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1.
Testing hydrological models over different spatio‐temporal scales is important for both evaluating diagnostics and aiding process understanding. High‐frequency (6‐hr) stable isotope sampling of rainfall and runoff was undertaken during 3‐week periods in summer and winter within 12 months of daily sampling in a 3.2‐km2 catchment in the Scottish Highlands. This was used to calibrate and test a tracer‐aided model to assess the (a) information content of high‐resolution data, (b) effect of different calibration strategies on simulations and inferred processes, and (c) model transferability to <1‐km2 subcatchment. The 6‐hourly data were successfully incorporated without loss of model performance, improving the temporal resolution of the modelling, and making it more relevant to the time dynamics of the isotope and hydrometric response. However, this added little new information due to old‐water dominance and riparian mixing in this peatland catchment. Time variant results, from differential split sample testing, highlighted the importance of calibrating to a wide range of hydrological conditions. This also provided insights into the nonstationarity of catchment mixing processes, in relation to storage and water ages, which varied markedly depending on the calibration period. Application to the nested subcatchment produced equivalent parameterization and performance, highlighting similarity in dominant processes. The study highlighted the utility of high‐resolution data in combination with tracer‐aided models, applied at multiple spatial scales, as learning tools to enhance process understanding and evaluation of model behaviour across nonstationary conditions. This helps reveal more fully the catchment response in terms of the different mechanistic controls on both wave celerites and particle velocities.  相似文献   

2.
Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km2 San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.  相似文献   

3.
Integrating stable isotope tracers into rainfall‐runoff models allows investigation of water partitioning and direct estimation of travel times and water ages. Tracer data have valuable information content that can be used to constrain models and, in integration with hydrometric observations, test the conceptualization of catchment processes in model structure and parameterization. There is great potential in using tracer‐aided modelling in snow‐influenced catchments to improve understanding of these catchments' dynamics and sensitivity to environmental change. We used the spatially distributed tracer‐aided rainfall‐runoff (STARR) model to simulate the interactions between water storage, flux, and isotope dynamics in a snow‐influenced, long‐term monitored catchment in Ontario, Canada. Multiple realizations of the model were achieved using a combination of single and multiple objectives as calibration targets. Although good simulations of hydrometric targets such as discharge and snow water equivalent could be achieved by local calibration alone, adequate capture of the stream isotope dynamics was predicated on the inclusion of isotope data in the calibration. Parameter sensitivity was highest, and most local, for single calibration targets. With multiple calibration targets, key sensitive parameters were still identifiable in snow and runoff generation routines. Water ages derived from flux tracking subroutines in the model indicated a catchment where runoff is dominated by younger waters, particularly during spring snowmelt. However, resulting water ages were most sensitive to the partitioning of runoff sources from soil and groundwater sources, which was most realistically achieved when isotopes were included in the calibration. Given the paucity of studies where hydrological models explicitly incorporate tracers in snow‐influenced regions, this study using STARR is an important contribution to satisfactorily simulating snowpack dynamics and runoff generation processes, while simultaneously capturing stable isotope variability in snow‐influenced catchments.  相似文献   

4.
This study aimed to investigate the seasonal variability of runoff generation processes, the sources of stream water, and the controls on the contribution of event water to streamflow for a small forested catchment in the Italian pre‐Alps. Hydrometric, isotopic, and electrical conductivity data collected between August 2012 and August 2013 revealed a marked seasonal variability in runoff responses. Noticeable differences in runoff coefficients and hydrological dynamics between summer and fall/spring rainfall events were related to antecedent moisture conditions and event size. Two‐component and three‐component hydrograph separation and end‐member mixing analysis showed an increase in event water contributions to streamflow with event size and average rainfall intensity. Event water fractions were larger during dry conditions in the summer, suggesting that stormflow generation in the summer consisted predominantly of direct channel precipitation and some saturated overland flow from the riparian zone. On the contrary, groundwater and hillslope soil water contributions dominated the streamflow response during wet conditions in fall. Seasonal differences were also noted between event water fractions computed based on isotopic and electrical conductivity data, likely because of the dilution effect during the wetter months. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

