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1.
《Comptes Rendus Geoscience》2019,351(2-3):113-120
A polycrystalline specimen of liebermannite [KAlSi3O8 hollandite] was synthesized at 14.5 GPa and 1473 K using glass starting material in a uniaxial split-sphere apparatus. The recovered specimen is pure tetragonal hollandite [SG: I4/m] with bulk density of within 98% of the measured X-ray value. The specimen was also characterized by Raman spectroscopy and nuclear magnetic resonance spectroscopy. Sound velocities in this specimen were measured by ultrasonic interferometry to 13 GPa at room T in a uniaxial split-cylinder apparatus using Al2O3 as a pressure marker. Finite strain analysis of the ultrasonic data yielded KS0 = 145(1) GPa, K0′ = 4.9(2), G0 = 92.3(3) GPa, G0′ = 1.6(1) for the bulk and shear moduli and their pressure derivatives, corresponding to VP0 = 8.4(1) km/s, VS0 = 4.9(1) km/s for the sound wave velocities at room temperature. These elasticity data are compared to literature values obtained from static compression experiments and theoretical density functional calculations.  相似文献   

2.
《Chemical Geology》2006,225(3-4):222-229
First principles phase diagram calculations were performed for the system NaCl–KCl. Plane-wave pseudopotential calculations of formation energies were used as a basis for fitting cluster expansion Hamiltonians, both with and without an approximation for the excess vibrational entropy (SVIB). Including SVIB dramatically improves the agreement between calculated and experimental phase diagrams: experimentally, the consolute point is {XC = 0.348, TC = 765 K}Exp; without SVIB, it is {XC = 0.46, TC ≈ 1630 K}Calc; with SVIB, it is {XC = 0.43, TC ≈ 930 K}Calc.  相似文献   

3.
《Comptes Rendus Geoscience》2019,351(2-3):121-128
We present a synchrotron-based, single-crystal X-ray diffraction and Raman spectroscopy study of natural green dioptase (Cu6Si6O18·6H2O) up to ∼30 GPa at room temperature. The lattice parameters of dioptase exhibit continuous compression behavior up to ∼14.5 GPa, whereupon a structural transition is observed. Pressure–volume data below 14.5 GPa were fitted to a second-order Birch–Murnaghan equation of state with V0 = 1440(2) Å3 and K0 = 107(2) GPa, with K0′ = 4(fixed). The low-pressure form of dioptase exhibits anisotropic compression with axial compressibility βa > βc in a ratio of 1.14:1.00. Based on the diffraction data and Raman spectroscopy, the new high-pressure phase could be regarded as a dehydrated form of dioptase in the same symmetry group. Pressure-induced dehydration of dioptase contributes broadly to our understanding of the high-pressure crystal chemistry of hydrous silicates containing molecular water groups.  相似文献   

4.
《Applied Geochemistry》2005,20(11):2017-2037
The Tertiary Thrace Basin located in NW Turkey comprises 9 km of clastic-sedimentary column ranging in age from Early Eocene to Recent in age. Fifteen natural gas and 10 associated condensate samples collected from the 11 different gas fields along the NW–SE extending zone of the northern portion of the basin were evaluated on the basis of their chemical and individual C isotopic compositions. For the purpose of the study, the genesis of CH4, thermogenic C2+ gases, and associated condensates were evaluated separately.Methane appears to have 3 origins: Group-1 CH4 is bacteriogenic (Calculated δ13CC1–C = −61.48‰; Silivri Field) and found in Oligocene reservoirs and mixed with the thermogenic Group-2 CH4. They probably formed in the Upper Oligocene coal and shales deposited in a marshy-swamp environment of fluvio-deltaic settings. Group-2 (δ13CC1–C = −35.80‰; Hamitabat Field) and Group-3 (δ13C1–C = −49.10‰; Değirmenköy Field) methanes are thermogenic and share the same origin with the Group-2 and Group-3 C2+ gases. The Group-2 C2+ gases include 63% of the gas fields. They are produced from both Eocene (overwhelmingly) and Oligocene reservoirs. These gases were almost certainly generated from isotopically heavy terrestrial kerogen (δ13C = −21‰) present in the Eocene deltaic Hamitabat shales. The Group-3 C2+ gases, produced from one field, were generated from isotopically light marine kerogen (δ13C = −29‰). Lower Oligoce ne Mezardere shales deposited in pro-deltaic settings are believed to be the source of these gases.The bulk and individual n-alkane isotopic relationships between the rock extracts, gases, condensates and oils from the basin differentiated two Groups of condensates, which can be genetically linked to the Group-2 and -3 thermogenic C2+ gases. However, it is crucial to note that condensates do not necessarily correlate to their associated gases.Maturity assessments on the Group-1 and -2 thermogenic gases based on their estimated initial kerogen isotope values (δ13C = −21‰; −29‰) and on the biomarkers present in the associated condensates reveal that all the hydrocarbons including gases, condensates and oils are the products of primary cracking at the early mature st age (Req = 0.55–0.81%). It is demonstrated that the open-system source conditions required for such an early-mature hydrocarbon expulsion exist and are supported by fault systems of the basin.  相似文献   

