic displacement in the Arctic Ocean due to the opening of the Canadian Basin.  相似文献   

13.
This study presents first results of a project which aims to develop an absolute chronology of the Weichselian ice marginal positions in north-eastern Germany using Optically Stimulated Luminescence (OSL) dating. Owing to the special geomorphological and stratigraphical setting, many of the sampling sites were situated close to the former ice margin. At some sections the sediments showed an incomplete resetting of the OSL signal. For this study the representative sandur sediment section from the Beelitz outwash cone was chosen to elaborate a strategy to reliably detect insufficient bleaching and to choose an appropriate age model for the calculation of the true burial dose of each sample. The age determined for the formation of the Beelitz outwash cone is 34.1 ± 3.0 ka. Although this age might still be a maximum age, this study shows that by applying the proposed methodological strategy, plausible ages can be derived from insufficiently bleached, ice proximal sandur sediments.  相似文献   

14.
Surface soil moisture is a critical parameter for understanding the energy flux at the land atmosphere boundary. Weather modeling, climate prediction, and remote sensing validation are some of the applications for surface soil moisture information. The most common in situ measurement for these purposes are sensors that are installed at depths of approximately 5 cm. There are however, sensor technologies and network designs that do not provide an estimate at this depth. If soil moisture estimates at deeper depths could be extrapolated to the near surface, in situ networks providing estimates at other depths would see their values enhanced. Soil moisture sensors from the U.S. Climate Reference Network (USCRN) were used to generate models of 5 cm soil moisture, with 10 cm soil moisture measurements and antecedent precipitation as inputs, via machine learning techniques. Validation was conducted with the available, in situ, 5 cm resources. It was shown that a 5 cm estimate, which was extrapolated from a 10 cm sensor and antecedent local precipitation, produced a root-mean-squared-error (RMSE) of 0.0215 m3/m3. Next, these machine-learning-generated 5 cm estimates were also compared to AMSR-E estimates at these locations. These results were then compared with the performance of the actual in situ readings against the AMSR-E data. The machine learning estimates at 5 cm produced an RMSE of approximately 0.03 m3/m3 when an optimized gain and offset were applied. This is necessary considering the performance of AMSR-E in locations characterized by high vegetation water contents, which are present across North Carolina. Lastly, the application of this extrapolation technique is applied to the ECONet in North Carolina, which provides a 10 cm depth measurement as its shallowest soil moisture estimate. A raw RMSE of 0.028 m3/m3 was achieved, and with a linear gain and offset applied at each ECONet site, an RMSE of 0.013 m3/m3 was possible.  相似文献   

15.
We present new high-precision 40Ar/39Ar ages on feldspar and biotite separates to establish the age, duration and extent of the larger Siberian Traps volcanic province. Samples include basalts and gabbros from Noril'sk, the Lower Tunguska area on the Siberian craton, the Taimyr Peninsula, the Kuznetsk Basin, Vorkuta in the Polar Urals, and from Chelyabinsk in the southern Urals. Most of the ages, except for those from Chelyabinsk, are indistinguishable from those found at Noril'sk. Cessation of activity at Noril'sk is constrained by a 40Ar/39Ar age of 250.3 ± 1.1 Ma for the uppermost Kumginsky Suite.The new 40Ar/39Ar data confirm that the bulk of Siberian volcanism occurred at 250 Ma during a period of less than 2 Ma, extending over an area of up to 5 million km2. The resolution of the data allows us to confidently conclude that the main stage of volcanism either immediately predates, or is synchronous with, the end-Permian mass extinction, further strengthening an association between volcanism and the end-Permian crisis. A sanidine age of 249.25 ± 0.14 Ma from Bed 28 tuff at the global section and stratotype at Meishan, China, allows us to bracket the P–Tr boundary to 0.58 ± 0.21 myr, and enables a direct comparison between the 40Ar/39Ar age of the Traps and the Permo–Triassic boundary section.Younger ages (243 Ma) obtained for basalts from Chelyabinsk indicate that volcanism in at least the southern part of the province continued into the Triassic.  相似文献   

16.
40Ar / 39Ar incremental heating ages for twenty one grains of cryptomelane, collected at 0, 42, 45, and 60 m depths in the Cachoeira Mine weathering profile, Minas Gerais, permit calculating long-term (10 Ma time scale) weathering rate (saprolitization rate) in SE Brazil. Pure well-crystallized cryptomelane grains with high K contents (3–5 wt.%) yield reliable geochronological results. The 40Ar / 39Ar plateau ages obtained decrease from the top to the bottom of the profile (12.7 ± 0.1 to 7.6 ± 0.1 Ma at surface; 7.6  ± 0.2 to 6.1 ± 0.2 Ma at 42 m; and 7.1 ± 0.2 to 5.9 ± 0.1 Ma at 45 m; 6.6 ± 0.1 to 5.2 ± 0.1 Ma at 60 m), yielding a weathering front propagation rate of 8.9 ± 1.1 m/m.y. From the geochronological results and the mineral transformations implicit by the current mineralogy in the weathering profiles, it is possible to calculate the saprolitization rate for the Cachoeira Mine lithologies and for adjacent weathering profiles developed on granodiorites and schists. The measured weathering front propagation rate yields a saprolitization rate of 24.9 ± 3.1 t/km2/yr. This average long-term (> 10 Ma) saprolitization rate is consistent with mass balance calculations results for present saprolitization rates in weathering watersheds. These results are also consistent with long-term saprolitization rates estimated by combining cosmogenic isotope denudation rates with mass balance calculations.  相似文献   

