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1.
Based on a review of the available petrological and petrochemical data on magmarie rocks in a certain district in China, the average chemical composition of magmarie rocks has been calculated, and the frequenee distribution of elements in rocks,mineralization of rock bodies and regional geochemical characteristics have been discussed. In response to the temporal and. spatiai variations during the evolutionary process of magmatie activity, a systematic variation is obvious from this study in the chemical compositions of magmatie rocks, the frequence distribution patterns of elements, the concentration levels of various elements, the calc-alkaline index of the rocks as well as in the average atomic weight and average atomie valence. Particularly,different geochemical indicators have been observed for mineralized and barren rock bodies respectively. Crystallization-differentiation and postmagmatic metasomatism constitute the most important mechanisms controlling mineralization.  相似文献   

2.
V.N. Makarov 《冰川冻土》2004,26(Z1):257-262
Placer diamond mining in the Anabar area involves various operations that cause long-term (nearly a quarter of a century) environmental impacts. The long history of mining activities, the technology used to mine the placers, as well as the poor assimilative capacity of the natural systems can result in serious environmental impacts in the area. The primary geochemical processes in the diamond-bearing area are affected by the occurrence of permafrost and relict ice, the lengthy duration of ice cover in water bodies, and the widespread development of cryogenic processes. This promotes physical migration of contaminants, cryogenic metamorphization of waters, and long-term accumulation of organic contaminants in low-temperature, reduction and sedimentation barriers. In this paper, some environmental and geochemical effects of diamond mining in the Arctic area are discussed.  相似文献   

3.
The sediment-hosted copper deposits according to the authors‘ study were formed from connate formation water during the post-sedimentary or diagenetic stage while the sediment-hosted disseminated gold deposits are unanimously considered to be of post-sedimentary hydrothermal origin.Therefore,apart from their own individulities.These two types of deposits must share some characters in common.Comparisons are attempted,in this paper,between the sediment-hosted copper deposits in southwest China and the Triassic sediment-hosted disseminated gold deposits in the Yunnan-Guizhou-Guangxi Triangle in terms of geological and geochemical features.  相似文献   

4.
四川盆地天然气地球化学特征   总被引：8，自引：3，他引：8  
黄籍中 《地球化学》1984,(4):307-321
The Sichuan Basin is one of the largest gas-oil-bearing basins in China. Oil and gas reservoirs occur in Mesozoic, Paleozoic and Proterozoic strata in this basin, with natural gases being dominant. A good wealth of data from 2,000 drill wells on the distribution of natural gases(hydrocarbons: CH4, C2H6^ ; non-hydrocarbons: H2S, CO2, N2; rare gases: He, At,Hg) show that natural gases in the basin are predominated by oil-thermoeraeked and coal-series gases.Geological-factor analysis of the geochemical characteristics of natural gases pro-vide evidence suggesting that the oceurrence of natural gases, especially dry gas, is attributed to the high maturity of organic matter, and the multi-productive formation has a great bearing on the multi-source rocks; the anomalies of some. components(e.g. H2S) are related not only to the type of primary organis matter, but also to the lithological characters of reservoir beds. Also discussed in this paper are some geochemical characteristics of coal-series and non-coal-series gases at the same degree of maturation, demonstrating that the former is characterized by high proportions of CH4, and Hg vapor, high C2/C2, ratio, high δ^13C8,low C2^ , and high iC4/nC4.  相似文献   

5.
Major, trace and rare earth element contents of Fe- and Al-rich metapelites from the Korda （Yenisey Ridge） and Amar （Kuznetsk Alatau） formations were determined to examine the nature, origin and evolution of their protoliths. Results indicate that these rocks are the redeposited and metamorphosed products of Precambrian kaolinitic weathering crusts, while the geochemical distinctions between the studied metapelites are determined by different weathering conditions in the source area and tectonic settings. The protolith of the Korda Formation metapelites was produced by erosion products of the post-Archean granitoid rocks, which accumulated under humid climate conditions in shallow-water basins along the continental margin. The geochemical characteristics of the deeper primary deposits of the Amar Formation suggest that volcanogenic material of mafic composition derived from an island-arc environment had a major role in supplying the erosion zone. These results agree with lithofacies data and with the geodynamic reconstruction of the evolution of the Yenisey Ridge and Kuznetsk Alatau during the Mesoproterozoic and Neoproterozoic, respectively. It was shown that REEs had limited mobility during contact metamorphism. The coherent mobility of REEs during collisional metamorphism may be attributed both to mineral reactions responsible for modal changes and to local chemical heterogeneity inherited from the initial protolith.  相似文献   

