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1.
Micro- and macroscale experiments which document the dynamics of salt damage to porous stone have yielded data which expose weaknesses in earlier interpretations. Previously unexplained differences are found in crystal morphology, crystallization patterns, kinetics and substrate damage when comparing the growth of mirabilite (Na2SO4. 10H2O) and thenardite (Na2SO4) versus halite (NaCl). The crystallization pattern of sodium sulphate was strongly affected by relative humidity (RH), while a lesser RH effect was observed for sodium chloride. Macroscale experiments confirmed that mirabilite (crystallizing at RH > 50 per cent) and thenardite (crystallizing at RH < 50 per cent) tend to form subflorescence in highly localized areas under conditions of constant RH and temperature. This crystallization pattern was more damaging than that of halite, since halite tended to grow as efflorescence or by filling the smallest pores of the stone in a homogeneous fashion, a result which contradicts Wellman and Wilson's theoretical model of salt damage. Low RH promoted rapid evaporation of saline solutions and higher supersaturation levels, resulting in the greatest damage to the stone in the case of both sodium sulphate and sodium chloride crystallization. At any particular crystallization condition, sodium chloride tended to reach lower supersaturation levels (resulting in the crystallization of isometric crystals) and created negligible damage, while sodium sulphate reached higher supersaturation ratios (resulting in non-equilibrium crystal shapes), resulting in significant damage. ESEM showed no damage from sodium sulphate due to hydration. Instead, after water condensation on thenardite crystals, rapid dissolution followed by precipitation of mirabilite took place, resulting in stone damage by means of crystallization pressure generation. It is concluded that salt damage due to crystallization pressure appears to be largely a function of solution supersaturation ratio and location of crystallization. These key factors are related to solution properties and evaporation rates, which are constrained by solution composition, environmental conditions, substrate properties, and salt crystallization growth patterns. When combined with a critical review of salt damage literature, these experiments allow the development of a model which explains variations in damage related to combinations of different salts, substrates and environmental conditions. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

2.
Salt weathering is a significant process affecting the deterioration and conservation of stone-built heritage in many locations and environments. While much research has focused on the impact of salt weathering under arid or coastal conditions with characteristic climatic conditions and salt types, many sites found to be experiencing salt-induced deterioration, such as sandstone rock-hewn cave temples in Gansu Province, China and sandstone buildings in the northern UK, experience high humidities, moderate temperature ranges, and different salt types. To evaluate the impact of salt weathering on sandstone-built heritage under such mild humid environmental conditions, a lab simulation experiment was designed. The experiment was carried out on three types of sandstone (used in the northern UK and Gansu Province, China) and utilized a realistic diurnal humidity and temperature cycle (85% RH/16°C + 60% RH/22°C), and three widespread damaging salts, that is, Na2SO4, MgSO4, and the mixture of Na2SO4–MgSO4. The nature and extent of deterioration was monitored by photography, weight loss, and the changes in petrophysical properties measured using hardness, ultrasonic pulse velocity (P-wave velocity), water absorption coefficient by capillarity, open porosity, and apparent density. All three sandstones were found to be susceptible to MgSO4 and the mixture of Na2SO4–MgSO4, but weakly affected by Na2SO4 under mild humid environmental conditions.  相似文献   

3.
The equipment and techniques being used at Bedford College, London to simulate salt weathering processes in deserts are described in the context of a general discussion of the nature of salt weathering processes and approaches to studying them. An experiment based on the equipment and techniques is described: it is designed to test the durability of three building stones in the presence of several different saline solutions under conditions of surface temperature and relative humidity that are considered typical of hot deserts. The experiment, the first of a series, shows that Na2SO4 is the most effective of the salts used, and that susceptibility of the rocks to weathering is related to such rock properties as porosity, microporosity and water absorption capacity.  相似文献   