5.
Assessing catchment runoff response remains a key research frontier because of limitations in current observational techniques to fully characterize water source areas and transit times in diverse geographical environments. Here, we report a study that combines empirical data with modelling to identify dominant runoff processes in a sparsely monitored humid tropical catchment. The analysis integrated isotope tracers into conceptual rainfall–runoff models of varying complexity (from 5 to 11 calibrated parameters) that are able to simulate discharge and tracer concentrations and track the evolving age of stream water exiting the catchment. The model structures can be seen as competing hypotheses of catchment functioning and were simultaneously calibrated against uncertain streamflow gaugings and a 2‐year daily isotope rainfall–runoff record. Comparison of the models was facilitated using global parameter sensitivity analysis and the resulting effect on calibration. We show that a variety of tested model structures reproduced water and tracer dynamics in stream, but the simpler models failed to adequately reproduce both. The resulting water age distributions of the tested models varied significantly with little similarity between the stream water age and stored water age distributions. The sensitivity analysis revealed that only some of the more complex models (from eight parameters) could be better constrained to infer more plausible water age distributions and catchment storage estimates. These models indicated that the age of water stored in the catchment is generally older compared with the age of water fluxes, with evapotranspiration age being younger compared with streamflow. However, the water age distributions followed a similar temporal behaviour dominated by climatic seasonality. Stream water ages increased during the dry season (greater than 1 year) and decreased with increased streamflow (a few weeks old) during the wet season. We further show that the ratios of the streamwater age to stored water age distribution and the water age distribution of actual evapotranspiration to the stored water age distribution from constrained models could potentially serve as useful hydrological indicators of catchment functioning. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

6.
Soil water storage and stable isotopes dynamics were investigated in dominant soil–vegetation assemblages of a wet northern headwater catchment (3.2 km2) with limited seasonality in precipitation. We determined the relative influence of soil and vegetation cover on storage and transmission processes. Forested and non‐forested sites were compared, on poorly drained histosols in riparian zones and freely draining podzols on steeper hillslopes. Results showed that soil properties exert a much stronger influence than vegetation on water storage dynamics and fluxes, both at the plot and catchment scale. This is mainly linked to the overall energy‐limited climate, restricting evaporation, in conjunction with high soil water storage capacities. Threshold behaviour in runoff responses at the catchment scale was associated with differences in soil water storage and transmission dynamics of different hydropedological units. Linear input–output relationships occurred when runoff was generated predominantly from the permanently wet riparian histosols, which show only small dynamic storage changes. In contrast, nonlinear runoff generation was related to transient periods of high soil wetness on the hillslopes. During drier conditions, more marked differences in soil water dynamics related to vegetation properties emerged, in terms of evaporation and impacts on temporarily increasing dynamic storage potential. Overall, our results suggest that soil type and their influence on runoff generation are dominant over vegetation effects in wet, northern headwater catchments with low seasonality in precipitation. Potential increase of subsurface storage by tree cover (e.g. for flood management) will therefore be spatially distributed throughout the landscape and limited to rare and extreme dry conditions. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

7.
Soil water, stream water, groundwater and rain water were sampled through a storm event in a moorland catchment. Samples were analysed for major ions and deuterium. Chloride and deuterium are used as tracers to enable separation of the stream runoff hydrograph into three components: rain, soil and groundwater. The results indicate that rain water arrives in the stream quickly during the event and contributes a significant volume to the runoff peak. The chemical signal in the rain water is, however, significantly damped, apparently due to mixing with soil water held in the catchment before the event. This is further modified before reaching the stream, apparently through mixing with a deeper groundwater component. Interpretation of tracer, chemistry and hydrological data to present an integrated picture of catchment hydrochemical response is difficult due to problems in the chemical and conceptual definition of the flow components.  相似文献   

