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1.
The newly discovered Zhunuo porphyry Cu-Mo-Au deposit is located in the western part of the Gangdese porphyry copper belt in southern Tibet, SW China. The granitoid plutons in the Zhunuo region are composed of quartz diorite porphyry, diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry. The quartz diorite porphyry yielded zircon U-Pb ages of 51.9±0.7 Ma(Eocene) using LA-ICP-MS, whereas the diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry yielded ages ranging from 16.2±0.2 to 14.0±0.2 Ma(Miocene). CuMo-Au mineralization is mainly hosted in the Miocene granodiorite porphyry. Samples from all granitoid plutons have geochemical compositions consistent with high-K calc-alkaline series magmatism. The samples display highly fractionated light rare-earth element(REE) distributions and heavy REE distributions with weakly negative Eu anomalies on chondrite-normalized REE patterns. The trace element distributions exhibit positive anomalies for large-ion lithophile elements(Rb, K, U, Th and Pb) and negative anomalies for high-field-strength elements(Nb and Ti) relative to primitive mantlenormalized values. The Eocene quartz diorite porphyry yielded εNd(t) values ranging from-3.6 to-5.2,(~(87)Sr/~(86)Sr)i values in the range 0.7046–0.7063 and initial radiogenic Pb isotopic compositions with ranges of 18.599–18.657 ~(206)Pb/~(204)Pb, 15.642–15.673 ~(207)Pb/~(204)Pb and 38.956–39.199 ~(208)Pb/~(204)Pb. In contrast, the Miocene granitoid plutons yielded ε_(Nd)(t) values ranging from-6.1 to-7.3 and(87Sr/86Sr)i values in the range 0.7071–0.7078 with similar Pb isotopic compositions to the Eocene quart diorite. The Sr-Nd-Pb isotopic compositions of the rocks are consistent with formation from magma containing a component of remelted ancient crust. Zircon grains from the Eocene quartz diorite have ε_(Hf)(t) values ranging from-5.2 to +0.9 and two-stage Hf model ages ranging from 1.07 to 1.46 Ga, while zircon grains from the Miocene granitoid plutons have ε_(Hf)(t) values from-9.9 to +4.2 and two-stage Hf model ages ranging from 1.05–1.73 Ga, indicating that the ancient crustal component likely derives from Paleo- to Mesoproterozoic basement. This source is distinct from that of most porphyry Cu-Mo-Au deposits in the eastern part of the Gangdese porphyry copper belt, which likely originated from juvenile crust. We therefore consider melting of ancient crustal basement to have contributed significantly to the formation Miocene porphyry Cu-Mo-Au deposits in the western part of the Gangdese porphyry copper belt.  相似文献   

2.
The Sanchahe quartz monzonite intrusion is situated in the middle segment of the North Qinling tectonic belt, Central China mainland, and consists chiefly of sanukitoid–like and granodioritic-monzogranitic rocks. The sanukitoid–like rocks are characterized by quartz monzonites, which display higher Mg#（55.0–59.0）, and enrichments in Na2 O＋K2 O（7.28–8.94 %）, Ni（21-2312 ppm）, Cr（56-4167 ppm）, Sr（553-923 ppm）, Ba（912-1355 ppm） and LREE（（La/Yb）N =9.47–15.3）, from negative to slightly positive Eu anomalies（δEu=＋0.61 to ＋1.10）, but also depletion in Nb, Ta and Ti. The granodioritic-monzogranitic rocks diaplay various Mg#of 6.00-53.0, high Na2 O＋K2 O（7.20– 8.30%）, Sr（455–1081 ppm） and（La/Yb）N（27.6–47.8）, with positive Eu anomalies（δEu=1.03–1.57） and depleted Nb, Ta and Ti. Laser ablation inductively coupled plasma mass spectrometry（LA-ICPMS） zircon U-Pb isotopic dating reveals that the sanukitoid-like rocks were emplaced at two episodes of magmatism at 457±3 Ma and 431±2 Ma, respectively. The monzogranites were emplaced at 445±7Ma. Sanukitoid–like rocks have their εHf（t） values ranging from ＋0.3 to ＋15.1 with Hf–depleted mantle model ages of 445 to 1056 Ma, and the monzogranite shows its εHf（t） values ranging from 21.6 to ＋10.8 with Hf–depleted mantle model ages of 635 to 3183 Ma. Petrological, geochemical and zircon Lu –Hf isotopic features indicate that the magmatic precursor of sanukitoid–like rocks was derived from partial melting of the depleted mantle wedge materials that were metasomatized by fluids and melts related to subduction of oceanic slab, subsequently the sanukitoid magma ascended to crust level. This emplaced mantle magma caused partial melting of crustally metamorphosed sedimentary rocks, and mixing with the crustal magma, and suffered fractional crystallization, which lead to formations of quartz monzonites. However, the magmatic precursor of the granodioritic-monzogranitic rocks were derived from partial melting of subducted oceanic slab basalts. Integrated previous investigation for the adackitic rocks in the south of the intrusion, the Sanchahe intrusion signed that the North Qinling tectonic zone was developed in an early Paleozoic transitionally tectonic background from an island arc to back–arc.  相似文献   

