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1.
N. S. Bezaeva D. D. Badyukov M. A. Nazarov P. Rochette J. Feinberg 《Geochemistry International》2013,51(7):568-574
This paper presents the distribution of magnetic susceptibility, χ0, in fragments of the Chelyabinsk ordinary chondrite (LL5, S4, W0, fall of February 15, 2013) from the collection of the Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, and results obtained by standard magnetic techniques for the meteorite material, including thermomagnetic analysis, measurements of natural remanent magnetization (NRM) and saturation isothermal remanent magnetization (SIRM), as well as the spectra of their alternating field demagnetization at amplitudes up to 170 mT, measurements of hysteresis loops and back-field remanence demagnetization curves at temperatures from 10 K to 700°C etc. The mean logχ0 values for the light-colored (main) lithology of the meteorite material and impact-melt breccia from our collection are 4.54 ± 0.10 (n = 66) and 4.65 ± 0.09 (n = 38) (×10?9 m3/kg), respectively. According to international magnetic classification of meteorites, Chelyabinsk falls within the range of LL5 chondrites. The mean metal content was estimated from the saturation magnetization, M s, of the light- and dark-colored lithologies as 3.7 and 4.1 wt %, respectively. Hence, the dark lithology is richer in metal. The metal grains are multidomain at room temperature and show low coercive force, B c (<2 mT) and remanent coercive force, B cr (15–23 mT). The thermomagnetic analyses of the samples showed that the magnetic properties of the Chelyabinsk meteorite are controlled mainly by taenite and kamacite at temperatures >75 K. In the temperature range below 75 K, magnetic properties are controlled by chromite; the magnetic hardness of the samples is maximal at 10 K and equals to 606 and 157 mT for the light- and dark-colored lithologies, respectively. 相似文献
2.
3.
EMP determinations of Fe, Co and Ni in the metal phases of ordinary chondrites confirm the report of Sears and Axon that kamacite Co contents show restricted, nonoverlapping ranges in the three groups; ranges are 3.3–4.8 mg/g in H, 6.7–8.2 mg/g in L and 15–110 mg/g in LL. Experimental data by Widge and Goldstein show that the Ni concentration of the boundary increases with increasing Co concentration: unexpectedly, we find lower kamacite Ni concentrations in unequilibrated LL chondrites (44–55 mg/g) than in H and L chondrites (57–69 mg/g). We infer that, at temperatures below 550° C increasing Co causes a decrease in the equilibrium kamacite Ni concentration of an α-γ system. Although some evidence indicates that the equilibrated L chondrites Barratta, Knyahinya and Shaw have siderophile concentrations lower than the normal L-group range, they have kamacite and taenite Co concentrations in the L-group range.Metal-phase studies of petrologic type-3 ordinary chondrites having highly unequilibrated silicates showed a wide range in the degree of matrix kamacite equilibration ranging from nearly equilibrated in Mezö-Madaras to highly unequilibrated in Bishunpur, Ngawi and Semarkona. Kamacite in chondrule interiors is highly unequilibrated in all 9 chondrites, and in each setting taenite data are consistent with the expectation that it should be less equilibrated than kamacite. Our kamacite Co data confirm that Sharps is H and Hallingeberg. Khohar and Mezö-Madaras are L chondrites. Chainpur and Parnallee have kamacite Co concentrations between the L and LL ranges: we present evidence indicating that they are truly intermediate, i.e. neither L nor LL. Highly unequilibrated Ngawi is either LL or, less likely, still more oxidized. Bishunpur and Semarkona have mean kamacite Co concentrations in the H range but too unequilibrated to be used for classification. The highly heterogeneous compositions of the metal in Bishunpur, Ngawi and Semarkona indicate that their metal partially preserves properties established during nebular processes. Most of the taenite in these chondrites has high Ni contents (>470 mg/g) and is essentially unzoned; much of the kamacite is polycrystalline with crystals ?5μm across. Metamorphism causes tiny grains to disappear, increases the grain size of both kamacite and taenite, tends to equilibrate metallic minerals and, during cooling, can produce zoned taenite.A petrologic type-5 clast in the Ngawi LL3 chondrite has 3 coexisting metal phases, clear taenite (540 mg/g Ni, 21 mg/g Co), kamacite (30 mg/g Ni, 120 mg/g Co) and a phase tentatively identified as ordered FeCo (8.5 mg/g Ni, 370 mg/g Co). 相似文献
4.
