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1.
Radiogenic isotope compositions of Hf and Nd are typically coupled in Phanerozoic and Proterozoic mafic rocks due to a similar behaviour of Lu-Hf and Sm-Nd during mantle melting. Eoarchean rocks, for instance those from southern West Greenland, exhibit an apparent decoupling of Hf and Nd isotope compositions. This apparent decoupling may either indicate metamorphic disturbance or, alternatively, mirror early differentiation processes in the silicate Earth. To evaluate the issue, we performed combined measurements of Hf-Nd isotope compositions together with major and trace element concentrations for well preserved >3720 to >3800 Ma old tholeiitic metabasalts and gabbros from the ∼3700 Ma and ∼3800 Ma old terranes of the Isua Supracrustal Belt, southern West Greenland. In contrast to younger mafic rocks, calculated initial εHf-εNd values of the Isua tholeiites show similar spreads and are both near chondritic to strongly depleted (−0.7 to +6.3 and −0.8 to +4.4, respectively), also in contrast to previously reported more depleted signatures in nearby boninite-like metabasalts of the Garbenschiefer unit. An evaluation of alteration effects based on preserved major and trace element arrays reveals pristine magmatic trends and therefore the measured isotope compositions indeed in most cases characterize contrasting Eoarchean mantle sources. In accord with this view, compositions of the Isua metabasalts yield Eoarchean regression ages in Sm-Nd and Lu-Hf isochron spaces, overlapping with emplacement ages inferred from crosscutting relationships with tonalites. Lutetium-Hf systematics of the Isua metabasalts studied here, yield clear isochron relationships. For both terranes, there is some scatter in Sm-Nd space, indicating early disturbance of the Sm-Nd system close in time to the extrusion ages, possibly by seafloor alteration. Trace element compositions of the metabasalts indicate an arc setting and a strong source overprint by melt-like subduction components. It is likely, that the source overprint may have caused partial decoupling of the εHf-εNd values, due to selective addition of Nd as observed in modern subduction settings. In this case, the most radiogenic initial εNd and εHf isotope values characterize the most depleted mantle sources, and less radiogenic values would reflect increased contributions of isotopically more enriched subduction components. However, the most depleted samples still exhibit decoupled Hf-Nd compositions, making a case for the presence of even older mantle heterogeneities. A proposed superchondritic composition of the silicate Earth (SCHEM), however, cannot account for the most depleted sample compositions. Conversely, a depleted upper mantle formed by crystallization of perovskite-rich cumulates in the early Hadean may well explain these observed compositions. A literature survey reveals an overlap in initial Hf-Nd compositions between southern West Greenland TTGs and the metabasalts analyzed here. This overlap suggests a genetic relationship between these lithologies, where the TTGs may have inherited their unusual Hf-Nd compositions from mafic precursors isotopically similar in composition to the Isua tholeiites.  相似文献   

2.
The covariant behavior of Lu-Hf and Sm-Nd isotopes during most magmatic processes has long been recognized, but the details of this behavior in the depleted mantle reservoir have not been adequately examined. We report new whole-rock Hf and Nd isotope data for 1) juvenile, mantle-derived rocks, mid-Archean to Mesozoic in age, and 2) early Archean gneisses from West Greenland. Hf and Nd isotopic compositions of the juvenile rocks are well correlated, with the best fit corresponding to the equation εHf = 1.40 εNd + 2.1, and is similar to the collective Hf-Nd correlation for terrestrial samples of εHf = 1.36 εNd + 3.0. The early Archean Greenland gneisses, in contrast, have an extreme range in εNd values (−4.4 to +4.2; Bennett et al., 1993) that is not mirrored by the Hf isotopic system. The εHf values for these rocks are consistently positive and have much less variation (0 to +3.4) than their εNd counterparts.The information from the Hf isotopic compositions of the West Greenland gneisses portrays an early Archean mantle that is relatively isotopically homogeneous at 3.8 to 3.6 Ga and moderately depleted in incompatible elements. There is no evidence that any of these gneisses have been derived from an enriched reservoir. The Hf isotopic data are in stark contrast to the Nd isotopic record and strongly imply that the picture of extreme initial isotopic heterogeneity indicated by Nd isotopes is not a real feature of the West Greenland gneisses but is rather an artifact produced by disturbances in the Sm-Nd isotope system of these rocks.Although Hf and Nd isotopic data do not uniquely constrain either the nature of the earliest crust or the timing of crustal growth, the most probable candidate for the enriched reservoir complementary to the depleted mantle in the pre-4.0 Ga Earth is a mafic, oceanic-type crust. In order to explain the predominantly positive εHf and εNd values for the early Archean rocks, this crust must have had a short residence time at the surface of the Earth before returning to the mantle where it was isolated from mixing with the depleted mantle for several hundred million years. The following period from 3.5 to 2.7 Ga may mark a transition during which this early formed mafic crust was mixed progressively back into the depleted mantle reservoir. While a present-day volume of continental crust at 4.0 Ga cannot be excluded on isotopic grounds, we find such a scenario unlikely based on the lack of direct isotopic and physical evidence for its existence. An important aspect of crustal growth and evolution, therefore, may be the transformation of the enriched reservoir from being predominantly mafic in the early Earth to becoming progressively more sialic through time.  相似文献   

