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1.
The O2 dayglow at 1.27 μm is formed by high-altitude ozone on Mars and is a sensitive tracer of Mars photochemistry. Mapping of this dayglow using the IRTF/CSHELL long-slit spectrograph requires the extraction of weak emission lines against a strong continuum of the reflected solar light. Some new tools are suggested to improve the data processing. The observed O2 dayglow intensities at LS=67°, 112°, 148°, and 173° show a decrease from late spring (aphelion) to fall equinox by a factor of ≈5 at low latitudes (±30°). This decrease agrees with that predicted by a model of Clancy and Nair (1996, J. Geophys. Res. 101 (12) 12785-12790), although the dayglow intensities are weaker than those based on that model. The measured dayglow variations with latitude are rather low at LS=67°, 112°, and 148° and unexpectedly high at 173°. The dayglow intensity peaks near noon and is smaller at 9:00 and 16:30 LT by a factor of 2. Some data on the ozone profile near aphelion are obtained from a combination of the dayglow and ozone observations. It is hardly possible to detect the O2 night airglow at 1.27 μm on Mars using the existing ground-based and on-orbit instruments. The O2 dayglow intensity as a function of latitude and season from aphelion to fall equinox has been obtained. Our goal is to extend this distribution to the full martian year and get a database for Mars photochemistry to complement the MGS/TES observations of water vapor, atmospheric temperature, and dust and ice aerosol.  相似文献   

2.
There is a significant progress in the observational data relevant to Mars photochemistry in the current decade. These data are not covered by and sometimes disagree with the published models. Therefore we consider three types of models for Mars photochemistry. A steady-state model for global-mean conditions is currently the only way to calculate the abundances of long living species (H2, O2, and CO). However, our model does not fit the observed CO abundance using gas-phase chemistry and reasonable values of heterogeneous loss of odd hydrogen on the water ice aerosol. The second type of the calculated models is steady-state models for local conditions. The MGS/TES data on temperature profiles, H2O, and dust are input parameters for these models. The calculations have been made for nine seasonal points spread over the martian year and for twelve latitudes with a step of 10° for each season. The only adopted heterogeneous reaction is a weak loss of H2O2 on water ice with probability of 5×10−4. The results are in good agreement with the recent observations of the O2 dayglow at 1.27 μm and the O3 and H2O2 abundances. Global maps of the seasonal and latitudinal behavior of these species have been made. The third type of models is a time-dependent model for local conditions. These models show that odd hydrogen quickly converts to H2O2 at the nighttime and the chemistry is switched off while the association of O, the heterogeneous loss of H2O2, and eddy diffusion continue. This requires significant changes in the global-mean and local steady-state models discussed above, and these changes have been properly done. The calculated diurnal variations of Mars photochemistry are discussed. The martian photochemistry at low and middle latitudes is significantly different in the aphelion period at LS=10°-130° from that in the remaining part of the year.  相似文献   

3.
Venus was observed at 2.4 and 3.7 μm with a resolving power of 4×104 using the long-slit high-resolution spectrograph CSHELL at NASA IRTF. The observations were made along a chord that covered a latitude range of ± 60° at a local time near 8:00. The continuous reflectivity and limb brightening at 2.4 μm are fitted by the clouds with a single scattering albedo 1−a=0.01 and a pure absorbing layer with τ=0.09 above the clouds. The value of 1−a agrees with the refractive index of H2SO4 (85%) and the particle radius of 1 μm. The absorbing layer is similar to that observed by the UV spectrometer at the Pioneer Venus orbiter. However, its nature is puzzling. CO2 was measured using its R32 and R34 lines. The retrieved product of the CO2 abundance and airmass is constant at 1.9 km-atm along the instrument slit in the latitude range of ± 60°. The CO mixing ratio (measured using the P21 line) is rather constant at 70 ppm, and its variations of ∼10% may be caused by atmospheric dynamics. The observed value is higher than the 50 ppm retrieved previously from a spectrum of the full disk, possibly, because of some downward extension of the mesospheric morningside bulge of CO. The observations of the HF R3 line reveal a constant HF mixing ratio of 3.5±0.5 ppb within ± 60° of latitude, which is within the scatter in the previous measurements of HF. OCS has been detected for the first time at the cloud tops by summing 17 lines of the P-branch. The previous detections of OCS refer to the lower atmosphere at 30-35 km. The retrieved OCS mixing ratio varies with a scale height of 1 to 3 km. The mean OCS mixing ratio is ∼2 ppb at 70 km and ∼14 ppb at 64 km. Vertical motions in the atmosphere may change the OCS abundance. The detected OCS should significantly affect Venus' photochemistry. A sensitive search for H2S using its line at 2688.93 cm−1 results in a 3 sigma upper limit of 23 ppb, which is more restrictive than the previous limit of 100 ppb.  相似文献   

