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1.
Hydrothermal experiments were conducted to determine the partitioning of Cl between rhyolitic to rhyodacitic melts, apatite, and aqueous fluid(s) and the partitioning of F between apatite and these melts at ca. 200 MPa and 900-924 °C. The number of fluid phases in our experiments is unknown; they may have involved a single fluid or vapor plus saline liquid. The partitioning behavior of Cl between apatite and melt is non-Nernstian and is a complex function of melt composition and the Cl concentration of the system. Values of DClapat/melt (wt. fraction of: Cl in apatite/Cl in melt) vary from 1 to 4.5 and are largest when the Cl concentrations of the melt are at or near the Cl-saturation value of the melt. The Cl-saturation concentrations of silicate melts are lowest in evolved, silica-rich melts, so with elevated Cl concentrations in a system and with all else equal, the maximum values of DClapat/melt occur with the most felsic melt. In contrast, values of DFapat/melt range from 11 to 40 for these felsic melts, and many of these are an order of magnitude greater than those applying to basaltic melts at 200 MPa and 1066-1150 °C. The Cl concentration of apatite is a simple and linear function of the concentration of Cl in fluid. Values of DClfluid/apat for these experiments range from 9 to 43, and some values are an order of magnitude greater than those determined in 200-MPa experiments involving basaltic melts at 1066-1150 °C.In order to determine the concentrations and interpret the behavior of volatile components in magmas, the experimental data have been applied to the halogen concentrations of apatite grains from chemically evolved rocks of Augustine volcano, Alaska; Krakatau volcano, Indonesia; Mt. Pinatubo, Philippines; Mt. St. Helens, Washington; Mt. Mazama, Oregon; Lascar volcano, Chile; Santorini volcano, Greece, and the Bishop Tuff, California. The F concentrations of these magmas estimated from apatite-melt equilibria range from 0.06 to 0.12 wt% and are generally equivalent to the concentrations of F determined in the melt inclusions. In contrast, the Cl concentrations of the magmas estimated from apatite-melt equilibria (e.g., ca. 0.3-0.9 wt%) greatly exceed those determined in the melt inclusions from all of these volcanic systems except for the Bishop Tuff where the agreement is good. This discrepancy in estimated Cl concentrations of melt could result from several processes, including the hypothesis that the composition of apatite represents a comparatively Cl-enriched stage of magma evolution that precedes melt inclusion entrapment prior to the sequestration of Cl by coexisting magmatic aqueous and/or saline fluid(s).  相似文献   

2.
Microscopic melt inclusions found in magmatic minerals are undoubtedly one of the most important sources of information on the chemical composition of melts. This paper reports on the successful application of near-infrared (NIR) femtosecond laser ablation (LA) - inductively coupled plasma-mass spectrometry to in situ determination of incompatible trace elements (Li, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Ta, Th, U) and ore metals (As, Mo, Pb) in individual melt inclusions hosted in quartz from the Mount Pinatubo dacites, Philippines. The determined elements cover a concentration range of five orders of magnitude. Femtosecond LA-ICP-MS analyses of twenty-eight individual melt inclusions demonstrate the efficiency of the microanalytical technique and suggests a spectacular homogeneity of the entrapped melt, at least with respect to the following incompatible trace elements: Rb, Sr, Nb, Cs, Ba, La, Ce, Pr, Nd, Pb, Th. The analytical precision (1s) for Na, Ca, Rb, Sr, Y, Nb, Ba and LREE ranged from 3 to 20%. Comparison of trace element concentrations in Mt. Pinatubo melt inclusions determined by femtosecond LA-ICP-MS with those of melt inclusions previously analysed by secondary ion mass spectrometry analysis (SIMS) and those of matrix glasses previously determined by nanosecond LA-ICP-MS showed an agreement typically within 30–40%. The homogeneity of trace element concentrations of the Mt. Pinatubo melt inclusions and the matrix glasses is consistent with the melt inclusion origin as homogeneous rhyolitic melt that was trapped in quartz phenocrysts at the final crystallisation stages of the host adakite (dacite) magma.  相似文献   

