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1.
Abstract We collected free-gas and in situ fluid samples up to a depth of 200.6 m from the Sagara oil field, central Japan (34°44'N, 138°15'E), during the Sagara Drilling Program (SDP) and measured the concentrations and stable carbon isotopic compositions of CH4 and C2 H6 in the samples. A combination of the CH4 /C2 H6 ratios with the carbon isotope ratios of methane indicates that the hydrocarbon gases are predominantly of thermogenic origin at all depths. The isotope signature of hydrocarbon gases of δ13 < δ13 suggests that these gases in the Sagara oil field are not generated by polymerization, but by the decomposition of organic materials. 相似文献
2.
Abstract Rocks from Karaginsky accretionary prism (Karaginsky Island, Bering Sea) yield both prefolding (close to original) and postfolding magnetic vectors. The prefolding vectors suggest that the Maastrichtian–Paleocene volcanic–terrigenous sequences of Karaginsky Island formed at approximately 40°N to 50°N ( n = 45, D G = 325, I G = 57, K G = 6, α95G = 8, F G = 15.06, D S = 332, I S = 63, K S = 20, α95S = 4.5, F S = 0.3297, F cr = 2.64) and were not originally part of either Eurasia ( F = 19, Δ F = 6.5) or North America ( F = 17, Δ F = 4.4). The geologic blocks rotated insignificantly counterclockwise about the horizontal plane, suggesting that the structure of Karaginsky Island arose without major strike-slip motions. Analysis of secondary magnetizations (for example, n = 28, D G = 311, I G = − 50, K G = 9, α95G = 8.7, F G = 2.44; D S = 293, I S = − 41, K S = 5, α95S = 11, F S = 12.04, F cr = 2.65) reveals that the development of this framework involved at least two stages of deformation. During the second stage the sequences must have been tilted to west-northwest and northwest directions at 45–65°. This agrees with the northwest vergence of the structure of Karaginsky Island. 相似文献
3.
A discussion on the boundary between diagenesis and metamorphism with reference to zeolite facies 总被引：1，自引：0，他引：1
Abstract A Triassic formation in the Turpan-Hami and Ordos basin of China gives two typical examples of occurrence of laumontite belonging to diagenetic facies. Sandstones of the Upper Triassic Yanchang Formation in the eastern sector of the Ordos basin are formed at the mature stage of mesodiagenesis at temperatures in the range of 71-120°C, while the temperatures of the oil-bearing beds Chang-6 and Chang-7 where laumontite is present are about 81-88°C. The laumontite-bearing beds of the Middle Triassic in the Hami depression are presently at the supermature stage of organic matter, the corresponding diagenetic temperature being about 140 °C. The term zeolite facies should be rejected, and the features of metamorphic stage should be clearly denned, such as closely packed grains, absence of pores and cements, and characteristic mineral assemblages including sericite, epidote, muscovite, illite (2M1 ), chlorite (IIb, β= 97°), dickite, pyrophyllite, graphite, chlorozeolite formed at temperatures of 200°C and Ro values of 2.5%; the stage is also characterized by schistosity and illite crystallinity of IC = 0.42°Δ 2θ. The anchimetamorphic zone is characterized by some characteristic minerals such as paragonite, rectorite, albite, laumontite, illite (1M), chlorite (Ib, P = 90°+ IIb, β= 97°) formed at temperatures of 130-200°C and Ro values of 1.3-2.5% as well as other quantitative parameters of organic matter. 相似文献
4.
Chrome-rich clinopyroxene in orthopyroxenite from Maowu, Dabie Mountains, central China: A second record and its implications for petrogenesis 总被引：1，自引：0，他引：1
A second occurrence of chrome-rich clinopyroxene has been discovered as inclusions in orthopyroxene in orthopyroxenite from Maowu, the Dabie Mountains, Central China. The average formula for chrome-rich clinopyroxene can be expressed as (Na0.39 Ca0.54 )0.93 (Mg0.57 Fe2+ 0.06 Fe3+ 0.01 Cr0.24 Al0.15 )1.03 Si2.02 O6 , with a maximum amount of kosmochlor component of 28.52 mol%. The unit cell parameters obtained from a single-crystal are a = 9.614 Å, b = 8.800 Å, c = 5.240 Å, β = 106.59°, space group C2 / c . The indices of refraction are α = 1.697, β = 1.704, γ = 1.726. Chrome-rich clinopyroxene, which coexists with chromite, chromian rutile and chromian pyrope, crystallized at a temperature of 1025 °C and very high pressure, and therefore represents a mantle relic. Together with the appearance of low-pressure inclusion mineral assemblage and the estimation of physical–chemical conditions for matrix minerals, the Maowu eclogite–ultramafic complex is considered to be formed during ultrahigh-pressure metamorphism from the mantle-derived protolith. 相似文献
5.