17.
Garnet geochronology was used to provide the first direct measurement of the timing of eclogitization in the central Himalaya. Lu–Hf dates from garnet separates in one relict eclogite from the Arun River Valley in eastern Nepal indicate an age of 20.7 ± 0.4 Ma, significantly younger than ultra-high pressure eclogites from the western Himalaya, reflecting either different origins or substantial time lags in tectonics along strike. Four proximal garnet amphibolites from structurally lower horizons are 14–15 Ma, similar to post-eclogitization ages published for rocks along strike in southern Tibet. P–T calculations indicate three metamorphic episodes for the eclogite: i) eclogite-facies metamorphism at ～ 670 °C and ≥ 15 kbar at 23–16 Ma; ii) a peak-T granulite event at ～ 780 °C and 12 kbar; and iii) late-stage amphibolite-facies metamorphism at ～ 675 °C and 6 kbar at ～ 14 Ma. The garnet amphibolites were metamorphosed at ～ 660 °C. Three models are considered to explain the observed P–T–t evolution. The first assumes that the Main Himalayan Thrust (basal thrust of the Himalayan thrust system) cuts deeper at Arun than elsewhere. While conceptually the simplest, this model has difficulty explaining both the granulite-facies overprint and the pulse of exhumation between 25 and 14 Ma. A second model assumes that (aborted) subduction, slab breakoff, and ascent of India's leading edge occurred diachronously: ～ 50 Ma in the western Himalaya, ～ 25 Ma in the central Himalaya of Nepal, and presumably later in the eastern Himalaya. This model explains the P–T–t path, particularly heating during initial exhumation, but implies significant along-strike diachroneity, which is generally lacking in other features of the Himalaya. A third model assumes repeated loss of mantle lithosphere, first by slab breakoff at ～ 50 Ma, and again by delamination at ～ 25 Ma; this model explains the P–T–t path, but requires geographically restricted tectonic behavior at Arun. The P–T–t history of the Arun eclogites may imply a change in the physical state of the Himalayan metamorphic wedge at 16–25 Ma, ultimately giving rise to the Main Central Thrust by 15–16 Ma.  相似文献   

18.
In Central Iran there are several cities along the Dehshir fault, which have similar geological conditions to that of the city of Bam prior to the 2003 earthquake (Mw 6.5), during which more than 30,000 lives were lost. Optical stimulated luminescence (OSL) samples were collected from the Dehshir fault in order to place constraints on its seismic history. The single aliquot regenerative (SAR) dose measurement protocol on coarse grained quartz extracts was used for this study. This SAR protocol had to be optimized for the low OSL sensitivity by varying both the preheat temperatures and test doses used. Dose recovery tests showed that given laboratory dose could be successfully recovered. However, replicate palaeodose (De) data were scattered and consequently ages based on mean De's had large uncertainties. As this is thought to largely reflect poor bleaching conditions prior to sediment burial at the site, various statistical procedures were employed in conjunction with the stratigraphic knowledge of the site to try and extract more refined burial ages from the samples. From this the timing of the last earthquake was estimated around 2.0 ± 0.2 kyr. This refined age suggests that the earthquake catalogue of Iran is incomplete and more paleoseismological investigation is required to recognize and date the previous events of Dheshir fault.  相似文献   

19.
The Adelaide rift complex in South Australia contains the type sections for Sturtian and Marinoan glacial deposits. The litho- and chemo-stratigraphy of these deposits play a central role in evaluating global Neoproterozoic ice age hypotheses and Rodinia supercontinent reconstructions, but reliable depositional age constraints have been extremely limited. We report results of in situ Th–U–total Pb (electron microprobe) dating of detrital and authigenic monazite in two samples from the Umberatana Group (Sturtian Holowilena Ironstone and pre-Marinoan Enorama Shale) in the Central Flinders Ranges. Several texturally and chemically distinct detrital and authigenic populations are recognized. Detrital dates range from 1600 Ma to 760 Ma and most relate to well-known orogenic or igneous events in surrounding cratonic regions. Authigenic monazite grew in three or more pulses ranging from 680 Ma to 500 Ma. The date of 680 ± 23 Ma (2σ) for the earliest generation of authigenic monazite in sandstone from the Enorama Shale (1) provides an estimate for the age of the base of the Trezona carbon isotopic anomaly just beneath the Marinoan glacial deposits, (2) provides an absolute minimum age constraint on the underlying Sturtian glacial deposits, and (3) supports proposed correlations between type Marinoan deposits and precisely dated glacial deposits in Namibia and China, which bracket the presumed Marinoan equivalents between 655 and 635 Ma. This age is inconsistent with a Re–Os isochron age of 643 ± 2.4 Ma (2σ) on shales near the bottom of the Sturtian–Marinoan interglacial succession, stratigraphically > 3000 m below the Enorama Shale sample, and militate against the hypothesis that the type Marinoan is correlative with the 580 Ma Gaskiers glaciation. Monazite growth near 600 Ma and again at about 500 Ma probably represent hydrothermal fluid-flow events, the latter of which also corresponds to the well-known Delamerian Orogeny during which the Adelaide sediments were folded into their present structural pattern.  相似文献   

20.
Since 1970, many prehistoric sites have been discovered in the alluvial terraces of several rivers of the Middle Loire River basin (France). During the last decade, the stepped-terraces systems of three of the Loire tributaries, the Creuse, the Cher and the Loir Rivers, were the focus of multidisciplinary studies, involving Quaternary geology, prehistory and geochronology. The geochronological data now available for these systems were mainly obtained by electron spin resonance (ESR) method applied to optically bleached fluvial quartz. These results provide a chronological framework for the evolution of fluvial systems and the human settlements of this area during Lower and Middle Pleistocene. Two phases of human settlement could be distinguished, around 1.1 Ma (Early Palaeolithic – Mode 1) and around 0.7 Ma ago (Acheulean – Mode II).  相似文献   

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