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1.
Tailings resulted from sulphuric acid leaching process of uranium from sedimentary rocks contain high concentrations of 226Ra and its daughters, the most important of which is 222Rn. Movement of radon gas out of the tailings is strongly influenced by the physicochemical characteristics of these tailings especially their radium content and the grain size. So, the tailing samples were size fractionated into four sizes (>?250, 250–125, 125–74 and <?74 µm). The natural radioactivity was investigated using hyper-pure germanium detector and solid-state nuclear track detectors (CR-39) for bulk size and after size fractionation. The activity concentrations of different radionuclides in size-fractionated tailing samples have been shown to be strongly dependent on the size of the particles. In the range of >?250 and <?74 µm, the activity concentrations of 230Th, 226Ra, 214Pb, 214Bi, 210Pb, 232Th and 40K increased throughout with decreasing particle size, while that of 238U, 234U and 235U have an opposite effect. The results revealed an inverse relationship between the radon exhalation rate and size fractionation. Also, the results showed a good correlation between radium activity concentration and radon mass exhalation rate.  相似文献   

2.
The variation of the natural radionuclide concentrations depends on the chemical composition of each site. In this work, two thermal springs in the east of Algeria have been chosen to assess the activity concentration of natural radionuclide, mainly the three natural radioactive series 238U, 235U and 232Th, and 40K. The high-resolution gamma ray spectroscopy was used to determine these concentrations. In these water samples, 235U, 234Th, 210Pb, 226Ra radionuclides are less than the minimum detectable activity. The activity of 238U is dominant. The 238U activity was determined by taking the mean activity of two separate photo-peaks of daughter nuclides 214Pb at 351.92 (37.2%) keV and 214Bi at 609.31 (45%) keV. The measured activity concentrations of 238U in water samples obtained from the concentrations of 214Bi and 214Pb ranged from 0.56 ± 0.20 to 1.13 ± 0.20 Bq/L. The annual effective dose value due to the ingestion of the measured radionuclide 238U in 1 L of water, for an adult, ranged from 9.20 to 18.56 µSv.  相似文献   

3.
Based on γ-radiation dose rate and radon concentration measurements and 238U, 232Th, 226Ra, and 40K radionuclide testing, this study identifies the radioactive anomalies of stone coal-bearing strata in East China and evaluates the natural radioactivity levels in the air, solid, water and plant media in the typical area of the regional stone coal-bearing layers. The stone coal-bearing strata in East China occur in the lower Cambrian system along the margin of the Yangtze block; additionally, the radioactive anomaly area is sporadically distributed in the stone coal-bearing layers. The background values of 238U, 232Th, 226Ra, and 40K are higher in the stone coal-bearing areas, and the spatial distribution of these natural radionuclides shows significant variability. 238U and 226Ra clearly accumulate in the coal, coal gangue and soil and are the main sources of the environmental radiation in coal mines. The γ-radiation shows a higher background value in the stone coal-bearing area, and this radioactive pollution cannot be ignored. Typically, the effective dose of γ-radiation exceeds the limit value of 5 mSv/a, and the total α and total β concentrations of the groundwater are 10–30 times the limit value at some points. The residents near the mining area are subjected to a higher radiation dose, and the groundwater, building materials, and plants have been contaminated by the radioactive pollution sporadically through time. It is necessary to strengthen the monitoring work of radioactive environments and to take appropriate control measures.  相似文献   

