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1.
Radiogenic isotope data (initial Nd, Pb) and elemental concentrations for the Mooselookmeguntic igneous complex, a suite of mainly granitic intrusions in New Hampshire and western Maine, are used to evaluate petrogenesis and crustal variations across a mid-Paleozoic suture zone. The complex comprises an areally subordinate monzodiorite suite [377±2 Ma; εNd (at 370 Ma)=−2.7 to −0.7; initial 207Pb/204Pb=15.56–15.58] and an areally dominant granite [370±2 Ma; εNd (at 370 Ma)=−7.0 to −0.6; initial 207Pb/204Pb=15.55–15.63]. The granite contains meter-scale enclaves of monzodiorite, petrographically similar to but older than that of the rest of the complex [389±2 Ma; εNd (at 370 Ma)=−2.6 to +0.3; initial 207Pb/204Pb 15.58, with one exception]. Other granite complexes in western Maine and New Hampshire are 30 Ma older than the Mooselookmeguntic igneous complex granite, but possess similar isotopic signatures.

Derivation of the monzodioritic rocks of the Mooselookmeguntic igneous complex most likely occurred by melting of Bronson Hill belt crust of mafic to intermediate composition. The Mooselookmeguntic igneous complex granites show limited correlation of isotopic variations with elemental concentrations, precluding any significant presence of mafic source components. Given overlap of initial Nd and Pb isotopic compositions with data for Central Maine belt metasedimentary rocks, the isotopic heterogeneity of the granites may have been produced by melting of rocks in this crustal package or through a mixture of metasedimentary rocks with magmas derived from Bronson Hill belt crust.

New data from other granites in western Maine include Pb isotope data for the Phillips pluton, which permit a previous interpretation that leucogranites were derived from melting heterogeneous metasedimentary rocks of the Central Maine belt, but suggest that granodiorites were extracted from sources more similar to Bronson Hill belt crust. Data for the Redington pluton are best satisfied by generation from sources in either the Bronson Hill belt or Laurentian basement. Based on these data, we infer that Bronson Hill belt crust was more extensive beneath the Central Maine belt than previously recognized and that mafic melts from the mantle were not important to genesis of Devonian granite magma.  相似文献   


2.
The Sr, Nd and Pb isotopic compositions for the Kovdor phoscorite–carbonatite complex (PCC), Kola Peninsula, NW Russia, have been determined to characterize the mantle sources involved and to evaluate the relative contributions of a plume and subcontinental lithospheric mantle in the formation of the complex. The Kovdor PCC is a part of the Kovdor ultramafic–alkaline–carbonatite massif, and consists of six intrusions. The initial isotopic ratios of the analyzed samples, calculated at 380 Ma, display limited variations: εNd, + 2.0 to + 4.7; 87Sr/86Sr, 0.70319 to 0.70361 (εSr, − 12.2 to − 6.2); 206Pb/204Pb, 18.38 to 18.74; 207Pb/204Pb, 15.45 to 15.50; 208Pb/204Pb, 37.98 to 39.28. The Nd and Sr isotope data of the Kovdor PCC generally fit the patterns of the other phoscorites and carbonatites from the Kola Alkaline Province (KAP), but some data are slightly shifted from the mixing line defined as the Kola Carbonatite Line, having more radiogenic 87Sr/86Sr ratios. However, the less radiogenic Nd isotopic compositions and negative Δ7/4 values of Pb isotopes of the analyzed samples exclude crustal contamination, but imply the involvement of a metasomatized lithospheric mantle source. Isotopic variations indicate mixing of at least three distinct mantle components: FOZO-like primitive plume component, EMI-like enriched component and DMM-like depleted component. The isotopic nature of the EMI- and DMM-like mantle component observed in the Kovdor samples is considered to be inherited from metasomatized subcontinental lithospheric mantle. This supports the previous models invoking plume–lithosphere interaction to explain the origin of the Devonian alkaline carbonatite magmatism in the KAP.  相似文献   

