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1.
The spectrophotometric (0.39 < λ < 0.7 λm) properties of three particle-size fractions (diameters <10 λm, <150 λm, and 420–850 λm) of sulfur have been investigated in the laboratory. Particle size, temperature, thermal history, and scattering geometry are all shown to influence the spectral reflectance of the normal (S8) sulfur samples and an “orange-colored” S8 sample produced by quenching molten sulfur. A scattering law consisting of a linear combination of lunar-like and Lambertian terms adequately describes the data for all particle sizes. Where sulfur is darkest (λ < 0.45 λm), the reflectance decreases with increasing particle size, whereas where sulfur is brightest (λ > 0.45 λm) the reflectance increases with decreasing particle size. In reflected light, the long wavelength edge of the strong ultraviolet absorption retreats smoothly to shorter wavelengths with decreasing temperature at ～1.6Å/°K, a value lower than the 2.2Å/°K value previously reported for transmitted light. Near opposition, sulfur powders are found to follow closely a Minnaert limb darkening law except where the reflectance is low, i.e., in the strong ultraviolet absorption band of the larger particle size fractions. It is clear from our data that quantitative comparisons between disk-integrated observations of Io and laboratory measurements of flat samples of sulfur are not adequate unless temperature effects and changes in scattering geometry are included.  相似文献   

2.
Abstract— The lunar soil characterization consortium, a group of lunar‐sample and remote‐sensing scientists, has undertaken the extensive task of characterization of the finest fractions of lunar soils, with respect to their mineralogical and chemical makeup. These compositional data form the basis for integration and modeling with the reflectance spectra of these same soil fractions. This endeavor is aimed at deciphering the effects of space weathering of soils on airless bodies with quantification of the links between remotely sensed reflectance spectra and composition. A beneficial byproduct is an understanding of the complexities involved in the formation of lunar soil. Several significant findings have been documented in the study of the <45 μm size fractions of selected Apollo 17 mare soils. As grain size decreases, the abundance of agglutinitic glass increases, as does the plagioclase, whereas the other minerals decrease. The composition of the agglutinitic glass is relatively constant for all size fractions, being more feldspathic than any of the bulk compositions; notably, TiO2 is substantially depleted in the agglutinitic glass. However, as grain size decreases, the bulk composition of each size fraction continuously changes, becoming more Al‐rich and Fe‐poor, and approaches the composition of the agglutinitic glasses. Between the smallest grain sizes (10–20 and < 10 μm), the IS/FeO values (amount of total iron present as nanophase Fe0) increase by greater than 100% (>2x), whereas the abundance of agglutinitic glass increases by only 10–15%. This is evidence for a large contribution from surface‐correlated nanophase Fe0 to the IS/FeO values, particularly in the <10 μm size fraction. The surface nanophase Fe0 is present largely as vapor‐deposited patinas on the surfaces of almost every particle of the mature soils, and to a lesser degree for the immature soils (Keller et al., 1999a). It is reasoned that the vapor‐deposited patinas may have far greater effects upon reflectance spectra of mare soils than the agglutinitic Fe0.  相似文献   

