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1.
This paper reveals the physicochemical properties such as component, formulation, genesis, tem- perature, pH, Eh, salinity and pressure of all main alteration fluid of interlayer oxidation zone sand- stone-type uranium deposits after studying the geologic process and geochemistry of internal typical sandstone-type uranium deposits such as Shihongtan deposit in the Turpan-Hami basin, 512 deposit in the Yili basin, Dongsheng deposit in the Ordos basin. The composition of fluid can be divided into two parts based on the analysis of inclusion one can be affirmed as atmospheric water with ordinary temperature epigenesist according to the character of hydrogen and oxygen isotope of inclusion, the other is natural gas containing gaseous hydrocarbon like CH4, and CO2 as well as a little H2S, CO, H2, N2 and so on, it always contains a small quantity of hydrocarbon liquid in petroliferous basins. The fluid property of oxidation alteration zone is always oxidation alkaline, and neutrality or weak acid-weak alkaline and reducibility during the metallizing process, but at secondary reduction or deoxidization zone it becomes strong reduction alkaline. Oxygenic groundwater in the fluid is the activate and mig- ratory medium of uranium element, but the gaseous hydrocarbon like CH4 as well as H2, H2S, CO from natural gas is the important sedimentary reducer of uranium mineral; the transformation of pH,Eh in fluid environment is the main reason for the formation of uranium metallization.  相似文献   

2.
Dajing Cu-Sn-Ag-Pb-Zn ore deposit, in the Inner Mongolia Autonomous Region of China, is a fissure-filling hydrothermal ore deposit. The δD values of quartz-hosted inclusion water are centered at −100%.– −130%.. The δ34S values of sulfide ore minerals and δ13 C values of carbonate gangue minerals vary from −0.3%. to 2.6%. and from −2.9%. to −7.0%., respectively. Integrated isotopic data point to two major contributions to the mineralizing fluid that include a dominant meteoric-derived groundwater, and sulfur and carbon species from hypogene magma. Linear trends are exhibited on the gaseous H2O versus CO2 plot, and plots of CO, N2, CH4, and C2H6. It is shown by quantitative simulation that magma degassing cannot explain the linear trends. Hence, these linear trends are interpreted in terms of mixing of CO2-rich magmatic fluid with meteoric-derived groundwater. The groundwater circulated in Paleozoic sedimentary rocks and absorbed CO, N2, CH4, C2H6 and radiogenic Ar from organic matter. Cooling effects resulting from mixing have caused the precipitation of ore minerals.  相似文献   

3.
松辽盆地深部地壳构造特征与无机油气生成模式   总被引：6，自引：1，他引：5       下载免费PDF全文
松辽盆地中地壳有一低速-高导层(也称塑性层),中地壳的塑性层与松辽盆地的成因以及盆山耦合系统有关.盆地地幔流体活动有下列表现:(1)高热流、高地温场;(2)深大断裂与火山岩喷溢;(3)碱交代作用(如钠长石化、伊利石化);(4)Mg2 交代作用(如白云石化)等等.地球化学省与地球化学急变带控制了大油气田的分布并显示了盆地发生的壳-幔相互作用.中地壳的低速-高导层不是岩浆岩,而是一充满地幔流体的地质体,它们富含氢、碱金属(K 、Na )、卤素(F-、Cl-)、碳(甲烷、CO、CO2)、氮、硫等.在中地壳的温度压力条件下,在Fe、Ni等催化荆的参与下,H2与CO(CO2)可发生费-托合成烃的反应.实验表明:这个反应不仅可生成气态烃还可生成液态烃,并将发生碳同位素分馏作用.松辽盆地的U形运移模型受到质疑.按照石油无机生成的模型,松辽盆地的深部将会有更多的石油与天然气,庆深气田的发现便是一个明证.  相似文献   

4.
In the Quaternary alkali-potassic volcanites of Northern Latium, there are classical solfataras related to volcanic structures, and very large kaolinized fields, at the borders of the volcanic systems (perivolcanic), related to pre-volcanic tectonic structures. In the solfataric type of mineralization thorium and sulphur ores in an opaline matrix are prevailing; in the perivolcanic type of deposit are prevailing uranium ores in very regular layers associated with kaolin. Marcasite-pyrite beds and lenses are common in both of them. The mineralization processes start with the oxidation of H2S coming out from volcanic edilices or from large faults. The origin of U and Th concentrations is to be seen in the anomalous high content of radioactive elements in the alkaline rocks, and in their enrichment in ground waters. The perivolcanic uranium mineralizations are of some economic interest: the ore deposition is controlled by ground water level in reducing conditions determined by H2S, not unlike to the principal sedimentary uranium ores known in the continental environment.  相似文献   

