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1.
A model describing the main processes determining the evolution of hydrocarbon dust grains of arbitrary size under astrophysical conditions corresponding to regions of ionized hydrogen (HII regions) and supernova remnants is presented. The processes considered include aromatization and photodestruction, sputtering by electrons and ions, and shattering during collisions between grains. The model can be used to calculate the size distribution of the grains and the degree of aromatization during the evolution of HII regions and supernova remnants for a specified radiation field, relative velocity between the gas and dust, etc. The contribution of various processes to the evolution of hydrocarbon dust grains for parameters typical for the interstellar medium of our Galaxy is considered. Small grains (with fewer than 50 carbon atoms) should be fully aromatized in the interstellar medium. If larger grains initially have an aliphatic structure, this is preserved to a substantial extent. Variation in the size distribution of the grains due to collisions between grains depend appreciably on the adopted initial size distribution. With an initial distribution corresponding to that of Mathis et al. (1977), the mass fraction contributed by smaller grains tends to increase with time, while, with an initial distribution corresponding to that of Jones et al. (2013), in which the fraction of small grains is initially high, there is a general decrease in the number of grains of various sizes with time. 相似文献
2.
Cometary grains containing large amounts of carbon and/or organic matter (CHON) were discovered by in situ measurements of comet Halley dust composition during VEGA and GIOTTO flyby missions. In this paper, we report the classification of these cometary grains by means of cluster analysis, discuss the resulting compositional groups, and compare them with substances observed or hypothesized in meteorites, interplanetary dust particles, and the interstellar medium. Grains dominated by carbon and/or organic matter (CHON grains) represent approximately 22% of the total population of measured cometary dust particles. They usually contain a minor abundance of rock-forming elements as well. Grains having organic material are relatively more abundant in the vicinity of the nucleus than in the outer regions of the coma, which suggests decomposition of the organics in the coma environment. The majority of comet Halley organic particles are multicomponent mixtures of carbon phases and organic compounds. Possibly, the cometary CHON grains may be related to kerogen material of an interstellar origin in carbonaceous meteorites. Pure carbon grains, hydrocarbons and polymers of cyanopolyynes, and multi-carbon monoxides are present in cometary dust as compositionally simple and distinctive components among a variety of others. There is no clear evidence of significant presence of pure formaldehyde or HCN polymers in Halley dust particles. The diversity of types of cometary organic compounds is consistent with the interstellar dust model of comets and probably reflects differences in composition of precursor dust. Preservation of this heterogeneity among submicron particles suggests the gentle formation of cometary nucleus by aggregation of interstellar dust in the protosolar nebula without complete mixing or chemical homogenization at the submicron level. 相似文献
3.
James Lequeux 《Geochimica et cosmochimica acta》1982,46(5):777-782
This paper is a short review of the present knowledge on the composition of dense clouds where stars form, with extensions to the less dense interstellar medium and to the most likely sites of grain formation. The problem is complex and intricate, and it is still difficult to answer such fundamental questions as the lifetime of the dense clouds or the lifetime of the interstellar grains. 相似文献
4.
Michael J. Mottl Brian T. Glazer Ralf I. Kaiser Karen J. Meech 《Chemie der Erde / Geochemistry》2007,67(4):253-282
Water is formed from two of the three most abundant elements in the universe and so is abundant in interstellar space, in our Solar System, and on Earth, where it is an essential compound for the existence of life as we know it. Water ice acts as a substrate and reactant in interstellar clouds of gas and dust, enabling the formation of organic compounds that are important precursors to life and that eventually became incorporated into comets and asteroids in the early Solar System. Laboratory experiments have allowed us to infer the reaction pathways and mechanisms by which some of these compounds are formed. In these reactions, water can act as an energy transfer medium, increasing product yields, or it can lower yields by diluting reaction centers. Water can also destroy organic compounds when water ice decomposes under ionizing radiation and the decomposition products attack the compounds; whether this happens depends critically on temperature and structure of the ice, whether crystalline or amorphous. Ice structure and temperature also largely determine its gas content. As the solar nebula collapsed, icy mantles on interstellar grains probably sublimated and then recondensed onto other grains, thus influencing the transport of energy, mass, and angular momentum in the disk. Icy grains also influenced the temperature structure of the disk because they influence mean disk opacity. Outside the “snow line” at 3–5 AU icy grains