4.
The detection of CH4 in the martian atmosphere, at a mixing ratio of about 10 ppb, prompted Krasnopolsky et al. [Krasnopolsky, V.A., Maillard, J.P., Owen, T.C., 2004. Icarus 172, 537-547] and Krasnopolsky [Krasnopolsky, V.A., 2006. Icarus 180, 359-367] to propose that the CH4 is of biogenic origin. Bar-Nun and Dimitrov [Bar-Nun, A., Dimitrov, V., 2006. Icarus 181, 320-322] proposed that CH4 can be formed in the martian atmosphere by photolysis of H2O in the presence of CO. We based our arguments on a clear demonstration that CH4 is formed in our experiments, and on thermodynamic equilibrium calculations, which show that CH4 formation is favored even in the presence of oxygen at a mixing ratio 1.3×10−3, as observed on Mars. In the present comment, Krasnopolsky [Krasnopolsky, V.A., 2007. Icarus, in press (this issue)] presents his arguments against the suggestion of Bar-Nun and Dimitrov [Bar-Nun, A., Dimitrov, V., 2006. Icarus 181, 320-322], based on the effect of O2 on CH4 formation, the absence of kinetic pathways for CH4 formation and on the inadequacy of thermodynamic equilibrium calculations to describe the martian atmosphere. In this rebuttal we demonstrate that experiments with molecular oxygen at a ratio of O2/CO2=(8.9-17)×10−3, exceeding the martian ratio, still form CH4. Thermodynamic equilibrium calculations replicate the experimental CH4 mixing ratio to within a factor of 1.9 and demonstrate that CH4 production is favored in the martian atmosphere, which is obviously not in thermodynamic equilibrium. Consequently, we do not find the presence of methane to be a sign of biological activity on Mars.  相似文献   

5.
Variations of the upper cloud boundary and the CO, HF, and HCl mixing ratios were observed using the CSHELL spectrograph at NASA IRTF. The observations were made in three sessions (October 2007, January 2009, and June 2009) at early morning and late afternoon on Venus in the latitude range of ±60°. CO2 lines at 2.25 μm reveal variations of the cloud aerosol density (∼25%) and scale height near 65 km. The measured reflectivity of Venus at low latitudes is 0.7 at 2.25 μm and 0.028 at 3.66 μm, and the effective CO2 column density is smaller at 3.66 μm than those at 2.25 μm by a factor of 4. This agrees with the almost conservative multiple scattering at 2.25 μm and single scattering in the almost black aerosol at 3.66 μm. The expected difference is just a factor of (1 − g)−1 = 4, where g = 0.75 is the scattering asymmetry factor for Venus’ clouds. The observed CO mixing ratio is 52 ± 4 ppm near 08:00 and 40 ± 4 ppm near 16:30 at 68 km, and the higher ratio in the morning may be caused by extension of the CO morningside bulge to the cloud tops. The observed weak limb brightening in CO indicates an increase of the CO mixing ratio with altitude. HF is constant at 3.5 ± 0.2 ppb at 68 km in both morningside and afternoon observations and in the latitude range ±60°. Therefore the observations do not favor a bulge of HF, though HF is lighter than CO. Probably a source in the upper atmosphere facilitates the bulge formation. The recent measurements of HCl near 70 km are controversial (0.1 and 0.74 ppm) and require either a strong sink or a strong source of HCl in the clouds. The HCl lines of the (2-0) band are blended by the solar and telluric lines. Therefore we observed the P8 lines of the (1-0) band at 3.44 μm. These lines are spectrally clean and result in the HCl mixing ratio of 0.40 ± 0.03 ppm at 74 km. HCl does not vary with latitude within ±60°. Our observations support a uniformly mixed HCl throughout the Venus atmosphere.  相似文献   