8.
Fine sediment delivery to and storage in stream channel reaches can disrupt aquatic habitats, impact river hydromorphology, and transfer adsorbed nutrients and pollutants from catchment slopes to the fluvial system. This paper presents a modelling tool for simulating the time‐dependent response of the fine sediment system in catchments, using an integrated approach that incorporates both land phase and in‐stream processes of sediment generation, storage and transfer. The performance of the model is demonstrated by applying it to simulate in‐stream suspended sediment concentrations in two lowland catchments in southern England, the Enborne and the Lambourn, which exhibit contrasting hydrological and sediment responses due to differences in substrate permeability. The sediment model performs well in the Enborne catchment, where direct runoff events are frequent and peak suspended sediment concentrations can exceed 600 mg l?1. The general trends in the in‐stream concentrations in the Lambourn catchment are also reproduced by the model, although the observed concentrations are low (rarely exceeding 50 mg l?1) and the background variability in the concentrations is not fully characterized by the model. Direct runoff events are rare in this highly permeable catchment, resulting in a weak coupling between the sediment delivery system and the catchment hydrology. The generic performance of the model is also assessed using a generalized sensitivity analysis based on the parameter bounds identified in the catchment applications. Results indicate that the hydrological parameters contributing to the sediment response include those controlling (1) the partitioning of runoff between surface and soil zone flows and (2) the fractional loss of direct runoff volume prior to channel delivery. The principal sediment processes controlling model behaviour in the simulations are the transport capacity of direct runoff and the in‐stream generation, storage and release of the fine sediment fraction. The in‐stream processes appear to be important in maintaining the suspended sediment concentrations during low flows in the River Enborne and throughout much of the year in the River Lambourn. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

9.
Hydrological budgets and flow pathways have been quantified for a small upland catchment (1.76 km2) in the northeast of Scotland. Water balance calculations for four subcatchments identified spatial variability within the catchment, with an estimated runoff enhancement of up to 25% for the upper western area, compared with the rest of the catchment. Data from spatial hydrochemical sampling, over a range of flow conditions, were used to identify the principal hillslope runoff mechanisms within the catchment. A hydrochemical mixing analysis revealed that runoff emerging from springs in various locations of the hillslope accounted for a significant proportion of flow in the streams, even during storm events. A hydrological model of the catchment was calibrated using the calculated stream flows for four locations, together with results from the mixing analysis for different time points. The calibrated model was used to predict the temporal variability in contributions to stream flow from the hillslope springs and soil water flows. The overall split ranged from 57%:43% spring water:soil water in the upper eastern subcatchment, to 76%:24% in the upper western subcatchment. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

10.
Australian arid zone ephemeral rivers are typically unregulated and maintain a high level of biodiversity and ecological health. Understanding the ecosystem functions of these rivers requires an understanding of their hydrology. These rivers are typified by highly variable hydrological regimes and a paucity, often a complete absence, of hydrological data to describe these flow regimes. A daily time‐step, grid‐based, conceptual rainfall–runoff model was developed for the previously uninstrumented Neales River in the arid zone of northern South Australia. Hourly, logged stage data provided a record of stream‐flow events in the river system. In conjunction with opportunistic gaugings of stream‐flow events, these data were used in the calibration of the model. The poorly constrained spatial variability of rainfall distribution and catchment characteristics (e.g. storage depths) limited the accuracy of the model in replicating the absolute magnitudes and volumes of stream‐flow events. In particular, small but ecologically important flow events were poorly modelled. Model performance was improved by the application of catchment‐wide processes replicating quick runoff from high intensity rainfall and improving the area inundated versus discharge relationship in the channel sections of the model. Representing areas of high and low soil moisture storage depths in the hillslope areas of the catchment also improved the model performance. The need for some explicit representation of the spatial variability of catchment characteristics (e.g. channel/floodplain, low storage hillslope and high storage hillslope) to effectively model the range of stream‐flow events makes the development of relatively complex rainfall–runoff models necessary for multisite ecological studies in large, ungauged arid zone catchments. Grid‐based conceptual models provide a good balance between providing the capacity to easily define land types with differing rainfall–runoff responses, flexibility in defining data output points and a parsimonious water‐balance–routing model. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