3.
S. Jung  E. Hoffer  S. Hoernes 《Lithos》2007,96(3-4):415-435
Major element, trace element and Nd–Sr–Pb–O isotope data for a suite of Neo-Proterozic, pre-orogenic, rift-related syenites from the Northern Damara orogen (Namibia) constrain their sources and petrogenesis. New U–Pb ages obtained on euhdreal titanite of inferred magmatic origin constrain the age of intrusion of the Lofdal and Oas syenites to ca. 750 Ma compatible with previous high-precision zircon analyses from the Oas complex. Major rock types from Lofdal and Oas are mildly sodic nepheline-normative and quartz-normative syenites and were primarily generated by fractional crystallization from a mantle-derived alkaline magma. Primitive samples from Lofdal and Oas show depletion of Rb, K and Th relative to Ba and Nb together with variable negative anomalies of P and Ti on a primitive mantle-normalized diagram. Evolved samples from Oas develop significant negative Ba, Sr, P and Ti anomalies and positive U and Th anomalies mainly as a function of crystal fractionation processes. The lack of a pronounced negative Nb anomaly in samples from Lofdal suggests that involvement of a crustal component is negligible. For the nepheline-normative samples from Lofdal, the unradiogenic Sr and radiogenic Nd isotope composition and low δ18O values suggest derivation of these samples from a moderately depleted lithospheric upper mantle with crustal-like U/Pb ratios (87Sr/86Sr: 0.7031–0.7035, ε Nd: ca. + 1, δ18O: 7‰, 206Pb/204Pb: ca.18.00, 207Pb/204Pb: 15.58–15.60). Primitive samples of the Oas quartz-normative syenites have identical isotope characteristics (87Sr/86Sr: 0.7034, ε Nd: ca. + 1, δ18O: 6.5‰, 206Pb/204Pb: ca.18.00, 207Pb/204Pb: 15.59) whereas more differentiated samples have higher 87Sr/86Sr ratios (0.709–0.714), slightly higher δ18O values (7.0–7.1‰), less radiogenic ε Nd values (− 1.1 to − 1.4) and more radiogenic 206Pb/204Pb ratios up to 18.27. These features together with model calculations using Sr–Nd–Pb isotopes suggest modification of a primary syenite magma by combined AFC processes involving ancient continental crust. In this case, high Nb abundances of the parental syenite liquid prevent the development of significant negative Nb anomalies that may be expected due to interaction with continental crust.  相似文献   

4.
Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial 143Nd/144Nd ( 0.5127–0.5128) and 87Sr/86Sr ( 0.7032–0.7040). The initial 206Pb/204Pb ratios are variable (18.5–19.7) at uniform 207Pb/204Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (143Nd/144Nd  0.5123, 87Sr/86Sr  0.704, 206Pb/204Pb  17.5–18.5, and 207Pb/204Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.  相似文献   


5.
Andreas Stracke  Ernst Hegner 《Lithos》1998,45(1-4):545-560
The Tabar–Lihir–Tanga–Feni (TLTF) volcanic island chain occurs in a zone of lithospheric extension superimposed on a post-collisonal tectonic setting along the Pacific and Indo-Australian plates northeast of Papua New Guinea. We present geochemical and Sr, Nd, and Pb isotope data for volcanic rocks from these islands and three recently discovered seamounts located at Lihir island. Major element data document an alkalic affinity of the sample suite and trachybasalts as the predominant rock type. Negative Nb-anomalies in extended trace element patterns, enrichment of the light rare earth elements, and Ce/Pb ratios of about 4 are typical of the values in calc alkaline island arc volcanics and support an origin from subduction-modified mantle. 87Sr/86Sr ratios of 0.7037 to 0.7044 and Nd values of +5.6 to +6.8 indicate that the upper mantle evolved with a time-integrated depletion in LREE, however, not as severe as that recorded in basalts from the East Pacific Rise. Variable 87Sr/86Sr ratios at less variable 143Nd/144Nd ratios suggest that 87Sr/86Sr ratios of the melts were modified by secondary processes, such as assimilation of seawater Sr from crustal rocks. The Pb isotope ratios are uniform, moderately radiogenic (206Pb/204Pb ca. 18.7 to 18.8), and similar to those reported for the active Mariana arc. Elevated 207Pb/204Pb ratios relative to Pacific MORB suggest melting of small amounts of subducted sediments (ca. 1–2 wt.%). An important control of subducted sediment on the chemistry of the melts can also be inferred from the ratios of highly incompatible trace elements (e.g., Th, U, Pb, La, and Nb). Additional mantle enrichment by subduction derived fluids is reflected in high values of highly incompatible trace element ratios between fluid mobile (e.g., Ba) and fluid immobile elements (e.g., Th, Nb). The results of this study document that the chemical composition of igneous rocks from post-collisional tectonic settings are strongly influenced by previous plate tectonics. This conclusion implies that the information conveyed by tectonic discrimination diagrams for these rocks must be interpreted with care.  相似文献   