3.
The origin of adakite magmas remains controversial because initially the term adakite had petrogenetic significance implying an origin by direct melting of the eclogitized subducting oceanic crust. Many models have been produced for their origin, and until now there has not been a straightforward method to discriminate between these models in a given adakite suite. Here, we use detailed chronological and geochemical studies of selected adakitic edifices that allows for the determination of the magmatic output rate parameter (Qe), which has been correlated with the rates of magma generation deep within subduction zones. By providing temporal and eruption rate estimates, we provide constraints on the possible petrogenetic processes involved in the generation of adakite-like signatures. Adakite magmas derived from the melting of the subducting slab should be volumetrically insignificant when compared to the adakite-like magmas produced by typical arc magma generation processes. In this study, we use this observation and the extraordinary stratigraphic exposure from Miocene to present in an adakitic volcano in Panama and to study the temporal and chemical variation in erupted magmas to estimate rates of magma generation. Detailed chemical and geochronological analyses of Baru volcano indicate that the volcanic edifice was constructed in its entirety during the Quaternary and magmas display adakite-like features such as steep rare earth elements patterns, pronounced depletions in the heavy rare earth elements, low Y, high Sr, and high Sr/Y. The magmatic output rates (Qe) that we have calculated show that compared to other typical adakitic volcanoes, most of the volcanic edifice of Baru volcano was constructed extremely rapidly (<~213 k.a.) and in time frames that are similar to typical arc volcanoes. The observed chemical and mineralogical variation, coupled with the high magma production rates, indicate that Baru volcano is more representative of a typical arc volcano than a small-volume melt of the subducting oceanic crust. The technique we outline may have broader application in determining the petrogenetic conditions of other adakite suites.  相似文献   

4.
中国斑岩铜矿与埃达克(质)岩关系探讨   总被引：16，自引：2，他引：14  
对比研究了中国26个主要斑岩铜矿的地球化学特征和年代学,结果表明其中25个矿床与埃达克(质)岩有成因联系,且多数与玄武质下地壳熔融形成的埃达克岩(C型)有关,现有数据表明土屋-延东和普朗斑岩铜矿可能与俯冲板片熔融形成的埃达克岩(O型)有关。容矿斑岩的初始锶值为0.7034～0.7090,均大于洋中脊玄武岩和亏损地幔的初始锶值,多数与EMI的初始锶值接近,推测其源区或源岩主要为玄武质下地壳,少数为洋中脊玄武岩,并受到中、上地壳不同程度的混染,这与两类埃达克岩的源区基本一致。虽然埃达克质岩浆具有形成斑岩铜矿的巨大潜力,但并非所有埃达克岩都能成矿,不同岩体需具体分析。  相似文献   

5.
Experimental Constraints on the Origin of the 1991 Pinatubo Dacite   总被引：12，自引：2，他引：12  
Crystallization (dacite) and interaction (dacite–peridotite)experiments have been performed on the 1991 Pinatubo dacite(Luzon Island, Philippines) to constrain its petrogenesis. Inthe dacite–H2O system at 960 MPa, magnetite and eitherclinopyroxene (low H2O) or amphibole (high H2O) are the liquidusphases. No garnet is observed at this pressure. Dacite–peridotite interaction at 920 MPa produces massive orthopyroxenecrystallization, in addition to amphibole ± phlogopite.Amphibole crystallizing in dacite at 960 MPa has the same compositionas the aluminium-rich hornblende preserved in the cores of amphibolephenocrysts in the 1991 dacite, suggesting a high-pressure stageof dacite crystallization with high melt H2O contents (>10wt %) at relatively low temperature (<950°C). The compositionsof plagioclase, amphibole and melt inclusion suggest that thePinatubo dacite was water-rich, oxidized and not much hotterthan 900°C, when emplaced into the shallow magma reservoirin which most phenocrysts precipitated before the onset of the1991 eruption. The LREE-enriched REE pattern of the whole-rockdacite demands garnet somewhere during its petrogenesis, whichin turn suggests high-pressure derivation. Partial melting ofsubducted oceanic crust yields melts unlike the Pinatubo dacite.Interaction of these slab melts with sub-arc peridotite is unableto produce a Pinatubo type of dacite, nor is a direct mantleorigin conceivable on the basis of our peridotite–daciteinteraction experimental results. Dehydration melting of underplatedbasalts requires unrealistically high temperatures and doesnot yield dacite with the low FeO/MgO, and high H2O, Ni andCr contents typical of the Pinatubo dacite. The most plausibleorigin of the Pinatubo dacite is via high-pressure fractionationof a hydrous, oxidized, primitive basalt that crystallized amphiboleand garnet upon cooling. Dacite melts produced in this way weredirectly expelled from the uppermost mantle or lower crust toshallow-level reservoirs from which they erupted occasionally.Magmas such as the Pinatubo dacite may provide evidence forthe existence of particularly H2O-rich conditions in the sub-arcmantle wedge rather than the melting of the young, hot subductingoceanic plate. KEY WORDS: Pinatubo dacite; slab melt; experimental petrology; arc magmas  相似文献   