6.
Studies of the mantle-derived iherzolites from Nushan show that in addition to CO2,there were present H2O and small amounts of CO, CH4, SO2,Cl and F in the initial mantlc fluids derived fron the asthenospheric mantlc plumc .The imitial fluids accumulated in some regions of the mantle, resulting in lowering of the mantle solidus (and liquidus) and partial melting of the upper mantle. Melts formed from low-degree of fluid-involved partial melting of the upper mantle would be highly enriched in incompatible elements.Fluies and melts are allthe metasomatic agents for mantle metasomatism, and the interaction between them and the depleted mantle could result in the substan-tial local enrichment of LREE and incompatible elements in the latter.In case that the concentration of H2O in the fluids (and melts) is lower ,only cryptic metasomatism would occur, in case that the concentration of H2O is higher,the degree of partial melting would be higher and hydrous metasomatic phases(e.g. amphiboles )would nucleate. Under such circumstances, there would occur model metasomatism.  相似文献   

7.
A garnet lherzolite xenolith hosted in olivine nephelinite from Xilong,Zhejiang Province ,southeastern China, shows clear evidence of modal metasomatism involving a special sanidine-olivine-diopside(SOD) association which was produced by replacement of primary orthopyroxene.The fluid responsible for the measomatism was a silica-undersaturated vapour,rich in K,Ba,Sr and Ti.It is suggested that the SOD assemblage is the product of metasomatism of a depleted lherzolite precursor,and formed in the upper mantle prior to entrainment and eruption.  相似文献   

8.
Whether there is a relationship between widespread Cenozoic igneous rocks and the activated Ailao Shan–Red River shear zone (ASRR) in western Yunnan, SE Tibet, remains highly controversial. New geochronological, and geochemical data derived from Cenozoic igneous rocks both within and far from the ASRR offers answers. Although these coeval felsic rocks (36.9–33.5 Ma) are enriched in large-ion lithophile elements relative to high field strength elements, they also display some special geochemical features, such as high Y and Yb values of syenitic porphyries, which contrast with the high Sr and low Y contents of monzoporphyries and granitic porphyries. The syenitic porphyries exhibit geochemical characteristics similar to those of coeval mafic magmas, e.g., high K2O, Y, and Yb contents, indicating that the former were probably generated by fractional crystallization of the latter. However, the high Sr/Y (56.1–109) monzoporphyries and granitic porphyries, combined with their low MgO, and Cr (or Ni) contents, suggest that they were mainly derived from partial melting of a thickened mafic lower crust. Given that these Cenozoic magmatic events exhibiting planar distributions occurred outside of the activation of the ASRR (31–20 Ma), then they were not controlled by the latter. Instead, they were tied to convective removal of a thickened lower lithospheric mantle in western Yunnan during the Paleogene.  相似文献   

