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1.

Well Yingnan 2, an important exploratory well in the east of Tarim Basin, yields high commercial oil and gas flow in Jurassic. Natural gas components and carbon isotopic composition indicate that it belongs to sapropel type gas. Because this region presents many suits of hydrocarbon source rocks, there are some controversies that natural gases were generated from kerogen gas or crude oil cracking gas at present. By using the kinetics of hydrocarbon generation and carbon isotope, natural gas of Well Yingnan 2 is composed mainly of crude oil cracking gas, about 72%, it is generated from secondary kerogen gas of Cambrian-Lower Ordovician source rock and crude oil cracking gas of Mid-Upper Ordovician oil reservoir. The main oil and gas filling time is 65 Ma later in the Jurassic gas reservoir of Well Yingnan 2, so the gas reservoir belongs to late accumulation and continuous filling type.

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2.
Well Yingnan 2, an important exploratory well in the east of Tarim Basin, yields high commercial oil and gas flow in Jurassic. Natural gas components and carbon isotopic composition indicate that it belongs to sapropel type gas. Because this region presents many suits of hydrocarbon source rocks, there are some controversies that natural gases were generated from kerogen gas or crude oil cracking gas at present. By using the kinetics of hydrocarbon generation and carbon isotope, natural gas of Well Yingnan 2 is composed mainly of crude oil cracking gas, about 72%, it is generated from secondary kerogen gas of Cambrian-Lower Ordovician source rock and crude oil cracking gas of Mid-Upper Ordovician oil reservoir. The main oil and gas filling time is 65 Ma later in the Jurassic gas reservoir of Well Yingnan 2, so the gas reservoir belongs to late accumulation and continuous filling type.  相似文献   

3.
Well Yingnan 2,an important exploratory well in the east of Tarim Basin,yields high commercial oil and gas flow in Jurassic.Natural gas components and carbon isotopic composition indicate that it belongs to sapropel type gas.Because this region presents many suits of hydrocarbon source rocks,there are some controversies that natural gases were generated from kerogen gas or crude oil cracking gas at present.By using the kinetics of hydrocarbon generation and carbon isotope,natural gas of Well Yingnan 2 is composed mainly of crude oil cracking gas,about 72%,it is generated from secondary kerogen gas of Cambrian-Lower Ordovician source rock and crude oil cracking gas of Mid-Upper Ordovician oil reservoir.The main oil and gas filling time is 65 Ma later in the Jurassic gas reservoir of Well Yingnan 2,so the gas reservoir belongs to late accumulation and continuous filling type.  相似文献   

4.

There exists a petroleum system rich of oil and gas around Halahatang depression, where the oil and gas possess obvious local distinctions of properties in different parts. The research proved that the discovered crude oil and natural gas in the region derived mainly from O2+3 source rock, and the differences of its properties were controlled by the oil and gas filling intensity. The comprehensive study result shows the oil and gas reservoirs of the region mainly underwent three important accumulation phases: late Caledonian-Early Hercynian epoch, late Hercynian epoch, and Yanshan-Himalayan epoch. In the first phase, the oil and gas derived mostly from Cambrian source rock, which formed the primary ancient oil reservoirs, then suffered strong degradation and remained a great quantity of pyrobitumen in the high position of Tabei uplift in the present. In the second phase, the O2+3 source rock of Manjia’er depression started its generation of hydrocarbon, which accumulated in the high position of Tabei up-lift afterwards, and then biodegradated to heavy oil in the late Hercynian epoch. In the last phase, the O2+3 source rock of southern Halahatang depression and margin of Manjia’er depression started its peak of generating liquid hydrocarbon, which mostly accumulated in the trap formed before the Indo-China and Yanshan epoch, and in somewhere the heavy oil suffered dilutions in various degrees or serious gas invading, to lead to obvious crude oil divergence.