3.
《Icarus》1987,72(3):492-506
The effects of particle size and mineral proportions on the spectral characteristics of plagioclase and pyroxene mixtures are investigated. Size separates (<25 μm, 25–45 μm, 45–75 μm, 75–125 μm, 125–250 μm, and 250–500 μm) have been prepared for the following labradorite/enstatite compositional mixtures: 100/0%, 95/5%, 85/15%, 50/50%, and 0/100%. Spectrally, the labradorite and enstatite samples are representative of the plagioclase feldspars and the orthopyroxenes: the labradorite exhibits a weak, broadband centered near 1.25 μm and the enstatite exhibits two well-defined bands centered near 0.9 and 1.9 μm. From analysis of the plagioclase bands of the mixtures, it is found that (1) the amount of plagioclase necessary for the plagioclase band to be observed as a discrete absorption band is dependent on particle size and (2) plagioclase can be detected by flattening of the pyroxene reflectance “peak” between the 0.9- and 1.9-μm absorption bands if significant amounts of plagioclase are present. Analogs for immature and mature lunar highland soils have been created to examine the combined effects of particle size and mineral proportions on spectra of plagioclase and pyroxene mixtures. bidirectional reflectance spectra of these soil analogs are used to examine the detectability of plagioclase in soil-like particle size distributions. Plagioclase in significant amounts is detected by the flattening of the pyroxene reflectance “peak” between the 0.9- and 1.9-μm absorption bands, and the plagioclase absorption band itself is observed with 85% plagioclase present. The soil analogs reveal that particle size accounts for only a minor spectral difference between immature and mature lunar highland soils. From comparisons with spectra of returned lunar samples, agglutinates are found to dominate the spectral variations associated with soil maturity. Spectra of the immature soil analogs can be used to estimate the minimum pyroxene abundance for immature regions observed remotely.  相似文献   

4.
Infrared radiation spectra of Mars which can be measured by an orbiting Planetary Fourier Spectrometer (PFS) have been simulated in the spectral region from 1 to 50 μm. The radiative transfer simulation technique considers absorption, emission and multiple scattering by molecular (CO2, H2O, CO) and particulate (palagonite) species. It is shown that the contribution from atmospheric dust extinction and surface reflectance can be separated in the region of the CO2 bands at 2.0 and 2.7 μm. Quantitative results of simultaneous surface pressure, reflectance and aerosol optical depth retrievals are discussed.  相似文献   

5.
Abstract— The fine fraction of lunar soils (<45 μm) dominates the optical properties of the bulk soil. Definite trends can be seen in optical properties of size separates with decreasing particle size: diminished spectral contrast and a steeper continuum slope. These trends are related to space weathering processes and their affects on different size fractions. The finest fraction (defined here as the <10 μm fraction) appears to be enriched in weathering products relative to the larger size fractions, as would be expected for surface correlated processes. This <10 μm fraction tends to exhibit very little spectral contrast, often with no distinguishable ferrous iron absorption bands. Additionally, the finest fractions of highland soils are observed to have very different spectral properties than the equivalent fraction of mare soils when compared with larger size fractions. The spectra of the finest fraction of feldspathic soils flatten at longer wavelengths, whereas those of the finest fraction of basaltic soils continue to increase in a steep, almost linear fashion. This compositional distinction is due to differences in the total amount of nanophase iron that accumulates in space weathering products. Such ground‐truth information derived from the <10 μm fraction of lunar soils provides valuable insight into optical properties to be expected in other space weathering environments such as the asteroids and Mercury.  相似文献   

6.
The apparent strength of absorptions due to H2O near 1.9 and 3 μm in reflectance spectra is strongly affected by sample albedo. This study uses experimental and analytical approaches to quantify the effects of albedo on estimating the water content of hydrated minerals using various band parameters. We compare spectral band parameters for a series of low-albedo physical and numerical mixtures to measured water contents. Physical experiments consist of montmorillonite, clinoptilolite, and palagonite mixed with lesser amounts of carbon black and ilmenite, whereas numerical mixtures are composed of these host minerals mixed with a material of constant, low albedo. We find the effective single-particle absorption-thickness parameter provides the best correlation to water content, independent of composition and albedo, when derived from continuum-removed single scattering albedo spectra. Uncertainties in estimated water content are on the order of ±1 wt% using this method. The normalized optical path length parameter provides the best correlation to water content when using reflectance spectra, yielding estimates within ±1.6 wt% H2O. The accuracy of these models is related to the physical nature of the darkening material. Scattering and absorption efficiencies are easier to model for intimate mixtures containing relatively large, dark grains than mixtures dominated by coatings of a fine-grained, strongly absorbing material. This suggests the physical properties that give rise to the albedo of a material are an important factor for accurate estimates of absolute water content.  相似文献   