5.
天山地区的高压自流水、高压油气藏及地热异常区的出露与天山地震带分布的一致性表明,孔隙水压异常高的动力条件可能成为触发浅源地震的重要机制。本文以丰富的震例为依据,认为天山地震带中强地震前地下流体出现两类异常:一类是应力应变能积累阶段的趋势性异常;一类是应力应变能预释放阶段的临震突发性异常。两类异常在形态上和时空分布上有完全不同的特征,它们显示出地震孕育过程中的两个完全不同的物理、化学过程。  相似文献   

6.

This paper presents gas compositions and H-, O-isotope compositions of sulfide- and quartz-hosted fluid inclusions, and S-, Pb-isotope compositions of sulfide separates collected from the principal Stage 2 ores in Veins 3 and 210 of the Jinwozi lode gold deposit, eastern Tianshan Mountains of China. Fluid inclusions trapped in quartz and sphalerite are dominantly primary. H-and O-isotopic compositions of pyrite-hosted fluid inclusions indicate two major contributions to the ore-forming fluid that include the degassed magma and the meteoric-derived but rock 18O-buffered groundwater. However, H- and O-isotopic compositions of quartz-hosted fluid inclusions essentially suggest the presence of groundwater. Sulfide-hosted fluid inclusions show considerably higher abundances of gaseous species CO2, N2, H2S, etc. than quartz-hosted ones. The linear trends among inclusion gaseous species reflect the mixing tendency between the gas-rich magmatic fluid and the groundwater. The relative enrichment of gaseous species in sulfide-hosted fluid inclusions, coupled with the banded ore structure indicating alternate precipitation of quartz with sulfide minerals, suggests that the magmatic fluid has been inputted to the ore-forming fluid in pulsation. Sulfur and lead isotope compositions of pyrite and galena separates indicate an essential magma derivation for sulfur but the multiple sources for metallic materials from the mantle to the bulk crust.

  相似文献   

7.
This paper presents gas compositions and H-, O-isotope compositions of sulfide- and quartz-hosted fluid inclusions, and S-, Pb-isotope compositions of sulfide separates collected from the principal Stage 2 ores in Veins 3 and 210 of the Jinwozi lode gold deposit, eastern Tianshan Mountains of China. Fluid inclusions trapped in quartz and sphalerite are dominantly primary. H-and O-isotopic compositions of pyrite-hosted fluid inclusions indicate two major contributions to the ore-forming fluid that include the degassed magma and the meteoric-derived but rock 18O-buffered groundwater. However, H- and O-isotopic compositions of quartz-hosted fluid inclusions essentially suggest the presence of groundwater. Sulfide-hosted fluid inclusions show considerably higher abundances of gaseous species CO2, N2, H2S, etc. than quartz-hosted ones. The linear trends among inclusion gaseous species reflect the mixing tendency between the gas-rich magmatic fluid and the groundwater. The relative enrichment of gaseous species in sulfide-hosted fluid inclusions, coupled with the banded ore structure indicating alternate precipitation of quartz with sulfide minerals, suggests that the magmatic fluid has been inputted to the ore-forming fluid in pulsation. Sulfur and lead isotope compositions of pyrite and galena separates indicate an essential magma derivation for sulfur but the multiple sources for metallic materials from the mantle to the bulk crust.  相似文献   

8.
The known uranium ore and anomaly occur-rences are distributed mainly in the southwestern part of the Turfan-Hami basin. The focus of current explo-ration is placed on the leachable interlayered oxidation zone type of sandstone uranium deposits. Uranium deposits in the sedimentary basin can be classified into three types in accordance with their host rock types, i.e. the sandstone-type uranium deposits, the coal rock-type uranium deposits and the mud-stone-type uranium deposits. The sandstone…  相似文献   

