共查询到20条相似文献，搜索用时 578 毫秒
1.
Chemistry on the icy surface of Europa is heavily influenced by the incident energetic particle flux from the jovian magnetosphere. The majority (>75%) of this energy is in the form of high energy electrons (extending to >10 MeV). We have simulated the electron irradiation environment of Europa with a vacuum system containing a high-energy electron gun for irradiation of ice samples formed on a gold mirror cooled with a cryostat. Pure water films of ∼2.6 μm thickness were grown at 100 K and then either cooled (to 80 K), warmed (to 120 K) or left at 100 K and subsequently irradiated with 10 keV electrons. The production of hydrogen peroxide (H2O2) was monitored by observation of the 2850 cm−1 (3.5 μm) band. Equilibrium concentrations of H2O2, in units of percent by number H2O2 relative to water, were found to be 0.043% (80 K), 0.029% (100 K), and 0.0063% (120 K). These values are 33%, 22%, and 5%, respectively, that of the reported surface concentration on the leading hemisphere of Europa (Carlson, R.W., Anderson, M.S., Johnson, R.E., Smythe, W.D., Hendrix, A.R., Barth, C.A., et al. [1999]. Science 283(5410), 2062-2064) and less than the equilibrium concentrations formed by ion irradiation. In addition to the ice film temperature, the current of electrons was varied between different experiments to determine the production and destruction of H2O2 as a function of both electron flux and ice temperature. Variation in current was found to have little effect on the results other than accelerating arrival at radiolytic equilibrium. 相似文献
2.
Oxygen is seen in the reflectance spectra of the icy surfaces of Ganymede and Europa via absorption bands at 627 and 573 nm. Here we show that the trapped O2 associated with these spectral features can be produced via radiation-induced decomposition of hydrogen peroxide dimers contained in hydrogen peroxide inclusions in these icy satellite surfaces. 相似文献
3.
Andreas F. Voegele Christofer S. Tautermann Andreas Hallbrucker Erwin Mayer Klaus R. Liedl 《Icarus》2004,169(1):242-249
Sulfurous acid (H2SO3) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H2SO3 within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H2SO3 at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H2SO3 presumably require cryogenic SO2 or SO2/H2O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H2SO3 which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H2SO3 is present on Io and probably but to a smaller extent on Europa. 相似文献
4.
In this paper we present the results of new experiments of ion irradiation of water ice deposited on top of a solid sulfurous residue to study the potential formation of SO2 at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the sulfur dioxide ice detected on the surfaces of the Galilean satellites. In situ infrared spectroscopy was the used experimental technique. We have irradiated a thin film of H2O frost on a sulfurous layer with 200 keV of He+ at 80 K. The used sulfurous residue was obtained by irradiation of frozen SO2 at 16 K and it is used as a template of sulfur bearing solid materials. We have not found evidences of the efficient formation of SO2 after irradiation of H2O ice on top of the sulfurous residue. An upper limit to the production yield of SO2, of interface area for each 100 eV of energy absorbed in 1 cm3 of ice-covered residue, has been estimated. These results have relevance in the context of the surfaces of the icy Galilean satellites in which SO2 was detected. Our results show that radiolysis of mixtures of water ice and refractory sulfurous materials is not the primary formation mechanism responsible for the SO2 present on the surfaces of the Galilean satellites. 相似文献
5.
We have determined the phase relation of the MgSO4-H2O binary system using an externally heated diamond anvil cell in the compositional range of 0-30 wt.% MgSO4, and under temperature and pressure conditions from 298 to 500 K and up to 4.5 GPa. Using our experimental results, we were able to estimate the composition of the ice mantle of the large icy satellites of Jupiter, such as Ganymede.In our experiments, we identified the following phases in the MgSO4-H2O system up to 4 GPa at 298 K: Ices VI and VII, magnesium heptahydrate, MgSO4·7H2O, and a liquid phase. The present phase relations suggest that there may be a deep internal ocean down to a depth about 800 km in the interior of Ganymede. 相似文献
6.
