首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 622 毫秒
1.
We present the chemical and isotope compositions of the water and gas phases of the unique Mukhen cold high-pCO2 spa. Estimated 518O, 5D, and 513Ctic values and data on geology and hydrogeology of the studied area indicate that the source of the groundwaters is meteoric waters, whereas carbon dioxide is of deep genesis and numerous regional faults are gas-feeding channels. Calculations of equilibrium reactions in the water-rock system show that the upper-aquifer waters (HCO3-Ca-Mg) with low TDS are undersaturated with carbonate minerals, montmorillonites, and aluminosilicates but are oversaturated with kaolinite, whereas the lower-aquifer waters (HCO3-Na) with high TDS are oversaturated with calcite, dolomite, and clay minerals but are undersaturated with main aluminosilicates. We propose a new concept of the formation of these groundwaters, demonstrating that long interaction between rocks and groundwaters in the presence of CO2 and considerable precipitation of secondary minerals are responsible for the high TDS of the lower-aquifer waters (up to 14 g/L) and their geochemical type (HCO3-Na) and unusual isotope composition (518O = -25.2%c, 5D = -69.0%c).  相似文献   

2.
In high temperature geothermal areas (T.200°C) in Iceland the alteration minerals formed show a regular zoning with increasing temperature i.e. smectite, chlorite, epidote and actinolite. To test the effect of varying composition of the hydrothermal circulation fluid drillhole chips from two contrasting areas were analyzed in detail. The Reykjanes area is fed with sea water while Krafla is fed with meteoric water and has a Cl− concentration of 28 ppm. Both areas have tholeiitic basalts, lavas and hyaloclastites as original reservoir rocks.

Although both systems have the same sequence of alteration minerals the actual composition of the minerals differs between systems reflecting the different chemical composition of the circulating waters. In Reykjanes, with its brine fluid, the composition of the original rock appears not to affect the composition of the alteration minerals while the reverse appears to be the case in Krafla.  相似文献   


3.
All northern areas of Western Siberia exhibit a discontinuity in the normal vertical hydrochemical zoning and formation of an inversion hydrochemcial profile characterized by total mineralization of formation waters that decrease with depth and by the discovery of waters with mineralization levels of 1–7 g/L and less, as well as a simultaneous “inconsistent” change in the chemical composition of formation waters with Cl-Na-Ca to HCO3-Cl-Na deeper than 2–3 km and simultaneous “irregular’ change in the chemical composition of formation waters with Cl-Na-Ca to HCO3-Cl-Na. Based on the use of the B/Br ratio and a Na-K geothermometer, a conclusion is made that the formation of slightly (<5 g/L) mineralized hydrocarbonate-sodium waters is caused by seepage of a considerable amount of deep high-temperature (>150°C) fluids saturated with CO2 into water-bearing rocks. This indicates the formation of deposits of hydrocarbons that are found in the regions of inversion waters as result of the upward vertical, but not lateral formation migration of a water-oil mixture.  相似文献   

4.
This paper presents the results of a study on the geochemistry of waters circulating in the mineralised area of the south-eastern sector of Mt. Peloritani (north-eastern Sicily, Italy), aimed at basic understanding of the geochemical processes influencing their chemical composition. Chemico-physical parameters and data on 26 major and minor chemical elements are reported for 103 water samples. Water chemistry is mainly dominated by dissolution of carbonates and hydrolysis of aluminosilicate minerals. Total dissolved salts (TDS) range from 80 to 1398 mg/L. All the waters exhibit EH characteristic of an oxygenated environment. Excluding two samples, which show very high H+ activity (pH = 3.0 and 2.7), all the waters have pH values in the range 6.2–8.6. Cluster analysis based on major ion contents defined three main chemical water types, reflecting different hydrochemical processes. The first, group I, has low salinity (average TDS = 118 ± 30 mg/L) and abundance orders (meq/L) Na > Ca ≈ Mg > K and Cl ≈ HCO3 > SO4. With increased water–rock interaction, waters in groups II and III become more saline, changing composition towards SO4–Cl-alkaline earth and HCO3-alkaline earth types. Weathering of carbonate minerals causes waters to become saturated with respect to calcite and dolomite, whereas the incongruent dissolution of aluminosilicate minerals causes the solution to reach equilibrium with kaolinite and to form smectites. Trace element geochemistry in the analysed waters reflects interactions between waters and existing mineralisation, with elemental concentrations showing highly variable values, and higher concentrations of As, Pb, Sb and Zn near known mineralisation. Lead–Zn and As–Sb statistical associations, probably distinguishing interactions with different mineralogical phase paragenesis, were revealed by factor analysis. The main aqueous chemical forms of trace elements predicted by chemical speciation calculations are also reported. As most of the analysed spring waters provide the main source of freshwater for domestic purposes, attention should be given to As and Sb, whose concentrations exceed the recommended limits.  相似文献   

