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1.
Lithospermum (Boraginaceae) belongs to a small group of plant taxa that accumulate biogenic carbonate in their fruits. In this genus, carbonate incrustations form in the cells of the epidermis and sclerenchyma of the pericarp. Fossil Lithospermum fruits (nutlets) with well-preserved calcified tissues commonly occur in Quaternary sediments and cultural layers. We tested the suitability of biogenic carbonate of Lithospermum fruits for radiocarbon dating using a total of 15 AMS measurement results from four modern and 11 fossil samples. The 14C data from modern samples suggest that Lithospermum utilises only atmospheric carbon to synthesise calcite in the nutlets. In general, the ages determined through 14C dating of fossil fruitscorresponded well with the absolute-age intervals for archaeological sites over the last 5000 yr. Biogenic carbonate of Lithospermum fruits, like that of Celtis, represents a new source of chronological information for late Quaternary studies.  相似文献   

2.
Hohle Fels Cave is one of several Upper Paleolithic sites on the eastern extension of the Swabian Alb in southwestern Germany. Several phases of excavations have been conducted since 1870. The archaeological inventories comprise a broad range of artifacts produced from stone, bone, teeth, ivory, and antler. The site has also yielded Paleolithic rock art, sculpture, and engravings. The Pleistocene inventories unearthed so far belong to the Magdalenian, Gravettian, and Aurignacian; Middle Paleolithic horizons may well be uncovered as excavations continue. The chronology of three main occupation phases has been established with numerous 14C measurements. The Magdalenian dates to about 13,000 yr B.P., and the richest Gravettian deposit contains a burnt bone‐layer extending over ca. 12 m2 that dates to about 29,000 yr B.P. The underlying Aurignacian horizons predate 30,000 yr B.P. The Gravettian burnt bone layer (archaeological layer IIcf) is a key horizon because of its distinct composition and color and its large horizontal extension. Layer IIcf has been examined using a combination of analytical techniques including micromorphological analysis of thin sections with polarizing light microscopy and scanning electron microscopy for fabric and identification of mineral and biogenic constituents. The bone mineral composition was analyzed by Fourier transform infrared spectroscopy (FTIR) and electron probe microanalytical techniques. These investigations in tandem with the field observations indicate intense burning of bones as fuel. The micromorphological and contextual archaeological data suggest that layer IIcf is a secondary dump rather than an in situ accumulation. This deposit and other Paleolithic burnt deposits in the Swabian Jura appear to reflect intense periods of winter occupation in these caves. © 2003 Wiley Periodicals, Inc.  相似文献   

3.
A high-resolution 14C chronology for the Teopancazco archaeological site in the Teotihuacan urban center of Mesoamerica was generated by Bayesian analysis of 33 radiocarbon dates and detailed archaeological information related to occupation stratigraphy, pottery and archaeomagnetic dates. The calibrated intervals obtained using the Bayesian model are up to ca. 70% shorter than those obtained with individual calibrations. For some samples, this is a consequence of plateaus in the part of the calibration curve covered by the sample dates (2500 to 1450 14C yr BP). Effects of outliers are explored by comparing the results from a Bayesian model that incorporates radiocarbon data for two outlier samples with the same model excluding them. The effect of outliers was more significant than expected. Inclusion of radiocarbon dates from two altered contexts, 500 14C yr earlier than those for the first occupational phase, results in ages calculated by the model earlier than the archaeological records. The Bayesian chronology excluding these outliers separates the first two Teopancazco occupational phases and suggests that ending of the Xolalpan phase was around cal AD 550, 100 yr earlier than previously estimated and in accordance with previously reported archaeomagnetic dates from lime plasters for the same site.  相似文献   

4.
The Paso Otero Locality is a cluster of archaeological sites within the middle Río Quequén Grande basin located in the northern coastal plain of Argentina. The valley fill is Holocene alluvial, eolian, and palustrine sediment, including the top of the Guerrero Member (∼10,000 14C yr B.P.), upper Río Salado Member (∼3000 14C yr B.P.), and lower La Postrera Formation (∼2400 14C yr B.P.). Regional soils include the Puesto Callejón Viejo (10,000 to 9400 14C yr B.P.) and the Puesto Berrondo (∼4800 14C yr B.P.). Radiocarbon sampling of buried A‐horizons on both sides of the river produced 17 dates considered reliable. The geoarchaeological information allows exploration of the implications for the formation of the archaeological record. Similar geological processes of differential intensity have resulted in contexts of different archaeological resolution and integrity. The Paso Otero Locality provides both a local and regional view of late Quaternary events and processes for the middle basin of the Río Quequén Grande.  相似文献   