Abstract The Maksyutov Complex, situated in the southern Ural Mountains of Russia, is the first location where quartz aggregates within garnets exhibiting radial fractures were identified as coesite pseudomorphs (Chesnokov & Popov 1965). The complex consists of two tectonic units: a structurally lower eclogite-bearing schist unit and an overlying meta-ophiolite unit. Both units show evidence for multiple stages of metamorphism and deformation. The high-pressure metamorphism of the eclogite-bearing schist unit, discussed in this report, is suspected to be related to a collision between the Russian platform and a fragment of the Siberian continent during the early Cambrian. At least three stages of metamorphism (M1-3 ) and two stages of deformation (S1 and S2 ) were observed in thin sections: M1 ) garnet (Alm55-60 , Prp22-28 , Grs16-20 ) + omphacite (Jd46-56 ) + phengite (Si ≅ 3.5) + rutile; M2 ) garnet + glaucophane ± lawsonite + white mica; and M3 ) epidote + chlorite ± albite ± actinolite + white mica. Observed mineral parageneses define a retrograde P-T path for the eclogite. Mineral assemblages within the most representative eclogite from the lower unit of the Maksyutov Complex indicate minimum peak pressures of 15 kbar at temperatures of approximately 600°C. If the presence of coesite pseudomorph is confirmed, the peak ultrahigh-pressure metamorphism may be as high as 27 kbar at 615°C. 相似文献
6.
Yoshihide Ogasawara Masahito Ohta Kyoka Fukasawa Ikuo Katayama and Shigenori Maruyama 《Island Arc》2000,9(3):400-416
Abstract Dolomite marble from the Kumdy–Kol area of the Kokchetav Massif contains abundant microdiamond, mainly in garnet and a few in diopside. The mineral assemblage at peak metamorphic condition consists of dolomite + diopside + garnet (+ aragonite) ± diamond. Inclusions of very low MgCO3 calcite and almost pure calcite occur in diopside and are interpreted as aragonite and/or aragonite + dolomite. Single-phase Mg–calcite in diopside with a very high MgCO3 component (up to 21.7 mol%) was also found in diamond-free dolomitic marble, and is interpreted as a retrograde product from aragonite + dolomite to Mg–calcite. The dolomite stability constrains the maximum pressure (P) at < 7 GPa using previous experimental data, whereas the occurrence of diamond yields the minimum peak pressure–temperature (P–T) condition at 4.2 GPa and 980 °C at X co 2 = 0.1. The highest MgCO3 in Mg–calcite constrains the minimum P–T condition higher than 2.5 GPa and 800 °C for the exhumation stage. As these marbles were subjected to nearly identical P–T metamorphic conditions, the appearance of diamond in some carbonate rocks was explained by high X co 2 . A low X co 2 condition refers to high oxidized conditions and diamond (and/or graphite) becomes unstable. Difference in X co 2 for marble from the same area suggests local heterogeneity of fluid compositions during ultrahigh-pressure metamorphism. 相似文献
7.
A conceptual model of eolian transport is proposed to address the widely distributed, high concentrations of hexavalent chromium (Cr+6 ) observed in ground water in the Emirate of Abu Dhabi, United Arab Emirates. Concentrations (30 to more than 1000 μg/L Cr+6 ) extend over thousands of square kilometers of ground water systems. It is hypothesized that the Cr is derived from weathering of chromium-rich pyroxenes and olivines present in ophiolite sequence of the adjacent Oman (Hajar) Mountains. Cr+3 in the minerals is oxidized to Cr+6 by reduction of manganese and is subsequently sorbed on iron and manganese oxide coatings of particles. When the surfaces of these particles are abraded in this arid environment, they release fine, micrometer-sized, coated particles that are easily transported over large distances by wind and subsequently deposited on the surface. During ground water recharge events, the readily soluble Cr+6 is mobilized by rain water and transported by advective flow into the underlying aquifer. Chromium analyses of ground water, rain, dust, and surface (soil) deposits are consistent with this model, as are electron probe analyses of clasts derived from the eroding Oman ophiolite sequence. Ground water recharge flux is proposed to exercise some control over Cr+6 concentration in the aquifer. 相似文献
8.