7.
Spectra from the Voyager 1 infrared interferometer spectrometer (IRIS) obtained near the time of closest approach to Jupiter were analyzed for the purpose of inferring ammonia cloud properties associated with the Equatorial Region. Comparisons of observed spectra with synthetic spectra computed from a radiative transfer formulation, that includes multiple scattering, yielded the following conclusions: (1) very few NH3 ice particles with radii less than 3 μm contribute to the cloud opacity; (2) the major source of cloud opacity arises from particles with radii in excess of 30 μm; (3) column particle densities are between 1 and 2 orders of magnitude smaller than those derived from thermochemical considerations alone, implying the presence of important atmospheric motion; and (4) another cloud system is confirmed to exist deeper in the Jovian troposphere.  相似文献   

8.
Abstract— Previous workers have shown that an impact ejecta layer at Massignano, Italy contains a positive Ir anomaly, flattened spheroids (pancake spherules), Ni‐rich spinel crystals, and shocked quartz with multiple sets of planar deformation features. Because of sample sizes and work by different investigators, it was not clear if the shocked quartz is associated with the Ir anomaly and pancake spherules or if it belongs to a separate impact event. To address this problem, we carried out a high‐resolution stratigraphic study of this ejecta layer. The ejecta layer was sampled continuously at 1 cm intervals in two adjacent columns. The carbonate was removed with dilute HCl, and the non‐carbonate fraction was gently sieved. Pancake spherules were recovered from the 250–500 μm size fraction and counted. At the peak abundance, the number of pancake spherules in the 250–500 μm size fraction is about 6–7/g of sample. The pancake spherules removed from the 250–500 μm size fraction are mostly translucent to opaque pale green, but some have a grey color or dark opaque patches due to a coating of Ni‐ and Cr‐rich spinel crystals. Energy‐dispersive X‐ray analysis and X‐ray diffraction data indicate that the green spherules are composed of iron‐rich smectite, probably nontronite. Black opaque spinel stringers (dark spinel‐rich pancake spherules), usually <200 μm across, can be seen in a polished section of a block that includes the ejecta layer. None of the dark spinel‐rich pancake spherules were recovered from the sieved non‐carbonate fraction due to their fragile nature, but we believe that they are from the same impact event as the green pancake spherules. The <250 μm size fractions from both columns were disaggregated using ultrasonics and re‐sieved. The 63–125 μm size fractions were then searched for shocked quartz using a petrographic microscope. At the peak‐abundance level, the number of shocked quartz grains in the 63–125 μm size fraction is about 7/g of sample. Some of the shocked quartz grains have a “toasted” appearance. These grains have a brownish color and contain a patchy distribution of faint, densely spaced planar deformation features (PDFs). Polymineralic fragments containing one or two shocked quartz grains with one or two sets of PDFs were observed. They appear to have an organic matrix and are probably fragments of agglutinated foraminiferal tests. We searched for, but did not find, coesite or shocked zircons. We found that the peak abundance of the shocked quartz is within a centimeter of the peak abundance of the green pancake spherules. We conclude that the pancake spherules are diagenetically altered clinopyroxene‐bearing spherules and that the shocked quartz, green (and presumably the dark spinel‐rich) pancake spherules, and Ir anomaly all belong to the same impact event. This conclusion is consistent with previous suggestions that the cpx spherule layer may be from the 100 km‐diameter Popigai impact crater in northern Siberia.  相似文献   

