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1.
Several organic molecules have now been detected in the coma of Hale–Bopp. These species may either emanate from the nucleus, or, as has been suggested by Bockelée–Morvan et al., could be synthesized in the coma. We have modelled the gas phase chemistry which occurred in the coma of Hale–Bopp, concentrating on the observed organic molecules HCOOH, HCOOCH3, HC3N and CH3CN. We find that gas phase chemical reactions are unable to synthesize the observed abundances of these molecules, so all these species are most probably present in the nuclear ice. We briefly discuss the implications of this result for the connection between cometary and interstellar ices.  相似文献   

2.
A solid-state feature was detected at around 2175 cm−1 towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm−1 (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm−1 (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10−19 cm  molecule−1. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H2O ice, which is, at most, half of the abundance (relative to H2O ice) of CO residing in H2O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.  相似文献   

3.
Summary The presence of solid carbon monoxide (CO) on interstellar grains was confirmed observationally in 1984 with the detection of infrared absorption at 4.67m wavelength in several molecular clouds. Subsequent observations suggest that solid CO is ubiquitous in the quiescent molecular cloud environment. In some lines of sight, the degree of frosting on to grains is sufficient to reduce appreciably the abundance of CO remaining in the gas, a result of considerable astrophysical significance: in addition to its importance as a tracer of molecular material, CO is vital to the production of many polyatomic molecules by gas phase reaction schemes, and its depletion could have a dramatic effect on the abundances of more complex carbon-bearing molecules. The infrared spectrum of solid CO provides an important diagnostic of the chemical composition and thermal evolution of grain mantles, leading to the prediction that CO2 is also present in solid form.As it is now some six years since observations of interstellar solid CO were first reported, this is an appropriate time to review the topic and to suggest some directions for future research. The introduction (Sect. 1) attempts to place the subject in its broader astrophysical context. The infrared observations and their implications are discussed in detail in Sect. 2. The question of the degree of CO depletion implied by the observations of both solid state and gas phase CO is re-examined in Sect. 3. We assess the possibility of CO detection by means of solid state absorption or luminescence in the ultraviolet in Sect. 4. Future prospects are summarised in the final section.This article was processed by the author using the Springer-Verlag TEX Theaar macro package 1988.  相似文献   

4.
We present 2–4 μm spectra of six infrared sources for which the extinction is not purely interstellar, but is dominated by circumstellar or molecular cloud dust. In all cases the absorption bands differ from the interstellar case, though a component of the interstellar absorption is often present. We also present an improved absorption spectrum for the galactic centre source IRS 7, correcting spurious features in our previous spectrum. Three independent components can be identified: (i) The interstellar component, probably of organic origin, and itself not necessarily invariant; (ii) The symmetrical water ice feature at 3.06 μm, found most commonly in molecular clouds; (iii) A component at 3.53 μm possibly identified with solid formaldehyde grains, and seen only in molecular clouds because of its weakness. Other absorption components appear to be unrelated to those in the 3–4 μm region, most notably the 10 μm absorption found in oxygen-rich giants and the interstellar medium, and presumable inorganic in nature. Our observations include the first detection of water ice absorption in a source in the ρ Oph dark cloud. Biological materials provide the best fit to the interstellar case, but do not presently account for the distinct 3.53 μm component. We stress the need for further laboratory experiments using simpler organic materials.  相似文献   

5.
There are two ways that water ice can form in the interstellar medium: H2O molecules can form in the gas phase and then freeze out onto dust grain surfaces, or O and OH can be converted at the surfaces of grains to form H2O, which is then retained. Bergin et al. (1998) have recently shown that shocks passing through interstellar clouds sufficiently frequently can make the first method effective. However, we present results from a similar chemical model which indicate that this requires significant optical shielding because of the high ionization fraction in regions exposedto a high UV flux. We deduce, therefore, that grain surface reactions probably represent the main source of H2O ice on lines of sight with visual extinction up to about 6 magnitudes to an embedded source or 12 magnitudes to a background object. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