accreted to become part of comets and planetesimals that occupy the region of the outer planets, the Kuiper belt, and the Oort cloud. Water was acquired by the growing Earth by several mechanisms. Evidence from noble gas isotopes indicates that Earth achieved sufficient mass fast enough to capture an early H-rich atmosphere from the Solar nebula itself. Although the remnant of this primary atmosphere is now found only in the mantle, it may also reside in the core, which could contain most of the H on Earth (or none at all). The bulk silicate Earth contains only 500–1100 ppm H2O, an amount small enough to explain by “wet” accretion, although most of it probably accumulated with the latter half of Earth's mass from wetter planetary embryos originating beyond 1.5 AU. Degassing on impact delivered water to Earth's surface, where it dissolved into a magma ocean, a process that likely saved it from loss during subsequent catastrophic impacts such as the Moon-forming giant impact, which resulted in >99% loss of the noble gas inventory. Although most of Earth's water probably came from meteoritic material, the depletion on Earth of Xe relative to Kr strongly suggests a role for comets. The role of water in supporting life is an essential one on Earth and probably elsewhere, given the unusual properties of water compared with other potentially abundant compounds. Its dipolarity, high boiling point and heat of vaporization and, for ice, melting temperature; its expansion on freezing; and its solvent properties make it an ideal medium for life. Life originated early on Earth, indicating an abundance of water, nutrients, precursor molecules, substrates, and appropriate physical and chemical conditions. Life adapted quickly to (and may have originated in) extreme environments, of heat, cold, dryness, saltiness, and acidity. This adaptation to extreme conditions bodes well for the prospect of finding life elsewhere in our Solar System and in planetary systems around other stars. 相似文献
5.
内蒙古临河市城市土壤环境地球化学特征 总被引：4，自引：3，他引：1
通过对内蒙古临河市区土壤、浮尘中元素地球化学特征的研究分析,表明在临河市区的表层土壤与浮尘中均存在Cd、Pb、Hg、Cu、Cr等重金属元素异常,而在深层土壤中上述元素呈背景值分布。在浮尘中各重金属元素含量明显高出对应表层土壤中元素含量,这些元素在浮尘中含量是土壤中的1.39~4.12倍。这些异常元素的来源包括燃煤产生、汽车尾气排放以及其他工业活动的排放。Pb、Cd是临河市区浮尘和土壤中的主要重金属异常元素,是主要的影响因子。Cu含量在临河市区明显高出河套平原,在浮尘中Cu含量明显高出土壤的,可能与Cu制品在城市区使用较多有关。作为一个主要以轻工业为主的城市,临河市区的重金属含量要明显低于其他大城市,但也存在元素的异常区,说明人类活动对城市区环境产生了严重影响。 相似文献
6.
We consider the interaction of interstellar dust grains with a galactic shock in the gaseous component. Typical parameters of dust grains and spiral density waves imply that the formation of large-scale dust lanes at the front of a galactic shock is possible only in models taking into account a self-focusing phenomenon. In the case of an isothermal flow of interstellar gas through a spiral arm in a model with a gaseous disk of variable thickness, dust lanes can be projected onto the region of increased gas density, although this is not associated with a galactic shock. The dust density peak derived from the classical model of a galactic shock (isothermal flow and a constant thickness of the gaseous disk) is appreciably shifted downstream of the gas flow, so that it does not outline the gas density maximum. 相似文献
7.
A catalog compiling the parameters of 346 open clusters, including their metallicities, positions, ages, and velocities has been composed. The elements of the Galactic orbits for 272 of the clusters have been calculated. Spectroscopic determinations of the relative abundances, [el/Fe], for 14 elements synthesized in various nuclear processes averaged over data from 109 publications are presented for 90 clusters. The compiled data indicate that the relative abundances of primary α elements (oxygen and magnesium) exhibit different dependences on metallicity, age, Galactocentric distance, and the elements of the Galactic orbits in clusters with high, elongated orbits satisfying the criterion (Zmax2 + 4e2)1/2 > 0.40 and in field stars of the Galactic thin disk (Zmax is the maximum distance of the orbit from the Galactic plane in kiloparsec and e is the eccentricity of the Galactic orbit). Since no systematic effects distorting the relative abundances of the studied elements in these clusters have been found, these difference suggest real differences between clusters with high, elongated orbits and field stars. In particular, this supports the earlier conclusion, based on an analysis of the elements of the Galactic orbits, that some clusters formed as a result of interactions between high-velocity,metal-poor clouds and the interstellar mediumof theGalactic thin disk. On average, clusters with high, elongated orbits and metallicities [Fe/H] < -0.1 display lower relative abundances of the primary a elements than do field stars. The low [O, Mg/Fe] ratios of these clusters can be understood if the high-velocity clouds that gave rise to them were formed of interstellar material from regions where the star-formation rate and/or the masses of Type II supernovae were lower than near the Galactic plane. It is also shown that, on average, the relative abundances of the primary a elements are higher in relatively metal-rich clusters with high, elongated orbits than in field stars. This can be understood if clusters with [Fe/H] > -0.1 formed as a result of interactions between metal-rich clouds with intermediate velocities and the interstellar medium of the Galactic disk; such clouds could form from returning gas in a so-called “Galactic fountain.” 相似文献
8.