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5.
There exists a petroleum system rich of oil and gas around Halahatang depression, where the oil and gas possess obvious local distinctions of properties in different parts. The research proved that the discovered crude oil and natural gas in the region derived mainly from O2+3 source rock, and the differences of its properties were controlled by the oil and gas filling intensity. The comprehensive study result shows the oil and gas reservoirs of the region mainly underwent three important accumulation phases: late Caledonian-Early Hercynian epoch, late Hercynian epoch, and Yanshan-Himalayan epoch. In the first phase, the oil and gas derived mostly from Cambrian source rock, which formed the primary ancient oil reservoirs, then suffered strong degradation and remained a great quantity of pyrobitumen in the high position of Tabei uplift in the present. In the second phase, the O2+3 source rock of Manjia’er depression started its generation of hydrocarbon, which accumulated in the high position of Tabei up-lift afterwards, and then biodegradated to heavy oil in the late Hercynian epoch. In the last phase, the O2+3 source rock of southern Halahatang depression and margin of Manjia’er depression started its peak of generating liquid hydrocarbon, which mostly accumulated in the trap formed before the Indo-China and Yanshan epoch, and in somewhere the heavy oil suffered dilutions in various degrees or serious gas invading, to lead to obvious crude oil divergence.  相似文献   

6.
Due to the complexity of geological background and the adverseness of natural geographical environment in the Qinghai-Tibet Plateau, it is very difficult to carry out petroleum geological study in this region. The Qinghai-Tibet Plateau is the only blank space of petroleum exploration on a large scale. The authors carried out the surface geochemical exploration of oil and gas in the Gangbatong-Ya’anxiang and Dongqiao-Nam Co of the Qinghai-Tibet region. Based on the data of actual detection and experiments in the studied area, the characteristics of concentration and profile distribution of the main geochemical exploration indicators (total adsorbed hydrocarbon, altered carbonate, thermal released mercury, etc.) were discussed. The origin of hydrocarbon was also discussed. Moreover, the oil and gas potential of different sections in the Qiangtang Basin and the Biru Basin were evaluated, which could provide references for the exploration and prediction of oil and gas in this region. The concentrations of total adsorbed hydrocarbons in the Ya’anxiang of Suoxian County-Zadong of Baqing County and the Jiecha-Dangxiong of Anduo County in the Qinghai-Tibet region are high, averaging 312.64 μL·kg?1 and 164.36 μL·kg?1. Their altered carbonate concentrations are relatively low, averaging 0.11% and 0.56%. Their concentrations of thermal released mercury are relatively high, averaging 13.09×10?9 and 1.94×10?9. Geochemical exploration results in fact reflect hydrocarbon information in the underground, which are mainly petroleum associated gas and over-matured cracking gas. The Jiecha-Charenluma and the Xiamaya’ertong-Suoba sections in the Qiangtang Basin are the most favorable ones for oil and gas and the Ekou-Zadong section is relatively favorable one, while the Nam Co and the Zigetangcuo-Dongqiao sections in the Biru Basin are the favorable ones for oil and gas, and the Jiang Co-Nading Co and the Ya’anxiang-Ya’ertong sections are relatively favorable ones.  相似文献   

7.
Organic-inorganic interaction exists universally and is important in the process of mineral resources formation.It is the essential reason why organic oil,gas,coal and inorganic uranium coexist,accumulate,and mineralize in the same sedimentary basins.Hydrocarbon-generating simulation experiment was conducted using low-mature hydrocarbon source rock containing kerogen type III with uranium(UO2CO3 solution)added to study the effects of uranium on the hydrocarbon generation of hydrocarbon source rocks.Experiment results show that uranium can enhance the yield of gas hydrocarbon,promote the total gas output,and increase the total hydrocarbon production(mass or volume).Uranium may lower the hydrocarbon generation threshold temperature and lead to the generation of liquid hydrocarbon in the relative low temperature of hydrocarbon source rock.Uranium can enhance the yield of saturated hydrocarbon,promote the low molecular weight hydrocarbons generating,and in turn increase the content of CH4 and the content of dry gas of the generated hydrocarbons.Uranium is one of the potential inorganic accelerating factors of the immature hydrocarbons.  相似文献   

8.
Gas formation mechanism of marine carbonate source rocks in China   总被引:5,自引:1,他引:4  
It has been proven in exploration practice that thecarbonates in China not only can generate hydrocar-bons, but also form commercial reservoirs. The car-bonates are different from clastic rocks in view of theirdeposition environment as well as their sedimentaryand diagenetic processes. Therefore, the evaluationcriteria and hydrocarbon generation mechanism forcarbonates can not be the same as that for clasticrocks, and it is important to establish a special hydro-carbon generation mechanism and…  相似文献   

9.