6.
Lori M. Feaga  Melissa McGrath 《Icarus》2009,201(2):570-1189
An extensive set of HI Lyman-α images obtained with the Hubble Space Telescope (HST) Space Telescope Imaging Spectrograph (STIS) from 1997-2001 has been analyzed to provide information about the spatial and temporal character of Io's SO2 atmosphere. An atmospheric distribution map derived from the observations reveals that the sunlit SO2 atmosphere is temporally stable on a global scale, with only small local changes. An anti-/sub-jovian asymmetry in the SO2 distribution is present in all 5 years of the observations. The average daytime atmosphere is densest on the anti-jovian hemisphere in the equatorial regions, with a maximum equatorial column density of 5.0×1016 cm−2 at 140° longitude. The SO2 atmosphere also has greater latitudinal extent on the anti-jovian hemisphere as compared to the sub-jovian. The atmospheric distribution appears to be best correlated with the location of hot spots and known volcanic plumes, although small number statistics for the plumes limits the correlation.  相似文献   

7.
D. Luz  F. Hourdin  S. Lebonnois 《Icarus》2003,166(2):343-358
We present a 2D general circulation model of Titan's atmosphere, coupling axisymmetric dynamics with haze microphysics, a simplified photochemistry and eddy mixing. We develop a parameterization of latitudinal eddy mixing by barotropic waves based on a shallow-water, longitude-latitude model. The parameterization acts locally and in real time both on passive tracers and momentum. The mixing coefficient varies exponentially with a measure of the barotropic instability of the mean zonal flow. The coupled GCM approximately reproduces the Voyager temperature measurements and the latitudinal contrasts in the distributions of HCN and C2H2, as well as the main features of the zonal wind retrieved from the 1989 stellar occultation. Wind velocities are consistent with the observed reversal time of the North-South albedo asymmetry of 5 terrestrial years. Model results support the hypothesis of a non-uniform distribution of infrared opacity as the cause of the Voyager temperature asymmetry. Transport by the mean meridional circulation, combined with polar vortex isolation may be at the origin of the latitudinal contrasts of trace species, with eddy mixing remaining restricted to low latitudes most of the Titan year. We interpret the contrasts as a signature of non-axisymmetric motions.  相似文献   

8.
We have analyzed spectra of CO recorded with the instrument PFS onboard Mars Express in the (1-0) band. The dataset we used ranges in time from January until June 2004 (LS=331°.17 until LS=51°.61; end of Mars Year 26, beginning of Mars Year 27). The aim of this work was to determine the amplitude of the CO mixing ratio departures from the mean globally averaged value currently admitted (8±3×10-4) [Kaplan, L.D., Connes, J., Connes, P., 1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187-L192] as a function of season, local time and location on the planet. We therefore processed the data from 90 calibrated orbits. The globally averaged CO mixing ratio value we derive from our dataset, 11.1×10-4, is compatible with the range found by Kaplan et al. [1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187-L192], although somewhat higher than the “standard” value. However, the CO mixing ratio we retrieve exhibits large variations (roughly between 3×10-4 and 18×10-4). Such relative variations have been used on a statistical basis to derive main trends as a function of latitude for three LS ranges: 331-360°, 0-30° and 30-52°. For the first LS range, we seem to have an enhancement of the CO mixing ratio towards the northern latitudes, probably linked to the CO2 condensation in winter on the north polar cap. The situation for the two other LS ranges is not so clear, mainly as we lack data on the southern hemisphere. We roughly agree with the work of Krasnopolsky [2007. Long-term spectroscopic observations of Mars using IRTF/CSHELL: mapping of O2 dayglow, CO and search for CH4. Icarus 190, 93-102] for LS=331-360°, thus confirming the effect of seasonal condensation of CO2 on the north polar cap, but we have no agreement for other seasons.  相似文献   