4.
《Applied Geochemistry》2002,17(6):751-779
Uranium concentrations and 234U/238U ratios in saturated-zone and perched ground water were used to investigate hydrologic flow and downgradient dilution and dispersion in the vicinity of Yucca Mountain, a potential high-level radioactive waste disposal site. The U data were obtained by thermal ionization mass spectrometry on more than 280 samples from the Death Valley regional flow system. Large variations in both U concentrations (commonly 0.6–10 μg l−1) and 234U/238U activity ratios (commonly 1.5–6) are present on both local and regional scales; however, ground water with 234U/238U activity ratios from 7 up to 8.06 is restricted largely to samples from Yucca Mountain. Data from ground water in the Tertiary volcanic and Quaternary alluvial aquifers at and adjacent to Yucca Mountain plot in 3 distinct fields of reciprocal U concentration versus 234U/238U activity ratio correlated to different geographic areas. Ground water to the west of Yucca Mountain has large U concentrations and moderate 234U/238U whereas ground water to the east in the Fortymile flow system has similar 234U/238U, but distinctly smaller U concentrations. Ground water beneath the central part of Yucca Mountain has intermediate U concentrations but distinctive 234U/238U activity ratios of about 7–8. Perched water from the lower part of the unsaturated zone at Yucca Mountain has similarly large values of 234U/238U. These U data imply that the Tertiary volcanic aquifer beneath the central part of Yucca Mountain is isolated from north-south regional flow. The similarity of 234U/238U in both saturated- and unsaturated-zone ground water at Yucca Mountain further indicates that saturated-zone ground water beneath Yucca Mountain is dominated by local recharge rather than regional flow. The distinctive 234U/238U signatures also provide a natural tracer of downgradient flow. Elevated 234U/238U in ground water from two water-supply wells east of Yucca Mountain are interpreted as the result of induced flow from 40 a of ground-water withdrawal. Elevated 234U/238U in a borehole south of Yucca Mountain is interpreted as evidence that natural downgradient flow is more likely to follow southerly paths in the structurally anisotropic Tertiary volcanic aquifer where it becomes diluted by regional flow in the Fortymile system.  相似文献   

5.
Indoor radon measurements were carried out in a total of 420 dwellings and 17 schools in Hail region of Saudi Arabia, using NTDs based radon dosimeters. The duration of the measurements was one year, from April 2008 to April 2009. The indoor radon concentrations varied from 4 to 513 Bq/m3 with an overall average of 45 Bq/m3 for all surveyed dwellings. These passive measurements were confirmed by the active measurements. The anomalous concentrations above 200 Bq/m3 were observed in 13 dwellings, representing 3.1 % of the total surveyed dwellings. In Inbowan village alone, it was found that 7.6 % of the dwellings have indoor radon concentration above 200 Bq/m3. The highest average indoor radon concentration of 64 Bq/m3 was found in Inbowan village while the lowest average of 24 Bq/m3 was found in Majasah village. The city of Hail showed an average indoor radon concentration of 49 Bq/m3. The average indoor radon concentration in one area located at the edge of the Aja Mountain in Hail city was 111 Bq/m3. The elevated indoor radon concentrations in many dwellings in the Hail region, prompted us to measure outdoor ground radon in such locations using gas monitor. It was found that radon concentrations at a depth of 0.5 m varied significantly from place to place ranging from 1.2 to 177 kBq/m3. The outdoor radon concentrations are generally correlated with the indoor radon measurements. Radon exhalations from construction materials and soil samples from the Hail region were also measured. It was found that radon exhalations from soil samples are higher than that of construction materials by a factor of at least 3 and reaching up to 11. These results indicate that soil is the main source of indoor radon. Geological interpretations of the results are also given.  相似文献   

6.
One hundred and twenty one samples from every major plutonic body (mainly granitic) of Greece have been analyzed by γ-ray spectrometry to determine the specific activities of 238U, 232Th and 40K (Bq/kg). The range of the activity concentrations of these radionuclides was 2.3–266.4, 1.8–375.5 and 55.0–1632.0 Bq/kg and their average values were 79.2, 85.3 and 881.4 Bq/kg respectively. Any possible connection between the specific activities of 238U, 232Th and 40K and some characteristics of the studied samples (age, rock-type, colour, grain-size, occurrence and chemical composition) is investigated. Samples of particular colour, rock-type, occurrence and chemical composition have been identified for their distinctive levels of natural radioactivity, while age and grain-size do not affect the concentrations of 238U, 232Th and 40K. The range of the Th/U ratio was 0.7–12.69. This great variation in the Th/U ratios, especially when it is found among the samples of the same pluton, is also discussed and explained by alteration and tectonic–metamorphic processes.  相似文献   