Andrew J. Campbell 《Geochimica et cosmochimica acta》2003,67(13):2481-2495
Siderophile element abundances in individual metal grains in the ungrouped chondrite Grosvenor Mountains (GRO) 95551 and in the ordinary chondrites Tieschitz H3.6, Soko-Banja LL4, and Allegan H5 were measured with laser ablation-inductively coupled plasma mass spectrometry. Matrix metal in GRO 95551 falls into two distinct compositional groups, a high-Ni group with 7.2 ± 0.4 wt% Ni and a low-Ni group with 3.7 ± 0.1 wt% Ni, indicating that kamacite/taenite equilibration at ∼1020 K was followed by rapid cooling. The nonrefractory siderophile elements P, Co, Cu, Ga, Ge, As, Pd, and Au also partition between the high-Ni and low-Ni metal in a manner consistent with kamacite/taenite fractionation, but the refractory siderophiles Ru, Re, Os, Ir, and Pt show correlated variations that are unrelated to kamacite/taenite partitioning and indicate that variations in refractory components of the metal were not completely erased during equilibration at ∼1020 K. The Ni-normalized bulk metal composition of GRO 95551 is refractory depleted and volatile rich relative to Bencubbin and related metal-rich chondrites but bears strong similarities to equilibrated ordinary chondrite metal. GRO 95551 represents a new chondrite type with chemical affinity to the ordinary chondrites. Individual metal grains in unequlibrated ordinary chondrites also have correlated variations in refractory siderophile contents that cannot be produced by redox processes alone; these variations span three orders of magnitude and diminish with increasing metamorphic grade of the ordinary chondrites. 相似文献
5.
随州陨石不透明矿物有陨硫铁、铁纹石、镍纹石、自然铜、含镍黄铜矿、洛铁矿、钛铁矿等。本文对它们进行了反光显微镜鉴定、X射线分析、反射率及硬度的测定和电子探针分析，总结了不同化学群的球粒陨石铬铁矿、钛铁矿中FeO、MgO含量变化规律。 相似文献
6.
Yu. V. Erokhin V. A. Koroteev V. V. Khiller E. V. Burlakov K. S. Ivanov D. A. Kleimenov 《Doklady Earth Sciences》2017,477(2):1441-1444
New data on the mineral composition of Kargapole meteorite, which was found in Kurgan oblast in 1961, are presented. It has been established that the meteoritic material is represented by olivine (chrysolite), orthopyroxene (bronzite), clinopyroxene (diopside), plagioclase (oligoclase), chromite, Fe and Ni metal particles (kamacite, taenite, tetrataenite), sulfides (troilite, pentlandite), chlorapatite, and merrillite. For the first time, diopside, tetrataenite, pentlandite, chlorapatite, and merrillite were identified in the Kargapole meteorite. The chemical compositions of all minerals studied are given in Table 1. In terms of petrology, the meteorite is classified a common H4 chondrite. 相似文献
7.
安徽亳县陨石不透明矿物研究 总被引：3，自引：2，他引：3
毫县陨石的不透明矿物有陨硫铁、铁纹石、镍纹石、镍黄铁矿、镁铁尖晶石、自然铜、石墨、方铁矿、铬铁矿、钛铁矿、磁铁矿、张衡矿及x矿物等。本文对它们进行了反光显微镜鉴定、X射线分析、反射率测定和电子探针分析。总结了不同化学群的球粒陨石中FeO和MgO的含量变化规律。 相似文献
8.