11.
Models simulating stream flow and conservative tracers can provide a representation of flow paths, storage distributions and mixing processes that is advantageous for many predictive purposes. Compared with models that only simulate stream flow, tracer data can be used to investigate the internal consistency of model behaviour and to gain insight into model performance. Here, we examine the strengths and weaknesses of a data‐driven, spatially distributed tracer‐aided rainfall‐runoff model. The model structure allowed us to assess the influence of landscape characteristics on the routing and mixing of water and tracers. The model was applied to a site in the Scottish Highlands with a unique tracer data set; ~4 years of daily isotope ratios in stream water and precipitation were available, as well as 2 years of weekly soil and ground water isotopes. The model structure was based on an empirically based, lumped tracer‐aided model previously developed for the catchment. The best model runs were selected from Monte Carlo simulations based on dual calibration criteria using objective functions for both stream isotopes and discharge at the outlet. Model performance for these criteria was reasonable (Nash–Sutcliffe efficiencies for discharge and isotope ratios were ~0.4–0.6). The model could generally reproduce the variable isotope signals in the soils of the steeper hill slopes where storage was low, and damped isotope responses in valley bottom cells with high storage. The model also allowed us to estimate the age distributions of internal stores, water fluxes and stream flow. Average stream water age was ~1.6 years, integrating older groundwater in the valley bottom and dynamic younger soil waters. By tracking water ages and simulating isotopes, the model captured the changes in connectivity driven by distributed storage dynamics. This has substantially improved the representation of spatio‐temporal process dynamics and gives a more robust framework for projecting environmental change impacts. Copyright © 2016 The Authors Hydrological Processes Published by John Wiley & Sons Ltd.  相似文献   

12.
Glaciers are of crucial importance for the livelihood of the local populations, which depend on their meltwater for water and energy supplies. For this reason, seasonal variations of oxygen‐18 of glacial stream water and their sources within a small glacial catchment in south western China were investigated during the wet season. The results showed significant difference of oxygen‐18 existed among meltwater, rainwater, ground water and stream water, and significantly seasonal variation of precipitation occurred during the observed period. The streamflow of Baishui catchment was separated into components of ice‐snowmelt and precipitation using oxygen‐18. As shown by the result of the two‐component mixing model, on average, 53.4% of the runoff came from ice‐snowmelt during the wet season, whereas the remaining 46.6% were contributed by precipitation in the catchment. According to monthly hydrograph, the contribution of snow and glacier meltwater varied from 40.7% to 62.2%, and that of precipitation varied from 37.8% to 59.3% in wet season. Uncertainties for this separation were mainly caused by the variation of tracer concentrations. The roles of glacier and snow meltwater should be noticed in water resource management in those glacial regions in south western China. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

13.
C. Soulsby  C. Birkel  D. Tetzlaff 《水文研究》2016,30(14):2482-2497
The importance of conceptualizing the dynamics of storage‐driven saturation area connectivity in runoff generation has been central to the development of TOPMODEL and similar low parameterized rainfall–runoff models. In this contribution, we show how we developed a 40‐year hydrometric data base to simulate storage–discharge relationships in the Girnock catchment in the Scottish Highlands using a simple conceptual model. The catchment is a unique fisheries reference site where Atlantic salmon populations have been monitored since 1966. The modelling allowed us to track storage dynamics in hillslopes, the riparian zone and groundwater, and explicitly link non‐linear changes of streamflows to landscape storage and connectivity dynamics. This provides a fundamental basis for understanding how the landscape and riverscape are hydrologically connected and how this regulates in‐stream hydraulic conditions that directly influence salmonids. We use the model to simulate storage and discharge dynamics over the 40‐year period of fisheries records. The modelled storage‐driven connectivity provides an ecohydological context for understanding the dynamics in stream flow generation which determine habitat hydraulics for different life stages of salmon population. This new, long‐term modelling now sets this variability in the riverscape in a more fundamental context of the inter‐relationships between storage in the landscape and stream flow generation. This provides a simple, robust framework for future ecohydrological modelling at this site, which is an alternative to more increasingly popular but highly parameterized and uncertain commercial ecohydrological models. It also provides a wider, novel context that is a prerequisite for any model‐based scenario assessment of likely impacts resulting from climate or land use change. Copyright © 2016 The Authors Hydrological Processes Published by John Wiley & Sons Ltd. Copyright © 2016 The Authors Hydrological Processes Published by John Wiley & Sons Ltd.  相似文献   