7.
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8.
A study of natural radionuclides and radon concentration of Hamirpur District of Himachal Pradesh, India is carried out using various methodologies. The activity concentration of the natural radionuclides viz. 226Ra, 232Th and 40K is measured using high-resolution-based HPGe detector. Indoor radon measurements in the dwellings of Hamirpur district is carried out using LR-115 type II cellulose nitrate films in the bare mode. The average activity concentrations of 226Ra, 232Th and 40K are 35.58, 54.95 and 580.58 Bq kg?1, respectively. The annual average indoor radon value in the study area varies from 173.90 to 198.25 Bq m?3, which is well within the recommended action level given by International Commission on Radiological Protection. The indoor radon values obtained in the present investigation are higher than the world average of 40 Bq m?3. Radon concentration in water samples is measured using RAD7, an active radon detector. The annual effective dose for stomach and lung is determined from the measured value of radon concentration in water. To assess the radiation hazard of the natural radioactivity in all samples to the people, the radium equivalent activity, external hazard index, lifetime fatality risk, absorbed dose rate and total annual effective dose is estimated. The results signify that the studied area does not possess any radiation hazards due to the presence of natural radioactivity concentration.  相似文献   

9.
Pressure of natural gas in its rock reservoir determines the final radon concentration in this gas after its decompression to normal conditions. In this investigation, radon contents of 62 natural gas samples were measured and a simple physical model of the gas reservoir was applied. The model takes into account an additional dependence of radon concentration on the natural gas pressure and on the porosity of the rock reservoir. The influence of the gas pressure on the value of the radon emanating power is discussed. The mean 226 Ra content in the source rock needed for generation of 222 Rn concentrations observed in gas is also calculated. The calculations are made with the help of regression analysis.  相似文献   

10.
The aim of the study is to assess the natural background radiation in and around Rameswaram Island. In this context, samples were collected to measure the gamma radiations of 238U, 232Th, and 40K using NaI(Tl) detector-based gamma ray spectrometer. The average activity concentrations of 238U, 232Th, and 40K are noted to be well below the world average values. The calculated absorbed dose rate, radium equivalent activity, and hazard index values were below the prescribed limit. The grain size of the sediment was analyzed following Trefethen’s nomenclature, and its correlation with the natural background radioactivity was studied. The sample that contained clay show elevated activity of 40K. The percentage of heavy minerals shows concomitant variation in natural radioactivity, especially in the activity of 238U and 232Th.  相似文献   

11.
Radon and its progenies have been ranked second of being responsible for lung cancer in humans. Hong Kong has four major groups of uranium-rich plutonic and volcanic rocks and is suffering from radon emanated therefrom. However, there is a lack of radon potential maps in Hong Kong to resolve the spatial distribution of radon-prone areas. A ten-point radon potential system was developed in Germany (2005) to predict radon potential using both the in situ geogenic and geographic parameters under hierarchical ranking. Primarily, the ten-point system requires the desk study of the geological environment of sampling sites, which has an advantage of saving resources and manpower in extensive radon potential mapping over the traditional soil radon concentration sampling method. This paper presents a trial of radon potential mapping in Hong Kong to further verify the system. Despite some slight departures, the system demonstrates an acceptable correlation with soil radon concentrations (R 2 = 0.62–0.66) from 768 samples of mainly intermediate radon potential. Hong Kong has a mean soil radon concentrations of 58.9 kBqm?3, while the radon potential from the ten-point system achieves an average of 4.93 out of 10 over the territory. The vicinity of fault zone showed high soil radon concentrations and potentials, which were conducive to uranium enrichment and rapid soil-gas diffusion near faults. High uranium-238 content in soil was found to cause high soil radon concentration with a large R 2, 0.84. The Jurassic granite and volcanic crystal tuff cover more than 85 % of the whole Hong Kong area, and they show relatively high radon concentrations (Geometric mean 83 and 49 kBqm?3, respectively) which are associated with their high uranium contents (Geometric mean 234 and 197 Bqkg?1, respectively). While indoor radon concentration is an important factor for radon risk assessment, this study has not considered the correlation between indoor radon concentration and radon potential. The reason is that almost all buildings in Hong Kong are high-rise buildings where indoor radon concentrations are governed only by the radium content in the building materials and the ventilation conditions.  相似文献   