3.
The Kooh-Shah region located in a Tertiary volcanic-plutonic belt of the Lut Block in eastern Iran comprises several subvolcanic intermediate to acidic intrusive rocks, diorite to syenite in composition, which have intruded into volcanic rocks. The Kooh-Shah granitoid rocks are characterized by enrichment in large ion-lithophile elements (LILE: e.g. Sr, Ba, Rb) and depletion in high field-strength elements (HFSE: e.g. Nb, Ta, Ti). The chondrite-normalized REE patterns are characterized by moderate LREE enrichment (La/Yb)N=6.01-10.01, medium-heavy REE enrichment, and absence of Eu anomalies. The Kooh-Shah intrusive rocks are metaluminous, shoshonitic with calc-alkaline affinity and high values of magnetic susceptibility, and classified as the magnetite-series of oxidant I-type granitoids. The age of Kooh-Shah granitoid rocks based on zircon U-Pb age dating is 39.7±0.7 Ma (=Middle Eocene) and the ranges of their initial 87Sr/86Sr and 143Nd/144Nd ratios are from 0.704812 to 0.704920 and 0.512579 to 0.512644, respectively, when recalculated to an age of 39 Ma. The initial ?Nd isotope values for the Kooh-Shah intrusive rocks range from -0.18 to 1.09. This geochemical data indicates that the Kooh-Shah granitoid rocks formed from depleted mantle in an island arc setting. The geochemical signature of the studied granitoid rocks represents a characteristic guide for future exploration of copper-gold porphyry-type deposits in the Lut block.  相似文献   

4.
We have determined the ages of the ore-bearing Tinggong porphyries and the Eocene granites using the LA-ICPMS zircon U-Pb method. Zircons from one adamellite porphyry and two diorite porphyries yield ages of 15.54±0.28 Ma, 15.02±0.25 Ma and 14.74±0.22 Ma, respectively. The ages of two granites are 50.48±0.71 Ma and 50.16±0.48 Ma. Light Rare Earth Elements(LREE) are enriched in the ore-bearing adamellite porphyries, which are high-K calc-alkaline and metaluminous, while Heavy Rare Earth Elements(HREE) and Y are strongly depleted, indicating an adakitic affinity. The Large Ion Lithophile Elements(LILE) of the adamellite porphyries are highly enriched, whereas some High Field Strength Elements(HFSE) are depleted. The diorite porphyry in this study is chemically similar to the adamellite porphyries, except that the Mg# of the diorite porphyry is a little higher, demonstrating more mantle contamination. Four samples from different rocks are selected for in situ zircon Hf isotopic analyses. The samples show positive εHf(t) values and young Hf model ages, indicating their derivation from juvenile crust. However, the adamellite porphyry and diorite porphyry formed in the Miocene exhibit more heterogeneous Hf isotopic ratios, with lower εHf(t) values than the granites formed in the Eocene, suggesting the involvement of old Indian continent crust in their petrogenesis. The geochronology and geochemistry of the adamellite porphyries and the diorite porphyries indicate that they formed from the same source region in a post-collisional environment, but contaminated by crust and mantle materials in different ratios. The metallic minerals formed mainly during the older adamellite porphyry stage, but they were recycled and reactivated by the diorite porphyry intrusion.  相似文献   