9.
A sound understanding of groundwater recharged from various sources occurring at different time scales is crucial for water management in arid and semi-arid river basins. Groundwater recharge sources and their geochemical evolution are investigated for the Heihe River Basin(HRB) in northwest China on the basis of a comprehensive compilation of geochemical and isotopic data. Geochemical massbalance modeling indicates that mountain-block recharge accounts for a small fraction(generally less than 5%) of the shallow and deep groundwater sustaining the oasis, whereas infiltration of rivers and irrigation water contribute most of the groundwater recharge. Dedolomitization is the primary process responsible for the changes in groundwater chemical and carbon isotope compositions from the piedmont to the groundwater discharge zone, where the dedolomitization is very likely enhanced by modern agricultural activities affecting the shallow groundwater quality. Analysis of radioactive isotopes suggests that these primary recharge sources occur at two different time scales. Radiocarbon-derived groundwater age profiles indicate a recharge rate of approximately 12 mm/year, which probably occurred during 2000–7000 years B.P., corresponding to the mid-Holocene humid period. The recharge of young groundwater on the tritium-dated time scale is much higher, about 360 mm/year in the oasis region. Infiltration from irrigation canals and irrigation return flow are the primary contributors to the increased young groundwater recharge. This study suggests that groundwater chemistry in the HRB has been influenced by the complex interaction between natural and human-induced geochemical processes and that anthropogenic effects have played a more significant role in terms of both groundwater quantity and quality.  相似文献   

10.
Tectono-geochemical samples were systematically collected from 5 drillcores along the No. 304 explora-tion line and at the -310 m level under the pit in the mining area, totalling 705 samples from the metamorphic rocks, granites, altered rocks and orebodies, and were determined for their contents of 20 kinds of elements including Au, Ag, As, Sb, Hg, Cu,,Pb, Zn, Sn, Bi, Mo, Co, Ni, Mn, Cr, V, Ti, Ba, Rb, Sr, etc. By using the Surfer software the geochemical exploration line profile maps for the 20 kinds of elements and the curves for the element geochemical contents of individual ore vein groups were established. In conbination with the geochemical map analytical method and Gregorian’s zoning index calculation method, the vertical, longitudinal and lateral zonation sequences of the elements were ascertained and the geochemical three-dimentional zonation model of the primary halos was estab-lished on the basis of the analysis of metallogenic structures and alteration zonation. Coupled with the results of analysis of the geology and geochemistry data, it may be concluded that the process of alteration of granites in the mining area is also accompanied with the process of gold enrichment and mineralization. With the intensification of alteration of granites from granite →potash feldspathization granite →sericite-quartz alteration granite, seric-ite-quartz rocks →beresitized granite, pyrite sericite-quartz rock, silicified granite →gold ore, the contents of thio-phile ore-forming elements such as Au, Ag, As, Cu, Bi, Mo, Pb, Sb, Hg, and Sn tended to increase. Factor analysis of trace elements indicated: factor F2 (Au, Ag, Cu, Sn, As) represents the element association brought in at the main stage of hydrothermal metallogenesis; factor F4 (Bi, Sb) and factor F5 (Pb, Zn) represent the ore-forming element association supperposed during the late stage of Au-bearing sulfides. By using the Gregorian’s zoning index and map analysis method we have ascertained the primary halo axial zonation sequence (form frontal halo →tail halo): Pb, Zn, Mn, Ba, Sr, Rb, As, Sb, Ag, Cu, Sn, Mo, Au, Bi, Hg, Ti, Cr, V, Ni, and Co. The geochemical anomalies in the mining area display a tendency of lateral plunging to WS, which is consistent with the lateral plunging of orebodies and mineralization alteration zone. Comprehensive analysis of the results of investigations on ore-controlling structures, mineralization-alteration zonation and geochemical zonation of the primary halos indicates that the gold orebodies in this area are still of greater extension.  相似文献   

