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1.
通过分析德合龙洼铜金矿床区域地质、矿床地质特征,利用钻孔岩心样品分析微量元素分布规律,运用1∶5 000原生晕确定多元素组合异常规律,对矿区进行成矿预测。研究表明,钻孔ZK01-1的前晕元素、中晕元素和尾晕元素均指示出该孔-210m处的强矿化区段,说明其微量元素的分布对成矿作用具有较好的指示意义;从原生晕地球化学特征可知,在矿体的东北部、西北部极有可能存在隐伏矿体,在矿区的东北角和西南部也有可能存在隐伏矿体;因子分析中成矿元素在主因子F3和F1均有较高的因子载荷,说明本区的成矿作用是多阶段多成因的。通过综合研究确定3个找矿预测靶区,为矿山进一步开展找矿工作提供了重要依据。  相似文献   

2.
景德镇朱溪钨铜多金属矿床是近年在赣东北地区发现的一个超大型矽卡岩矿床。在对该矿床成矿地质背景及地质特征已有认识的基础上,本文通过对钻孔揭露出的岩浆岩及矽卡岩型矿石进行微量-稀土元素地球化学分析,结合岩浆岩含矿性、矿化分带性及已有成岩-成矿年代学数据,初步分析了岩浆岩的地球化学特征及其对成矿作用的制约。结果表明岩浆岩与成矿有密切的成因联系,朱溪钨铜多金属矿床的形成可能主要受华南中生代岩石圈多阶段伸展-减薄而形成的一系列地壳重熔型花岗质岩石控制。  相似文献   

3.
娄里金矿位于邯郸洪山杂岩体北侧的火山凝灰岩中。该类型金矿在太行山南段为首次发现,其成矿规律和深部成矿潜力的研究对圈定成矿远景区及增加矿山资源量有重要的指导意义。据此系统采集了矿区ZK11-2和ZK16-1钻孔岩心样品,在分析区域成矿地质规律和矿床地质特征的基础上,采用格里戈良分带指数法和广义衬值法两种方法计算了元素垂向分带序列,结果显示不同方法虽在元素排列顺序上存在一定差异,但在反映热夜活动期次及元素空间叠加模式上基本相同。两个钻孔中均出现了明显的"前尾晕共存"及"反向分带"现象。在此基础上结合微量元素垂向变化规律,分析了区内金矿体形成的热夜活动过程。研究表明两个钻孔的垂向分带都由两个完整的小循环组成,说明区内金矿体的形成至少经历了两次热夜活动叠加。  相似文献   

4.
A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Province. Using the multifractal method, the distribution and migration characteristics of the major and trace elements are analyzed. The multifractal spectrum of the major elements is left-skewed, whereas the spectrum of the trace elements is right-skewed, which shows that in the process of skarn formation, the trace elements were enriched only locally, and major elements transported within a much larger range. The correlation coefficients of the multifractal parameters Aa (width of the multifractal spectrum) of the four drill cores are relatively low, but the correlation coefficients of the multifractal parameters R (spectrum symmetry parameter) and Af are relatively higher, indicating that although the non-homogeneous intensity of the distribution of elements is inconsistent, their spatial accumulation patterns are almost the same during the ore-forming process. The statistics of the mnltifractal parameters of various elements in the different locations show that the ore-forming processes and element migration pattern in the Shizishan orefield are consistent, and that the migrations of trace elements and major elements exhibit some differences.  相似文献   

5.
The Dabaoshan polymetallic deposit, located in the middle Nanling metallogenic belt, is an important and representative W-Mo-Cu-Pb-Zn deposit in the northern Guangdong. The deposit is characterized by a complex combination of ore-forming elements, containing 0.86 Mt Cu, 0.85 Mt Zn, 0.31 Mt Pb, 0.14 Mt WO3 at grades of 0.86%, 12%, 1.77% and 0.12%, respectively. Due to different mineral association and occurrence, mineralization at Dabaoshan can be defined as three types: porphyry W-Mo mineralization, skarn Mo-W mineralization and strata-bound sulfide mineralization. Pyrite from the three-mineralization types has different textures and element compositions. EMPA mapping analysis suggested that distribution of Co, Ni, and As is nearly homogeneous, whilst As in pyrite from the stratabound sulfides shows weak irregular zoning. LA-ICP-MS analyses of pyrite suggested that the three type have distinctive trace element characteristics even though the concentrations of the trace elements are relatively low. Cobalt, Ni, As and Se substitutes Fe and S in pyrite respectively while Cu, Zn, Sn Sb are mainly represented by chalcopyrite, sphalerite, cassiterite and stibnite inclusions enclosed in pyrite. Ni and Ag are rich in the pyrite from the stratabound mineralization. The results suggested that the trace element characteristic of pyrite can be used to: a) study the occurrence of trace element in pyrite; b) imply the chemical-physical conditions; c) trace the regional ore-forming substance and ore forming process. The stratabound mineralization is formed during the volcano eruption during the Devonian then and overprinted by the deep source material and multiple ore-forming fluids in the Yanshanian period. © 2018, Science Press. All right reserved.  相似文献   