Keika Horiguchi Sadato Ueki Yuji Sano Naoto Takahata Akira Hasegawa George Igarashi 《Island Arc》2010,19(1):60-70
In order to study the precise geographical distribution of helium isotope ratios in northeastern Japan and compare it with geophysical data, we collected 43 gas and water samples from hot and mineral springs in the region where the ratio had never been reported, and measured the 3 He/4 He and 4 He/20 Ne ratios of these samples. It was found that the 3 He/4 He ratios show clear contrasts between the forearc and the back-arc regions in the Tohoku district in northeastern Japan. In the forearc region, the ratios are smaller than 1 RA (1 RA = 1.4 × 10−6 ; RA means the 3 He/4 He ratio of the atmosphere). On the other hand, those along the volcanic front and in the back-arc region are apparently higher. Moreover, we found a variation in the 3 He/4 He ratios along the volcanic front. In Miyagi Prefecture (38–39°N), the ratios range from 2 to 5 RA . On the other hand, the ratios are less than 1 RA in and around the southern border between Iwate and Akita Prefectures (39–39.5°N). Comparing the distribution of helium isotope ratios to results of recent geophysical studies, we found that the features in geographical distribution of helium isotope ratios are similar to those of seismic low-velocity zone distributions and high Qp−1 distributions in the uppermost mantle. These observations strongly suggest that the helium isotope ratios reflect the distribution of melts in the uppermost mantle and are a useful tool for investigating the origin, behavior, and distribution of deep fluids and melts. 相似文献
9.
Hydraulic Conductivity Measurements in the Unsaturated Zone Using Improved Well Analyses 总被引：4，自引：0，他引：4
The flow of ponded water into and through the unsaturated zone depends on both the saturated and unsaturated components of the hydraulic conductivity. Recent studies indicate that the ratio of the saturated (Kfs ) to the unsaturated (φm ) components (Kfs /φm =α*) of flow lies within prescribed bounds for most field soils, i.e., 1m−1 ≤α*≤ 100 m−1 . In addition, the fact that the calculation of Kfs and φm is not strongly dependent on the choice of α*, suggests that a site estimation of α* leads to reasonable "best estimates" of Kfs and φm when using the constant head well permeameter technique. As a consequence, measurement of the steady flow rate using only one ponded head may be all that is necessary for many practical applications. Multiple head measurements or independent measurements of α* or φm can be used, however, to give more accurate estimates of Kfs if required. 相似文献
10.
大地震的震源机制及地震矩、应力降等参数,不(又对认识地震的破裂过程,而且对预报强地面运动都是非常重要的。一些文章对板内地震应力降的特点、地震矩与高频源谱的关系及区域特征的讨论,使我们可直接由长周期体波或面波得出的地震矩M0估计出不同地区中大地震的高频源谱,以供强地面运动预报参考。 由于对发生在中国板内的1976年11月6日盐源地震（Ms=6.5）和1976年11月15日宁河地震（Ms=6.3）的震源参数还没有详尽的报道;另外,对1973年7月14日 相似文献
11.
Geothermal gradient of the upper mantle beneath Jeju Island, Korea: Evidence from mantle xenoliths 总被引：2，自引：0，他引：2
Abstract Ultramafic xenoliths found in alkali basalts from Jeju Island, Korea are mostly spinel lherzolites accompanied by subordinate amount of spinel harzburgites and pyroxenites. The combination of results from a two-pyroxene geothermometer and Ca-in-olivine geobarometer yields temperature–pressure (T–P) estimates for spinel peridotites that fall in experimentally determined spinel lherzolite field in CaO-Fe-MgO-Al2 O3 -SiO2 -Cr2 O3 (CFMASCr) system. These T–P data sets have been used to construct the Quaternary Jeju Island geotherm, which defines a locus from about 13 kbar at 880°C to 26 kbar at 1040°C. The geothermal gradient of Jeju Island is greater than that of the conventional conductive models, and may be as a result of a thermal perturbation by the heat input into the lithospheric mantle via the passage and emplacement of magma. Spinel–lherzolite is the main constituent rock-type of the lithospheric mantle beneath Jeju Island. Pyroxenites may be intercalated in peridotites at similar depth and temperature as re-equilibrated veins or lenses. 相似文献
12.
