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1.
P–T conditions and prograde P–T paths have beencalculated for amphibolite-grade pelites and amphibolites fromCordillera Darwin, Tierra del Fuego, Chile. Peak P–T conditionsare nearly all within the kyanite stability field; temperaturesgenerally show an increase with increasing grade, but pressureshave a less consistent trend, possibly increasing slightly fromgarnet to kyanite grade. P–T paths from pelites show heatingby 80–100C during loading of 0•2–3 kbar. Texturalanalysis and previous structural work indicate that this segmentof the path correlates with back-folding deformation. P–Tpaths from two Mg-rich garnet amphibolites suggest a decreasein pressure of as much as 3 kbar with 25–50C of heatingfrom the kyanite stability field to the sillimanite, and areconsistent with pervasive, minor development of fibrolitic sillimanitealong plagioclase grain boundaries. Together, the P–Tpath segments from pelites and amphibolites constitute a clockwiseP–T trajectory. The proposed clockwise P–T paths are consistent with theinterpretation that Cordillera Darwin represents an extensionallyexhumed metamorphic core complex, in which loading during garnetgrowth in the pelitic rocks was succeeded by differential upliftduring garnet growth in magnesian amphibolites. * Present address: Department of Geology and Geophysics, University of Wisconsin, Madison, Wisconsin 53706  相似文献   

2.
Integrated metamorphic and geochronological data place new constraintson the metamorphic evolution of a Neoproterozoic orogen in eastAntarctica. Granulite-facies rocks from a 150 km stretch ofthe Kemp Land coast reflect peak conditions involving T 870–990°Cat P 7·4–10 kbar, with pressure increasing westwardtowards an Archaean craton. Electron microprobe-derived (Th+ U)–Pb monazite ages from metapelitic assemblages indicatethat the major mineral textures in these rocks developed duringthe c. 940 Ma Rayner Orogeny. Complex compositional zoning inmonazite suggests high-T recrystallization over c. 25 Myr. Diversityin metapelitic reaction textures reflects silica and ferromagnesiancontent: Si-saturated Fe-rich metapelites contain garnet thatis partially pseudomorphed by biotite and sillimanite, whereasSi-saturated Mg-rich metapelites and Si-undersaturated metapeliticpods have reaction microstructures involving cordierite enclosingorthopyroxene, garnet and/or sapphirine, cordierite + sapphirinesymplectites around sillimanite and coarse-grained orthopyroxene+ corundum separated by sapphirine coronae. Interpretationsbased on P–T pseudosections provide integrated bulk-rockconstraints and indicate a clockwise P–T–t pathcharacterized by a post-peak P–T trajectory with dP/dT 15–20 bar/ °C. This moderately sloped decompressive-coolingP–T path is in contrast to near-isothermal decompressionP–T paths commonly cited for this region of the RaynerComplex, with implications for the post-collisional tectonicresponse of the mid- to lower crust within this orogenic belt. KEY WORDS: electron microprobe monazite dating; granulite facies; Rayner Complex; sapphirine; THERMOCALCMinerals abbreviations: q, quartz; g, garnet; sill, sillimanite; ky, kyanite; opx, orthopyroxene; cd, cordierite; ksp, alkali feldspar; pl, plagioclase; bi, biotite; sp, spinel; ilm, ilmenite; mt, magnetite; ru, rutile; sa, sapphirine; cor, corundum; osm, osumilite; liq, silicate melt; mnz, monazite  相似文献   

3.
Talc–kyanite schists (whiteschists), magnesiohornblende–kyanite–talc–quartzschists and enstatite–sapphirine–chlorite schistsoccur at Mautia Hill in the East African Orogen of Tanzania.They are associated with metapelites and garnet–clinopyroxene–quartzmetabasites. Geobarometry (GASP/GADS equilibria) applied tothe latter two rock types indicates a peak pressure of P = 10–11kbar. These results are confirmed by the high fO2 assemblagehollandite–kyanite–quartz and late-stage manganianandalusite that contains up to 19·5 mol. % Mn2SiO5. Maximumtemperatures of T = 720°C are inferred from late-stage yoderite+ quartz. A clockwise P–T evolution is constrained byprograde kyanite inclusions in metapelitic garnet and late-stagereaction rims of cordierite between green yoderite and talcthat reflect conditions at least 3–4 kbar below the peakpressure. Oxidizing conditions are recorded throughout the metamorphichistory of the whiteschists and chlorite schists, as indicatedby the presence of haematite coexisting with pseudobrookiteand/or rutile. Increasing water activity near peak pressuresis thought to have led to the breakdown of the high-pressureassemblages (Tlc–Ky–Hem and Mg-Hbl–Ky–Hem)and the subsequent formation of certain uncommon minerals, e.g.yellow sapphirine, Mn–andalusite, green and purple yoderite,piemontite and boron-free kornerupine. The proposed increasein water activity is attributed to fluid infiltration resultingfrom the devolatilization of underlying sediments during metamorphism. KEY WORDS: fluid infiltration; high-pressure amphibolite facies; East African Orogen; Pan-African; whiteschist  相似文献   

