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1.
Temporal and spatial patterns of inherent optical properties in the Bohai Sea are very complex.In this paper,we used 77 groups of field data of AOPs(apparent optical properties) and IOPs(inherent optical properties) collected in June,August,and September of 2005 in the Bohai Sea,to retrieve the spectral total absorption coefficient a(λ) with the quasi-analytical algorithm(QAA).For QAA implementation,different bands in the region 680-730 nm(in 5 nm intervals) were selected and compared,to determine the optimal band domain of the reference wavelength.On this basis,we proposed a new algorithm(QAA-Com),a combination of QAA-685 and QAA-715,according to turbidity characterized by a(440).The percentage difference of model retrievals in the visible domain was between 4.5%-45.1%,in average of 18.8% for a(λ).The QAA model was then applied to Medium Resolution Imaging Spectrometer(MERIS) radiometric products,which were temporally and spatially matched with in-situ optical measurements.Differences between MERIS retrievals and in-situ values were in the range 9.2%-27.8% for a(λ) in the visible domain.Major errors in satellite retrieval are attributable to uncertainties of QAA model parameters and in-situ measurements,as well as imperfect atmospheric correction of MERIS data by the European Space Agency(ESA).During a storm surge in April 2009,time series of MERIS images together with the QAA model were used to analyze spatial and temporal variability of the total absorption coefficient pattern in the Bohai Sea.It is necessary to collect more independent field data to improve this algorithm.  相似文献   

2.
In-situ data from cruises in the Pearl River estuary and adjacent marine areas were collected during March to May 2001. The absorption coefficients of the water color components were studied in detail containing total suspended matter (TSM), chlorophyll-a (chl-a), colored dissolved organic matter (CDOM), and de-pigment particles. For absorption coefficient of TSM, ap, and that of de-pigment particles, ad, correlations of ap(440)-TSM, ad(440)-TSM, ap(440)-chl-a and ad-chl-a were done (the italicized term means the concentration). There was a good correlation between ap(440) and chl-a concentration. An empirical relationship model between aph(675) and chl-a was developed showing a strong correlation of 0.93. Based on the two models the chl-a and aph(λ) were correlated. The values of calculated empirical spectral slope for CDOM absorption coefficients and that of de-pigment particles, 0.017 0 and 0.011 6 respectively, both are within a relative standard error of 10.0%.  相似文献   

3.
The diffuse attenuation coefficient for downwelling irradiance （Kd（λ）） is an important parameter for ocean studies. Based on the optical profile data measured during three cruises in the northern South China Sea in autumn from 2003 to 2005, variations in the Kd（λ） spectra were analyzed. The variability of Kd（λ） shows much distinct features in both magnitude and spectra pattern, it is much higher in coastal waters than that of open oceanic waters; and the blue-to-green （443/555） ratio of Kd（λ） tends to increase with chlorophyll a concentration （[Chl-a]） from open ocean to coastal waters. These characteristics can be explained most by the increase of aw＋p（443）/aw＋p（555） with [Chl-a]. In short waveband, the relation between Kd（λ）-Kw（λ） and [Chl-a] can be well described by a power law function, indicating the large contribution of phytoplankton to the variations in Kd（λ）. As for the spectral model of the diffuse attenuation coefficient, there are good linear relationships between Kd（490） and Kd（λ） in other wavelengths with own slope and intercept of a linear functions in the spectral range 412-555 nm. Kd（490） is well correlated with the spectral ratio of remote sensing reflectance; and should enough measurement data are given, this empirical algorithm would be used in the Kd（λ） retrieval from ocean color satellite data. The variation in Kd（λ） provides much useful information for us to study the bio-optical property in the northern South China Sea.  相似文献   

4.
1 INTRODUCTION The Yellow Sea and the East China Sea are typical coastal Case-II waters with high sediment load and complicate optical properties. The total absorption coefficient of sea water is one of the main parameters influencing the calculation of o…  相似文献   