5.
Three models were examined to predict C aromaticity (fa) of biochars based on either their elemental composition (C, H, N and O) or fixed C (FC) content. Values of fa from solid state 13C nuclear magnetic resonance (NMR) analysis with Bloch-decay (BD) or direct polarisation (DP) techniques, concentrations of total C, H, N, and organic O, and contents of FC of 60 biochars were either compiled from the literature (dataset 1, n = 52) or generated in this study (dataset 2, n = 8). Models were first calibrated with dataset 1 and then validated with dataset 2. All models were able to fit dataset 1 when atomic H to C ratio (H/C) < 1 (except two ash rich biochars) and to estimate fa of HF treated biochars (H/C < 1). Model 1, which was based on values of H/C only and calibrated with a root mean square of error (RMSE) of 0.04 fa-unit (n = 41), could predict the experimental data with a RMSE = 0.02 fa-unit (n = 6). Model 2, which was based on biochar elemental composition data, showed the most accurate prediction, with a RMSE of 0.03 fa-unit (n = 41) for the calibration data, and of 0.02 fa-unit (n = 6, H/C < 1) for the validation data. Model 3, which was based on contents of FC and C, and modified with a correction factor of 0.96, displayed the highest RMSE (0.06 fa-unit, n = 19) among the three models. Models 1 and 2 did not work properly for samples having either an H/C ratio > 1, high concentrations of carbonate or high inorganic H. These models need to be further tested with a wider range of biochars before they can be recommended for classification of biochar stability.  相似文献   

6.
《Gondwana Research》2016,29(4):1391-1414
Experiments on the origin of the Udachnaya-East kimberlite (UEK) have been performed using a Kawai-type multianvil apparatus at 3–6.5 GPa and 900–1500 °C. The studied composition represents exceptionally fresh Group-I kimberlite containing (wt.%): SiO2 = 25.9, TiO2 = 1.8, Al2O3 = 2.8, FeO = 9.0, MgO = 30.1, CaO = 12.7, Na2O = 3.4, K2O = 1.3, P2O5 = 1.0, Cl = 0.9, CO2 = 9.9, and H2O = 0.5. The super-solidus assemblage consists of melt, olivine (Ol), Ca-rich (26.0–30.2 wt.% CaO) garnet (Gt), Al-spinel (Sp), perovskite (Pv), a CaCO3 phase (calcite or aragonite), and apatite. The low pressure assemblage (3–4 GPa) also includes clinopyroxene. The apparent solidus was established between 900 and 1000 °C at 6.5 GPa. At 6.5 GPa and 900 °C Na–Ca carbonate with molar ratio of (Na + K)/Ca ≈ 0.44 was observed. The UEK did not achieve complete melting even at 1500 °C and 6.5 GPa, due to excess xenogenic Ol in the starting material. In the studied P–T range, the melt has a Ca-carbonatite composition (Ca# = molar Ca/(Ca + Mg) ratio = 0.62–0.84) with high alkali and Cl contents (7.3–11.4 wt.% Na2O, 2.8–6.7 wt.% K2O, 1.6–3.4 wt.% Cl). The K, Na and Cl contents and Ca# decrease with temperature. It is argued that the primary kimberlite melt at depths > 200 km was an essentially carbonatitic (< 5 wt.% SiO2), but evolved toward a carbonate–silicate composition (up to 15–20 wt.% SiO2) during ascent. The absence of orthopyroxene among the run products indicates that xenogenic orthopyroxene was preferentially dissolved into the kimberlite melt. The obtained subliquidus phase assemblage (Ol + Sp + Pv + Ca-rich Gt) at P–T conditions of the UEK source region, i.e. where melt was in the last equilibrium with source rock before magma ascent, differs from the Opx-bearing peridotitic mineral assemblage of the UEK source region. This difference can be ascribed to the loss of substantial amounts of CO2 from the kimberlite magma at shallow depths, as indicated by both petrological and experimental data. Our study implies that alkali-carbonatite melt would be a liquid phase within mantle plumes generated at the core–mantle boundary or shallower levels of the mantle, enhancing the ascent velocity of the plumes. We conclude that the long-term activity of a rising hot mantle plume and associated carbonatite melt (i.e. kimberlite melt) causes thermo-mechanical erosion of the subcontinental lithosphere mantle (SCLM) roots and creates hot and deformed metasomatic regions in the lower parts of the SCLM, which corresponds to depths constrained by P–T estimates of sheared Gt-peridotite xenoliths. The sheared Gt-peridotites undoubtedly represent samples of these regions.  相似文献   

