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1.
Elemental and Sr–Nd isotopic data on metatexites, diatexites, orthogneisses and charnockites from the central Ribeira Fold Belt indicate that they are LILE-enriched weakly peraluminous granodiorites. Harker and Th–Hf–La correlation trends suggest that these rocks represent a co-genetic sequence, whereas variations on CaO, MnO, Y and HREE for charnockites can be explained by garnet consumption during granulitic metamorphism.Similar REE patterns and isotopic results of ?Nd565 = ?5.4 to ?7.3 and 87Sr/86Sr565 = 0.706–0.711 for metatexites, diatexites, orthogneisses and charnockites, as well as similar TDM ages between 2.0 and 1.5 Ga are consistent with evolution from a relatively homogeneous and enriched common crustal (metasedimentary) protolith.Results suggest a genetic link between metatexites, diatexites, orthogneisses and charnockites and a two-step process for charnockite development: (a) generation of the hydrated igneous protoliths by anatexis of metasedimentary rocks; (b) continuous high-grade metamorphism that transformed the “S-type granitoids” (leucosomes and diatexites) into orthogneisses and, as metamorphism and dehydration progressed, into charnockites.  相似文献   

2.
K-feldspar–plagioclase–quartz mineral textures aswell as biotite and hornblende compositions are compared forsuites of metamorphosed mafic rocks from two widely separatedtraverses. A portion of either traverse has experienced a high-gradedehydration event transforming it from an H2O-rich, hornblende-bearingzone to an H2O-poor, hornblende-free, orthopyroxene-bearing,‘granulite facies’ zone at 700–800°C and7–8 kbar. In the Kigluaik Mountains, Seward Peninsula,Alaska, dehydration took place over an 85 cm thick layer ofmetatonalite in contact with a marble during regional metamorphismand involved a CO2-rich fluid, whereas for the Val Strona diOmegna traverse, Ivrea–Verbano Zone, northern Italy, dehydrationtook place over a 3–4 km thick sequence of metabasitesinterlayered with metapelites in a contact metamorphic eventinvolving basaltic magmas intruded at the base of the sequence.Orthopyroxene-bearing samples from both dehydration zones showmicro-veins of K-feldspar along quartz and plagioclase grainboundaries as well as replacement antiperthite in plagioclase.K came primarily from the breakdown of hornblende + quartz toorthopyroxene ± clinopyroxene, feldspar and fluid. Biotiteeither was stabilized or formed in the dehydration zones andis enriched in Ti, Mg, F and Cl relative to biotite in the amphibolitefacies zone. KEY WORDS: KCl–NaCl brines; metasomatism; granulite facies metamorphism; charnockite–enderbite; orthopyroxene; K-feldspar; biotite; hornblende  相似文献   

3.
We describe a suite of metamorphic and migmatitic rocks fromthe Sierra de Comechingones (Sierras Pampeanas of Central Argentina)that include unmelted gneisses, migmatites and refractory granulites.The gneisses are aluminous greywackes metamorphosed in the amphibolitegrade and are likely to have been the protoliths for the higher-grademigmatites and granulites. Mineralogical characteristics andmajor and trace element compositions show that metatexite migmatites,diatexite migmatites and granulites are all melt-depleted rocks.The migmatites (both metatexites and diatexites) have undergoneH2O-fluxed melting and lost  相似文献   

4.
Quartz–calcite sandstones experienced the reaction calcite+ quartz = wollastonite + CO2 during prograde contact metamorphismat P = 1500 bars and T = 560°C. Rocks were in equilibriumduring reaction with a CO2–H2O fluid with XCO2 = 0·14.The transition from calcite-bearing, wollastonite-free to wollastonite-bearing,calcite-free rocks across the wollastonite isograd is only severalmillimeters wide. The wollastonite-forming reaction was drivenby infiltration of quartz–calcite sandstone by chemicallyreactive H2O-rich fluids, and the distribution of wollastonitedirectly images the flow paths of reactive fluids during metamorphism.The mapped distribution of wollastonite and modeling of an O-isotopeprofile across a lithologic contact indicate that the principaldirection of flow was layer-parallel, directed upward, withany cross-layer component of flow <0·1% of the layer-parallelcomponent. Fluid flow was channeled at a scale of 1–100m by pre-metamorphic dikes, thrust and strike-slip faults, foldhinges, bedding, and stratigraphic contacts. Limits on the amountof fluid, based on minimum and maximum estimates for the displacementof the wollastonite reaction front from the fluid source, are(0·7–1·9) x 105 cm3 fluid/cm2 rock. Thesharpness of the wollastonite isograd, the consistency of mineralthermobarometry, the uniform measured 18O–16O fractionationsbetween quartz and calcite, and model calculations all arguefor a close approach to local mineral–fluid equilibriumduring the wollastonite-forming reaction. KEY WORDS: contact metamorphism, fluid flow, wollastonite, oxygen isotopes, reaction front  相似文献   