5.
地下深层富钾卤水是非常重要的钾盐资源,目前很少从区域尺度系统研究沉积盆地中富钾卤水水化学特征及成因.对潜江凹陷深层富钾卤水进行了主、微量元素分析.研究区卤水矿化度为125.70～347.00 g/L,K含量为0.32～6.83 g/L;富集Li、B、I、Na、Cl,亏损Mg、Br,Ca、SO4有富集也有亏损.储层岩石矿...  相似文献   

6.
We studied recent sedimentation in small saline and brackish lakes located in the Ol’khon region (western Baikal area) with arid and semiarid climate. The lakes belong to the Tazheran system; it is a series of compactly located closed shallow lakes, with a limited catchment area and different mineralization, under the same landscape, climatic, geologic, and geochemical conditions. Two complementary approaches are applied in the research: (1) a detailed study of individual lake and (2) a comparison of the entire series of lakes, which can be considered a natural model for studying the relationship between endogenic mineral formation and the geochemistry of lake waters. The lake waters and bottom sediments were studied by a set of modern methods of geochemistry, mineralogy, and crystal chemistry. The mineral component of the bottom sediments was analyzed by powder X-ray diffraction (XRD), IR spectroscopy, and electron microscopy. The lakes are characterized by predominant carbonate sedimentation; authigenic pyrite, smectite, chlorite, and illite are detected in assemblage with carbonate minerals in the bottom sediments. Carbonate phases have been identified, and their proportions have been determined in the samples by decomposition of the complex XRD profiles of carbonate minerals into peaks using the Pearson VII function. Mathematical modeling of the XRD profiles of carbonates has revealed that predominantly Mg-calcites with variable Mg content and excess-Ca dolomite accumulate in lake bottom sediments influenced by biogenic processes. Aragonite, monohydrocalcite, and rhodochrosite form in some lakes along with carbonates of the calcite-dolomite series. We show a dependence of the composition of the assemblages of the newly formed endogenic carbonate minerals and their crystallochemical characteristics on the chemical composition of lake waters.  相似文献   

7.
The chemical, gas, and isotopic compositions of nitric thermal waters in the Baikal Rift Zone are considered. It is shown that the behavior of sulfate and carbonate ions in hydrothermal systems is different, which indicates that they are of two different origins. The studied thermal waters are of five chemical types formed in different geologic conditions. Special attention is given to the genesis of hydrotherms, the geologic and geomorphologic conditions of their recharge, and their equilibrium with rocks. It has been established that most of chemical elements of the waters migrated from rocks, but a significant portion of them is bound by secondary minerals, which results in their deep differentiation, accumulation, or precipitation. Thus, the so-called redundant elements appear, which were earlier considered to be of mantle origin.  相似文献   

8.
In this work the conditions of the formation of low-mineral deep hydrocarbonate sodium waters of oil-and-gas fields are considered. Analysis of the boron-bromine ratio of reservoir and condensed waters in several fields of Western Siberia shows that the influx of endogenous high-temperature gas-steam fluids into zones containing sedimentogenic brines is a decisive factor in the formation of the chemical composition of deep waters that are low in minerals.  相似文献   