5.
The Zhalantun terrane from the Xing'an massif, northeast China, was used to be considered as Proterozoic basements. However, amounts of detrital zircon ages from the meta-sedimentary rocks deny the existence of Precambrian basements recently. Notably, magmatic rocks were barely reported to limit the exact ages of the Zhalantun basements. In this study, we collected rhyolite, gabbro and quartz diorite for zircon in-situ U-Pb isotopic dating, which yield crystallization ages of ～505 Ma, ～447 Ma and ～125 Ma, respectively. Muscovite schist and siltstone define maximum depositional ages of ～499 Ma and ～489 Ma, respectively. Additionally, these dated supracrustal rocks and plutons also yield ancient detrital/xenocryst zircon ages of ～600–1000 Ma, ～1600–2220 Ma, ～2400 Ma, ～2600–2860 Ma. Based on the whole-rock major and trace element compositions, the ～505 Ma rhyolites display high SiO_2 and alkaline contents, low Fe_2O_3T, TiO_2 and Al_2O_3, and relatively high Mg O and Mg#, which exhibit calc-alkaline characteristics. These rhyolites yield fractionated REE patterns and negative Nb, Ta, Ti, Sr, P and Eu anomalies and positive Zr anomalies. The geochemistry, petrology and Lu-Hf isotopes imply that rhyolites were derived from the partial melting of continental basalt induced by upwelling of sub-arc mantle magmas, and then experienced fractional crystallization of plagioclase, which points to a continental arc regime. The ～447 Ma gabbros exhibit low Si O2 and alkaline contents, high Fe2 O3 T, Ti O2, Mg O and Mg#. They show minor depletions of La and Ce, flat MREE and HREE patterns, and negative Nb, Ta, Zr and Hf anomalies. Both sub-arc mantle and N-MORB-like mantle were involved in the formation of the gabbros, indicative of a probable back-arc basin tectonic setting. Given that, the previously believed Proterozoic supracrustal rocks and several plutons from the Zhalantun Precambrian basements were proved to be Paleozoic to Mesozoic rocks, among which these Paleozoic magmatic rocks were generally related to subduction regime. So far, none Proterozoic rocks have been identified from the Zhalantun Precambrian basement, though some ～600–3210 Ma ancient detrital/xenocryst zircons were reported. Combined with ancient zircon ages and newly reported ～2.5 Ga and ～1.8 Ga granites from the south of the Zhalantun, therefore, the Precambrian rocks probably once exposed in the Zhalantun while they were re-worked and consumed during later long tectonic evolutionary history, resulting in absence of Precambrian rocks in the Zhalantun.  相似文献   

6.
This paper presents new petrographic observations and geochemical and microprobe analyses for the Laomiaojishan, Xiaotongguanshan, and Tianebaodanshan intrusions in the Tongguanshan mineral district, East China. The plutons vary in composition from quartz monzonitic diorite to pyroxene monzonitic diorite, and contain gabbroic to dioritic xenoliths. The Xiaotongguanshan intrusion yields a SHRIMP zircon U–Pb age of 139.5±2.9 Ma, indicating Late Jurassic to Early Cretaceous magmatism in the Lower Yangtze River Valley. Relative to host rocks, the gabbro and diorite xenoliths are low in SiO2 (52.03–54.61 wt‐%), Al2O3 (12.87–14.43 wt‐%), and total alkalis (Na2O+K2O; 5.26–6.30 wt‐%), but high in MgO (5.41–11.66 wt‐%); the host rocks have high SiO2 (59.97–64.44 wt‐%), Al2O3 (16.43–17.59 wt‐%), and total alkalis (6.67–8.25 wt‐%), but are low in MgO (1.52–2.50 wt‐%). Concentrations of rare earth elements (REEs) in the xenoliths (165.70–190.40 ppm) are similar to those in the host rocks (166.12–185.95 ppm), although the ratio of light REEs to heavy REEs in the xenoliths (3.39–4.27) is lower than that in the host plutons (4.86–5.94). All of the analysed rocks show similar REE patterns, although the xenoliths display marked positive Eu anomalies and the host rocks show slightly negative Eu anomalies. Values of epsilon Nd (t) ranges from ?4.9 to ?9.9 in the gabbro xenoliths and from ?11.4 to ?11.9 in the host intrusives. Initial 87Sr/86Sr ratios are 0.7064–0.7073 in the xenoliths and 0.7072–0.7084 in the quartz monzonitic diorite host rocks. Crystallization temperatures of hornblende and plagioclase in the gabbro xenoliths, diorite xenoliths, and host rocks are 816, 773–790, and 664–725°C, respectively, based on an amphibole–plagioclase geothermometer. The pressures recorded by these phases indicate that they formed at depths of 26, 12–15, and 3–4 km, respectively, based on an aluminum‐in‐hornblende geobarometer. The petrological and geochemical features of the analysed intrusions and xenoliths are consistent with their derivation from basic to intermediate‐acidic magmas that possibly formed via a series of complex interactions between underplated, mantle‐derived basaltic magma and varying amounts of middle‐ to lower‐crustal material, followed by assimilation–fractional crystallization.  相似文献   