9.
Methods used previously to remove compositional modifications from volcanic gas analyses for Mount Etna and Erta'Ale lava lake have bean employed to estimate the gas phase composition at Nyiragongo lava lake, based on samples obtained in 1959. H2O data were not reported in 11 of the 13 original analyses. The restoration methods have been used to estimate the H2O contents of the samples and to correct the analyses for atmospheric contamination, loss of sulfur and for pre- and pest-collection oxidation of H2S, S2, and H2. The estimated gas compositions are relatively CO2-rich, low in total sulfur and reduced. They contain approximately 35–50% CO2 45–55% H2O, 1–2% SO2, 1–2% H2., 2–3% CO, 1.5–2.5% H2S, 0.5% S2 and 0.1% COS over,he collection temperature range 102° to 960° C. The oxygen fugacities of the gases are consistently about half an order of magnitude below quartz-magnetite-fayalite. The low total sulfur content and resulting low atomic S/C of the Nyiragongo gases appear to be related to the relatively low fO2 of the crystallizing lava. At temperatures above 800°C and pressures of 1–1.5 k bar, the Nyiragongo gas compositions resemble those observed in primary fluid inclusions believed to have formed at similar temperatures and pressures in nephelines of intrusive alkaline rocks. Cooling to 300°C, with fO2 buffered by the rock, results in gas compositions very rich in CH4 (50–70%) and resembling secondary fluid inclusions formed at 200–500°C in alkaline rocks. Below 600°C the gases become supersaturated in carbon as graphite. These inferences are corroborated by several reports of hydrocarbons in plutonic alkaline rocks, and by the presence of CH4-rich waters in Lake Kivu — a lake on the flanks of Nyiragongo volcano.  相似文献   

10.
The Okinawa trough is a spreading back-are basin featuring emitting hydrothermal solutions (black chimney type) and modem sulfide precipitation on the sea floor. The study of fluid inclusions in water-rock interaction products in the Jade hydrothermal field indicates that the deep hydrothermal system beneath the sea floor is fairly rich in gas and there are two independent and coexisting fluids-CO2-hydrocarbon fluid and salt aqueous fluid. On the whole, the composition of CO2-hydrocarbon fluid inclusions is similar to that of the fluid inclusions in natural gas fields. The dominant composition of the inclusions in aqueous fluid is H2O with CO2 and CH4 being oversaturated. The salt aqueous fluid of the Jade hydrothermal system might be emitted through a black chimney, whereas CO2-rich fluids discharge CO2 bubbles and CO2 hydrate through fissures. Hydrocarbons in gas phase or in fluid might be enclosed somewhere under the sea. Large storage of CO2-CH4-H2S gas or fluid and reaction of this gas or fluid with salt water will lead to commercial sulfide deposits.  相似文献   

11.
Organic-inorganic interaction exists universally and is important in the process of mineral resources formation.It is the essential reason why organic oil,gas,coal and inorganic uranium coexist,accumulate,and mineralize in the same sedimentary basins.Hydrocarbon-generating simulation experiment was conducted using low-mature hydrocarbon source rock containing kerogen type III with uranium(UO2CO3 solution)added to study the effects of uranium on the hydrocarbon generation of hydrocarbon source rocks.Experiment results show that uranium can enhance the yield of gas hydrocarbon,promote the total gas output,and increase the total hydrocarbon production(mass or volume).Uranium may lower the hydrocarbon generation threshold temperature and lead to the generation of liquid hydrocarbon in the relative low temperature of hydrocarbon source rock.Uranium can enhance the yield of saturated hydrocarbon,promote the low molecular weight hydrocarbons generating,and in turn increase the content of CH4 and the content of dry gas of the generated hydrocarbons.Uranium is one of the potential inorganic accelerating factors of the immature hydrocarbons.  相似文献   