5.
Chlorophyll α（ch1-α） and suspended solid concentrations are two frequently used water quality parameters for monitoring a lake. Traditional measurement of ch1-α and suspended solids, requiring laborious laboratory work, which is often expensive and time consuming. Hyperspectral remote-sensing measurement provides a fast and easy tool for estimating water trophic status. In situ hyperspectral data on March 7-8, July 6-7, September 20 and December 7-8, 2004 and the corresponding water chemical data were used to regress the algorithm of water quality parameters. Results showed that the peak of water leaving radiance around 700 nm （R700） varied proportionally with ch1-α concentration, and moved to infrared when algal bloom occurred. The reflectance ratio of R702/R685 was well correlated with ch1-α when water surface in no algal bloom case and the correlation coefficient was better if absorption of phycocyanin was considered. The reflectance ratio R620/R531 was highly correlated to the concentration of suspended solids. The relationship between suspended solids and other band groups were also compared. Secchi disk depth could be calculated by non-linear correlation with suspended solids concentration.  相似文献   

6.
The ion-transport enzyme activities were studied in the nauplii 1–2, zoea 1–3, mysis 1–3, and postlarva 1–7 of the shrimps Marsupenaeus japonicus and Fenneropenaeus chinensis. The results showed that total ATPase, Na+-K+-ATPase, and V-ATPase (V-type H+-ATPase) activities increased during the early development for both the species, from zero in nauplii to stable levels after zoea stage. The enzyme activities of the latter species were significantly higher than those of the former species after zoea stage (F>F 0.05). The contributions of Na+-K+-ATPase, V-ATPase and HCO3 −-ATPase to the total ATPase activity of the two species varied in different developmental stages and accounted for 40%–70%, 22%–46% and 2%–13% in M. japonicus from zoea to postlarva stage, whilst the shares of them were 42%–69%, 28%–44% and 2.5%–22%, respectively in F.chinensis. These findings suggest the possible culture of the two species with varying water quality, especially the salinity and pH.  相似文献   

7.
Dilution incubations and Calanus sinicus addition incubations were simultaneously conducted at five stations in the Yellow Sea in June of 2004 to evaluate the impact of microzooplankton and Calanus sinicus on phytoplankton based on the Chlorophyll a (Chl-a) levels. The Chl-a growth rates (k) ranged from 0.60–1.67 d−1, while microzooplankton grazed the Chl-a at rates (g) of 0.29–0.62 dt-1. The addition of C. sinicus enhanced the Chl-a growth rate (Z) by 0.004–0.037 d−1 ind.−1 L. C. sinicus abundance ranged from 84.1–160.9 ind. m−3, which occupied 90.7%–99.1% of the copepod (>500 μm) population. The in-situ increase in phytoplankton by C. sinicus community was estimated to be 0.000 4–0.005 9 d−1. These results showed that microzooplankton were the main grazers of phytoplankton, while C. sinicus induced a slight increase in the levels of phytoplankton.  相似文献   

8.
This study showed that the combined effect of absorption of planktonic algae and water on water color shift can be simulated approximately by the exponential function: Log(E 100cm W +E 100cm Xch1 )=0.002λ−2.5 whereE 100 cm W ,E 100cm Xchl are, respectively, extinction coefficients of seawater and chlorophyll—a (concentration is equal toX mg/m3), and λ (nm) is wavelength. This empirical regression equation is very useful for forecasting the relation between water color and biomass in water not affected by terrigenous material. The main factor affecting water color shift in the ocean should be the absorption of blue light by planktonic algae.  相似文献   

9.
To gain a better understanding of water quality and eutrophication, we investigated the seasonal and spatial distribution of water quality at 17 stations in the Guangzhou Sea Zone (GZSZ). Nutrients, chlorophyll-a (Chl-a), salinity, chemical oxygen demand, and other physical and chemical parameters were determined in February, May, August and October from 2005 to 2007. The concentrations showed ranges of 93.2–530.4 μmol/L for dissolved inorganic nitrogen (DIN), 0.62–3.16 μmol/L for phosphate (PO4-P) and 50–127 μmol/L for silicate (SiO3-Si). The results indicated that DIN was strongly influenced by domestic sewage coming from Guangzhou City and NO3-N was the main form of DIN in most areas, while concentrations of phosphate and silicate were generally controlled by Pearl River runoff, land-based sources along the land or islands, and algae assimilation. N/P ratios were very high in both dry season and wet season, and varied from 57 to 667, suggesting that P was potentially the most limiting nutrient in the GZSZ. The concentrations of Chl-a were 3–96 μg/L, and were highly correlated with the distribution characteristics of COD. The concentrations of nutrients have increased over the past two decades (1982–2007). This means it is necessary to control the input of nutrients to the GZSZ, especially that of phosphate.  相似文献   