5.
Petrology and phase equilibria of rocks from two profiles inEastern Nepal from the Lesser Himalayan Sequences, across theMain Central Thrust Zone and into the Greater Himalayan Sequencesreveal a Paired Metamorphic Mountain Belt (PMMB) composed oftwo thrust-bound metamorphic terranes of contrasting metamorphicstyle. At the higher structural level, the Greater HimalayanSequences experienced high-T/moderate-P metamorphism, with ananticlockwise P–T path. Low-P inclusion assemblages ofquartz + hercynitic spinel + sillimanite have been overgrownby peak metamorphic garnet + cordierite + sillimanite assemblagesthat equilibrated at 837 ± 59°C and 6·7 ±1·0 kbar. Matrix minerals are overprinted by numerousmetamorphic reaction textures that document isobaric coolingand re-equilibrated samples preserve evidence of cooling to600 ± 45°C at 5·7 ±1·1 kbar.Below the Main Central Thrust, the Lesser Himalayan Sequencesare a continuous (though inverted) Barrovian sequence of high-P/moderate-Tmetamorphic rocks. Metamorphic zones upwards from the loweststructural levels in the south are: Zone A: albite + chlorite + muscovite ± biotite; Zone B: albite + chlorite + muscovite + biotite + garnet; Zone C: albite + muscovite + biotite + garnet ± chlorite; Zone D: oligoclase + muscovite + biotite + garnet ± kyanite; Zone E: oligoclase + muscovite + biotite + garnet + staurolite+ kyanite; Zone F: bytownite + biotite + garnet + K-feldspar + kyanite± muscovite; Zone G: bytownite + biotite + garnet + K-feldspar + sillimanite+ melt ± kyanite. The Lesser Himalayan Sequences show evidence for a clockwiseP–T path. Peak-P conditions from mineral cores average10·0 ± 1·2 kbar and 557 ± 39°C,and peak-metamorphic conditions from rims average 8·8± 1·1 kbar and 609 ± 42°C in ZonesD–F. Matrix assemblages are overprinted by decompressionreaction textures, and in Zones F and G progress into the sillimanitefield. The two terranes were brought into juxtaposition duringformation of sillimanite–biotite ± gedrite foliationseams (S3) formed at conditions of 674 ± 33°C and5·7 ± 1·1 kbar. The contrasting averagegeothermal gradients and P–T paths of these two metamorphicterranes suggest they make up a PMMB. The upper-plate positionof the Greater Himalayan Sequences produced an anticlockwiseP–T path, with the high average geothermal gradient beingpossibly due to high radiogenic element content in this terrane.In contrast, the lower-plate Lesser Himalayan Sequences weredeeply buried, metamorphosed in a clockwise P–T path anddisplay inverted isograds as a result of progressive ductileoverthrusting of the hot Greater Himalayan Sequences duringprograde metamorphism. KEY WORDS: thermobarometry; P–T paths; Himalaya; metamorphism; inverted isograds; paired metamorphic belts  相似文献   

6.
Scapolite and other halogen-rich minerals (phlogopite, amphibole,apatite, titanite and clinohumite) occur in some high-pressureamphibolite facies calc-silicates and orthopyroxene-bearingrocks at Sare Sang (Sar e Sang or Sar-e-Sang), NE Afghanistan.The calc-silicates are subdivided into two groups: garnet-bearingand garnet-free, phlogopite-bearing. Besides garnet and/or phlogopite,the amphibolite facies mineral assemblages in the calc-silicatesinclude clinopyroxene, calcite, quartz and one or more of theminerals scapolite, plagioclase, K-feldspar, titanite, apatiteand rarely olivine. Orthopyroxene-bearing rocks consist of clinopyroxene,garnet, plagioclase, scapolite, amphibole, quartz, calcite andaccessory dolomite and alumosilicate (kyanite?). Retrogradephases in the rocks are plagioclase, scapolite, calcite, amphibole,sodalite, haüyne, lazurite, biotite, apatite and dolomite.The clinopyroxene is mostly diopside and rarely also hedenbergite.Aegirine and omphacite with a maximum jadeite content of 29mol % were also found. Garnet from the calc-silicates is Grs45–95Py0–2and from the orthopyroxene-bearing rocks is Grs10–15Py36–43.Peak P–T metamorphic conditions, calculated using availableexchange thermobarometers and the TWQ program, are 750°Cand 1·3–1·4 GPa. Depending on the rock type,the scapolite exhibits a wide range of composition (from EqAn= 0·07, XCl =0·99 to EqAn = 0·61, XCl =0·07).Equilibria calculated for scapolite and coexisting phases atpeak metamorphic conditions yield XCO2 = 0·03–0·15.XNaCl (fluid), obtained for scapolite, ranges between 0·04and 0·99. Partitioning of F and Cl between coexistingphases was calculated for apatite–biotite and amphibole–biotite.Fluorapatite is present in calc-silicates, but orthopyroxene-bearingrocks contain chlorapatite. Cl preferentially partitions intoamphibole with respect to biotite. All these rocks have sufferedvarious degrees of retrogression, which resulted in removalof halogens, CO2 and S. Halogen- and S-bearing minerals formedduring retrogression and metasomatism are fluorapatite, sodalite,amphibole, scapolite, clinohumite, haüyne, pyrite, andlazurite, which either form veins or replace earlier formedphases. KEY WORDS: scapolite; fluid composition; high-pressure; amphibolite facies; Western Hindukush; Afghanistan  相似文献   