3.
According to isotopic analysis of rocks of the Reft gabbro–diorite–tonalite complex (Middle Urals), gabbro and related diorite and dikes and vein-shaped bodies of plagiogranitoids, crosscutting gabbro, are similar to the depleted mantle substance in εNd(T) = 8.6–9.7 and εHf(T) = 15.9–17.9. Their model Hf ages are correlated with the time of crystallization. Here, the tonalites and quartz diorites constituting most of the Reft massif are characterized by lower values: εNd(T) = 3.7–6.0, εHf(T) = 11.1–12.7, and T DM values significantly exceeding the age datings. This is evidence that Neoproterozoic crustal rocks were a source of parental magma for these rocks. The primary 87Sr/86Sr ratio in rocks of both groups is highly variable (0.70348–0.70495). The data obtained allow us to reach the conclusion that the Reft gabbro–diorite–tonalite complex was formed as a result of nearly synchronous processes occurring in the crust and the mantle within a limited area.  相似文献   

4.
The nature of the lower crust and tectonic setting of the Chinese Altai in the early to middle Paleozoic are still hotly debated. Decoupling between zircon Hf and whole-rock Nd isotopic systems for granites results in different interpretations for the above issues. In order to solve the problem, whole-rock Nd–Hf isotopic analyses were conducted on representative early to middle Paleozoic I-type granite and strongly peraluminous granites and rhyolites from the Chinese Altai. The I-type granites show metaluminous to weakly peraluminous feature and have εNd(t) values ranging from − 2.2 to + 0.8 and εHf(t) from + 3.9 to + 12.9, respectively. The strongly peraluminous granites and rhyolites have similar εNd(t) and εHf(t) values ranging from − 3.0 to + 1.7 and from + 2.1 to + 10.4, respectively. All samples plot above the Terrestrial Array on Nd–Hf isotopic diagram, indicating significant Nd–Hf isotopic decoupling in the magma sources. These samples show flatten HREE pattern and have Lu/Hf ratios similar to the average crust, suggesting that Nd–Hf isotopic decoupling was not originated from an ancient basement with elevated Lu/Hf ratios. The observed isotopic decoupling is similar to those modern island arcs, such as the Lesser Antilles and Sunda, where Nd selectively enriched over Hf due to metasomatism in the mantle wedge and consequently resulted in decoupling between the Sm–Nd and Lu–Hf isotopic systems. Our results, combined with the available data, show that prolonged subduction and crust–mantle interaction caused the Nd–Hf isotopic decoupling in the lithospheric mantle beneath the Chinese Altai. The crust of the Chinese Altai was extracted from the lithospheric mantle and inherited the Nd–Hf isotopic decoupling feature. Therefore, the Hf, rather than Nd, isotopic data more faithfully reflect the nature of the lower crust that was quite juvenile in the Paleozoic, and the Chinese Altai represents an early Paleozoic magmatic arc possibly built near western Mongolia.  相似文献   

