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1.
Four state-of-the-art ground water sampling systems were analyzed to determine their reliability in providing representative samples of the volatile chlorinated hydrocarbons trichloroethylene (TCE), perchloroethylene (PCE), and 1,1,1-trichloroethane (TCA) from a simulated monitoring well. The sampling systems studied represent four commonly used devices, including a stainless steel and Teflon® piston pump, a Teflon bailer, a Teflon bladder pump, and a PVC air-lift pump.
Controlled laboratory sampling experiments were conducted in a tank and well test chamber designed to approximate field conditions. A well purging and sampling procedure was used in the test apparatus to determine the accuracy and precision of each device for detecting low concentrations of the compounds in ground water. The compounds selected are some of the most ubiquitous hazardous contaminants found in shallow aquifers near hazardous waste sites throughout the United States.
No significant statistical difference was found among the four sampling systems in detecting the compounds.  相似文献   

2.
Eighteen sites in South Carolina under investigation by the Superfund program were sampled to determine ambient ground water quality. Samples from 11 of 15 monitoring wells sampled with a bailer contained either caprolactam or Santowhite® (a registered trademark of the Monsanto Co.) or both organic compounds. A maximum of 540 μg/L of caprolactam and 780 μg/L of Santowhite was observed in the samples from the monitoring wells. None of the samples collected using dedicated submersible pumps at 28 other wells contained either compound.
Caprolactam is used in the manufacturing of nylon cord, and Santowhite is used as an antioxidant in latex gloves. Therefore, it was suspected that the nylon cord used to raise and lower the bailer and the latex gloves that were worn during sampling may have contributed the caprolactam and Santowhite to the sample.
An experiment using pH-adjusted distilled water and private well water revealed that the nylon cord and the latex gloves may contribute contaminants to ground water samples. Research is needed into the potential for caprolactam and Santowhite to interfere with laboratory analyses in addition to the potential for absorption of contaminants by nylon cord. Until additional information is available, alternative materials or sampling techniques should be considered to minimize the potential impact of nylon cord and latex gloves on the quality of bailed samples.  相似文献   

3.
The objective of most ground water quality monitoring programs is to obtain samples that are "representative" or that retain the physical and chemical properties of the ground water in an aquifer. Many factors can influence whether or not a particular sample is representative, but perhaps the most critical factor is the method or type of sampling device used to retrieve the sample.
The sampling equipment available today ranges from simple to highly sophisticated, and includes bailers, syringe devices, suction-lift pumps, gas-drive devices, bladder (Middelburg-type) pumps, gear-drive and helical rotor electric submersible pumps and gas-driven piston pumps. New devices are continually being developed for use in small-diameter wells in order to meet the needs of professionals engaged in implementing elaborate ground water monitoring programs.
In selecting a sampling device for a monitoring program, the professional must consider a number of details. Among the considerations are: the outside diameter of the device, the overall impact of the device on ground water sample integrity (including the materials from which the sampling device and associated equipment are made and the method by which the device delivers the sample), the capability of the device to purge the well of stagnant water, the rate and the ability to control the rate at which the sample is delivered, the depth limitations of the device, the ease of operating, cleaning and maintaining the device, the portability of the device and required accessory equipment, the reliability and durability of the device, and the initial and operational cost of the device and accessory equipment. Based on these considerations, each of the devices available for sampling ground water from small-diameter wells has its own unique set of advantages and disadvantages that make it suitable for sampling under specific sets of conditions. No one sampling device is applicable to all sampling situations.  相似文献   

4.
Efforts to sample representative, undisturbed distributions of uranium in ground water beneath the Fernald Environmemal Management Project (FEMP) prompted the application of a novel technique that is less invasive in the monitoring well. Recent studies (Kearl et al. 1992; Barcelona et al. 1994) indicate that representative samples can and should be collected without prior well volume exchange purging or borehole evacuation. Field experiments conducted at the FMMP demonstrate that under specific sampling conditions in a welldefined hydrogeologic system, representative ground water samples for a monitoring program can be obtained without removing the conventional three well volumes from the well. The assumption is made that indicator parameter equilibration may not be necessary to determine when to collect representative samples at the P'liMP. Preliminary results obtained from the field experiment suggest that this may be true. The technique employs low purge rates (< 1 L/min) with dedicated bladder pumps with inlets located in the screened interval of the well, while not disturbing the stagnant water column above the screened interval. If adopted, this technique, termed micro-purge low-flow sampling, will produce representative ground water samples, significantly reduce sampling costs, and minimize; waste water over the monitoring life cycle at the FEMP. This technique is well suited for sites that have been fully characterized and are undergoing long-term monitoring.  相似文献   