9.
Dynamic models of the martian polar caps are in abundance, but most rely on the assumption that the rate of sublimation of CO2 ice can be calculated from heat transfer and lack experimental verification. We experimentally measured the sublimation rate of pure CO2 ice under simulated martian conditions as a test of this assumption, developed a model based on our experimental results, and compared our model's predictions with observations from several martian missions (MRO, MGS, Viking). We show that sun irradiance is the primary control for the sublimation of CO2 ice on the martian poles with the amount of radiation penetrating the surface being controlled by variations in the optical depth, ensuring the formation and sublimation of the seasonal cap. Our model confirmed by comparison of MGS-MOC and MRO-HiRISE images, separated by 2-3 martian years, shows that ∼0.4 m are currently being lost from the south perennial cap per martian year. At this rate, the ∼2.4-m-thick south CO2 perennial cap will disappear in about 6-7 martian years, unless a short-scale climatic cycle alters this rate of retreat.  相似文献   

10.
While CO, HCl, and HF, that were considered in the first part of this work, have distinct absorption lines in high-resolution spectra and were detected four decades ago, the lines of HDO, OCS, and SO2 are either very weak or blended by the telluric lines and have not been observed previously by ground-based infrared spectroscopy at the Venus cloud tops. The H2O abundance above the Venus clouds is typically below the detection limit of ground-based IR spectroscopy. However, the large D/H ratio on Venus facilitates observations of HDO. Converted to H2O with D/H ≈ 200, our observations at 2722 cm−1 in the Venus afternoon show a H2O mixing ratio of ∼1.2 ppm at latitudes between ±40° increasing to ±60° by a factor of 2. The observations in the early morning reveal the H2O mixing ratio that is almost constant at 2.9 ppm within latitudes of ±75°. The measured H2O mixing ratios refer to 74 km. The observed increase in H2O is explained by the lack of photochemical production of sulfuric acid in the night time. The recent observations at the P-branch of OCS at 4094 cm−1 confirm our detection of OCS. Four distributions of OCS along the disk of Venus at various latitudes and local times have been retrieved. Both regular and irregular components are present in the variations of OCS. The observed OCS mixing ratio at 65 km varies from ∼0.3 to 9 ppb with the mean value of ∼3 ppb. The OCS scale height is retrieved from the observed limb darkening and varies from 1 to 4 km with a mean value of half the atmospheric scale height. SO2 at the cloud tops has been detected for the first time by means of ground-based infrared spectroscopy. The SO2 lines look irregular in the observed spectra at 2476 cm−1. The SO2 abundances are retrieved by fitting by synthetic spectra, and two methods have been applied to determine uncertainties and detection limits in this fitting. The retrieved mean SO2 mixing ratio of 350 ± 50 ppb at 72 km favors a significant increase in SO2 above the clouds since the period of 1980-1995 that was observed by the SOIR occultations at Venus Express. Scale heights of OCS and SO2 may be similar, and the SO2/OCS ratio is ∼500 and may be rather stable at 65-70 km under varying conditions on Venus.  相似文献   

11.
We have investigated the abundances of Titan's stratospheric oxygen compounds using 0.5 cm−1 resolution spectra from the Composite Infrared Spectrometer on the Cassini orbiter. The CO abundance was derived for several observations of far-infrared nadir spectra, taken at a range of latitudes (75° S-35° N) and emission angles (0°-60°), using rotational lines that have not been analysed before the arrival of Cassini at Saturn. The derived volume mixing ratios for the different observations are mutually consistent regardless of latitude. The weighted mean CO volume mixing ratio is 47±8 ppm if CO is assumed to be uniform with latitude. H2O could not be detected and an upper limit of 0.9 ppb was determined. CO2 abundances derived from mid-infrared nadir spectra show no significant latitudinal variations, with typical values of 16±2 ppb. Mid-infrared limb spectra at 55° S were used to constrain the vertical profile of CO2 for the first time. A vertical CO2 profile that is constant above the condensation level at a volume mixing ratio of 15 ppb reproduces the limb spectra very well below 200 km. This is consistent with the long chemical lifetime of CO2 in Titan's stratosphere. Above 200 km the CO2 volume mixing ratio is not well constrained and an increase with altitude cannot be ruled out there.  相似文献   