4.
Petrogenetic grids in the system NCKFMASH (Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O)and the subsystems NCKMASH and NCKFASH calculated with the softwareTHERMOCALC 3.1 are presented for the P–T range 7–30kbar and 450–680°C, for assemblages involving garnet,chloritoid, biotite, carpholite, talc, chlorite, kyanite, staurolite,paragonite, glaucophane, jadeite, omphacite, diopsidic pyroxene,plagioclase, zoisite and lawsonite, with phengite, quartz/coesiteand H2O in excess. These grids, together with calculated compatibilitydiagrams and P–T and T–XCa and P–XCa pseudosectionsfor different bulk-rock compositions, show that incorporationof Ca into the NKFMASH system leads to many of the NKFMASH invariantequilibria moving to lower pressure and/or lower temperature,which results, in most cases, in the stability of jadeite andgarnet being enlarged, but in the reduction of stability ofglaucophane, plagioclase and AFM phases. The effect of Ca onthe stability of paragonite is dependent on mineral assemblageat different P–T conditions. The calculated NCKFMASH diagramsare powerful in delineating the phase equilibria and P–Tconditions of natural pelitic assemblages. Moreover, contoursof the calculated phengite Si isopleths in P–T and P–XCapseudosections confirm that phengite barometry in NCKFMASH isstrongly dependent on mineral assemblage. KEY WORDS: phase relations; metapelites; NCKFMASH; THERMOCALC; phengite geobarometry  相似文献   

5.
The Menderes Massif and the overlying Lycian Nappes occupy anextensive area of SW Turkey where high-pressure–low-temperaturemetamorphic rocks occur. Precise retrograde P–T pathsreflecting the tectonic mechanisms responsible for the exhumationof these high-pressure–low-temperature rocks can be constrainedwith multi-equilibrium P–T estimates relying on localequilibria. Whereas a simple isothermal decompression is documentedfor the exhumation of high-pressure parageneses from the southernMenderes Massif, various P–T paths are observed in theoverlying Karaova Formation of the Lycian Nappes. In the uppermostlevels of this unit, far from the contact with the MenderesMassif, all P–T estimates depict cooling decompressionpaths. These high-pressure cooling paths are associated withtop-to-the-NNE movements related to the Akçakaya shearzone, located at the top of the Karaova Formation. This zoneof strain localization is a local intra-nappe contact that wasactive in the early stages of exhumation of the high-pressurerocks. In contrast, at the base of the Karaova Formation, alongthe contact with the Menderes Massif, P–T calculationsshow decompressional heating exhumation paths. These paths areassociated with severe deformation characterized by top-to-the-eastshearing related to a major shear zone (the Gerit shear zone)that reflects late exhumation of high-pressure parageneses underwarmer conditions. KEY WORDS: exhumation; high-pressure–low-temperature metamorphism; multi-equilibrium P–T estimates; Lycian Nappes; Menderes Massif  相似文献   