5.
An Analysis of Low-Flow Ground Water Sampling Methodology   总被引：1，自引：0，他引：1  
Low-flow ground water sampling methodology can minimize well disturbance and aggravated colloid transport into samples obtained from monitoring wells. However, in low hydraulic conductivity formations, low-flow sampling methodology can cause excessive drawdown that can result in screen desaturation and high ground water velocities in the vicinity of the well, causing unwanted colloid and soil transport into ground water samples taken from the well. Ground water velocities may increase several fold above that of the natural setting. To examine the drawdown behavior of a monitoring well, mathematical relationships can be developed that allow prediction of the steady-state drawdown for constant low-flow pumping rates based on well geometry and aquifer properties. The equations also estimate the time necessary to reach drawdown equilibrium. These same equations can be used to estimate the relative contribution of water entering a sampling device from either the well standpipe or the aquifer. Such equations can be useful in planning a low-flow sampling program and may suggest when to collect a water sample. In low hydraulic conductivity formations, the equations suggest that drawdown may not stabilize for well depths, violating the minimal drawdown requirement of the low-flow technique. In such cases, it may be more appropriate to collect a slug or passive sample from the well screen, under the assumption that the water in the well screen is in equilibrium with the surrounding aquifer.  相似文献   

6.
Borehole television has been successfully utilized to gather in situ information on boreholes and wells in several ground water monitoring programs. Borehole television surveys are proposed as a viable alternative to other downhole instruments in the subsurface investigation stages of a ground water monitoring program.
The borehole television camera used by the authors was originally developed for use in the examination of nuclear reactor cores; the camera has since been modified for use in borehole investigations. The lens attachments are capable of looking sideward or downward and include built-in lighting assemblies. Use of the camera, lenses and various support equipment are discussed.
The in situ characterization of fractures that can provide pathways for contaminant migration poses a significant challenge. Borehole television inspection can provide information on the frequency, size and orientation of these fractures. Vertical correlations of rock cores in areas where voids are present (i.e. deep mining or karst topography) can also be simplified by this technique. In addition, borehole television can also be used to check monitoring well integrity. Casing inspections are especially useful where construction details are not known. Well screens may be inspected in place to determine if rusting has enlarged the screen openings or if screens have been damaged during emplacement or well development operations (i.e. surge block, air jetting, etc.). This information may prove to be very valuable in the decision to decommission a well. Examples of these successful applications in ground water monitoring programs at several Superfund hazardous waste sites are presented.  相似文献   

7.
Waste disposal sites with volatile organic compounds (VOCs) frequently contain contaminants that are present in both the ground water and vadose zone. Vertical sampling is useful where transport of VOCs in the vadose zone may effect ground water and where steep vertical gradients in chemical concentrations are anticipated. Designs for combination ground water and gas sampling wells place the tubing inside the casing with the sample port penetrating the casing for sampling. This physically interferes with pump or sampler placement. This paper describes a well design that combines a ground water well with gas sampling ports by attaching the gas sampling tubing and ports to the exterior of the casing. Placement of the tubing on the exterior of the casing allows exact definition of gas port depth, reduces physical interference between the various monitoring equipment, and allows simultaneous remediation and monitoring in a single well. The usefulness and versatility of this design was demonstrated at the Idaho National Engineering and Environmental Laboratory (INEEL) with the installation of seven wells with 53 gas ports, in a geologic formation consisting of deep basalt with sedimentary interbeds at depths from 7.2 to 178 m below land surface. The INEEL combination well design is easy to construct, install, and operate.  相似文献   

8.
Cone penetrometer tests and HydroPunch® sampling were used to define the extent of volatile organic compounds in ground water. The investigation indicated that the combination of these techniques is effective for obtaining ground water samples for preliminary plume definition. HydroPunch samples can be collected in unconsolidated sediments and the analytical results obtained from these samples are comparable to those obtained from adjacent monitoring wells. This sampling method is a rapid and cost-effective screening technique for characterizing the extent of contaminant plumes in soft sediment environments. Use of this screening technique allowed monitoring wells to be located at the plume boundary, thereby reducing the number of wells installed and the overall cost of the plume definition program.  相似文献   

9.
A simple, inexpensive sampling pump has lately come into use in ground water monitoring. The pump is referred to as an inertial pump; its only downhole components are a foot valve connected to a length of tubing or pipe. The operating principle of the pump is based on the inertia of a column of water within the riser tubing. Ground water is drawn through the foot valve and up the riser tubing by rapid up and down movements of the tubing. This pumping method is not new, but has only recently been applied to monitoring wells. Foot valves are available in a variety of materials and sizes and can be used in monitoring wells as small as 19mm (3/4 inch) I.D. Flexible polyethylene or Teflon® tubing, and in some cases stainless steel tubing or rigid PVC pipe, is used as the riser. The inertial pump satisfies most of the criteria normally cited for an "ideal" sampling device. The pump is easy to operate, reliable, durable, portable, and virtually maintenance-free. It can be operated manually from as deep as 40m or from as deep as 60m using a motor drive. The pump is inexpensive, and therefore suitable for use as a dedicated sampling pump. Recent tests have shown the pump to be suitable for sampling volatile organics. The inertial pump has a high flow capacity and performs well in silty/sandy environments, which makes it useful for developing and purging monitoring wells. It may also be used to perform field hydraulic conductivity tests.  相似文献   