12.
Using the SPICAV-UV spectrometer aboard Venus Express in nadir mode, we were able to derive spectral radiance factors in the middle atmosphere of Venus in the 170-320 nm range at a spectral resolution of R ? 200 during 2006 and 2007 in the northern hemisphere. By comparison with a radiative transfer model of the upper atmosphere of Venus, we could derive column abundance above the visible cloud top for SO2 using its spectral absorption bands near 280 and 220 nm. SO2 column densities show large temporal and spatial variations on a horizontal scale of a few hundred kilometers. Typical SO2 column densities at low latitudes (up to 50°N) were found between 5 and 50 μm-atm, whereas in the northern polar region SO2 content was usually below 5 μm-atm. The observed latitudinal variations follow closely the cloud top altitude derived by SPICAV-IR and are thought to be of dynamical origin. Also, a sudden increase of SO2 column density in the whole northern hemisphere has been observed in early 2007, possibly related to a convective episode advecting some deep SO2 into the upper atmosphere.  相似文献   

13.
T.A. Cassidy  R.E. Johnson  M.C. Wong 《Icarus》2007,191(2):755-764
Results from a three-dimensional ballistic model of Europa's O2 atmosphere are presented. Hubble Space Telescope (HST) ultraviolet observations show spatially non-uniform O2 airglow from Europa. One explanation for this is that the O2 atmosphere is spatially non-uniform. We show that non-uniform ejection of O2 alone cannot reproduce the required morphology, but that a non-uniform distribution of reactive species in Europa's porous regolith can result in a non-uniform O2 atmosphere. By allowing O2 molecules to react with Europa's visibly dark surface material, we produced a spatially non-uniform atmosphere which, assuming uniform electron excitation of O2 over the trailing hemisphere, compares favorably with the morphology suggested by the HST observations. This model, which requires a larger source of O2 than has previously been estimated, can in principal be tested by the New Horizons observations of Europa's O2 atmosphere.  相似文献   

14.
The model is intended to respond to the recent findings in the Venus atmosphere from the Venus Express and ground-based submillimeter and infrared observations. It extends down to 47 km for comparison with the kinetic model for the lower atmosphere (Krasnopolsky, V.A. [2007]. Icarus 191, 25–37) and to use its results as the boundary conditions. The model numerical accuracy is significantly improved by reduction of the altitude step from 2 km in the previous models to 0.5 km. Effects of the NUV absorber are approximated using the detailed photometric observations at 365 nm from Venera 14. The H2O profile is not fixed but calculated in the model. The model involves odd nitrogen and OCS chemistries based on the detected NO and OCS abundances. The number of the reactions is significantly reduced by removing of unimportant processes. Column rates for all reactions are given, and balances of production and loss may be analyzed in detail for each species.The calculated vertical profiles of CO, H2O, HCl, SO2, SO, OCS and of the O2 dayglow at 1.27 μm generally agree with the existing observational data; some differences are briefly discussed. The OH dayglow is ～30 kR, brighter than the OH nightglow by a factor of 4. The H + O3 process dominates in the nightglow excitation and O + HO2 in the dayglow, because of the reduction of ozone by photolysis. A key feature of Venus’ photochemistry is the formation of sulfuric acid in a narrow layer near the cloud tops that greatly reduces abundances of SO2 and H2O above the clouds. Delivery of SO2 and H2O through this bottleneck determines the chemistry and its variations above the clouds. Small variations of eddy diffusion near 60 km result in variations of SO2, SO, and OCS at and above 70 km within a factor of ～30. Variations of the SO2/H2O ratio at the lower boundary have similar but weaker effect: the variations within a factor of ～4 are induced by changes of SO2/H2O by ±5%. Therefore the observed variations of the mesospheric composition originate from minor variations of the atmospheric dynamics near the cloud layer and do not require volcanism. NO cycles are responsible for production of a quarter of O2, SO2, and Cl2 in the atmosphere. A net effect of photochemistry in the middle atmosphere is the consumption of CO2, SO2, and HCl from and return of CO, H2SO4, and SO2Cl2 to the lower atmosphere. These processes may be balanced by thermochemistry in the lower atmosphere even without outgassing from the interior, though the latter is not ruled out by our models. Some differences between the model and observations and the previous models are briefly discussed.  相似文献   