11.
The A-type Harsora-Dadikar granites in the Alwar complex of northern Aravalli orogen,NW India provide evidence for subsolidus-requilibration of feldspars.They record three new discrete stages of albitisation,producing trondhjemite and albitite sequentially at the expense of original granite.Stage-Ⅰ metasomatism deanorthised the magmatic oligoclase and transformed the grey least-albitised granite to pinkish grey microcline-oligoclase granite.Stage-II converted the latter to trondhjemite by replacement of microcline to oligoclase.Stage-Ⅲ metasomatism led to the formation of albitite/albite granite from trondhjemite,where the metasomatically formed oligoclase was replaced by albite.This stage of metasomatism resulted in nearly complete disappearance of amphibole and biotite,producing a monomineralic rock(albitite),which is consistent with Korzhinskii theory of infiltration metasomatism.The reaction fronts delineating the Stage-Ⅱ and Stage-Ⅲ are sharp and easily discernible by their prominent color differences in Harsora on the outcrop scale.Chemically,the mineral transformations during three stages are manifested by the differential gains/losses in Na,K,Ca,Rb,Ba,Sr,Fe and Mg.The formation of albite,Cl-rich marialitic scapolite and Cl-rich amphibole in the albitised granites are suggestive of Naand Cl-brines as the metasomatising fluids.The fluid-rock interactions,which can significantly transform the pristine mineralogy of granitoids,should be carefully considered to avoid any misinterpretations about their petrological history.  相似文献   

12.
TD-2 structure is located in the eastern part of the Central Uplift zone of the Tarim Basin, China. It is a basement-uplift anticline-type structure confirmed by seismic and gravity prospecting, and it is expected to have good potential for oil and gas according to the analysis of regional geological evolution history. But further exploration such as drilling is suspended because of lacking direct geochemical information. Therefore, multi-parametric geochemical surveys, such as free hydrocarbons (C1-C5), acid hydrocarbons (C1-C5) and ?C, Hg of soil, were conducted. It is concluded in this paper that free hydrocarbons are obviously better than other geochemical parameters and could be used for evaluation of oil and gas potential of TD-2 structure in the desert area. Shapes of near-surface geochemical anomalies and geochemical characteristic parameters suggested that TD-2 structure was a dry gas-bearing structure at the early-middle dissipation stage. So TD-2 structure should have some promising potential for oil-gas. Multi-parametric geochemical survey provided important information for further drilling exploration.  相似文献   

13.
The early Mesozoic marked an important transition from collisional orogeny to post-orogenic extension at the northern margin of the North China Craton(NCC). In this study, we undertook zircon U-Pb dating and whole-rock majorand trace-element geochemical analyses of early Mesozoic granitic rocks in the Chifeng area to establish their geochronological framework, petrogenesis, and implications for the tectonic evolution of the eastern Central Asia Orogenic Belt(CAOB). Zircon U-Pb dating results show that these rocks were emplaced in three stages during the Triassic:(1) syenogranites during 250–248 Ma,(2) granodiorites during 244–243 Ma, and(3) monzogranites and granodiorites during 232–230 Ma. These Triassic granitoids belong to the high-K calc-alkaline series and are evolved I-type granites. They have high SiO_2 and low Mg O contents with enrichments in light rare-earth elements, Zr, Hf, Rb, Th, and U, and depletions in Ba, Nb, Ta, Sr, and Eu. These geochemical data indicate that the granitoids were derived from partial melting of a lower-crustal source under relatively low-pressure conditions and subsequently underwent extensive fractional crystallization. Considering both the geochemical data and regional geological information, we propose that the 250–248 Ma syenogranites were emplaced in an extensional environment linked to slab break-off after closure of the Paleo-Asian Ocean(PAO) along the Solonker-Xra Moron-Changchun suture zone. The 244–243 Ma granodiorites were formed in a compressional orogenic setting during collision between the Erguna-Xing'an-Songliao composite block and the NCC. The 232–230 Ma granodiorites and monzogranites were emplaced during the transition from compressional orogeny to post-orogenic extension. Overall, the early Mesozoic tectonic evolution of the Chifeng area can be divided into three main stages:(1) closure of the Paleo-Asian Ocean and extension related to slab break-off during the Early Triassic;(2) continuous collisional compression during the Middle Triassic after closure of the PAO; and(3) post-orogenic extension during the Late Triassic, most probably due to lithospheric delamination after amalgamation of the Erguna-Xing'an-Songliao composite block and the NCC.  相似文献   