6.
Fractal geostatistics are being applied to subsurface geological data as a way of predicting the spatial distribution of hydrocarbon reservoir properties. The fractal dimension is the controlling parameter in stochastic methods to produce random fields of porosity and permeability. Rescaled range (R/S)analysis has become a popular way of estimating the fractal dimension, via determination of the Hurst exponent (H). A systematic investigation has been undertaken of the bias to be expected due to a range of factors commonly inherent in borehole data, particularly downhole wireline logs. The results are integrated with a review of previous work in this area. Small datasets. overlapping samples, drift and nonstationariry of means can produce a very large bias, and convergence of estimates of H around 0.85–0.90 regardless of original fractal dimension. Nonstationarity can also account for H>1, which has been reported in the literature but which is theoretically impossible for fractal time series. These results call into question the validity of fractal stochastic models built using fractal dimensions estimated with the R/Smethod.  相似文献   

7.
Sedimentary pyrites in black shales contain abundant trace elements that provide information on the chemistry of the seawater at the time of sedimentation. This study focuses on the Barney Creek Formation (~ 1640 Ma) in the McArthur Basin in the Northern Territory of Australia, which is host to one of the world's largest SEDEX Zn-Pb-Ag deposits, and several smaller deposits. Fine-grained sedimentary pyrite has been sampled from three drill holes through the Barney Creek Formation at various distances from SEDEX mineralisation. Samples were selected through the stratigraphy of each hole and analysed by LA-ICPMS for a suite of 14 trace elements. The data show that sedimentary pyrite at the base of the Barney Creek Formation, closest (within 1 km) to SEDEX mineralisation, is strongly enriched in Zn and Tl by one to two orders of magnitude compared to the global average for sedimentary pyrite. In contrast sedimentary pyrite from the hole furthest from SEDEX mineralisation (~ 60 km) contains mean Zn and Tl values equal to, or less than, the global average. Based on the three drill hole pyrite data sets it is concluded that trace elements that are contributed to the basin during hydrothermal exhalation, and adsorbed into contemporaneous sedimentary pyrite, are principally Zn, Tl, Cu, Pb, Ag and As. In contrast, trace elements that are adsorbed into sedimentary pyrite from background seawater are principally Mo, Ni, Co, Se and As. These differences have enabled the development of a SEDEX fertility diagram for sedimentary basins, based on the composition of sedimentary pyrite, that distinguish high Zn, but barren shales, from high zinc SEDEX-related shales. In parallel with the increase in Zn and Tl in sedimentary pyrite approaching mineralisation there is a decrease in Ni, Co and Mo. This means that the ratios Zn/Ni and Tl/Co are particularly good pyrite vectors to SEDEX mineralisation in the McArthur Basin, varying over 4 to 6 orders of magnitude from barren shales to mineralised shales. It is speculated that the reason for the reverse relationship between Ni, Co and Zn, Tl may be caused by hydrothermal exhalations into the water column that effect the ion-exchange pyrite surface complexation processes that alter the uptake of these elements into sedimentary pyrite.Another important conclusion of this study is that hydrothermal exhalations into a sedimentary basin may affect the redox sensitive trace element chemistry of sedimentary pyrite and therefore the trace element chemistry of pyritic black shales. Nickel, Co and Mo all decrease in proximity to hydrothermal vents that form SEDEX deposits, whereas Zn, Tl and Pb increase. Selenium and bismuth are the only redox sensitive trace elements that appear to be unaffected by hydrothermal activity in the McArthur Basin. This has implications on how trace element concentrations of black shales and pyrite are used to reflect past global ocean chemistry.  相似文献   