7.
An unusual series of C22–C27 monounsaturated sterenes and C24–C30 tetracyclic terpanes (17,21-secohopanes) were detected in relatively high concentrations in an immature evaporitic marl sediment of the Jinxian Sag, Bohai Bay Basin, North China. The site of unsaturation in these novel sterenes is assigned tentatively to the D ring on the basis of mass spectral interpretation, which also distinguishes them from reported unsaturated sterenes. Other hydrocarbon biomarker or stable isotope characteristics are indicative of microbial (e.g. methyl hopanes), phytoplankton or higher plant (depleted δ13C values of isoprenoids and hopanes) inputs and an anoxic carbonate depositional environment (hexacyclic hopanes; tetracyclic terpanes). The hydrocarbon composition showed no obvious biodegradation and the relatively high concentration of unsaturated terpenoids (e.g. gammacerene) and low values of other established maturity parameters (Ts/Tm = 0.23; Ro = 0.44%; Tmax = 417 °C), are consistent with sediments of low maturity. The novel, low molecular weight sterenes and the tetracyclic terpanes may be early diagenetic products of microbial sources in a carbonate environment.  相似文献   

8.
《Gondwana Research》2014,25(2):668-684
Studies on lower crustal and mantle xenoliths as well as geophysical data provide important information on the cratonic lithosphere. While geothermobarometric calculations of a majority of mantle xenoliths are in agreement with the typically low surface heat flow values of a craton (~ 40 mW/m2), P–T estimates for lower crustal xenoliths deviate significantly from the cratonic geotherms. Independent from the individual cratonic history, the temperatures are ~ 200–300 °C higher than what is expected at the base of the lower crust (~ 500–600 °C at ~ 1.3–1.6 GPa). Possible explanations may be a lack of equilibration to the cratonic geotherm or a relatively recent localized heat input. The presence of granulitic rocks under eclogite-facies conditions which are expected to prevail in the lower cratonic crust has consequences for the interpretation of geophysical rock properties. A mafic granulite which has been preserved under eclogite-facies conditions has densities and P-wave velocities similar to a felsic composition equilibrated to eclogite-facies conditions. Furthermore, phase diagrams calculated from xenolith bulk compositions demonstrate that eclogitization at relatively high temperatures as required for delamination of continental crust can only be triggered at significantly higher pressures than lithostatic at the base of the lower crust. As long as P–T conditions and the rock composition entail the assemblage to be granulitic, the addition of fluid at temperatures above 800 °C will not result in eclogitization, but rather in melt generation. This can also lead to an increase in density of up to 3%, however, this is strongly dependent on the amount of water saturation.  相似文献   

9.
The critical issue in the study of kimberlites, known as principal host rocks of diamonds, is the reconstruction of their primary melt composition, which is poorly constrained due to contamination by xenogenic materials, significant loss of volatiles during eruption, and post-magmatic alteration. It is generally accepted that the last equilibration of primary kimberlite melt with surrounding mantle (garnet lherzolite) occurred beneath cratons at 5–7 GPa (150–230 km depths). However, the subliquidus mineral assemblages obtained in kimberlite melting experiments at mantle pressures differ from lherzolite, probably owing to unaccounted loss of CO2. Here we present experiments at 6.5 GPa and 1200–1600 °C on unaltered kimberlite with an addition of 2–22 mol% CO2 over its natural abundance in the rock (13 mol%), but keeping proportions of other components identical to those in an exceptionally fresh anhydrous kimberlite from Udachnaya-East pipe in Siberia. We found that the partial melt achieves equilibrium with garnet lherzolite at 1500 °C and 19–23 mol% CO2 in the system. Under these conditions this melt contains (mol%): SiO2 = 9, FeO = 6–7, MgO = 23–26, CaO = 16, Na2O = 4, K2O = 1, and CO2 = 30–35. We propose, therefore, the alkali-rich carbonatitic composition of primary kimberlite melt and loss of 34–45 mol% (34–46 wt%) CO2 during ascent of the kimberlite magma to the surface.  相似文献   