Yu. V. Erokhin V. A. Koroteev V. V. Khiller E. V. Burlakov K. S. Ivanov D. A. Kleimenov 《Doklady Earth Sciences》2016,471(2):1273-1276
New data on the mineral composition of the Ozernoye meteorite, found in the Kurgan region in 1983, are presented. It has been found that that the meteorite’s matter is composed of olivine (chrysolite), orthopyroxene (bronzite), clinopyroxene (augite), maskelynite, chromite, ilmenite, metals Fe and Ni (kamasite, taenite), sulfides (troilite, pentlandite), chlorapatite, and merrillite. Augite, taenite, pentlandite, and merrillite were identified in the Ozernoye meteorite for the first time. The chemical compositions are given for all these minerals. The meteorite itself is an ordinary chondrite stone belonging to petrological type L5. 相似文献
9.
Analytical results for the material of the Chelyabinsk meteorite 总被引：1，自引：0，他引：1
E. M. Galimov V. P. Kolotov M. A. Nazarov Yu. A. Kostitsyn I. V. Kubrakova N. N. Kononkova I. A. Roshchina V. A. Alexeev L. L. Kashkarov D. D. Badyukov V. S. Sevast’yanov 《Geochemistry International》2013,51(7):522-539
This paper presents the results of the mineralogical, petrographic, elemental, and isotopic analysis of the Chelyabinsk meteorite and their geochemical interpretation. It was shown that the meteorite can be assigned to LL5-group ordinary chondrites and underwent moderate shock metamorphism (stage S4). The Chelyabinsk meteorite contains a significant fraction (approximately one-third by volume) of shock-melted material similar in composition to the main volume of the meteorite. The results of isotopic analysis suggest that the history of meteorite formation included an impact event approximately 290 Ma ago. 相似文献
10.
The metallic phases in six bronzite and six hypersthene chondrites were studied metallographically and by electron microprobe. All of the chondrites studied contain zoned taenite. In bronzite chondrites, only about 5 per cent of the zoned taenite abuts on kamacite (the rest being apparently isolated from it) whereas in hypersthene chondrites an average of over 20 per cent abuts on kamacite. The compositions of the centers of zoned taenite can be used to obtain cooling rates by Wood's method. Including Wood's results, 14 out of 18 ordinary chondrites have cooling rates between 1 and 10°C/m.y. 相似文献
11.
《Chemie der Erde / Geochemistry》2019,79(4):125528
Primitive CO3.00–3.1 chondrites contain ∼2-8 vol.% magnetite, minor troilite and accessory carbide and chromite; some CO3.1 chondrites have fayalite-rich veins, chondrule rims and euhedral matrix grains. All CO3.00–3.1 chondrites contain little metallic Fe-Ni (0.4–1.2 vol.%). CO3.2–3.7 chondrites contain 1–5 vol.% metallic Fe-Ni, minor troilite, accessory chromite and 0-0.6 vol.% magnetite. Magnetite is formed in primitive CO3 chondrites from metallic Fe by parent-body aqueous alteration, resulting in decreased metallic Fe-Ni and an increase in the proportion of high-Ni metal grains. The paucity or absence of magnetite in CO chondrites of subtype ≥3.2 suggests that magnetite is destroyed during thermal metamorphism; thermochemical calculations from the literature suggest that magnetite is reduced by H2 and reacts with SiO2 to form fayalite and secondary kamacite. Analogous processes of magnetite formation and destruction occur in other chondrite groups: (1) Primitive type-3 OC have opaque assemblages containing magnetite, carbide, Ni-rich metal and Ni-rich sulfide, but OC of subtype >3.4 contain little or no magnetite. (2) Primitive R3 chondrites and clasts (subtype ≲3.5) contain up to 6 vol.% magnetite, but most R chondrites contain no magnetite. The principal exception is magnetite with 9–20 wt.% Cr2O3 in a few R4-6 chondrites. Magnetite grains with high Cr2O3 behave like chromite and are more stable under reducing conditions. (3) CK chondrites average ∼4 vol.% magnetite with substantial Cr2O3 (up to ∼15 wt.%); these magnetite grains also are stable against reduction during metamorphism. (4) The modal abundance of magnetite decreases with metamorphic grade in CV3 chondrites. (5) Chromite occurs instead of magnetite in those rare samples classified CR6, CR7 and CV7. 相似文献
12.