From their birth as condensates in the outflows of oxygen-rich evolved stars, processing in interstellar space, and incorporation into disks around new stars, amorphous silicates predominate in most astrophysical environments. Amorphous silicates were a major building block of our Solar System and are prominent in infrared spectra of comets. Anhydrous interplanetary dust particles (IDPs) thought to derive from comets contain abundant amorphous silicates known as GEMS (glass with embedded metal and sulfides) grains. GEMS grains have been proposed to be isotopically and chemically homogenized interstellar amorphous silicate dust. We evaluated this hypothesis through coordinated chemical and isotopic analyses of GEMS grains in a suite of IDPs to constrain their origins. GEMS grains show order of magnitude variations in Mg, Fe, Ca, and S abundances. GEMS grains do not match the average element abundances inferred for ISM dust containing on average, too little Mg, Fe, and Ca, and too much S. GEMS grains have complementary compositions to the crystalline components in IDPs suggesting that they formed from the same reservoir. We did not observe any unequivocal microstructural or chemical evidence that GEMS grains experienced prolonged exposure to radiation.We identified four GEMS grains having O isotopic compositions that point to origins in red giant branch or asymptotic giant branch stars and supernovae. Based on their O isotopic compositions, we estimate that 1-6% of GEMS grains are surviving circumstellar grains. The remaining 94-99% of GEMS grains have O isotopic compositions that are indistinguishable from terrestrial materials and carbonaceous chondrites. These isotopically solar GEMS grains either formed in the Solar System or were completely homogenized in the interstellar medium (ISM). However, the chemical compositions of GEMS grains are extremely heterogeneous and seem to rule out this possibility. Based on their solar isotopic compositions and their non-solar elemental compositions we propose that most GEMS grains formed in the nebula as late-stage non-equilibrium condensates. 相似文献
9.
The results of laboratory mass-spectrometer studies of the laser-induced dissociation of molecules of simple aromatic hydrocarbons adsorbed on a quartz substrate under the conditions of deep vacuum and low temperatures are adapted to the physical and chemical conditions in regions of active star formation in molecular clouds. The main properties of the photolysis of physically adsorbed molecules compared to the photodissociation of isolated molecules in the gas phase are identified. The relevance of molecular photolytic desorption to the real conditions in the interstellar medium is analyzed, in particular, to the conditions in photodissociation regions. It is shown that the photodissociation of adsorbed benzene occurs along other channels and with appreciably lower efficiency than does the corresponding process in the gas phase. The photodissociation of aromatic hydrocarbons adsorbed on the surfaces of interstellar grains cannot make a large contribution to the abundance of hydrocarbons with small numbers of atoms observed in the interstellar medium.
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12.
Results of modeling the chemical evolution of protostellar objects are presented. The models take into account the existence of different dust populations with distinct grain sizes, total mass fractions, and temperatures. In addition to ”classical” dust grains, the models include an entirely different second dust population, with dust grain sizes of 30 Å and a higher temperature. Two chemical-evolution models are compared, one taking into account only classical dust and the other including both dust populations. The influence of a complex dust composition on the general evolution of the molecular contents of prestellar cores and the abundances of a number of chemical species is studied. At early evolutionary stages, differences are mainly determined by the modification changes in the photoprocesses’ balance due to efficient UV absorption by the second population of dust grains and in collisional reactions with the dust grains. At late stages, distinctions between the models are also determined by the increasing dominance of additional reaction channels. The species that respond to the presence of small grains in different ways are separated into different groups. Allowing for the presence of small grains makes it possible to significantly lower the water abundance in the gas phase. 相似文献
13.
