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1.
Lost circulation, the inadvertent injection of drilling fluids into a highly permeable and/or fractured aquifer during rotary drilling, may result in collection of spurious information if the lost drilling fluids are not adequately purged before sampling the ground water. The purpose of this study was to determine whether removal of the volume of water lost during coring of a monitoring well in the carbonate Scotch Grove Formation (Silurian, east central Iowa) necessarily ensures collection of representative ground water samples. To monitor dilution of the ground water due to lost circulation, rhodamine dye was added to the drilling water and dye recovery was measured in samples collected during purging of five separate 5- to 10-foot intervals.
Circulation loss occurred in all five intervals, ranging from nearly 200 gallons in the upper permeable portion of the Scotch Grove to 25 gallons in the less permeable Buck Creek Member below. When the volume of water purged from the upper three intervals corresponded to the volume of water lost during coring, the purge water still contained 11 to 20 percent dyed drilling water. As purging continued, the proportion of drilling water in the samples decreased slowly. After purging more than 200 gallons of water, 86 to 98 percent of the dyed drilling water was recovered from the five test intervals. Four traditionally measured water quality parameters-pH, temperature, specific conductance, and dissolved oxygen — were less useful than the dye recovery for distinguishing drilling water from formation water in those zones in which the ground water quality was similar to the drilling water. These results indicate that the determination of the quantity of water to be purged prior to sampling must be based, at least in part, on aquifer lithology and hydraulic characteristics.  相似文献   

2.
Standard methodologies for sampling the physicochemical conditions of groundwater recommend purging a bore for three bore volumes to avoid sampling the stagnant water within a bore and instead gain samples representative of the aquifer. However, there are currently no methodological standards addressing the amount of purging required to gain representative biological samples to assess groundwater bacterial and viral abundances. The objective of this study was to examine how bacterial and viral abundances change during the purging of bore volumes. Six bores infiltrating into unconfined aquifers were pumped for five or six bore volumes each and bacteria and virus‐like particles (VLPs) were enumerated from each bore volume using flow cytometry. In examination of the individual bores trends in bacterial abundances were observed to increase, decrease, or remain constant with each purged bore volume. Furthermore, triplicates taken at each bore volume indicated substantial variations in VLP and bacterial abundances that are often larger than the differences between bore volumes. This indicates a high level of small scale heterogeneity in microbial community abundance in groundwater samples, and we suggest that this may be an intrinsic feature of bore biology. The heterogeneity observed may be driven by bottom up processes (variability in the distribution of organic and inorganic nutrients), top‐down processes (grazing and viral lysis), physical heterogeneities in the bore, or technical artifacts associated with the purging process. We suggest that a more detailed understanding of the ecology underpinning this variability is required to adequately describe the microbiological characteristics of groundwater ecosystems.  相似文献   

3.
Efforts to sample representative, undisturbed distributions of uranium in ground water beneath the Fernald Environmemal Management Project (FEMP) prompted the application of a novel technique that is less invasive in the monitoring well. Recent studies (Kearl et al. 1992; Barcelona et al. 1994) indicate that representative samples can and should be collected without prior well volume exchange purging or borehole evacuation. Field experiments conducted at the FMMP demonstrate that under specific sampling conditions in a welldefined hydrogeologic system, representative ground water samples for a monitoring program can be obtained without removing the conventional three well volumes from the well. The assumption is made that indicator parameter equilibration may not be necessary to determine when to collect representative samples at the P'liMP. Preliminary results obtained from the field experiment suggest that this may be true. The technique employs low purge rates (< 1 L/min) with dedicated bladder pumps with inlets located in the screened interval of the well, while not disturbing the stagnant water column above the screened interval. If adopted, this technique, termed micro-purge low-flow sampling, will produce representative ground water samples, significantly reduce sampling costs, and minimize; waste water over the monitoring life cycle at the FEMP. This technique is well suited for sites that have been fully characterized and are undergoing long-term monitoring.  相似文献   