7.
The Laocheng granitoid pluton is located in the South Qinling tectonic domain of the Qinling orogenic belt,southern Shaanxi Province,and consists chiefly of quartz diorite,granodiorite and monzogranite.A LA-ICP-MS zircon U-Pb isotopic dating,in conjunction with cathodoluminescence images,reveals that the quartz diorite and granodiorite were emplaced from 220 Ma to 216 Ma,while the monzogranite was emplaced at～210 Ma.In-situ zircon Hf isotopic analyses show that theε_(Hf)(t) values of the quartz diorite a...  相似文献   

8.
ABSTRACT

The Boein–Miandasht Complex (BMC) is a part of the Sanandaj–Sirjan metamorphic basement and is cut by gabbroic to granitoid bodies. These intrusive bodies comprise gabbro, gabbro–diorite associated with fine-grained, in part porphyritic leucocratic granitoids. Zircon U–Pb dating of representative gabbro–diorite samples yielded ages of 166.4 ± 1.8 Ma and 163.5 ± 6.3 Ma (Callovian, the latest stage of the Middle Jurassic). Mineral chemistry of the gabbro–diorites shows a homogeneous composition of the main minerals, main augite to diopside clinopyroxene and plagioclase (~An17–59). Moreover, low AlZ/TiO2 ratios of the clinopyroxene grains suggest that the rocks were generated in a within-plate tectonic regime. The SiO2 contents of the gabbro-diorite rocks are between 46.36 and 55.61 wt. %, Al2O3 ranges from 7.57 to 17.98 wt. %. The TiO2 contents vary from 1.18 to 3.65 wt. %, Fe2O3 from 7.41 to 12.95 wt. %, the MgO ranges between 3.49 and 15.75 wt. %, Na2O from 0.65 to 5.08 wt. % and K2O from 0.48 to 1.08 wt. %. These rocks mostly plot in the alkali-gabbro field. Compared to chondrite are characterized by enrichment of LREEs over HREE, enrichment of LIL elements (e.g. Rb, Sr and Ba) and obvious positive anomalies of Nb and Ti. Based on the chemical composition, and mineral composition, this complex was generated in an extensional tectonic regime by partial melting of the hot asthenospheric mantle which is not more consistent with previous models which have suggested for SaSZ evolution in before.  相似文献   

9.
We report petrologic, geochemical, and zircon U?Pb and Hf isotope data from an early Palaeozoic mafic-intermediate suite of rocks in Baluntai, heartland of the Central Tianshan. Analysed major elements of the intermediate rocks show a close affinity to metaluminous I-type granitoids, resembling arc plutons. The mafic rocks display depletions of Nb, Ta, and Ti typical of volcanic arc basalts (VAB). All of the samples fall within the subduction-related field in tectonic discrimination diagrams. Zircons from a granodiorite and a hornblende diorite yield indistinguishable crystallization ages of 475.1 ± 1.7 million years and 473.7 ± 1.6 Ma, indicating an early Palaeozoic magmatic event. Zircons in the mafic rocks yield younger crystallization ages of 427 ± 1 Ma and 426.5 ± 1.4 Ma. Combined with previous published results, our data suggest that the southward subduction of the Palaeo-Tianshan oceanic crust beneath the northern margin of the Tarim block probably began no later than Early Ordovician time and did not end prior to the middle Silurian. Zircons from the granodiorite and hornblende diorite show ?Hf(t) values of??11.19 to??5.98 and??12.85 to??6.01, respectively, suggesting the reworking of ancient crust. Correspondingly, these zircons yield two T DM2 age ranges: 2140–1812 Ma and 2241–1812 Ma, probably representing a significant episode of juvenile addition during the assembly of Columbia. In contrast, zircons from the mafic rocks yield ?Hf(t) values of 3.12–8.91 and 3.19–8.76, corresponding to the T DM1 ages ranging from 911 to 685 Ma and from 905 to 688 Ma, respectively, suggesting crustal growth in the Central Tianshan microcontinent associated with the initial break-up of Rodinia.  相似文献   