2013年2月15日,俄罗斯车里雅宾斯克(Chelyabinsk)发生了伴随罕见的空中爆炸的大规模陨石雨事件。本文对3块代表不同冲击变质程度的车里雅宾斯克陨石碎块进行了研究。它们都具有部分熔壳,其中1块仅出现碎裂,1块含有冲击熔融细脉,1块基本由冲击熔融囊和冲击熔脉组成。冲击变质程度最低的样品,代表了该陨石母体小行星的原始岩石矿物学特征:即具有粗粒的岩石结构和均一的矿物化学组成,但仍保留一些残余球粒,表明受到了明显的热变质作用,其岩石类型可划分为5型。铁镁质硅酸盐高的Fe O含量(橄榄石Fa:27.9mol%~28.2mol%,辉石Fs值:23.3mol%~23.7mol%)、以及较低的Fe-Ni金属含量,表明其化学群属于低铁低金属的LL群。我们所分析的样品与前人报导的结果相似,未发现不同岩性的岩屑,表明车里雅宾斯克陨石的原始岩矿特征较为均一。3块陨石碎块中,随着冲击程度的增强,其冲击变质特征依次表现为硅酸盐矿物的破碎、熔长石化更为普遍、陨硫铁与铁镍合金共熔、硅酸盐熔脉的形成、铬铁矿与长石共熔、以及大量熔融囊的发育等。但是,在冲击熔融囊和熔脉中,以及相邻围岩中均未发现高压矿物相。熔脉中的橄榄石晶屑和相邻围岩的橄榄石颗粒表现为化学成分的不均一,在背散射电子图像中呈不同灰度的结构。这与其他强烈冲击变质陨石中橄榄石的林伍德石或瓦茨利石相变相似。该陨石中林伍德石或瓦茨利石的缺失很可能是由于强烈撞击后高温产生的退变质。这也表明车里雅宾斯克陨石的母体小行星可能遭受了非常强烈的撞击事件。 相似文献
13.
L.K. Ives M.B. Kasen R.E. Schramm A.W. Ruff R.P. Reed 《Geochimica et cosmochimica acta》1978,42(7):1051-1066
Metallography, electron microscopy and X-ray diffraction techniques were employed to study a fragment of the Tishomingo iron meteorite. The results suggest the following thermal-mechanical history: The fragment was originally a large crystal of taenite (γ). Cooling through the α + γ phase boundary did not result in accompanying precipitation of kamacite (α). Transformation to a martensitic structure initiated between ? 25 and ?65°C. Transformation continued as the temperature fell to ? 75 to ? 115°C, resulting in approx 80% martensite (α′). Subsequent shock deformation and thermal aging processes substantially modified the taenite and martensite microstructures. Twins in the retained taenite phase are attributed to shock deformation at a pressure estimated for a single event at ~170 kbar. The existing complex, altered martensite structure containing both taenite and kamacite (3–15% Ni) particles was apparently the product of both shock deformation and thermal aging processes. The maximum temperature reached during thermal aging is estimated to be less than 400°C, and perhaps below 310°C. 相似文献
14.
Caio Vinícius Gabrig Turbay Rangel Marcos Tadeu D’Azeredo Orlando Cláudio De Morisson Valeriano Alexandre de Oliveira Chaves 《International Geology Review》2017,59(15):1966-1973
The Varre-Sai meteorite fell along the border of the states of Espirito Santo and Rio de Janeiro, Brazil; on 19 June 2010 at 5:40 pm. Petrography and X-ray powder diffraction (XRD) indicate that the rock is an L5 S4 chondrite, with blastoporphyritic texture that has not been previously described. Geochemical data based on major and rare-earth elements (REEs) show that Varre-Sai is highly similar to the other L chondrites. In Harker diagrams, Varre-Sai, L, and LL chondrites form a single group, suggesting no significant chemical differences between them and contributing to the long-standing debate of whether LL chondrites form a distinct group or whether they are a subset of the L group. Harker diagrams also define a trend from E to H and L/LL chondrites, similar to the cosmochemical trends suggested by other authors. The behaviour of Fe2O3t and NiO indicates a relationship with Fe-Ni alloys, and their trend in the diagram suggests some chemical differentiation in the ordinary chondrite parental bodies. The REE content in Varre-Sai, normalized to C chondrites, falls in the field of L chondrites and others, but with slight REE enrichment. The chemical differences in chondrites, mainly in REEs, Fe2O3t and NiO could be alternatively interpreted as variations in the inherited agglutinated materials as chondrules, Ca–Al-rich inclusions and Fe–Ni nodules. 相似文献
15.