9.
Computer simulations of carbon dioxide leaching of Aptian–Albian sandstone at the Nagutskoe groundwater field, Caucasian Mineral Waters, are compared with laboratory experimental data obtained using a high-pressure autoclave under parameters close to conditions under which mineral waters are formed at the Nagutskoe and Essentuki fields (temperatures 20–25 and 65–70°C, carbon dioxide pressure up to 4.04 MPa). The solvents were distilled water and naturally occurring groundwaters from the Caucasian Mineral Waters (CMW) area, individual experimental runs lasted for 2 h, the starting material (rock) was crushed to 0.25 mm, and the gas phase was carbon dioxide. In most of the experiments, the solid: liquid phase (R/W) ratio was 1: 5 and was varied from 1: 10 to 1: 100 in other experiments. Our simulation results indicate that multiple-cycle (10 cycles) leaching leads to an increase in mineralization from 1.3 g/L to 4 g/L and transformation of the geochemical type of the waters from the hydrocarbonate calcic–sodic one (leaching cycle 1) to chloride–hydrocarbonate sodic (cycles 5 and later). The mineralization increased mostly because the and Na+ ions are transferred into solution at an insignificant increase in the Cl concentration and a practically unchanging concentrations of the sulfate, calcium, and magnesium ions. With regard for the averaged mineralogical composition of the sandstone (quartz, feldspars, mica, glauconite, magnetite, ilmenite, garnet, rutile, zircon, and tourmaline) used in our thermodynamic simulations, we arrived at the conclusion that the chemical compositions of the waters, including their minor-element compositions, are controlled by (i) the composition of the cement (clay, calcareous, siliceous, limonitic, chloritic, zeolitic, phosphate, sulfate, or mixed) of the rocks, (ii) weight percentages of minerals containing certain elements, and (iii) temperature, at a given composition of the gas phase of the simulated system (silty sandstone–rainwater–CO2 gas phase).  相似文献   

10.
Primary aluminosilicates are transformed at low temperature into a sequence of metastable and thermodynamically stable secondary minerals by an irreversible process. The aqueous concentrations in the associated solution may continuously change during the process or they may be maintained constant through hydrodynamic or chemical steady-state mechanisms or through chemical equilibrium with a reversible metastable solid.Disequilibrium indices calculated for 152 natural waters and experimental solutions show that the solutions are unsaturated with amorphous aluminum hydroxide, microcrystalline gibbsite, amorphous silica and amorphous aluminosilicate, and they are supersaturated with gibbsite and kaolinite. The disequilibrium index for halloysite varies widely from unsaturation to supersaturation.Only the index for the reversible metastable cryptocrystalline aluminosilicate whose composition is pH dependent is very close to zero indicating saturation. The index varies in a narrow range. This, supported by electron micrographs and the results of X-ray fluorescence spectroscopy presented by other authors, suggests that this metastable solid, and not the secondary aluminosilicate minerals, controls the concentrations of alumina and silica in natural waters.  相似文献   

11.
Highly mineralized waters of different chemical types and origin occur in the flysch formations and their bedrocks in the western part of the Polish Carpathians. The marine sedimentation water of the flysch formations is not preserved, as the most mineralized and the heaviest isotopic values of flysch waters are characterized by δ18O and δ2H values in the ranges of 5–7‰ and −(20–30)‰, respectively. Their origin is related to the dehydration of clay minerals during burial diagenesis, with molecules of marine water completely removed by molecules of released bound water. They are relatively enriched in Na+ in respect to the marine water, supposedly due to the release of Na+ during the illitization of smectites and preferable incorporation of other cations from the primary brine into newly formed minerals. In some parts of younger formations, i.e. in the Badenian sediments, brines occur with isotopic composition close to SMOW and Cl− contents greatly exceeding the typical marine value of about 19.6 g/L, supposedly due to ultrafiltration. Most probably, the marine water of the flysch formations was similarly enriched chemically in its initial burial stages. Final Cl− contents in diagenetic waters depend on different Cl− contents in the primary brines and on relationships between diagenetic and further ultrafiltration processes. In some areas, diagenetic waters migrate to the surface along fault zones and mix with young local meteoric waters becoming diluted, with the isotope composition scattering along typical mixing lines. In areas with independent CO2 flow from great depths, they form chloride CO2-rich waters. Common CO2-rich waters are formed in areas without near-surface occurrences of diagenetic waters. They change from the HCO3–Ca type for modern waters to HCO3–Mg–Ca, HCO3–Na–Ca and other types with elevated TDS, Mg2+ and/or Na− contents for old waters reaching even those of glacial age. Bedrocks of the flysch are represented by Mesozoic and Paleozoic mudstones, sandstones and carbonates, and in some areas by Badenian sediments. Brines of the Mesozoic and Paleozoic bedrocks are usually significantly enriched in Ca2+ and Mg2+ in comparison with the Badenian brines. By analogy to the deepest brines in the adjacent Upper Silesian Coal Basin, they are supposed to originate from paleometeoric waters of a hot climate.  相似文献   