5.
We have determined the ages of the ore-bearing Tinggong porphyries and the Eocene granites using the LA-ICPMS zircon U-Pb method. Zircons from one adamellite porphyry and two diorite porphyries yield ages of 15.54±0.28 Ma, 15.02±0.25 Ma and 14.74±0.22 Ma, respectively. The ages of two granites are 50.48±0.71 Ma and 50.16±0.48 Ma. Light Rare Earth Elements(LREE) are enriched in the ore-bearing adamellite porphyries, which are high-K calc-alkaline and metaluminous, while Heavy Rare Earth Elements(HREE) and Y are strongly depleted, indicating an adakitic affinity. The Large Ion Lithophile Elements(LILE) of the adamellite porphyries are highly enriched, whereas some High Field Strength Elements(HFSE) are depleted. The diorite porphyry in this study is chemically similar to the adamellite porphyries, except that the Mg# of the diorite porphyry is a little higher, demonstrating more mantle contamination. Four samples from different rocks are selected for in situ zircon Hf isotopic analyses. The samples show positive εHf(t) values and young Hf model ages, indicating their derivation from juvenile crust. However, the adamellite porphyry and diorite porphyry formed in the Miocene exhibit more heterogeneous Hf isotopic ratios, with lower εHf(t) values than the granites formed in the Eocene, suggesting the involvement of old Indian continent crust in their petrogenesis. The geochronology and geochemistry of the adamellite porphyries and the diorite porphyries indicate that they formed from the same source region in a post-collisional environment, but contaminated by crust and mantle materials in different ratios. The metallic minerals formed mainly during the older adamellite porphyry stage, but they were recycled and reactivated by the diorite porphyry intrusion.  相似文献   

6.
The North Lhasa terrane in Tibet is generally interpreted to be paleotectonically unrelated to the East African Orogen (EAO) and is instead thought to have derived from northeastern India or northwestern Australia. In this study, we present petrogenetic and geochronological results pertaining to the analysis of gabbros (ca. 652 Ma), diorites (ca. 658 and 646 Ma), and tonalites (ca. 652 Ma) from the North Lhasa terrane. The gabbros are calc-alkaline and exhibit arc-like geochemical features. Low positive zircon εHf(t) values (+1.0 to +3.8), high zircon δ18O (6.25‰ to 7.94‰), and low negative whole-rock εNd(t) values (−3.5 to −1.4) indicate that the gabbros were derived from the lithospheric mantle, with geochemical modification by a subduction component. The diorite suite is characterized by a wide range of whole-rock chemistries (e.g., SiO2 = 51.33–61.98 wt%) and Hf–O–Sr isotopic compositions (εHf(t) = −10.8 to −0.1; δ18O = 5.17‰ to 7.11‰; ISr = 0.706 to 0.710), and negative whole-rock εNd(t) values (−7.0 to −4.7). These diorites are geochemically similar to OIB and are interpreted to be products of the partial melting of a relatively deep mantle source (>85 km) prior to extensive modification by continental crustal material. The tonalites are adakitic and have moderate Mg# values (47–54), low compatible element abundances, positive zircon εHf(t) values (+3.4 to +6.2), high ISr values (0.714 to 0.715), and small negative whole-rock εNd(t) values (−1.6 to −0.4). These tonalites most likely formed by the melting of thickened Mesoproterozoic continental crust. The generation of these ca. 650 Ma magmatic rocks was related to slab break-off in a collision zone. By integrating the findings of previous studies with the data of the present study, we suggest that the North Lhasa terrane was most likely located in the northern segment of the EAO in paleotectonic reconstructions of the Gondwana supercontinent.  相似文献   

7.
This paper reports Rb–Sr and Sm–Nd isotope data on the gabbro–diorite–tonalite rock association of the Reft massif (eastern margin of the Middle Urals) and Lu–Hf isotope data on zircon populations from these rocks. In terms of Nd and Hf isotope composition, the rocks of the studied association are subdivided into two distinctly different groups. The first group consists of gabbros and diorites, as well as plagioclase granites from thin dikes and veins cutting across the gabbros. In terms of 43Nd/144Nd i = 0.512518–0.512573 (εNd(T) = +8.6...+9.7) and 176Hf/177Hf i = 0.282961–0.283019 (εHf(T) = +15.9...+17.9), these rocks are practically identical to depleted mantle. Their Nd and Hf model ages show wide variations, but in general are close to their crystallization time. The second group is represented by tonalites and quartz diorites, which compose a large body occupying over half of the massif area. These rocks are characterized by the lower values of 143Nd/144Nd i = 0.512265–0.512388 (εNd(T) = +3.7...+6.0) and 176Hf/177Hf i = 0.282826–0.282870 (εHf(T) = +11.1...+12.7). The TDM values of the second group are much (two–three times) higher than their geological age (crystallization time), which indicates sufficiently long crustal residence time of their source. The initial 87Sr/86Sr in the rocks of both the groups varies from 0.70348 to 0.70495. This is likely explained by the different saturation of melts with fluid enriched in radiogenic Sr. The source of this fluid could be seawater that was buried in a subduction zone with oceanic sediments and released during slab dehydration. Obtained data make it possible to conclude that the formation of the studied gabbro–diorite–tonalite association is a result of spatially and temporally close magma formation processes in the crust and mantle, with insignificant contribution of differentiation of mantle basite magma.  相似文献   