4.
Acquisition of Representative Ground Water Quality Samples for Metals   总被引：1，自引：0，他引：1  
R.S. Kerr Environmental Research Laboratory (RSKERL) personnel have evaluated sampling procedures for the collection of representative, accurate, and reproducible ground water quality samples for metals for the past four years. Intensive sampling research at three different field sites has shown that the method by which samples are collected has a greater impact on sample quality, accuracy, and reproducibility than whether the samples are filtered or not. In particular, sample collection practices that induce artificially high levels of turbidity have been shown to have the greatest negative impacts on sample quality. Results indicated the ineffectiveness of bailers for collection of representative metal samples. Inconsistent operator usage together with excessive purging generally resulted in excessive turbidity (>100 NTUs) and large differences in filtered and unfiltered metal samples. The use of low flow rate purging and sampling consistently produced filtered and unfiltered samples that showed no significant differences in concentrations. Turbidity levels were generally less than 5 NTUs, even in fine-textured glacial till. We recommend the use of low flow rates, during both purging and sampling, placement of the sampling intake at the desired sampling point, minimal disturbance of the stagnant water column above the screened interval, monitoring of water quality indicators during purging, minimization of atmospheric contact with samples, and collection of unfiltered samples for metal analyses to estimate total contaminant loading in the system. While additional time is spent due to use of low flow rates, this is compensated for by eliminating the need for filtration, decreased volume of contaminated purge water, and less resampling to address inconsistent data results.  相似文献   

5.
Monitoring well sand packs are theoretically capable of retarding metal ions and organic contaminants. If this retardation does indeed occur it may have a significant effect on the purging requirements of newly installed monitoring wells. Calculations based on mass balance and retardation concepts demonstrate that if common guidelines for well purging are followed, contaminants may not be detected or may be detected in lower concentrations than are actually present in the ground water. This problem is greatest in relatively shallow wells installed in low to moderate permeability materials. In most cases, the effect of solute retardation in the sand pack can be avoided simply by additional purging prior to the first sampling of the monitoring well. Common purging guidelines can then be applied to subsequent samplings. The methodology outlined in this paper can be used to calculate the purging requirements of existing monitoring wells or it may be applied to alternative monitoring well designs to test which will require the smallest volume of purged water.  相似文献   

6.
An investigation of elevated concentrations of nickel and chromium in certain ground water samples collected at Williams Air Force Base (AFB) indicated that type 304 stainless steel well materials are the source. Chloride in the ground water has apparently caused crevice corrosion of the stainless steel well screens installed during site characterization. An evaluation of site geochemistry suggested that chromium released from the well screen would precipitate, while nickel would remain dissolved. Thus, low-flow purging and sampling significantly reduces the chromium found in the ground water samples because such sampling minimizes the collection of artificially entrained particulates. In contrast to chromium, nickel concentrations did not decrease during low-flow purging and sampling, indicating that it is dissolved. Nickel and chromium concentrations are both low following high-volume purging when turbidity levels are stabilized below 10 nephelometric turbidity units prior to sampling. In the latter case, chromium concentration is low because particulate collection is minimized, and nickel concentration is low because of increased dilution. Based on these results, it is recommended that elevated levels of nickel and chromium in ground water samples collected from stainless steel monitoring wells be carefully evaluated, because well materials may be the source. In addition, although low-volume purging is increasingly becoming the sampling method of choice, high-volume purging may be a useful means of determining whether the well materials influence nickel and chromium concentrations.  相似文献   

7.
In this paper, we relate recent developments in ground water sampling techniques to the practical application of sampling for toxic contaminants in ground water. We address the choices that must be made in choosing equipment for a particular project by going through a step-by-step procedure for collecting a ground water sample from a typical monitoring well. Ground water sampling topics that are discussed include: choice of equipment for purging and sampling a well, monitoring for purged ground water indicators and quality assurance/quality control.  相似文献   

8.
Soil-gas sampling and analysis is a common tool used in vapor intrusion assessments; however, sample collection becomes more difficult in fine-grained, low-permeability soils because of limitations on the flow rate that can be sustained during purging and sampling. This affects the time required to extract sufficient volume to satisfy purging and sampling requirements. The soil-gas probe tubing or pipe and sandpack around the probe screen should generally be purged prior to sampling. After purging, additional soil gas must be extracted for chemical analysis, which may include field screening, laboratory analysis, occasional duplicate samples, or analysis for more than one analytical method (e.g., volatile organic compounds and semivolatile organic compounds). At present, most regulatory guidance documents do not distinguish between soil-gas sampling methods that are appropriate for high- or low-permeability soils. This paper discusses permeability influences on soil-gas sample collection and reports data from a case study involving soil-gas sampling from silt and clay-rich soils with moderate to extremely low gas permeability to identify a sampling approach that yields reproducible samples with data quality appropriate for vapor intrusion investigations for a wide range of gas-permeability conditions.  相似文献   

9.
Observations of colloidal movement under natural conditions and during pumping were conducted at several field sites. Results indicate that several modifications to present sampling protocols may improve the representativeness and cost effectiveness of obtaining ground water samples for assessing the total mobile contaminant load. These modifications include the installation of dedicated sampling devices, limited purging of the well prior to sampling, sampling at a flow rate of 100 mL/min, and no filtering of samples. This sampling approach can result in significant cost savings while providing the best possible water samples.  相似文献   