Thomas D. Papiernik Sharon K. Widmer Roy F. Spalding 《Ground Water Monitoring & Remediation》1996,16(1):80-84
Studies have shown that materials, such us polytetra-fluoroethylene (PTFE), rigid polyvinyl chloride (rigid PVC). flexible polyvinyl chloride (flexible PVC), stainless steel (SS). low-density polyethylene (LDPE), and high-density polyethylene (HDPE), have the potential to influence certain analyte concentrations in ground water samples. The effects of HDPE, LDPE, PTFE, rigid PVC, and SS on aqueous concentrations of nitrate-N, atrazine, deethylatrazine (DEA), and deisopropylatrazine (DIA) were evaluated in a field study A laboratory study was conducted to evaluate sorption of atrazine DEA, DIA, cyanazine, alachlor, metolachlor, and butachlor to PTFE, HDPE, and SS materials. Butachlor is rarely use in the United States, but was included because of its expected high sorptivity. No significant differences between HDPE, LDPE, PTFE, rigid PVC, and SS were determined for any of the analytes tested in the field study. In the laboratory study, sorption of DIA to PTFE and SS was significant at 2.6 × 10−5 and 4.1 × 10−5 μg/m2 respectively. Sorption of DIAA to HDPE was not significantly > 0 sorption of all other compounds to HDPE, PTFE, and SS were also not significantly >0. Results of the two studies indicate that for these analytes (relatively polar or ionized compounds), representative ground water samples are not dependent on the materials used for multilevel sampler construction. When considering these compounds, it appears that the least expensive materials (HDPE, rigid PVC, and LDPE) are good choices for the construction of ground water monitoring wells. 相似文献
13.
Abstract Elemental and isotopic compositions of noble gases extracted from the bore hole water in Osaka plain, central Japan were examined. The water samples were collected from four shallow bore holes (180-450 m) and seven deep bore holes (600-1370 m) which have been used for an urban resort hot spring zone. The water temperatures of the deep bore holes were 22-50°C and that of the shallow bore holes, 13-23°C. The elemental abundance patterns show the progressive enrichment of the heavier noble gases compared with the atmospheric noble gas composition except for He, which is heavily enriched in deep bore hole water samples. 3 He/4 He ratios from the bore holes reaching the Ryoke granitic basement were higher than the atmospheric value (1.4 × 10−6 ), indicating a release of mantle He through the basement. The highest value of 8.2 × 10−6 is in the range of arc volcanism. On the other hand, the bore holes in sedimentary rocks overlying the basement release He enriched in radiogenic 4 He, resulted in a low 3 He/4 He ratio of 0.5 × 10−6 . 4 He/20 Ne and 40 Ar/36 Ar ratios indicate that the air contamination is generally larger in shallow bore holes than in deep ones from each site. The helium enriched in mantle He is compatible with the previous work which suggested up-rising magma in 'Kinki Spot', the area of Osaka and western Wakayama, in spite of no volcanic activity in the area. A model to explain an initiation of magma generation beneath this area is presented. 相似文献
14.
A six year field experiment has shown that a sand-bentonite mixture used to seal monitoring wells in aquitards contributes solutes to the ground water sampled from these wells. Monitoring wells were installed at field sites with hydraulic conductivity (K) ranging from 5 × 10 -9 m/s to 3 × 1011 m/s. In most cases the boreholes remained dry during installation which allowed the placement of a dry powdered bentonite/sand mixture tagged with potassium bromide (KBr) to seal and separate sampling points. Over six years, wells were sampled periodically and ground-water samples were analyzed for Br and Cl and other major ions. Typical Br results ranged from 10 mg/1 to 35 mg/1 in the first 700 days, as compared to an estimated initial concentration in the seal material of about 75 mg/1. After six years the bromide concentrations had decreased to between 3 mg/1 and 5 mg/1. The total mass of Br removed in six years is less than 50% of that placed; therefore the contamination effects, although considerably diminished, persist. The trends of Br, Cl, Na, and SO4 indicate that varying degrees of contamination occur. These data show that the materials used to seal monitoring wells in aquitards can have a significant and long-lasting impact on the chemistry of the water in the wells. 相似文献
15.