Yu. A. Shchekinov 《Astronomy Reports》2000,44(2):65-75
The paper considers possible observational implications of the presence of dark matter in the Galaxy in the form of dense gas clouds—clumpuscules with masses M c ～10?3 M ⊙ and radii R c～3×1013 cm. The existence of such clouds is implied by modern interpretations of extreme scattering events—variations in quasar radio fluxes due to refraction in dense plasma condensations in the Galactic halo. The rate of collisions between these clouds is shown to be rather high: from 1 to 10M ⊙ per year is ejected into the interstellar medium as a result of such collisions. The optical continuum and 21-cm emission from hot post-collision gas could be observable. Gas clouds composed of dark matter could be formed around O stars in an H II region with radius R～30 pc and emission measure EM?20 cm?6 pc. They could also be observable in the Hα line. The evaporation of clumpuscules by external ionizing radiation could be a substantial source of matter for the interstellar medium. Assuming that the total mass of matter entering the interstellar medium over the Hubble time does not exceed the mass of luminous matter in the Galaxy, upper limits are found for the cloud radii (R c<3.5×1012 cm) and the contribution of clouds to the surface density of the Galaxy (<50M ⊙pc?2). Dissipation of the kinetic energy of matter lost by clumpuscules could provide an efficient mechanism for heating gas in the Galactic halo. 相似文献
14.
Current views of the origin and evolution of single and binary stars suggest that the planets can form aroundmain-sequence
single and binary stars, degenerate dwarfs, neutron stars, and stellarmass black holes according to several scenarios. Planets
can arise during the formation of a star mainly due to excess angular momentum leading to the formation of an accretion-decretion
disk of gas and dust around a single star or the components of a binary. It is the evolution of such disks that gives rise
to planetary systems. A disk can arise around a star during its evolution due to the accretion of matter from dense interstellar
clouds of gas and dust onto the star, the accretion of mass froma companion in a binary system, and the loss of matter during
the contraction of a rapidly rotating star, in particular, if the star rotates as a rigid body and the rotation accelerates
with its evolution along the main sequence. The fraction of stars with planetary systems is theoretically estimated as 30–40%,
which is close to the current observational estimate of ∼34%. 相似文献
15.
Yu. I. Sidorov 《Geochemistry International》2006,44(1):94-107
The paper presents a review of publications devoted to the mathematical simulations of natural systems whose large spatiotemporal scales make impossible their adequate experimental modeling in nature. The studies include the modeling of the mineralogy of the surface rocks of Venus and Mars, fractional condensation from the gaseous constituent of the preplanetary nebula, the genesis of chondrites and the material of the Earth’s upper mantle, and the evaporation of interstellar dust and the stratification of material in cooling planets. 相似文献
16.
The homogenization of inhomogeneities in the elemental composition of the interstellar medium due to stellar evolution and weak mixing are inevitably related to the action of shocks. This paper considers the influence of variations in the elemental composition on the thermal and ionizational evolution of a collisional gas with the solar metallicity that is cooled behind a shock front with a velocity of 50–120 km/s. The intensities of lines of heavy elements in plasma cooling behind a shock front depend not only on variations in the elemental composition, but also on the shock velocity, due to the different values of the critical density for the transition to the equilibrium level populations in atoms and ions of heavy elements. This circumstance can be used to determine the elemental composition of cool and warm gas of the interstellar medium, as well as the thermal history of the gas. 相似文献
17.
We have investigated the presolar grain inventories of two CR chondrites, QUE 99177 and MET 00426, which are less altered than most members of this meteorite group. Both meteorites contain high abundances of O-anomalous presolar grains, with concentrations of 220 ± 40 and 160 ± 30 ppm for QUE 99177 and MET 00426, respectively. The presolar grain inventories are dominated by ferromagnesian silicates with group 1 oxygen isotopic compositions, indicative of origins in low mass red giant or asymptotic giant branch stars. Grains with pyroxene-like compositions are somewhat more common than those with olivine-like compositions, but most grains are non-stoichiometric with compositions intermediate between these two phases, consistent with recent work suggesting that amorphous interstellar silicates have stoichiometries between olivine and pyroxene type silicates. Although structural data are not available, one grain contains only Si and O, and has a stoichiometry consistent with SiO2.Our presolar grains are much more Fe-rich than predicted by astronomical observations. Although secondary alteration may play a role in enhancing the Fe contents of presolar grains, it seems unlikely that the large and ubiquitous Fe enrichments observed in the grains from this study can be due only to secondary processing, particularly given the highly primitive nature of these two meteorites. Grain condensation in the stellar outflows where these grains formed likely proceeded under rapidly changing kinetic conditions that may have enhanced the incorporation of Fe into the grains over that expected based on equilibrium condensation theory.Both QUE 99177 and MET 00426 appear to contain unusually low abundances of oxide grains and have higher silicate/oxide ratios than other primitive meteorites analyzed to date. We explore various possibilities for this discrepancy, but note that most scenarios are not likely to result in the preferential destruction of oxides relative to silicates. Thus, the highest silicate/oxide ratios, such as those observed in the CR chondrites, should reflect the true initial proportions of presolar silicate and oxide grains in the parent molecular cloud from which the solar nebula evolved. 相似文献
18.