5.
The 10 m thick Madaras loess–palaeosol profile is one of the Hungarian outcrops that yielded Upper Palaeolithic artefacts in 1966. To clarify the nature of the deposits and establish a reliable litho- and chronostratigraphy, a profile was opened and sampled at 25 cm intervals on the northern side of the brickyard in 1975. Analyses focused on grain size, carbonate content and the mollusc fauna. The chronology was based on the mollusc composition and a single date from the archaeological layer at the depth of ca 7 m below the surface. The 1975 profile was destroyed by mining but the reposited samples allowed an extended analysis of this important Marine Isotope Stage 2 record to which archaeological features were directly assigned. A new absolute chronology was built based on 11 14C dates. Environmental magnetic, geochemical and palaeoecological investigations allowed a refined view of site evolution with reliable chronology for the Last Glacial Maximum. Our results corroborated those of previous investigations done on other coeval loess–palaeosol sequences of the Southern Carpathian Basin. This also allowed for a temporal correlation to another local record with the published high-resolution chronology of the same brickyard and enabled modelling of local-scale heterogeneity of the environment in the long run.  相似文献   

6.
Two composite radiocarbon dates on wood beams from a unique, prehistoric building in southern Arizona are the result of growth series subsampling of the beams and statistical evaluation of radiocarbon dates on the subsamples. This procedure avoids some of the problems caused by secular variations in the biospheric 14C activity and by the dating of specimens grown over a range of years. This procedure yields results similar to more precise tree-ring dates from other sites in the southwestern United States. The procedure illustrated here is applicable to any archaeological tree specimen consisting of at least the last 40 growth rings.  相似文献   

7.
Four massive brecciated, chimney-like, and slender pipe network carbonate samples(JA-4, JA-5, JX-8 and BG-12) were collected from southwestern Taiwan, which were suggested to have formed as a result of anaerobic oxidization of methane(AOM). Considering that the environmental conditions of the carbonates precipitation and the sources of carbon and organic matter need to be further declared, molecular fossils and compound-specific carbon isotopic investigations of the carbonates were conducted in this study. According to lipid biomarkers of 2,6,10,15,19-pentamethyleicosane(PMI) and squalane diagnostic to methanotrophic archaea, as well as the extremely low δ13C values(as low as -113.4‰) detected in samples JA-4, JA-5 and JX-8, these carbonates were revealed to be a result of AOM. Based on the varied δ13C values of characteristic archaea biomarkers in specific samples, biogenic methane was proposed to be responsible for the formation of samples JA-4 and JA-5, whereas a mixed carbon source of 13C-depleted methane and 13C-enriched residual CO_2 from methanogenesis was suggested for the carbonate of JX-8 due to the co-occurrence of a highly positive δ13 Ccarb value(+8‰) and a moderate 13C depletion of PMI. The low content of AOM-related biomarkers and the absence of indicators for ANME-2 suggested that these carbonates were formed in weak seep settings. By comparison, no typical lipid biomarkers for methanotrophic archaea was detected in carbonate BG-12. The short-chain and long-chain n-alkanes accounted for 30% and 45% of all hydrocarbons, respectively, with a CPI value of 1.2, suggesting that the n-alkanes were derived from both marine organisms and terrestrial inputs. A low thermal maturity could be revealed by the incomplete equilibrium value of the C31αβ 22S/(22S+22R) ratio(0.5), and the carbonate BG-12 was probably deposited in a suboxic condition indicated by a value of Pr/Ph ratio(2.5).  相似文献   

8.
Microlithic artifacts, some found in situ, are abundant in the Zhongba archaeological site in southwestern Tibet. The site environment consists of extant wetlands and paleo‐wetland deposits found in depressions between sand dunes derived from the Yarlung Tsangpo floodplain. Constraining 14C dates from wetland vegetation and shell from one site fall between ca. 6600–2600 cal. yr B.P., while a second site is dated 3400–1200 cal. yr B.P. A significant and variable 14C reservoir effect—up to 1400 14C yr—limits these ranges to terminus post quem constraints. The in situ artifacts are supplemented by surface collections fully characterizing raw material and typological variability for each site. Raw material found at Zhongba is chert and chalcedony likely sourced from Cretaceous bedrock near the site. Typologically, microblades are nongeometric and are derived from conical and wedge‐shaped cores similar to those identified in the Qinghai Lake Basin and the Chang Tang Nature Reserve of similar or greater age. The later occupation period at Zhongba is broadly contemporaneous with sites on the Qinghai‐Tibet Plateau containing bronze and iron artifacts, indicating microlithic technology remained an important tool‐making strategy in western Tibet late into the protohistoric period.  相似文献   