10.
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11.
Length-frequency data of eight commercial fish species in the Beibu Gulf (Golf of Tonkin), northern South China Sea, were collected during 2006-2007. Length-weight relationships and growth and mortality parameters were analyzed using FiSAT II software. Five species had isometric growth, two species had negative allometric growth, and one species had positive allometric growth. Overall, the exploitation rates of the eight species were lower in 2006-2007 than in 1997-1999: for four species (Saurida tumbil, Saurida undosquamis, Argyrosomus macrocephalus, and Nemipterus virgatus) it was lower in 2006-2007 than in 1997-1999, for two species (Parargyrops edita and Trichiurus haumela) it remained the same, and for the other two species (Trachurus japonicus and Decapterus maruadsi) it was higher in 2006-2007 than in 1997-1999. The exploitation rates might have declined because of the decline in fishing intensity caused by high crude oil prices. The optimum exploitation rate, estimated using Beverton-Holt dynamic pool models, indicated that although fishes in the Beibu Gulf could sustain high exploitation rates, the under-size fishes at first capture resulted in low yields. To increase the yield per recruitment, it is more effective to increase the size at first capture than to control fishing effort.  相似文献   

12.
Phytoplankton pigment patterns and community composition were investigated in the northern South China Sea using high-performance liquid chromatography and the CHEMTAX software from February 11 to 23, 2009. We recognized four different vertical distribution patterns of pigments: chlorophyll a (Chl a)-like type, divinyl chlorophyll a (DV Chl a) type, even distribution type, and surface type. The average value of ratios of accessory photo-protective pigments (APP) to accessory photo-synthetic pigments was 0.89±0.63 in the upper 50 m and 0.16±0.06 below 50 m depth. With increasing depth, APP decreased and photo-synthetically active radiation was attenuated. There was an obvious succession in the phytoplankton community from inshore to the open sea. Diatoms were dominant in the inshore region, while pelagophytes, Prochlorococcus, cyanobacteria and prymnesiophytes were dominant in the open sea. The vertical distribution of phytoplankton also differed greatly from inshore to the open sea. In the coastal and shelf region, diatoms were important components in the whole water column. Cyanobacteria also had a high abundance at the Subsurface Chlorophyll a Maxima (SCM) in the shelf region. In the slope and open sea, Prochlorococcus and cyanobacteria were important groups above the SCM, while pelagophytes dominated below the SCM.  相似文献   

13.
Two surveys were performed for determining bacteria biomass (BB), temperature, salinity, chlorophyll a (chl-a) and nutrient concentrations at 11 stations with three sampling depths in the high-incidence regions of red tide in the East China Sea (ECS) in the spring of 2006. Temperature and salinity increased from nearshore to offshore region and from high latitude to low latitude in the two cruises of 2006. BB were between 0.3–5.2 mgC m−3 (about 2.1 mgC m−3 on average) and 0.2–6.0 mgC m−3 (about 2.7 mgC m−3 on average) respectively in the two cruises. BB in the surface layer decreased from the Changjiang River estuary to high sea and from low latitude to high latitude. The results showed that bacterial growth was regulated by temperature, primary production and inorganic nutrient concentrations depending on different hydrographic conditions. In the surface and middle layers where the primary production can supply enough organic substrate, temperature was the main factor to control bacteria biomass. BB showed a good correlation between the surface and middle layers in both cruises. The distribution of nutrients during both cruises showed a similar decreasing trend from nearshore region and high latitude to offshore region and low latitude. High BB values were mainly recorded from samples in the middle layer where chl-a concentrations were also high, indicating primary production being strongly correlated with temperature over the ECS shelf. In the offshore area, phosphate and silicate became limiting factors for phytoplankton growth with indirect influence on BB. Bacteria played an important role in nitrogen regeneration process turning organic nitrogen to inorganic forms such as NH4 +. The increasing ratio of NH4 +/DIN could be a proof of that.  相似文献   

14.
A previously developed model was modified to derive three phytoplankton size classes (micro-, nano-, and pico-phytoplankton) from the overall chlorophyll-a concentration, assuming that each class has a specific absorption coefficient. The modified model performed well using in-situ data from the northern South China Sea, and the results were reliable and accurate. The relative errors of the size-fractioned chlorophyll-a concentration for each size class were: micro-: 21%, nano-: 41%, pico-: 26%, and nano+pico: 23%. The model was then applied on ocean color remote sensing data to examine the distribution and variation of phytoplankton size classes in northern South China Sea on a large scale.  相似文献   