6.
The Qinling–Dabie–Sulu belt is the world's largest ultrahigh pressure (UHP) metamorphic belt. The UHP metamorphism is well dated at 220–245 Ma in the Dabie–Sulu belt but at 507 Ma in the Qinling belt. The Tongbaishan is located between the Qinling orogenic belt to the west and the Dabie–Sulu UHP metamorphic belt to the east. It is the key area for studying the tectonic relation between the Qinling and Dabie–Sulu belts and the diachronous UHP metamorphism. The Jigongshan granitic pluton (t=128 Ma) with a total area of 1200 km2, composed of monzogranite, was mostly emplaced into the Tongbai complex, an exposed basement in the Tongbaishan. The Jigongshan granites have SiO2=69.85–72.35%, K2O/Na2O=0.87–1.13, A/CNK=0.91–1.03, Rb/Sr=0.14–0.25 and Th/U=3.3–12. Their REE compositions show strongly fractionated patterns with (La/Yb)N=14–58 and Eu*/Eu=0.79–1.05. The granites are characterized by low radiogenic Pb isotopic composition. The present-day whole-rock Pb isotopic ratios are 206Pb/204Pb=16.707–17.055, 207Pb/204Pb=15.239–15.326 and 208Pb/204Pb=37.587–37.853, which are similar to that of the continental lower crust. Their Nd(t) values range from −16 to −20, and depleted-mantle Nd model ages (TDM) from 1.8 to 2.2 Ga. The above evidence indicates that the magma of the Jigongshan granites was derived from the partial melting of the continental crust. The Pb and Nd isotopic compositions of the Jigongshan granites resemble those of the Dabie core complex in the Dabieshan but are distinct from those of the Tongbai complex in the Tongbaishan. Thus, the Dabie core complex would be the magma source of the Jigongshan granites. The result implies that the Dabie core complex is extended to the west and constitutes the unexposed basement underlaying the Tongbai complex in the Tongbaishan.  相似文献   

7.
Late Triassic granitoids in the Songpan-Garzê Fold Belt (SGFB), on the eastern margin of the Tibetan Plateau, formed at 230 to 220 Ma and can be divided into two groups. Group 1 are high-K calc-alkaline rocks with adakitic affinities (K-adakites), with Sr > 400 ppm, Y < 11 ppm, strongly fractionated REE patterns ((La/Yb)N = 32–105) and high K2O/Na2O (≈ 1). Group 2 are ordinary high-K calc-alkaline I-types with lower Sr (< 400 ppm), higher Y (> 18 ppm) and weakly fractionated REE patterns ((La/Yb)N < 20). Rocks of both groups have similar negative Eu anomalies (Eu/Eu = 0.50 to 0.94) and initial 87Sr/86Sr (0.70528 to 0.71086), but group 1 rocks have higher εNd(t) (− 1.01 to − 4.84) than group 2 (− 3.11 to − 6.71). Calculated initial Pb isotope ratios for both groups are: 206Pb/204Pb = 18.343 to 18.627, 207Pb/204Pb = 15.610 to 15.705 and 208Pb/204Pb = 38.269 to 3759. Group 1 magmas were derived through partial melting of thickened and then delaminated TTG-type, eclogitic lower crust, with some contribution from juvenile enriched mantle melts. Group 2 magmas were generated by partial melting of shallower lower crustal rocks. The inferred magma sources of both groups suggest that the basement of the SGFB was similar to the exposed Kangding Complex, and that the SGFB was formed in a similar manner to the South China basement. Here, passive margin crust was greatly thickened and then delaminated, all within a very short time interval ( 20 Myr). Such post-collisional crustal thickening could be the tectonic setting for the generation of many adakitic magmas, especially where there is no spatial and temporal association with subduction.  相似文献   

8.
Alana M. Hinchey  Sharon D. Carr   《Lithos》2006,90(3-4):223-248
The 62–52 Ma Ladybird granite (LBG) suite is a peraluminous, leucocratic, S-type, quartz monzonitic to granitic suite which occurs as batholiths, stocks, dikes, sills, and pegmatite veins predominantly in the high-grade rocks of the Shuswap complex, in southeastern British Columbia. The emplacement of the LBG was synchronous with the production of abundant migmatites within Thor–Odin dome of the Monashee complex, an exposure of North American basement, exhumed from depths of ca. 26–33 km by Eocene extensional faults. The LBG and the leucosome in migmatites from Thor–Odin dome have similar major and trace element patterns, and are both characterized by zircons which have inherited Precambrian cores. Whole rock Nd isotope compositions show a range of values for the LBG with εNd(55 Ma) values from − 5.0 to − 17.2. The εNd(55 Ma) for the leucosome samples range from − 9.5 to − 23.6, overlapping with those of the granitic suite. These data support the interpretation of a genetic link between formation of the LBG suite and melting of North American basement rocks, such as those exposed in the core of Thor–Odin dome. The leucosome samples have lower high field strength element (HFSE) concentrations and positive Eu anomalies, whereas the LBG samples have higher HFSE concentrations and negative Eu anomalies. The similar trace element characteristics suggest that the leucosome from the migmatites and the LBG are related, whereby most of the leucosome samples are cumulates and the LBG samples represent evolved or residual melts. The initial 87Sr/86Sr isotope values for both the LBG and leucosome samples have a large range. However, the initial Sr isotopic ratios for the LBG suite are lower than those of the leucosome samples, with 87Sr/86Sr(55 Ma) ranging from 0.70603 to 0.73688 and 0.74256 to 0.76593, respectively. This isotopic discrepancy suggests either: a) isotopic disequilibrium during partial melting in the mid- to lower crust where the leucosome formed, b) the distribution of Sr during partial melting was controlled by different melt-producing reactions, and/or c) isotopic heterogeneity in the source rocks. At least part of the LBG suite likely formed via melting of North American basement rocks that were dominantly of sedimentary origin. Melting of the Proterozoic supracrustal metasedimentary rocks overlying North American basement may also have contributed to the formation of the different phases of the suite found at the regional scale. However, the abundant leucosomes in the basement rocks of Thor–Odin dome may mark the paths along which anatectic melt migrated in the structurally overlying Ladybird granites of the South Fosthall pluton.  相似文献   