15.
Mid-infrared limb spectra in the range 600-1400 cm−1 taken with the Composite InfraRed Spectrometer (CIRS) on-board the Cassini spacecraft were used to determine vertical profiles of HCN, HC3N, C2H2, and temperature in Titan's atmosphere. Both high (0.5 cm−1) and low (13.5 cm−1) spectral resolution data were used. The 0.5 cm−1 data gave profiles at four latitudes and the 13.5 cm−1 data gave almost complete latitudinal coverage of the atmosphere. Both datasets were found to be consistent with each other. High temperatures in the upper stratosphere and mesosphere were observed at Titan's northern winter pole and were attributed to adiabatic heating in the subsiding branch of a meridional circulation cell. On the other hand, the lower stratosphere was much colder in the north than at the equator, which can be explained by the lack of solar radiation and increased IR emission from volatile enriched air. HC3N had a vertical profile consistent with previous ground based observations at southern and equatorial latitudes, but was massively enriched near the north pole. This can also be explained in terms of subsidence at the winter pole. A boundary observed at 60° N between enriched and un-enriched air is consistent with a confining polar vortex at 60° N and HC3N's short lifetime. In the far north, layers were observed in the HC3N profile that were reminiscent of haze layers observed by Cassini's imaging cameras. HCN was also enriched over the north pole, which gives further evidence for subsidence. However, the atmospheric cross section obtained from 13.5 cm−1 data indicated a HCN enriched layer at 200-250 km, extending into the southern hemisphere. This could be interpreted as advection of polar enriched air towards the south by a meridional circulation cell. This is observed for HCN but not for HC3N due to HCN's longer photochemical lifetime. C2H2 appears to have a uniform abundance with altitude and is not significantly enriched in the north. This is consistent with observations from previous CIRS analysis that show increased abundances of nitriles and hydrocarbons but not C2H2 towards the north pole.  相似文献   

16.
New maps of martian water vapor and hydrogen peroxide have been obtained in November-December 2005, using the Texas Echelon Cross Echelle Spectrograph (TEXES) at the NASA Infra Red Telescope facility (IRTF) at Mauna Kea Observatory. The solar longitude Ls was 332° (end of southern summer). Data have been obtained at 1235-1243 cm−1, with a spectral resolution of 0.016 cm−1 (R=8×104). The mean water vapor mixing ratio in the region [0°-55° S; 345°-45° W], at the evening limb, is 150±50 ppm (corresponding to a column density of 8.3±2.8 pr-μm). The mean water vapor abundance derived from our measurements is in global overall agreement with the TES and Mars Express results, as well as the GCM models, however its spatial distribution looks different from the GCM predictions, with evidence for an enhancement at low latitudes toward the evening side. The inferred mean H2O2 abundance is 15±10 ppb, which is significantly lower than the June 2003 result [Encrenaz, T., Bézard, B., Greathouse, T.K., Richter, M.J., Lacy, J.H., Atreya, S.K., Wong, A.S., Lebonnois, S., Lefèvre, F., Forget, F., 2004. Icarus 170, 424-429] and lower than expected from the photochemical models, taking in account the change in season. Its spatial distribution shows some similarities with the map predicted by the GCM but the discrepancy in the H2O2 abundance remains to be understood and modeled.  相似文献   

17.
H.G. Roe  I. de Pater 《Icarus》2004,169(2):440-461
All previous observations of seasonal change on Titan have been of physical phenomena such as clouds and haze. We present here the first observational evidence of chemical change in Titan's atmosphere. Images taken during 1999-2002 (late southern spring on Titan) with the W.M. Keck I 10-meter telescope at 8-13 μm show a significant accumulation of ethylene (C2H4) in the south polar stratosphere as well as north-south stratospheric temperature variation (colder at poles). Our observations restrict this newly discovered south polar ethylene accumulation to latitudes south of 60° S. The only other observations of the spatial distribution of C2H4 were those of Voyager I, which found a significant north polar accumulation in early northern spring. We see no build-up in the north, although the highest northern latitudes are obstructed from view in the current season. Our observations constrain any unobserved north polar accumulation of C2H4 to north of 50° N latitude. Comparison of the Voyager I results with our new results show seasonal chemical change has occurred in Titan's atmosphere.  相似文献   