6.
Abstract— The presence of isotopic anomalies is the most unequivocal demonstration that meteoritic material contains circumstellar or interstellar components. In the case of organic compounds in meteorites and interplanetary dust particles (IDPs), the most useful isotopic tracer has been deuterium (D). We discuss four processes that are expected to lead to D enrichment in interstellar materials and describe how their unique characteristics can be used to assess their relative importance for the organics in meteorites. These enrichment processes are low‐temperature gas phase ion‐molecule reactions, low‐temperature gas‐grain reactions, gas phase unimolecular photodissociation, and ultraviolet photolysis in D‐enriched ice mantles. Each of these processes is expected to be associated with distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.), especially in the molecular population of polycyclic aromatic hydrocarbons (PAHs). We describe these differences and discuss how they may be used to delineate the various interstellar processes that may have contributed to meteoritic D enrichments. We also briefly discuss how these processes may affect the isotopic distributions in C, O, and N in the same compounds.  相似文献   

7.
H2 is the most abundant molecule in the universe. We demonstrate that this molecule may be an important component of interstellar and possibly intergalactic ices, both because it can be formed in situ, within the ices, and because gas phase H2 can freeze out onto dust grains in some astrophysical environments. The condensation-sublimation and infrared spectral properties of ices containing H2 are presented. We show that solid H2 in H20-rich ices can be detected by an infrared absorption band at 4137 cm-1 (2.417 micrometers). The surface binding energy of H2 to H2O ice was measured to the delta Hs/k = 555 +/- 35 K. Surface binding energies can be used to calculate the residence times of H2 on grain surfaces as a function of temperature. Some of the implications of these results are considered.  相似文献   

8.
The Paris meteorite is one of the most primitive carbonaceous chondrites. It is reported to be the least aqueously altered CM chondrite, and to have experienced only weak thermal metamorphism. We have analyzed for the first time the amino acid and hydrocarbon contents of this pristine meteorite by gas chromatography–mass spectrometry (GC–MS). When plotting the relative amino acids abundances of several CM chondrites according to the increasing hydrothermal scale (petrologic subtypes), from the CM2.7/2.8 Paris to the CM2.0 MET 01070, Paris has the lowest relative abundance of β‐alanine/glycine (0.15), which fits with the relative abundances of β‐alanine/glycine increasing with increasing aqueous alteration for CM chondrites. These results confirm the influence of aqueous alteration on the amino acid abundances and distribution. The amino acid analysis shows that the isovaline detected in this meteorite is racemic (d /l  = 0.99 ± 0.08; l ‐enantiomer excess = 0.35 ± 0.5%; corrected d /l  = 1.03; corrected l ‐enantiomer excess = ?1.4 ± 2.6%). The identified hydrocarbons show that Paris has n‐alkanes ranging from C16 to C25 and 3‐ to 5‐ring nonalkylated polycyclic aromatic hydrocarbons (PAHs). The lack of alkylated PAHs in Paris seems to be also related to this low degree of aqueous alteration on its parent body. The extraterrestrial hydrocarbon content, suggested by the absence of any biomarker, may well have a presolar origin. The chemistry of the Paris meteorite may thus be closely related to the early stages of the solar nebula with a contribution from interstellar (molecular cloud) precursors.  相似文献   

9.
This work reports theoretical infrared and electronic absorption spectra of formaldehyde and its ions in gas phase and H2O ice at different levels of theory. The vibrational frequencies from this work at B3LYP/6-311++G** level are in agreement with the experimental determinations. The gas phase dipole moment of neutral formaldehyde 2.4 D is in excellent agreement with the experimental value of 2.33 D. An influence of ice on vibrational frequencies of neutral formaldehyde molecule was obtained using Self Consistence Isodensity Polarizable Continuum Model (SCI-PCM) with dielectric constant 78.5. Significant shift in vibrational frequencies for neutral formaldehyde molecule when studied in H2O ice and upon ionization is observed. All the vibrational modes in cation and anion of formaldehyde in gas phase are red shifted than the corresponding modes in neutral formaldehyde. Two vibrational modes are blue shifted and all other modes are red shifted for neutral formaldehyde in H2O ice. Time dependent density functional theory (TDDFT) is used to study electronic absorption spectrum of neutral formaldehyde and its charged states. It is found that like neutral formaldehyde, its cation and anion also display strong σ→σ ∗ electronic transitions in vacuum and far UV regions. This study should help in detecting formaldehyde molecule and its ions in gas phase and in H2O ice in different astronomical environment.  相似文献   

10.
A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol−1, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ3( A v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.  相似文献   

11.
The equivalent width of the diffuse interstellar absorption band W2200 and the abundances of neutral interstellar hydrogen and sodium derived from the interstellar absorption lines in the spectra of hot stars are well correlated each other.  相似文献   