12.
Clarification of the molecular mechanism underlying the interaction of coal with CH4, CO2, and H2O molecules is the basis for an in-depth understanding of the states of fluid in coal and fluid-induced coal swelling/contraction. In terms of instrumental analysis, molecular simulation technology based on molecular mechanics/dynamics and quantum chemistry is a powerful tool for revealing the relationship between the structure and properties of a substance and understanding the interaction mechanisms of physical-chemical systems. In this study, the giant canonical ensemble Monte Carlo (GCMC) and molecular dynamics (MD) methods were applied to investigate the adsorption behavior of a Yanzhou coal model (C222H185N3O17S5). We explored the adsorption amounts of CH4, CO2, and H2O onto Yanzhou coal, the adsorption conformation, and the impact of oxygen-containing functional groups. Furthermore, we revealed the different adsorption mechanisms of the three substances using isosteric heat of adsorption and energy change data. (1) The adsorption isotherms of the mono-component CH4, CO2, and H2O were consistent with the Langmuir model, and their adsorption amounts showed an order of CH4<CO2<H2O. In addition, high temperatures were non-conducive to adsorption. When the three components of CH4/CO2/H2O were mixed (at a molar ratio of 1:1:1) for adsorption, only the adsorption curve of H2O was consistent with the Langmuir model. (2) The mean values of the isosteric heat of adsorption of CH4, CO2, and H2O were 22.54, 36.90, and 37.82 kJ/mol, respectively; that is, H2O>CO2>CH4. In addition, at higher temperatures, the isosteric heat of adsorption decreased; pressure had no significant effect on the heat of adsorption. (3) CH4 molecules displayed an aggregated distribution in the pores, whereas CO2 molecules were cross arranged in pairs. Regarding H2O molecules, under the influence of hydrogen bonds, the O atom pointed to surrounding H2O molecules or the H atoms of coal molecules in a regular pattern. The intermolecular distances of the three substances were 0.421, 0.553, and 0.290 nm, respectively. The radial distribution function (RDF) analysis showed that H2O molecules were arranged in the most compact fashion, forming a tight molecular layer. (4) H2O molecules showed a significantly stratified distribution around oxygen-containing functional groups on the coal surface, and the bonding strength showed a descending order of hydroxyl> carboxyl>carbonyl. In contrast, CO2 and CH4 showed only slightly stratified distributions. (5) After the adsorption of CH4, CO2, and H2O, the total energy, the energy of valence electrons, and the non-bonding interaction of the system in the Yanzhou coal model all decreased. The results regarding the decrease in the total energy of the system indicated an order of H2O>CO2>CH4 in terms of the adsorption priority of the Yanzhou coal model. The results regarding the decrease in the energy of valence electrons showed that under certain geological conditions, a pressure-induced “coal strain” could lead to a structural rearrangement during the interaction of coal with fluid to form a more stable conformation, which might be the molecular mechanism of coal swelling resulting from the interaction between fluid and coal. An analysis of the contribution of Van der Waals forces, electrostatic interactions and hydrogen bonds to the decrease in non-bonding interactions revealed the mechanism underlying the interactions between coal molecules and the three substances. The interaction between coal molecules and CH4 consisted of typical physical adsorption, whereas that between coal molecules and CO2 consisted mainly of physical adsorption combined with weak chemical adsorption. The interaction between coal molecules and H2O is physical and chemical.  相似文献   

13.
Chemical properties of magmatic emanation can be estimated roughly by i) volatiles from rocks by heating at various temperatures, ii) volcanic emanations, iii) residual magmatic emanations, iv) calculation from chemical equilibrium between volatile matters and magmas. Magmatic emanation is assumed to consist all of the volatile matters in magmas such asH 2 O, HCl, HF, SO 2 H 2 S, H 2,CO 2,N 2 and others (halides, etc.) at about 1200°C, although various kinds of magmatic emanations can be formed at different conditions. Magmatic emanation separated from magmas will change their chemical properties by many factors such as changes of temperature and pressure (displacement of chemical equilibrium), and reactions with other substances and it will differentiate into volcanic gases, volcanic waters, volcanic sublimates, and hydrothermal deposits (hot spring deposits). At temperatures above the critical point of water, separation of solid phase (sublimates), liquid phase, and displacement of chemical equilibrium may take place, and gaseous phase will gradually change their chemical properties as will be seen at many fumaroles. Chloride, hydrogen, andSO 2 contents will gradually decrease along with lowering temperature. Once aqueous liquid phase appears below the critical point of water, all the soluble materials may dissolve into this hydrothermal solution. Consequently, the gaseous phase at this stage must have usually a little hydrogen chloride as is observed at many fumaroles. Aqueous solutions must be of acidic nature by dissolution of acid forming components, and by hydrolysis (Chloride type). When a self-reduction-oxidation reaction of sulfurous acid takes place, an aqueous solution of sulfate type will be formed. At this stage, solid phases consist of the remained sublimates which are difficultly soluble in aqueous solution, and deposits formed by reaction in the hydrothermal solutions. The gaseous phases below the boiling point of water, have usually a little water, and consist mainly ofCO 2 type,H 2 S type,N 2 type, and mixed type owing to elimination or addition of components by reactions with waters or wall rocks according to their geological conditions. Aqueous solutions which was of acidic nature must be changed into alkaline solutions by reaction with wall rocks for a long time. When the oxidation of sulfur compounds takes place, an aqueous solution of sulfate type will be formed. Hydrogen sulfide type of water will be formed by reaction of sulfides with acid waters or absorption of hydrogen sulfide. Carbonate type of water will be formed whenCO 2 is absorbed. Solid phases at this stage consist usually of hydrothermal deposits except for that at solfatara or mofette. The course of differentiation of magmatic emanation could take place in more complicated ways than that of magmatic differentiation.  相似文献   