Due to the complexity of geological background and the adverseness of natural geographical environment in the Qinghai-Tibet Plateau, it is very difficult to carry out petroleum geological study in this region. The Qinghai-Tibet Plateau is the only blank space of petroleum exploration on a large scale. The authors carried out the surface geochemical exploration of oil and gas in the Gangbatong-Ya’anxiang and Dongqiao-Nam Co of the Qinghai-Tibet region. Based on the data of actual detection and experiments in the studied area, the characteristics of concentration and profile distribution of the main geochemical exploration indicators (total adsorbed hydrocarbon, altered carbonate, thermal released mercury, etc.) were discussed. The origin of hydrocarbon was also discussed. Moreover, the oil and gas potential of different sections in the Qiangtang Basin and the Biru Basin were evaluated, which could provide references for the exploration and prediction of oil and gas in this region. The concentrations of total adsorbed hydrocarbons in the Ya’anxiang of Suoxian County-Zadong of Baqing County and the Jiecha-Dangxiong of Anduo County in the Qinghai-Tibet region are high, averaging 312.64 μL·kg−1 and 164.36 μL·kg−1. Their altered carbonate concentrations are relatively low, averaging 0.11% and 0.56%. Their concentrations of thermal released mercury are relatively high, averaging 13.09×10−9 and 1.94×10−9. Geochemical exploration results in fact reflect hydrocarbon information in the underground, which are mainly petroleum associated gas and over-matured cracking gas. The Jiecha-Charenluma and the Xiamaya’ertong-Suoba sections in the Qiangtang Basin are the most favorable ones for oil and gas and the Ekou-Zadong section is relatively favorable one, while the Nam Co and the Zigetangcuo-Dongqiao sections in the Biru Basin are the favorable ones for oil and gas, and the Jiang Co-Nading Co and the Ya’anxiang-Ya’ertong sections are relatively favorable ones.

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10.
As a relatively stable craton block in the earth system, the petroliferous basin is influenced by the evolution of the earth system from the early development environment of source rocks, hydrocarbon formation, and reservoir dissolution to hydrocarbon accumulation or destruction. As a link between the internal and external factors of the basin, deep fluids run through the whole process of hydrocarbon formation and accumulation through organic-inorganic interaction. The nutrients carried by deep fluids promote the bloom of hydrocarbon-generating organisms and extra addition of carbon and hydrogen source, which are beneficial to the development of high-quality source rock and enhancement of the hydrocarbon generation potential. The energy carried by the deep fluid promotes the early maturation of the source rock and facilitates the hydrocarbon generation by activation and hydrogenation in high-mature hydrocarbon sources. The dissolution alteration of carbonate rocks and clastic reservoirs by CO_2-rich deep fluids improves the deep reservoir space, thus extending the oil and gas reservoir space into greater depth. The extraction of deeply retained crude oil by deep supercritical CO_2 and the displacement of CH_4 in shale have both improved the hydrocarbon fluidity in deep and tight reservoirs. Simultaneously, the energy and material carried by deep fluids(C, H, and catalytic substances) not only induce inorganic CH_4 formation by Fischer-Tropsch(F-T) synthesis and "hydrothermal petroleum" generation from organic matter by thermal activity but also cause the hydrothermal alteration of crude oil from organic sources. Therefore, from the perspective of the interaction of the earth's sphere, deep fluids not only input a significant amount of exogenous C and H into sedimentary basins but also improve the reservoir space for oil and gas, as well as their enrichment and accumulation efficiencies.  相似文献   

11.
Wang  ZhenQi  Zhi  DongMing  Zhang  ChangMin  Xue  XinKe  Zhang  ShangFeng  Li  TianMing  Yang  Fei  Liu  LouJun  Cheng  Liang  Lu  Dong  Zhou  FengJuan  Chen  YuanYong 《中国科学:地球科学(英文版)》2010,52(1):106-114

Well che89, located in the Chepaizi area in the northwest margin of Junggar basin, acquires high production industrial oil flow, which is an important breakthrough in the exploration of the south foreland slope area of Junggar basin. The Chepaizi area is near two hydrocarbon generation depressions of Sikeshu and Shawan, which have sets of hydrocarbon source rock of Carboniferous to Jurassic as well as Upper Tertiary. Geological and geochemical parameters are proper for the accumulation of mixed source crude oil. Carbon isotope, group composition and biomarkers of crude oil in Upper Tertiary of well Che89 show that the features of crude oil in Upper Tertiary Shawan Formation are between that of Permian and Jurassic, some of them are similar to these two, and some are of difference, they should be the mixed source of Permian and Jurassic. Geochemical analysis and geological study show that sand extract of Lower Tertiary Wulunguhe Formation has the same source as the crude oil and sand extract of Upper Tertiary Shawan Formation, but they are not charged in the same period. Oil/gas of Wulunguhe Formation is charged before Upper Tertiary sedimentation, and suffered serious biodegradation and oxidation and rinsing, which provide a proof in another aspect that the crude oil of Upper Tertiary Shawan Formation of well Che89 is not from hydrocarbon source rock of Lower Tertiary.