10.
Precise indices based on n-alkane signatures were developed in order to determine the sources and composition of sedimentary organic matter (SOM) in coastal systems. The Arcachon Bay (France), a well-studied temperate lagoon, was used as an example of a complex coastal system sheltering a wide diversity of OM sources. Three main groups of sources were well discriminated from their n-alkane signatures: seagrass (Zostera sp.) produced mainly n-C17, n-C19, n-C21, n-C23 and n-C25 alkanes, algae (Rhodophyta, Chlorophyta) produced n-C15 and n-C17 and the terrigenous input [Quercus sp., Spartina sp. and river suspended particulate OM (SPOM)] was characterized by n-C25, n-C27, n-C29, n-C31 and n-C33. From the above and literature n-alkane fingerprints, we developed a set of indices (n-alkane ratios) to quantify the contribution of these three major sources of the SOM. At the Arcachon Bay scale, they indicated that SOM was composed mainly of seagrass (ca. 53 ± 19%) and terrestrial (ca. 41 ± 17%) material, followed by algae (ca. 6 ± 9%). Moreover, the new n-alkane indices exhibited more relevant spatial patterns than classical ones – the TAR (C27 + C29 + C31/C15 + C17 + C19; terrestrial to aquatic ratio) and the Paq (C23 + C25/C23 + C25 + C29 + C31; aquatic plant %) – with a greater contribution from marine sources in the central part of the lagoon where a high density of Zostera seagrass was observed. Therefore, the development of precise indices adapted to the local diversity of OM sources is needed when using n-alkanes for quantifying the source composition of SOM in complex coastal systems.  相似文献   

11.
《Comptes Rendus Geoscience》2018,350(8):476-486
In this study, the model H(i) = 109.6103 + C1 × F1(i) + C2 × F2(i) + … + C33 × F33(i) obtained from depth modelling based on 33 recent benthic foraminifer species distribution, has been applied to the fossil benthic foraminifers from the borehole GDEC-4-2 drilled at a water depth of 491 m, in the East-Corsica basin, covering the last 550,000 years. The obtained variations of the paleo-depths show a medium correlation with the oscillations of the relative sea level and also with the fluctuations of the oxygen isotopic ratio (δ18O G. bulloides and δ18O C. pachyderma–C. wuellerstorfi). This newly developed transfer function is accompanied by an error margin of ± 86 m, suggesting that this model will probably be more suitable for a time scale of the order of a million years where sea level variations are recorded with larger amplitudes. Without considering these problems related to amplitudes, it also turns out that the “eustatic” signal of the microfauna is accompanied by a “trophic” signal, which should not to be neglected, especially at a millennial scale time resolution. Thus, the application of this method would require taking into account the bottom trophic effects strongly controlling the distribution of benthic foraminifer assemblages.  相似文献   

12.
Previously studied thermosequences of wood (chestnut) and grass (rice straw) biochar were subjected to hydrogen pyrolysis (hypy) to evaluate the efficacy of the technique for determining pyrogenic carbon (CP) abundance. As expected, biochar from both wood and grass produced at higher temperature had higher CP amount. However, the trend was not linear, but more sigmoidal. CP/CT ratio values (CT = total organic carbon) for the wood thermosequence were ⩽0.03 at biochar production temperature (TCHAR) ⩽ 300 °C. They increased dramatically until 600 °C and remained relatively constant and near unity at higher biochar production temperature. Grass biochar was similar in profile, but CP/CT values rose dramatically after 400 °C. The findings are consistent with the hypothesis that hypy residues contain polycyclic aromatic hydrocarbons (PAHs) with a degree of condensation above at least 7–14 fused rings, with labile organic matter and pyrogenic PAHs below this degree of condensation removed by hypy.Both wood and grass thermosequences displayed δ13CP values that decreased with increased TCHAR, indicating that recalcitrant carbon compounds (pyrogenic aromatic PAHs with a relatively high degree of condensation) were first formed from structural components with relatively high δ13C values (e.g. cellulose). Relatively constant δ13C values at TCHAR ⩾ 500 °C suggested the dominant pyrolysis reaction was condensation of PAHs with no additional fractionation. Comparison of hypy with benzene polycarboxylic acid (BPCA), ‘ring current’ NMR and pyrolysis gas chromatography–mass spectrometry (GC–MS) results from the same suite of samples indicated a consistent overview of the structure of CP, but provided unique and complimentary information.  相似文献   