4.
A total of 21 different types of British and European Mesozoic limestones have been subjected to simulated salt weathering using sodium sulphate (Na2SO4) with the following aims: assessment of the relative durabilities of different types of limestone; assessment of the importance of modulus of elasticity and other factors in affecting durability; and assessment of the use of impulse excitation techniques to monitor changes in rock modulus of elasticity. The rocks showed a wide spectrum of durabilities; while rocks with high values of modulus of elasticity, lower water absorption capacities, high densities and low salt uptakes tended to be durable, there were anomalies, the explanation for which probably lies in their pore structures. Non-destructive testing techniques showed that, although the more durable rocks failed to lose weight or to show visual signs of disintegration, their modulus of elasticity values did tend to decline, indicating a loss in strength. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

5.
Mass balance studies in forested catchments in the northeastern USA show that S losses via streamwater SO42? exceed measured atmospheric S inputs. Possible sources of the excess S loss include underestimated dry deposition, mineralization of organic S in soils, desorption of soil sulphate, oxidation of recently formed sulphides and mineral weathering. Evaluating the relative contribution of these sources and processes to SO42? export is important to our understanding of S cycling as well as to policy makers in their evaluation of the efficacy of S emission controls. In order to evaluate the potential for mineral weathering contributions to SO42? export, we measured concentration and isotopic composition (δ34S and δ18O) of SO42? in stream water, and concentration and δ34S values of four S fractions in bedrock and soil parent material in catchments of varying geological composition. Geological substrates with low S concentrations were represented by catchments underlain by quartzite and granite, whereas geological substrates with high S concentrations were represented by catchments underlain by sulphidic slate, schist and metavolcanic rocks. Catchments with S‐poor bedrock had stream‐water SO42? concentrations <100 µeq L?1 and isotopic values consistent with those of atmospheric SO42? that had been cycled through the organic soil pool. Catchments with S‐rich bedrock had stream‐water SO42? concentrations ranging from 56 to 229 µeq L?1. Isotopic values deviated from those of SO42? in atmospheric deposition, clearly indicating a mineral weathering source in some cases, whereas in others spatial variability of mineral δ34S values precluded the isotopic detection of a weathering contribution. These results, along with evidence suggesting formation of secondary sulphate minerals in bedrock weathering rinds, indicate that mineral weathering may be an important source of S in the surface waters of some forested catchments in the northeastern USA. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

6.
The ion-exchange properties of terrigenous rocks have been studied, and physicochemical modeling has been used to study the formation of sulfate sodium water in the Volga–Ural Basin of the Russian Plate and the Kartalinskii Basin of the Caucasian hydrogeological folded area. Hydrogeochemical experiments have shown that the exchange-adsorption interaction between gypsum water and adsorbed Na+ of terrigenous rocks in the water–rock system involves many stages, resulting in the accumulation in solution of considerable amounts of Na2SO4 (up to 9–17 g/dm3).  相似文献   

7.
On the pumice flow deposits of the Asama volcano, Japan, many salts such as halite (NaCl), gypsum (CaSO4·2H2O), hexahydrite (MgSO4·6H2O) and mirabilite (Na2SO4·10H2O) crystallize at the base of south-facing valley cliffs. The zone of salt efflorescence and of resulting polygonal rind correspond to the zones of notch formation and high water content. The main conditions for salt crystallization and polygonal rind formation are: (1) the existence of groundwater containing a high concentration of Cl?, SO, Ca2+, Mg2+, and Na+; (2) a valley cliff material with a high capillary action and small tensile strength; and (3) low humidity and a high ground-surface temperature derived from the direct incidence of sunshine. Given the right conditions, salt weathering can occur not only in the arid regions but also in humid, temperate inland regions.  相似文献   