Archival infrared Spitzer Space Telescope observations are used to study the dust component of the ISM in the irregular galaxy
IC 10. The dust distribution in the galaxy is compared to the distributions of the Hα and [S II] emission, neutral gas and CO clouds, and ionizing radiation sources. The distribution of polycyclic aromatic hydrocarbons
(PAHs) in the galaxy is shown to be highly non-uniform, with the fraction of these particles in total dust mass reaching 4%.
On the whole, PAHs avoid bright H II regions and correlate with the atomic and molecular gas. This pattern suggests that they
form in the dense interstellar gas. It is suggested that the observed metallicity dependence of the PAH abundance shows up
not only globally (at the level of the entire galaxy), but also locally (at least, at the level of individual H II regions).
No conclusive evidence for shock destruction of PAHs in the IC 10 galaxy has been found. 相似文献
19.
The conditions for the destruction of dust in hot gas in galaxy clusters are investigated. It is argued that extinction measurements can be subject to selection effects, hindering their use in obtaining trustworthy estimates of dust masses in clusters. It is shown, in particular, that the ratio of the dust mass to the extinction M d /S d increases as dust grains are disrupted, due to the rapid destruction of small grains. Over long times, this ratio can asymptotically reach values a factor of three higher than the mean value in the interstellar medium in the Galaxy. This lowers dust-mass estimates based on measurements of extinction in galaxy clusters. The characteristic lifetime of dust in hot cluster gas is determined by its possible thermal isolation by the denser medium of gas fragments within which the dust is ejected from galaxies, and can reach 100–300 million years, depending on the kinematics and morphology of the fragments. As a result, the mass fraction of dust in hot cluster gas can reach 1–3% of the Galactic value. Over its lifetime, dust can also be manifest through its far-infrared emission. The emission characteristics of the dust change as it is disrupted, and the ratio of the fluxes at 350 and 850 μm can increase appreciably. This can potentially serve as an indicator of the state of the dust and ambient gas. 相似文献
20.
Thomas J Bernatowicz Scott Messenger Patrick Swan 《Geochimica et cosmochimica acta》2003,67(24):4679-4691
We report the results of a study of 81 micrometer-sized presolar SiC grains in the size range 0.5-2.6 μm from the Murchison (CM2) carbonaceous chondrite. We describe a simple, nondestructive physical disaggregation technique used to isolate the grains while preserving them in their pristine state, as well as the scanning electron microscopy energy-dispersive X-ray mapping procedure used to locate them.Nine-tenths of the pristine SiCs are bounded by one or more planar surfaces consistent with cubic (3C polytype) crystal faces based on manifest symmetry elements. In addition, multiple polygonal depressions (generally <100 nm deep) are observed in more than half of these crystal faces, and these possess symmetries consistent with the structure of the 3C polytype of SiC. By comparison of these features with the surface features present on heavily etched presolar SiC grains from Murchison separate KJG, we show that the polygonal depressions on pristine grains are likely primary growth features. The etched SiCs have high densities of surface pits, in addition to polygonal depressions. If these pits are etched linear defects in the SiC, then defect densities are quite high (as much as 108 -109/cm2), about 103-104 times higher than in typical synthetic SiCs. The polygonal depressions on crystal faces of pristine grains, as well as the high defect densities, indicate rapid formation of presolar SiC.No other primary minerals are observed to be intergrown with or overgrown on the pristine SiCs, so the presence of overgrowths of other minerals cannot be invoked to account for the survival of presolar SiC in the solar nebula. We take the absence of other primary condensates to indicate that further growth or back-reaction with the gas became kinetically inhibited as the gas-phase densities in the expanding asymptotic giant branch (AGB) stellar atmospheres (in which most of the grains condensed) became too low. However, we did observe an oxygen peak in the X-ray spectra of most pristine grains, implying silica coatings of as much as several tens of nm thickness, perhaps due to oxidation of the SiC in the solar nebula.We see little or no evidence on the pristine grains of the surface sputtering or cratering that are predicted theoretically to occur in the interstellar medium (ISM) due to supernova shocks. A possible implication is that the grains may have been protected during their residence in the ISM by surface coatings, including simple ices. Residues of such coatings may indeed be present on some pristine SiCs, because many (60%) are coated with an apparently amorphous, possibly organic phase. However, at present we do not have sufficient data on the coatings to draw secure inferences as to their nature or origin.A few irregular pristine SiCs, either fragments produced by regolith gardening on the Murchison parent body or by grain-grain collisions in the ISM, were also observed. 相似文献