6.
High-Mg–Al, silica-undersaturated metapelites from theOygarden Group of islands, East Antarctica, preserve clear evidencefor the stable coexistence of the assemblage orthopyroxene +corundum in natural rocks. The quartz-absent metapelite occursas pods and isolated layers within a high-strain zone relatedto deformation during the c. 0·93 Ga Rayner StructuralEpisode. Assemblages that include orthopyroxene, corundum, sapphirine,sillimanite, cordierite, garnet and kornerupine are developedacross a pre-existing compositional zoning, leading to contrastingmineral Fe–Mg ratios. The assemblage orthopyroxene–corundumis shown to exist in only a very restricted range of bulk compositionsand P–T histories. Simplified qualitative FMAS grids havebeen constructed for kornerupine-absent and -present systems,illustrating MAS terminations and divariant equilibria thathelp to describe the mineral assemblage and reaction history.Reaction textures that include coronas of sapphirine and sillimaniteseparating orthopyroxene and corundum, and symplectites of orthopyroxene+ sapphirine ± cordierite/plagioclase, orthopyroxene+ sillimanite ± cordierite/plagioclase and orthopyroxene+ sapphirine + sillimanite embaying garnet, imply a clockwiseP–T–t evolution. Conditions of P > 9–10kbar and T  相似文献   

7.
Using an internally consistent thermodynamic dataset and updatedmodels of activity–composition relation for solid solutions,petrogenetic grids in the system NKFMASH (Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O)and the subsystems NKMASH and NKFASH have been calculated withthe software THERMOCALC 3.1 in the P–T range 5–36kbar and 400–810°C, involving garnet, chloritoid,biotite, carpholite, talc, chlorite, kyanite/sillimanite, staurolite,phengite, paragonite, albite, glaucophane, jadeite, with quartz/coesiteand H2O in excess. These grids, together with calculated AFMcompatibility diagrams and P–T pseudosections, are shownto be powerful tools for delineating the phase equilibria andP–T conditions of Na-bearing pelitic assemblages for avariety of bulk compositions from high-P terranes around theworld. These calculated equilibria are in good agreement withpetrological studies. Moreover, contours of the calculated phengiteSi isopleths in P–T pseudosections for different bulkcompositions confirm that phengite barometry is highly dependenton mineral assemblage. KEY WORDS: phase relations; HP metapelite; NKFMASH; THERMOCALC; phengite geobarometry  相似文献   

8.
A combined petrological and geochronological study was carriedout on mafic granulites and associated felsic gneisses fromthe McKaskle Hills, eastern Amery Ice Shelf, East Antarctica.Garnet-bearing mafic granulites exhibit reaction textures andexsolution textures that indicate two-stage metamorphic evolution.Thermobarometric estimates from matrix and symplectite assemblagesyield peak and retrograde P–T conditions of 9·0–9·5kbar and 880–950°C and 6·6–7·2kbar and 700–750°C, respectively. Similar but slightlyscattered peak P–T estimates of 7·9–10·1kbar and 820–980°C are obtained from the core compositionsof minerals from felsic para- and orthogneisses. Evidence forthe prograde history is provided by muscovite inclusions ingarnet from a paragneiss. Sensitive high-resolution ion microprobeU–Pb zircon dating reveals an evolutionary history forthe granulites, including a mafic and felsic igneous intrusionat 1174–1019 Ma, sedimentation after 932–916 Ma,and a high-grade metamorphism at 533–529 Ma. In contrast,Sm–Nd mineral–whole-rock dating mainly yields asingle age population at 500 Ma. This suggests that the McKaskleHills form part of the Prydz Belt, and that the relatively highpeak P–T conditions and a decompression-dominated P–Tpath for the rocks resulted from a single Cambrian metamorphiccycle, rather than two distinct metamorphic events as formerlyinferred for the granulites from Prydz Bay. The age data alsoindicate that the Precambrian history of the McKaskle Hillsis not only distinct from that of the early Neoproterozoic terranein the northern Prince Charles Mountains, but also differentfrom that of other parts of the Prydz Belt. The existence ofmultiple basement terranes, together with considerable crustalthickening followed by tectonic uplift and unroofing indicatedby the clockwise P–T–t evolution, suggests thatthe Prydz Belt may represent a collisional orogen that resultedin the assembly of Gondwana during the Cambrian period. KEY WORDS: Mesoproterozoic basement; Cambrian metamorphism; P–T path; Prydz Belt; East Antarctica  相似文献   