15.
A new kinetic spectrophotometric method has been developed for the determination of trace Ni (II) in natural water.The method is based on the catalytic effect of Ni (II) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium.The concentration of nickel (II) can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ= 626 nm using the fix-time method.The influencing factors are investigated by the orthogonal experimental design.The obtained optimum analytical conditions are:pH=2.00,c RAWL=5.00×10-5 mol L-1,cKIO 4= 2.00×10-5 mol L-1,the reaction time t=10 min and the temperature T=25℃..Under the optimum conditions,the developed method allows the measurement of Ni (II) in a range of 0-40.0 ng mL-1.The standard deviation of eleven independent measurements of blank reaction is S=3.08×10-3 and the limit of detection is 2.20 ng mL-1.The relative standard deviations (RSDs) in six replicate determinations of 5 ng mL-1 and 8 ng mL-1 Ni (II) are 2.87% and 1.11%,respectively.Moreover,the experiments show few cations and anions can interfere with the measurement of Ni (II).The recovery efficiencies of this method are in a range of 97.0%-102.5% in freshwater samples.But there is a decreasing effect,which is about 0.2 times the added Ni (II) in seawater medium.After reasonable calibration this processing method is used for the determination of Ni (II) in seawater samples successfully.The results show this developed method has high accuracy and precision,high sensitivity,large range of linearity and high speed.The method can,therefore,be employed at room temperature.  相似文献   

16.
The distribution of sediment chloroplastic pigments (Chl-a, i.e. chlorophyll a and Pha-a, i.e. phaeophorbide a) in the Southern Yellow Sea of China was studied. Samples were collected from four cruises in January and June 2003, and January and June 2004. The results show that the vertical distribution of Chl-a and Pha-a in the sediment layers 0-2cm, 2-5cm and 5-8cm, follows a stable ratio, 5:3:2. The average ratio of Pha-a to Chl-a in sediment is 2.83. Spearman 2-tailed rank correlation analysis shows that Chl-a and Pha-a contents in each sediment layer have a highly significant correlation. The average contents of Chl-a and Pha-a in the sediment of the 0-8cm layer in the investigated area are 0.31 -0.47μgg-1 and 1.28-1.40 μgg-1 sediment (dry weight), respectively. The average Chl-a and Pha-a contents in sediment are higher in summer than in winter. ANOVA analysis shows that there is a highly significant variation among the Chl-a contents (P = 0.002 <0.01) of the four cruies, but this is not true for the case of Pha-a content (P = 0.766>0.05). The average Chl-a and Pha-a contents in the 2 sediment layers (0-2cm and 2-5cm) have significant or highly significant correlations with organic matter (OM), median diameter (Mdφ), silt plus clay percentage in the January 2003 cruise. In the June 2003 cruise, the average Chl-a content in the 3 sediment layers (0-2cm, 2-5cm, and 5-8cm) has a significant correlation with meiofauna biomass, and Pha-a content has highly significant correlations with water depth, bottom water temperature, OM and Mdφ The contents of Chl-a and Pha-a are lower than those in estuaries and intertidal areas, but close to those in the same area studied previously.  相似文献   

17.
Rainwater samples were collected in series in Qianliyan Island (southern Yellow Sea) and Shengsi Archipelago (East China Sea) between May 2000 and May 2002, chemical analysis for pH values,concentrations of heavy metals (Cu, Pb, Zn and Cd) and nutrients (NH4^-, NO3^-, PO43^-, SiO32^-) were performed.Results indicate that concentrations of most of the heavy metals and nutrients in rainwater show clear seasonal variation, i.e. high level in winter and low level in summer. Regionally, concentrations are higher in the southern Yellow Sea than in the East China Sea, but the annual input of heavy metals into oceans by wet deposition is similar in both stations. However, the input of nutrients by wet deposition in the East China Sea is 2-3 times higher than that in the southern Yellow Sea. In individual, Pb and PO4^3- are input to the sea mainly by dry deposition; whereas Cu, Zn, Cd and N compounds are input dominantly by wet deposition, the N/P ratios in the rainwater from two stations are much higher than those in seawater, showing a significant impact of atmospheric wet deposition on marine production and biogeochemical circulation of nutrients in these sea regions.  相似文献   