8.
Various methods have been used to secure the certainty of significant relations among the sunspot cycles and some of the terrestrial climate parameters such as temperature, rainfall, and ENSO. This study investigates the behavior of ENSO cycles and mean monthly sunspot cycles. Sunspot cycles range from 1755 to 2016 whereas, ENSO cycles range from 1866 to 2012. In this regard, the appropriateness of distributions is investigated with the help of Kolmogorov-Smirnov D, Anderson-Darling, and chi-square tests. It is found that most of the sunspot cycle follows generalized Pareto distribution whereas, generalized extreme value distribution was found appropriate for ENSO cycles. Probability distribution is used to analyze the behavior of each sunspot cycle and ENSO cycle separately. Probability distribution indicates the tail behavior of each cycle; tail explored correlation cycles. Furthermore, self-similar and self-affine fractal dimension methods are used to compute Hurst exponents to determine the persistency of the available data. Fractal dimension has an ability to study the complexity involved in sunspot and ENSO cycles. The fractal dimension and Hurst exponent describe persistency (smoothness) and complexity of data. Hurst exponent measures long-term behavior of time series, making it more helpful for forecasting. This is the measure of regularity or irregularity (chaos) of the time function in the form of their persistency or anti-persistency, respectively. Hurst exponents are computed using rescaled range analysis method and box counting methods. Both these methods are suitable for long-term forecasting. The results of this study confirm that during the period 1980–2000, ENSO cycles were very active. Simultaneously, ENSO was active for the periods 1982–1983, 1986–1987, 1991–1993, 1994–1995, and 1997–1998; these periods include two strongest periods of the century viz., 1982–1983 and 1997–1998. Sunspot cycles and ENSO cycles both were found to be persistent. Self-similar fractal dimensions exhibited a better persistency and a better correlation as compared to self-affine fractal dimension. This research is a part of a larger research project investigating the correlation of sunspot cycles and ENSO cycles, and the influence of ENSO cycles on variations of the local climatic parameters which in turn depends on solar activity changes.  相似文献   

9.
滇西红牛矽卡岩型铜矿床石榴子石特征   总被引:13,自引:7,他引:6  
高雪  邓军  孟健寅  闫寒  李建新  杨春海  孙诺  魏超 《岩石学报》2014,30(9):2695-2708
红牛矽卡岩型铜矿床是义敦岛弧南段格咱火山-岩浆弧新探明的铜矿床之一,目前探明铜金属资源量已达大型规模。与由侵入岩和大理岩直接接触形成的典型矽卡岩矿床不同,红牛铜矿床是隐伏岩体远程矽卡岩化的产物,其矽卡岩矿体与地层产状基本一致,通常相间排列,且距离岩体较远,大理岩中可见粗粒石榴子石和硅灰石,矽卡岩中常见大理岩捕掳体。根据矽卡岩矿物组合可将该矿床矽卡岩类型划分为石榴子石矽卡岩、石榴子石透辉石(或透辉石石榴子石)矽卡岩、透辉石矽卡岩、符山石-石榴子石矽卡岩、硅灰石-石榴子石矽卡岩、绿帘石-石榴子石矽卡岩、阳起石-绿帘石矽卡岩、硅灰石矽卡岩和绿帘石矽卡岩,其中以石榴子石矽卡岩、透辉石矽卡岩和硅灰石矽卡岩为主。石榴子石是最重要的矽卡岩矿物,分布广泛、颜色变化大,且石榴子石矽卡岩中黄铜矿、黄铁矿、磁黄铁矿化最好。本文通过对0ZK10、3ZK11和7ZK16钻孔岩芯的地质编录,查明石榴子石在红牛铜矿床的空间分布和矿化特征,采集该矿区新鲜的石榴子石矽卡岩、矽卡岩化大理岩和角岩磨制成光薄片,开展详细的显微镜下鉴定工作,观察石榴子石的颜色、粒度、结构、光性等岩相学特征,并通过电子探针分析其化学成分。红牛铜矿床石榴子石集中产出于矽卡岩中,少量产出于矽卡岩化大理岩和角岩中,具有明显的两期。早期石榴子石分布广泛,多呈褐色-红褐色,非均质性,异常干涉色,粒径一般在0.2~4mm之间,半自形-自形中细粒结构,韵律环带发育。SiO2含量变化范围为35.18%~37.69%、CaO为33.34%~36.35%、Al2O3为3.64%~13.69%、FeO为11.90%~24.18%、MgO为0.00%~0.08%,FeO和Al2O3含量变化呈负相关,SiO2和CaO含量变化整体呈正相关。石榴子石端员组分总体以钙铁榴石(36.88%~82.36%)为主,其次为钙铝榴石(16.59%~60.75%),还有少量的镁铝榴石、铁铝榴石和锰铝榴石,属于钙铁榴石-钙铝榴石系列(And37-82Gro17-61Spe+Pyr+Alm0.33-3.71)。晚期石榴子石呈浅褐色-浅红色,多发育于矽卡岩化角岩和大理岩中,少量发育于矽卡岩中,半自形-他形粒状结构,均质性,全消光,常具有溶蚀结构。SiO2含量变化范围为35.06%~36.27%、CaO为33.07%~33.77%、Al2O3为0.04%~1.05%、FeO为27.38%~28.18%、MgO为0.00%~0.04%,属于钙铁榴石(94.42%~98.46%)。早期石榴子石韵律环带发育,其主量元素含量变化显示出一定的规律性,由核部向边缘,SiO2和CaO基本保持不变,FeO含量增加,Al2O3含量减少,钙铁榴石含量增加,钙铝榴石含量减少,反映在石榴子石形成早期,成岩环境为低氧逸度、酸性还原环境;形成过程中氧逸度增加,成矿溶液由酸性向弱碱性演化。黄铜矿、磁黄铁矿、辉钼矿等金属硫化物多呈他形充填于石榴子石颗粒之间,或在石榴子石的裂隙中形成细脉,或沿石榴子石生长环带面交代,表明石榴子石形成于矽卡岩早期、早于铜矿化,并为金属硫化物的沉淀富集提供了空间。  相似文献   