8.
ABSTRACT

The Ordovician plutons in the Erguna Block, NE China, can be classified into two groups: Early Ordovician diorites with zircon U–Pb ages ranging from 486 to 485 Ma and Middle Ordovician gabbros and granites with zircon U–Pb ages ranging from 466 to 463 Ma. The diorites are calc-alkaline in nature and are characterized by weak to moderate enrichments of large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to high field strength elements (HFSE) and heavy rare earth elements (HREE). The gabbros and granites have high total alkali contents, and all samples are enriched in LREE and LILE and depleted in HFSE such as Nb, Ta, and Ti. Isotopically, Early Ordovician diorites display values that are less radiogenic [εHf(t) = + 9.9–+16.8] compared to those of Middle Ordovician gabbros [εHf(t) = ? 3.0–+5.0]. Middle Ordovician granites have positive εHf(t) values of +1.4 to +4.3 and two-stage Hf model ages (TDM2) of 1167 to 1356 Ma. These data indicate that the diorites may have been generated by the partial melting of a recently metasomatized mantle source, whereas the gabbros and granites may have been formed by the partial melting of enriched lithospheric mantle and Mesoproterozoic crust, respectively. Our results, combined with other regional results, suggest that Early Ordovician magmatism was likely associated with the northward subduction of the Heihe–Xilinhot oceanic plate beneath the Erguna–Xing’an Block, whereas the Middle Ordovician gabbros and granites were most likely formed in an extensional setting controlled by the rollback of this subducted oceanic plate.  相似文献   

9.
The Duolong porphyry Cu–Au deposit (5.4 Mt at 0.72% Cu, 41 t at 0.23 g/t Au) was recently discovered in the southern Qiangtang terrane, central Tibet. Here, new whole‐rock elemental and Sr–Nd–Pb isotope and zircon Hf isotopic data of syn‐ and post‐ore volcanic rocks and barren and ore‐bearing granodiorite porphyries are presented for a reconstruction of magmas associated with Cu–Au mineralization. LA–ICP–MS zircon U–Pb dating yields mean ages of 117.0 ± 2.0 and 120.9 ± 1.7 Ma for ore‐bearing granodiorite porphyry and 105.2 ± 1.3 Ma for post‐ore basaltic andesite. All the samples show high‐K calc‐alkaline compositions, with enrichment of light rare earth elements (LREE) and large ion lithophile elements (LILE: Cs and Rb) and depletion of high field strength elements (HFSE: Nb and Ti), consistent with the geochemical characteristics of arc‐type magmas. Syn‐ and post‐ore volcanic rocks show initial Sr ratios of 0.7045–0.7055, εNd(t) values of −0.8 to 3.6, (206Pb/204Pb)t ratios of 18.408–18.642, (207Pb/204Pb)t of 15.584–15.672 and positive zircon εHf(t) values of 1.3–10.5, likely suggesting they dominantly were derived from metasomatized mantle wedge and contaminated by southern Qiangtang crust. Compared to mafic volcanic rocks, barren and ore‐bearing granodiorite porphyries have relatively high initial Sr isotopic ratios (0.7054–0.7072), low εNd(t) values (−1.7 to −4.0), similar Pb and enriched zircon Hf isotopic compositions [εHf(t) of 1.5–9.7], possibly suggesting more contribution from southern Qiangtang crust. Duolong volcanic rocks and granodiorite porphyries likely formed in a continental arc setting during northward subduction of the Bangong–Nujiang ocean and evolved at the base of the lower crust by MASH (melting, assimilation, storage and homogenization) processes. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