9.
The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (Nd (540 Ma)=−6.3 to −19.8; δ18O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (87Sr/86Srinitial=0.70794–0.70982). Two leucogranites and one aplite have higher initial 87Sr/86Sr ratios (0.70828–0.71559), but similar initial Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K2O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.  相似文献   


10.
The major and trace elements and Sr–Nd–Pb isotopes of the host rocks and the mafic microgranular enclaves (MME) gathered from the Dölek and Sariçiçek plutons, Eastern Turkey, were studied to understand the underlying petrogenesis and geodynamic setting. The plutons were emplaced at  43 Ma at shallow depths ( 5 to 9 km) as estimated from Al-in hornblende geobarometry. The host rocks consist of a variety of rock types ranging from diorite to granite (SiO2 = 56.98–72.67 wt.%; Mg# = 36.8–50.0) populated by MMEs of gabbroic diorite to monzodiorite in composition (SiO2 = 53.21–60.94 wt.%; Mg# = 44.4–53.5). All the rocks show a high-K calc-alkaline differentiation trend. Chondrite-normalized REE patterns are moderately fractionated and relatively flat [(La/Yb)N = 5.11 to 8.51]. They display small negative Eu anomalies (Eu/Eu = 0.62 to 0.88), with enrichment of LILE and depletion of HFSE. Initial Nd–Sr isotopic compositions for the host rocks are εNd(43 Ma) = − 0.6 to 0.8 and mostly ISr = 0.70482–0.70548. The Nd model ages (TDM) vary from 0.84 to 0.99 Ga. The Pb isotopic ratios are (206Pb/204Pb) = 18.60–18.65, (207Pb/204Pb) = 15.61–15.66 and (208Pb/204Pb) = 38.69–38.85. Compared with the host rocks, the MMEs are relatively homogeneous in isotopic composition, with ISr ranging from 0.70485 to 0.70517, εNd(43 Ma) − 0.1 to 0.8 and with Pb isotopic ratios of (206Pb/204Pb) = 18.58–18.64, (207Pb/204Pb) = 15.60–15.66 and (208Pb/204Pb) = 38.64–38.77. The MMEs have TDM ranging from 0.86 to 1.36 Ga. The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data, in conjunction with the geodynamic evidence, suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, probably triggered by the upwelling of the asthenophere, and interacted with a crustal melt that originated from the dehydration melting of the mafic lower crust at deep crustal levels. Modeling based on the Sr–Nd isotope data indicates that  77–83% of the subcontinental lithospheric mantle involved in the genesis. Consequently, the interaction process played an important role in the genesis of the hybrid granitoid bodies, which subsequently underwent a fractional crystallization process along with minor amounts of crustal assimilation, en route to the upper crustal levels generating a wide variety of rock types ranging from diorite to granite in an extensional regime.  相似文献   

11.
陈吉琛 《地质科学》1991,(2):174-183
澜沧江西侧的临沧花岗岩带和怒江以西的腾冲花岗岩带是滇西最主要的两个花岗岩带,它们形成于不同构造环境。Pb、Sr 同位素研究表明,腾冲花岗岩主要来源于1200-2000Ma 的上地壳(或未分异的地壳)物质,同位素组成变化范围较小,说明源区物质组分较均一。临沧带 Pb 同位素组成变化较大,其物源是上地壳、造山带和上地幔不均匀的混合物,基底时代为800-1600Ma。因此,临沧地区和腾冲地区的基底时代和性质不同,应视为两个不同的基底地体。  相似文献   