7.
Metapelitic rock samples from the NE Shackleton Range, Antarctica,include garnet with contrasting zonation patterns and two agespectra. Garnet porphyroblasts in K-rich kyanite–sillimanite–staurolite–garnet–muscovite–biotite schistsfrom Lord Nunatak show prograde growth zonation, and give Sm–Ndgarnet, U–Pb monazite and Rb–Sr muscovite ages of518 ± 5, 514 ± 1 and 499 ± 12 Ma, respectively.Geothermobarometry and P–T pseudo-section calculationsin the model system CaO–Na2O–K2O– TiO2–MnO–FeO–MgO–Al2O3–SiO2–H2Oare consistent with garnet growth during prograde heating from540°C/7 kbar to 650°C/7·5 kbar, and partial resorptionduring a subsequent P–T decrease to <650°C at <6kbar. All data indicate that rocks from Lord Nunatak were affectedby a single orogenic cycle. In contrast, garnet porphyroblastsin K-poor kyanite–sillimanite– staurolite–garnet–cordierite–biotite-schistsfrom Meade Nunatak show two growth stages and diffusion-controlledzonation. Two distinct age groups were obtained. Laser ablationplasma ionization multicollector mass spectrometry in situ analysesof monazite, completely enclosed by a first garnet generation,yield ages of c. 1700 Ma, whereas monazite grains in open garnetfractures and in most matrix domains give c. 500 Ma. Both agegroups are also obtained by U–Pb thermal ionization massspectrometry analyses of matrix monazite and zircon, which fallon a discordia with lower and upper intercepts at 502 ±1 and 1686 ± 2 Ma, respectively. Sm–Nd garnet datingyields an age of 1571 ± 40 Ma and Rb–Sr biotiteanalyses give an age of 504 ± 1 Ma. Integrated geochronologicaland petrological data provide evidence that rocks from MeadeNunatak underwent a polymetamorphic Barrovian-type metamorphism:(1) garnet 1 growth and subsequent diffusive garnet annealingbetween 1700 and 1570 Ma; (2) garnet 2 growth during the RossOrogeny at c. 500 Ma. During the final orogenic event the rocksexperienced peak P–T conditions of about 650°C/7·0kbar and a retrograde stage at c. 575°C/4·0 kbar. KEY WORDS: garnet microtexture; P–T pseudosection; geochronology; polymetamorphism; Shackleton Range; Antarctica  相似文献   

8.
The upper Triassic Karmutsen metabasites from northeast VancouverIsland, B.C., are thermally metamorphosed by the intrusion ofthe Coast Range Batholith. The amygdaloidal metabasites developedin the outer portion of the contact aureole show a progressivemetamorphism from zeolite to prehnite-pumpellyite facies. Thesize of an equilibrium domain is extremely small for these metabasites,and the individual amygdule assemblages are assumed to be inequilibrium. Two major calcite-free assemblages (+chlorite+quartz)are characteristic: (i) laumontite+pumpellyite+epidote in thezeolite facies and (ii) prehnite+pumpellyite+epidote in theprehnite-pumpellyite facies. The assemblages and compositionsof Ca-Al silicates are chemographically and theoretically interpretedon the basis of the predicted P-T grid for the model basalticsystem, CaO-MgO-A12O3-Fe2O3-SiO2-H2O. The results indicate:(1) local equilibrium has been approached in mineral assemblagesand compositions; (2) the XFe3+ values in the coexisting Ca-Alsilicates decrease from epidote, through pumpellyite to prehnite;(3) with increasing metamorphic grade, the Fe3+ contents ofepidotes in reaction assemblages decrease in the zeolite facies,then increase in the prehnite-pumpellyite facies rocks. Suchvariations in the assemblages and mineral compositions are controlledby a sequence of continuous and discontinuous reactions, andallow delineation of T-XFe3+ relations at constant pressure.The transition from the zeolite to prehnite-pumpellyite faciesof the Karmutsen metabasites is defined by a discontinuous reaction:0·18 laumontite+pumpellyite+0·15 quartz = 1·31prehnite+ 0·78 epidote+0·2 chlorite+ 1·72H2O, where the XFe3+ values of prehnite, pumpellyite and epidoteare 0·03, 0·10 and 0·18, respectively.These values together with available thermodynamic data andour preliminary experimental data are used to calculate theP-T condition for the discontinuous reaction as P = 1·1±0·5 kb and T = 190±30°C. The effectsof pressure on the upper stability of the zeolite facies assemblagesare discussed utilizing T-XFe3+ diagrams. The stability of thelaumontite-bearing assemblages for the zeolite facies metamorphismof basaltic rocks may be defined by either continuous or discontinuousreactions depending on the imposed metamorphic field gradient.Hence, the zeolite and prehnite-pumpellyite facies transitionboundary is multivariant.  相似文献   