13.
《Comptes Rendus Geoscience》2019,351(2-3):253-259
We extended the attainable pressure of the Kawai-type multianvil apparatus to 71.3 GPa and 120.3 GPa at room temperature by equipping it with tungsten carbide (WC) and sintered diamond (SD) cubic anvils, respectively. In the experiments with WC anvils, pressure decreased largely, ΔP ∼−20 GPa, on heating from room temperature to 1500 K. In the experiments with SD anvils, pressure also dropped to 105 GPa from 120 GPa at 1673 K. In order to generate higher pressure and temperatures, therefore, innovation of SD material in both quality and size are essential, together with improvements of cell assembly. Besides pressure generation, we conducted in situ energy-dispersive X-ray diffraction observations on CaSnO3 and (Mg,Fe)SiO3 in the experiments with WC and SD anvils, respectively. We observed the growth of new peaks, which can be assigned to the post-perovskite phase, transformed from a starting material of CaSnO3 perovskite at 48.4 GPa and 1500 K, although they are not clearly identified. In contrast, we could not observe the post-perovskite phase of (Mg,Fe)SiO3 in the present P–T conditions generated by experiments with SD anvils.  相似文献   

14.
The stable carbon isotopic compositions of light hydrocarbon gases adsorbed in near-surface soil and sediments from the Saurashtra basin were characterized for their origin and maturity. Saurashtra is considered geologically prospective for oil and gas reserves; however, a major part of the basin is covered by the Deccan Traps, hindering the exploration of Mesozoic hydrocarbon targets. Surface geochemical prospecting, based on micro-seepage of hydrocarbons from subsurface accumulations, could be advantageous in such areas. In light of this, 150 soil samples were collected from the northwestern part of Saurashtra, around the Jamnagar area, where a thick sedimentary sequence of about 2–3 km exists under 1–1.5 km of Deccan basalt. The concentration of acid desorbed alkane gases from soil samples was found to vary (in ppb) as: methane (C1) = 3–518; ethane (C2) = 0–430; propane (C3) = 0–331; i-butane (iC4) = 0–297; n-butane (nC4) = 2–116; i-pentane (iC5) = 0–31 and n-pentane (nC5) = 0–23, respectively.Fifteen samples with high concentrations of alkane gases were measured for their δ13C1; δ13C2 and δ13C3 compositions using gas chromatography–combustion-isotope ratio mass spectrometry (GC–C-IRMS). The values for methane varied from ? 27 to ? 45.4‰, ethane from ? 20.9 to ? 27.6‰, and propane from ? 20.4 to ? 29.1‰ versus the Vienna PeeDee Belemnite (VPDB). The carbon isotope ratio distribution pattern represents isotopic characteristics pertaining to hydrocarbon gases derived from thermogenic sources. Comparisons of carbon isotopic signatures and compositional variations with the standard carbon isotopic models suggest that hydrocarbon gases found in the shallow depths of the study area are not of bacterial origin but are formed thermally from deeply buried organic matter, likely to be mainly a terrestrial source rock with a partial contribution from a marine source. These gases may have migrated to the near-surface environment, where they represent an admixture of thermally generated hydrocarbon gases from mixed sources and maturity. The maturity scale (δ13C versus Log Ro %) applied to the surface sediment samples of the Jamnagar area indicated the source material to be capable of generating oil and gas. The detection of thermogenic alkane gases in near-surface sediments offers the possibility of hydrocarbons at depth in Saurashtra.  相似文献   