18.
The condensing CO2 south polar cap of Mars and the mechanisms of the CO2 ice accumulation have been studied through the analysis of spectra acquired by the Planetary Fourier Spectrometer (PFS) during the first two years of ESA's Mars Express (MEX) mission. This dataset spans more than half a martian year, from Ls∼330° to Ls∼194°, and includes the southern fall season which is found to be extremely important for the study of the residual south polar cap asymmetry. The cap expands symmetrically and with constant speed during the fall season. The maximum extension occurs sometime in the 80°-90° Ls range, when the cap edges are as low as −40° latitude. Inside Hellas and Argyre basins, frost can be stable at lower latitudes due to the higher pressure values, causing the seasonal cap to be asymmetric. Within the seasonal range considered in this paper, the cap edge recession rate is approximately half the rate at which the cap edge expanded. The longitudinal asymmetries reduce during the cap retreat, and disappear around Ls∼145°. Two different mechanisms are responsible for CO2 ice accumulation during the fall season, especially in the 50°-70° Ls range. Here, CO2 condensation in the atmosphere, and thus precipitation, is allowed exclusively in the western hemisphere, and particularly in the longitudinal corridor of the perennial cap. In the eastern hemisphere, the cap consists mainly of CO2 frost deposits, as a consequence of direct vapor deposition. The differences in the nature of the surface ice deposits are the main cause for the residual south polar cap asymmetry. Results from selected PFS orbits have also been compared with the results provided by the martian general circulation model (GCM) of the Laboratoire de Météorologie dynamique (LMD) in Paris, with the aim of putting the observations in the context of the global circulation. This first attempt of cross-validation between PFS measurements and the LMD GCM on the one hand confirms the interpretation of the observations, and on the other hand shows that the climate modeling during the southern polar night on Mars is extremely sensitive to the dynamical forcing.  相似文献   

19.
Hydrocarbons such as acetylene (C2H2) and ethane (C2H6) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm−1 (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm−1) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν4 band of CH4, and in the troposphere at 150-400 mbar, via the H2 absorption at 600-800 cm−1. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C2H2 and C2H6 by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C2H2ν5 and C2H6ν9 bands, and also emission of the acetylene (ν4+ν5)−ν4 hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼3×10−9. Additionally, the abundance gradient of C2H2 between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C2H2 and C2H6 by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C2H6 in the stratosphere (3×1010 s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5-50×108 s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C2H2, the opposite occurs, with the relatively short photochemical lifetime (3×107 s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible.  相似文献   

20.
Mars Express observations give ozone abundances that are smaller than those from the ground-based infrared heterodyne and HST observations at low and middle latitudes. Both ground-based and Mars Express observations of the O2 dayglow at 1.27 μm, which originates from photolysis of ozone, are in mutual agreement after correction for the local time variability. Therefore a problem appears: whether the MEX ozone data are compatible with (1) the observed O2 dayglow intensities and (2) the photochemical model by Krasnopolsky [Krasnopolsky, V.A., 2006. Icarus 185, 153-170] within uncertainties of its reaction rate coefficients. That model involves heterogeneous loss of H2O2 on water ice and agrees with the observations of the O2 dayglow, H2O2, and the ground-based and HST ozone. The answers are ‘yes’ to both questions. A version of the model is given that fits the MEX ozone as well as the observed O2 dayglow and H2O2. Laboratory studies of two reaction rate coefficients could indicate a preferable version of the model and a preferable set of the ozone data (MEX versus the ground-based and HST). The predicted seasonal behavior of H2O2 is different from that in the model by Lefevre et al. [Lefevre, F., Bertaux, J.L., Clancy, R.T., Encrenaz, T., Fast, K., Forget, F., Lebonnois, S., Montmessin, F., Perrier, S., 2008. Nature 454, 971-975], and future observations may help to choose between the models.  相似文献   

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