9.
The northern margin of the Inland Branch of the Pan-AfricanDamara Orogen in Namibia shows dramatic along-strike variationin metamorphic character during convergence between the Congoand Kalahari Cratons (M3 metamorphic cycle). Low-P contact metamorphismwith anticlockwise P–T paths dominates in the westerndomains (Ugab Zone and western Northern Zone), and high-P Barrovianmetamorphism with a clockwise P–T path is documented fromthe easternmost domain (eastern Northern Zone). The sequenceof M3 mineral growth in contact aureoles shows early growthof cordierite porphyroblasts that were pseudomorphed to biotite–chlorite–muscoviteat the same time as an andalusite–biotite–muscovitetransposed foliation was developed in the matrix. The peak-Tmetamorphic assemblages and fabrics were overprinted by crenulationsand retrograde chlorite–muscovite. The KFMASH P–Tpseudosection for metapelites in the Ugab Zone and western NorthernZone contact aureoles indicates tight anticlockwise P–Tloops through peak metamorphic conditions of 540–570°Cand 2·5–3·2 kbar. These semi-quantitativeP–T loops are consistent with average P–T calculationsusing THERMOCALC, which give a pooled mean of 556 ± 26°Cand 3·2 ± 0·6 kbar, indicating a high averagethermal gradient of 50°C/km. In contrast, the eastern NorthernZone experienced deep burial, high-P/moderate-T Barrovian M3metamorphism with an average thermal gradient of 21°C/kmand peak metamorphic conditions of c. 635°C and 8·7kbar. The calculated P–T pseudosection and garnet compositionalisopleths in KFMASH, appropriate for the metapelite sample fromthis region, document a clockwise P–T path. Early plagioclase–kyanite–biotiteparageneses evolved by plagioclase consumption and the growthof garnet to increasing XFe, XMg and XCa and decreasing XMncompositions, indicating steep burial with heating. The developedkyanite–garnet–biotite peak metamorphic parageneseswere followed by the resorption of garnet and formation of plagioclasemoats, indicating decompression, which was followed by retrogressivecooling and chlorite–muscovite growth. The clockwise P–Tloop is consistent with the foreland vergent fold–thrustbelt geometry in this part of the northern margin. Earlier formed(580–570 Ma) pervasive matrix foliations (M2) were overprintedby contact metamorphic parageneses (M3) in the aureoles of 530± 3 Ma granites in the Ugab Zone and 553–514 Magranites in the western Northern Zone. Available geochronologicaldata suggest that convergence between the Congo and KalahariCratons was essentially coeval in all parts of the northernmargin, with similar ages of 535–530 Ma for the main phaseof deformation in the eastern Northern Zone and Northern Platformand 538–505 Ma high-grade metamorphism of the CentralZone immediately to the south. Consequently, NNE–SSW-directedconvergent deformation and associated M3 metamorphism of contrastingstyles are interpreted to be broadly contemporaneous along thelength of the northern margin of the Inland Branch. In the westheat transfer was dominated by conduction and externally drivenby granites, whereas in the east heat transfer was dominatedby advection and internally driven radiogenic heat production.The ultimate cause was along-orogen variation in crustal architecture,including thickness of the passive margin lithosphere and thicknessof the overlying sedimentary succession. KEY WORDS: Pan-African Orogeny; P–T paths; pseudosections; low-P metamorphism; contact metamorphism; Barrovian metamorphism  相似文献   

10.
High-pressure, regional metamorphic rocks (the Raspas Formation)constitute an inclusion more than 10 km long and 3 km wide ina protrusion of extensively serpentinized harzburgite in ElOro Province, southwestern Ecuador. The high-pressure rocks,all feldspar-free, consist of a dominant pelitic schist withquartzite layers, eclogite, eclogite amphibolite, garnetite,and retrograde mafic rocks. The pelitic schist is coarse grainedand is composed of quartz + phengite + paragonite + garnet +chloritoid + rutile + graphite ± kyanite ± pyrite.Eclogite is fine to medium grained, massive to strongly foliated(average mode: omphacite (Jd42Ac6(Di + He)32), 38.2 per cent;garnet (Alm53 Spess2 Pyr19 Gross26), 26.6; barroisite (4.1 percent Na2O), 22.6; clinozoisite, 4.1; rutile, 2.1; quartz, 5.7;other minerals, 0.7).Eclogite amphibolite is a medium-grainedand massive to foliated rock composed of amphibole (3.1 percent Na2O) + garnet + zoisite + kyanite + rutile + pyrite ±omphacite± paragonite ± quartz ± apatite. Retrogrademafic rocks include glaucophane schist, greenschist, and coarse-grained,amphibole-rich rocks. Prograde metamorphism took place in an active Benioff zone.Based on phase relations in the pelitic schist, partitioningof Mg/(Mg + Fetotal + Mn) in garnet-amphibole and in omphacite-amphibolepairs (Dòbretsov et al., 1975), the absence of lawsonite,and other evidence, the conditions of metamorphism are estimatedto have been T = 580 ° ± 20 °C and P total =13 ± 3 kb (43 ± 10 km depth). P H2O ranged from P total in pelitic schist, through P total in eclogite amphibolitc,to «P total in eclogite. Retrograde metamorphism accompaniedrapid uplift of the Raspas Formation during which the rockspassed through the stability field of glaucophane-epidote schist,but not the stability field of lawsonite. The inclusion of high-pressure rocks was carried upward intactin a protrusion of extensively serpentinized harzburgite whichrose diapirically through the relatively denser amphiboliteand greenschist which constitute the regional basement of ElOro Province. Serpentinization of harzburgite began at depth,and continued coevally with eclogitization. Protrusive riseoccurred upon abandonment of the Benioff zone. Radiometric K-Arages on the uplift of the Raspas Formation and the youngestlavas of a volcanic are of Jurassic-Early Cretaceous age ineastern Ecuador are synchronous (132 m.y.). Present address: Département de Géologie, Université Laval, Québec, P. Q. G1K 7P4 Canada  相似文献   