10.
Whole-rock geochemical, zircon U-Pb geochronological and Sr-Nd-Hf isotopic data are presented for the Early Cretaceous volcanic rocks from the northern Da Hinggan Mountains. The volcanic rocks generally display high SiO2(73.19–77.68 wt%) and Na2O+K2O(6.53–8.98 wt%) contents, with enrichment in Rb, Th, U, Pb and LREE, and depletion in Nb, Ta, P and Ti. Three rhyolite samples, one rhyolite porphyry sample, and one volcanic breccia sample yield weighted mean 206Pb/238 U ages of 135.1±1.2 Ma, 116.5±1.1 Ma, 121.9±1.0 Ma, 118.1±0.9 Ma and 116.9±1.4 Ma, respectively. All these rocks have moderate(87Sr/86Sr)i values of 0.704912 to 0.705896, slightly negative εNd(t) values of –1.4 to –0.1, and positive εHf(t) values of 3.7 to 8. Their zircon Hf and whole-rock Nd isotopic model ages range from 594 to 1024 Ma. These results suggest that the Early Cretaceous volcanic rocks were originated from melting of subducted oceanic crust and associated sediments during the closure of the Mongol-Okhotsk Ocean.  相似文献   

11.
The Yangchang granite‐hosted Mo deposit is typical of the Xilamulun metallogenic belt, which is one of the important Mo–Pb–Zn–Ag producers in China. A combination of major and trace element, Sr, Nd and Pb isotope, and zircon U–Pb age data are reported for the Yangchang batholith to constrain its petrogenesis and Mo mineralization. Zircon LA‐ICPMS U–Pb dating yields mean ages of 138 ± 2 and 132 ± 2 Ma for monzogranite and granite porphyry, respectively. The monzogranites and granite porphyries are calc‐alkaline with K2O/Na2O ratios of 0.75–0.92 and 1.75–4.42, respectively. They are all enriched in large‐ion lithophile elements (LILEs) and depleted in high‐field‐strength elements (HFSEs) with negative Nb and Ta anomalies in primitive‐mantle‐normalized trace element diagrams. The monzogranites have relatively high Sr (380–499 ppm) and Y (14–18 ppm) concentrations, and the granite porphyries have lower Sr (31–71 ppm) and Y (5–11 ppm) concentrations than those of monzogranites. The monzogranites and granite porphyries have relatively low initial Sr isotope ratios of 0.704573–0.705627 and 0.704281, respectively, and similar 206Pb/204Pb ratios of 18.75–18.98 and 18.48–18.71, respectively. In contrast, the εNd(t) value (−3.7) of granite porphyry is lower than those of monzogranites (−1.5 to −2.7) with Nd model ages of about 1.0 Ga. These geochemical features suggest that the monzogranite and granite porphyries were derived from juvenile crustal rocks related to subduction of the Paleo‐Pacific plate under east China. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

12.
Late Mesozoic volcanic-subvolcanic rocks and related iron deposits, known as porphyry iron deposits in China, are widespread in the Ningwu ore district (Cretaceous basin) of the middle–lower Yangtze River polymetallic ore belt, East China. Two types of Late Mesozoic magmatic rocks are exposed: one is dioritic rocks closely related to iron mineralization as the hosted rock, and the other one is granodioritic (-granitic) rocks that cut the ore bodies. To understand the age of the iron mineralization and the ore-forming event, detailed zircon U-Pb dating and Hf isotope measurement were performed on granodioritic stocks in the Washan, Gaocun-Nanshan, Dongshan and Heshangqiao iron deposits in the basin. Four emplacement and crystallization (typically for zircons) ages of granodioritic rocks were measured as 126.1±0.5 Ma, 126.8±0.5 Ma, 127.3±0.5 Ma and 126.3±0.4 Ma, respectively in these four deposits, with the LA-MC-ICP-MS zircon U-Pb method. Based on the above results combined with previous dating, it is inferred that the iron deposits in the Ningwu Cretaceous basin occurred in a very short period of 131–127 Ma. In situ zircon Hf compositions of εHf(t) of the granodiorite are mainly from ?3 to ?8 and their corresponding 176Hf/177Hf ratio are from 0.28245 to 0.28265, indicating similar characteristics of dioritic rocks in the basin. We infer that granodioritic rocks occurring in the Ningwu ore district have an original relationship with dioritic rocks. These new results provide significant evidence for further study of this ore district so as to understand the ore-forming event in the study area.  相似文献   