The purpose of this study was to determine if any temporal variability in the broadband UV spectral properties of the icy Galilean satellites exists, and if so, to characterize its spatial distribution as a function of longitude in order to attempt to correlate any temporal changes with satellite surface interactions with the space environment. The temporal time period examined is between 1978-1984 (referred to as the 1980s data) and those from 1995-1996 (referred to as the 1990s data). The plausible temporal characteristics detected appear to vary from one satellite to the next. For Europa possible temporal variations are concentrated on the leading, anti-jovian quadrant. Example broadband UV spectra show Europa's spectral slope decreases (and darkens) with time on the leading and anti-jovian hemispheres, but remains essentially constant with time on the trailing hemisphere. The data quality does not support any definitive temporal changes for Ganymede. Possible temporal changes seen in the Callisto data set are concentrated on the jovian hemisphere. Example broadband UV spectra for Callisto show no definitive change in slope with time. The hypothesis is that these temporal differences in UV spectral properties are caused by variations in the surface ice chemistry due to temporal variability in the space environment. It is postulated that the UV spectral changes suggested for Europa may be linked to changes in H2O2 concentrations, whereas the changes on Callisto may be linked to variability in SO2 concentration. 相似文献
7.
Vladimir A. Krasnopolsky 《Icarus》2011,215(1):197-203
The vertical profile of H2SO4 vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H2O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H2O and H2SO4 and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H2SO4 vapor mixing ratio is ∼10−12 at 70 and 110 km with a deep minimum of 3 × 10−18 at 88 km. The H2O-H2SO4 system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H2SO4 is 1.6 × 105 cm−2 s−1 at 70 km and 23 cm−2 s−1 at 90 km. The calculated abundance of H2SO4 vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 106 and 109, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H2SO4 (impossible for a source of SOX), and cross sections for H2SO4·H2O (impossible above the pure H2SO4) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SOX at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SOX on Venus remains unclear and probably does not exist. 相似文献
8.
We report 12.6-cm-wavelength radar observations of Europa, Ganymede, and Callisto made at the Arecibo Observatory in November 1977 and February 1979. When combined with previous observations, our results establish firmly the distinguishing radar properties of these satellites: (i) high geometric albedos, α; (ii) circular polarization ratios, μC, which anomalously exceed unity; (iii) linear polarization ratios, μL, which are approximately 0.5; and (iv) diffuse scattering which varies as cosnθ, where θ is angle of incidence and 1 ? n ? 2. We tabulate weighted-mean values of α, μC, μL, and n derived from observations between 1975 and 1979. The values of μC for Ganymede and Europa are nearly identical and significantly larger than that for Callisto. The values of n for Ganymede and Callisto are nearly identical and significantly smaller than that for Europa. Although significant albedo and/or polarization features are common in the radar spectra, the fractional rms fluctuation in disk-integrated properties is only ～10%. No time variation in the radar properties has been evident during 1976–1979. 相似文献
9.
Infrared spectra and radiation chemical behavior of N2-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N2-rich ices containing CH4 and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH2N2) form in the solid phase, along with several radicals. NH3 is also identified in irradiated N2 + CH4 and N2 + CH4 + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N2/CH4 ratios from 100 to 4, and in three-component mixtures have an initial N2/(CH4 + CO) ratio of 50. HCN and HNC are not detected in N2-dominated ices when CH4 is replaced with C2H6, C2H2, or CH3OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N2 + CH4 and N2 + CH4 + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N2-rich ices containing CH4.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH3) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN−, CN−, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH3, NH4OCN, and NH4CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides. 相似文献
10.
V. I. Shematovich 《Solar System Research》2008,42(6):473-487
The processes of the formation and dynamics of tenuous gaseous envelopes of icy moons in giant-planet systems are considered. Tenuous exospheres with relatively dense surface layers are likely to form around more massive icy satellites, such as, for example, the Galilean satellites Europa and Ganymede in the Jovian system. Escaping exospheres are formed in the case of low-mass icy moons, as happens for the icy satellite Enceladus in the Saturnian system. The main parent component of such gaseous envelopes is water vapor, which enters into the atmosphere as a result of thermal degassing processes, nonthermal radiolysis, and other active processes and phenomena on the icy surface of a satellite. A numerical kinetic model has been developed to study on a molecular level the processes of the formation, chemical evolution, and dynamics of tenuous gaseous envelopes dominated mainly by H2O. The ionization processes in such tenuous gaseous envelopes are caused by solar ultraviolet (UV) radiation and solar-wind and/or magnetospheric plasma. The primary processes when ultraviolet solar photons and plasma electrons affect the tenuous gas of the H2O-dominated atmosphere are responsible for the chemical diversity of the gaseous envelopes of icy moons. Ionization chemistry, including ion-molecular reactions, dissociative recombination of molecular ions, and the reactions of the charge exchange with magnetospheric ions, is important for the formation of chemical diversity in gaseous envelopes of icy satellites. The model considered in the study was used to numerically simulate the formation and development of chemical diversity in the tenuous gaseous envelope of Enceladus. The numerical results were compared to the direct Cassini measurements during its close flyby near Enceladus. 相似文献
11.