9.
We report high-spectral-resolution (λ/δλ = 800-2300) near-infrared mapping observations of Mars at Ls = 130° (April 1999), which were obtained by drift-scanning the cryogenic long-slit spectrometer at the KPNO 2.2-m telescope across the disk. Data were reformatted into calibrated spectral image cubes (x,y,λ) spanning 2.19 to 4.12 μm, which distinguish atmospheric CO2 features, solar lines, and surface and aerosol features. Maps of relative band depth between 3.0 and 3.5 μm trace water ice clouds and show the diurnal evolution of features in the persistent northern summer aphelion cloud belt, which was mapped contemporaneously but at fixed local time by the Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES). Cloud optical depth, particle sizes, and ice aerosol content were estimated using a two-stream, single-layer scattering model, with Mie coefficients derived from recently published ice optical constants, followed by a linear spectral deconvolution process. A comparison of data and model spectra shows evaporating nighttime clouds in the morning followed by afternoon growth of a prominent orographic cloud feature on the west flank of Elysium Mons. Cloud optical depth at 3.2 μm evolved to 0.28 ± 0.13 and ice aerosol column abundance to 0.9 ± 0.3 pr μm in the afternoon. Column abundances as large as 0.17 pr μm were retrieved in nonorographic clouds within the aphelion cloud band around midday. These clouds exhibit a modest decline in optical depth during the afternoon. Results show that ice particle radii from <2 μm to >4 μm exist in both cloud types. However, large particles dominate the spectra, consistent with recent MGS/TES emission phase function measurements of aphelion cloud aerosol properties.  相似文献   

10.
Patricia Gavin  Vincent Chevrier 《Icarus》2010,208(2):721-12100
To test the effects of meteorite impacts on martian phyllosilicate deposits, we heated two smectites (nontronite and montmorillonite) to temperatures ranging from 350 °C to 1150 °C for durations of 4-24 h in two different atmospheres, under air and a steady flow of CO2. Samples were analyzed using X-ray diffraction (XRD) and near-infrared (NIR) and mid-infrared (MIR) reflectance spectroscopy. Interlayer water was lost after heating to temperatures of ∼400 °C. Between 400 °C and 700 °C, nontronite converted to an intermediary phase which conserved the XRD pattern of untreated nontronite with the exception of the 0 0 1 peak. Nanocrystalline high-temperature phases formed for both smectites at temperatures between 700 °C and 1000 °C. Finally, after being heated to temperatures above ∼1100 °C, the samples melted and recrystallized into secondary phases. Secondary high-temperature phases included sillimanite and cristobalite for both smectites plus hematite for nontronite. NIR and MIR reflectance spectra significantly evolved with increasing temperature. NIR spectra of smectites showed that 1.4 and 1.9 μm bands decrease in intensity and disappear above 700 °C. Similarly, the 2.2-2.3 μm metal-OH band showed a decrease in intensity as well as an overall shift towards lower wavelengths (for nontronite) due to the thermal resistance of the Al-OH bond compared to the Fe-OH bond. NIR spectra of montmorillonite showed a gradual increase in band depth up to temperatures between 500 °C and 600 °C, then decreased with increasing temperature. In the MIR spectra of samples heated to temperatures above ∼1100 °C, newly formed bands confirmed the secondary phases identified by XRD. Similarities between the NIR spectra of our heated samples and the phyllosilicates in some martian craters imply that these phyllosilicates were altered by the impact-generated heat and thus were not formed post-impact. In addition, NIR reflectance spectra provide a proxy for shock temperatures of smectites up to 700 °C while MIR is optimum for identification of high-temperature phases of smectites above 700 °C.  相似文献   

11.
Spectra taken by the Cassini Ultraviolet Imaging Spectrograph (UVIS) of Saturn’s C ring, B ring, Cassini Division, and A ring have been analyzed in order to characterize ring particle surface properties and water ice abundance in the rings. UVIS spectra sense the outer few microns of the ring particles. Spectra of the normalized reflectance (I/F) in all four regions show a characteristic water ice absorption feature near 165 nm. Our analysis shows that the fractional abundance of surface water ice is largest in the outer B ring and decreases by over a factor of 2 across the inner C ring. We calculate the mean path length of UV photons through icy ring particle regolith and the scattering asymmetry parameter using a Hapke reflectance model and a Shkuratov reflectance model to match the location of the water ice absorption edge in the data. Both models give similar retrieved values of the photon mean length, however the retrieved asymmetry (g) values are different. The photon mean path lengths are nearly uniform across the B and A rings. Shortward of 165 nm the rings exhibit a slope that turns up towards shorter wavelengths, while the UV slope of 180/150 nm (reflectance outside the water absorption ratioed to that inside the absorption band) tracks I/F with maxima in the outer B ring and in the central A ring. Retrieved values of the scattering asymmetry parameter show the regolith grains to be highly backscattering in the FUV spectral regime.  相似文献   