13.
板山坪岩体是北秦岭二郎坪群中的侵入岩。为了查明该岩体的成因,对该岩体进行了锆石U-Pb年代学、锆石原位Hf同位素研究以及矿物化学分析等方面的研究。研究结果表明,板山坪岩体岩性组成主要为石英闪长岩和花岗闪长岩,花岗闪长岩内部存在暗色包体。本次研究获得板山坪石英闪长岩锆石U-Pb年龄为442.7～432.2 Ma,花岗闪长岩锆石U-Pb年龄为436.8～432.7 Ma,暗色包体锆石U-Pb年龄为437.6 Ma。锆石176Hf/177Hf值为0.282 737～0.282 736,εHf（t）值集中分布在8.4～9.4之间,二阶段Hf模式年龄（TDM2）在876～832 Ma之间。石英闪长岩结晶温压分别为673 ℃～745 ℃和0.19～0.54 GPa,花岗闪长岩结晶温压分别为657 ℃～730 ℃和0.48～0.96 GPa,暗色包体结晶温压分别为680 ℃～734 ℃和0.69～1.65 GPa。综合分析认为板山坪岩体为复式岩体,两期结晶年龄分别为496～487 Ma和442～432 Ma。岩石来源于地幔分离出来的新生下地壳。  相似文献   

14.
In this paper we present new zircon U–Pb ages, whole-rock major and trace element analyses, and zircon Hf isotopic data for magmatic rocks in the Tuotuohe region of the western segment of the Jinshajiang suture. Our aim is to constrain the Early Permian–Late Triassic tectonic evolution of the region. Zircons from the magmatic rocks of the Tuotuohe region are euhedral–subhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios(0.4–4.6), indicating a magmatic origin. The zircon U–Pb ages obtained using LA–ICP–MS are 281 ± 1 Ma, 258 ± 1 Ma, 244 ± 1 Ma, and 216 ± 1 Ma, which indicate magmatism in the Early Permian–Late Triassic. A diorite from Bashihubei(BSHN) has SiO2 = 57.18–59.97 wt%, Al2O3 = 15.70–16.53 wt%, and total alkalis(Na2O + K2O) = 4.46–6.34 wt%, typical of calc-alkaline and metaluminous series. A gabbro from Bashibadaoban(BSBDB) belongs to the alkaline series, and is poor in SiO2(45.46–54.03 wt%) but rich in Al2O3(16.19–17.39 wt%) and total alkalis(Na2O + K2O = 5.48–6.26 wt%). The BSHN diorite and the BSBDB gabbro both display an enrichment of LREEs and LILEs and depletion of HFSEs, and they have no obvious Eu anomaly; they have relatively low MgO contents(2.54–4.93 wt%), Mg# values of 43 to 52, and low Cr and Ni contents(8.07–33.6 ppm and 4.41–14.2 ppm, respectively), indicating they differentiated from primitive mantle magmas. They have low Nb/U, Ta/U, and Ce/Pb ratios(1.3–9.6, 0.2–0.8, and 0.1–18.1, respectively), and their initial Hf isotopic ratios range from +9.6 to +16.9(BSHN diorite) and +6.5 to +12.6(BSBDB gabbro), suggesting their primary magmas were derived mainly from the partial melting of a mantle wedge that had been metasomatized by subduction fluids. Taking all the new data together, we conclude that the western and eastern segment of the Jinshajiang suture regions underwent identical processes of evolution in the Early Permian–Late Triassic: oceanic crust subduction before the Early Permian, continental collision during the Early–Middle Triassic, and post-collisional extension from the Late Triassic.  相似文献   