10.
Garnet-facies continental mantle is poorly understood because the vast majority of mantle xenoliths in continental basalts are spinel peridotite. Peridotite xenoliths from Vitim (southern Siberia) and Mongolia provide some of the best samples of garnet and garnet-spinel facies off-craton lithospheric mantle. Garnets in those fertile to moderately depleted lherzolites show a surprisingly broad range of HREE abundances, which poorly correlate with modal and major oxide compositions. Some garnets are zoned and have Lu-rich cores. We argue that these features indicate HREE redistribution after the partial melting, possibly related to spinel-garnet phase transition on isobaric cooling. Most peridotites from Vitim have depleted to ultra-depleted Hf isotope compositions (calculated from mineral analyses: εHf(0) = +17 to +45). HREE-rich garnets have the most radiogenic εHf values and plot above the mantle Hf-Nd isotope array while xenoliths with normal HREE abundances usually fall within or near the depleted end of the MORB field. Model Hf isotope ages for the normal peridotites indicate an origin by ancient partial melt extraction from primitive mantle, most likely in the Proterozoic. By contrast, an HREE-rich peridotite yields a Phanerozoic model age, possibly reflecting overprinting of the ancient partial melting record with that related to a recent enrichment in Lu. Clinopyroxene-garnet Lu-Hf isochron ages (31-84 Ma) are higher than the likely eruption age of the host volcanic rocks (∼16 Ma). Garnet-controlled HREE migration during spinel-garnet and garnet-spinel phase transitions may be one explanation for extremely radiogenic 176Hf/177Hf reported for some mantle peridotites; it may also contribute to Hf isotope variations in sub-lithospheric source regions of mantle-derived magmas.  相似文献   

11.
The Aqishan-Yamansu belt in the Eastern Tianshan (NW China) contains many intermediate to felsic intrusive rocks and spatially and temporally associated Fe (-Cu) deposits. Zircon U-Pb dating of the Bailingshan granitoids, including diorite enclaves (in granodiorite), diorite, monzogranite and granodiorite, and andesitic tuff from the Shuanglong Fe-Cu deposit area yielded ages of 329.3 ± 2.1 Ma, 323.4 ± 2.6 Ma, 313.0 ± 2.0 Ma, 307.5 ± 1.7 Ma and 318.0 ± 2.0 Ma, respectively. These new ages, in combination with published data can be used to subdivide magmatism of the Bailingshan intrusive complex into three phases at ca. 329–323 Ma, ca. 318–313 Ma and ca. 308–297 Ma. Of the analyzed rocks of this study, the Shuanglong diorite enclave, diorite and andesitic tuff show calc-alkaline affinities, exhibiting LILE enrichment and HFSE depletion, with negative Nb and Ta anomalies. They have high MgO contents and Mg# values, with depleted εHf(t) and positive εNd(t) values, similar crustal-derived Nb/Ta and Y/Nb ratios, low Th/Yb and Th/Nb, and high Ba/La ratios, which are consistent with them being sourced from a depleted mantle wedge metasomatized by slab-derived fluids and crustal contamination. However, the monzogranite and granodiorite are metaluminous with characteristics of low- to high-K calc-alkaline I-type granites. The granitic rocks are enriched in LILE, depleted in HFSE and have significant Eu anomalies, with high Y contents and low Sr/Y ratios, resembling typical of normal arc magmas. Depleted εHf(t) and positive εNd(t) values with corresponding young TDMC ages of zircons, as well as Nb/Ta, Y/Nb, Th/U and La/Yb ratios suggest that the granitic rocks were probably formed by re-melting of juvenile lower crust or pre-existing mantle-derived mafic–intermediate igneous rocks. Integrating published data, we conclude that the Bailingshan granitoids (excluding the Shuanglong diorite and diorite enclave) were derived from re-melting of juvenile lower crust and mantle-derived mafic–intermediate igneous rocks, with mantle components playing a more prominent role in the formation of the younger and more felsic rocks. A comprehensive review, including our new data, suggests that the Aqishan-Yamansu belt formed as a fore-arc basin during the Carboniferous (ca. 350–300 Ma) when the Kangguer oceanic slab subducted beneath the Yili-Central Tianshan block. The ongoing southward subduction of the slab resulted in the closure of the Aqishan-Yamansu fore-arc basin (ca. 320–300 Ma), due to slab steepening and rollback followed by slab breakoff and rebound. During the Aqishan-Yamansu fore-arc basin inversion, the main phase of the Bailingshan granitoids emplaced in the Aqishan-Yamansu belt, accompanied by contemporary Fe and Fe-Cu mineralization.  相似文献   

12.
Four types of pre-accretionary Early Cambrian lava sequences are distinguishable in the geological structure of the Ozernaya zone in western Mongolia: (I) close to N-MORB; (II) close to E-MORB; (III) enriched with trace elements and with HFSE minimums; (IV) depleted in trace elements and with HFSE minimums. All these lavas could have been formed in an island-arc?back-arc basin system. N-MORB basalts were melted from depleted magma sources with с εNd(t) = 10.0–11.5. Plume melts originated from mantle sources with εNd(t) = 4.8–9.7. The sources of island arc lavas were characterized by εNd(t) = 7.3–9.9.  相似文献   

