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利用高铝粉煤灰制备莫来石微晶玻璃的实验研究 总被引：1，自引：0，他引：1
以高铝粉煤灰为主要原料,采用粉末烧结法制备出莫来石微晶玻璃。X射线衍射分析显示,经1350~1550℃热处理后,制得的微晶玻璃的主晶相均为莫来石。扫描电镜分析表明,较高的温度下热处理有利于晶体的生长。微晶玻璃的理化性能如吸水率、气孔率、体积密度、抗折强度和化学稳定性,随热处理温度的不同而发生相应的变化。1500℃热处理2 h制得的微晶玻璃具有优良的理化性能,在工程和结构领域具有潜在的应用前景。 相似文献
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利用高铝粉煤灰制备堇青石微晶玻璃的实验研究 总被引：1，自引：0，他引：1
以高铝粉煤灰为主要原料，制备了堇青石微晶玻璃。通过差热分析（DTA）和X射线粉末衍射分析（XRD）确定了合适的热处理条件：核化温度807℃，核化时间2h，晶化温度960℃，晶化时间3h。XRD分析显示，制得微晶玻璃的主晶相为堇青石。SEM分析表明，基础玻璃晶化完全，微晶玻璃中微晶体呈不规则柱状、棒状，微晶体长度为5～15μm，长径比为5～10。 相似文献
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利用矿物内部一致性热力学数据，建立了在ＣａＯ－Ａｌ２Ｏ３－ＭｇＯ－ＳｉＯ２－Ｈ２Ｏ体系中含钙铝榴石的葡萄石－绿纤石变质相平衡，确立了在葡萄石－绿纤石－钙铝榴石－绿帘石－绿泥石－石英组合中出现绿纤石－钙铝榴石共生、葡萄石－绿纤石共生、葡萄石－绿帘石共生和绿泥石－绿帘石－钙铝榴石共生的ＰＴ区间及其意义。根据该相平衡计算了新疆萨尔托海蛇绿岩中变基性岩石的葡萄石－绿纤石相变质ＰＴ条件为Ｔ＝３２５℃～３３５℃，Ｐ＝０．４５～０．４７５ＧＰａ。并讨论了Ｆｅ３＋＝Ａｌ替代对于形成钙铝榴石－绿纤石共生的影响。本文的研究表明，葡萄石－绿纤石－钙铝榴石－绿帘石－绿泥石－石英共生组合是葡萄石－绿纤石相中偏高压组合，钙铝榴石－绿纤石共生与绿纤石－阳起石相一样代表着葡萄石－绿纤石相中较高压相，钙铝榴石在葡萄石－绿纤石相中是可以稳定存在的。 相似文献
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钙铝—钙铁系列石榴子石的特征及其交代机理 总被引：1，自引：0，他引：1
本文作者在全国14个典型矿区的野外工作基础上，进行了超基性-酸性侵入岩与碳酸盐岩的接触交代实验;火山气热液与火山岩的相互交代实验;区域沉积变质和混合岩化过程中的交代作用实验。实验结果表明，在350-700℃和300×105-1400 ×lO5 Pa的温度、压力条件下，在lon fO2=-28.637- -16.514的氧逸度范围内，在pH= 4.0-11.0的含不同浓度Na、K卤化物的溶液中，形成了水榴石、水钙铝榴石、钙铝榴石、钙铁榴石以及水榴石-水钙铝榴石、水钙铝榴石-钙铝榴石和钙铝榴石-钙铁榴石的过渡性矿物。用显微镜、X射线衍射和红外光谱等分析方法，测定了它们的主要光学特征。最后，通过物理化学条件的分析，揭示了它们形成的交代机理。 相似文献
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钙铝－钙铁系列石榴子石的特征及其交代机理 总被引：10，自引：0，他引：10
本文作者在全国１４个典型矿区的野外工作基础上，进行了超基性－酸性侵入岩与碳酸盐岩的接触交代实验；火山气热液与火山岩的相互交代实验；区域沉积变质和混合岩化过程中的交代作用实验。实验结果表明，在３５０－７００℃和３００×１０￣５－１４００×１０￣５ｐａ的温度、压力条件下，在ｌｏｇｆＯ＿２＝－２８．６３７－－１６．５１４的氧逸度范围内，在ｐＨ＝４．０－１１．０的含不同浓度Ｎａ、Ｋ卤化物的溶液中，形成了水榴石、水钙铝榴石、钙铝榴石、钙铁榴石以及水榴石、水钙铝榴石、水钙铝榴石－钙铝榴石和钙铝榴石－钙铁榴石的过渡性矿物。用显微镜、Ｘ射线衍射和红外光谱等分析方法，测定了它们的主要光学特征。最后，通过物理化学条件的分析，揭示了它们形成的交代机理。 相似文献
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利用钾长石合成雪硅钙石纳米粉体的反应机理研究 总被引：2，自引：2，他引：0
采用CaO为助剂,在水热条件下分解钾长石,进而合成雪硅钙石。影响反应的主要因素为：n(CaO)/n(SiO2+AlO1.5)、晶化温度和晶化时间等。在n(CaO)/n(SiO2+AlO1.5)为0.75～1.00、晶化温度为230～250 ℃、晶化时间为5～8 h的条件下,可以合成结晶良好的雪硅钙石晶体。反应机理分析表明：在钾长石-氧化钙的水热体系中,钾长石的分解并不是简单的离子交换作用或铝硅酸盐解聚作用,而是在碱金属离子与水作用的基础上,反应物中H+与矿物表面的碱金属离子K+、Na+、Ca2+作用,首先形成表面富硅贫铝的前驱聚合体（SiO2·nH2O）;然后这些前驱聚合体分解,与溶液中的Ca2+作用,生成C-S-H凝胶和水钙铝榴石;随着反应时间的延长,C-S-H凝胶和水钙铝榴石进一步转变为雪硅钙石。 相似文献