6.
The Toquima caldera complex (TCC) lies near the middle of a west-northwest-trending belt of Oligocene to early Miocene volcanic rocks that stretches from southwestern Utah to west-central Nevada. Three overlapping to eccentrically nested calderas, called Moores Creek, Mt. Jefferson, and Trail Canyon, comprise the TCC. The calderas formed due to eruption of the tuffs of Moores Creek, Mt. Jefferson, and Trail Canyon at 27.2 Ma, 26.4 Ma, and 23.6 Ma, respectively. In total, 900+ km3 of magma was erupted from the complex. The high-silica rhyolite tuff of Moores Creek is the least strongly zoned in silica (78.0–76.8 wt% SiO2), and the tuff of Mt. Jefferson is the most strongly zoned (77.5–65.3 wt% SiO2); the tuff of Trail Canyon is moderately zoned (75.9–70.4 wt% SiO2). All eruptive products contain plagioclase, sanidine, quartz, biotite, Fe–Ti oxides, and accessory zircon, allanite, and apatite. Amphibole and clinopyroxene join the assemblage where compositions of bulk tuff are 74 wt% SiO2 and 70 wt% SiO2 respectively. Proportions and compositions of phenocrysts vary systematically with composition of the host tuff. Compositional zoning trends of sanidine and biotite suggest the presence of a high Ba-bearing magmatic component at depth or its introduction into the Mt. Jefferson and Trail Canyon magma chambers at a late stage of magmatic evolution. Rocks of the complex constitute a high-K, calc-alkaline series.Empirical data from other systems and results of published phase-equilibria and thermo-chemical studies suggest that magma erupted from the TCC was oxidized ( 1.5 to 2.0 log units above NNO), thermally zoned ( 700–730° C for high-silica rhyolite to 800–840° C for dacite) and water-rich (5.0–5.5. wt% H2O for highsilica rhyolite to 4.0 wt% H2O for dacite). Geologic relations and amphibole compositional data are consistent with total pressures of 1.5 to 2 kbars.Onset of mid-Tertiary magmatism in vicinity of the TCC began with intrusion of a small granodioritic stock and a northeast-trending dike swarm at 37–34 Ma. The dikes are broadly bimodal assemblage of silicic andesite and rhyolite. Voluminous ash-flow-tuff magmatism commenced at 32.3 Ma and persisted for 9 m.y. without eruption of intermediate to mafic magmas (<62 wt% SiO2). As such, the TCC is probably a remnant of a more extensive complex of calderas whose identities are obscured by recurrent volcanism and by late Tertiary basin-range block faulting. The change from small-volume, broadly bimodal volcanism to voluminous outpourings of silicic magma is similar to that which occurred in east-central Nevada, where magmatism and rapid crustal extension overlapped in space and time. Although supracrustal extension at the time of formation of the TCC apears limited, the comparable magmatic histories and compositional characteristics of rocks erupted from east-central Nevada and the TCC suggest that fundamentally similar magmatic processes acted at depth and that extension may have been more pronounced in the lower and middle crust below the TCC and vicinity. Because strain is partitioned heterogeneously in the upper crust, the magmatic record, rather than surface structural features, may reflect better the actual state of crustal stress during volcanism.Mid-Tertiary magmatism in the TCC and vicinity probably began with intrusion of mantle-derived basalt into the lower crust, which led to crustal heating, local partial melting of crustal rocks, and intrusion of rhyolitic melts and contaminated basaltic differentiates (alkalirich andesite) into the upper crust. With time, intrusion to extrusion ratios increased as silicic melts retarded the rise of mafic magmas and mixing between mafic magmas and crustal partial melts occurred. The oxidized, water-rich, and low-temperature nature of these magmas reflects protracted crustal residence and interaction prior to eruption. The resulting hybridized and differentiated magmas ultimately erupted to form extensive deposits of silicic ash-flow tuff. By contrast, silicic lavas are scarce possibly because of coherent roof rocks that limited volatile degassing between major pyroclastic eruptions.  相似文献   