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12.
Hu  GuoYi  Li  Jin  Cui  HuiYing  Ran  QiGui  Zhang  Li  Wang  XiaoBo  Wang  YiFeng 《中国科学:地球科学(英文版)》2010,52(1):96-105

Focusing on the two natural gas exploration geological problems with abundant source of oil cracking gas in the late stage and the sealing condition of the oil cracking gas reservoir, the kinetics of oil cracking gas and the evaluation parameters of gas cap rock are adopted to the study on the natural gas accumulation conditions in the Tadong area. Both the study on the kinetics of oil cracking gas and the statistical results of reservoir bitumen reveal that the geological formation of oil cracking gas in the Tadong area is located in the top of Cambrian. Two kinds of oil cracking gas geological models at least, namely well Mandong-1’s early rapid generation model (Middle Ordovician-end Silurian) and peak cracking model (with the natural gas conversion rate >90%), namely well Yingnan-2’s two-stage generation model of oil cracking gas, have been set up. The oil cracking gas of Yingnan-2 in the late stage is very significant in the evaluation of natural gas exploration in the Tadong area. The evaluation results of the cap rock show that the microscopic parameters of cap rock from the lower assemblage of Cambrian-Ordovician are better than those from the upper assemblage. The former has strong capillary sealing ability and higher cap rock breakthrough pressure than the upper assemblage, with strong sealing ability, so that natural gas dissipates mainly by diffusion. According to the above investigations, the lower assemblage Cambrian-Ordovician natural gas of Kongquehe slope, Tadong low uplift and Yingjisu depression in the Tadong area prospects well.

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13.

Lunnan region is a large-scale paleohigh with many coexisting oil and gas bearing series. At present, about 2 billions tons of proved, probable and possible oil and gas reverses have been proved there. Eight oil and gas bearing series have been found in the Ordovician, Carboniferous, Triassic and Jurassic of Lunnan region, they all bear the characteristics of large-scale multilayer oil-gas province. Ordovician is the main reservoir series where over 0.8 billion tons of oil geologic reserves were discovered, and a super large-scale marine carbonate oil and gas field has formed. Reservoir space of the carbonate reservoirs is mainly composed of dissolved hole, dissolved pore and fracture in Lunnan paleo-burial hill. Generally, dissolved holes are widely distributed among them. Reservoir developments are mainly controlled by karstification and tectonic disruption. Due to the similar geochemical characters, the Ordovician, Carboniferous, Triassic and Jurassic oil and gas reservoirs present the same oil source rock of Mid-Upper Ordovician, the latter except Ordovician are mostly of secondary oil and gas reservoirs migrated vertically by faults during the process of multiple phase tectonic movement, adjustment and reconstruction. Lunnan composite oil and gas accumulation region is situated in the vicinity of large-scale hydrocarbon generation depressions in three directions, ample oil and gas from hydrocarbon generation depressions supplied the adjacent oil and gas reservoirs once. Hereby, the succeed paleohigh is the long-term hydrocarbon accumulation region, which is favor for the formations of high quality reservors, fault systems and huge-scale composite oil and gas accumulation.

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14.
Well che89, located in the Chepaizi area in the northwest margin of Junggar basin, acquires high production industrial oil flow, which is an important breakthrough in the exploration of the south foreland slope area of Junggar basin. The Chepaizi area is near two hydrocarbon generation depressions of Sikeshu and Shawan, which have sets of hydrocarbon source rock of Carboniferous to Jurassic as well as Upper Tertiary. Geological and geochemical parameters are proper for the accumulation of mixed source crude oil. Carbon isotope, group composition and biomarkers of crude oil in Upper Tertiary of well Che89 show that the features of crude oil in Upper Tertiary Shawan Formation are between that of Permian and Jurassic, some of them are similar to these two, and some are of difference, they should be the mixed source of Permian and Jurassic. Geochemical analysis and geological study show that sand extract of Lower Tertiary Wulunguhe Formation has the same source as the crude oil and sand extract of Upper Tertiary Shawan Formation, but they are not charged in the same period. Oil/gas of Wulunguhe Formation is charged before Upper Tertiary sedimentation, and suffered serious biodegradation and oxidation and rinsing, which provide a proof in another aspect that the crude oil of Upper Tertiary Shawan Formation of well Che89 is not from hydrocarbon source rock of Lower Tertiary.  相似文献   