10.
元素品位分布的相依性指标——赫斯特指数(Hurst指数)是矿体分布稳定性的动力学控制参量,重标极差(R/S)分析是相依性分析的有效方法。利用R/S分析对胶东大尹格庄金矿黄铁绢英岩内不同勘探线金元素品位系列的Hurst指数计算发现,Hurst指数主要介于0.59至0.89之间,均值为0.75,标准差为0.09,均大于随机行走经验Hurst指数的均值与标准差;计算结果说明元素品位分布存在正相关性,但由于受多种因素影响,其空间分布的相依性具有一定波动。元素品位分布的正相依性显示在特定的地质背景内,矿体连续分布或者间断出现,发育相对稳定,其与大尹格庄金矿的地质事实相吻合。  相似文献   

11.
大冶铁矿田铁山矿区三维地质体建模及深部成矿预测   总被引:2,自引:1,他引:1  
祝嵩  肖克炎 《矿床地质》2015,34(4):814-827
利用三维地质体建模软件Minexplorer建立了湖北大冶铁矿田铁山矿区矽卡岩矿体的三维地质模型,并对其进行了深部成矿预测。通过收集钻孔数据,建立地质数据库,生成三维钻孔;通过剖面定义、单工程矿体圈定、剖面编辑、曲面连接、封装成体建立矿体三维模型,获得铁山矿区三维地形-地质模型。该模型显示,铁山矿体呈NWW向展布,应沿该方向部署找矿;黑云母辉石闪长岩呈S形接触的转折部位是成矿的有利位置。矿体与航磁异常复合关系表明,5号矿体下方存在巨大找矿潜力,狮子山-尖山是下一步找矿勘探的重点方向。2号矿体与地层复合关系表明,铁矿体主要赋存于闪长岩上方和大理岩下方,因此,沿闪长岩和大理岩往下延伸可以寻找铁矿体。2号矿体主成矿元素Fe含量具有随深度增加而逐渐降低的变化趋势,显示矿化强度由浅部到深部逐渐减弱的变化特点,暗示2号矿体在-700 m深部以下的找矿潜力较小。三维控矿构造界面的凹兜部位和平缓部位是找矿的有利位置。  相似文献   