7.
Mt. Shasta andesite and dacite lavas contain high MgO (3.5–5 wt.%), very low FeO*/MgO (1–1.5) and 60–66 wt.% SiO2. The range of major and trace element compositions of the Shasta lavas can be explained through fractional crystallization (~50–60 wt.%) with subsequent magma mixing of a parent magma that had the major element composition of an H2O-rich primitive magnesian andesite (PMA). Isotopic and trace element characteristics of the Mt. Shasta stratocone lavas are highly variable and span the same range of compositions that is found in the parental basaltic andesite and PMA lavas. This variability is inherited from compositional variations in the input contributed from melting of mantle wedge peridotite that was fluxed by a slab-derived, fluid-rich component. Evidence preserved in phenocryst assemblages indicates mixing of magmas that experienced variable amounts of fractional crystallization over a range of crustal depths from ~25 to ~4 km beneath Mt. Shasta. Major and trace element evidence is also consistent with magma mixing. Pre-eruptive crystallization extended from shallow crustal levels under degassed conditions (~4 wt.% H2O) to lower crustal depths with magmatic H2O contents of ~10–15 wt.%. Oxygen fugacity varied over 2 log units from one above to one below the Nickel-Nickel Oxide buffer. The input of buoyant H2O-rich magmas containing 10–15 wt.% H2O may have triggered magma mixing and facilitated eruption. Alternatively, vesiculation of oversaturated H2O-rich melts could also play an important role in mixing and eruption.  相似文献   

8.
The petrogenesis and geodynamic implications of the Cenozoic adakites in southern Tibet remain topics of debate. Here we report geochronological and geochemical data for host granites and mafic enclaves from Wolong in the eastern Gangdese Batholith, southern Tibet. Zircon LA-ICP-MS dating indicates that the Wolong host granites and enclaves were synchronously emplaced at ca. 38 Ma. The host granites are medium- to high-K calc-alkaline, metaluminous (A/CNK = 0.93-0.96), with high Al2O3 (15.47-17.68%), low MgO (0.67-1.18%), very low abundances of compatible elements (e.g., Cr = 3.87-8.36 ppm, Ni = 3.04-5.71 ppm), and high Sr/Y ratios (127-217), similar to those typical of adakite. The mafic enclaves (SiO2 = 51.08-56.29%) have 3.83-5.02% MgO and an Mg# of 48-50, with negative Eu anomalies (δEu = 0.59-0.79). The Wolong host granites and enclaves have similar Sr-Nd isotopic compositions (initial 87Sr/86Sr = 0.7053-0.7055, εNd(t) = − 2.7 to − 1.4), with varying zircon εHf(t) values, ranging from + 6.0 to + 12.6. A comprehensive study of the data available for adakitic rocks from the Gangdese Batholith indicates that the Wolong adakitic host granites were derived from partial melting of a thickened lower crust, while the parental magmas of the mafic enclaves were most likely derived from lithospheric mantle beneath southern Tibet. The Wolong granitoids are interpreted as the result of mixing between the thickened lower crust-derived melts and lithospheric mantle-derived mafic melts, which are likely the protracted magmatic response to the break-off of the Neo-Tethyan oceanic slab at about 50 Ma. Our results suggest that the crustal thickening in southern Tibet occurred prior to ~ 38 Ma, and support the general view that the India-Asia collision must have occurred before 40 Ma.  相似文献   

9.
Mid-Miocene volcanic rocks are rare in the Aegean region, although early Miocene and late Miocene-Quaternary volcanism is widespread. At Oxylithos (island of Evia), 14 Ma dacites form a dome or sub-volcanic complex. Phreatomagmatic eruptions formed nearby rhyolitic pyroclastic surge deposits. The calc-alkaline dacites contain bronzite, Mg-rich clinopyroxene, phlogopite and plagioclase phenocrysts. The magma results from mixing of a Mg-rich andesitic magma, similar to that in the nearby island of Skyros, with more felsic magmas represented by the rhyolitic pyroclastics. The dacites are geochemically similar to adakites, which are derived by partial melting of eclogitic subducted oceanic crust and have low Y and Yb and high Sr/Y ratio. 87Sr/86Sr≈0.7095 is found in both dacite and rhyolite. Lead isotopic composition from the high-Mg andesite from Skyros, with 207Pb/204Pb= 15.70 and 208Pb/204Pb= 38.90, forms a linear trend with Evia dacite and rhyolite with 207Pb/204Pb= 15.71 and 208Pb/204Pb= 39.05. The high temperatures required to produce such magma resulted from decompression due to extension of the Aegean basin at the same time as the initial intrusion of the detached subducted slab in the western Aegean that has been imaged by seismic tomography. The Oxylithos rocks extend the known occurrences of adakite series rocks: this series is not restricted to sites with subduction of young oceanic crust.  相似文献   