15.
Focusing on the two natural gas exploration geological problems with abundant source of oil cracking gas in the late stage and the sealing condition of the oil cracking gas reservoir, the kinetics of oil cracking gas and the evaluation parameters of gas cap rock are adopted to the study on the natural gas accumulation conditions in the Tadong area. Both the study on the kinetics of oil cracking gas and the statistical results of reservoir bitumen reveal that the geological formation of oil cracking gas in the Tadong area is located in the top of Cambrian. Two kinds of oil cracking gas geological models at least, namely well Mandong-1’s early rapid generation model (Middle Ordovician-end Silurian) and peak cracking model (with the natural gas conversion rate >90%), namely well Yingnan-2’s two-stage generation model of oil cracking gas, have been set up. The oil cracking gas of Yingnan-2 in the late stage is very significant in the evaluation of natural gas exploration in the Tadong area. The evaluation results of the cap rock show that the microscopic parameters of cap rock from the lower assemblage of Cambrian-Ordovician are better than those from the upper assemblage. The former has strong capillary sealing ability and higher cap rock breakthrough pressure than the upper assemblage, with strong sealing ability, so that natural gas dissipates mainly by diffusion. According to the above investigations, the lower assemblage Cambrian-Ordovician natural gas of Kongquehe slope, Tadong low uplift and Yingjisu depression in the Tadong area prospects well.  相似文献   

16.
Organic-inorganic interaction exists universally and is important in the process of mineral resources formation.It is the essential reason why organic oil,gas,coal and inorganic uranium coexist,accumulate,and mineralize in the same sedimentary basins.Hydrocarbon-generating simulation experiment was conducted using low-mature hydrocarbon source rock containing kerogen type III with uranium(UO2CO3 solution)added to study the effects of uranium on the hydrocarbon generation of hydrocarbon source rocks.Experiment results show that uranium can enhance the yield of gas hydrocarbon,promote the total gas output,and increase the total hydrocarbon production(mass or volume).Uranium may lower the hydrocarbon generation threshold temperature and lead to the generation of liquid hydrocarbon in the relative low temperature of hydrocarbon source rock.Uranium can enhance the yield of saturated hydrocarbon,promote the low molecular weight hydrocarbons generating,and in turn increase the content of CH4 and the content of dry gas of the generated hydrocarbons.Uranium is one of the potential inorganic accelerating factors of the immature hydrocarbons.  相似文献   

17.
二连盆地及邻区是我国油气勘探的重点区域之一,普遍认为烃源岩层主要分布在中生代地层,对其晚古生代地层的烃源岩潜力研究较少,本文对研究区内晚古生代碳酸盐岩及泥岩进行了有机地球化学实验并分析其烃源岩潜力,评价结果表明二连盆地及邻区内晚古生代地层具有一定的生烃潜力,受高成熟度的影响,剩余潜力以生气能力为主.依据研究区内电法剖面、布格重力异常特征及磁性资料认为晚古生代潜在烃源岩层具有"低电阻、高密度、弱磁性"的地球物理性质,并初步预测了二连盆地及邻区晚古生代的深度大致分布在3~5km的范围内,进一步利用优化后的小子域滤波重力异常分离技术对晚古生代地层进行了厚度预测,刻画其平面分布特征,认为研究区内的晚古生代地层具有两个分布中心,其中心区厚度范围为1000~2000m之间,与野外地质剖面的厚度基本一致,晚古生代潜在烃源岩的平面预测可以为二连盆地油气勘探工作提供新方向.  相似文献   