14.
The spatial distribution of ore-forming elements is the result of interaction and influence among multiple factors in the process of mineralization, and is the specific embodiment of non-linearity and coupling of mineralization. The fractal theory has such functions as to characterize non-lineariry and coupling, and can find out the deterministic law from the complicated coupling process. The primary geochemical fractal distribution of metallogenic elements such as Cu and Au possesses the characteristics of multi-fractal distribution in the Dehelongwa copper-gold deposit. Copper follows 2-d fractal distribution, and Au follows 3- or 4-d fractal distribution. The primary geo- chemical fractal distribution has a certain similarity on the same prospecting line, and this similarity is not obvious among different prospecting lines. The secondary geochemical fractal distribution of Cu and Au is higher in similar- ity, and simpler than the primary geochemical fractal distribution. These results show that the mineralization of Cu and Au is out of sync and also is inconsistent in this deposit, and the mineralization of Cu mainly experienced two mineralization stages, while the mineralization of Au experienced three to four mineralization stages. Besides the mineralization of Cu and Au shows a certain direction and along the strike of vertical orebodies it is relatively bal- anced. While along the strike of the ore bodies the mineralization of Cu and Au shows a significant difference. The hypergenic geologic process has a certain effect on the balance of spatial distribution of Cu and Au. From these it can be seen that the mineralization process of this deposit is well characterized by the geochemical fractal distribu- tion of Cu and Au.  相似文献   

15.
The latest Cretaceous magmatic activity in the eastern segment of the Lhasa terrane provides important insights for tracking the magma source and geodynamic setting of the eastern Gangdese batholith, eastward of eastern Himalayan Syntaxis. Detailed petrological, geochemical and geochronological studies of the intrusive rocks (monzodiorites and granodiorites) of the eastern Gangdese batholith are presented with monzodiorites and granodiorites giving zircon U–Pb crystallization dates of 70–66 Ma and 71–66 Ma with εHf(t) values of ?4.8 to +6.2 and ?1.9 to +5.3, respectively. These rocks are metaluminous to weakly peraluminous I-type granites showing geochemically arc-related features of enrichment in LREEs and some LILEs, e.g., Rb, Th, and U, and depletion in HREEs and some HFSEs, e.g., Nb, Ta, and Ti. The rocks are interpreted to be derived from partial melting of mantle material and juvenile crust, respectively, which are proposed to be triggered by Neo-Tethyan slab rollback during northward subduction, with both experiencing ancient crustal contamination. The studied intrusive rocks formed in a transitional geodynamic setting caused by Neo-Tethyan oceanic flat subduction to slab rollback beneath the eastern Gangdese belt during the latest Cretaceous.  相似文献   

16.
Listwanite from the Luobusa ophiolite,Tibet,forms a narrow,discontinuous band along the eastern part of the southern boundary fault. We undertook a detailed petrographic and geochemical study to understand the mineral transformation processes and the behaviour of major and trace elements during listwanite formation. Three alteration zones characterized by distinct mineral components and texture are recognized and,in order of increasing degree of alteration,these are: zoneIII is rich in serpentine minerals; zoneII is rich in talc and carbonates; and zoneI is mainly composed of carbonates and quartz. Geochemical data for the three alteration zones show significant modification of some major and trace elements in the protolith,although some oxides show linear correlations with Mg O. Gold mineralization is recognized in the Luobusa listwanite and may signify an important target for future mineral exploration. Gold enrichment occurs in both zoneI and zoneIIand is up to 0.91 g/t in one sample from zoneI. We show that CO2-rich hydrothermal fluids can modify both the occurrence and composition of chromite grains,indicating some degree of chromite mobility. Low-Cr anhedral grains are more easily altered than high-Cr varieties. The compositions of chromite and olivine grains in the listwanite suggest a dunite protolith.  相似文献   