15.
The study area lies between latitude 18–26°N and longitude 73–83°E, and mainly covers the Central India Tectonic Zone (CITZ). The frequency-dependent shear wave quality factor (Qs) has been estimated over the CITZ and its surroundings using Double Spectral Ratio (DSR) method. We have considered 25 local earthquakes with magnitude (ML) varies from 3.0 to 4.7 recorded at 11 stations running under national seismic network. The Fast Fourier Transformed (FFT) spectra were computed from the recorded waveform having time-window from onset of S-phase to 1.0 s and for a frequency-band of 0.1–10 Hz. Three different shear wave velocities (i.e., 3.87, 3.39 and 3.96 km/s) were obtained over the study area based on a pair of earthquakes recorded at a pair of stations. The low Qs values of 51–96 at 1 Hz (i.e., Qs = 51f0.49; Qs = 90f0.488 and Qs = 96f0.53) were found in the area covering the Son–Narmada–Tapti (SONATA) lineament, CITZ, eastern part of the Satpura fold belt, Vindhyan and Gondwana basins, Godavari and Mahanadi grabens, and southern part of Gangetic plain. Intermediate Qs values of the order of 204–277 (i.e., Qs = 204f0.56 and Qs = 277f0.55) were noted in the cartonic areas, namely, Bundelkhand, Dharwar-Bhandara and Bastar. While the higher Qs values of 391–628 at 1 Hz (i.e., Qs = 391f0.49, Qs = 409f0.48, Qs = 417f0.48, Qs = 500f0.66, Qs = 585f0.65 and Qs = 628f0.69) were found in the eastern part of the SONATA, CITZ, and the northeastern part of the Satpura fold belt. The low Qs values might be attributing to the more heterogeneous SONATA rift system. Low Qs values further may presumably be associated with lower-level of seismicity and apparently account for higher tectonic stress accumulation over long duration. The long-term accumulated stress is generally released through occasional triggering of moderate magnitude earthquakes in the SONATA zone. Surrounding the SONATA region, the higher Qs values possibly accounts for a more homogeneous subsurface structure along the SONATA zone.  相似文献   

16.
《Gondwana Research》2014,25(3):1120-1138
Phosphatized microfossils from ca. 580 Ma from the Doushantuo Formation in the Weng'an region of South China were analyzed by Fourier transform infrared (FTIR) microspectroscopy for their chemical characterization. Two morpho-types of phosphatized embryo-like fossils (Megasphaera and Megaclonophycus) were analyzed, together with algal fossils. Transmission IR spectra of the microfossils have absorption bands of around 2960 cm− 1 and 2925 cm− 1, indicating the presence of aliphatic hydrocarbon (anti-symmetric aliphatic CH3 and aliphatic CH2), and have an additional band of around 1595 cm− 1, probably derived from aromatic moieties (aromatic CC). In addition, IR microscopic mapping shows that aliphatic hydrocarbon and aromatics are distributed inside the embryo-like fossils. The embryo-like fossils appear to show three types of CH3/CH2 peak height ratios (R3/2) and aromatic CC/CH2 peak height ratios (RCC/2 values): (1) high-R3/2/low-RCC/2 type (R3/2 = ~ 0.2–1.0 and RCC/2 ~ 0–2), (2) low-R3/2/medium-RCC/2 type (R3/2 = ~ 0.2–0.6 and RCC/2 = ~ 1–4); and (3) low-R3/2/high-RCC/2 type (R3/2 = ~ 0.2–0.6 and RCC/2 ~ 1–8). All three types are contained in both Megasphaera and Megaclonophycus. Raman spectra for the carbonaceous matter within the rock sample show a similar degree of thermal alteration, indicating that the organics were embedded in situ prior to thermal maturation. The IR spectroscopic differences might reflect differences in original organic compositions of microorganisms, and/or immediate post-mortem alteration. This suggests that the origins of phosphatized embryo-like fossils are more diverse than was previously recognized on the basis of their morphology. A comparison of R3/2 and RCC/2 values in the embryo-like fossils with those of the algal fossils and the extant microorganisms indicates the possible interpretation that some of the embryo-like fossils belong to animal embryo, others are algae, but none of them originate from bacteria.  相似文献   