11.
Olivine-rich rocks containing olivine + orthopyroxene + spinel+ Ca-amphibole ± clinopyroxene ± garnet are presentin the central Ötztal–Stubai crystalline basementassociated with eclogites of tholeiitic affinity. These rockscontain centimetre-sized garnet layers and lenses with garnet+ clinopyroxene ± corundum. Protoliths of the olivine-richrocks are thought to be olivine + orthopyroxene + spinel dominatedcumulates generated from an already differentiated Fe-rich () tholeiitic magma that was emplaced into shallowcontinental crust. Protoliths of the garnet-rich rocks are interpretedas layers enriched in plagioclase and spinel intercalated ina cumulate rock sequence that is devoid of, or poor in, plagioclase.U–Pb sensitive high-resolution ion microprobe dating ofzircons from a garnet layer indicates that emplacement of thecumulates took place no later than 517 ± 7 Myr ago. Aftertheir emplacement, the cumulates were subjected to progressivemetamorphism, reaching eclogite-facies conditions around 800°Cand >2 GPa during a Variscan metamorphic event between 350and 360 Ma. Progressive high-P metamorphism induced breakdownof spinel to form garnet in the olivine-rich rocks and of plagioclase+ spinel to form garnet + clinopyroxene ± corundum inthe garnet layers. Retrogressive metamorphism at T 650–680°Cled to the formation of Ca-amphibole, chlorite and talc in theolivine-rich rocks. In the garnet layers, högbomite formedfrom corundum + spinel along with Al-rich spinel, Ca-amphibole,chlorite, aspidolite–preiswerkite, magnetite, ilmeniteand apatite at the interface between olivine-rich rocks andgarnet layers at P < 0·8 GPa. Progressive desiccationof retrogade fluids through crystallization of hydrous phasesled to a local formation of saline brines in the garnet layers.The presence of these brines resulted in a late-stage formationof Fe- and K-rich Ca-amphibole and Sr-rich apatite, both characterizedby extremely high Cl contents of up to 3·5 and 6·5wt % Cl, respectively. KEY WORDS: cumulates; Variscan metamorphism; SHRIMP dating; högbomite; saline brines  相似文献   

12.
The early augite syenite unit in the 1·13-Ga-old Ilímaussaqintrusive complex, South Greenland, consists of a magmatic assemblageof ternary alkali feldspar + fayalitic olivine + augite + titanomagnetite+ apatite + baddeleyite ± nepheline ± quartz ±ilmenite ± zircon. Feldspar, nepheline and QUILF thermometryyield T = 1000–700°C, at P = 1 kbar, which is derivedfrom fluid inclusion data from other parts of the complex. Ternaryfeldspar was the first major liquidus phase. It crystallizedat temperatures between 950 and 1000°C from a homogeneousmagma with aSiO2 = 0·8 and fO2 about 1·5–2log units below the fayalite–magnetite–quartz (FMQ)buffer. Later, closed system fractionation produced nepheline-bearingassemblages with aSiO2 = 0·4 and log fO2 = FMQ –3 to FMQ – 5. Assimilation of wall rocks produced localvariations of melt composition. Four traverses through the unitwere sampled parallel to the assumed direction of crystallization.They exhibit significant differences in their mineral assemblagesand compositions. The chemical zoning and calculated intensiveparameters of four sample suites reflect both closed systemfractional crystallization and local assimilation of wall rocks. KEY WORDS: alkaline magmatism; assimilation; fractionation; redox equilibria; QUILF  相似文献   

13.
The 456 ± 4 Ma Skattøra migmatite complex in thenorth Norwegian Caledonides consists of migmatitic nepheline-normativemetagabbros and amphibolites that are net-veined by numerousnepheline-normative anorthositic and leucodioritic dykes. Plagioclase(An20–50) is the dominant mineral (85–100%) in thedykes and the leucosome, but amphibole is generally presentin amounts up to 15%. The following observations strongly suggestformation of the anorthositic magma by anatexis of the surroundinggabbro in the presence of an H2O-bearing fluid phase: (1) themigmatites have plagioclase-rich (anorthositic) leucosomes andamphibole-rich restites; (2) crystallization of amphibole inthe anorthositic and leucodioritic dykes suggests high H2O activity;(3) the presence of coarse-grained to pegmatitic dykes and miaroliticcavities indicates a fluid-rich magma; (4) hydration zones thatsurround many anorthosite dykes suggest that the magma probablyexpelled H2O-rich fluids during crystallization. Water-saturatedmelting experiments at 0·5–1·5 GPa and temperaturesfrom 800 to 1000°C have been performed on a nepheline-normativegabbro to test the proposed petrogenesis of the Skattøraanorthosites. The glasses produced close to the solidus aretonalitic in composition, but they become richer in plagioclaseat higher temperatures. At and below 1·0 GPa, the residuesare composed of amphibole. Experiments above 1·0 GPaproduced residual garnet and/or zoisite in addition to amphibole,suggesting that the anorthositic dykes in the Skattøramigmatite complex formed below 1·25 GPa. The experimentsshow that the high Na2O content of the anorthosite dykes canonly be produced if Na is added to the charges. The glass thatbest fits the composition of the Skattøra dykes was producedat 1·0 GPa and 900°C with 2 wt % Na(OH) added. KEY WORDS: anorthosite; dyke swarm; anatexis; experimental petrology  相似文献   

