共查询到18条相似文献，搜索用时 632 毫秒
1.
充分认识元素和同位素在不同环境条件下的地球化学行为,是运用元素和同位素示 踪环境变化的前提。对来自于黄土高原的黄土、古土壤和红粘土样品的宇宙成因核素10Be测量和化学成分分析,以及各种化学淋溶实验表明：10Be主要以吸附状态赋存于粉尘沉积物粘粒矿物的表面,部分已结合进自生的粘土矿物中;在粉尘沉积物风化过程中10Be与9Be和～的活动性相似,基本没有发生迁移,其原因是连续沉积的粉尘含有大量的碱性物质,阻止了…Be的解吸附和淋滤;沉积和风化作用导致了10Be浓度与化学指标在黄土-古土壤和红粘土剖面中的协同变化。 相似文献
2.
DSDP519钻孔10Be测定结果表明，在B／M，M／G两地磁极性倒转期间，10Be产生率均约增加20％。DSDP519孔δ10Be曲线与DSDP502孔δ18O曲线具有明显的正相关关系。CT85－5钻孔10Be曲线在34000±3000aB．P存在明显的峰，峰值比正常值高出2．5倍，9Be，Zn变化曲线中均未观察到此峰，与Vostok冰芯10Be峰在时间上属于同期。这进一步说明了此时期内10Be浓度增加是全球性的，只能归因于10Be产生率的增加。Raisbeck峰讯号可以成为某些储存库精确时标。 相似文献
3.
4.
暴露测年样品中26Al和10Be分离及其加速器质谱测定 总被引：4，自引：4，他引：0
在已有实验流程基础上,建立并优化了石英样品中Be和Al提取、纯化等实验流程,设计的流程条件实验包括实验试剂、器皿和离子交换柱选择、离子交换树脂分离Be和Al时酸浓度选择等。结果表明,选择钢铁研究总院研制的9Be标准溶液作为10Be样品制备的载体;使用一次性实验器皿;选用4 cm规格的离子交换柱;用0.05 mol/L草酸和0.75 mol/L盐酸混合溶液洗脱吸附于阴离子树脂上的Al,可有效提取、纯化样品中的Be和Al。加速器质谱(AMS)测量结果显示,13组化学空白的10Be/9Be和26Al/27Al比值平均值分别为7.48×10-15和1.96×10-15,与国内已有宇宙成因核素实验室的结果(5×10-15~8×10-15)具有可比性。电感耦合等离子体发射光谱(ICP-AES)的测量结果表明,Be、Al回收率分别达90%和60%。基于新建立的实验流程分析了祁连山北侧金佛寺的一个岩石样品,获得了10Be和26Al的暴露年代分别为(10.7±1.0) ka和(10.0±1.2) ka,与前人研究结果一致。 相似文献
5.
6.
主要讨论宇宙射线成因核素10Be（T 1/2＝ 1．5Ma）在大洋边缘海洋学尤其是中国近海海洋研究中的应用。在过去的近20年中，在中国开展的10Be研究在黄土堆积年龄及地层对比方面获得了诸多成果，但在海洋方面的应用研究距国际水平仍有一定的差距，尚需进一步加强。综述了海洋环境中10Be作为一个地球化学示踪剂的研究现状，着重介绍10Be在中国东部海域的收支平衡模式以及讨论10Be在太平洋西部边缘海及岛弧地区的应用前景。 相似文献
7.
柴北缘锡铁山榴辉岩退变质成因角闪石40Ar/39Ar年代学研究 总被引：2，自引：2，他引：0
采用激光阶段加热40Ar/39Ar技术,对柴达木盆地北缘锡铁山榴辉岩退变质作用形成的榴闪岩和斜长角闪岩之角闪石进行了定年分析。09NQ44Amp来自榴闪岩,各阶段表观年龄(以现代空气氩40Ar/36Ar比值295.5扣除非放射性成因40Ar)构成了单调下降的阶梯状年龄谱。在反等时线图解上,2~4阶段数据点和5~18阶段数据点分别构成了两条等时线,等时年龄分别为427.6±10Ma和425.1±2.6Ma,对应的初始40Ar/36Ar比值则分别为435.2±6.1和705.3±13。角闪石09NQ43Amp来自榴辉岩强烈退变质作用形成的斜长角闪岩,40Ar/39Ar阶段加热分析也获得单调下降的年龄谱,在反等时线图解上其数据点3~6阶段和7~16阶段分别构成了两条等时线,等时年龄分别为418.9±2.9Ma和418.1±2.1Ma,对应的初始40Ar/36Ar比值则分别为493.7±2.8和685.8±34.3。等时线截距值高于现代大气40Ar/36Ar比值,表明角闪石中含过剩40Ar。同时,由低温和中-高温阶段加热数据点分别构成两条等时年龄基本一致,截距值却明显不同的等时线,表明在角闪石热力学性质不同的源区,存在两期明显不同且未混合的初始捕获Ar组分。等时年龄425~418Ma代表的是锡铁山榴辉岩角闪岩相退变质作用发生的时间。等时线图解法虽然有效的校正了角闪石中的过剩40Ar,但仅根据表观年龄图谱和等时线图谱还无法清晰判断过剩40Ar在角闪石中的赋存状态,有待进一步探讨。 相似文献
8.