8.
Samples from the surface of lava flows discharged by the 2012–2013 Tolbachik Fissure Eruption were found to contain oxysulfates of copper, sodium, and potassium: K2Cu3O(SO4)2 (fedotovite), NaKCu2O(SO4)2, and Na3K5Cu8O4(SO4)8. The last two phases have no naturally occurring or synthetic analogues that we are aware of. They form flattened crystals of prismatic to long-prismatic habits. The crystals of Na3K5Cu8O4(SO4)8 have a chemical composition corresponding to the empirical formula Na2.22K5.47Cu8.02S8.05O36. An X-ray analysis of this compound showed that it has a monoclinic symmetry, P2/c, a = 13.909(4), b = 4.977(1), c = 23.525(6) Å, β = 90.021(5)°, V = 1628.3(7) Å3. The crystal structure was determined by direct techniques and refined to yield R 1 for 3955 reflexes//web// with F 2 > 4σF. The compound NaKCu2O(SO4)2 also belongs to the monoclinic system, P2/c, a = 14.111(4), b = 4.946(1), c = 23.673(6) Å, β = 92.052(6)°, V = 1651.1(8) Å3. The structure was determined by direct techniques to yield a tentative structural model that has been refined up to R 1 = 0.135 for 4088 reflexes with F 2 > 4σF. The crystal structure of Na3K5Cu8O4(SO4)8 is based on chains of [O2Cu4]4+ consisting of rib-coupled oxy-centered tetrahedrons of (OCu4)6+. The chains are surrounded by sulfate radicals, resulting in columns of {[O2Cu4](SO4)4}4? aligned along the b axis. The interchain space contains completely ordered positions of Na+ and K+ cations. The principle underlying the connection of NaKCu2O(SO4)2 columns in the crystal structure of {[O2Cu4](SO4)4}4? is different, in view of the relation Na:K = 1 as contrasted with 3:5 for the compound Na3K5Cu8O4(SO4)8. The presence of oxy-centered tetrahedrons in the structure of these new compounds furnishes an indirect hint at the importance of polynuclear copper-oxygen radicals with centering oxygen atoms as forms of transport of copper by volcanic gases.  相似文献   

9.
A laboratory simulation of salt weathering was used to ascertain the effects of sodium sulphate and sodium carbonate under ‘Negev’ conditions using a single immersion technique. Three main points were addressed: what are the grain size and textural characteristics of the debris liberated from limestones and a sandstone, what do scanning electron microscope observations of the weathered samples tell us about the decay processes involved, and how does the rate of debris liberation change during the course of 100 cycles? The grain size characteristics of the liberated debris tended to be multimodal and were related to the original petrological characteristics of the rock. Large amounts of fines were produced which are believed to be analogous to the ‘rock flour’ of arid areas. Blistering was also observed. Scanning electron microscope analysis revealed differences in the style of attack for different rock types and salt treatments, and revealed the pattern of salt crystallization in pores and the nature of cracking. The rate of debris liberation tended to decline or remain constant through time. The reasons for this remain obscure, but it is evident that diurnal cycles of temperature and humidity change can cause continuing rock weathering long after the initial input of salt to the rock has taken place.  相似文献   

10.
Pore water has been extracted from Boom Clay by mechanical squeezing. Clay cores were obtained from various boreholes, all drilled at the SCK·CEN domain (Mol, Belgium).In contrast to pore water collected from piezometers, high sulphate concentrations are measured in the squeezed pore water. The lowest sulphate concentrations (<60 mg/l) were measured in pore waters squeezed immediately after drilling. Higher sulphate concentrations were often measured in the pore water when the clay cores were preserved for some time (generally <500 mg/l SO42−, but sometimes up to 20,000 mg/l SO42−). Nevertheless, a relation between preservation time and sulphate content could not be retrieved. However, major ion concentrations were obviously correlated with the sulphate content in the squeezed waters. The observed evolution in chemical composition were explained by water–rock interactions considering the pyrite oxidation and the subsequent ion exchange and mineral dissolution reactions.  相似文献   

11.
粤东五华河流域的化学风化与CO2吸收   总被引：1，自引：1，他引：0  
基于对粤东五华河干流和支流水体的物理、化学组成测试数据,应用质量平衡法和相关分析法探讨湿热山地丘陵地区岩石化学风化过程对大气CO2的吸收.结果表明:五华河水体的总溶解性固体含量(77.11 mg/L)接近于世界河流的平均值(65 mg/L);离子组成以Ca2+、Na+和HCO3-为主,可溶性Si次之.五华河流域化学径流组成主要源自硅酸盐矿物化学风化过程的贡献,碳酸盐矿物的贡献较少;大气和土壤CO2是流域内岩石化学风化的主要侵蚀介质.与同一气候带其他河流相比较,五华河流域岩石化学风化过程对大气CO2的吸收通量(2.14×105mol/(km2·a))较低,这主要是由于流域内缺乏碳酸盐岩所导致.  相似文献   