14.
Phase relations for the bulk compositions 3CaO·2FeOx·3SiO2+excessH2O and CaO·FeOx·2SiO2+excess H2O were determinedusing conventional hydrothermal techniques with solid phaseoxygen buffers to control fO2. Andradite, Ca3Fe3+2Si3O12, synthesized above 550 °C hasan average unit cell edge, ao, of 12.055±0.001 Å,and an index of refraction, n, of 1.887±0.003. Belowthis temperature, ao increases whereas n decreases, indicatingthe formation of a member of the andradite-hydroandradite solidsolution. At 2000 bars Pfluid andradite is stable above an fO2of 1015 bar at 800 °C and 10-32 bar at 400 °C. At lowerfO2 andradite+fluid gives way at successively lower temperaturesto the condensed assemblages magnetite+wollastonite, kirschsteinite(CaFe2+SiO4)+ wollastonite and kirschsteinite+xonotlite (Ca6Si6O17(OH)2). Synthetic hedenbergite, CaFe2+Si2O6, has average unit cell dimensionsof ao = 9.857± 0.004 Å, bo = 9.033±0.002Å, co = 5.254±0.002 Å and ß = 104.82°±0.03°,and refractive indices of n = 1.731±0.003 and n = 1.755±0.005.At 2000 bars Pfiuid, hedenbergite is stable below an fO2 of10-13 bar at 800 °C and 10-28 bar at 400 °C. Above thesefO2 values, hedenbergite+O2 breaks down to andradite+magnetite+quartz. The mineral pair andradite +hedenbergite thus limit the fO2range possible for their joint formation under equilibrium conditions. The hydration of wollastonite to xonotlite occurs at much lowertemperatures than previous experimental work indicated. A tentativehigh temperature limit for this reaction is set at 185°±15°C and 5000±25 bars and 210°±15 °Cand 2000±20 bars. Inasmuch as the growth of xonotlitefrom wollastonite + H2O was never accomplished, this high temperaturelimit does not represent an equilibrium univariant curve. Nine phases were encountered in the study of andradite and hedenbergite.They are andradite, hedenbergite, magnetite, wollastonite, kirschsteinite,xonotlite, quartz, ilvaite, and vapor (fluid). An invariantpoint analysis using the method of Schreinemakers shows thetopologic relations of the reactions involved. The resultinggrid can be used to interpret natural occurrences.  相似文献   

15.
Blue Mountain is a central-type alkali ultrabasic-gabbro ringcomplex (lxl7middot;5 km) introducing Upper Jurassic sediments,Marlborough, New Zealand. The ultrabasic-gabbroic rocks containlenses of kaersutite pegmatite and sodic syenite pegmatite andare intruded by ring dykes of titanaugite-ilmenite gabbro andlamprophyre. The margin of the intrusion is defined by a ringdyke of alkali gabbro. The plutonic rocks are cut by a swarmof hornblendebiotite-rich lamprophyre dykes. Thermal metamorphismhas converted the sediments to a hornfels ranging in grade fromthe albite-epidote hornfels facies to the upper limit of thehornblende hornfels facies. The rocks are nepheline normative and consist of olivine (Fo82–74),endiopside (Ca45Mg48Fe7–Ca36Mg55Fe9), titanaugite (Ca40Mg50Fe10–Ca44Mg39Fe17),plagioclase (An73–18), and ilmenitetitaniferous magnetite,with various amounts of titaniferous hornblende and titanbiotite.There is a complete gradation between endiopside and titanaugitewith the coupled substitution Ry+2+Si;;(Ti+4+Fe+3+Al+3 and asympathetic increase in CaAl2SiO6 (0·2–10·2percent) and CaTiAl2O6 (2·1–8·1 per cent)with fractionation. Endiopside shows a small, progressive Mgenrichment along a trend subparallel to the CaMgSi2O6–Mg2Si2O6boundary, and titanaugite is enriched in Ca and Fe+2+Fe+3 withdifferentiation. Oscillatory zoning between endiopside and titanaugiteis common. Exsolved ilmenite needles occur in the most Fe-richtitanaugites. The amphiboles show the trend: titaniferous hornblende(1·0–57middot;7 per cent TiO2) kaersutite (6·4per cent TiO2) Fe-rich hastingsite (18·0–19·1per cent FeO as total Fe). Biotite is high in TiO2 (6·6–7·8per cent). Ilmenite and titaniferous magnetite (3·5–10·6per cent TiO2) are typically homogeneous grains; their compositioncan be expressed in terms of R+2RO3:R+2O:R2+3O4. The intrusion of igneous rocks was probably controlled by subterraneanring fracturing. Subsidence of the country rock within the ringfracture provided space for periodic injections of magma froma lower reservoir up the initial ring fracture to form the BlueMountain rocks at a higher level. Downward movement of the floorof the intrusion during crystallization caused inward slumpingof the cumulates which affected the textural, mineralogical,and chemical evolution of the rocks in different parts of theintrusion. The order of mineral fractionation is reflected by the chemicalvariation in the in situ ultrabasic-gabbroic rocks and the successiveintrusions of titanaugite-ilmenite gabbro and lamprophyre ringdykes, marginal alkali gabbro and lamprophyre dyke swarm. Aninitial decrease, then increase in SiO2; a steady decrease inMgO, CaO, Ni, and Cr: an initial increase, then decrease inFeO+Fe2O3, TiO2, MnO, and V; almost linear increase in A12O3and late stage increase in alkalis and P2O3, implies fractionationof olivine and endiopside, followed by titanaugite and Fe-Tioxides, followed by plagioclase, hornblende, biotite, and apatite.Reversals in the composition of cumulus olivine and endiopsideand Solidification Index, indicate that the ultrabasic-gabbroicsequence is composed of four main injections of magma. The ultrabasic rocks crystallized under conditions of high PH2Oand fairly high, constant  相似文献   