9.
Carbon isotope composition (δ13C) in tree-rings has become routinely used in palaeoclimatic research for the assessment of changes in plant water availability in seasonally dry climates. However, the distribution of long tree-ring records around the world is very limited. Alternatively, the original climate signal of wood δ13C is well preserved in fossil charcoal and, accordingly, charcoal δ13C can be used to quantify past changes in water availability (e.g. precipitation). We report a case study on spatial palaeoclimate reconstruction which aims to characterize the transition between Bronze and Iron Ages, the so-called Iron Age Cold Epoch (ca. 900–300 BCE), using charcoals of Quercus ilex/coccifera from a set of 11 contemporary archaeological sites of eastern Spain. Climatic inferences were obtained after calibrating a linear model predicting seasonal precipitation from δ13C of Q. ilex wood samples obtained across a rainfall gradient. The best regression model corresponded to September–December (autumn) precipitation (Paut), in agreement with the fact that Q. ilex is able to exploit previous-year water reserves thanks to very effective water uptake. Subsequently, we estimated Paut from the δ13C of fossil charcoal to infer spatial patterns in water availability. Overall, estimated past Paut was about 19% higher (296 mm) than present-time values averaged across archaeological sites (249 mm). However, a clear geographic pattern of differences in precipitation could be observed in which the inner continental regions of eastern Spain were characterized by more humid conditions in the past, whereas the coastal strip of the Mediterranean Sea barely differed in past and present Paut values. The quite uniform distribution of archaeological sites over eastern Spain allowed development of contour maps of absolute and relative (to present) past Paut using gridded interpolation methods implemented in a GIS, highlighting the potential of this approach for reconstructing high-resolution spatial patterns of past climate.  相似文献   

10.
In this paper we discuss the limitation of radiocarbon dates on the pedogenic calcic nodules formed in situ within the vertisols in the upland region of Coimbatore, Tamil Nadu. The radiocarbon ages were obtained using low-level scintillation counters and the dates range from ∼24 to 31 14C kyrs BP. The ages correlate with the marine isotope stage of Late MIS3. However, since the calcic nodules are pedogenised and formed in an open system, the 14C ages should only be considered as estimates and not absolute ages because of the possibility of open-system behaviour with respect to carbon. Thus, we express caution in the interpretation of these and other radiocarbon ages obtained on pedogenic carbonate nodules. Multiple sub-mm size subsamples could provide more reliable age estimates.  相似文献   

11.
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12.
The first systematic geoarchaeological study of a rockshelter in Kansas yielded information about rockshelter formation, Holocene paleoenvironments, archaeological site formation processes, and prehistoric human habitation and site use. The rockshelter was carved by groundwater sapping; colluvium, alluvium, and roof‐fall debris subsequently accumulated on its floor. An assemblage of Late Archaic (∼2000–4000 14C years before present [yr B.P.]) cultural deposits (lithic material, bone, and charcoal) is preserved in a 2‐m thick package of colluvium and alluvium in front of the shelter. Chipped stone analysis indicates that Late Archaic occupants of the shelter were using mostly local materials and resharpening their stone tools at the shelter. Stable carbon isotope and phytolith analyses indicate that a mixed C3 and C4 plant community existed in the study area and that it changed in composition through the late Holocene. Based on the phytolith assemblage from an unlined fire pit at the front of the shelter, Late Archaic people used local hackberry trees for fuel and/or food.  相似文献   

13.
Wohlfarth, B. 2010: Ice‐free conditions in Sweden during Marine Oxygen Isotope Stage 3? Boreas, 10.1111/j.1502‐3885.2009.00137.x. ISSN 0300‐9483 Published and unpublished 14C dates for Sweden older than the Last Glacial Maximum ice advance were evaluated. Acceptable 14C dates indicate that age ranges for interstadial organic material in northern and central Sweden are between c. 60 and c. 35 cal. kyr BP and for similar deposits in southern Sweden are between c. 40 and c. 25 cal. kyr BP, which is in good agreement with recently derived Optical Stimulated Luminescence ages. 14C dates on mammoth remains show a larger scatter, possibly as a result of incomplete laboratory pretreatment. A possible scenario based on calibrated 14C dates from interstadial deposits is that central and northern Sweden was ice‐free during the early and middle part of Marine Oxygen Isotope Stage 3 and that southern Sweden remained ice‐free until c. 25 cal. kyr BP. A first ice advance into northern and central Sweden might have occurred as late as around 35 cal. kyr BP, more or less coeval with the Last Glacial Maximum ice advance onto the Norwegian shelf. To test the conclusions drawn here, new multi‐proxy and high‐resolution investigations of several key sites in north, central and south Sweden are required.  相似文献   