12.
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13.
淮北临涣矿采煤沉陷区不同水体水化学特征及其影响因素   总被引：3，自引：0，他引：3  
为研究淮北临涣矿采煤沉陷区不同水体的补给水源及溶质来源,在现场调查的基础上,系统采集丰水期、平水期、枯水期沉陷区积水、地表河水和浅层地下水样进行测试分析,采用Piper三线图、Gibbs图和因子分析方法,对不同水体水化学特征及其影响因素进行讨论.结果表明:地表水水体总溶解性固体(TDS)质量浓度表现为枯水期丰水期平水期,浅层地下水表现为枯水期平水期丰水期,地表水TDS质量浓度明显高于浅层地下水.地表水中主要阴阳离子为Na~+、Cl~-和SO_4~(2-),水化学类型主要为SO_4~(2-)-Cl~--Na~+型;浅层地下水离子以HCO_3~-、Ca~(2+)和Mg~(2+)为主,表现为HCO_3~--Ca~(2+)-Mg~(2+)型.结合Gibbs图和因子分析可知,地表水受蒸发作用、地表径流以及采煤活动等因素影响,浅层地下水在一定程度上体现出大气降水和地表水补给的特点,受岩石风化作用影响较为明显.  相似文献   

14.
The factors controlling the chemistry of 69 low-order streams in the Blue Ridge and Valley and Ridge physiographic provinces of Virginia and Maryland were studied over a 13-month period. Principal component analysis was used to examine regional patterns in stream chemistry and to examine the degree to which the chemistry of low-order streams is controlled by the bedrock upon which they flow. Streams clustered into regionally isolated groups, strongly related to bedrock type, with SO2?4 and HCO?3 the chemical variables of most importance. Sulphate concentrations appear to be strongly controlled by climate and hydrology, and sorption in the soils within the watershed. Much of the atmospherically derived SO2?4 accumulates in watersheds during the growing season and is later flushed out. Weathering reactions were found to be particularly important in the production of HCO?3, accounting for 91 per cent on an annual basis, and export of divalent cations from these watersheds, accounting for 48–50 per cent on an annual basis. About half of non-anthropogenic Na+ was derived from weathering of silicates, whereas nearly all K+ was identified with leaching by SO2?4. Water chemistry was strongly related to the rock type in the watershed and the weatherability of the component minerals. Rock type is not a randomly distributed function; instead, it is controlled by geologic factors that result in clusters of similar rock types in a given region. When planning large synoptic studies, it is extremely important to consider that a sampling scheme based on random sampling of a non-randomly distributed function May, not provide the most accurate representation of the variables of interest. Instead, a hierarchical sampling scheme May, be indicated. Our results also suggest that, although one sample in time May, be sufficient to characterize the primary geochemical factors controlling stream chemistry throughout the year, it May, not be sufficient to detect subtle, flow-related alterations in chemistry.  相似文献   

15.
Solute and runoff time-series at Finsterwalderbreen, Svalbard, provide evidence for considerable basal routing of water and the existence of at least two contrasting subglacial chemical weathering environments. The hydrochemistry of a subglacial upwelling provides evidence for a snowmelt-fed subglacial reservoir that dominates bulk runoff during recession flow. High concentrations of Cl− and crustal ions, high pCO2 and ratios of [*SO2−4/(*SO2−4+HCO−3)] close to 0·5 indicate the passage of snowmelt through a subglacial weathering environment characterized by high rock:water ratios, prolonged residence times and restricted access to the atmosphere. At higher discharges, bulk runoff becomes dominated by icemelt from the lower part of the glacier that is conveyed through a chemical weathering environment characterized by low rock:water ratios, short residence times and free contact with atmospheric gases. These observations suggest that icemelt is routed via a hydrological system composed of basal/ice-marginal, englacial and supraglacial components and is directed to the glacier margins by the ice surface slope. Upwelling water flows relatively independently of icemelt to the terminus via a subglacial drainage system, possibly constituting flow through a sediment layer. Cold basal ice at the terminus forces it to take a subterranean routing in its latter stages. The existence of spatially discrete flow paths conveying icemelt and subglacial snowmelt to the terminus may be the norm for polythermal-based glaciers on Svalbard. Proglacial mixing of these components to form the bulk meltwaters gives rise to hydrochemical trends that resemble those of warm-based glaciers. These hydrochemical characteristics of bulk runoff have not been documented on any other glacier on Svalbard to date and have significance for understanding interactions between thermal regime and glacier hydrology. © 1998 John Wiley & Sons, Ltd.  相似文献   