12.
The Canning Basin contains several Mississippi Valley‐type Zn‐Pb sulphide prospects and deposits in Devonian carbonate reef complexes on the northern edge of the Fitzroy Trough, and in Ordovician and Silurian marine sequences on the northern margin of the Willara Sub‐basin. This study uses the ionic composition and 5D, δ18O, δ34S, 87Sr/86Sr isotopic data on present‐day deep formation waters to determine their origin and possible relationship to the Zn‐Pb mineralizing palaeofluids.

The present‐day Canning Basin formation waters have salinity ranging from typically less than 5000 mg/L up to 250 000 mg/L locally. The brines are mixtures of highly saline water, formed by seawater which evaporated beyond halite saturation (bittern water), with meteoric water ranging in salinity from low (<5000 mg/L) to hypersaline water (up to about 50 000 mg/L) formed by re‐solution of halite and calcium sulphate minerals. The original marine chemical composition of the bittern‐dominated brines was changed to that of a Na‐Ca‐Cl water by addition of Ca and removal of Mg and SO4, initially by bacterial sulphate reduction and later by dolomitization of carbonate. Other reactions with terrigenous components of the sediment have provided additional Ca and Sr, including a small proportion of 87Sr‐rich material. The δ34S values of the bittern‐containing waters are within the range over which marine sulphate has fluctuated from the Ordovician to the Holocene, although one of the hypersaline waters has a value of +6.8%, indicating SO4 of non‐marine origin. The pH of the bittern‐containing waters is low (about 5) and they contain significant concentrations of dissolved Fe (up to 120 mg/L).

The Canning Basin bitterns appear similar in origin and chemical composition to highly saline marine brines in the Mississippi Salt Dome Basin, USA, which are known to be either metal or sulphide‐rich depending on the organic content of the host rock. In the Canning Basin, mixing of the bittern water with the various types of meteoric water has resulted in decreases in salinity, Na, Ca, Mg, K, Sr, Li and Fe, and increases in HCO3, SO4 and pH.

Mixing of the bitterns with other types of metalliferous fluids and/or with sulphate‐containing hypersaline meteoric waters formed from the same marine evaporite sequence should produce ore‐precipitating fluids which are relatively hot and saline, and the resulting ore deposit should be of high grade and contain abundant sulphate minerals. In the southern Canning Basin, this type of mixing and the corresponding style of ore deposit is evident in the evaporite‐associated areas of Zn‐Pb mineralization near the Admiral Bay Fault. If the bitterns mix with low salinity HCO3‐waters in near‐surface environments, then the ore‐precipitating fluids should have relatively low salinities and carbonate minerals would precipitate during later stages of mixing. In the Lennard Shelf, the present‐day formation waters, the style of the Zn‐Pb deposits, and range of salinity and temperature of the ore‐forming palaeofluids are consistent with this type of mixing.  相似文献   