17.
A prograde pressure–temperature (P–T) path is estimated for pelitic schists from the latest Precambrian Kokchetav ultrahigh-pressure massif, Kazakhstan, using compositional zoning and mineral inclusions in coarse-grained and inclusion-rich garnets. Ti-bearing inclusions are abundant in garnet and display a zonal distribution. Ilmenite occurs in the inner-core, where most of it makes a composite inclusion with rutile, whereas monomineralic rutile occurs in the outer-core to mantle domains. In the rim region both ilmenite and rutile are present, although in small amounts. Application of the ilmenite-garnet thermometer yields a systematic temperature increase towards rim from 500 to 750 °C. The pressure-sensitive reaction: 3 Fe-Ilm (in Ilm) + Ky + 2 Qtz = 3 Rt + Alm (in Grt) yielded pressures of 1.2–1.3 GPa for the outer-core inclusions.A petrogenetic grid in the K2O–CaO–FeO–MgO–Al2O3–SiO2–H2O model system was used to estimate the equilibrium compositions of the garnet. The change of the grossular component along the model P–T path expected from the forward modelling is close to the observed compositional profile of the outer-core to rim domains. No constraint is available from thermobarometry in the inner-core; however, the forward modelling of garnet zoning provides information on the early stage of the P–T path during the garnet growth.The estimated P–T path is counter-clockwise in the prograde stage with a steep bend at around 700 °C and 1.2–1.5 GPa. This is similar to the metamorphic P–T gradient of the Kokchetav massif. This result contrasts markedly with the traditional clockwise P–T path in many collisional metamorphic terranes, and is regarded to represent a subduction geotherm at the Precambrian–Cambrian boundary. The P–T path proposed in this study also supports the models for the recovery of the “snowball Earth” from late-Proterozoic glaciation through effect of water in the solid Earth mantle.  相似文献   

18.
Orogenic gold mineralization in the Amalia greenstone belt is hosted by oxide facies banded iron-formation (BIF). Hydrothermal alteration of the BIF layers is characterized by chloritization, carbonatization, hematization and pyritization, and quartz-carbonate veins that cut across the layers. The alteration mineral assemblages consist of ankerite-ferroan dolomite minerals, siderite, chlorite, hematite, pyrite and subordinate amounts of arsenopyrite and chalcopyrite. Information on the physico-chemical properties of the ore-forming fluids and ambient conditions that promoted gold mineralization at Amalia were deduced from sulfur, oxygen and carbon isotopic ratios, and fluid inclusions from quartz-carbonate samples associated with the gold mineralization.Microthermometric and laser Raman analyses indicated that the ore-forming fluid was composed of low salinity H2O-CO2 composition (~3 wt% NaCl equiv.). The combination of microthermometric data and arsenopyrite-pyrite geothermometry suggest that quartz-carbonate vein formation, gold mineralization and associated alteration of the proximal BIF wall rock occurred at temperature-pressure conditions of 300 ± 30 °C and ∼2 kbar. Thermodynamic calculations at 300 °C suggest an increase in fO2 (10−32–10−30 bars) and corresponding decrease in total sulfur concentration (0.002–0.001 m) that overlapped the pyrite-hematite-magnetite boundary during gold mineralization. Although hematite in the alteration assemblage indicate oxidizing conditions at the deposit site, the calculated low fO2 values are consistent with previously determined high Fe/Fe + Mg ratios (>0.7) in associated chlorite, absence of sulfates and restricted positive δ34S values in associated pyrite. Based on the fluid composition, metal association and physico-chemical conditions reported in the current study, it is confirmed that gold in the Amalia fluid was transported as reduced bisulfide complexes (e.g., Au(HS)2−). At Amalia, gold deposition was most likely a combined effect of increase in fO2 corresponding to the magnetite-hematite buffer, and reduction in total sulfur contents due to sulfide precipitation during progressive fluid-rock interaction.The epigenetic features coupled with the isotopic compositions of the ore-forming fluid (δ34SΣS = +1.8 to +2.3‰, δ18OH2O = +6.6 to +7.9‰, and δ13CΣC = −6.0 to −7.7‰ at 300–330 °C) are consistent with an externally deep-sourced fluid of igneous signature or/and prograde metamorphism of mantle-derived rocks.  相似文献   