12.
We have obtained a simple representation to the observed invariant cross-section for the production of neutral pions in proton-proton collisions. Making use of this representation, we have calculated the differential and integral production spectra of gamma rays in the Galaxy from interactions of cosmic ray nuclei with interstellar gas. It is shown that the uncertainties in deducing interstellar proton spectrum by demodulating the observed spectrum do not affect very much the gamma ray spectrum. We have also determined the gamma ray production spectrum through bremsstrahlung process for a typical interstellar electron spectrum derived from the radio spectrum in the Galaxy. From these, the total gamma ray production spectrum resulting from the interaction of cosmic rays with interstellar matter is compared with the observed gamma ray spectrum in the Galaxy and some inferences have been obtained. We also point out the possible uncertainty in the present calculation and suggest the improvements needed.  相似文献   

13.
Several processes have been suggested as ways of returning accreted grain mantles to the gas, thus preventing the total removal of molecules from the gas phase in dark quiescent clouds. We attempt to distinguish between them by considering not only the calculated gas-phase abundances, but also the ratio of the abundances of deuterated species to non-deuterated species. We find that the D/H ratio in molecules is relatively model-independent, but that desorption due to the formation of H2 on grains gives the best overall agreement with the observations.  相似文献   

14.
We have developed a model for reflection nebulae around luminous infrared sources embedded in dense dust clouds. The aim of this study is to determine the sizes of the scattering grains. In our analysis, we have adopted an MRN-like power-law size distribution (Mathis, Rumpl, and Nordsieck) of graphite and silicate grains, but other current dust models would give results which were substantially the same. In the optically thin limit, the intensity of the scattered light is proportional to the dust column density, while in the optically thick limit, it reflects the grain albedo. The results show that the shape of the infrared spectrum is the result of a combination of the scattering properties of the dust, the spectrum of the illuminating source, and foreground extinction, while geometry plays a minor role. Comparison of our model results with infrared observations of the reflection nebula surrounding OMC-2/IRS 1 shows that either a grain size distribution like that found in the diffuse interstellar medium, or one consisting of larger grains, can explain the observed shape of the spectrum. However, the absolute intensity level of the scattered light, as well as the observed polarization, requires large grains (approximately 5000 angstroms). By adding water ice mantles to the silicate and graphite cores, we have modeled the 3.08 micrometers ice band feature, which has been observed in the spectra of several infrared reflection nebulae. We show that this ice band arises naturally in optically thick reflection nebulae containing ice-coated grains. We show that the shape of the ice band is diagnostic of the presence of large grains, as previously suggested by Knacke and McCorkle. Comparison with observations of the BN/KL reflection nebula in the OMC-1 cloud shows that large ice grains (approximately 5000 angstroms) contribute substantially to the scattered light.  相似文献   

15.
The ?2200 Å interstellar absorption band, generally attributed to graphite grains, could equally well arise from π→π* electronic transitions in conjugated double bonds of organic molecules. These molecules, which should comprise ～10% of the total interstellar dust mass, may be lodged within clumps of 100 Å-sized refractory grains.  相似文献   

16.
We analyze the chemical composition and abundances of comets based on in situ measurements of Comet 1P/Halley and remote sensing observations of several recent bright comets including Hale-Bopp (C/1995 O1) and Hyakutake (C/1996 B2), in light of the elemental abundances of the solar system. Nitrogen is underabundant in comets relative to the solar system because nitrogen tends to be in N2, which is chemically relatively inert. While many details remain uncertain, some gross features are emerging. The abundance of water : silicates: carbonaceous molecules (CO, CO2, and hydrocarbons) by mass is approximately 1 : 1 : 1. Furthermore, the mass abundance of ice : dust (silicates and hydrocarbon polycondensates) is about1 : 1. We compare a list of identified comet molecules with molecules detected in the interstellar medium, although a comparison with their relative abundances, particularly in the ice phase, would be more meaningful. However, ice-phase abundances are not yet available. One can expect a variation of the abundances of carbon-bearing molecules in comets to be associated with their place of origin in the solar nebula. However, we also note that comets are heterogeneous. Thus, observed differences may be related to the place of origin, heterogeneity of the nucleus, or acquired through evolution. The molecular and elemental compositions of the coma are most likely not the same as those in the nucleus. This is particularly true for volatile ices and their gases and for the dust-to-ice and dust-to-gas ratios. Analyses must carefully consider the three sources of gas: Water from the surface of the nucleus, gases more volatile than water from the interior of the nucleus, and gases from the sublimation of the dust distributed in the coma. Topography on the surface of the nucleus may cause important evolutionary differences in the dust-to-gas mass ratio. Relatively inactive areas on the surface of the nucleus are probably associated with convex topography. Gas sublimated from convex areas (hills and mountains) diverges more strongly relative to gas sublimated from concave areas, which can entrain dust more efficiently. Thus, the entrainment of dust from convex areas is poor and dust may fall back to the surface of the nucleus creating a dust mantle, which further inhibits outgassing.  相似文献   