13.
The major ion and trace element chemistry of water samples, including springs, rivers and irrigation ditches, collected during a survey on August 2016 in the Upper Mustang region of the Mustang District of Dhawalagiri Zone (Nepal) has been investigated. The Upper Mustang region, a cold desert, represents a hot-spot for climate change: indeed, violent hailstorms and rainstorms have been recently observed, consequently exposing land to erosion. Results of this study indicate that waters in the region belong to the Ca–HCO3, Ca–Mg–Cl–SO4 and Na–K–Cl-types, reflecting different hydrochemical regimes. Uranium is widespread in waters, with concentrations up to 19 µg/L recorded in a potable water supply. Locally, anoxic conditions affect uranium mobility due to the low solubility of U(IV) minerals. Highly toxic thallium was detected in a thermal spring at an elevated concentration (45 µg/L Tl). The association of thallium with high concentrations of iron suggests that these elements are derived from pyrite oxidation. Detectable levels of thallium were also measured in the water of an irrigation ditch. Lithium concentrations ranged from 7 µg/L to 12 mg/L in the thermal water and showed a strong association with chloride ions. Arsenic concentrations up to 4.7 µg/L were measured in tributaries of the Kali Gandaki river. The data provide evidence that solutes in water have originated from an array of input sources, including carbonate dissolution, the dissolution of soluble salts, silicate weathering and localized sulfide oxidation. In particular, chemical weathering of granitic rocks is likely the primary source for metals and metalloids in waters. Since the erosion rate is a factor affecting lithological weathering, high-intensity rainfalls due to climate change are expected to influence the release and fate of potentially harmful elements in the in the Upper Mustang Valley.  相似文献   

14.
Thermal waters of the Usak area have temperatures ranging from 33 to 63°C and different chemical compositions. These waters hosted by the Menderes Metamorphic rocks emerge along fault lineaments from two geothermal reservoirs in the area. The first reservoir consists of gneiss, schists, and marbles of the Menderes Metamorphic rocks. The recorded reservoir is Pliocene lacustrine limestone. Hydrogeochemical studies indicate that thermal waters were mixed with surface waters before and/or after heating at depth. The results of mineral equilibrium modeling indicate that all the thermal waters are undersaturated at discharge temperatures for gypsum, anhydrite, and magnesite minerals. Calcite, dolomite, aragonite, quartz, and chalcedony minerals are oversaturated in all of the thermal waters. Water from the reservoir temperatures of the Usak area can reach upto120°C. According to δ18O and δ2H values, all thermal and cold groundwater are of meteoric origin.  相似文献   

15.
Lateritic Ni ore mined in the Rio Tuba Mine, Philippines, derived from ultramafic rock by tropical intense weathering, is generally composed of two accumulated zones, an upper laterite zone and a lower saprolite zone. These two zones are very different in appearance, mineral assemblage, chemical composition, and in other ways. A transitional zone may be seen between the upper and lower zones, but it does not develop to any appreciable thickness. Although serpentine and goethite are still predominant in the constituent minerals, other clay minerals are increasing.

The transitional zone may be subdivided into three groups based on chemical composition. The behaviour of the chemical composition in this horizon indicates a complicated process of component transportation under the weathering process.

In the ore, chemical components are closely related in particle size of constituent minerals. In the laterite - transitional - saprolite sequence, a common variation range and tendency in chemical composition for each particle size can be seen. However, taking samples with the same particle size the chemical composition obviously differed, representing the characteristics of the components for each zone.

Concerning the correlation coefficient of the chemical components of each zone, a somewhat different inter-component relationship can be seen in these zones. These differences of correlation suggest the different complicated lateritized conditions under which they are formed.  相似文献   


16.
The results of studying the features of the hydrogeological structure and chemical and isotope composition of thermal waters from the central part of Vietnam that are characterized by intense manifestations of intrusive magmatism are presented. It is established that low–and high–thermal waters with temperature varying within 30–85°C are developed in the area under study. The value of total mineralization of the hydrotherms ranges from 0.05 to 10.05 g/dm3. It is assumed that the circulation of thermal waters that are different in temperature and chemical composition occurs at two levels. The regular change of the hydrotherm composition in the direction from mineralized chloride sodium, including with increased Ca content, to fresh sodium bicarbonate is revealed. The ratio of δ18O–δ2H isotopes indicates that the water component is based on meteoric water. In the coastal areas, there is an isotope shift towards the ocean waters, which is also confirmed by the hydrogeochemical data. The key factors for forming the chemical composition of the thermal waters in South Trungbo are their genetic type, the interaction processes in the “water–rock–gas–organic substance” system, and their equilibrium–nonequilibrium state.  相似文献   