12.
The Korosten complex is a Paleoproterozoic gabbro–anorthosite–rapakivi granite intrusion which was emplaced over a protracted time interval — 1800–1737 Ma. The complex occupies an area of about 12 000 km2 in the north-western region of the Ukrainian shield. About 18% of this area is occupied by various mafic rocks (gabbro, leucogabbro, anorthosite) that comprise five rock suites: early anorthositic A1 (1800–1780 Ma), main anorthositic A2 (1760 Ma), early gabbroic G3 (between 1760 and 1758 Ma), late gabbroic G4 (1758 Ma), and a suite of dykes D5 (before 1737 Ma). In order to examine the relationships between the various intrusions and to assess possible magmatic sources, Nd and Sr isotopic composition in mafic whole-rock samples were measured. New Sr and Nd isotope measurements combined with literature data for the mafic rocks of the Korosten complex are consistent and enable construction of Rb–Sr and Sm–Nd isochronous regressions that yield the following ages: 1870 ± 310 Ma (Rb–Sr) and 1721 ± 90 Ma (Sm–Nd). These ages are in agreement with those obtained by the U–Pb method on zircons and indicate that both Rb–Sr and Sm–Nd systems have remained closed since the time of crystallisation. In detail, however, measurable differences in isotopic composition of the Korosten mafic rock depending on their suite affiliation were revealed. The oldest, A1 rocks have lower Sr (87Sr/86Sr(1760) = 0.70233–0.70288) and higher Nd (εNd(1760) = 1.6–0.9) isotopic composition. The most widespread A2 anorthosite and leucogabbro display higher Sr and lower Nd isotopic composition: 87Sr/86Sr(1760) = 0.70362, εNd(1760) varies from 0.2 to − 0.7. The G3 gabbro–norite has slightly lower εNd(1760) varying from − 0.7 to − 0.9. Finally, G4 gabbroic rocks show relatively high initial 87Sr/86Sr (0.70334–0.70336) and the lowest Nd isotopic composition (εNd(1760) varies from − 0.8 to − 1.4) of any of the mafic rocks of the Korosten complex studied to date. On the basis of Sr and Nd isotopic composition we conclude that Korosten initial melts may have inherited their Nd and Sr isotopic characteristics from the lower crust created during the 2.05–1.95 Ga Osnitsk orogeny and 2.0 Ga continental flood basalt event. Indeed, εNd(1760) values in Osnitsk rocks vary from 0.0 to − 1.9 and from 0.2 to 3.4 in flood basalts. We suggest that these rocks being drawn into the upper mantle might melt and give rise to the Korosten initial melts. 87Sr/86Sr(1760) values also support this interpretation. We suggest that the Sr and Nd isotopic data currently available on mafic rocks of the Korosten complex are consistent with an origin of its primary melts by partial melting of lower crustal material due to downthrusting of the lower crust into upper mantle forced by Paleoproterozoic amalgamation of Sarmatia and Fennoscandia.  相似文献   

13.
The Oshurkovo Complex is a plutonic sheeted complex which represents numerous successive magmatic injections into an expanding system of subparallel and subvertical fractures. It comprises a wide range of rock types including alkali monzodiorite, monzonite, plagioclase-bearing and alkali-feldspar syenites, in the proportion of about 70% mafic rocks to 30% syenite. We suggest that the variation within the complex originated mainly by fractional crystallization of a tephrite magma.

The mafic rocks are considered as plutonic equivalents of lamprophyres. They exhibit a high abundance of ternary feldspar and apatite, the latter may attain 7–8 vol.% in monzodiorite. Ternary feldspar is also abundant in the syenites. The entire rock series is characterized by high Ba and Sr concentrations in the bulk rock samples (3000–7000 ppm) and in feldspars (up to 1 wt.%). The mafic magma had amphibole at the liquidus at 1010–1030 °C based on amphibole geothermometer. Temperatures as low as this were due to high H2O and P2O5 contents in the melt (up to 4–6 and 2 wt.%, respectively). Crystallization of the syenitic magmas began at about 850 °C (based on ternary feldspar thermometry). The series was formed at an oxygen fugacity from the NNO to HM buffer, or even higher.

The evolution of the alkali monzodiorite–syenite series by fractional crystallization of a tephritic magma is established on the basis of geological, mineralogical, geochemical and Sm–Nd and Rb–Sr isotope data. The geochemical modeling suggests that fractionation of amphibole with subordinate apatite from the tephrite magma leaves about 73 wt.% of the residual monzonite melt. Further extraction of amphibole and plagioclase with minor apatite and Fe–Ti oxides could bring to formation of a syenite residuum. Rb–Sr isotopic analyses of biotite, apatite and whole-rock samples constrain the minimum age of basic intrusions at ca. 130 Ma and that of cross-cutting granite pegmatites at ca. 120 Ma. Hence the entire evolution took place in an interval of ≤10 My. Initial 87Sr/86Sr ratios for the mafic rocks range from 0.70511 to 0.70514, and for syenites from 0.70525 to 0.70542. Initial Nd (130 Ma) values for mafic rocks vary from −1.9 to −2.4, and for syenites from −2.9 to −3.5. In a Nd(T) vs. (87Sr/86Sr)i diagram, all rock types of the complex fall in the enriched portion of the Mantle Array, suggesting their derivation from a metasomatized mantle source. However, the small but distinguishable difference in Sr and Nd isotopic compositions between mafic rocks and syenites probably resulted from mild (10–20%) crustal contamination during differentiation. Large negative Nb anomalies are interpreted as a characteristic feature of the source region produced by Precambrian fluid metasomatism above a subduction zone rather than by crustal contamination.  相似文献   