14.
The concentration of dissolved uranium and234U/238U alpha activity ratio (“A.R.”) were determined in water samples from 23 locations in the Edwards carbonate aquifer of south central Texas by isotope dilution methods and alpha spectrometry. This aquifer consists of two parts, an updip oxidized portion and a downdip reduced portion. At some places the boundary is associated with faulting and at others it is not. The boundary between the two portions of the aquifer can be located by an abrupt change in chemical properties of the water such as a large increase in concentration of Cl?, SO42? and total dissolved solids, the presence of H2S and a decrease in Eh in moving from updip to downdip. Compared with the oxidized samples, the uranium concentration is much lower and the A.R. higher in the reduced samples so that the uranium from each portion falls in a distinct field. The oxidized aquifer samples show very little variation in the measured uranium parameters even though, in some cases, there is evidence that the water has flowed through some tens of kilometers of aquifer. Samples collected near the boundary at those places not associated with faulting yield dissolved uranium values which fall in neither field and which, for the most part, cannot result from mixing of the oxidized and reduced waters. These samples probably result from changes in location of the oxidation-reduction boundary.  相似文献   

15.
Evidence for a deuteric alteration process induced by a magmatic fluid has been found in the feeder zone of the Mururoa volcano (French Polynesia). Within the dikes, where basaltic glass does not show any evidence of pervasive alteration, vesicles are filled with dioctahedral smectites and calcite, while olivine phenocrysts are replaced by dioctahedral smectites, ankerite and calcite.The 13C signature of carbonates, the carbon and H2O content of the whole rocks and their impoverishment in deuterium are compatible with the presence of magmatic CO2 during the crystallization of intruding lavas and exclude contamination by seawater. Mass balance calculations on selected thin sections photographs of partly filled up vesicles and replaced olivine crystals, constrain, assuming a closed system interaction, the chemical composition of the initial fluid and the respective amounts of the initial solid phases involved in the alteration process. Thermodynamic modelings using the EQ3/6 software package correctly predict the mineralogic, chemical and isotopic exchanges accompanying alteration, thus validating the closed system assumption. The model which allows prediction of the influence of CO2 on the alteration products, shows that, above a 0.25 CO2 mole fraction in the initial fluid, the alteration is entirely controlled by the chemical composition of the initial solid phases. The presence of CO2 implies the precipitation of dioctahedral smectites and carbonates instead of the magnesian smectites commonly observed in CO2-free systems.The Mururoa feeder zone shows alteration features typical of a closed system interaction between the basaltic rock and a magmatic fluid in which seawater did not take part.  相似文献   

16.
Volcanic gases from Showashinzan are qualitatively the same as those liberated from igneous rocks when they are heated in vacuum. Their main components are H2O, CO2, and H2. Then follow HCl, HF, N2, SO2, H2S, S, CH4, CO, Ar, Si, B, Mg, Na, K, Ca, Al, Fe, P, Br, NH3, As, Zn, Sr, Ba, Cu, Pb, Sn, Sb, Bi, Ge, Ag, Cr, Ni, Mo, Rn, Ra, etc. They come through fumaroles of high temperature (～750°C.). Metallic compounds deposit as sublimates around the outlet of fumaroles. They are fractionated there according to their thermodynamic properties. When the temperature of gases falls, heavy metal elements deposit before reaching the surface of the earth. Ra is among them. Owing to the contribution of Ra thus depositted, Rn content of vapor is larger in low temperature fumaroles than in high temperature ones. Chemical compounds of H, C, N, O, and S vary their composition according to the condition of temperature and pressure. Sulfur exists as SO2 more than H2S. As the temperature of gases falls, SO2 and H2 decrease and H2S increases. Mutual relation among them is ruled by the chemical equilibrium: SO2+3H2=H2S+2H2O. The structure of Showashinzan is not simple. Some deviations from the general rule are explained in connection with ground water.  相似文献   