Yu. V. Erokhin V. A. Koroteev V. V. Khiller K. S. Ivanov D. A. Kleimenov 《Doklady Earth Sciences》2018,482(1):1189-1192
New data on the mineral composition of the Severny Kolchim meteorite, found in Perm Region in 1965, are presented. It has been found that that the meteorite matter is composed of olivine (chrysolite), orthopyroxene (bronzite), clinopyroxene (diopside), plagioclase (oligoclase, bytownite), glass, chromite, magnetite, ilmenite, rutile, metals Fe and Ni (kamasite, taenite, tetrataenite), copper, sulfides (troilite, pentlandite, covellite), chlorapatite, and merrillite. Diopside, tetrataenite, chlorapatite, and merrillite were identified in the Severny Kolchim meteorite for the first time. The chemical compositions are given for all these minerals. The meteorite itself is a nonequilibrium ordinary chondrite stone belonging to petrological type H3. 相似文献
16.
The mineralogical composition of the meteorite of Kiel was analyzed microscopically and with the electron microprobe. The meteorite consists mainly of chondrules, which are recrystallized to some extend and which are embedded in a recrystallized ground-mass. The chondrite contains 55 Vol.-% olivine of composition (Fa24,2Fo75,3Te0,5), 28 Vol.-% orthopyroxene (Fs21,4 En76,8Wo1,8), 9 Vol.-% plagioclase (An9,4 Ab85,1 Or5,5), 4,5 Vol.-% troilite and 2,5 Vol.-% Fe-Ni-metal grains, consisting of kamazite, zonal taenite and plessite; furthermore the chondrite contains chromite, whitlockite and a very small amount of ilmenite, native copper, chalcopyrrhotine and valeriite.The kamazite is partly monocrystalline, in part polycrystalline and contains 6–7% Ni. The Ni-contents of the zonal taenites increase from approximately 30% in the core to 50% at the rim. The rim rich in Ni is broader adjacent to troilite and kamazite than adjacent to silicates. Some zonal taenite grains are partially replaced by a mixture of Ni-rich taenite, kamazite and troilite. The plessites have an average Ni-content of 15–20%. The two phases of a coarsely disintegrated plessite contain 55% and 4–5% Ni. According to Wood (1967) a primary cooling rate of 1–10° C per one million years can be deducted from the zonal structure of the taenite. The formation of the taenite rims rich in Ni, of the taenite-troilite-kamazite-replacements, and of the coarsely disintegrated plessites is probably due to a long lasting annealing or a very slow passage through the temperature range of about 300–400° C.The meteorite of Kiel is a L6-chondrite according to the petrological classification of chondrites (van Schmus and Wood, 1967). The deformation of the olivines, pyroxenes and plagioclases indicates a slight to moderate shock deformation with a peak pressure of about 150–200 kbar.
Dank. Die Mikrosonde wurde von der Stiftung Volkswagenwerk bereitgestellt. Wir bedanken uns bei Herrn Prof. Dr. F. Karl (gestorben am 15. 8. 1972) für sein Interesse an dieser Arbeit. 相似文献
Dank. Die Mikrosonde wurde von der Stiftung Volkswagenwerk bereitgestellt. Wir bedanken uns bei Herrn Prof. Dr. F. Karl (gestorben am 15. 8. 1972) für sein Interesse an dieser Arbeit. 相似文献
17.