12.
Abstract Reflectance spectra were collected from chondritic interplanetary dust particles (IDPs), a polar micrometeorite, Allende (CV3) meteorite matrix, and mineral standards using a microscope spectrophotometer. Data were acquired over the 380–1100 nm wavelength range in darkfield mode using a halogen light source, particle aperturing diaphrams, and photomultiplier tube (PMT) detectors. Spectra collected from titanium oxide (Ti4O7), magnetite (Fe3O4), and Allende matrix establish that it is possible to measure indigenous reflectivities of micrometer-sized (>5 μm in diameter) particles over the visible (VIS) wavelength range 450–800 nm. Below 450 nm, small particle effects cause a fall-off in signal into the ultraviolet (UV). Near-infrared (IR) spectra collected from olivine and pyroxene standards suggest that the ～1 μm absorption features of Fe-bearing silicates in IDPs can be detected using microscope spectrophotometry. Chondritic IDPs are dark objects (<15% reflectivity) over the VIS 450–800 nm range. Large (>1 μm in diameter) embedded and adhering single mineral grains make IDPs significantly brighter, while surficial magnetite formed by frictional heating during atmospheric entry makes them darker. Most chondritic smooth (CS) IDPs, dominated by hydrated layer silicates, exhibit generally flat spectra with slight fall-off towards 800 nm, which is similar to type CI and CM meteorites and main-belt C-type asteroids. Most chondritic porous (CP) IDPs, dominated by anhydrous silicates (pyroxene and olivine), exhibit generally flat spectra with a slight rise towards 800 nm, which is similar to outer P and D asteroids. The most C-rich CP IDPs rise steeply towards 800 nm with a redness comparable to that of the outer asteroid object Pholus (Binzel, 1992). Chondritic porous IDPs are the first identified class of meteoritic materials exhibiting spectral reflectivities (between 450 and 800 nm) similar to those of P and D asteroids. Although large mineral grains, secondary magnetite, and small particle effects complicate interpretation of IDP reflectance spectra, microscope spectrophotometry appears to offer a rapid, nondestructive technique for probing the mineralogy of IDPs, comparing them with meteorites, investigating their parent body origins, and identifying IDPs that may have been strongly heated during atmospheric entry.  相似文献   

13.
Very low values of the radio brightness temperature of the rings of Saturn indicate that their high refar reflectivity is not simply due to a gain effect in the backscattering direction. These two sets of observations are consistent with the ring particles having a very high single scattering albedo at radio wavelenghts, with multiple scattering effects being important. Comparison of scattering calculations for ice and silicate particles with the radio and radar observations imply a mean particle radius of ～1 cm. The ice bands observed in the rings' near-infrared reflectivity spectra are formed by scattering within a microstructure on the surface of the ring particles, with the scattering centers being 25–125 μm in size. The Poynting-Robertson effect has caused a significant spiraling-in of the ring particles, probably resulting in a broadening of the rings. The inferred mean size is consistent with a model in which meteoroid impacts have caused a substantial reduction in the mean particle size from its initial value.  相似文献   