12.
The daughter to parent (234U/238U) activity ratio in natural waters is often out of secular radioactive equilibrium. The major reason for this disequilibrium is related to the energetic α-decay of 238U and differential release of 234U relative to 238U. This disequilibrium originates from (1) preferential release of more loosely bound 234U from damaged mineral lattice sites or; (2) direct recoil of 234Th into surrounding media from near mineral surface boundaries, however, it is unclear which of the two mechanisms is most important in nature. To better quantify the effects of preferential release of 234U, two continuous laboratory granite leaching experiments conducted over 1100 h were performed. The leachates were characterized by declining U concentrations with time and (234U/238U) initially greater than unity (up to 1.15), which changed to below unity during leaching (∼0.95). The early elevated (234U/238U) suggests that additional 234U is released into solution by preferential release of 234U from mineral phases. However, the excess 234U constitutes a finite pool of easy leachable 234U and the (234U/238U) values become lower than unity when this pool is used up. A model based on first-order kinetics, dissolution rates and preferential release of 234U from damaged lattice sites was developed and is able to quantitatively predict the observed pattern of (234U/238U) values and U concentrations for the two granite leaching experiments. Extending the modeling to longer time scales more comparable to natural systems shows that the production of waters with high (234U/238U) ratios can be achieved in two distinct regimes (1) slow weathering where the rate of directly recoiled 234U near mineral surfaces into waters is high; (2) fast weathering where the role of incipient chemical weathering and preferential release of loosely bound 234U are important. The model is able to explain apparent opposite correlations between physical erosion rates and (234U/238U) in waters and it provides a new framework that will be useful for examining weathering regimes, their timescales and their coupling with physical erosion.  相似文献   

13.
This study was conducted primarily to measure and map radon activity concentration in soil gas and to understand the effect of geology and lithology and meteorology on radon concentration. Portable radon meter has been used for the measurement of soil gas radon at 30 different locations around Uro and Korn area in eastern Nuba Mountain South Kordofan State. The results indicate that the activity concentrations of 222Rn in soil gas fall within the range of 20–1,359 Bq/m3 with geometric mean of 102.80 Bq/cm3. The obtained data show that samples around Uro have anomaly of 222Rn concentrations than the sample around Korn. The reason could be attributed to differences in the geological structure, lithology and climate parameters. GIS predicative map has shown that the elevated levels of radon concentration were measured in North study area. Upon comparing the results with global data, it was found that the obtained values are far below the reported range of India, Slovenia, Portugal and Syria. However, the range of 222Rn concentrations in the soil observed in this study is significantly high relative to similar data reported from Libya. The regression analysis has shown that no correlation was noted between radon concentrations, climatic parameters and trace element.  相似文献   

14.
A study of the indoor radon gas levels was performed in 935 homes in Scania, southernmost Sweden, located on geologically different ground with regard to uranium (U) content. In one of these two areas the bedrock consists of alum shale with U contents exceeding 200 ppm. In the other area there is no U-rich bedrock. Indoor radon levels are influenced by U content and permeability as shown below.For maam nancy for table, please place here. Thanx!The results show that the indoor radon levels were highest in homes located on bedrock with medium to high U content combined with a highly permeable drift covering the bedrock. The difference was statistically significant(P < 0.0001). Other results of the investigation are: 14 homes built from aerated concrete made from U-rich alum shale had higher levels than 767 homes with walls from other material (312 vs 106 Bq/m3;P = 0.0011); 242 homes with a cellar had lower radon levels than 563 without (62 vs 138 Bq/m3;P <0.0001); further, 418 homes with private well had higher levels than 360 with public water supply (140 vs 82 Bq/m3;P <0.0001). The results of the investigation show a profound effect of a combination of high bedrock U content and high cover permeability. The effect of the uraniferous drift on the indoor radon levels is evident. Thus, the geological conditions should be carefully considered when screening for high-risk buildings, as well as when planning for new ones. Also, the construction of the building and its water supply have some influence.  相似文献   