Gregory W. Kallemeyn William V. Boynton John Willis John T. Wasson 《Geochimica et cosmochimica acta》1978,42(5):507-515
The Bencubbin meteorite is a polymict breccia consisting of a host fraction of ~60% metal and ~40% ferromagnesian silicates and a selection of carbonaceous, ordinary and ‘enstatite’ chondritic clasts. Concentrations of 27 elements were determined by neutron activation in replicate samples of the host silicates and the ordinary and carbonaceous chondritic clasts; 12 elements were determined in the host metal. Compositional data for the ordinary chondrite clast indicate a classification of LL4 ± 1. Refractory element data for the carbonaceous chondrite clast indicate that it belongs to the CI-CM-CO clan; its volatile element abundances are intermediate between those of CM and CO chondrites. Abundances of nonvolatile elements in the silicate host are similar to those in the carbonaceous chondrite clast and in CM chondrites; the rare earths are unfractionated. We conclude that it is not achondritic as previously designated, but chondritic and that it is probably related to the CI-CM-CO clan; its volatile abundances are lower than those in CO chondrites. Oxygen isotope data are consistent with these classifications. Host metal in Bencubbin and in the closely related Weatherford meteorite has low abundances of moderately volatile siderophiles; among iron meteorite groups its nearest relative is group IIIF.We suggest that Bencubbin and Weatherford formed as a result of an impact event on a carbonaceous chondrite regolith. The impact generated an ‘instant magma’ that trapped and surrounded regolithic clasts to form the polymict breccia. The parent of this ‘magma’ was probably the regolith itself, perhaps mainly consisting of the so-called ‘enstatite’ chondrite materials. Accretion of such a variety of materials to a small parent body was probably only possible in the asteroid belt. 相似文献
18.
球粒陨石的冲击作用与热释光特征研究 总被引：1，自引：0，他引：1
测定了我国部分球粒陨石的自然热释光峰温、峰半高宽度和灵敏度, 强冲击型陨石的热释光灵敏度偏低,峰温、峰半高宽温度则偏高。岩庄陨石属天然冲击球粒陨石,具有强烈的冲击特征。测定岩庄陨石两种不同颜色冲击脉体的热释光,其强度明显地不一样,并发现该陨石的热释光具有β辐照诱发热释光位移和退火热释光位移现象。冲击作用明显地改变着热释光的各种特性。 相似文献
19.
We have studied metal grains in the hosts and lithic fragments of widely differing petrologic types in four xenolithic chondrftes, using reflected-light microscopy and electron-probe analysis. In Weston and Fayetteville, which both contain solar-flare tracks and solar-wind gases, kamacite, taenite and tetrataenite (ordered FeNi) and troilite show a variety of textures. On a Wood plot of central Ni content vs dimension, taenite analyses scatter as if metal grains cooled at rates of 10–1000 and 1–100 K/Myr respectively through 700 K, although metal in an H6 clast in Fayetteville plots coherently with a cooling rate of 50 K/Myr. We propose that metal grains cooled at these rates in chondritic clasts at different locations before host and clasts were compacted, and were not subsequently heated above 650 K. We predict a similar history for all gas-rich ordinary chondrites.By contrast, metallic minerals throughout Bhola and Mezö-Madaras show more uniform textures and plot coherently giving cooling rates in the range 750 to ~600 K of 0.1 and 1 K/Myr, respectively. We conclude that host and xenoliths in both chondrites were slowly cooled after compaction. Thus clasts in these chondrites experienced peak metamorphic temperatures and slow cooling through 700 K in different environments.According to the conventional onion-shell model for H, L or LL chondrite parent bodies, material of petrologic types 3–5 was arranged in successive shells around a type 6 core prior to catastrophic collisions which mixed all types intimately. But if peak metamorphic temperatures were reached during, not after accretion, as seems plausible, maximum metamorphism may have occurred in planetesimals <10 km in radius. Cooling through 700 K may then have occurred in larger bodies that accreted from these planetesimals. Iron meteorites, mesosiderites and some achondrites may also have experienced melting in planetesimals and slow cooling in larger bodies. 相似文献