9.
The Bixiling mafic-ultramafic metamorphic complex is a 1•5km2 tectonic block within biotite gneiss in the southern Dabieultrahigh-pressure terrane, central China. The complex consistsof banded eclogites that contain thin layers of garnet-bearingcumulate ultramafic rock. Except for common eclogitic phases(garnet, omphacite, kyanite, phengite, zoisite and rutilc),banded eclogites contain additional talc and abundant coesiteinclusions in omphacite, zoisite, kyanite and garnet. Some metaultramaficrocks contain magnesite and Ti-clinohumite. Both eclogites andmeta-ultramafic rocks have undergone multi-stage metamorphism.Eclogite facies metamorphisrn occurred at 610–700C andP>27 kbar, whereas amphibolite facies retrograde metamorphismis characterized by symplectites of plagioclase and hornblendeafter omphacite and replacement of tremolite after talc at P<6–15kbar and T <600C. The meta-ultramafic assemblages such asolivine + enstatite + diopside + garnet and Ti-clinohumite +diopside + enstatite + garnet + magnesite olivine formed at700–800C and 47–67 kbar. Investigation of the phaserelations for the system CaO-MgO-SiO2-H2O-CO2 and the experimentallydetermined stabilities of talc, magnesite and Ti-clinohumiteindicate that (1) UHP talc assemblages are restricted to Mg-Algabbro composition and cannot be an important water-bearingphase in the ultramafic mantle, and (2) Ti-clinohumite and magnesiteare stable H2O-bearing and CO2-bearing phases at depths >100km. The mafic-ultramafic cumulates were initially emplaced atcrustal levels, then subducted to great depths during the Triassiccollision of the Sine-Korean and Yangtze cratons. KEY WORDS: eclogite; magnesite; meta-ultramafics; talc; ultrahigh-P metamorphism *Corresponding author  相似文献   

10.
We report experimental results and whole-rock trace-elementcharacteristics of a corundum-bearing mafic rock from the Horomanperidotite complex, Japan. Coronitic textures around corundumin the sample suggest that corundum was not stable in maficrock compositions during the late-stage P–T conditionsrecorded in the complex (P < 1 GPa, T < 800°C). Basedon the experimental results, corundum is stable in aluminousmafic compositions at pressures of 2–3 GPa under dry conditions,suggesting that the corundum-bearing mineral assemblages developedunder upper-mantle conditions, probably within the surroundingperidotite. Variations in the trace-element compositions ofthe corundum-bearing mafic rock and related rocks can be controlledby modal variations of plagioclase, clinopyroxene and olivine,suggesting that they formed as gabbroic rocks at low-pressureconditions, and that the corundum-bearing mafic rock was derivedfrom a plagioclase-rich protolith. A complex P–T trajectory,involving metamorphism of the plagioclase-rich protolith ata pressure higher than that at which it was first formed, isneeded to explain the origin of the corundum-bearing mafic rocks.They show no evidence for partial melting after their formationas low-pressure cumulates. The Horoman complex is an exampleof a large peridotite body containing possible remnants of subductedoceanic lithosphere still retaining their original geochemicalsignatures without chemical modification during subduction andexhumation. KEY WORDS: Horoman; mafic rock; corundum; experiment; P–T history; recycling  相似文献   

11.
Extensive high-grade polydeformed metamorphic provinces surroundingArchaean cratonic nuclei in the East Antarctic Shield recordtwo tectono-thermal episodes in late Mesoproterozoic and lateNeoproterozoic–Cambrian times. In Western Dronning MaudLand, the high-grade Mesoproterozoic Maud Belt is juxtaposedagainst the Archaean Grunehogna Province and has traditionallybeen interpreted as a Grenvillian mobile belt that was thermallyoverprinted during the Early Palaeozoic. Integration of newU–Pb sensitive high-resolution ion microprobe and conventionalsingle zircon and monazite age data, and Ar–Ar data onhornblende and biotite, with thermobarometric calculations onrocks from the H.U. Sverdrupfjella, northern Maud Belt, resultedin a more complex P–T–t evolution than previouslyassumed. A c. 540 Ma monazite, hosted by an upper ampibolite-faciesmineral assemblage defining a regionally dominant top-to-NWshear fabric, provides strong evidence for the penetrative deformationin the area being of Pan-African age and not of Grenvillianage as previously reported. Relics of an eclogite-facies garnet–omphaciteassemblage within strain-protected mafic boudins indicate thatthe peak metamorphic conditions recorded by most rocks in thearea (T = 687–758°C, P = 9·4–11·3kbar) were attained subsequent to decompression from P >12·9 kbar. By analogy with limited U–Pb singlezircon age data and on circumstantial textural grounds, thisearlier eclogite-facies metamorphism is ascribed to subductionand accretion around 565 Ma. Post-peak metamorphic K-metasomatismunder amphibolite-facies conditions is ascribed to the intrusionof post-orogenic granite at c. 480 Ma. The recognition of extensivePan-African tectonism in the Maud Belt casts doubts on previousRodinia reconstructions, in which this belt takes a pivotalposition between East Antarctica, the Kalahari Craton and Laurentia.Evidence of late Mesoproterozoic high-grade metamorphism duringthe formation of the Maud Belt exists in the form of c. 1035Ma zircon overgrowths that are probably related to relics ofgranulite-facies metamorphism recorded from other parts of theMaud Belt. The polymetamorphic rocks are largely derived froma c. 1140 Ma volcanic arc and 1072 ± 10 Ma granite. KEY WORDS: Maud Belt; Pan-African orogeny; geochronology; P–T–t path, East Antarctica  相似文献   