10.
在柴达木北缘吉绿素滩间山群火山岩中发现埃达克质 (adakitic)英安岩 ,其主要地球化学特征如下 :SiO26 3.7%～ 6 4.3%,Al2 O3 15 .0 7%～ 15 .2 7%,MgO 3.47%～ 3.72 %,K2 O/Na2 O 0 .14～ 0 .2 5 ,Y和Yb含量较低 ,Y为17.82× 10 -6～ 18.10× 10 -6,平均 17.96× 10 -6,Yb为 1.47× 10 -6～ 1.5 5× 10 -6,Sr含量较高 ,为 5 2 7× 10 -6～ 5 37× 10 -6,亏损HREE ,具弱负Eu和Sr异常。除MgO高于正常的埃达克岩外 ,与世界上典型埃达克岩极为相似。据其地球化学研究结果并结合该区埃达克质英安岩 (5 14.2± 8.5Ma)和榴辉岩 (494.6± 6 .5Ma)的年龄数据 ,推测柴北缘板片在晚寒武世开始俯冲 ,俯冲板片在 75～ 85km深处开始部分熔融形成埃达克质岩浆 ,而熔融残留部分继续俯冲 ,在早奥陶世形成含石榴石残留相的榴辉岩。柴北缘埃达克质英安岩的发现进一步证实了早古生代柴北缘发生过洋陆俯冲作用。  相似文献   

11.
The geochemical partitioning of bromine between hydrous haplogranitic melts, initially enriched with respect to Br and aqueous fluids, has been continuously monitored in situ during decompression. Experiments were carried out in diamond anvil cells from 890 °C to room temperature and from 1.7 GPa to room pressure, typically from high P, T conditions corresponding to total miscibility (presence of a supercritical fluid). Br contents were measured in aqueous fluids, hydrous melts and supercritical fluids. Partition coefficients of bromine were characterized at pressure and temperature between fluids, hydrous melts and/or glasses, as appropriate: DBrfluid/melt = (Br)fluid/(Br)melt, ranges from 2.18 to 9.2 ± 0.5 for conditions within the ranges 0.66-1.7 GPa, 590-890 °C; and DBrfluid/glass = (Br)fluid/(Br)glass ranges from 60 to 375 at room conditions. The results suggest that because high pressure melts and fluids are capable of accepting high concentrations of bromine, this element may be efficiently removed from the slab to the mantle source of arc magmas. We show that Br may be highly concentrated in subduction zone magmas and strongly enriched in subduction-related volcanic gases, because its mobility is strongly correlated with that of water during magma degassing. Furthermore, our experimental results suggest that a non negligible part of Br present in the subducted slab may remain in the down-going slab, being transported toward the transition zone. This indicates that the Br cycle in subduction zones is in fact divided in two related but independent parts: (1) a shallower one where recycled Br may leave the slab with a water and silica-bearing “fluid” leading to enriched arc magmas that return Br to the atmosphere. (2) A deeper cycle where Br may be recycled back to the mantle maybe to the transition zone, where it may be present in high pressure water-rich metasomatic fluids.  相似文献   

12.
Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na2O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na2O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na2O, SiO2 and perhaps K2O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.  相似文献   