10.
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11.
The Hydropunch™ is a stainless steel and Teflon® sampling tool that is capable of collecting a representative ground water sample without requiring the installation of a ground water monitoring well. To collect a sample, the Hydropunch (Patent #4669554) is connected to a small-diameter drive pipe and either driven or pushed hydraulically to the desired sampling depth. As the tool is advanced, it remains in the closed position, which prevents soil or water from entering the Hydropunch. Once the desired sampling depth is obtained, the tool is opened to the aquifer by pulling up the drive pipe approximately 1.5 feet (0.46m). In the open position, ground water can flow freely into the sample chamber of the tool. When the sample chamber is full, the Hydropunch is pulled to the surface. As the tool is retracted, check valves close and trap the ground water in the sample chamber. At the surface the sample is transferred from the Hydropunch to an appropriate sample container. The tool is a fast, inexpensive alternative for collecting ground water samples from a discrete interval. It is excellent for vertical profiling or defining the areal extent of a contaminant plume.  相似文献   

12.
Ground water injection and sampling systems were developed for bacterial transport experiments in both homogenous and heterogeneous unconsolidated, surficial aquifers. Two types of injection systems, a large single tank and a dynamic mixing tank, were designed to deliver more than 800 L of amended ground water to the aquifer over 12 hours, without altering the ground water temperature, pH, Eh, or dissolved gas composition. Two types of multilevel samplers (MLSs) were designed and installed. Permanent MLSs performed well for the homogenous surficial aquifer, but their installation procedure promoted vertical mixing, which could obfuscate experimental data obtained from vertically stratified, heterogeneous aquifers. A novel, removable MLS was designed to fit in 2- and 4-inch wells. Expandable O-rings between each sampling port hydraulically isolated each port for sample collection when a nut was tightened at the land surface. A low-cost vacuum manifold system designed to work with both MLS designs used 50 mL centrifuge tubes to efficiently sample 12 MLS ports with one peristaltic pump head. The integrated system was developed and used during four field campaigns over a period of three years. During each campaign, more than 3000 ground water samples were collected in less than one week. This system should prove particularly useful for ground water tracer, injection, and push-pull experiments that require high-frequency and/or high-density sampling.  相似文献   

13.
State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.
The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.
The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.  相似文献   

14.
Micropurge sampling of ground water wells has been suggested as a possible replacement to traditional purge and sample methods. To compare methods, duplicate ground water samples were collected at two field sites using iraditional and micropurge methods. Samples were analyzed for selected organic and inorganic constituents, and the results were compared statistically. Analysis of the data using the nonparametric sign test indicates that within a 95 percent confidence interval, there was no significant difference between the two methods for the site contaminants and the majority of analytes. These analytical results were supported by visual observations with the colloidal borescope, which demonstrated impacts on the flow system in the well when using traditional sampling methods. Under selected circumstances, the results suggest replacing traditional sampling with micropurging based on reliability, cost, and waste minimization.  相似文献   

15.
In this paper, we relate recent developments in ground water sampling techniques to the practical application of sampling for toxic contaminants in ground water. We address the choices that must be made in choosing equipment for a particular project by going through a step-by-step procedure for collecting a ground water sample from a typical monitoring well. Ground water sampling topics that are discussed include: choice of equipment for purging and sampling a well, monitoring for purged ground water indicators and quality assurance/quality control.  相似文献   

16.
Recent advances in high throughput/automated compositing with robotics/field-screening methods offer seldom-tapped opportunities for achieving cost-reduction in ground water quality monitoring programs. An economic framework is presented in this paper for the evaluation of sample compositing as a screening tool in ground water quality monitoring. When the likelihood of occurrence of a contaminant in a well is very small, the use of sample compositing instead of routine exhaustive sampling will lead to reduction in analytical efforts. Such reduction will be maximum when there are no contaminated wells in the network. An N-fold reduction will result when none of the wells in a network of N wells are contaminated. When 25 percent or more wells in a network are contaminated, the use of sample compositing will require, at the most, an additional 50 percent analytical effort compared to exhaustive sampling. A quantitative measure of the cost-effectiveness of sample compositing as a screening tool is shown to be dependent on two factors: a ratio (f1) of laboratory analytical cost to that of well installation and field sampling costs and a ratio (f2) of the expected number of contaminated wells to that of the total number of wells in the network. Several useful mathematical results of primary interest are derived and illustrated with case examples in the paper. Selected areas for further research are also outlined.  相似文献   