14.
Isotope and trace element geochemistry of Colorado Plateau volcanics   总被引：5，自引：0，他引：5  
Basalts from the San Francisco Peaks and North Rim of Grand Canyon, nephelinites from the Hopi Buttes and Navajo minettes (Colorado Plateau) have been analyzed for trace element contents and Sr, Nd, Pb isotope compositions. The ages increase eastward from the Quaternary (basalt) to 5 Ma (nephelinite) and 30 Ma (minette) as does the depth of melt generation inferred from xenolith mineralogy and major element geochemistry.

The three rock types present an enrichment of incompatible elements (although minettes present negative concentration spikes for Nb, Zr, Ti, Ba, Sr) relative to other magma types. The chondrite-normalized Ce/Yb ratio changes from 8–22 (basalt) to 25–30 (nephelinite) and 33–60 (minette) and reflects small degrees of partial melting of a mantle source with a garnet/clinopyroxene ratio increasing with depth. The negative Eu anomaly present in minette, the low Sr/Nd and high Pb/Ce suggest the presence of a recycled continental crust component in their mantle source.

The 87Sr/86Sr ratio varies from 0.7032-0.7045 (basalt and nephelinite) to 0.7052-0.7071 (minette), while εNd is remarkably more constant at +0.8 to +3.7 (nephelinite) and −2.6 to +2.2 (basalt and minette). Good linear correlations are observed in both 207Pb/204Pb and 208Pb/204Pb vs. 206Pb/204Pb diagrams with basalt being the least and nephelinite the most radiogenic and indicate a 2.3 ±0.1 Ga age and a Th/U of 3.4.

Three lithospheric source components are indicated: a) an OIB-type depleted mantle source, b) an end-member with unradiogenic Sr, Nd and Pb for basalt and nephelinite and c) a recycled crustal component for minette.  相似文献   


15.
In NE China, voluminous granitoids were emplaced in late Paleozoic and Mesozoic times. We report here Sr–Nd–O isotopic and elemental abundance data for two highly evolved granitic plutons, Woduhe and Baerzhe, from the Great Xing'an Mountains. They show a rather “juvenile” Sr–Nd isotopic signature and a spectacular tetrad effect in their REE distribution patterns as well as non-CHARAC (charge-and-radius-controlled) trace element behavior. The emplacement ages are constrained at 130±4 Ma for the Woduhe and 122±5 Ma for the Baerzhe granites by Rb–Sr and Sm–Nd isotope analyses. Both granites are also characterized by low but imprecise initial 87Sr/86Sr ratios of about 0.703. The Nd–Sr isotope data argue for their generation by melting of dominantly juvenile mantle component with subordinate recycled ancient crust. This is largely compatible with the general scenario for much of the Phanerozoic granitoids emplaced in the Central Asian Orogenic Belt. The parental magmas for both the Woduhe and Baerzhe granites have undergone extensive magmatic differentiation, during which intense interaction of the residual melts with aqueous hydrothermal fluids (probably rich in F and Cl) resulted in the non-CHARAC trace element behavior and the tetrad effect of REE distribution. Both the Woduhe and Baerzhe granites show the characteristic trace element patterns of rare-metal granites, but their absolute abundances differ by as much as two orders of magnitude. The oxygen isotope compositions of the two granites have been severely disturbed. Significant 18O depletion in feldspar, but not so much in quartz, suggests that the hydrothermal alteration took place in a temperature condition of 300–500 °C. This subsolidus hydrothermal alteration is decoupled from the late-stage magma–fluid interaction at higher temperatures. Despite the two distinct and intense events of “water–rock” interaction, the Rb–Sr and Sm–Nd geochronological systems seem to have maintained closed, hence, suggesting that the two events occurred shortly after the plutonic emplacements.  相似文献   