12.
SAJEEV  K.; OSANAI  Y. 《Journal of Petrology》2004,45(9):1821-1844
Mg- and Al-rich granulites of the central Highland Complex,Sri Lanka preserve a range of reaction textures indicative ofa multistage P–T history following an ultrahigh-temperaturemetamorphic peak. The granulites contain a near-peak assemblageof sapphirine–garnet–orthopyroxene–sillimanite–quartz–K-feldspar,which was later overprinted by intergrowth, symplectite andcorona textures involving orthopyroxene, sapphirine, cordieriteand spinel. Biotite-rims, kornerupine and orthopyroxene-rimson biotite are considered to be late assemblages. Thermobarometriccalculations yield an estimated P–T of at least 1100°Cand 12 kbar for the near-peak metamorphism. Isopleths of Al2O3in orthopyroxene are consistent with a peak temperature above1150°C. The P–T path consists of four segments. Initialisobaric cooling after peak metamorphism (Segment A), whichproduced the garnet–sapphirine–quartz assemblage,was followed by near-isothermal decompression at ultrahigh temperature(Segment B), which produced the multiphase symplectites. Furtherisobaric cooling (Segment C) resulted in the formation of biotiteand kornerupine, and late isothermal decompression (SegmentD) formed orthopyroxene rims on biotite. This evolution canbe correlated with similar P–T paths elsewhere, but thereare not yet sufficient geochronological and structural dataavailable from the Highland Complex to allow the tectonic implicationsto be fully assessed. KEY WORDS: central Highland Complex; granulites; multistage evolution; Sri Lanka; UHT metamorphism  相似文献   

13.
The P–T gradient in a Late Eocene low-T high-P metamorphicbelt in northern New Caledonia increases from SW to NE. Metapelitesin the pumpellyite–prehnite and blueschist zones containlawsonite, Mg-carpholite, Fe-stilpnomelane and Fe-glaucophane.Thermodynamic calculations indicate a progression of metamorphicconditions from less than 0·3 GPa and 250°C in akaolinite-bearing rock in the SW, up to 1·5 GPa and 410°Cin a lawsonite–glaucophane-bearing sample in the NE ofthe Diahot terrane. Through a multi-method investigation ofphyllosilicates, organic matter and fluid inclusions, we demonstratethat the evolution of organic matter and illite crystallinitydepends strongly on the evolution of the P–T path withtime. In addition, we show that the illite–muscovite bcell dimension provides a robust estimate of maximum pressurereached in low-temperature domains with polyphase metamorphichistories, despite subsequent high-temperature–low-pressureevents. Fluid inclusion study reveals an isothermal decompressionin the Diahot terrane. KEY WORDS: low-temperature/high-pressure metapelites; illite crystallinity; coal rank; illite–muscovite b cell dimension; New Caledonia  相似文献   