The sorption of heavy oil onto sediment collected from Jiaozhou Bay was studied in a series of kinetic and equilibrium experiments using NaCl solutions. The effects of temperature, salinity, and pH of the medium on sorption behavior were investigated.Sorption equilibrium of the heavy oil and sediment was established within 60 min. The process was shown to follow a pseudo-second-order kinetic rate model. The sorption rate decreased with increasing initial heavy oil concentration in the solution. Batch equilibrium experiments showed that the sorption isotherm could be described by the Freundlich model. The standard free energy change and enthalpy change at the temperatures studied (283, 288, 293, and 298 K) were negative. These findings indicated that the process was spontaneous and exothermic. Salinity, pH and temperature influenced sorption performance. Sorption was favored by higher concentrations of NaCl, by lower pH values and by lower temperatures. 相似文献
16.
Abstract Illite crystallinity (IC) and illite b, lattice spacing were measured across the Cretaceous Shimanto Belt, Kii Peninsula, Southwest Japan. For the IC survey, 103 samples of argillaceous rocks were analyzed from the central area and the western area of the belt. Values of IC (Kubler Index) vary between 0.28 and 0.71 Δ°2θ and indicate diagenetic and anchizone metamorphism respectively. The IC distribution reveals two contrasting patterns of thermal maturity. The Hanazono Formation, exposed in the northern area of the belt, generally dips north, but IC values increase systematically from 0.28 Δ°2θ in the north to 0.54 Δ°2θ in the south and indicate an inverted thermal structure. Values in other formations vary widely in the southern area of the belt ranging between 0.45 and 0.71 Δ°2θ, but the values do not show any systematic change from north to south and on average remain almost constant. Illite bo , lattice spacing values for 56 samples vary between 9.006 and 9.041 Å corresponding to intermediate pressure conditions of the metamorphic facies. These values, combined with paleotemperatures estimated from IC, indicate paleogeothermal gradients of 22 and 31°C/km for the northern and southern areas of the belt, respectively. The inverted thermal structure of the Hanazono Formation, together with a lower paleogeothermal gradient, possibly is a result of the subduction of a relatively cold oceanic plate during the Late Cretaceous. The higher geothermal gradient could be a product of late thermal overprinting caused by the later subduction of a comparatively younger and hotter oceanic plate during the Eocene. 相似文献
17.
P.C. Johnson R.A. Ettinger J.P. Kurtz R. Bryan J.E. Kester 《Ground Water Monitoring & Remediation》2009,29(1):153-159
The area surrounding the Colorado Department of Transportation Materials Testing Laboratory in Denver was the subject of intense investigation, involving the collection of thousands of ground water, soil-gas, and indoor air samples in order to investigate indoor air impacts associated with a subsurface release of chlorinated solvents. The preremediation portion of that data set is analyzed and reduced in this work to ground water–to-indoor air attenuation factors (αgw = the ratio of the measured indoor air concentration to the soil-gas concentration predicted to be in equilibrium with the local ground water concentration). The empirical αgw values for this site range from about 10−6 to 10−4 with an overall average of 3 × 10−5 (μg/L indoor air)/(μg/L soil gas). The analysis of this data set highlights the need for a thorough data review and data screening when using large data sets to derive empirical relationships between subsurface concentrations and indoor air. More specifically, it is necessary to identify those parts of the data that contain a strong vapor intrusion pathway signal, which generally will require concentrations well above reported detection levels combined with spatial or temporal correlation of subsurface and indoor concentrations. 相似文献
18.