We report laboratory studies on the 0.8 MeV proton irradiation of ices composed of sulfuric acid (H2SO4), sulfuric acid monohydrate (H2SO4·H2O), and sulfuric acid tetrahydrate (H2SO4·4H2O) between 10 and 180 K. Using infrared spectroscopy, we identify the main radiation products as H2O, SO2, (S2O3)x, H3O+, , and . At high radiation doses, we find that H2SO4 molecules are destroyed completely and that H2SO4·H2O is formed on subsequent warming. This hydrate is significantly more stable to radiolytic destruction than pure H2SO4, falling to an equilibrium relative abundance of 50% of its original value on prolonged irradiation. Unlike either pure H2SO4 or H2SO4·H2O, the loss of H2SO4·4H2O exhibits a strong temperature dependence, as the tetrahydrate is essentially unchanged at the highest irradiation temperatures and completely destroyed at the lowest ones, which we speculate is due to a combination of radiolytic destruction and amorphization. Furthermore, at the lower temperatures it is clear that irradiation causes the tetrahydrate spectrum to transition to one that closely resembles the monohydrate spectrum. Extrapolating our results to Europa’s surface, we speculate that the variations in SO2 concentrations observed in the chaotic terrains are a result of radiation processing of lower hydration states of sulfuric acid and that the monohydrate will remain stable on the surface over geological times, while the tetrahydrate will remain stable in the warmer regions but be destroyed in the colder regions, unless it can be reformed by other processes, such as thermal reactions induced by diurnal cycling. 相似文献
12.
We present near-IR spectra of solid CO2 in H2O and CH3OH, and find they are significantly different from that of pure solid CO2. Peaks not present in either pure H2O or pure CO2 spectra become evident when the two are mixed. First, the putative theoretically forbidden CO2 (2ν3) overtone near 2.134 μm (4685 cm−1), that is absent from our spectrum of pure solid CO2, is prominent in the spectra of H2O/CO2=5 and 25 mixtures. Second, a 2.74-μm (3650 cm−1) dangling OH feature of H2O (and a potentially related peak at 1.89 μm) appear in the spectra of CO2-H2O ice mixtures, but are probably not diagnostic of the presence of CO2. Other CO2 peaks display shifts in position and increased width because of intermolecular interactions with H2O. Warming causes some peak positions and profiles in the spectrum of a H2O/CO2=5 mixture to take on the appearance of pure CO2. Absolute strengths for absorptions of CO2 in solid H2O are estimated. Similar results are observed for CO2 in solid CH3OH. Since the CO2 (2ν3) overtone near 2.134 μm (4685 cm−1) is not present in pure CO2 but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO2 is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies. 相似文献
13.
The four Galilean satellites are thought to harbor one or even two global internal liquid layers beneath their surface layer. The iron core of Io and Ganymede is most likely (partially) liquid and also the core of Europa may be liquid. Furthermore, there are strong indications for the existence of a subsurface ocean in Europa, Ganymede, and Callisto. Here, we investigate whether libration observations can be used to prove the existence of these liquid layers and to constrain the thickness of the overlying solid layers. For Io, the presence of a small liquid core increases the libration of the mantle by a few percent with respect to an entirely solid Io and mantle libration observations could be used to determine the mantle thickness with a precision of several tens of kilometers given that the libration amplitude can be measured with a precision of 1 m. For Europa, Ganymede, and Callisto, the presence of a water ocean close to the surface increases by at least an order of magnitude the ice shell libration amplitude with respect to an entirely solid satellite. The shell libration depends essentially on the shell thickness and to a minor extent on the density difference between the ocean and the ice shell. The possible presence of a liquid core inside Europa and Ganymede has no noticeable influence on their shell libration. For a precision of several meters on the libration measurements, in agreement with the expected accuracy with the NASA/ESA EJSM orbiter mission to Europa and Ganymede, an error on the shell thickness of a few tens kilometers is expected. Therefore, libration measurements can be used to detect liquid layers such as Io’s core or water subsurface oceans in Europa, Ganymede, and Callisto and to constrain the thickness of the overlying solid surface layers. 相似文献
14.