17.
Dongsheng sandstone-type uranium deposit is located in the northern part of Ordos Basin, occurring in the transitional zones between gray-green and gray sandstones of Jurassic Zhiluo Formation. Sandstones in oxidized zone of the ore bed look gray-green, being of unique signature and different from one of ordinary inter-layered oxidation zone of sandstone-type uranium deposits. The character and origin of gray-green sandstones are systematically studied through their petrology, mineralogy and geochemistry. It is pointed out that this color of sandstones is originated from secondary oil-gas reduction processes after paleo-oxidation, being due to acicular-leaf chlorite covering surfaces of the sandstone grains. To find out the origin of gray-green sandstone and recognize paleo-oxidation zones in the ore bed are of not only theoretical significance for understanding metallogenesis of this kind of sandstone-type uranium deposit, but also very importantly practical significance for prospecting for similar kind of sandstone-type uranium deposit.  相似文献   

18.
Dongsheng sandstone-type uranium deposit is located in the northern part of Ordos Basin, occurring in the transitional zones between gray-green and gray sandstones of Jurassic Zhiluo Formation. Sandstones in oxidized zone of the ore bed look gray-green, being of unique signature and different from one of ordinary inter-layered oxidation zone of sandstone-type uranium deposits. The character and origin of gray-green sandstones are systematically studied through their petrology, mineralogy and geochemistry. It is pointed out that this color of sandstones is originated from secondary oil-gas reduction processes after paleo-oxidation, being due to acicular-leaf chlorite covering surfaces of the sandstone grains. To find out the origin of gray-green sandstone and recognize paleo-oxidation zones in the ore bed are of not only theoretical significance for understanding metallogenesis of this kind of sandstone-type uranium deposit, but also very importantly practical significance for prospecting for similar kind of sandstone-type uranium deposit.  相似文献   

19.
Changkeng Au-Ag deposit is a newly-discovered new type precious metal deposit. N2-Ar-He systematics studies and3He/4He and δD- δ18O composition analyses show that the ore-forming fluid of the deposit is composed mainly of formation water (sedimentary brine) but not of meteoric water, which was thought to be source of the ore-forming fluid by most previous researchers. The content of mantle-derived magmatic water in the ore-forming fluid is quite low, usually lower than 10%. According to the source of the ore-forming fluid, the Changkeng Au-Ag deposit should belong to sedimentary brine transformed deposits. From the Late Jurassic to the Early Cretaceous Period, with deposition and accumulation of thick sediments in Sanzhou Basin, the formation water in the sedimentary layers was expelled from the basin because of overburden pressure and increasing temperature. The expelled fluid moved laterally along sedimentary layers to the margin of the basin, and finally moved upward along a gently-dipping interlayer fault. Because of a decline in pressure and temperature, ore minerals were deposited in the fault. Project supported by the National Natural Science Foundation of China (Grant No. 495020291, the Natural Science Foundation of Zhongshan University, the Research Foundation of National Key Laboratory of Metallogenesis in Nanjing University (Grant No. 039704) and the Lingnan Foundation.  相似文献   

20.
Data of hydrological and hydrochemical observations conducted in August 2000 at Lake Seliger and its major tributaries are presented. The analyzed characteristics included: O2, H2S, CH4, microelements; mineral and organic compounds of P and N, ionic composition components (HCO3 –, Cl–, Na+, K+, dry residue, pH; color index, electrical conductivity. Bottom sediment samples were analyzed for microelement concentrations, CH4, oil hydrocarbons. The influence of the basin on the ecological state of the lake was assessed, and tendencies in the evolution of its ecosystem are analyzed. It is shown that the ecological conditions of the lake has not changed significantly since 1960–1991, however, nutrient concentrations in the lake water was found to increase.  相似文献   

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