15.
Groundwater constitutes the major source of utility water in Ekiti State with the majority of the population depending on groundwater for drinking and other household uses. Soil in the area is commonly used as a component of building materials, which may produce radon in the indoor environment. Excessive concentrations of radon in water and soil can cause radiological health risks to human as witnessed by the increased cases of lung cancer among non-smokers in Nigeria, which may be traceable to the ingestion and inhalation 222Rn in drinking water and indoor air. In the present study, comparative in situ measurements of radon in groundwater and soil gas were carried out at one hundred selected locations across the Ekiti State in southwest Nigeria, using a RAD7 radon detector to generate a radon distribution map and to estimate radiation hazards due to radon. The concentrations of radon in groundwater ranged from 0.9 to 472 Bq L?1 with a mean of 34.7?±?4.4 Bq L?1, while those of soil gas ranged from 0.1 to 315 kBq L?1 with a mean of 38.9?±?1.4 kBq L?1. The total annual effective dose due to inhalation and ingestion of radon in groundwater amounted to 94.7 µSv year?1, which is lower than the reference dose of 100 µSv year?1 recommended by the World Health Organization (WHO). The radon map generated for groundwater and soil gas identified three distinct areas with radon levels ranging from low to high. The results of this study show that some locations (Emure, Gbonyin, Ijero and Ikole) show mean total annual effective doses which are higher than the recommended limit. It can then be inferred that the groundwater samples pose significant radiological hazards to the population and that the noticed increase in lung cancer cases may be attributed to the consumption of groundwater in the area.  相似文献   

16.
Drill cuttings generated during unconventional natural gas extraction from the Marcellus Shale, Appalachian Basin, U.S.A., generally contain a very large component of organic-rich black shale because of extensive lateral drilling into this target unit. In this study, element concentrations and Pb isotope ratios obtained from leached drill cuttings spanning 600 m of stratigraphic section were used to assess the potential for short and long term environmental impacts from Marcellus Shale waste materials, in comparison with material from surrounding formations. Leachates of the units above, below and within the Marcellus Shale yielded Cl/Br ratios of 100–150, similar to produced water values. Leachates from oxidized and unoxidized drill cuttings from the Marcellus Shale contain distinct suites of elevated trace metal concentrations, including Cd, Cu, Mo, Ni, Sb, U, V and Zn. The most elevated Mo, Ni, Sb, U, and V concentrations are found in leachates from the lower portion of the Marcellus Shale, the section typically exploited for natural gas production. In addition, lower 207Pb/206Pb ratios within the lower Marcellus Shale (0.661–0.733) provide a distinctive fingerprint from formations above (0.822–0.846) and below (0.796–0.810), reflecting 206Pb produced as a result of in situ 238U decay within this organic rich black shale. Trace metal concentrations from the Marcellus Shale leachates are similar to total metal concentrations from other black shales. These metal concentrations can exceed screening levels recommended by the EPA, and thus have the potential to impact soil and water quality depending on cuttings disposal methods.  相似文献   

17.
U-Pb systems were examined in samples (ranging from 4 to 10 cm3 in volume) of ore material taken from along a 3.5-m profile across a zone of U mineralization exposed in an underground mine at the Strel’tsovskoe U deposit in eastern Transbaikalia. The behaviors of two isotopic U-Pb systems (238U-206Pb and 235U-207Pb) are principally different in all samples from our profile. While the individual samples are characterized by a vast scatter of their T(206Pb/238U) age values (from 112 to 717 Ma), the corresponding T(207Pb/235U) values vary much less significantly (from 127 to 142 Ma) and are generally close to the true age of the U mineralization. The main reason for the distortion of the U-Pb system is the long-lasting (for tens of million years) migration of intermediate decay products in the 238U-206Pb(RD238U) in the samples. This process resulted in the loss of RD238U from domains with high U concentrations and the subsequent accommodation of RD238U at sites with low U concentrations. The long-term effect of these opposite processes resulted in a deficit or excess of 206Pb as the final product of 238U decay. The loss or migration of RD238U are explained by the occurrence of pitchblende in association with U oxides that have higher Si and OH concentrations than those in the pitchblende and a higher +6U/+4U ratio. The finely dispersed character of the mineralization and the loose or metamict texture of the material are the principal prerequisites for RD238U loss and an excess of 206Pb in adjacent domains with low U concentrations. Domains with low U contents in the zone with U mineralization serve as geochemical barriers (because of sulfides contained in them) at which long-lived RD238U(226Ra, 210Po, 210Bi, and 210Pb) were accommodated and subsequently caused an excess of 206Pb. The 235U-207Pb system remained closed because of the much briefer lifetime of the 235U decay products. This may account for the significant discrepancies between the T(206Pb/238U) and T(207Pb/235U) age values. RD238U was most probably lost via the migration of radioisotopes at the middle part and end of the 238U family (starting with 226Ra). The heavy Th, Pa, and U radioisotopes (234Th, 234Pa, 234U, and 230Th) that occur closer to the beginning of 238U decay, before 226Ra, only relatively insignificantly participated in the process. Our results show that the loss and migration of RD238U are, under certain conditions, the main (or even the only) process responsible for the distortion of the U-Pb system.  相似文献   