In situ measurements of stratospheric H2SO4 and HSO3vapors using passive chemical ionization mass spectrometry were made in October 1982 after the eruption of volcano El Chichon. Data were obtained between about 20 and 41 km showing [H2SO4 + HSO3] sum concentrations between about 104 and 2 × 105 cm?3 below 29 km and a steep rise above this altitude. Maximum [H2SO4 + HSO3] values of about 3 × 106 cm?3 are reached above 35 km.Partial [HSO3] concentrations increase above 34 km reaching about around 40 km. From the measurements it is concluded that H2SO4 and probably HSO3photolysis have an important influence above 34 km leading to the observed increase of [HSO3] and a depletion of H2SO4vapor.It also seems that the data support the view of heterogeneous HSO3 removal. If correct, this would imply that stratospheric aerosols are formed primarily from HSO3 rather than H2SO4vapor. 相似文献
15.
Ices in the solar system are observed on the surface of planets, satellites, comets and asteroids where they are continuously subordinate at particle fluxes (cosmic ions, solar wind and charged particles caught in the magnetosphere of the planets) that deeply modify their physical and structural properties. Each incoming ion destroys molecular bonds producing fragments that, by recombination, form new molecules also different from the original ones. Moreover, if the incoming ion is reactive (H+, On+, Sn+, etc.), it can concur to the formation of new molecules.Those effects can be studied by laboratory experiments where, with some limitation, it is possible to reproduce the astrophysical environments of planetary ices.In this work, we describe some experiments of 15-100 keV H+ and He+ implantation in pure sulfur dioxide (SO2) at 16 and 80 K and carbon dioxide (CO2) at 16 K ices aimed to search for the formation of new molecules. Among other results we confirm that carbonic acid (H2CO3) is formed after H-implantation in CO2, vice versa H-implantation in SO2 at both temperatures does not produce measurable quantity of sulfurous acid (H2SO3). The results are discussed in the light of their relevance to the chemistry of some solar system objects, particularly of Io, the innermost of Jupiter's Galilean satellites, that exhibits a surface very rich in frost SO2 and it is continuously bombarded with H+ ions caught in Jupiter's magnetosphere. 相似文献
16.
We have measured the bulk radar reflectance properties of the mid-size saturnian satellites Rhea, Dione, Tethys, and Enceladus with the Arecibo Observatory's 13 cm wavelength radar system during the 2004 through 2007 oppositions of the Saturn system. Comparing to the better studied icy Galilean satellites, we find that the total reflectivities of Rhea and Tethys are most similar to Ganymede while Dione is most similar to Callisto. Enceladus' reflectivity falls between those of Ganymede and Europa. The mean circular polarization ratios of the saturnian satellites range from ∼0.8 to 1.2, and are on average lower than those of the icy Galilean satellites at this wavelength although still larger than expected for single reflections off the surface. The ratio for the trailing hemisphere of Enceladus may be the exception with a value ?0.56. The 13 cm wavelength radar albedos and polarization ratios may be systematically lower than similar results from the Cassini orbiter's RADAR instrument at 2.2 cm wavelength [Ostro, S.J., and 19 colleagues, 2006. Icarus 183, 479-490]. Overall, these reflectivities and polarization properties, together with the shapes of the echo spectra, suggest subsurface multiple scattering to be the dominant reflection mechanism although operating less efficiently than on the large icy moons of Jupiter. All these saturnian moons and icy jovian moons are atmosphere-less, low temperature water ice surfaces, and any differences in radar properties may be indicative of differences in composition or the effects of various processes that modify the regolith structure. The degree of variation in radar properties with wavelength on each satellite may constrain the thickness and efficiency of the scattering layer. 相似文献
17.