17.
The Napo-Qinzhou Tectonic Belt (NQTB) lies at the junction of the Yangtze, Cathaysia and Indochina (North Vietnam) Blocks, which is composed of five major lithotectonic subunits: the Qinzhou-Fangcheng Suture Zone (QFSZ), the Shiwandashan Basin (SB), the Pingxiang-Nanning Suture Zone (PNSZ), the Damingshan Block (DB) and the Babu-Lingma Suture Zone (BLSZ). On the basis of geochemical compositions, the Permian mafic igneous rocks can be divided into three distinct groups: (1) mafic igneous rocks (Group 1) from the Longjing region in the PNSZ and Hurun region in the BLSZ, which are characterized by intermediate Ti, P and Zr with low Ni and Cr contents; (2) mafic igneous rocks (Group 2) from the Naxiao and Chongzuo region in the DB, characterized by low-intermediate Ti, P and Zr with high Ni and Cr concentrations; and (3) mafic igneous rocks (Group 3) from the Siming region in the Jingxi carbonate platform of the northwestern margin of the NQTB, with intermediate-high Ti, P and Zr and low Ni and Cr contents. The Group 1 rocks yield a weighted mean 206Pb/238U age of 250.5±2.8 Ma and are geochemically similar to basalts occurring in back-arc basin settings. The Group 2 rocks exhibit geochemical features to those basalts in island arcs, whereas the Group 3 rocks show geochemical similarity to that of ocean island basalts. All three groups are characterized by relatively low εNd(t) values (–2.61 to +1.10) and high initial 87Sr/86Sr isotopic ratios (0.705309–0.707434), indicating that they were derived from a subduction-modified lithospheric mantle and experienced assimilation, fractional crystallization, and crustal contamination or mixing during magmatic evolution. Accordingly, we propose the existence of an arc-back arc basin system that developed along the NQTB at the border of SW Guangxi Province (SW China) and northern Vietnam, and it was formed by continued northwestward subduction of the Cathaysian (or Yunkai) Block under the Yangtze Block, and northeastward subduction of the Indochina Block beneath the Yangtze Block during Permian time.  相似文献   

18.
On the basis of mineralogical ,geochemical and micro-textural studies of the typical sections of the red weathering crust of carbonate rocks in the subtropical karst areas of Guizhou Province and Guangxi Autonomous Region,we have found,either on a microscopic or on a mac-roscopical scale and in different positions of the sections,the most direct and most important mineralogical and micro-textural evidence for the development of metasomatism in the process of weathering-pedogenesis of numerous carbonate rocks.This paper also has expounded for the first time and systematically the mechanism of metasomatism involved in the process of weathering-pedogenesis of carbonate rocks and proposed the sequence of mineral metasomatic evolution in the process of weathering-pedogenesis of carbonate rocks.  相似文献   

19.
The differential enrichment of gold and arsenic observed in As-bearing hydrothermal gold deposits in Southwest Gizhou is induced by vapor-liquid separation in response to changing physico-chemical conditions during the hydrothermal evolution and is a reflection of the geochemical behavior of the two elements.  相似文献   

20.
含锡磁铁矿-矽卡岩的地球化学特征   总被引：5，自引：0，他引：5  
任治机 《地球化学》1982,(3):301-309
Geological and geochemical features of tin-bearing magnetite-skarns are reviewed in this paper together with the author‘s opinion with respect to the mechanism of transportation of tin in this environment. In addition to cassiterite, the commonest mode of occurrence of tin in nature, three other occurrences are also of interest in tin-bearing magnetite-skarns: (1) Tin is present in extremely fine eassiterite as exsolution colloform in magnetite; (2) Being Found in some tin-bearing minerals such as malayaite,stokesite,nordenskioldine,Snpaigeite,Sn-lundwigite and hulsite in a variety of skarns;(3)Occurring in a numbor of skarn minerals such as garnet,pyroxene,spinel,amphibole,epidote,wollastonite and axinite,which become tinrich as a results of the substitution of Sn^4 for Fe^3 or Ti^4 rather than for Fe^2 ,Ca^2 or Si^4 ,When Mg^2 -,Fe^2 -bearing minerals and in some eases even sulfides or other mineralizer-containing minerals replace tin-bearing,Fe^3 -,Ti^4 -skarn minerals during the late stages of skarn alteration,tin in the pre-exsiting silicates may be extracted and remobilized thus contributing to the formation of the associated tindeposits.  相似文献   

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