13.
Data set of rocks and glasses whose compositions correspond to the term “adakite” (SiO2 > 56 wt %, Sr > 400 ppm, Sr/Y > 18) was compiled from two large geochemical data bases. It was revealed that the adakitic melts are characterized by extremely low abundance as compared to adakitic rocks. Only 50 adakitic compositions (~0.5%) were identified in the data base that includes the major and trace element compositions of over 9700 quenched and melt inclusion glasses. It was established that only 22 of selected analyses characterize melt inclusion glasses, while other analyses represent residual glass or “pocket melts” in ultramafic mantle xenoliths. The question of a genetic relationship between adakitic rocks, adakitic melts, and melting of subsiding plate remains open. Original data on the Shiveluch volcanic center (Kamchatka) were used to demonstrate the formation of adakitic signatures through mineral accumulation.  相似文献   

14.
Composite dikes at Hell Hole Meadow, in the central Sierra Nevada, contain hybrids created by small scale mixing of andesitic and rhyolitic magmas. Early rhyolitic injections had partially solidified when subsequent andesitic magmas arrived and mixed with small increments of remnant rhyolitic magma. In major element chemistry, the hybrid rocks define linear MgO-variation diagrams that closely resemble those for the Half Dome, Mt. Givens, and Eagle Peak granodiorites. The patterns suggest that mixing of mafic and felsic magmas has been important in the evolution of these plutons.Hornblendes in three Hell Hole Meadow hybrid rocks ranging from dacite to andesite display indistinguishable crystal-chemical variation patterns. The crystals apparently developed as phenocrysts of endmember andesitic magma prior to the mixing event and retained their compositional character in the hybridization event. Plutonic hornblendes (Dodge et al. 1968; Noyes et al. 1983) display crystal-chemical patterns nearly identical to those in the dike cores making it unlikely that the plutonic hornblendes represent restite of a complex lower crust.Hornblende chemical data from a suite of rocks collected across the width of the compositionally zoned Half Dome granodiorite (Yosemite National Park) define clusters, like their Hell Hole Meadow counterparts, that are very similar to one another despite the large range in host rock bulk composition. Sr isotopic data (Kistler et al. 1986) and linear MgO-variation patterns for the major elements (Reid et al. 1983) suggest that the Half Dome is a mixture of high-alumina basalt and rhyolitic magmas. We propose that while the bulk chemistry of hybrid granodiorites is determined by the proportions of the constituent mafic and felsic magmas, the hornblendes in the mixed rocks largely retain compositions created in the mafic component prior to mixing. Mixing may occur either by incremental addition of felsic magma into a relatively large volume of mafic magma (as at Hell Hole Meadow), or by the chilling and subsequent disaggregation of mafic pillows in a largely felsic host.  相似文献   

15.
Oxidized sulfur-rich mafic magma at Mount Pinatubo,Philippines   总被引：3，自引：2，他引：1  
Basaltic fragments enclosed in andesitic dome lavas and pyroclastic flows erupted during the early stages of the 1991 eruption of Mount Pinatubo, Philippines, contain amphiboles that crystallized during the injection of mafic magma into a dacitic magma body. The amphiboles contain abundant melt inclusions, which recorded the mixing of andesitic melt in the mafic magma and rhyolitic melt in the dacitic magma. The least evolved melt inclusions have high sulfur contents (up to 1,700 ppm) mostly as SO4 2–, which suggests an oxidized state of the magma (NNO+1.4). The intrinsically oxidized nature of the mafic magma is confirmed by spinel–olivine oxygen barometry. The value is comparable to that of the dacitic magma (NNO+1.6). Hence, models invoking mixing as a means of releasing sulfur from the melt are not applicable to Pinatubo. Instead, the oxidized state of the dacitic magma likely reflects that of parental mafic magma and the source region in the sub-arc mantle. Our results fit a model in which long-lived SO2 discharge from underplated mafic magma accumulated in the overlying dacitic magma and immiscible aqueous fluids. The fluids were the most likely source of sulfur that was released into the atmosphere during the cataclysmic eruption. The concurrence of highly oxidized basaltic magma and disproportionate sulfur output during the 1991 Mt. Pinatubo eruption suggests that oxidized mafic melt is an efficient medium for transferring sulfur from the mantle to shallow crustal levels and the atmosphere. As it can carry large amounts of sulfur, effectively scavenge sulfides from the source mantle and discharge SO2 during ascent, oxidized mafic magma forms arc volcanoes with high sulfur fluxes, and potentially contributes to the formation of metallic sulfide deposits.Editorial responsibility: J. Hoefs
J. C. M. de HoogEmail:
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16.
The paper reports the first results of the petrological studies of magmatic melts that formed siliceous pyroclastic deposits related to voluminous eruptions on Iturup Island. The caldera-forming eruptions of the Lvinaya Past and the Vetrovoy Isthmus, having similar features, resulted from the evolution of silicic melts that originated from partial melting of metabasalts. According to the mineral thermometry results, the melt was crystallized at ~800°C. The phenocrysts from the Vetrovoy Isthmus pumices were crystallized at <1 kbar, while those from the Lvinaya Past were formed at higher pressures. The pyroclastic rock compositions in both calderas correspond to moderately aluminous dacite and rhyolitic dacite of the normal series, whose melts likely did not undergo significant crystallization differentiation before the eruptions. The main volatile components of the magma include H2O, CO2, S, F, and Cl. Degassing with emission of water–carbon-dioxide fluid accompanied the early crystallization of plagioclase in the Vetrovoy Isthmus pumice. Evidence of pre-eruption melt degassing in the Lvinaya Past were not found. Water release from the melts may be related to both the early magma degassing and the eruptions. The lack of data evidencing the deep differentiation and mixing of contrasting melts implies a relatively small time period between the acid melt appearance and eruptions.  相似文献   