14.
The surface of Enceladus consists almost completely of water ice. As the band depths of water ice absorptions are sensitive to the size of particles, absorptions can be used to map variations of icy particles across the surface. The Visual and Infrared Mapping Spectrometer (VIMS) observed Enceladus with a high spatial resolution during three Cassini flybys in 2005 (orbits EN 003, EN 004 and EN 011). Based on these data we measured the band depths of water ice absorptions at 1.04, 1.25, 1.5, and 2 μm. These band depths were compared to water ice models that represent theoretically calculated reflectance spectra for a range of particle diameters between 2 μm and 1 mm. The agreement between the experimental (VIMS) and model values supports the assumption that pure water ice characterizes the surface of Enceladus and therefore that variations in band depth correspond to variations in water ice particle diameters. Our measurements show that the particle diameter of water ice increases toward younger tectonically altered surface units with the largest particles exposed in relatively “fresh” surface material. The smallest particles were generally found in old densely cratered terrains. The largest particles (∼0.2 mm) are concentrated in the so called “tiger stripes” at the south pole. In general, the particle diameters are strongly correlated with geologic features and surface ages, indicating a stratigraphic evolution of the surface that is caused by cryovolcanic resurfacing and impact gardening.  相似文献   

15.
The recent detection of up to ∼10 wt% water-equivalent H heterogeneously distributed in the upper meter of the equatorial regions of the martian surface and the presence of the 3-μm hydrations feature across the entire planet raises the question whether martian surficial dust can account for this water-equivalent H. We have investigated the H2O and CO2 adsorption properties of palagonitic dust (<5 μm size fraction of phyllosilicate-poor palagonitic tephra HWMK919) as a martian dust analog and two smectites under simulated martian equatorial surface conditions. Our results show that the palagonitic dust, which contains hydrated and hydroxylated volcanic glass of basaltic composition, accommodates significantly more H2O under comparable humidity and temperature conditions than do the smectites nontronite and montmorillonite.  相似文献   

16.
Photometric and polarimetric laboratory measurements were made as a function of phase angle in the U(0.36 μm), G(0.54 μm) and R(0.67 μm) bands for 0°, 30° and 60° incident illumination on four particle size ranges of Bruderheim, an L6 olivine-hypersthene chondritic meteorite. The four particle size ranges were: 0.25–4.76 mm, 0.25–4.76 mm coated with <74 μm powder, 74–250 μm, and <37 μm. In addition, normal reflectance measurements were made in the spectral range from 0.31 to 1.1 μm. Comparison with astronomical data reveals that none of the asteroids in the main belt for which adequate observations exist can be matched with Bruderheim, which is representative of the most common meteoritic material encountered by the Earth. However, it appears from the polarization and photometry data that the surface of the Apollo asteroid Icarus is consistent with an ordinary chondrite composition. This suggests the possibility that this material, although common in Earth-crossing orbits, is rare as a surface constituent in the main asteroid belt.  相似文献   

17.
Mariner 9 ultraviolet spectra of the 1971 dust clouds were analyzed to obtain the phase function times single scattering albedo of the dust particles. The phase functions were matched with Mie scattering calculations for size distributions of spheres of homogeneous and isotropic material. The absorption index of the dust particles was found to increase with decreasing wavelenght from 350 nm down to about 210 nm, and drop off shortward of this wavelength. A structural shoulder occurs in the absorption spectrum between 240 and 250 nm. Titanium dioxide (anatase) has the correct transitions at 210 and 250 nm to match the absorption curve of Martian dust, and is proposed as a candidate constituent in Martian surface material. The spectral neutrality of TiO2 between 0.5 and 4 μm is consistent with visible and infrared observations of Mars. The high refractive index of TiO2 can explain the large refringence of Martian dust. The titanium dioxide content of the dust particles is estimated to be a few percent or less. Uncertainties in the results due to limitations in the model and data are discussed.  相似文献   