14.
Oxygen isotopes (δ18O) derived from archaeological Mercenaria campechiensis shells and Ariopsis felis otoliths potentially provide low-latitude paleoclimate data for studying Late Holocene human–climate interactions in coastal southwest Florida. Specimens analyzed come from the Pineland site complex. Deposits record abrupt and subtle environmental changes appearing to have been climate-related and to have impacted the sedentary human residents. One archaeological shell-otolith set dates to 2nd/3rd century A.D. within the Roman Optimum (RO) climatic episode. A second set dates to 13th/14th century A.D. within the Little Ice Age (LIA). A modern shell-otolith set was analyzed for comparison. δ18OARAGONITE of modern and LIA shells suggest similar seasonal conditions. RO shell is 1‰ more positive during summer, suggesting higher estuarine salinity than in modern and LIA times. Modern and LIA otoliths also have similar δ18OARAGONITE. Estimated Winter temperatures are within measured instrument records. Summer temperatures are overestimated reflecting Summer migration into less-saline water. Estimated Summer temperatures for RO otolith are similar to today's, suggesting elevated estuarine salinity and diminished rainy season, consistent with similar aged zooarchaeological assemblages. Comparisons of two taxa aid in interpreting archaeological δ18O data; however, early results are mixed with expected profiles for RO specimens and unexpected profiles for LIA specimens.  相似文献   

15.
环渤海海岸带14C数据集（Ⅱ）   总被引：10，自引：2，他引：10       下载免费PDF全文
王宏  范昌福 《第四纪研究》2005,25(2):14-156
作为晚更新世与全新世地层年代测定的一种重要手段,14C测年被广泛应用于地质样品的年代测定。但对于14C数据的系统校正,迄今未得到应有的重视。文章在环渤海海岸带14C数据集(Ⅰ)的基础上,对所收集的421个由其他研究者获得的环渤海海岸带14C数据进行了系统校正。并讨论了百年、千年与万年尺度的14C数据校正效果。结果表明,直接测定值与系统校正值之间的差值常有数百年至两千年的差别。经统一校正的14C年龄,最大限度地接近样品太阳历纪年的“真实”年龄,从而有助于更加准确地重建该地区的晚更新世晚期以来的地质年代史,并可与考古纪年及其他测年方法获得的绝对年龄直接对比。  相似文献   

16.
Understanding the hydrology of cold seep environments is crucial to perform accurate estimates of fluid and chemical fluxes at sedimentary wedges. Shallow convection processes may affect fluid flux estimates and could favor the destabilization of gas hydrate accumulations, increasing the sediment-ocean methane flux. Evidence for the occurrence of convection at cold seeps, however, is still limited. We use the concentration of 14C (D14C) in carbonate crusts formed at cold seeps of the eastern Mediterranean Sea as a tracer for convective recirculation of seawater-derived fluids. A numerical model is applied to investigate the controls on 14C incorporation in cold seep carbonates. Our simulations show that increased amounts of CH4 in the expelled fluids result in elevated crust D14C, while high Ca2+ and HCO3− concentrations produce the opposite effect. Convection is the only transport process that can significantly increase crust D14C. Advection, bioirrigation, eddy diffusion and bioturbation instead, have little effect on, or produce a decrease of, crust D14C. In addition, the presence of old or modern carbon (MC) in host sediments prior to cementation and the 14C-decay associated to the time needed to form the crust contribute in defining the D14C of carbonate crusts. We then use the model to reproduce the 14C content of the eastern Mediterranean Sea crusts to constrain the chemical and hydrological conditions that led to their formation. Some crusts contain relatively low amounts of 14C (−945.0<D14C ‰<−930.2) which, assuming no ageing after crust formation, can be reproduced without considering convection. Other crusts from two sites (the Amsterdam and Napoli mud volcanoes), instead, have a very high 14C-content (−899.0<D14C ‰<−838.4) which can only be reproduced by the model if convection mixes deep fluids with seawater. Order-of-magnitude calculations using the Rayleigh criterion for convection suggest that the slow seepage (about 10 cm year−1) of low salinity (20‰) fluids at the Amsterdam sites could trigger haline convection there. On the Napoli mud volcano, where high-density brines are expelled, density-driven convection cannot take place and other processes, possibly involving the rapid movement of free gas in the sediment, could be important.  相似文献   