17.
Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site.
Leaf samples of broad-leafed cottonwood, Populus deltoides , were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or "well plant," functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby.
Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.  相似文献   

18.
Arrays of unpumped wells can be used as discontinuous permeable walls in which each well serves both as a means to focus ground water flow into the well for treatment and as a container either for permeable reactive media which directly destroy dissolved ground water contaminants or for devices or materials which release amendments that support in situ degradation of contaminants within the aquifer downgradient of the wells. This paper addresses the use of wells for amendment delivery, recognizing the potential utility of amendments such as electron acceptors (e.g., oxygen nitrate), electron donors (primary substrates), and microbial nutrients for stimulating bioremediation, and the potential utility of oxidizers, reducers, etc., for controlled abiotic degradation. Depending on its rate and constraints, the remedial reaction may occur within the well and/or downgradient. For complete remediation of ground water passing through the well array, the total flux of amendment released must meet or exceed the total flux demand imposed by the plume. When there are constraints on the released concentration of amendment (relative to the demand), close spacing of the wells may be required. If the flux balance allows wider spacing, it is likely that limited downgradient spreading of the released amendment will then be the primary constraint on interwell spacing. Divergent flow from the wells, roughly two times the well diameter, provides the bulk of downgradient spreading and constrains maximum well spacing in the absence of significant lateral dispersion. Stronger lateral dispersion enhances the spreading of amendment, thereby increasing the lateral impact of each well, which allows for wider well spacing.  相似文献   

19.
Hydrogeologic and ground water quality data obtained from a gas-driven multilevel sampler system and a polyvinyl chloride (PVC) monitoring well nest with the same aquifer communication intervals are compared. All monitoring points are in close proximity to each other. The study was conducted at an eight-acre uncontrolled hazardous waste site. The site is located in an alluvial valley composed of approximately 40 feet of alluvium overlying shale bedrock. The ground water at the site is contaminated with various organic constituents. A ground water monitoring network consisting of 26 conventional monitoring wells, nine observation well points, and six multilevel gas-driven samplers was established to characterize the hydrogeologic regime and define the vertical and horizontal extent of contamination in the vicinity of the abandoned chemical plant. As part of this study, a multilevel monitoring system was installed adjacent to a well nest. The communication zones of the multilevel samplers were placed at the same elevation as the sand packs of the well nest. The multilevel sampler system and well nest are located in a contaminated area directly downgradient of the site. A comparison of the vertical head distribution and ground water quality was performed between the well nest and the multilevel sampling system. The gas-driven multilevel sampling system consists of three gas-driven samplers that monitor separate intervals in the unconsolidated materials. The well nest, composed of two PVC monitoring wells in separate boreholes, has the same communication interval as the other two gas-driven samplers. Hydraulic head information for each multilevel sampler was obtained using capillary tubing. This was compared with heads obtained from the well nest utilizing an electric water level indicator. Chemical analyses from the PVC and multilevel sampler wells were performed and compared with one another. The analyses included organic acids, base neutrals, pesticides, PCBs, metals, volatile organics, TOX, TOC, CN, pH and specific conductance.  相似文献   

20.
Temperature is often used to infer the effect of land use and climate conditions on aquifers. Reliable data are needed to examine the temperature behaviour in the subsurface; thus, the use of robust acquisition techniques is unavoidable. Three temperature measurement techniques were applied to assess the sources of bias that could occur during temperature logging in a shallow Quaternary coastal aquifer in Ferrara (Northern Italy). Open borehole temperature logging, multilevel sampling straddle packers isolated temperature measurements within a flow cell above ground and multilevel sampling straddle packers isolated temperature measurements via an in‐well level logger (MLS‐IW) were compared for several coastal monitoring wells to gain insights on the limitations of each technique. Results show that the source of bias between the three applied techniques are different: (i) the open borehole temperature logging method tends to record heat convection through the open borehole and is not representative of the aquifer temperature distribution; (ii) the multilevel sampling straddle packers isolated temperature measurements within a flow cell above ground method is swayed by the air temperature and the heating of the submersible pump used to lift groundwater above ground; and (iii) the MLS‐IW provides the most reliable vertical thermal profiling both in summer and winter, because groundwater temperature is directly measured at the selected monitoring depth. The implementation of a 1D flow model demonstrates that if precise temperature profiles are needed to infer the influence that land use and climate changes have on groundwater, the MLS‐IW method is a reliable method that could be applied to existing monitoring wells. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

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