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在165℃、175℃、185℃和195℃的温度条件下,对水热处理前和处理后的粗晶三水铝石样品分别进行了XRD分析和SEM表征,研究了粗晶三水铝石在水蒸气和热水中转变成勃姆石的相变过程。结果表明,水热条件下粗晶三水铝石转化成勃姆石的过程受控于溶解-再沉淀机制,而并非是通常认为的固体状态下的转变;相对于在热水中,水蒸气环境可以加速三水铝石向勃姆石的转化;所形成的勃姆石的粒径（4~7 μm）明显比前驱体三水铝石的粒径（120~200 μm）要小得多,表明可以利用粗晶三水铝石生产微晶勃姆石。在转化过程中,勃姆石微晶首先生长在三水铝石的晶体表面上,通过控制反应温度和反应时间,可形成壳层为勃姆石、壳下为三水铝石的具有双层结构的铝的氢氧化物颗粒,也有可能形成具有中空结构的勃姆石集合体颗粒。 相似文献
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与翡翠相似的玉石“不倒翁”的矿物学研究 总被引：1，自引：0，他引：1
对与翡翠相似的玉石“不倒翁”尚无统一的认识。通过对其外表及镜下特征的鉴别、电子探针矿物成分分析、X光粉晶衍射和红外光谱分析等测试研究表明,不倒翁玉石主要矿物成分为含水钙铝榴石,同时有辉石和符山石矿物组成。含水钙铝榴石呈绿色是因含Cr致色元素所致。 相似文献
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石榴子石是冀东地区沉积变质铁矿中常见的变质矿物之一。本文采集迁安-滦县地区代表性铁矿中含有石榴子石的岩石样品,对其石榴子石进行电子探针和X-射线粉晶衍射分析,得出司马地区为角闪岩相,杏山-黄柏峪一带为角闪岩-麻粒岩相,水厂-大石河地区为麻粒岩相,这与前人对迁滦地区用主要矿物共生组合等来研究变质相的结论相一致;同时迁滦地区沉积变质铁矿中石榴子石的端元组分和晶胞参数a0随变质程度的增加呈规律性变化: 司马地区的铁铝榴石+钙铝榴石→杏山-黄柏峪一带的铁铝榴石→水厂-大石河一带铁铝榴石+镁铝榴石,其晶胞参数a0值逐渐减小。因此在沉积变质型铁矿床中,变质矿物石榴子石的化学成分及晶胞参数特征对不同地区的变质程度具有示踪意义。 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Emmanuel Skourtsos Daniel Vachard Alexandra Zambetakis-Lekkas Rossana Martini Louisette Zaninetti 《Comptes Rendus Geoscience》2002,334(12):925-931
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931. 相似文献
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正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.) 相似文献
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正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.) 相似文献
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正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.) 相似文献
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正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus., 相似文献
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正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an 相似文献
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正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of 相似文献