16.
The Miocene Tokuwa pluton of ‘I-type’ granitoidaffinity was emplaced discordantly into a Cretaceous to Paleogeneaccretionary complex and induced a contact aureole in whichvarious thermally metamorphosed rocks were developed, includinghornfels, metatexite, diatexite and cordierite-bearing tonalite(Crd-tonalite) of ‘S-type’ granite affinity. Thethermally metamorphosed rocks show low-pressure reaction texturesculminating in partial melting. Peak P–T conditions of3 kbar at 780°C are estimated on the basis of the TWQ thermobarometerfor the garnet-bearing rocks. The rocks in the contact aureoleexhibit a gradual transition from hornfels, through metatexiteand diatexite to Crd-tonalite. The Sr-isotopic composition atthe time of Tokuwa pluton emplacement at 12 Ma decreases systematicallyfrom metatexite (0·7100–0·7112) throughdiatexite (0·7078–0·7094) to Crd-tonalite(0·7067–0·7068); this trend is interpretedin terms of mixing between the Tokuwa magma and the aureolemigmatites. The field relationships, geochemical data, and isotopicdata collectively suggest that the emplacement of the Tokuwapluton triggered partial melting of the surrounding metasedimentaryrocks. Subsequent hybridization of the Tokuwa magma with themetatexite in variable proportions produced the Crd-tonaliteand diatexite. The hybridization was caused by invasion of theTokuwa magma into the migmatite zone, accompanied by gravitationalcollapse of the previously crystallized wall of the magma chamber.The data presented demonstrate that even a relatively low-temperature,shallow, ‘I-type’ granitoid pluton can induce contactanatexis and hybrid ‘S-type’ granitoid formationat the intrusive contact. KEY WORDS: contact metamorphism; hybridization; magma–host-rock interaction; migmatite; ‘S-type’ granitoid  相似文献   

17.
The aluminous pyroxene, fassaite, occurs in two small tabularbodies within mafic plutonites of the Boulder Batholith nearits north-east margin twelve miles east of Helena, Montana.First described by Knopf & Lee (1957), the bodies are contact-metasomatizedlimestone septa, now magnesian-tactites, consisting chieflyof fassaite, spinel, garnet, vesuvianite, and clintonite. Lesscommon minerals include pargasite, diopside, wollastonite, sphene,perovskite, anorthite, forsterite, calcite and chlorite. Sometwenty-five microprobe analyses of the fassaite show it is variablein composition and largely consists of the components CaMgSi2O6(53–83 per cent), CaAl2SiO6 (7–25 per cent), CaFeAlSiO6(8–28 per cent), and CaTiAl2O6 (0–7 per cent). Thestoichiometry generally requires that most of the iron is ferric,consistent with Mössbauer data taken on a typical sample.If fassaite analyses from these and other contact metamorphicrocks are plotted on a triangular diagram with Ca(Mg,Fe)Si2O6,CaAl2SiO6 and CaFeAlSiO6 as end-members, the distribution ofpoints offers no positive evidence for a solvus gap betweenfassaite and diopside as proposed by Ginzburg (1969). The mostaluminous fassaites occur with spinel-clintonite ± grossularand have 25 per cent of the Si replaced by Al, making them truepolymorphs of a garnet (i.e. Gr42And23Pp35). No unusual cationordering is detected in these fassaites by single-crystal X-rayphotographs or Mössbauer measurements. Smede's (1966) estimate of 3–4 km of stratigraphic coverfor the Boulder Batholith indicates pressures of approximately1 kb, in agreement with the occurrence of andalusite + K-feldsparin a hornfels at the Kokaruda Ranch complex. The partial assemblagesof grossular, epidote, perovskite, anorthite-wollastonite, anorthite-calcite,and fassaite-calcite require XCO2 = 0·12 ± 0·08and T = 570 ± 10 °C at these pressures. These pressuresand temperatures place this occurrence in the upper portionsof the hornblende-hornfels facies after Turner (1968), althoughthe low pressures and water-rich fluids permit assemblages (wollastonite,calcite-forsterite-diopside) that Turner lists as characteristicof the pyroxene-hornfels facies.  相似文献   