西藏波龙斑岩铜金矿床钾长石和绢云母40Ar/39Ar年龄及其地质意义 总被引：5，自引：1，他引：4
西藏波龙斑岩铜金矿床是新近在青藏高原中部发现的规模最大的斑岩型矿床。文章对该矿床内的蚀变钾长石和蚀变绢云母进行了40Ar/39Ar年代学测试,获得蚀变钾长石的40Ar/39Ar坪年龄为(118.33±0.60) Ma,反等时线年龄为(118.49±0.74) Ma (初始40Ar/36Ar=286.1±8.4),表明波龙斑岩铜金矿床的钾化蚀变年龄为118~119 Ma;蚀变绢云母的40Ar/39Ar坪年龄为(121.61±0.67) Ma,反等时线年龄为(121.1±2.0) Ma (初始40Ar/36Ar=279±19)。由于蚀变绢云母测试样品内可能混入了斜长石,受其影响,蚀变绢云母测年结果的下限可能代表了该矿床绢英岩化蚀变年龄。这些蚀变钾长石和蚀变绢云母40Ar/39Ar测年结果与波龙矿床的成岩年龄值和成矿年龄值在误差范围内基本一致,表明该矿床的钾化和绢英岩化与成岩、成矿同期,该矿床的岩浆-热液活动过程的时限为121~118 Ma。 相似文献
9.
内蒙古大青山逆冲推覆体系中生代逆冲构造活动的40Ar-39Ar定年 总被引：3，自引：2，他引：1
内蒙古大青山呼和浩特段北侧发育3条走向北东东、指向北西的逆冲断层,并与被其分割的3个逆冲席体及一个原地系构成大青山逆冲推覆体系。逆冲断层上盘底部发育较深层次的糜棱岩,下盘顶部多发育低温的千糜岩。本研究在构造地质调查基础上,结合宏-微观岩石矿物学分析,采用40Ar-39Ar定年对该逆冲体系的活动时间进行约束。逆冲断层带内3个千糜岩绢云母40Ar-39Ar年龄范围为120~119Ma,另一样品给出了120Ma的概率统计峰值年龄。千糜岩为低温同变形变质产物,细粒绢云母为同变形新生矿物,其40Ar-39Ar年龄可代表变形年龄。侵位在断层内弱变形的花岗闪长岩为同构造晚期侵位,角闪石40Ar-39Ar年龄限定其冷却时间下限为121Ma,概率统计峰值年龄为119Ma。逆冲断层上盘底部发育较高温的糜棱岩,而低温千糜岩的形成时间应属于变形后期。因此,120Ma至119Ma期间,大青山逆冲推覆体系的逆冲作用应已是处于变形晚期。 相似文献
10.
宗务隆构造带南侧的成矿环境与"马尔康-雅江-喀喇昆仑巨型锂矿带"具有很大的相似性,新发现的茶卡北山伟晶岩型锂多金属矿床证实此带是青藏高原北部的一条重要的锂、铍矿成矿带,该矿床内含矿伟晶岩主要为含锂辉石花岗伟晶岩和含绿柱石白云母花岗伟晶岩,形成于晚三叠世。对含矿白云母伟晶岩进行白云母40Ar-39Ar同位素测年结果显示,随着温度从750 ℃逐渐升到1100 ℃,白云母40Ar-39Ar年龄坪非常平坦,其年龄值为210.4 Ma—212.7 Ma,坪年龄为212.60 Ma±0.64 Ma,与晚期伟晶岩结晶年龄相近,基本限定茶卡北山伟晶岩型锂稀有多金属矿床的成矿年龄为晚三叠世晚期。 相似文献
11.