17.
Viscosity of silicate melts is a critical property for understanding volcanic and igneous processes in the Earth. We investigate the pressure effect on the viscosity of rhyolitic melts using two methods: indirect viscosity inference from hydrous species reaction in melts using a piston cylinder at pressures up to 2.8 GPa and direct viscosity measurement by parallel-plate creep viscometer in an internally-heated pressure vessel at pressures up to 0.4 GPa. Comparison of viscosities of a rhyolitic melt with 0.8 wt% water at 0.4 GPa shows that both methods give consistent results. In the indirect method, viscosities of hydrous rhyolitic melts were inferred based on the kinetics of hydrous species reaction in the melt upon cooling (i.e., the equivalence of rheologically defined glass transition temperature and chemically defined apparent equilibrium temperature). The cooling experiments were carried out in a piston-cylinder apparatus using hydrous rhyolitic samples with 0.8-4 wt% water. Cooling rates of the kinetic experiments varied from 0.1 K/s to 100 K/s; hence the range of viscosity inferred from this method covers 3 orders of magnitude. The data from this method show that viscosity increases with increasing pressure from 1 GPa to 3 GPa for hydrous rhyolitic melts with water content ?0.8 wt% in the high viscosity range. We also measured viscosity of rhyolitic melt with 0.13 wt% water using the parallel-plate viscometer at pressures 0.2 and 0.4 GPa in an internally-heated pressure vessel. The data show that viscosity of rhyolitic melt with 0.13 wt% water decreases with increasing pressure. Combining our new data with literature data, we develop a viscosity model of rhyolitic melts as a function of temperature, pressure and water content.  相似文献   

18.
Hadi Omrani 《Petrology》2018,26(1):96-113
Cretaceous to Eocene plutonic and volcanic rocks of the Sabzevar zone have an adakite characteristic with high Sr/Y ratio, depleted HFSE and enriched LILE features. Most of the Sabzevar adakites are high silica adakites with low Ni, Cr and Co contents. LREE/HREE ratio is high, while K2O content is low to intermediate. Adakites in the Sabzevar zone are exposed in two areas, which are named southern and northern adakites here. The combination of Sr, Nd and Pb isotopic data with major and trace elements indicates that the adakitic rocks are formed by partial melting of the Sabzevar oceanic slab. Nb/Ta content of the samples indicates that the adakitic magmas were generated at different depth in the subduction system. Dy/Yb ratios of adakitic samples indicate positive, negative and roughly flat patterns for different samples, suggesting garnet and amphibole as residual phases during slab-derived adakitic magma formation. Sabzevar adakites emplaced during late to post-kinematic events. Sabzevar oceanic basin demised during a northward subduction by central Iranian micro-continents (CIM) and Eurasia plate convergence.  相似文献   