14.
We examined the contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments by conducting detailed hydrochemical observations in five catchments that ranged from zero to second order. End‐member mixing analysis (EMMA) was performed to identify the geographical sources of stream water. Throughfall, hillslope groundwater, shallow bedrock groundwater, and deep bedrock groundwater were identified as end members. The contribution of each end member to storm runoff differed among the catchments because of the differing quantities of riparian groundwater, which was recharged by the bedrock groundwater prior to rainfall events. Among the five catchments, the contribution of throughfall was highest during both baseflow and storm flow in a zero‐order catchment with little contribution from the bedrock groundwater to the riparian reservoir. In zero‐order catchments with some contribution from bedrock groundwater, stream water was dominated by shallow bedrock groundwater during baseflow, but it was significantly influenced by hillslope groundwater during storms. In the first‐order catchment, stream water was dominated by shallow bedrock groundwater during storms as well as baseflow periods. In the second‐order catchment, deeper bedrock groundwater than that found in the zero‐order and first‐order catchments contributed to stream water in all periods, except during large storm events. These results suggest that bedrock groundwater influences the upscaling of storm‐runoff generation processes by affecting the linkages of geomorphic units such as hillslopes, riparian zones, and stream channels. Our results highlight the need for a three‐dimensional approach that considers bedrock groundwater flow when studying the upscaling of storm‐runoff generation processes. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

15.
P. Rodgers  C. Soulsby  S. Waldron 《水文研究》2005,19(11):2291-2307
δ18O measurements of precipitation and stream waters were used as a natural tracer to investigate hydrological pathways and residence times in the River Feshie, a complex mesoscale (231 km2) catchment in the Cairngorm Mountains of Scotland. Precipitation δ18O exhibited strong seasonal variation over the 2001–02 hydrological year, ranging from −6·9‰ in the summer, to −12·0‰ during winter snowfalls (mean δ18O −9·59‰). Although damped, this seasonality was reflected in stream water outputs at seven sampling sites in the catchment, allowing δ18O variations to be used to infer hydrological source areas. Thus, stream water δ18O was generally controlled by a seasonally variable storm flow end member, mixing with groundwater of more constant isotopic composition. Periodic regression analysis allowed the differences in this mixing process between monitoring subcatchments to be assessed more quantitatively to provide a preliminary estimate of mean stream water residence time. This demonstrated the importance of responsive hydrological pathways associated with peat and shallow alpine soils in the headwater subcatchments in producing seasonally variable runoff with short mean residence times (33–113 days). In contrast, other tributaries with more freely draining soils and larger groundwater storage in shallow aquifers provided more effective mixing of variable precipitation inputs, resulting in longer residence time estimates (178–445 days). The mean residence time of runoff leaving the Feshie catchment reflected an integration of these contrasting influences (110–200 days). These insights from δ18O measurements extend the hydrological understanding of the Feshie catchment gained from other hydrochemical tracers, and demonstrate the utility of isotope tracers in investigating hydrological processes at the mesoscale. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

16.
J.J. Dick  D. Tetzlaff  C. Soulsby 《水文研究》2015,29(14):3098-3111
We monitored temperatures in stream water, groundwater and riparian wetland surface water over 18 months in a 3.2‐km2 moorland catchment in the Scottish Highlands. The stream occupies a glaciated valley, aligned east–west. It has three main headwater tributaries with a large north facing catchment, a south facing catchment and the smallest east facing headwater. The lower catchment sampling locations begin after the convalescence of all three headwaters. Much of the stream network is fringed by riparian peatlands. Stream temperatures are mainly regulated by energy exchanges at the air–water interface. However, they are also influenced by inflows from the saturated riparian zone, where surface water source areas are strongly connected with the stream network. Consequently, the spatial distribution of stream temperatures exhibits limited variability. Nevertheless, there are significant summer differences between the headwaters, despite their close proximity to each other. This is consistent with aspect (and incident radiation), given the south and east facing headwaters having higher temperatures. The largest, north‐facing sub‐catchment shows lower summer diurnal temperature variability, suggesting that lower radiation inputs dampen temperature extremes. Whilst stream water temperature regimes in the lower catchment exhibit little change along a 1‐km reach, they are similar to those in the largest headwater; probably reflecting size and comparable catchment aspect and hydrological flow paths. Our results suggest that different parts of the channel network and its connected wetlands have contrasting sensitivity to higher summer temperatures. This may be important in land management strategies designed to mitigate the impacts of projected climatic warming. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