12.
新田岭矿床是南岭钨锡成矿带中的一个大型矽卡岩型钨矿床,产于骑田岭岩体东北部与石炭系碳酸盐地层的接触带位置。本文运用LA-ICP-MS技术对该矿床矽卡岩中的石榴子石进行了系统的成分分析,获得了其主量、微量和稀土元素含量。结果显示,新田岭矿床中的石榴子石属于钙铁榴石-钙铝榴石固溶体系列(And24Gro66 -And71Gro22),石榴子石的端元成分在富钙铝榴石和富钙铁榴石之间变化。稀土元素的配分模式也同时出现了左倾、Eu负异常和右倾、Eu正异常两种类型,暗示新田岭矿床石榴子石结晶过程中热液流体存在不同的氧化还原环境和水/岩比条件,这也与其晶体中是否出现振荡环带相对应。将不同矽卡岩型矿床中石榴子石的W、Sn含量进行对比显示,含W矿化的矽卡岩型矿床中石榴子石的W、Sn含量整体上显著高于不含W矿化的矿床,指示石榴子石中的W、Sn含量在一定程度上具有预测矽卡岩型矿床成W矿潜力的作用。此外,石榴子石中Fe、Eu、U等元素的含量还可以进一步区分矽卡岩W矿床中的伴生金属元素类型(包括W-Mo、W-Sn、W-Cu-...  相似文献   

13.
《China Geology》2018,1(1):36-48
The Truong Son Fold Belt, located at the northeastern margin of the Indochina Block, is considered to be tectonically linked to the subduction of the Paleotethys Ocean and subsequent collision. Sepon is one of the most important super large deposits of the Truong Son Fold Belt. Our LA-ICP-MS zircon U-Pb dating results show that granodiorite porphyry samples from the Sepon deposit have ages of 302.1±2.9 Ma, which is a crucial phase for magmatic-tectonical activities from the Late Carboniferous to Early Permian and has avital influence on the mineralization of copper and gold. Zircon from granodiorite porphyry yields εHf (t) values of 4.32 to 9.64, and TDM2 has an average age of 914 Ma, suggesting that the source of the granodiorite porphyry in the region were mainly mantle components but underwent mixing and contamination of crust materials. The Ce4+/Ce3+ value of zircon in the granodiorite porphyry varys greatly from 2.4 to 1438.29, which shows magma mixing might occur. Considering the characteristics of trace elements in the zircon and the whole rock geochemical characteristics of intrusion rocks as well as the characteristics of regional volcanic-sedimentary association, it is indicated that the tectonic setting may be the continental arc environment. The Sepon Au-Cu deposit is derived from emplacement of calc-alkaline intermediate-acid magma with coming from deep sources in the subduction process of the Paleotethys Ocean, forming porphyry Mo-Cu, skarn Cu-Au mineralization and a hydrothermal sedimentary-hosted Au mineralization in the wall rocks.  相似文献   