18.
Since the discovery of the Tahe oilfield, it has been controversial on whether the main source rock is in the Cambrian or Middle-Upper Ordovician strata. In this paper, it is assumed that the crude oil from the Wells YM 2 and TD 2 was derived from the Middle-Upper Ordovician and Cambrian source rocks, respectively. We analyzed the biomarkers of the crude oil, asphalt-adsorbed hydrocarbon and saturated hydrocarbon in bitumen inclusions from the Lunnan and Hade areas in the North Uplift of the Tarim Basin. Results show that the ratios of tricyclic terpane C21/C23 in the crude oil, asphalt-adsorbed hydrocarbon and saturated hydrocarbon in bitumen inclusions are less than 1.0, indicating that they might be from Upper Ordovician source rocks; the ratios of C28/(C27+C28+C29) steranes in the saturated hydrocarbon from reservoir bitumen and bitumen inclusions are higher than 25, suggesting that they might come from the Cambrian source rocks, however, the ratios of C28/(C27+C28+C29) steranes in oil from the North Uplift are less than 25, suggesting that they might be sourced from the Upper Ordovician source rocks. These findings demonstrate that the sources of crude oil in the Tarim Basin are complicated. The chemical composition and carbon isotopes of Ordovician reservoired oil in the Tarim Basin indicated that the crude oil in the North Uplift (including the Tahe oilfield) and Tazhong Depression was within mixture areas of crude oil from the Wells YM 2 and TD 2 as the end members of the Cambrian and Middle-Upper Ordovician sourced oils, respectively. This observation suggests that the crude oil in the Ordovician strata is a mixture of oils from the Cambrian and Ordovician source rocks, with increasing contribution from the Cambrian source rocks from the southern slope of the North Uplift to northern slope of the Central Uplift of the Tarim Basin. Considering the lithology and sedimentary facies data, the spatial distribution of the Cambrian, Middle-Lower Ordovician and Upper Ordovician source rocks was reconstructed on the basis of seismic reflection characteristics, and high-quality source rocks were revealed to be mainly located in the slope belt of the basin and were longitudinally developed over the maximum flooding surface during the progressive-regressive cycle. Affected by the transformation of the tectonic framework in the basin, the overlays of source rocks in different regions are different and the distribution of oil and gas was determined by the initial basin sedimentary structure and later reformation process. The northern slope of the Central Uplift-Shuntuo-Gucheng areas would be a recent important target for oil and gas exploration, since they have been near the slope area for a long time.  相似文献   

19.
Lunnan region is a large-scale paleohigh with many coexisting oil and gas bearing series. At present, about 2 billions tons of proved, probable and possible oil and gas reverses have been proved there. Eight oil and gas bearing series have been found in the Ordovician, Carboniferous, Triassic and Jurassic of Lunnan region, they all bear the characteristics of large-scale multilayer oil-gas province. Ordovician is the main reservoir series where over 0.8 billion tons of oil geologic reserves were discovered, and a super large-scale marine carbonate oil and gas field has formed. Reservoir space of the carbonate reservoirs is mainly composed of dissolved hole, dissolved pore and fracture in Lunnan paleo-burial hill. Generally, dissolved holes are widely distributed among them. Reservoir developments are mainly controlled by karstification and tectonic disruption. Due to the similar geochemical characters, the Ordovician, Carboniferous, Triassic and Jurassic oil and gas reservoirs present the same oil source rock of Mid-Upper Ordovician, the latter except Ordovician are mostly of secondary oil and gas reservoirs migrated vertically by faults during the process of multiple phase tectonic movement, adjustment and reconstruction. Lunnan composite oil and gas accumulation region is situated in the vicinity of large-scale hydrocarbon generation depressions in three directions, ample oil and gas from hydrocarbon generation depressions supplied the adjacent oil and gas reservoirs once. Hereby, the succeed paleohigh is the long-term hydrocarbon accumulation region, which is favor for the formations of high quality reservors, fault systems and huge-scale composite oil and gas accumulation.  相似文献   

20.
Shallow gas reservoirs are distributed widely in Chinese heavy oil-bearing basins. At present, shallow gas resources have opened up giant potentials. The previous researches indicate the intimate genetic relationship between shallow gas and heavy oil. Shallow gas resources are generated from crude oil degraded by anaerobic microscopic organism, it belongs to biogenic gas family of secondary genesis, namely heavy oil degraded gas. Shallow gas resources are usually distributed in the upward position or the vicinity of heavy oil reservoirs. They are mainly of dry gas, which are composed of methane and only tiny C 2 + heavy hydrocarbon and relatively higher contents of nitrogen gas. Generally, methane isotopes are light, whose values are between biogenic gas and thermal cracking gas. Ethane isotopes are heavy, which mixed possibly with thermogenic gas. Carbon dioxide bear the characteristics of very heavy carbon isotope, so carbon isotopic fractionation effects are very obvious on the process of microscopic organism degradation crude oil. The heavy oil degraded gas formation, a very complex geological, geochemical and microbiological geochemical process, is the result of a series of reactions of organic matter-microbes and water-hydrocarbon, which is controlled by many factors.  相似文献   

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