17.
《Icarus》1987,70(1):99-110
Recent interpretations of the reflectance spectra of the icy Galilean satellites (Europa, Ganymede, and Callisto) have implied very ice-rich surfaces, as high as 90 wt% ice even on the dark surface of Callisto. A reevaluation of the spectra, taking into account the depth of the 3-μm fundamental water ice absorption feature as well as the shorter wavelength bands, suggests that the spectra of at least Ganymede and Callisto may also be consistent with much lower ice abundances if the ice is segregated from the nonicy material. Reasonable fits to all band depths (including the shallow 1.04- and 1.25-μm bands) are obtained with around 50% areal coverage of ice on Ganymede and 10% on Callisto, the rest of the surface being occupied by carbonaceous chondrite-like material which has a strong 3-μm absorption due to bound water. Europa's spectrum probably indicates a homogeneous icy surface. The darkness beyond 3 μm, and lack of a 3.6-μm peak, for all three objects may be consistent with the presence of small quantities of sulfuric acid on the satellite surfaces.  相似文献   

18.
We present 20–110 µm absorbance spectra of H2O ice, deposited on amorphous carbon and silicate substrates, obtained over the 10–140 K temperature range. The measurements have been carried out in a manner that simulates the deposition, warming and cooling of H2O ice mantles on interstellar and circumstellar grains. For H2O ice films deposited on these substrates we find (i) similar 44-µm-band peak wavelength temperature dependences, (ii) no bandshape differences in the respective spectra, and (iii) a structural phase transition occurring between 120 and 130 K. In comparison with published data obtained using a polyethylene substrate, the 52-µm feature (the longitudinal optical mode) observed in our spectra is less prominent. This suggests the presence of material-dependent substrate effects that can alter the appearance of the H2O far-infrared spectrum. The crystallization temperature of H2O ice films deposited on our amorphous silicate substrate is significantly different from that reported by Moore et al. (1994) , who found crystallization temperatures down to < 20 K for ice also deposited on an amorphous silicate substrate. This is attributed to differences in the surface structures of the respective substrates. This may indicate that, at least in the context of laboratory measurements, substrate material composition is not as significant as substrate surface structure.  相似文献   

19.
The λ2200 Å interstellar absorption band, generally attributed to graphite grains, could equally well arise from π → π*electronic transitions in conjugated double bonds of organic molecules. These molecules, which should comprise ～ 10% of the total interstellar dust mass, may be lodged within clumps of100 Å-sized refractory grains.  相似文献   

20.
Thanks to the mid-IR sensitivities of the ISO and IRTS orbiting spectrometers it is now possible to search the diffuse interstellar medium for heretofore inaccessible molecular emission. In view of the recent strong case for the presence of C(7-) (Kirkwood et al. 1998, Tulej et al. 1998),and the fact that carbon chains possess prominent infrared active modes in a very clean portion of the interstellar spectrum, we have analyzed the IRTS spectrum of the diffuse interstellar medium for the infrared signatures of these species. Theoretical and experimental infrared band frequencies and absolute intensities of many different carbon chain species are presented. These include cyanopolyynes, neutral and anionic linear carbon molecules, and neutral and ionized, even-numbered, hydrogenated carbon chains. We show that--as a family--these species have abundances in the diffuse ISM on the order of 10(-10) with respect to hydrogen, values consistent with their abundances in dense molecular clouds. Assuming an average length of 10 C atoms per C-chain implies that roughly a millionth of the cosmically available carbon is in the form of carbon chains and that carbon chains can account for a few percent of the visible to near-IR diffuse interstellar band (DIB) total equivalent width (not DIB number).  相似文献   

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