14.
Abstract. Medium‐ and large‐scaled skarn Cu‐Au±Mo deposits, e.g. Kelu, Liebu, Chongmuda and Chenba among others, are distributed in Shannan area of the Gangdese Cu‐Au metallogenic belt. Intrusions‐related skarn copper mineralization belongs to high K and calc‐alkaline rock series, located in late collision volcano‐magmatic arc and formed between 20 to 30 Ma. Copper mineralization occurs at exocontact zone of the lower Cretaceous Bima Group carbonate and other calcareous‐bearing sedimentary rocks with intrusions. At present, three main mineralization types are identified, including skarn type, hydrothermal vein type and porphyry type. Mineralizing associations are Cu‐Mo, Cu‐Au and Cu. In ore districts, those mineralization types form an entire porphyry‐skarn Cu‐Au±Mo ore‐forming system. Alterations of the exocontact are mainly skarnization and hornfelsization, while the alterations of the endocontact are mainly sericitization, silicification, and chloritization of intrusion. In the study area, the endoskarn is not well developed. Copper mineralization occurs mainly in the exocontact in the form of stratoid, lenticular and pockety ore body. Veined mineralization can be seen in marblized and hornfelsed siltstone, being away from the contact zone. In the endocontact, the mineralization is mainly veinlet‐like and disseminated. In Shannan area, skarnization can be divided into early skarnization stage and late hydrous silicate stage. The early skarnization stage is featured by mainly andradite and grossular skarn, containing minor diopside, hedenbergite, magnetite and some copper minerals; and the late hydrous silicate stage is of replacement of garnet skarn by chlorite, epidote, quartz and calcite together with sulfides precipitation. The latter is the main stage of copper mineralization. Bornite is the dominant ore mineral associated with minor chalcopyrite and pyrite; and gold as well as silver are distributed in bornite and wittichenite. Results of microthermometry study of fluid inclusions in quartz of late hydrous silicate stage from different deposits show intermediate temperature and low to intermediate‐salinity features for all samples. The dominant inclusion type is composed of two phases, being about 4 to 15 % vapor and 85 to 96 % liquid at room temperature. Homogenization temperatures range from 232 to 335d?C. Salinities have been recorded between 4.2 and 15.5 wt% NaCl equivalent. Boiling fluid inclusions are not identified and it indicates that metal deposition mainly resulted from water‐rock reactions. The results of sulfur isotope analysis indicate that the sulfur isotope values (δ34S 1.29–1.68 %o) of the samples collected from skarns are similar with that from the endocontact (δ34S 1–1.75 %o). Both of them have very close sulfur isotope values (near δ34S 0 %o), which indicate the sulfur of both the skarn type and the porphyry type mineralization was from deep sources. Ages determined on biotite from ore‐bearing intermediate porphyries by Ar‐Ar methods range from 23.77±0.29 to 29.88±0.56 Ma, showing that skarn copper mineralization in the study area evidently is older than the porphyry Cu(‐Mo) mineralization in Gangdese, and likely representing another metallogenic event. The Cu‐Au skarn deposits in the Kelu‐Liebu‐Chongmuda belt are interpreted as the shallow level, skarn‐related deposits in a porphyry‐skarn mineralization. Appearance of porphyry copper mineralization in some skarn deposits implies that skarn copper mineralization of the study area resemble to those in northern sub‐metallogenic belt, having uniform porphyry‐skarn ore‐forming system. Therefore, it is presumed there should be potential to find deep level porphyry‐type Cu‐Au mineralization targets.  相似文献   

15.
16.
新疆东天山白山钼矿深部岩体地球化学特征及成因意义   总被引:2,自引:2,他引:0  
白山钼矿深部钻探表明矿体下部存在着矿化花岗斑岩体,所获岩芯显示其岩性主要为似斑状钾长花岗岩、黑云母斜长花岗岩和花岗斑岩.该岩体具有高Al、Na和Sr,低Mg、Y和Yb,以及高Sr/Y和La/Yb比值等特点,类似于埃达克质岩的地球化学特征,暗示来源于较深的含石榴子石的源区;岩石形成时代和地球化学构造判别图解表明,岩体形成于造山后的构造环境.因此,白山钼矿岩体可能为加厚下地壳熔融的产物.白山钼矿床的成矿作用可能与埃达克质岩浆活动有关,其成矿过程得益于高Mo丰度的地壳源区、成岩过程中提供流体和岩浆高氧逸度环境等.  相似文献   

17.
万丽  刘欢  杨林  朱永强 《岩石学报》2015,31(11):3455-3465
成矿元素含量的变化受控于成矿系统内部的动力学过程,具有较强的随机性与混沌特征,对其变化特征的定量刻画有助于深入理解成矿过程,并为找矿预测提供理论依据。本文以三江普朗斑岩型铜矿的Cu元素与胶东大尹格庄构造蚀变岩型金矿的Au元素品位序列为研究对象,运用混沌时间序列分析法中的相空间重构技术、吸引子的关联维及最大Lyapunov指数解析了Cu与Au元素品位序列的分布特征。结果显示:斑岩型铜矿强矿化和中矿化Cu元素品位的饱和关联维介于4.42与9.69之间,饱和嵌入维介于25与28之间,最大Lyapunov指数介于0.0021与0.0661之间,弱矿化勘探线Cu元素关联维没有出现饱和现象,最大Lyapunov指数随着嵌入维的增大,由正数变为负数;构造蚀变岩型金矿的强矿化勘探线Au元素的关联维为3.18,饱和嵌入维为23,最大Lyapunov指数为0.0082,而中矿化和弱矿化勘探线Au元素的关联维没有出现饱和现象,且随着嵌入维的增大,最大Lyapunov指数由正数变为负数,表明斑岩型中-强矿化地区的Cu元素和构造蚀变岩型强矿化区域的Au元素品位序列具有混沌动力学特征,而弱矿化地区的Cu元素及中弱矿化地区的Au元素品位序列则具有更强的随机性特征;同时,具有混沌特征的斑岩型铜矿的饱和嵌入维和关联维及最大Lyapunov指数的均值都大于蚀变岩型矿床,说明斑岩型铜矿比蚀变岩型矿床的元素具有更强混沌特性与更复杂的控制因素,如温度、硫化作用、流体不混溶、蚀变叠加等。  相似文献   