19.
Although oil cracking has been documented as one of the important sources of gas in many overmature marine sedimentary basins, the chemical and carbon isotopic signatures of gases of this origin are still open to question. In this study a Cambrian crude oil from the central Tarim basin, along with its main separated fractions (saturates, aromatics and asphaltenes), were pyrolyzed in sealed gold tubes to investigate how generated gases vary in chemical and carbon isotopic composition and how this variation would influence the genetic interpretation of oil cracking gas. The results indicate that the gases from cracking of aromatics and asphaltenes are much drier and more enriched in 13C than the gases from the cracking of saturates and crude oil at the same level of thermal maturity. In the experimental run of 20 °C/h, the dryness index of the gases (defined as the volume percentage of C1 in C1–5) from the cracking of saturates ranges from 26.2–90.6% with the methane carbon isotope change ranging from −54.8‰ to −35.5‰, whereas the dryness index is never lower than 60.6% for the gases from the cracking of aromatics with methane carbon isotope ranging from −39.9‰ to −32.2‰. Correspondingly, experimental data for the four samples plot in different areas in diagrams designed to distinguish oil cracking gas from kerogen cracking gas, such as ln(C2/C3) vs. δ13C2–δ13C3 and δ13C1 vs. δ13C2–δ13C3, indicating compositional variability of crude oil could assert an important influence in these diagrams. Therefore it is prudent to bring other geological constraints into consideration to avoid misinterpretation.The kinetic parameters for the bulk generation of C1–5 gas and the methane carbon isotope fractionation extrapolated to geological conditions of 2 °C/Ma and an initial temperature of 50 °C show that the temperatures of C1–5 gas generation from the aromatics and asphaltenes are lower than those from the saturates and crude oil due to their lower activation energies and frequency factors. Generation of C1–5 gases from the aromatics is modeled to be initiated about 122 °C whereas the initiation temperature for the saturates sample is 176 °C. Below 189 °C (EasyRo = 1.8%), the yields of C1–5 gases follow the order: aromatics > asphaltenes > crude oil > saturates. At similar thermal maturity levels, the methane carbon isotopic compositions are significantly different for the four samples, with an order of 13C enrichment: aromatics > asphaltenes > crude oil > saturates, however the difference in methane carbon isotopes becomes smaller with increasing temperature. This indicates that methane carbon isotopic values can be significantly different for gases cracked from oils that are compositionally diverse, especially in the early stage of methane generation.  相似文献   

20.
Surface sediments from the Gulf of Cádiz (GoC) were analyzed by alkaline CuO oxidation, in order to estimate the contribution of terrigenous organic matter (TOM) to the inner continental shelf of the southwest Iberian Peninsula. The parallel analysis of sediment samples from the two most important rivers draining to this coastal area (i.e. Guadiana River and Tinto–Odiel fluvial system) provided fundamental information regarding local terrestrial sources. Relatively constant intensive lignin parameters (S:V = 1.0 ± 0.1 and C:V = 0.22 ± 0.04) and high values of the lignin phenol vegetation index (LPVI = 155 ± 43) indicated that non-woody angiosperm tissues constitute the dominant component of vascular plant material reaching the shelf sediments. The NW to SE decreasing isotopic (13C) and molecular (Λ8) signatures found among the sediments, coinciding with the Guadiana delivery plume, suggest that this river is the main terrestrial source in the inner GoC shelf. Slightly elevated values of degradation indicative ratios ([Ad:Al]V = 0.41 ± 0.10; [Ad:Al])S = 0.34 ± 0.07; [3,5-Bd:V] = 0.14 ± 0.05; P:[V + S] = 0.24 ± 0.09) suggested the alteration state of the shelf sediments. The two fold higher ratios of the river sediments (Guadiana: [Ad:Al]V = 0.82 ± 0.08; [Ad:Al]S = 0.84 ± 0.03; Tinto–Odiel: [Ad:Al]V = 0.86 ± 0.12; [Ad:Al]S = 0.83 ± 0.013) and the increasing degradation trend observed outward in the shelf, lead us to consider preferential sorption processes, instead of in situ diagenesis, to affect the degradation signature of the shelf sediments. Preferentially solubilized degraded OM is more likely to be sorbed and stabilized prior to transport to the marine system, showing an apparently more advanced degradation state. The use of the 3,5-Bd:V ratio in conjunction with (Ad:Al)V revealed a composition continuum of the sedimentary OM ranging from fresh plant materials to highly altered soil humic constituents. Elemental and molecular analyses show a land to sea gradient by a NW to SE decrease of the terrestrial influence, accounting for larger terrestrial inputs (TOM: 71–98%) in those sediments near the Guadiana mouth, and predominantly autochthonous composition (TOM: 42–50%) in those located offshore. This work utilizes lignin derived biomarkers to determine the contribution of terrigenous OM delivered to this poorly described coastal area from regional rivers. Within a context of increasing international efforts to better understand the global C cycling, this study illustrates the relevance of using the alkaline CuO oxidation approach to evaluate C budgets and continental influence in river dominated ocean margins.  相似文献   

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