14.
A light-coloured, fine-grained eclogite sample from near thevillage of Hammerunterwiesenthal in the Erzgebirge (NW BohemianMassif) preserves the low-variance mineral assemblage of garnet,omphacite, phengite, talc, amphibole, clinozoisite, quartz,rutile, and accessory phases. Porphyroblasts of amphibole, clinozoisite,and phengite formed during a late stage (III) of metamorphism.Paragonite joined the assemblage late in this stage (IIIb).The chemical zonation of the minerals was carefully studied.Various geothermobarometric methods were applied, especiallyinvolving phengite and talc. The constrained P–T pathfor the eclogite starts at about 480°C and 25 kbar (stageIb), followed by a significant temperature rise (stage II) atslightly increasing pressure. At the peak P–T conditionsof 720°C and 27 kbar, blastesis of amphibole, clinozoisite,and phengite was caused by infiltrating hydrous fluids. Theresulting density reduction may have allowed buoyant upliftof the eclogite. Subsequently, significant cooling occurredat high pressures. Stage IIIb is characterized by P–Tconditions around 520°C and 18 kbar at reduced water activities.This unusual late P–T evolution might explain the freshnessof the eclogite, including the preservation of chemical zonationon the micrometre scale. KEY WORDS: eclogite; Saxonian Erzgebirge; P–T evolution; talc; phengite  相似文献   

15.
Migmatitic granulites and arc-related felsic intrusives of Pan-Africanage form the bedrock in the Rio de Janeiro area, SE Brazil.These rocks preserve a partial record of three parageneses.The earliest assemblage (M1) grew during fabric formation inthe rocks (D1) and is characterized by the mineral assemblagePl + Bt + Sil + Kfs + Qtz. Peak metamorphic conditions (M2)are characterized by the assemblage Bt + Crd + Kfs + Pl + Grt+ liq + Qtz and are inferred to have developed during D2 foldingof the rocks at T = 750–800°C and P = 7 kbar. M3 reactiontextures overprint the M2 assemblage and comprise symplectiticintergrowth of cordierite(II) and quartz that formed after garnet,whereas secondary biotite formed as a result of reactions betweengarnet and K-feldspar. By comparing the observed modal abundanceswith modal contours of garnet, cordierite and quartz on therelevant pseudosection a post M2 P–T vector indicatingcontemporaneous cooling and decompression can be deduced. Theinferred equilibrium assemblage and reaction textures are interpretedto reflect a clockwise P–T path involving heating followedby post-peak decompression and associated cooling. We inferthat metamorphism occurred in response to advective heatingby the abundant syn-collisional (arc-related) I-type granitoidsin the region, consistent with the unusually high peak T/P ratio. KEY WORDS: advective heating; Ribeira belt; granulite; partial melting; P–T pseudosection  相似文献   

16.
Metapelitic rock samples from the NE Shackleton Range, Antarctica,include garnet with contrasting zonation patterns and two agespectra. Garnet porphyroblasts in K-rich kyanite–sillimanite–staurolite–garnet–muscovite–biotite schistsfrom Lord Nunatak show prograde growth zonation, and give Sm–Ndgarnet, U–Pb monazite and Rb–Sr muscovite ages of518 ± 5, 514 ± 1 and 499 ± 12 Ma, respectively.Geothermobarometry and P–T pseudo-section calculationsin the model system CaO–Na2O–K2O– TiO2–MnO–FeO–MgO–Al2O3–SiO2–H2Oare consistent with garnet growth during prograde heating from540°C/7 kbar to 650°C/7·5 kbar, and partial resorptionduring a subsequent P–T decrease to <650°C at <6kbar. All data indicate that rocks from Lord Nunatak were affectedby a single orogenic cycle. In contrast, garnet porphyroblastsin K-poor kyanite–sillimanite– staurolite–garnet–cordierite–biotite-schistsfrom Meade Nunatak show two growth stages and diffusion-controlledzonation. Two distinct age groups were obtained. Laser ablationplasma ionization multicollector mass spectrometry in situ analysesof monazite, completely enclosed by a first garnet generation,yield ages of c. 1700 Ma, whereas monazite grains in open garnetfractures and in most matrix domains give c. 500 Ma. Both agegroups are also obtained by U–Pb thermal ionization massspectrometry analyses of matrix monazite and zircon, which fallon a discordia with lower and upper intercepts at 502 ±1 and 1686 ± 2 Ma, respectively. Sm–Nd garnet datingyields an age of 1571 ± 40 Ma and Rb–Sr biotiteanalyses give an age of 504 ± 1 Ma. Integrated geochronologicaland petrological data provide evidence that rocks from MeadeNunatak underwent a polymetamorphic Barrovian-type metamorphism:(1) garnet 1 growth and subsequent diffusive garnet annealingbetween 1700 and 1570 Ma; (2) garnet 2 growth during the RossOrogeny at c. 500 Ma. During the final orogenic event the rocksexperienced peak P–T conditions of about 650°C/7·0kbar and a retrograde stage at c. 575°C/4·0 kbar. KEY WORDS: garnet microtexture; P–T pseudosection; geochronology; polymetamorphism; Shackleton Range; Antarctica  相似文献   