18.
The study of the mineralogical and geochemical features of ores and their textural and structural relationships at the Nikolaevsky base-metal skarn deposit allowed us to establish the succession of mineral assemblages and to ascertain the complex distribution of elements in minerals, ores, and orebodies resulting from nonuniform development of metasomatic zones in the single ore-metasomatic process. The vertical mineralogical and geochemical zoning of the deposit is expressed in the replacement of economic Pb-Zn mineralization at the lower levels of the skarn orebodies with Ag-Pb-Zn mineralization at the upper levels of the major Vostok-1 orebody located at the contact of limestone and felsic volcanics and the block orebodies at the lower level of felsic volcanic rocks. Au-bearing vein Pb-Ag-Sb mineralization occurs in the near-surface zone of the deposit. Three mineralogical types of ores have been identified: sulfide-hedenbergite, quartz-carbonate-sulfide, and sulfide. The zonal distribution of these types within orebodies is combined with variations in mineralogy and in the distribution of major and minor elements. The statistical processing (the Geokhimiya-1 program) of 96 chemical analyses of monomineralic galena and sphalerite samples taken from skarn showed that an intimate Pb ? Bi assemblage is characteristic of the lower levels, whereas a Ag Bi assemblage is typical of the upper levels. The elemental assemblages correspond to definite mineral assemblages, determining the mineralogical and geochemical zoning of the deposit.  相似文献   

19.
The paper presents pioneering data on the composition, texture, and crystal structure of molybdenite from various types of molybdenum mineralization at the Bystrinsky Cu–Au–Fe porphyry–skarn deposit in the eastern Transbaikal region, Russia. The data were obtained using electron microprobe analysis (EMPA), laser ablation–inductively coupled plasma mass spectrometry (LA-ICP-MS), and high-resolution transmission electron microscopy (HRTEM). Molybdenite found at the deposit in skarn, sulfide-poor quartz veins, and quartz–feldspar alteration markedly differs in the concentrations of trace elements determined by their species in the mineral, as well as in its structural features. Molybdenite-2H from skarn associated with phyllosilicates occurs as ultrafine crystals with uniform shape and texture; no dislocations or inclusions were found but amorphous silica was. The molybdenite composition is highly contrasting in the content and distribution of both structure-related (Re, W, and Se) and other (Mn, Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Te, Ag, Pd, Au, Hg, Pb, and Bi) metals. In the sulfide-poor quartz veins, highly structurally heterogeneous (2H + 3R) molybdenite microcrystals with abundant defects (dislocations and volumetrically distributed inclusions) are associated with illite, goethite, and barite. Some single crystals are unique three-phase (2H + 3R polytypes + amorphous MoS2). The mineral has a low concentration of all trace elements, which are uniformly distributed. However, individual domains with uniquely high Pd, Te, Ni, Hg, and W concentrations caused by mineral inclusions are found in some grains. Molybdenite from quartz–feldspar alteration is characterized by low concentrations of all trace elements except for Re and Se, which enrich some domains of the grains. Our data indicate that the compositional and structural heterogeneity of molybdenite from the Bystrinsky deposit are its crucial features, which obviously correlate with the types of Mo mineralization.  相似文献   

20.
Time series analysis (autocorrelation, cross correlation, spectral analysis)is used to reconstruct tectonic structures from geochemical drill hole log data. After segmentation of a log one obtains typical patterns of significant correlations by cross correlation analysis. These patterns can be included in a “log-segment-correlation matrix” (LSCM)and are interpreted as repetitions caused by fractures or as folds extending over one or more segments. Smaller tectonic structures can be detected by spectral analysis. Examples are given from Pb-Zn exploration drill holes in the Paleozoic of Graz (Austria).  相似文献   

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