《Geochimica et cosmochimica acta》1996,60(1):109-119
We report the development of a NaOH-leaching technique to extract the authigenic Al and Be in marine sediments, which should allow the sedimentary signals of cosmogenic 26Al and 10Be to be more effectively studied as geochemical/geophysical tracers. The technique has been applied to the study of 26Al and 10Be in opal-rich sediments from the North Pacific. The 26Al/27Al and 10Be/9Be ratios of ~3 × 10−14 and 1 × 10−7 leached from the sediments are higher than those in the total sediments by factors of 3–10 and 2–3, respectively. The authigenic 10Be/9Be ratios are similar to those in deep waters at the study site, pointing to the potential usefulness of the ratios in paleoceanographic studies. The fractions of total Be and Al in the sediment studied that are of authigenic origin average about 40 and 17%, respectively. Estimated 26AL/27A1 ratios in detrital sediments are ≤ 10−15, low enough to indicate that the source of 26Al in the ocean mainly comes from atmospheric production. In the study area, the deposition flux of 26Al is comparable to its atmospheric supply. However, the deposition flux of 10Be is about threefold higher than the atmospheric input, signifying lateral transport of 10Be from the open ocean to this area of relatively high particle flux. The 26Al/10Be ratio, being insensitive to the oceanic influx of lithogenic particles, may serve as a valuable proxy for paleoproductivity. Both the authigenic and total-sediment 26Al/27Al and 10Be/ 9Be ratios decreased significantly at ~6 ka, which could reflect an enhanced input of windblown lithogenic particles to the North Pacific. While the enhanced dust input did not significantly alter the deep-water 9Be concentration, it contributed to the observed increase of authigenic 9Be flux to the sediment. 相似文献
12.
We have found clear evidence of live 10Be in five normal Type A Calcium-aluminum-rich inclusions (CAIs), one normal Type B CAI, and one FUN Type A CAI, all from CV3 chondrites. The (10Be/9Be)0 ratios range from ∼0.36 × 10-3 to ∼0.77 × 10-3 and are similar to those found by previous workers. The (10Be/9Be)0 ratios do not correlate in a temporal fashion with (26Al/27Al)0, suggesting that 10Be and 26Al were produced by different mechanisms. An examination of possible sources for the short-lived radionuclides indicates that production of 10Be was almost certainly by particle irradiation, possibly within the solar system, and was probably accompanied by significant production of 41Ca and 53Mn. In contrast, all of the 60Fe, most of the 26Al, and some of the 53Mn were probably produced in stars and were imported into the solar system within presolar dust grains. 相似文献
13.
充分认识元素和同位素在不同环境条件下的地球化学行为,是运用元素和同位素示踪环境变化的前提。对来自于黄土高原的黄土、古土壤和红粘土样品的宇宙成因核素10Be测量和化学成分分析,以及各种化学淋溶实验表明：10Be主要以吸附状态赋存于粉尘沉积物粘粒矿物的表面,部分已结合进自生的粘土矿物中;在粉尘沉积物风化过程中10BC与9Be和Al的活动性相似,基本没有发生迁移,其原因是连续沉积的粉尘含有大量的碱性物质,阻止了10Be的解吸附和淋滤;沉积和风化作用导致了10Be浓度与化学指标在黄土－古土壤和红粘土剖面中的协同变化。 相似文献
14.
沉积物的化学成分无疑取决于来源物质的成分和沉积后的化学作用。对来自于甘肃灵台7MaBP以来风成沉积序列的红粘土、黄土和古土壤样品的化学分析表明,风成沉积物化学成分的演化主要由沉积前所经历的各种地表作用(尤其是风化作用)所决定,当地成壤作用对化学成分的影响叠加在106a演化趋势上5反映风化程度的化学指标Na／Al值和Fe2+／Fe3+值总体均呈逐步增加的趋势,基本一致于上新世以来全球气候变化的趋势,这可能与青藏高原隆升和北半球冰盖发育加速粉尘物质源区侵蚀同时降低化学风化程度有关。 相似文献
15.
B. L. K. Somayajulu 《Journal of Earth System Science》1996,105(4):357-364
An increase in the cosmogenic beryllium-10 content of the Orca basin sediments due to the flooding of the Gulf of Mexico (GM)
by meltwaters during the late Wisconsin interglacial is reported. A strong negative correlation (γ =-0.99) betweenδ
18
O (in the range o f-1.5‰ to +0.5‰) and10Be/Al ratio is seen. During intense flooding reflected by a decrease in δ18O by ∼ 2‰, this correlation may not hold as some of the sediments with low10Be/Al ratio and deposited on the shelf and slope regions of the GM during the earlier glacial period would also be washed
into the basin. The deposited sediment would then be a mixture with a10Be/Al ratio lower than expected from the correlation 相似文献
16.