13.
The Laocheng granitoid pluton is located in the South Qinling tectonic domain of the Qinling orogenic belt,southern Shaanxi Province,and consists chiefly of quartz diorite,granodiorite and monzogranite.A LA-ICP-MS zircon U-Pb isotopic dating,in conjunction with cathodoluminescence images,reveals that the quartz diorite and granodiorite were emplaced from 220 Ma to 216 Ma,while the monzogranite was emplaced at～210 Ma.In-situ zircon Hf isotopic analyses show that theε_(Hf)(t) values of the quartz diorite a...  相似文献   

14.
Volcanic suites from Wawa greenstone belts in the southern Superior Province comprise an association of typical late Archean arc volcanic rocks including adakites, magnesian andesites (MA), niobium-enriched basalts (NEB), and ‘normal’ tholeiitic to calc-alkaline basalts to rhyolites. The adakites represent melts from subducted oceanic crust and all other suites were derived from the mantle wedge above the subducting oceanic lithosphere. The magnesian andesites are interpreted to be the product of hybridization of adakite melts with arc mantle wedge peridotite. The initial ?Hf values of the ∼2.7 Ga Wawa adakites (+3.5 to +5.2), magnesian andesites (+2.6 to +5.1), niobium-enriched basalts (+4.4 to +6.6), and ‘normal’ tholeiitic to calc-alkaline arc basalts (+5.3 to +6.4) are consistent with long-term depleted mantle sources. The niobium-enriched basalts and ‘normal’ arc basalts have more depleted ?Hf values than the adakites and magnesian andesites. The initial ?Nd values in the magnesian andesites (+0.4 to +2.0), niobium-enriched basalts (+1.4 to +2.4), and ‘normal’ arc tholeiitic to calc-alkaline basalts (+1.6 to +2.9) overlap with, but extend to lower values than, the slab-derived adakites (+2.3 to +2.8). The lower initial ?Nd values in the mantle-wedge-derived suites, particularly in the magnesian andesites, are attributed to recycling of an Nd-enriched component with lower ?Nd to the mantle wedge. As a group, the slab-derived adakites plot closest to the 2.7 Ga depleted mantle value in ?Nd versus ?Hf space, additionally suggesting that the Nd-enriched component in the mantle wedge did not originate from the 2.7 Ga slab-derived melts. Accordingly, we suggest that the enriched component had been added to the mantle wedge at variable proportions by recycling of older continental material. This recycling process may have occurred as early as 50-70 Ma before the initiation of the 2.7 Ga subduction zone. The selective enrichment of Nd in the sources of the Superior Province magmas can be explained by experimental studies and geochemical observations in modern subduction systems, indicating that light rare earth elements (e.g., La, Ce, Sm, Nd) are more soluble than high field strength elements (e.g., Zr, Hf, Nb, Ta) in aqueous fluids that are derived from subducted slabs. As a corollary, we suggest that the recycled Nd-enriched component was added to the mantle source of the Wawa arc magmas by dehydration of subducted sediments.  相似文献   

15.
Diabase dyke swarms are widespread in the East Tianshan and Beishan regions. LA-ICP-MS zircon U-Pb ages of these diabase vary from 305 Ma to 278 Ma, showing that these dykes were formed during Late Carboniferous-Early Permian magmatism. All diabase samples are subalkali calc-alkali, characterized by slight LREE and LILEs enrichment, and weak negative Ti, Nb and Ta anomalies. The diabase samples have positive εNd(t) values (>+3), high Sr isotopic compositions (initial 87Sr/86Sr values=0.7030-0.7097), and large variation of Pb isotopic compositions, indicating they were derived from a deplete mantle source. Regional geology and geochemistry evidences indicate that these diabase dyke swarms were generated in a lithosphere extensional setting and had the same magma sources. Initial magmas may be a mixture of depleted asthenosphere mantle and enriched lithospheric mantle during rapid magma ascending.  相似文献   