Xiaoning Pan 《Icarus》2004,172(2):521-525
Hydrogen peroxide (H2O2) is one of the minor constituents of the water ice covered surfaces of the jovian satellites Europa, Ganymede, and Callisto. Here we demonstrate that H2O2 production may be initiated by the dissociative electron attachment (DEA) of low-energy electrons (LEEs) to water molecules. Electronic excitation or ionization by electrons also contributes to H2O2 formation at higher electron energies. Finally, we show that hydroperoxyl (HO2) radicals could be formed on the surfaces of icy satellites by LEE impact. 相似文献
18.
The surface composition of Europa is of special interest due to the information it might provide regarding the presence of a subsurface ocean. One source of this information is the infrared reflectance spectrum. Certain surface regions of Europa exhibit distorted H2O vibrational overtone bands in the 1.5 and 2.0 μm region, as measured by the Galileo mission Near Infrared Mapping Spectrometer (NIMS). These bands are clearly the result of highly concentrated solvated contaminants. However, two interpretations of their identity have been presented. One emphasizes hydrated salt minerals and the other sulfuric acid, although each does not specifically rule out some of the other. It has been pointed out that accurate chemical identification of the surface composition must depend on integrating spectral data with geochemical models, and information on the tenuous atmosphere sputtered from the surface. It is also extremely important to apply detailed chemistry when interpreting the spectral data, including knowledge of mineral dissolution chemistry and the subsequent optical signatures of ion solvation in low-temperature ice. We present studies of flash frozen acid and salt mixtures as Europa surface analogs and demonstrate that solvated protons, metal cations and inorganic anions all influence the spectra and must all, collectively, be considered when assigning Europa spectral features. These laboratory data show best correlation with NIMS Europa spectra for multi-component mixtures of sodium and magnesium bearing sulfate salts mixed with sulfuric acid. The data provide a concentration upper bound of 50-mol% for MgSO4 and 40-mol% for Na2SO4. This newly reported higher sodium and proton content is consistent with low-temperature aqueous differentiation and hydrothermal processing of carbonaceous chondrite-forming materials during the formation and early evolution of Europa. 相似文献
19.
The near infrared spectral reflectance of pure CH4, CO2, H2O, H2S, NH3 and NH4SH frosts has been measured. Comparison with recent Galilean satellite spectra indicates that H2O at approximately 150°K and with about 0.01 cm grain size is the major component on the surface of JII (Europa) and JIII (Ganymede); upper limits for the remaining frosts range from 5 to 28%. Materials other than these frosts must be present on the surface of JI (Io) and JIV (Callisto). 相似文献
20.
V. V. Busarev 《Solar System Research》2014,48(1):48-61
The results of ground-based spectrophotometry of the icy Galilean satellites of Jupiter—Europa, Ganymede, and Callisto—are discussed. The observations were carried out in the 0.39–0.92 μm range with the use of the CCD spectrometer mounted on the 1.25-m telescope of the Crimean laboratory of the Sternberg Astronomical Institute in March 2004. It is noted that the calculated reflectance spectra of the satellites mainly agree with the analogous data of the earlier ground-based observations and investigations in the Voyager and Galileo space missions. The present study was aimed at identifying new weak absorption bands (with the relative intensity of ～3–5%) in the reflectance spectra of these bodies with laboratory measurements (Landau et al., 1962; Ramaprasad et al., 1978; Burns, 1993; Busarev et al., 2008). It has been ascertained that the spectra of all of the considered objects contain weak absorption bands of molecular oxygen adsorbed into water ice, which is apparently caused by the radiative implantation of O+ ions into the surface material of the satellites in the magnetosphere of Jupiter. At the same time, spectral features of iron of different valence (Fe2+ and Fe3+) values typical of hydrated silicates were detected on Ganymede and Callisto, while probable indications of methane of presumably endogenous origin, adsorbed into water ice, were found on Europa. The reflectance spectra of the icy Galilean satellites were compared to the reflectance spectra of the asteroids 51 Nemausa (C-class) and 92 Undina (X-class). 相似文献