18.
Experimental studies were carried out to evaluate phase relationsinvolving titanite–F–Al-titanite solid solutionin the system CaSiO3–Al2SiO5–TiO2–CaF2. Theexperiments were conducted at 900–1000°C and 1·1–4·0GPa. The average F/Al ratio in titanite solid solution in theexperimental run products is 1·01 ± 0·06,and XAl ranges from 0·33 ± 0·02 to 0·91± 0·05, consistent with the substitution [TiO2+]–1[AlF2+]1.Analysis of the phase relations indicates that titanite solidsolutions coexisting with rutile are always low in XAl, whereasthe maximum XAl of titanite solid solution occurs with fluoriteand either anorthite or Al2SiO5. Reaction displacement experimentswere performed by adding fluorite to the assemblage anorthite+ rutile = titanite + kyanite. The reaction shifts from 1·60GPa to 1·15 ± 0·05 GPa at 900°C, from1·79 GPa to 1·375 ± 0·025 GPa at1000°C, and from 1·98 GPa to 1·575 ±0·025 GPa at 1100°C. The data show that the activityof CaTiSiO4O is very close to the ideal molecular activity model(XTi) at 1100°C, but shows a negative deviation at 1000°Cand 900°C. The results constrain  相似文献   

19.
In the Ranmal migmatite complex, non-anatectic foliated graniteprotoliths can be traced to polyphase migmatites. Structural–microtexturalrelations and thermobarometry indicate that syn-deformationalsegregation–crystallization of in situ stromatic and diatexiteleucosomes occurred at 800°C and 8 kbar. The protolith,the neosome, and the mesosome comprise quartz, K-feldspar, plagioclase,hornblende, biotite, sphene, apatite, zircon, and ilmenite,but the modal mineralogy differs widely. The protolith compositionis straddled by element abundances in the leucosome and themesosome. The leucosomes are characterized by lower CaO, FeO+MgO,mg-number, TiO2 , P2O5 , Rb, Zr and total rare earth elements(REE), and higher SiO2 , K2O, Ba and Sr than the protolith andthe mesosome, whereas Na2O and Al2O3 abundances are similar.The protolith and the mesosome have negative Eu anomalies, butprotolith-normalized abundances of REE-depleted leucosomes showpositive Eu anomalies. The congruent melting reaction for leucosomeproduction is inferred to be 0·325 quartz+0·288K-feldspar+0·32 plagioclase+0·05 biotite+0·014hornblende+0·001 apatite+0·001 zircon+0·002sphene=melt. Based on the reaction, large ion lithophile element,REE and Zr abundances in model melts computed using dynamicmelting approached the measured element abundances in leucosomesfor >0·5 mass fraction of unsegregated melts withinthe mesosome. Disequilibrium-accommodated dynamic melting andequilibrium crystallization of melts led to uniform plagioclasecomposition in migmatites and REE depletion in leucosome. KEY WORDS: migmatite; REE; trace element; partial melting; P–T conditions  相似文献   

20.
The terrane in the Panamint Mountains, California, was regionallymetamorphosed under low-pressure conditions and subsequentlyunderwent retrograde metamorphism. Prograde metamorphic isogradsthat mark the stability of tremolite + calcite, diopside, andsillimanite indicate a westward increase in grade. The studywas undertaken to determine the effects of the addition of Caon the types of assemblages that may occur in pelitic schists,to contribute to the understanding of the stability limits inP – T – aH2O – XFe of the pelitic assemblagechlorite + muscovite + quartz, and to estimate the change inenvironment from prograde to retrograde metamorphism. Peliticassemblages are characterized by andalusite + biotite + stauroliteand andalusite + biotite + cordierite. Within a small changein grade, chlorite breaks down over nearly the entire rangein Mg/(Mg + Fe) to biotite + aluminous mineral. Chlorite withMg/(Mg + Fe) = 0.55 is stable to the highest grade, and thegeneralized terminal reaction is chlorite + muscovite + quartz= andalusite + biotite + cordierite + H2O. Calcic schists arecharacterized by the assemblage epidote + muscovite + quartz+ chlorite + actinolite + biotite + calcite + plagioclase atlow grades and by epidote + muscovite + quartz + garnet + hornblende+ biotite + calcite + plagioclase at high grades. Epidote doesnot coexist with any AFM phase that is more aluminous than garnetor chlorite. Lithostatic pressure ranged from 2.3 kb to 3.0kb. During prograde-metamorphism temperatures ranged from lessthan 400° to nearly 700°C, and XH2O (assuming PH2O +PCO3 = Ptotal) is estimated to be 0.25 in siliceous dolomite,0.8 in pelitic schist, and 1.0 in calcic schist. Temperatureduring retrograde metamorphism was 450° ± 50°C,and all fluid were H2O-rich. A flux of H2O-rich fluid duringfolding is believed to have caused retrograde metamorphism.The petrogenetic grid of Albee (1965b) is modified to positionthe (A, Cd) invariant point relative to the aluminosilicatetriple point, which allows the comparison of facies series thatinvolve different chloritoid-reactions.  相似文献   

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