16.
Voluminous late Mesoproterozoic monzonite through granite of the Vernon Supersuite underlies an area of approximately 1300 km2 in the Highlands of northern New Jersey. The Vernon Supersuite consists of hastingsite±biotite-bearing granitoids of the Byram Intrusive Suite (BIS) and hedenbergite-bearing granitoids of the Lake Hopatcong Intrusive Suite (LHIS). These rocks have similar major and trace element abundances over a range of SiO2 from 58 to 75 wt.%, are metaluminous to weakly peraluminous, and have a distinctive A-type chemistry characterized by high contents of Y, Nb, Zr, LREE, and Ga/Al ratios, and low MgO, CaO, Sr and HREE. Whole-rock Rb–Sr isochrons of BIS granite yield an age of 1116±41 Ma and initial 87Sr/86Sr ratio of 0.70389, and of LHIS granite an age of 1095±9 Ma and initial 87Sr/86Sr ratio of 0.70520. Both suites have similar initial 143Nd/144Nd ratios of 0.511267 to 0.511345 (BIS) and 0.511359 to 0.511395 (LHIS). Values of Nd are moderately high and range from +1.21 to +2.74 in the BIS and +2.24 to +2.95 in the LHIS. Petrographic evidence, field relationships, geochemistry, and isotopic data support an interpretation of comagmatism and the derivation of both suites from a mantle-derived or a juvenile lower crustal parent with little crustal assimilation. Both suites crystallized under overlapping conditions controlled by P–T–fH2O. Lake Hopatcong magma crystallized at a liquidus temperature that approached 900°C and a pressure of about 6 kbar, and remained relatively anhydrous throughout its evolution. Initial P–T conditions of the Byram magma were ≥850°C and about 5.5 kbar. BIS magma was emplaced contemporaneous with, or slightly preceding LHIS magma, and both magmas were emplaced during a compressional tectonic event prior to granulite facies metamorphism that occurred in the Highlands between 1080 and 1030 Ma.  相似文献   

17.
Mesozoic alkaline intrusive complexes are widespread in the southern portion of the North China Craton and can provide some important constraints on the evolution of the Mesozoic lithosphere beneath the region. Three selected intrusive complexes (Tongshi, Hongshan, and Longbaoshan) are generally high in alkalis (K2O+Na2O=913 wt.%) and Al2O3 (1421.6 wt.%) and low in CaO and TiO2 (<0.6 wt.%), with high and variable SiO2 contents. Rocks from these complexes are all enriched in LREE and LILE (Cs, Rb, Ba, U, Th), depleted in Nb and Ti, have a highly positive Pb anomaly, and are characterized by lack of a clear Eu anomaly despite trace element abundances and isotopic ratios that vary greatly between complexes. The Tongshi complex has high Cs (2.68.5 ppm) and REE abundances (∑REE=112.6297 ppm, (La/Yb)N=13.130.9) and MORB-like Sr–Nd–Pb isotopic ratios ((87Sr/86Sr)i<0.704; εNd>0; (206Pb/204Pb)i>18). The Hongshan complex has low REE concentrations (∑REE=28.2118.7 ppm, (La/Yb)N=4.614.7) and is moderately enriched as demonstrated by their Sr–Nd isotopic ratios ((87Sr/86Sr)i>0.706; εNd<−7). The Longbaoshan complex is extremely REE enriched (∑REE=211.3392.6 ppm, (La/Yb)N=32.460.9) and has an EM2-like Sr–Nd isotopic character ((87Sr/86Sr)i>0.7078; εNd<−11). We suggest that the Tongshi complex originated from the asthenosphere and the Hongshan complex and the Longbaoshan complex were derived from the partial melting of previously subduction-modified lithospheric mantle, in response to post-collisional lithospheric extension and asthenospheric upwelling. The occurrence of these alkaline intrusive complexes demonstrates that the lithosphere beneath the region must have been considerably thinned at the time of intrusion of these complexes. This study also shed light on the temporal evolution of the Mesozoic lithosphere and the timing of the lithospheric thinning.  相似文献   

18.
The Quaternary Acatlán Volcanic Field (AVF) is located at the western edge of the Trans-Mexican Volcanic Belt (TMVB). This region is related to the subduction of the Pacific Cocos and Rivera plates beneath the North American plate since the late Miocene. AVF rocks are products of Pleistocene volcanic activity and include lava flows, domes, erupted basaltic andesite, trachyandesite, trachydacite, and rhyolite of calc–alkaline affinity. Most rocks show depletion in high field-strength elements and enrichment in large ion lithophile elements and light rare earth elements as is typical for magmas in subduction-related volcanic arcs. 87Sr/86Sr values range from 0.70361 to 0.70412, while Nd values vary from +2.3 to +5.2. Sr–Nd isotopic data plot along the mantle array. On the other hand, lead isotope compositions (206Pb/204Pb=18.62–18.75, 207Pb/204Pb=15.57–15.64, and 208Pb/204Pb=38.37–38.67) give evidence for combined influences of the upper mantle, fluxes derived from subducted sediments, and the upper continental crust involved in magma genesis at AVF. Additionally δ18O whole rock analyses range from +6.35‰ in black pumice to +10.9‰ in white pumice of the Acatlán Ignimbrite. A fairly good correlation is displayed between Sr as well as O isotopes and SiO2 emphasizing the effects of crustal contamination. Compositional and isotopic data suggest that the different AVF series derived from distinct parental magmas, which were generated by partial melting of a heterogeneous mantle source.  相似文献   