17.
On the basis of the net transfer reactions among garnet, biotite,plagioclase and quartz (for both Mg and Fe end-member models),the garnet–biotite–plagioclase–quartz (GBPQ)geobarometer was empirically calibrated under physical conditionsof P = 1·0–11·4 kbar and T = 515–878°C,based on the input garnet–biotite temperatures and garnet–aluminosilicate–plagioclase–quartz(GASP) pressures of 224 natural aluminosilicate-bearing metapeliticsamples collated from the literature. The calibrations are internallyconsistent with the asymmetric quaternary solid solution modelof garnet, the symmetric quaternary solid solution model ofbiotite, and the Al-avoidance ternary solid solution model ofplagioclase in calibrating the garnet–biotite geothermometerand the GASP geobarometer. The resulting two GBPQ barometerformulae reproduce the input GASP pressures well within ±1·0kbar (mostly within ±0·5 kbar). For both aluminosilicate-bearingand aluminosilicate-absent metapelites, the two GBPQ barometryformulae yielded identical pressures, whether the sample wasincluded or not included in calibrating the GBPQ barometry.The random error of the GBPQ barometry may be expected as ±1·2kbar. The dP/dT slopes of these two GBPQ formulae are closeto that of the GASP barometer in P–T space. Applicationsof the GBPQ barometry of aluminosilicate-absent metapelitesto the rocks within a thermal contact aureole, or rocks withina limited geographical area without post-metamorphic structuraldiscontinuity, show no obvious pressure change. It may be concludedthat the two GBPQ barometry formulae derived in this study maybe used as practical tools for metamorphic pelites under theconditions of 515–878°C and 1·0–11·4kbar, in the composition range of Xgros >3% in garnet, Xan>17% in plagioclase, and  相似文献   

18.
INUI  M.; TORIUMI  M. 《Journal of Petrology》2004,45(7):1369-1392
Chemical zoning of garnet is often used to deduce P–Tpaths of rocks by inverse calculation. To validate the derivedP–T paths, it is desired to establish a method to predictthe chemical compositions of garnet theoretically. This studyproposes a new forward calculation of the formation of Mg–Fe–Mngarnet from chlorite, which solves the non-linear simultaneousequations using nested iterative calculations. Growth of garnetconsuming chlorite and quartz was modelled in a MnO–FeO–MgO–Al2O3–SiO2–H2Osystem, using the most recent thermodynamic data for the minerals.The prograde P–T history of the Sambagawa metamorphicbelt, SW Japan, was modelled. To reproduce growth zoning, crystallizedgarnet was removed step by step from the system; perfect diffusionwas assumed for chlorite. The proposed model derived the evolutionof molar amounts and chemical compositions of Mg–Fe–Mnchlorite and garnet. It successfully reproduced the shape ofthe observed chemical profile of garnet, although the temperaturecondition was higher than general observations. The Mn contentof the garnet core was generally high, and Mg/Fe ratio alwaysstarted rising rapidly after Mn was depleted. Thermodynamicproperties of minerals, initial chlorite composition, P–Tpath, H2O partial pressure, and Ca content in garnet were variedto test the behaviour of the system. The properties of Mn phasesinfluenced only the chemical composition of the garnet core.The temperature range in which garnet grew depended on the H2Opartial pressure or the Ca content in garnet. KEY WORDS: chemical equilibrium; chemical zoning; garnet; forward modelling; Sambagawa metamorphic belt  相似文献   