16.
The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ34S-SO4) and oxygen (δ18O-SO4) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO3 film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO4 was not representative of the actual SO4 concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO4 in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

17.
Xiaohu Wen  Meina Diao  De Wang  Meng Gao 《水文研究》2012,26(15):2322-2332
Groundwater salinization has become a crucial environmental problem worldwide and is considered the most widespread form of groundwater contamination in the coastal zone. In this study, a hydrochemical investigation was conducted in the eastern coastal shallow aquifer of Laizhou Bay to identify the hydrochemical characteristics and the salinity of groundwater using ionic ratios, deficit or excess of each ions, saturation indices and factor analysis. The results indicate that groundwater in the study area showed wide ranges and high standard deviations for most of hydrochemical parameters and can be classified into two hydrochemical facies, Ca2+‐Mg2+‐Cl‐ facies and Na+‐Cl‐ facies. The ionic ratio, deficit or excess of each ions and SI were applied to evaluate hydrochemical processes. The results obtained indicate that the salinization processes in the coastal zones were inverse cation exchange, dissolution of calcite and dolomite, and intensive agricultural practices. Factor analysis shows that three factors were determined (Factor 1: TDS, EC, Cl‐, Mg2+, Na+, K+, Ca2+ and SO42‐; Factor 2: HCO3‐ and pH; Factor 3: NO3‐ and pH), representing the signature of seawater intrusion in the coastal zone, weathering of water–soil/rock interaction, and nitrate contamination, respectively. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

18.
Waters were sampled from 17 boreholes at Haut Glacier d'Arolla during the 1993 and 1994 ablation seasons. Three types of concentrated subglacial water were identified, based on the relative proportions of Ca2+, HCO3? and SO42? to Si. Type A waters are the most solute rich and have the lowest relative proportion of Si. They are believed to form in hydrologically inefficient areas of a distributed drainage system. Most solute is obtained from coupled sulphide oxidation and carbonate dissolution (SO–CD). It is possible that there is a subglacial source of O2, perhaps from gas bubbles released during regelation, because the high SO42? levels found (up to 1200 µeq/L) are greater than could be achieved if sulphides are oxidized by oxygen in saturated water at 0 °C (c.414 µeq/L). A more likely alternative is that sulphide is oxidized by Fe3+ in anoxic environments. If this is the case, exchange reactions involving FeIII and FeII from silicates are possible. These have the potential to generate relatively high concentrations of HCO3? with respect to SO42?. Formation of secondary weathering products, such as clays, may explain the low Si concentrations of Type A waters. Type B waters were the most frequently sampled subglacial water. They are believed to be representative of waters flowing in more efficient parts of a distributed drainage system. Residence time and reaction kinetics help determine the solute composition of these waters. The initial water–rock reactions are carbonate and silicate hydrolysis, and there is exchange of divalent cations from solution for monovalent cations held on surface exchange sites. Hydrolysis is followed by SO–CD. The SO42? concentrations usually are <414 µeq/L, although some range up to 580 µeq/L, which suggests that elements of the distributed drainage system may become anoxic. Type C waters were the most dilute, yet they were very turbid. Their chemical composition is characterized by low SO42? : HCO3? ratios and high pH. Type C waters were usually artefacts of the borehole chemical weathering environment. True Type C waters are believed to flow through sulphide‐poor basal debris, particularly in the channel marginal zone. The composition of bulk runoff was most similar to diluted Type B waters at high discharge, and was similar to a mixture of Type B and C waters at lower discharge. These observations suggest that some supraglacial meltwaters input to the bed are stored temporarily in the channel marginal zone during rising discharge and are released during declining flow. Little of the subglacial chemical weathering we infer is associated with the sequestration of atmospheric CO2. The progression of reactions is from carbonate and silicate hydrolysis, through sulphide oxidation by first oxygen and then FeIII, which drives further carbonate and silicate weathering. A crude estimate of the ratio of carbonate to silicate weathering following hydrolysis is 4 : 1. We speculate that microbial oxidation of organic carbon also may occur. Both sulphide oxidation and microbial oxidation of organic carbon are likely to drive the bed towards suboxic conditions. Hence, we believe that subglacial chemical weathering does not sequester significant quantities of atmospheric CO2 and that one of the key controls on the rate and magnitude of solute acquisition is microbial activity, which catalyses the reduction of FeIII and the oxidation of FeS2. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