10.
An Analysis of Low-Flow Ground Water Sampling Methodology   总被引：1，自引：0，他引：1  
Low-flow ground water sampling methodology can minimize well disturbance and aggravated colloid transport into samples obtained from monitoring wells. However, in low hydraulic conductivity formations, low-flow sampling methodology can cause excessive drawdown that can result in screen desaturation and high ground water velocities in the vicinity of the well, causing unwanted colloid and soil transport into ground water samples taken from the well. Ground water velocities may increase several fold above that of the natural setting. To examine the drawdown behavior of a monitoring well, mathematical relationships can be developed that allow prediction of the steady-state drawdown for constant low-flow pumping rates based on well geometry and aquifer properties. The equations also estimate the time necessary to reach drawdown equilibrium. These same equations can be used to estimate the relative contribution of water entering a sampling device from either the well standpipe or the aquifer. Such equations can be useful in planning a low-flow sampling program and may suggest when to collect a water sample. In low hydraulic conductivity formations, the equations suggest that drawdown may not stabilize for well depths, violating the minimal drawdown requirement of the low-flow technique. In such cases, it may be more appropriate to collect a slug or passive sample from the well screen, under the assumption that the water in the well screen is in equilibrium with the surrounding aquifer.  相似文献   

11.
Determination of the nature, extent, and rate of off-site chemical migration are common objectives of hazardous waste site investigations. Chemical analyses of water samples from monitoring wells and measurements of hydraulic head and hydraulic conductivity provide the basis for making these determinations. Accurate site assessment, therefore, depends upon the appropriate monitoring well design and sampling and testing procedures.
During the course of remedial investigations in Niagara Falls, New York, it has been necessary to evaluate the ground water quality and hydraulic characteristics of 5- to 30-feet thick overburden formations. Many of the monitoring wells completed to these formations consist of a partially penetrating screen (5 feet at the base of the formation) with a fully penetrating sandpack. Questions regarding how this well design influences the source of sampled ground water and hydraulic tests were examined using an extremely fine axisymmetric grid with SATURN, a two-dimensional, finite-element ground water model, and a particle tracking post-processor.
A discrete sensitivity analysis was made to determine how flow patterns induced by pumping at 1 gpm are affected by: different screen and sandpack configurations, the ratio of sandpack to formation hydraulic conductivities, heterogeneity, anisotropy, and sandpack thickness. The simulations show that the source (and chemistry given a non-uniform chemical distribution) of ground water sampled will vary considerably depending on a number of factors. Analysis of simulated drawdowns in the monitoring well during purging shows that calculated transmissivities for the range of well designs and conditions modeled will be accurate to within one-half order of magnitude.  相似文献   

12.
Aquifer microbial water quality evaluations are often performed by collecting groundwater samples from monitoring wells. While samples collected from continuously pumped sources are seldom disputed as representative of the aquifer, natural biofilm present in the vicinity of well screens may introduce unwanted microbial artefacts in monitoring wells that are only periodically sampled. The need for well water purging to obtain samples void of these artefacts has been widely recognized. However, purging methods are not standardized; many approaches presume that physico-chemical water quality stability achieved through the removal of 3 to 5 well volumes is indicative of the stability of target analytes. Using a data set collected from a shallow unconfined aquifer in Southern Ontario, Canada, the need for using dedicated approaches that account for the time-dependent nature of microbial water quality changes was demonstrated. Specifically, the utility of adenosine triphosphate (ATP) as a rapid, field-ready biochemical indicator of microbial water quality stability was investigated. This work shows that ATP concentrations reflect time-limited (bio)colloid transport processes that are consistent with other microbial water quality parameters monitored, but different from commonly measured physical and chemical water quality indicators of well purging adequacy. ATP concentrations occasionally fluctuated even after 3 or 4 h of purging, indicating that microbial artefacts attributable to biofilms in the vicinity of the well screen can still persist. The recurrence of characteristic ATP patterns in each well was systematically examined through the novel application of dynamic time warping (DTW), a nonparametric time series analysis approach. These patterns are believed to be linked with seasonal hydrogeological conditions, which warrant consideration in the design and interpretation of subsurface microbial water quality investigations.  相似文献   