Quartz microtextures of the Sambagawa schists and their implications in convergent margin processes 总被引：1，自引：0，他引：1
Nobuo Sakakibara Ikuo Hara Kenji Kanai Kenji Kaikiri Tugio Shiota Kei Hide Peter Paulitsch 《Island Arc》1992,1(1):186-197
Abstract Quartz c-axis fabrics of the Sambagawa schists produced along a late Mesozoic convergent plate margin were analysed so that their tectono-metamorphic history could be clarified. It has been noted by many authors that quartz fabrics produced by earlier phase deformation are easily modified by strain increment during later phase deformation. This paper attempts to elucidate the high-temperature phases of prograde metamorphism (Sim-Bim phase) and of retrograde metamorphism (Sb1 phase and Sb2−1 phase) from quartz grains included in garnet and plagioclase porphyroblasts. Quartz c-axis fabrics for all these phases are explained in terms of a type I crossed girdle, without (only rarely with) higher concentration in the principal axis of strain Y (X>Y>Z), that must have been produced by the activity of a dominant slip system such as rhomb and basal. As a result, the plastic deformation of quartz, which was responsible for the formation of the type I crossed girdle, occurred even under temperatures greater than 500°C and pressures a little greater than 10–11 kb, which correspond to the physical condition of the Sim-Bim phase. It has been assumed that a high strain rate (and/or low H2 O content) caused rhomb and basal to be active as dominant slip systems in the subduction zone related to the formation of the Sambagawa schists even under high temperatures (> 500°C). 相似文献
19.
Monitoring the Removal of Phosphate from Ground Water Discharging through a Pond-Bottom Permeable Reactive Barrier 总被引：1，自引：0，他引：1
Timothy D. McCobb Denis R. LeBlanc Andrew J. Massey 《Ground Water Monitoring & Remediation》2009,29(2):43-55
Installation of a permeable reactive barrier to intercept a phosphate (PO4 ) plume where it discharges to a pond provided an opportunity to develop and test methods for monitoring the barrier's performance in the shallow pond-bottom sediments. The barrier is composed of zero-valent-iron mixed with the native sediments to a 0.6-m depth over a 1100-m2 area. Permanent suction, diffusion, and seepage samplers were installed to monitor PO4 and other chemical species along vertical transects through the barrier and horizontal transects below and near the top of the barrier. Analysis of pore water sampled at about 3-cm vertical intervals by using multilevel diffusion and suction samplers indicated steep decreases in PO4 concentrations in ground water flowing upward through the barrier. Samples from vertically aligned pairs of horizontal multiport suction samplers also indicated substantial decreases in PO4 concentrations and lateral shifts in the plume's discharge area as a result of varying pond stage. Measurements from Lee-style seepage meters indicated substantially decreased PO4 concentrations in discharging ground water in the treated area; temporal trends in water flux were related to pond stage. The advantages and limitations of each sampling device are described. Preliminary analysis of the first 2 years of data indicates that the barrier reduced PO4 flux by as much as 95%. 相似文献
20.
Eloctromigraiion offers a potential tool for remediating ground water contaminated with highly soluble components, such as Na+ , Cl, NO3 and SO4 − . A field experiment was designed to lest the efficacy of electromigration for preconcontrating dissolved SO4 2 in ground water associated with a fossil-fuel power plant. Two shallow wells, 25 feel apart (one 25 feel deep, the other 47 feet deep), were constructed in the upper portion of an unconfined alluvial aquifer. The wells were constructed with a double-wall design, with an outer casing of 4-inch PVC and an inner lube of 2-inch FVC; both were fully slotted (0.01 inch). Electrodes were constructed by wrapping the inner lulling with a 100-foot length of rare-earth metal oxide/copper wire. An electrical potential of 10.65 volts DC Was applied, and tests were run for periods of 12, 44, and 216 hours. Results showed large changes in the pH from the initial pH of ground water of about 7.5 to values of approximately 2 and 12 at the anode and cathode, respectively. Despite the fact that the test conditions were far from ideal, dissolved SO4 2- ; was significantly concentrated at the anode. Over a period of approximately nine days, the concentration of SO4 2- at the anode reached what appeared to he a steady-state value of 2200 mg/L. compared lo the initial value in ground water of approximately 1150 mg/L. The results of this field lest should encourage further investigation of electromigration as a tool in the remediation of contaminated ground water. 相似文献