19.
The northern margin of the Inland Branch of the Pan-AfricanDamara Orogen in Namibia shows dramatic along-strike variationin metamorphic character during convergence between the Congoand Kalahari Cratons (M3 metamorphic cycle). Low-P contact metamorphismwith anticlockwise P–T paths dominates in the westerndomains (Ugab Zone and western Northern Zone), and high-P Barrovianmetamorphism with a clockwise P–T path is documented fromthe easternmost domain (eastern Northern Zone). The sequenceof M3 mineral growth in contact aureoles shows early growthof cordierite porphyroblasts that were pseudomorphed to biotite–chlorite–muscoviteat the same time as an andalusite–biotite–muscovitetransposed foliation was developed in the matrix. The peak-Tmetamorphic assemblages and fabrics were overprinted by crenulationsand retrograde chlorite–muscovite. The KFMASH P–Tpseudosection for metapelites in the Ugab Zone and western NorthernZone contact aureoles indicates tight anticlockwise P–Tloops through peak metamorphic conditions of 540–570°Cand 2·5–3·2 kbar. These semi-quantitativeP–T loops are consistent with average P–T calculationsusing THERMOCALC, which give a pooled mean of 556 ± 26°Cand 3·2 ± 0·6 kbar, indicating a high averagethermal gradient of 50°C/km. In contrast, the eastern NorthernZone experienced deep burial, high-P/moderate-T Barrovian M3metamorphism with an average thermal gradient of 21°C/kmand peak metamorphic conditions of c. 635°C and 8·7kbar. The calculated P–T pseudosection and garnet compositionalisopleths in KFMASH, appropriate for the metapelite sample fromthis region, document a clockwise P–T path. Early plagioclase–kyanite–biotiteparageneses evolved by plagioclase consumption and the growthof garnet to increasing XFe, XMg and XCa and decreasing XMncompositions, indicating steep burial with heating. The developedkyanite–garnet–biotite peak metamorphic parageneseswere followed by the resorption of garnet and formation of plagioclasemoats, indicating decompression, which was followed by retrogressivecooling and chlorite–muscovite growth. The clockwise P–Tloop is consistent with the foreland vergent fold–thrustbelt geometry in this part of the northern margin. Earlier formed(580–570 Ma) pervasive matrix foliations (M2) were overprintedby contact metamorphic parageneses (M3) in the aureoles of 530± 3 Ma granites in the Ugab Zone and 553–514 Magranites in the western Northern Zone. Available geochronologicaldata suggest that convergence between the Congo and KalahariCratons was essentially coeval in all parts of the northernmargin, with similar ages of 535–530 Ma for the main phaseof deformation in the eastern Northern Zone and Northern Platformand 538–505 Ma high-grade metamorphism of the CentralZone immediately to the south. Consequently, NNE–SSW-directedconvergent deformation and associated M3 metamorphism of contrastingstyles are interpreted to be broadly contemporaneous along thelength of the northern margin of the Inland Branch. In the westheat transfer was dominated by conduction and externally drivenby granites, whereas in the east heat transfer was dominatedby advection and internally driven radiogenic heat production.The ultimate cause was along-orogen variation in crustal architecture,including thickness of the passive margin lithosphere and thicknessof the overlying sedimentary succession. KEY WORDS: Pan-African Orogeny; P–T paths; pseudosections; low-P metamorphism; contact metamorphism; Barrovian metamorphism  相似文献   

20.
The Diahot terrane of NE New Caledonia contains an interbeddedsequence of Cretaceous to Eocene metasediments, felsic and maficmetavolcanics that experienced c. 40 Ma high-P/T metamorphism.Metabasaltic assemblages define two prograde events (M1 andM2) and a tectonically disrupted crustal profile that extendsfrom lawsonite–blueschist conditions in the SW to paragonite–eclogiteconditions in the NE. Weakly deformed metabasalts from lowest-gradeparts of the Diahot terrane contain M1 omphacite, chlorite,lawsonite and glaucophane-bearing assemblages that partiallypseudomorph igneous plagioclase and augite, and reflect P =0·7–1·0 GPa and T = 350–400°C.M1 assemblages are enveloped by a steeply SW-dipping S2 foliationthat becomes progressively more intense towards the NE overa distance of c. 15 km. S2 assemblages are divided into fourzones: (1) lawsonite–omphacite; (2) lawsonite–clinozoisite–spessartine;(3) clinozoisite–hornblende–almandine; (4) almandine–omphacite.S2 assemblages reflect a P–T gradient that spans the exposed15 km of the Diahot terrane from P = 0·8–1·0GPa and T = 350–400°C (Zone 1) to P = 1·6–1·7GPa and T = 550–600°C (Zone 4). The systematic mineralogicalchanges reflect parts of a P–T array between 1·0and 1·7 GPa that was extensively disrupted by tectonicthinning during exhumation. KEY WORDS: blueschist; eclogite; New Caledonia; CNFMASH; pseudosection  相似文献   

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