16.
ABSTRACT

Southeastern China is characterized by an extensive Late Mesozoic (Yanshanian) tectono-magmatic-metallogenic event. Although Late Cretaceous volcanism gradually weakened during the epilogue of the Yanshanian event, its petrogenesis and geodynamic processes remain unclear. In this study, we present new zircon U–Pb–Hf isotopic, whole-rock elemental, and Sr–Nd isotopic compositions data, for volcanic rocks from the Zhaixia Formation of the Shimaoshan Group in Fujian Province. The lower member of the Zhaixia Formation consists of basalts and rhyolites, and the upper member is only rhyolites. These volcanic rocks erupted in the early stage of Late Cretaceous, with basalts erupting earlier (ca. 99–98 Ma) than rhyolites (ca. 98–94 Ma). These basalts record high-K calc-alkaline to shoshonitic, light rare earth element (LREE)- and LILE-enrichment, high field strength element (HFSE)depletion with negligible Eu anomalies, and uniform whole-rock εNd(t) (–3 to –6) and zircon εHf(t) (–3.3 to –14.1) values. The overlying rhyolites record peraluminous and high-K calc-alkaline characteristics, LREE- and LILE-enrichment with negative Eu anomalies, and Nb–Ta depletion. The whole-rock εNd(t) and zircon εHf(t) values of these rhyolites both increase from the lower member (εNd(t), –1.5 to –4.7; εHf(t), –5.1 to –16.1) to the upper member (εNd(t), –0.5 to 0.1; εHf(t), –0.3 to –4.3). The features imply that these basalts were derived from the partial melting of the enriched lithospheric mantle and the overlying rhyolites from the melting of the crustal components, respectively. Data from the rhyolites in the upper member indicate that more juvenile, Nd–Hf isotopically depleted materials were injected into their source. During the Late Cretaceous, the new, fast rollback of the subducting slab triggered lithospheric extension and asthenospheric upwelling beneath the coastal regions, which induced the melting of lithospheric mantle and crustal components. As continued, the new round of basaltic underplating provided necessary heat to cause partial melting of the deep crust, including the younger, juvenile, and isotopically depleted crustal components.  相似文献   

17.
ABSTRACT

The Eastern Pontides orogenic belt in NE Turkey hosts numerous I-type plutons of Eocene epoch. Here, we report new U–Pb SHRIMP zircon ages and in situ zircon Lu-Hf isotopes along with bulk-rock geochemical and Sr-Nd-Pb-O isotope data from the Kemerlikda??, Ayd?ntepe and Pelitli plutons and mafic microgranular enclaves (MMEs) to constrain their parental melt source(s) and evolutionary processes. U-Pb SHRIMP zircon dating yielded crystallization ages between 45 and 44 Ma for the studied plutons and their MMEs. The plutons range from gabbro to granite and have I-type, medium to high-K calc-alkaline, and metaluminous to slightly peraluminous characteristics. On the primitive mantle-normalized multi-trace-element variations, the plutons and their MMEs are characterized by signi?cant enrichment in LILE/HFSE. Chondrite-normalized REE patterns of the plutons and their MMEs are close to each other and show moderate enrichment with variable negative Eu anomalies. The studied plutons have fairly homogeneous isotope composition (87Sr/86Sr(i) = 0.70502 to 0.70560; εNd(i) = +0.9 to – 1.4; δ18O = +5.0 to +8.7‰, εHf(i) = – 2.2 to +13.5). The MMEs show medium to high-K calc-alkaline and metaluminous character. Although the isotope signatures of the MMEs (87Sr/86Sr(i) = 0.70508 to 0.70542; εNd(i) = +0.9 to ?1.1; δ18O = +5.8 to +8.0, εHf(i) = +4.3 to +10.4) are very similar to those of the host rocks. Fractionation of plagioclase, amphibole, pyroxene and Fe-Ti oxides played an important role in the evolution of the plutons. The isotopic composition of the studied plutons and MMEs are similar to I-type plutons derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. The parental magma(s) of the studied plutons were generated from the enriched lithospheric mantle and then modified by fractional crystallisation, and lesser assimilation and mixing/mingling in the crustal magma chambers.  相似文献   