19.
Continental weathering plays a dominant role in regulating the global carbon cycle, soil chemistry and nutrient supply to oceans. The CO2-mediated silicate weathering acts as a major CO2 sink, whereas sulphuric acid-mediated carbonate dissolution releases CO2 to the atmosphere–ocean system. In this study, dissolved major ions and silica concentrations of two tropical (Damodar and Subarnarekha) river systems from India have been measured to constrain the type and rate of chemical weathering for these basins. The total dissolved solids (TDS) of these rivers, a measure of total solute supply from all possible sources, are about 2–3 times higher than that of the global average for rivers. Mass balance calculations involving inverse modelling estimate that 63 ± 11% of total cations are derived from rock weathering, of which 27 ± 7% of cations are supplied through silicate weathering. The sulphide-S concentrations are estimated by comparing the water chemistry of these two rivers with that of a nearby river (Brahmani) with similar lithology but no signatures of sulphide oxidation. The outflows of Damodar and Subarnarekha rivers receive 17% and 55% of SO4 through sulphide oxidation, respectively. The sulphide oxidation fluxes from the ore mining areas, such as upper Damodar (0.52 × 109 mol/yr) and lower Subarnarekha (0.66 × 109 mol/yr) basins, are disproportionally (~9 times) higher compared to their fractional areal coverage to the global drainage area. The corresponding CO2 release rate (2.84 × 104 mol/km2/yr) for the Damodar basin is lower by five times than its CO2 uptake rate (1.38 × 105 mol/km2/yr). The outcomes of this study underscore the dominance of sulphide oxidation in controlling the dissolved chemical (cationic and sulphur) fluxes.  相似文献   

20.
Snowmelt‐fed springs and small (0.5 km2) upland catchments in alpine areas of the western United States contribute significantly to the quantity and inorganic chemistry of water delivered to downstream basins but have not been studied extensively. Mineral weathering, transit time, and hydrologic mixing control the solute chemistry of waters that drain the upland zone of Niwot Ridge, Colorado Front Range, and adjacent areas in the granitic core of the Southern Rocky Mountains. Water in 37 springs sampled in this study flows in generally short steep paths (~0.3 km) through shallow regolith with mean transit times (MTT) of weeks to months, producing solutions dominated by Si, Ca2+, Na+, and HCO3?, locally SO42?. Rock type is a significant control on spring, surface, and shallow groundwater chemistry, and plagioclase (oligoclase) is the major source of dissolved Na+ and Si. Concentrations of Ca2+ exceed stoichiometric predictions of oligoclase weathering by ~3.5×; excess Ca2+ likely represents weathering of aeolian material, vein calcite, or trace minerals. Concentrations of base cations and Si increase slowly with estimated MTT of 0.2 years for Niwot Ridge spring waters, and several years for shallow groundwater sampled by wells. Chemical weathering of silicate minerals is slow with estimated rates of ~2.0 and 0.2 pmol·m?2·s?1 for oligoclase and microcline, respectively; the most mineralized spring waters are saturated only with respect to kaolinite and montmorillonite. More than 50% of the dissolved base cations + Si measured in Boulder Creek at Orodell (~25 km downstream) accumulate before water emerges from alpine springs on Niwot Ridge. Warming global temperatures are shifting more high‐elevation precipitation to rain, potentially changing run‐off patterns, transit time, and solute loads. Acquisition of solutes by alpine waters thus has implications far beyond small upland catchments.  相似文献   

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