19.
The Indosinian granites in the South China Block (SCB) have important tectonic significance for the evolution of East Asia. Samples collected from Hunan Province can be geochemically classified into two groups. Group 1 is strongly peraluminous (A/CNK > 1.1), similar to S-type granites, and Group 2 has A/CNK = 1.0–1.1, with an affinity to I-type granites. Group 1 has lower FeOt, Al2O3, MgO, CaO, TiO2 and εNd(t) values but higher K2O + Na2O, Rb/Sr, Rb/Ba and 87Sr/86Sr(t) than those of Group 2. Samples of both groups have similar LREE enriched pattern, with (Eu/Eu) = 0.19–0.69, and strongly negative Ba, Sr, Nb, P and Ti anomalies. Geothermobarometry study indicates that the precursor magmas were emplaced at high-level depth with relatively low temperature (734–827 °C). Geochemical data suggest that Group 1 was originated from a source dominated by pelitic composition and Group 2 was from a mixing source of pelitic and basaltic rocks with insignificant addition of newly mantle-derived magma. Eight granitic samples in Hunan Province are dated at the cluster of 243–235 and 218–210 Ma by zircon U–Pb geochronology. Together with recent zircon U–Pb ages for other areas in the SCB, two age-clusters, including 243–228 Ma just after peak-metamorphism ( 246–252 Ma) and 220–206 Ma shortly after magma underplating event (224 Ma), are observed. It is proposed that in-situ radiogenic heating from the over-thickened crust induced dehydrated reaction of muscovite and epidote/zoisite to form the early Indosinian granites in response to the isostatic readjustments of tectonically thickened crust. Conductive heating from the underplating magma in the postcollisional setting triggered the formation of late Indosinian granites. Such a consideration is supported by the results from FLAC numerical simulation.  相似文献   

20.
Temperature estimates and chemical composition of mantle xenoliths from the Cretaceous rift system of NW Argentina (26°S) constrain the rift evolution and chemical and physical properties of the lithospheric mantle at the eastern edge of the Cenozoic Andean plateau. The xenolith suite comprises mainly spinel lherzolite and subordinate pyroxenite and carbonatized lherzolite. The spinel lherzolite xenoliths equilibrated at high-T (most samples >1000 °C) and P below garnet-in. The Sm–Nd systematics of compositionally unzoned clino- and orthopyroxene indicate a Cretaceous minimum age for the high-T regime, i.e., the asthenosphere/lithosphere thermal boundary was at ca. 70 km depth in the Cretaceous rift. Major elements and Cr, Ni, Co and V contents of the xenoliths range between values of primitive and depleted mantle. Calculated densities based on the bulk composition of the xenoliths are <3280 kg/m3 for the estimated P–T conditions and indicate a buoyant, stable upper mantle lithosphere. The well-equilibrated metamorphic fabric and mineral paragenesis with the general lack of high-T hydrous phases did not preserve traces of metasomatism in the mantle xenoliths. Late Mesozoic metasomatism, however, is obvious in the gradual enrichment of Sr, U, Th and light to medium REE and changes in the radiogenic isotope composition of an originally depleted mantle. These changes are independent of the degree of depletion evidenced by major element composition. 143Nd/144Ndi ratios of clinopyroxene from the main group of xenoliths decrease with increasing Nd content from >0.5130 (depleted samples) to ca. 0.5127 (enriched samples). 87Sr/86Sri ratios (0.7127–0.7131, depleted samples; 0.7130–0.7134, enriched samples) show no variation with variable Sr contents. Pbi isotope ratios of the enriched samples are rather radiogenic (206Pb/204Pbi 18.8–20.6, 207Pb/204Pbi 15.6–15.7, 208Pb/204Pbi 38.6–47) compared with the Pb isotope signature of the depleted samples. The large scatter and high values of 208Pb/204Pbi ratios of many xenoliths indicates at least two Pb sources that are characterized by similar U/Pb but by different Th/Pb ratios. The dominant mantle type in the investigated system is depleted mantle according to its Sr and Nd isotopic composition with relatively radiogenic Pb isotope ratios. This mantle is different from the Pacific MORB source and old subcontinental mantle from the adjacent Brazilian Shield. Its composition probably reflects material influx into the mantle wedge during various episodes of subduction that commenced in early Paleozoic or even earlier. Old subcontinental mantle was already replaced in the Paleozoic, but some inheritance from old mantle lithosphere is represented by rare xenoliths with isotope signatures indicating a Proterozoic origin.  相似文献   

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