18.
《International Geology Review》2012,54(15):1823-1841
ABSTRACT

The Song Ma zone in Northwestern Vietnam is considered as a suture of the South China and Indochina blocks, and plays an important role in understanding the tectonic evolution in Southeast Asia and surrounding areas. Granitic rocks of the Muong Lat complex are distributed in the Song Ma suture, consisting mainly of monzogranite and granodiorite. The rocks are sub-alkaline in affinity with high K contents and characteristics of S-type granite. They have high SiO2, total Na2O + K2O, and Zr contents and high aluminium saturation index values (0.97 to 1.29 with an average of 1.14). All these geochemical signatures, together with high (87Sr/86Sr)i ratios (0.71391 to 0.74568), and low whole rock εNd(t) and zircon εHf(t) values (?13.1 to ?9.4) suggested an origin from partial melting of crustal source rocks. Primitive mantle normalized trace element contents exhibit positive anomalies of Rb, Th, U and Pb, but negative anomalies of Nb, Ta, and Ti, indicating a collision-related environment. The depleted Nd and Hf zircon model ages from investigated samples, in combination with inherited zircon ages, suggest the existence of Precambrian basement in the study region. S-type granites of the late Permian-early Triassic (the Muong Lat, Phia Bioc and Hai Van complexes) in Vietnam were formed by the subduction-collision of the South China and Indochina blocks.  相似文献   

19.
Bulk-rock Lu-Hf and Sm-Nd isotope compositions, as well as major and trace element data are presented for metavolcanic rocks from the Mesoarchaean (ca. 3075 Ma) Ivisaartoq Supracrustal Belt in the Nuuk region of southern West Greenland. The εHft calculated at 3075 Ma range from +0.8 to +3.1 and the corresponding εNdt values range from +0.7 to +3.6, which forms an array that is displaced off the mantle array for these two isotopic systems. Primitive mantle normalized trace element plots of the metabasalts display negative Nb- and Ti-anomalies in combination with the elevated Th abundances, which is consistent with a subduction zone affinity as proposed by previous studies of this metavolcanic belt. No significant correlations are observed between the isotope compositions and proxies of shallow crustal contamination in the Ivisaartoq rocks, despite clear evidence for inherited Eoarchaean zircon [Polat et al. (2009a) Chemical Geology 268, 248-271], which would have dominated the bulk-rock Hf-isotope budget. Furthermore, the measured samples are less radiogenic than the estimate for the depleted mantle composition at 3075 Ma. The lack of isotope and trace element correlation suggests incomplete equilibration between the crustal contaminant and the parental Ivisaartoq melts. We prefer a petrogenetic model with some combination of slab-derived metasomatism of the mantle source region for the Ivisaartoq magmas, which homogenized their trace element contents, in combination with the incorporation of granitoid residue with unradiogenic Hf-isotope composition at higher degrees of partial melting and finally the eruption of mechanically entrained Eoarchaean crust without significant chemical equilibration. The geochemical arc-affinity and lower than depleted mantle (DM) isotope compositions of these metavolcanic rocks support the notion that crustal recycling and plate tectonics has been operating on Earth since at least the Mesoarchaean Eon.  相似文献   

20.
The Weihai migmatite in the Sulu ultra-high-pressure (UHP) metamorphic terrane, eastern China, underwent partial melting in the Late Triassic during its exhumation. The primary partial melts experienced a decompressional fractional crystallization (DFC) process to produce plagioclase (Pl)-rich leucosome crystallized under eclogite to granulite facies conditions and K-feldspar (Kfs)-rich pegmatitic veins crystallized under amphibolite-facies conditions. In this study, our results demonstrate that the DFC process can cause decoupling between whole-rock Sr and Nd isotopes. The Pl-rich leucosome has εNd(t) values (–10.4 to ?15.0) and initial (87Sr/86Sr) ratios (0.708173–0.712476) very similar to those of the melanosome, but the Kfs-rich pegmatitic veins have homogeneous εNd(t) values (?14.8 to ?15.2) and significantly high initial (87Sr/86Sr) ratios (0.713882–0.716284). Our results also suggest that the DFC process can change zircon 176Yb/177Hf and 176Lu/177Hf isotopic ratios, with no effect on 176Hf/177Hf ratios or εHf (t) values. Zircon 176Yb/177Hf and 176Lu/177Hf ratios increase dramatically from the Pl-rich leucosome to the Kfs-rich pegmatitic veins, but zircon 176Hf/177Hf ratios (Pl-rich leucosomes = 0.282330 ± 0.000017; Kfs-rich pegmatitic veins = 0.282321 ± 0.000026) and εHf (t) values (Pl-rich leucosomes = ?10.9 ± 0.6; Kfs-rich pegmatitic veins = ?11.6 ± 0.8) remain almost unchanged. We propose that the isotopic decoupling between the Pl-rich leucosome and Kfs-rich pegmatitic vein might be caused by melt fractional crystallization occurring too rapidly to allow complete equilibrium between them.  相似文献   

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