17.
Appropriate marine–terrestrial reservoir offset (ΔR) values are essential for accurate calibration of marine radiocarbon dates. However, ΔR values are only valid for the specific calibration curve that their calculation is based on. Here, we present revised ΔR values for the Marine20 calibration curve from Arctic North America, based on previously published 14C dates on pre-bomb live-collected marine molluscs (n = 124) and cetaceans (beluga whales; tooth dentine; n = 12), and bowhead whale–driftwood age comparisons from the same glacio-isostatically uplifted shorelines (n = 18). Molluscan-based ΔR are: Chukchi/Beaufort sea coasts, 265±116 14C years; NW Canadian Arctic Archipelago, 188±91 14C years; NE Baffin Island, 81±18 14C years; SE Baffin Island, 14±58 14C years; Hudson Strait, −73±64 14C years; Ungava Bay, 0±86 14C years; Foxe Basin, 175±89 14C years; Hudson Bay, −21±72 14C years; James Bay, 209±114 14C years; West Greenland, −93±111 14C years. Species-specific marine mammal ΔR terms are 107±59 14C years for beluga and 24±58 14C years for bowheads. Our revised ΔR values are applicable for as long as the same broad oceanographic conditions (circulation, ventilation) have persisted, i.e. through the Holocene. While molluscan values are applicable to other marine carbonate (e.g. foraminifera), cetacean ΔR are valid only for the species they were calculated for and should not be applied to other marine mammals. Importantly, the ΔR terms calculated here are only valid for Marine20 and should not be used with earlier or later calibration curves.  相似文献   

18.
Authigenic calcite and dolomite and biogenic aragonite occur in Holocene pan sediments in a Mediterranean‐type climate on the western coastal plain of South Africa. Sediment was analysed from a Late Pleistocene coastal pan at Yzerfontein and four Holocene inland pans ranging from brackish to hypersaline. The pans are between 0·08 and 0·14 km2 in size. The δ18OPDB values of carbonate minerals in the pan sediments range from ?2·41 to 5·56‰ and indicate precipitation from evaporative waters. Covariance of total organic content and percentage carbonate minerals, and the δ13CPDB values of pan carbonate minerals (?8·85 to ?1·54‰) suggest that organic matter degradation is a significant source of carbonate ions. The precipitation of the carbonate minerals, especially dolomite, appears to be mediated by sulphate‐reducing bacteria in the black sulphidic mud zone found in the brine‐type hypersaline pans. The knobbly, sub‐spherical texture of the carbonate minerals suggests that the precipitation of the carbonate minerals, particularly dolomite, is related to microbial processes. The 87Sr/86Sr ratios of pan carbonate minerals (0·7108 to 0·7116) are slightly higher than modern sea water and indicate a predominantly sea water (marine aerosol) source for calcium (Ca2+) ions with relatively minor amounts of Ca2+ derived from the chemical weathering of bedrock.  相似文献   

19.
Two multi-year oxygen isotope (δ18O) records were obtained from archaeological Ostrea angasi shells, confirming the potential of this species to provide valuable environmental records for the late Holocene period in southeastern Australia. High-resolution δ18Oshell samples from the O. angasi clearly display a seasonal variability, offering insight into past climate conditions in a region where such information is presently limited.

The oxygen isotope record in O. angasi reflects a combined temperature–salinity signal. Observations of δ18Oshell data from modern specimens are used as a point of reference to assist in decoupling these two influences, with the two archaeological samples compared with the δ18Oshell profile of four modern O. angasi. Assuming similar paleo- δ18Owater values at the collection sites, data from these archaeological shells present a record of temperatures during the period of their growth that are consistently lower than modern day, with mean annual temperatures ～2°C cooler.  相似文献   


20.
The presence of an independently dated marker in an archaeological site offers rare opportunities for assessing the reliability of radiocarbon dates, especially when these are close to the age limit of the technique. Two different pretreatment protocols (routine ABA and more rigorous ABOx-SC) were employed in the chemical preparation of the same charcoal sample from a layer closely associated to the Campanian Ignimbrite tephra at the Russian Palaeolithic site of Kostenki 14 (Markina Gora). The ABA-treated fraction gave an age of ∼33 14C ka BP, comparable to a previous determination from the same layer, whereas the ABOx-SC produced an older age of ∼35 14C ka BP. This is the first radiocarbon determination of an archaeological sample to provide an age consistent with the “calendar” age for the CI tephra marker.  相似文献   

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