17.
The temporal and spatial dynamics of groundwater was investigated in a small catchment in the Spanish Pyrenees, which was extensively used for agriculture in the past. Analysis of the water table fluctuations at five locations over a 6‐year period demonstrated that the groundwater dynamics had a marked seasonal cycle involving a wetting‐up period that commenced with the first autumn rainfall events, a saturation period during winter and spring and a drying‐down period from the end of spring until the end of the summer. The length of the saturation period showed great interannual variability, which was mainly influenced by the rainfall and evapotranspiration characteristics. There was marked spatial variability in the water table, especially during the wetting‐up period, which could be related to differences in slope and drainage area, geomorphology, soil properties and local topography. Areas contributing to runoff generation were identified within the catchment by field mapping of moisture conditions. Areas contributing to infiltration excess runoff were correlated with former cultivated fields affected by severe sheetwash erosion. Areas contributing to saturation excess runoff were characterized by a marked spatial dynamics associated with catchment wetness conditions. The saturation spatial pattern, which was partially related to the topographic index, was very patchy throughout the catchment, suggesting the influence of other factors associated with past agricultural activities, including changes in local topography and soil properties. The relationship between water table levels and stream flow was weak, especially during the wetting‐up period, suggesting little connection between ground water and the hydrological response, at least at some locations. The results suggest that in drier and human‐disturbed environments, such as sub‐Mediterranean mountains, saturation patterns cannot be represented only by the general topography of the catchment. They also suggest that groundwater storage and runoff is not a succession of steady‐state flow conditions, as assumed in most hydrological models. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

18.
Recent studies have demonstrated that compartmentalized pools of water preferentially supply either plant transpiration (poorly mobile water) or streamflow and groundwater (highly mobile water) in some catchments, a phenomenon referred to as ecohydrologic separation. The omission of processes accounting for ecohydrologic separation in standard applications of hydrological models is expected to influence estimates of water residence times and plant water availability. However, few studies have tested this expectation or investigated how ecohydrologic separation alters interpretations of stores and fluxes of water within a catchment. In this study, we compare two rainfall‐runoff models that integrate catchment‐scale representations of transport, one that incorporates ecohydrologic separation and one that does not. The models were developed for a second‐order watershed at the H.J. Andrews Experimental Forest (Oregon, USA), the site where ecohydrologic separation was first observed, and calibrated against multiple years of stream discharge and chloride concentration. Model structural variations caused mixed results for differences in calibrated parameters and differences in storage between reservoirs. However, large differences in catchment storage volumes and fluxes arise when considering only mobile water. These changes influence interpreted residence times for streamflow‐generating water, demonstrating the importance of ecohydrologic separation in catchment‐scale water and solute transport.  相似文献   

19.
The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km2) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

20.
The spatial and temporal characterization of geochemical tracers over Alpine glacierized catchments is particularly difficult, but fundamental to quantify groundwater, glacier melt, and rain water contribution to stream runoff. In this study, we analysed the spatial and temporal variability of δ2H and electrical conductivity (EC) in various water sources during three ablation seasons in an 8.4‐km2 glacierized catchment in the Italian Alps, in relation to snow cover and hydro‐meteorological conditions. Variations in the daily streamflow range due to melt‐induced runoff events were controlled by maximum daily air temperature and snow covered area in the catchment. Maximum daily streamflow decreased with increasing snow cover, and a threshold relation was found between maximum daily temperature and daily streamflow range. During melt‐induced runoff events, stream water EC decreased due to the contribution of glacier melt water to stream runoff. In this catchment, EC could be used to distinguish the contribution of subglacial flow (identified as an end member, enriched in EC) from glacier melt water to stream runoff, whereas spring water in the study area could not be considered as an end member. The isotopic composition of snow, glacier ice, and melt water was not significantly correlated with the sampling point elevation, and the spatial variability was more likely affected by postdepositional processes. The high spatial and temporal variability in the tracer signature of the end members (subglacial flow, rain water, glacier melt water, and residual winter snow), together with small daily variability in stream water δ2H dynamics, are problematic for the quantification of the contribution of the identified end members to stream runoff, and call for further research, possibly integrated with other natural or artificial tracers.  相似文献   

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