18.
A new kinetic spectrophotometric method has been developed for the determination of vanadium (V). The method is based on the catalytic effect of vanadium (V) on the oxidation of weak acid brilliant blue dye (RAWL) by KBrO3 using the citric acid as activation reagent. The obtained optimum conditions are: c (RAWL) = 1×10−4 molL−1, c (KBrO3) = 3×10−2 molL−1, c (citric acid) = 9×10−3 molL−1, pH = 2.50, the reaction time being 7.0 min and the temperature being 25.0°C. Under the optimum conditions, the proposed method allows the determination of vanadium (V) in the range of 0–70.0 ng mL−1 and the detection limit is down to 0.407 ng mL−1. For standard vanadium (V) solution determination, the recovery efficiency is in the range of 98.5%–102% and the RSD ranges from 0.76%–1.25%. Moreover, it is demonstrated that most cations and anions do not interfere with the determination of vanadium (V) under the analytical condition. The new method was successfully applied in the determination of vanadium (V) in fresh water and seawater samples with satisfactory results. Vanadium (V) in the seawater samples from Qingdao offshore was determined using the method and the distribution of vanadium (V) was mapped. Compared with other instrumental analytical methods, the proposed method shows good selectivity, sensitivity, simplicity, lower cost and rapidity. It can be employed on shipboard easily.  相似文献   

19.
Spatial distribution of phaeopigment and size-fractionated chlorophyll a (Chl a) concentrations were examined in relation to hydrographic conditions in the northern South China Sea (NSCS) during a survey from 20 August to 12 September, 2014. The total Chl a concentration varied from 0.006 to 1.488 µg/L with a mean value of 0.259±0.247 (mean±standard deviation) µg/L. Chl a concentration was generally higher in shallow water (<200 m) than in deep water (>200 m), with mean values of 0.364±0.311 µg/L and 0.206±0.192 µg/L respectively. Vertically, the maximum total Chl a concentration appeared at depths of 30–50 m and gradually decreased below 100 m. The size-fractionated Chl a concentrations of grid stations and time-series stations (SEATS and J4) were determined, with values of pico- (0.7–2 µm), nano- (2–20 µm) and micro-plankton (20–200 µm) ranging from 0.001–0.287 (0.093±0.071 µg/L), 0.004–1.149 (0.148±0.192 µg/L) and 0.001–0.208 (0.023±0.036 µg/L), respectively. Phaeopigment concentrations were determined at specific depths at ten stations, except for at station A9, and varied from 0.007 to 0.572 (0.127±0.164) µg/L. Nano-and pico-plankton were the major contributors to total phytoplankton biomass, accounting for 50.99%±15.01% and 39.30%±15.41%, respectively, whereas microplankton only accounted for 9.39%±8.66%. The results indicate that the contributions of microplankton to total Chl a biomass were less important than picoplankton or nanoplankton in the surveyed NSCS. Different sized-Chl a had similar spatial patterns, with peak values all observed in subsurface waters (30–50 m). The summer monsoon, Kuroshio waters, Zhujiang (Pearl) River plume, and hydrological conditions are speculated to be the factors controlling the abundance and spatial heterogeneity of Chl a biomass in the NSCS.  相似文献   

20.
In this study we assessed the current status of coral reefs along the Saudi Arabian coast of the Red Sea. Among the three growth forms of Acroporid corals, the branching forms were found to dominate in the Farassan Islands(44.55%±11.10% cover) followed by tabular forms in the Doga Islands(ranging between 18%±6.47% and 18.30%±9.47% cover). Digitate forms were rarely found along the coast except at Maqna. Among the five growth forms of non-Acroporid corals, we observed maximum cover of branching forms in the Yanbu offshore area(58.89%±15.11% cover) followed by the Jeddah coast(24.76%±14.04% cover). The Millepora spp., a non-Scleractinian coral, was abundant at all the near-shore sites, such as Jeddah(10.70%±8.21%) and Al-Wajh(9.81%±6.69%). The live coral cover(including both Scleractinian and non-Scleractinian corals) of Saudi Red Sea coast was seen to be higher in the north and gradually decrease towards the south. Principal Component analysis showed that the contribution of Acroporid corals was greater in the southern region than in the northern and middle regions, but vice-versa in the case of non-Acroporid corals. Bray-Curtis cluster analysis categorized all the study sites into two major clusters with 60% similarity. Among them, one cluster-forming sites from Maqna to Masturah(Northern region) and the second one comprised the middle and southern regions(Jeddah to Farassan Islands), and one outlier Rabigh.  相似文献   

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