13.
The Effect of Three Drilling Fluids on Ground Water Sample Chemistry   总被引：1，自引：0，他引：1  
Three monitoring wells were installed in borings that were constructed using water-based drilling fluids containing either (1) guar bean, (2) guar bean with breakdown additive, or (3) bentonite. These fluids were selected to observe their effect on the chemistry of subsequent water samples collected from the wells. The wells were installed to depths of 66 feet, 100.5 feet and 103 feet, respectively, in fine-to-medium sand and gravel outwash deposits near Antigo, Wisconsin. Drilling fluids were necessary to maintain an open borehole during well construction through strata containing cobbles and boulders.
The bentonite and guar drilling fluids caused temporarily elevated concentrations of chemical oxygen demand (COD) in ground water samples collected from the monitoring wells. Using standard development, purging and sampling procedures, elevated COD concentrations persisted for about 50 days for the well bored with the guar-with-additive fluid, 140 days for the bentonite well and 320 days for the guar well. Unfiltered ground water samples for all wells had greater concentrations of COD than samples filtered through a 0.45 micron filter. Sulfate concentrations also decreased with time in the guar-with-additive well and bentonite well, but not in the guar well.
The elevated COD concentrations are attributed to the large concentrations of oxidizable carbon present in the guar bean drilling fluid and in the organic polymers present in the bentonite drilling fluid. Well development and purging procedures, including borehole flushing, surging, bailing and/or chemically induced viscosity breakdown of the guar mud decreased the time before background conditions were achieved. Future research should evaluate the physical and geochemical interaction of different drilling fluid compositions with a variety of geologic matrices and drilling, well development and well purging techniques.  相似文献   

14.
Pumped waters from 14 Pennsylvania wells, located in shallow sandstone, siltstone and shale aquifers, were continuously monitored for dissolved oxygen (D. O.), nitrate (NO3), pH, electrical conductivity (EC) and water temperature in a discharge manifold at the well head. The amount of pumping or purging required to stabilize these parameter readings varied by well site and parameter being analyzed. However, the purging required was generally greatest for D. O. and least for water temperature where: D. O. < NO3 pH < EC < water temperature. Wells located near the siltstone-shale interface generally required far more purging than did wells located elsewhere. Although parameter stability was often achieved within purging one bore volume, the complexity, diversity, and variability in the data and these well-ground water systems, suggest that no single purging rule is appropriate. Instead, the extent of purging required before sampling these shallow aquifers should be determined by incorporating on-site monitoring of target or related parameters into the purging process.
From a sampling perspective, the relationship between NO3 and D. O. concentrations during purging were analyzed relative to aquifer type. For most wells located in sandstone or siltstone, NO3 concentrations remained relatively constant during purging irrespective of changes in D. O. For most wells located in shale, these two were positively and similarly correlated, suggesting that a general relationship exists.  相似文献   

15.
A discrete point sampler has been developed that overcomes disadvantages inherent in several current small-volume samplers. It is designed to obtain ground water samples after a well has been purged with a pump. It consists of a sample chamber, two ports, and a stopcock for withdrawing sample aliquots. After lowering the sampler into a well, sampling is initiated by pulling on a line that sequentially removes the plugs in the lower and the upper level ports. The sample chamber fills from the bottom port and vents air from the top port. The device is suitable for sampling for volatile organic compounds in ground waters that are not subject to spontaneous bubble degassing. The upper port is sufficiently far above the lower port that none of the water that is sampled is exposed to the vented air. The sample chamber fills in such a way that the water that is taken from the chamber for analysis is not exposed to the headspace in the chamber.  相似文献   

16.
Regional ground water flow is most usually estimated using Darcy's law, with hydraulic conductivities estimated from pumping tests, but can also be estimated using ground water residence times derived from radioactive tracers. The two methods agree reasonably well in relatively homogeneous aquifers but it is not clear which is likely to produce more reliable estimates of ground water flow rates in heterogeneous systems. The aim of this paper is to compare bias and uncertainty of tracer and hydraulic approaches to assess ground water flow in heterogeneous aquifers. Synthetic two-dimensional aquifers with different levels of heterogeneity (correlation lengths, variances) are used to simulate ground water flow, pumping tests, and transport of radioactive tracers. Results show that bias and uncertainty of flow rates increase with the variance of the hydraulic conductivity for both methods. The bias resulting from the nonlinearity of the concentration–time relationship can be reduced by choosing a tracer with a decay rate similar to the mean ground water residence time. The bias on flow rates estimated from pumping tests is reduced when performing long duration tests. The uncertainty on ground water flow is minimized when the sampling volume is large compared to the correlation length. For tracers, the uncertainty is related to the ratio of correlation length to the distance between sampling wells. For pumping tests, it is related to the ratio of correlation length to the pumping test's radius of influence. In regional systems, it may be easier to minimize this ratio for tracers than for pumping tests.  相似文献   