18.
Relatively high activity concentrations of some radionuclides (226Ra, 238U, 232Th, and 40K) have been measured in surface and subsurface soils in areas (southern Iraq) where many warfare actions have taken place during the Iran–Iraq and Gulf wars. Such high activity concentrations might be related to the increase in cancerous injuries and birth defects recently reported. The study was aimed to estimate the activity concentrations of some nuclides and a comparison of results with international health hazard indices. In addition, the excess lifetime cancer risk (ELCR) was assessed. Soil samples were collected at three depths (0, 30, and 60 cm) in three locations in Abu Al Khasib and Ad Dayr in Basrah governorates. The average activity concentrations were estimated employing hyper-pure germanium HPGe gamma-ray detection technology. The values obtained in Abu Al Khasib were: 58.44 Bq/kg (226Ra), 43.56 Bq/kg (238U), 19.38 Bq/kg (232Th), and 321.76 Bq/kg (40K) whereas in Ad Dayr 45.71 Bq/kg (226Ra), 35.53 Bq/kg (238U), 20.33 Bq/kg (232Th), and 337.02 Bq/kg (40K). According to UNSCEAR (Sources and effects of ionizing radiations: a report on the effects of atomic radiation to the general assembly with scientific annexes, Annex B, United Nations, New York, 2000) report, higher levels of 226Ra, 238U concentrations than the world’s average values (35 Bq/kg) were observed in both locations. In addition, some radiation hazard indices were determined for both locations: average outdoor external dose (D out), average indoor external dose (D in), total average value of the external dose (D tot), average annual outdoor effective dose (E out), average annual indoor effective dose (E in), and averaged total annual effective dose (E tot). Values for D tot and E tot were higher than the worldwide median (143 nGy/h and 0.48 mSv/y, respectively) in both regions. The measured values of activity concentrations were also used to estimate the outdoor, indoor, and total ELCR. The ELCR values were higher than the worldwide averages. Further analyses and studies need to assess the real risks for human health and possible soil remediation.  相似文献   

19.
High-sensitivity experiments with particles that are strongly enriched in alpha-emitting nuclei show that damaged regions are produced that can be eroded by subsequent exposure to water. Direct ejection of recoil nuclei from solid grains is also observed. These observations appear to supply a basis for understanding disequilibria between 238U and 234U in natural samples that have been exposed to water. The two mechanisms observed are expected to act under different natural conditions.  相似文献   

20.
In 1996–1997, indoor radon values of more than 40,000 Bq/m3 and large seasonal and geographical variations in indoor air radon were reported from a residential area located on a highly permeable ice-marginal deposit. Geochemical analyses of bedrock, groundwater and sediments and comparisons between indoor radon values and soil radon values indicate that the indoor radon concentrations in this area are strongly affected by subterranean airflows caused by temperature differences between soil air and atmospheric air. The airflows concentrate the radon-laden soil air towards the topographic highest part of the deposit in winter and towards the topographic lowest part in summer. In areas where subterranean airflows are likely to occur, radon measurements performed both in summer and in winter provide the best estimate of annual average indoor radon concentrations, and assessments of indoor radon concentrations based on single soil gas measurements are not recommended.  相似文献   

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