18.
Abstract— The grain-size distribution of the regolith of asteroid 4 Vesta has been estimated by comparing its reflectance spectra (0.3–2.6 μm) with those of HED meteorites. The finest grain-size separate (<25 μm) of a particular howardite has a reflectance spectrum most similar to Vesta's. In order to better simulate Vesta's surface mineralogy, reflectance spectra of those finest HED meteorite powders were linearly combined, and Vesta's spectrum was scaled for the best fit between them. Both the albedo and the shape of reflectance spectrum of Vesta were well reproduced by regional mixtures of the finest (<25 μm) powders of HED meteorites. The result suggests the heterogeneity of Vesta's surface and provides an estimate of the visible reflectance of Vesta that is close to its IRAS albedo. Thus, this suggests that fine grains can be generated and retained by relatively small bodies (Vesta is approximately 500 km in diameter).  相似文献   

19.
Stéphane Erard  Wendy Calvin 《Icarus》1997,130(2):449-460
About 15 areas were observed in the equatorial regions of Mars by the infrared spectrometers IRS (Mariner 6 and 7) and ISM (Phobos-2). The comparison between the spectra shows a remarkable consistency between two data sets acquired 20 years apart and calibrated independently. This similarity demonstrates the accuracy of ISM calibration above 2 μm, except for a possible stray light contribution above 2.6 μm, on the order of ∼1–2% of the solar flux at 2.7 μm. Most differences in spectral shapes are related to differences in spectral/spatial resolution and viewing geometries. No important variation in surface properties is detected, except for a spot in southern Arabia Terra which has a much deeper hydration feature in IRS spectra; differences in viewing geometries and spatial resolutions do not seem to account for this difference that could result from shifting or dehydration of surface materials. Composite spectra of several types of bright and dark materials are computed by modeling the thermal emission and are completed with telescopic spectra in the visible range. Modeled reflectance in the 3.0–5.7 μm range is consistent with basalts and palagonites. The bright regions and analog palagonite spectra are different from hematite in this range, but resemble several phyllosilicates. We infer that (1) although hematite dominates the spectra in the 0.4- to 2.5-μm range, the silicate-clay host is spectrally active beyond 3 μm and can be identified from this domain; (2) phyllosilicates such as montmorillonite or smectite may be abundant components of the martian soils, although the domain below 3 μm lacks the characteristic features of the most usual terrestrial clay minerals.  相似文献   

20.
High-resolution (0.34 nm) reflectance spectra of a suite of terrestrial ortho- and clinopyroxenes were characterized in the 506-nm region. This region exhibits absorption bands attributed to spin-forbidden transitions in Fe2+ located in the M2, and possibly M1, crystallographic site(s). The most intense absorption bands (up to 3.8% deep in <45 μm fractions) are present in low Ca-content orthopyroxene spectra. This region exhibits two (spectral Group I) or more (spectral Group II) absorption bands in the 500-515 nm interval. Group I spectra are associated with the lowest Ca-content samples. For orthopyroxenes, the number of constituent absorption bands and band depths vary as a function of Ca content; increasing Ca content results the appearance of more than two absorption bands and a general reduction in band depths, offsetting an expected increase in band depth with increasing Fe2+ content; band depths may also be reduced due to the long wavelength wing of ultraviolet region Fe-O charge transfer absorptions. Band depths and shapes in this region are also a function of grain size, with the strongest bands appearing for larger grain sizes - in the 90-250 μm range. The number and position of constituent absorption bands can be used to constrain factors such as cooling rates, as expressed in the formation of Guinier-Preston zones versus coarser-grained augite exsolution lamellae. Band depths in the spectra of fine-grained (<45 μm) clinopyroxenes do not exceed 1% and are generally lowest for spectral type A clinopyroxenes, where most of the Fe2+ is present in the M1 crystallographic site. The appearance of the 506 nm band in the spectra of pyroxene-bearing asteroids can be used to constrain pyroxene composition and structure. The results of this study suggest that detailed analysis of absorption features in the 506 nm region is a powerful tool for determining the composition and structure of pyroxenes. The spectral resolution of the VIR-MS spectrometer aboard the Dawn spacecraft - which will examine Asteroid 4 Vesta, a body possessing surficial pyroxenes - will be sufficient to provide some constraints on pyroxene composition.  相似文献   

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