17.
A field study was conducted to assess purging requirements for dedicated sampling systems in conventional monitoring wells and for pumps encased in short screens and buried within a shallow sandy aquifer. Low-flow purging methods were used, and wells were purged until water quality indicator parameters (dissolved oxygen, specific conductance, turbidity) and contaminant concentrations (chromate, trichloroethylene, dichloroethylene) reached equilibrium. Eight wells, varying in depth from 4.6 to 15.2 m below ground surface, were studied. The data show that purge volumes were independent of well depth or casing volumes. Contaminant concentrations equilibrated with less than 7.5 I. of purge volume in all wells. Initial contaminant concentration values were generally within 20 percent of final values. Water quality parameters equilibrated in less than 10 L in all wells and were conservative measures for indicating the presence of adjacent formation water. Water quality parameters equilibrated faster in dedicated sampling systems than in portable systems and initial turbidity levels were lower.  相似文献   

18.
Hydraulic head differences across the screened or open interval of a well significantly influence the sampled water mixture. Sample bias can occur due to an insufficient pumping rate and/or due to native groundwater displacement by intraborehole flow (IBF). Proper understanding of the sampled water mixture is crucial for accurate interpretation of environmental tracers and groundwater chemistry data, and hence groundwater characterization. This paper uses numerical modeling to quantify sample bias caused by IBF in an un-pumped high-yield well, and the influence of pumping rate and heterogeneity on the volume of pumpage required to purge an IBF plume. The results show that (1) the pumping rate must be at least an order of magnitude greater than the IBF rate to achieve permeability-weighted yield, (2) purge volume was 2.2 to 20.6 times larger than the IBF plume volume, with the ratio depending on plume location relative to hydraulic conductivity and head distributions, and (3) after an example 1000-day un-pumped period, purging required removal of at least three orders of magnitude more water than the common practice of three to five well volumes. These results highlight the importance of knowing the borehole flow regime to identify IBF inflow and outflow zones, estimate IBF rates, and to develop a strategic sampling approach.  相似文献   

19.
Controls of Wellbore Flow Regimes on Pump Effluent Composition   总被引：1，自引：0，他引：1  
Where well water and formation water are compositionally different or heterogeneous, pump effluent composition will vary due to partial mixing and transport induced by pumping. Investigating influences of purging and sampling methodology on composition variability requires quantification of wellbore flow regimes and mixing. As a basis for this quantification, analytical models simulating Poiseuille flow were developed to calculate flow paths and travel times. Finite element modeling was used to incorporate influences of mixing. Parabolic velocity distributions within the screened interval accelerate with cumulative inflow approaching the pump intake while an annulus of inflowing formation water contracts uniformly to displace an axial cylinder of pre‐pumping well water as pumping proceeds. Increased dispersive mixing forms a more diffuse formation water annulus and the contribution of formation water to pump effluent increases more rapidly. Models incorporating viscous flow and diffusion scale mixing show that initially pump effluent is predominantly pre‐pumping well water and compositions vary most rapidly. After two screen volumes of pumping, 94% of pump effluent is inflowing formation water. Where the composition of formation water and pre‐pumping well water are likely to be similar, pump effluent compositions will not vary significantly and may be collected during early purging or with passive sampling. However, where these compositions are expected to be considerably different or heterogeneous, compositions would be most variable during early pumping, that is, when samples are collected during low‐flow sampling. Purging of two screen volumes would be required to stabilize the content and collect a sample consisting of 94% formation water.  相似文献   

20.
Saline water from a storm surge can flow down storm-damaged submerged water supply wells and contaminate boreholes and surrounding aquifers. Using data from conventional purging techniques, aquifer test response analysis, chemical analysis, and regression analysis of chloride/silica (Cl/Si) ratio, equations were derived to estimate the volume of saline water intrusion into a well and a porous media aquifer, the volume of water needed to purge a well shortly following an intrusion event, and the volume of water needed after delay of several or more months, when the saline plume has expanded. Purging time required is a function of volume of water and pumping rate. The study site well is located within a shoreline community of Lake Pontchartrain, St. Tammany Parish, in southeastern Louisiana, United States, which was impacted by two hurricane storm surges and had neither been rehabilitated nor chlorinated prior to our study. Chemical analysis of water samples in fall 2005 and purging of well and aquifer in June 6, 2006, indicated saline water had intruded the well in 2005 and the well and aquifer in 2006. The volume of water needed to purge the study well was approximately 200 casing volumes, which is significantly greater than conventionally used during collection of water samples for water quality analyses.  相似文献   

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