19.
Volcán Ceboruco, Mexico, erupted ~1,000 years ago, producing the Jala pumice and forming a ~4-km-wide caldera. During that eruption, 2.8 to 3.5 km3 of rhyodacite (~70 wt% SiO2) magma and 0.2 to 0.5 km3 of mixed dacite (~67 wt% SiO2) magma were tapped and deposited as the Jala pumice. Subsequently, the caldera was partially filled by extrusion of the Dos Equis dome, a low-silica (~64 wt% SiO2) dacite dome with a volume of ~1.3 km3. Petrographic evidence indicates that the Jala dacite and Dos Equis dacite originated largely through the mixing of three end-member magmas: (1) rhyodacite magma, (2) dacite magma, and (3) mafic magma. Linear least-squares modeling and detailed modal analysis indicate that the Jala dacite is predominantly a bimodal mixture of rhyodacite and dacite with a small additional mafic component, whereas the Dos Equis dacite is composed of mostly dacite mixed with subordinate amounts of rhyodacite and mafic magma. According to Fe–Ti oxide geothermometry, before the caldera-forming eruption the rhyodacite last equilibrated at ~865 °C, whereas the dacite was originally at ~890 °C but was heated to ~960 °C by intrusion of mafic magma as hot as ~1,030 °C. Zoning profiles in plagioclase and/or magnetite phenocrysts indicate that mixing between mafic and dacite magma occurred ~34–47 days prior to eruption, whereas subsequent mixing between rhyodacite and dacite magmas occurred only 1–4 days prior to eruption. Following the caldera-forming eruption, continued inputs of mafic magma led to effusion of the Dos Equis dome dacite. In this case, timing between mixing and eruption is estimated at ~93–185 days based on the thickness of plagioclase overgrowth rims.Editorial responsibility: T.L. Grove  相似文献   

20.
Petrogenesis of high Mg# adakitic rocks in intracontinental settings is still a matter of debate. This paper reports major and trace element, whole-rock Sr–Nd isotope, zircon U–Pb and Hf isotope data for a suite of adakitic monzogranite and its mafic microgranular enclaves (MMEs) at Yangba in the northwestern margin of the South China Block. These geochemical data suggest that magma mixing between felsic adakitic magma derived from thickened lower continental crust and mafic magma derived from subcontinental lithospheric mantle (SCLM) may account for the origin of high Mg# adakitic rocks in the intracontinental setting. The host monzogranite and MMEs from the Yangba pluton have zircon U–Pb ages of 207 ± 2 and 208 ± 2 Ma, respectively. The MMEs show igneous textures and contain abundant acicular apatite that suggests quenching process. Their trace element and evolved Sr–Nd isotopic compositions [(87Sr/86Sr)i = 0.707069–0.707138, and εNd(t) = −6.5] indicate an origin from SCLM. Some zircon grains from the MMEs have positive εHf(t) values of 2.3–8.2 with single-stage Hf model ages of 531–764 Ma. Thus, the MMEs would be derived from partial melts of the Neoproterozoic SCLM that formed during rift magmatism in response to breakup of supercontinent Rodinia, and experience subsequent fractional crystallization and magma mixing process. The host monzogranite exhibits typical geochemical characteristics of adakite, i.e., high La/Yb and Sr/Y ratios, low contents of Y (9.5–14.5 ppm) and Yb, no significant Eu anomalies (Eu/Eu* = 0.81–0.90), suggesting that garnet was stable in their source during partial melting. Its evolved Sr–Nd isotopic compositions [(87Sr/86Sr)i = 0.7041–0.7061, and εNd(t) = −3.1 to −4.3] and high contents of K2O (3.22–3.84%) and Th (13.7–19.0 ppm) clearly indicate an origin from the continental crust. In addition, its high Mg# (51–55), Cr and Ni contents may result from mixing with the SCLM-derived mafic magma. Most of the zircon grains from the adakitic monzogranite show negative εHf(t) values of −9.4 to −0.1 with two-stage Hf model ages of 1,043–1,517 Ma; some zircon grains display positive εHf(t) of 0.1–3.9 with single-stage Hf ages of 704–856 Ma. These indicate that the source region of adakitic monzogranite contains the Neoproterozoic juvenile crust that has the positive εHf(t) values in the Triassic. Thus, the high-Mg adakitic granites in the intracontinental setting would form by mixing between the crustal-derived adakitic magma and the SCLM-derived mafic magma. The mafic and adakitic magmas were generated coevally at Late Triassic, temporally consistent with the exhumation of deeply subducted continental crust in the northern margin of the South China Block. This bimodal magmatism postdates slab breakoff at mantle depths and therefore is suggested as a geodynamic response to lithospheric extension subsequent to the continental collision between the South China and North China Blocks.  相似文献   

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