17.
钾长石是南平伟晶岩中分布广泛的一种造岩矿物，它的结晶作用几乎贯穿于伟晶岩形成－演化过程的所有阶段。通过对不同类型伟晶岩和同一类型伟晶岩中不同世代钾长石的产出条件、物理性质、矿物粉晶X光衍射、化学成分等方面研究，发现钾长石在伟晶岩中的分布有明显的规律性。这不仅深化了对南平伟晶岩形成机制的了解，而且对钾长石的综合利用也有重要意义。  相似文献   

18.
Longling is characterized by a wide distribution of hydrothermal areas, among which the Banglazhang hydrothermal system is the most geothermally active. Banglazhang is marked by intensive hydrothermal activities including hot springs, geysers, fumaroles and hydrothermal explosions. The geothermal waters from the Longling region are mainly HCO_3-Na type with low but comparable SO_4 and Cl concentrations. Calculations based on a variety of chemical geothermometers and a K-Ca geobarometer indicate that the Banglazhang hydrothermal system has much higher subsurface temperature and CO_2 pressure compared to the other systems such as Daheba, Dazhulin and Huangcaoba. However, geothermal water samples collected from all these alternative hydrothermal areas are either partially equilibrated with reservoir minerals or are immature. The silica-enthalpy relationships of Banglazhang geothermal waters indicate the presence of a deep geothermal fluid with an enthalpy value and silica concentration of 945 J/g(up to around 220 °C) and 339 mg/L. Our work indicates the Banglazhang area is a promising source in terms of long-term utilization of hydrothermal resources.  相似文献   

19.
The systematic sampling of the chemical composition of the groundwater from five karst springs (including an overflow spring) and one outflowing borehole have permitted to determine distinctive chemical changes in the waters that reflect the geochemical processes occurring in a carbonate aquifer system from southern Spain. The analysis of the dissolution parameters revealed that geochemical evolution of the karst waters basically depends on the availability of the minerals forming aquifer rocks and the residence time within the aquifers. In the three proposed scenarios in the aquifers, which include the preferential flow routines, the more important geochemical processes taking place during the groundwater flow from the recharge to the discharge zones are: CO2 dissolution and exsolution (outgassing), calcite net dissolution, calcite and dolomite sequential dissolution, gypsum/anhydrite and halite dissolution, de-dolomitization and calcite precipitation. A detailed analysis of the hydrochemical data set, saturation indices of the minerals and partial pressure of CO2 in the waters joined to the application of geochemical modelling methods allowed the elaboration of a hydrogeochemical model of the studied aquifers. The developed approach contributes to a better understanding of the karstification processes and the hydrogeological functioning of carbonate aquifers, the latter being a crucial aspect for the suitable management of the water resources.  相似文献   

20.
吐鲁番盆地是我国西北干旱区内陆盆地之一,盆地内赋存铁矿等重要矿产资源。研究吐鲁番盆地地表水和地下水化学成分的演化对于吐鲁番盆地地下水资源的合理开发具有重要意义。采用无机离子示踪剂的方法,通过主要离子浓度与Cl-离子浓度之间的关系,以及主要离子/Cl- 与Cl- 离子浓度之间的关系,对盆地地表水和地下水的主要化学成分的形成进行了分析。同时参照地表水中主要化学成分的形成与演化,揭示盆地地下水化学成分的演化过程以及盐分的潜在来源。在吐鲁番盆地,影响不同深度地下水水化学变化的主要是蒸发矿物,其来源主要包括土壤表面的蒸发矿物、土壤层和包气带中的蒸发矿物以及艾丁湖中的表层沉积物。  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号