Here, we provide evidence suggesting that marine (diatom) opal contains not only a high fidelity record of dissolved oceanic concentrations of cosmic ray-produced radionuclides, 10Be and 26Al, but also a record of temporal variations in a large number of trace elements such as Ti, Fe, Zn and Mn. This finding is derived from measurements in purified biogenic opal that can be separated from detrital materials using a newly developed technique based on surface charge characteristics. Initial results from a sediment core taken near the present-day position of the Antarctic Polar Front (ODP Site 1093) show dramatic changes in the intrinsic concentrations of, Be, Al, Ti, Fe, Mn and Zn in the opal assemblages during the past ∼140 kyr BP. The results imply appreciable climatically controlled fluctuations in the level of bioreactive trace elements. The time series of total Be, Al, Ti, Fe and 10Be in the sediment core are all well correlated with each other and with dust records in the polar ice cores. The observations suggest that a significant flux of these trace metals to oceans is contributed by the aeolian dust, in this case, presumably from the Patagonia. This observation also allows determination of fluxes of dust-contributed 10Be to the Antarctica ice sheets. However, our data show that the relationships among the various metals are not perfectly linear. During periods of higher dissolved concentrations of trace elements (indicated by Fe and Ti) the relative concentrations of bioreactive elements, Be, Al, Mn and Zn are decreased. By contrast, the Fe/Zn and Fe/Mn ratios decrease significantly during each transition from cold to warm periods. The relative behavior could be consistent with any of the following processes: (i) enhanced biological productivity due to greater supply of the bioreactive elements (e.g. Zn) during cold periods (ii) increased biological and inorganic scavenging of particle active elements (e.g. Be and Al) during early interglacial periods (iii) differential uptake/removal of the metals by the various diatom taxa whose relative productivity or growth rate changes with large scale climate. In any case, with one sedimentary phase and in single sedimentary sections, we now have the potential to compare directly a proxy for aeolian input of micronutrients (e.g. Fe or Ti), with a proxy for production (e.g. 26Al/Al ratios). We expect that studies of the temporal records of trace elements and cosmogenic nuclides in contrasting regions of upwelling and productivity, which exhibit different sensitivities to global climate fluctuations and micronutrient inputs, would lead to a direct and comprehensive test of ideas such as the hypothesis of iron control of atmospheric carbon dioxide [Martin, J.H., 1990. Glacial-interglacial CO2 change: the iron hypothesis. Paleoceanography5, 1-13]. Our present data from a single site do not show that increases in dissolved Fe concentrations, per se, were responsible for increased biological productivity. However, a much clearer picture of the effect of increased dust fluxes should emerge when we have data for trace elements and the cosmogenic nuclides, 10Be and 26Al from various oceanic provinces. 相似文献
17.
ANNE HORMES NAKI AKÇAR PETER W. KUBIK 《Boreas: An International Journal of Quaternary Research》2011,40(4):636-649
Hormes, A., Akçar, N. & Kubik, P. W. 2011: Cosmogenic radionuclide dating indicates ice‐sheet configuration during MIS 2 on Nordaustlandet, Svalbard. Boreas, 10.1111/j.1502‐3885.2011.00215.x. ISSN 0300‐9483.0300‐9843 Glacial geological field surveys, aerial image interpretation and cosmogenic radionuclide (CRN) dating allowed us to reconstruct the ice‐sheet configuration on Nordaustlandet, the northernmost island of the European sector on the margin of the Arctic Ocean. The timing of deglaciation was investigated by determining the 26Al and 10Be ages of glacially scoured bedrock, weathered periglacial blockfields and glacial erratic boulders. Only 10Be ages were useful for our interpretations, because of unresolved analytical problems with 26Al. Fjords and lowlands on Nordaustlandet yielded Late Weichselian 10Be ages, indicating that actively erosive ice streams scoured the coastal fjord bathymetry during marine isotope stage (MIS) 2. In Murchisonfjorden, ground‐truthed air‐photograph interpretation and 10Be ages of boulders indicated a cold‐based glacier ice cover during MIS 2 on higher plateaus. 10Be ages and lithological studies of erratic boulders on higher and interior plateaus of Prins Oscars Land (>200–230 m a.s.l.) suggest that the Mid‐Weichselian glaciation (MIS 4) might have been more extensive than that during MIS 2. 相似文献
18.
D. Lal 《Journal of Earth System Science》2000,109(1):181-186
The radionuclide10Be (half-life = 1.5my), produced naturally in the Earth’s atmosphere by nuclear interactions of cosmic rays, was sought in
ocean sediments in the late fifties, considering its potential usefulness as a radiotracer for dating sediments.10Be was discovered independently by two groups, one in India and the other in the USA, and used only for dating marine sediments
and manganese nodules until the seventies. Subsequently, as a result of a technical advance resulting in the improvement in
the sensitivity of measurement of10Be by about a factor of 106, there was a global rush to measure this nuclide in most materials participating in the physical, chemical and biological
processes in the dynamic geosphere. This paper outlines the reasons for this “isotope rush”, and the lessons learned from
these studies. I also present my personal views of the special attractive features of this nuclide on the one hand, and on
the other, the pitfalls or the wrong message this nuclide could convey! 相似文献