15.
锡矿往往与长英质岩浆岩伴生,然而锡矿形成的热能源区尚不清楚,其可能与地幔物质相关。我国云南锡矿带中出露的中-酸性岩石及碱性岩杂岩体为研究锡矿及其周围岩浆成因提供了良好的物质条件。本文报道了云南个旧地区代表性的花岗岩、辉长-闪长岩和碱性岩类新的全岩地球化学、锆石U-Pb年代学和Hf同位素数据。LA-ICP-MS锆石U-Pb定年表明上述岩石分别形成于81.43±0.46Ma(82.89±0.58M)、81.35±0.22Ma和80.35±0.72Ma,指示它们为晚白垩世近同期岩浆活动的产物。其中闪长岩、碱性岩和花岗岩中锆石的Hf同位素组成不均一,ε_(Hf)(t)分别为-4.2~+0.8、-7.5~-1.9和-8.4~+0.4。尽管这些岩体的侵入时代一致,但它们的地球化学特征和同位素特征存在差异,表明这三类火成岩来自不同的岩浆源区,三者不是同一母岩浆相互演化的关系。个旧杂岩体中花岗岩为弱过铝质岩石,SiO_2与P_2O_5含量呈负相关的关系,排除S型花岗岩的可能。亏损Zr、Nb、Sr、Eu等大离子亲石元素的特征可能为锆石、磷灰石、长石类造岩矿物分离结晶作用的结果;Zr、Nb、Ce和Y总量较低,低的FeOT/MgO比值和低的锆石饱和温度表明,指示出个旧地区的花岗岩应为高分异I型花岗质岩石而非A型花岗岩。个旧地区形成于晚白垩世时期的中基性、碱性岩石可能为不同的幔源岩浆近同时侵入的产物,底侵的幔源熔体带来热量诱发中、下地壳岩石发生部分熔融形成含矿的花岗岩,幔源岩浆对于成矿至少在能量也可能在成矿物质上有重要的贡献。  相似文献   

16.
相鹏  崔敏利  吴华英  张晓静  张连昌 《岩石学报》2012,28(11):3655-3669
河北滦平县周台子铁矿位于华北克拉通北缘,是产于前寒武纪单塔子群变质岩系中的鞍山式铁矿,具有条带状铁建造(BIF)特征。矿石主要呈条带状构造,有的呈条纹和致密块状构造。矿石类型主要以石英磁铁矿型为主,含铁介于30%~35%。前寒武纪变质岩是矿床的主要围岩,出露有黑云母(角闪)斜长片麻岩和斜长角闪岩,局部见花岗片麻岩。原岩恢复表明,黑云母(角闪)斜长片麻岩的原岩为英安岩-流纹岩,斜长角闪岩原岩为玄武岩。花岗片麻岩的SiO2含量大于56%,MgO含量小于3%,Al2O3含量大于15%,Sr含量大于500×10-6,Yb含量均小于1.9×10-6,轻重稀土元素分异明显,重稀土元素强烈亏损,并且Eu负异常不明显,表明该片麻岩具埃达克质岩石的地球化学特征。锆石U-Pb定年结果显示出几组年龄,分别是2512±21Ma, 2452±9.6Ma,2394±55Ma。大体看,2512Ma代表了火山喷发和周台子铁矿BIF沉淀年龄,2452Ma左右的锆石年龄代表了TTG质花岗片麻岩的侵位结晶年龄,2394Ma锆石年龄代表了周台子铁矿经历了一次变质作用,并对原有的岩石和矿石进行了改造。锆石Hf同位素特征显示斜长角闪岩和TTG质片麻岩的岩浆源区受到过古老地壳物质的混染。周台子铁矿构造环境可能是与裂谷有关的张性环境。  相似文献   

17.
The Aqishan-Yamansu belt in the Eastern Tianshan (NW China) contains many intermediate to felsic intrusive rocks and spatially and temporally associated Fe (-Cu) deposits. Zircon U-Pb dating of the Bailingshan granitoids, including diorite enclaves (in granodiorite), diorite, monzogranite and granodiorite, and andesitic tuff from the Shuanglong Fe-Cu deposit area yielded ages of 329.3 ± 2.1 Ma, 323.4 ± 2.6 Ma, 313.0 ± 2.0 Ma, 307.5 ± 1.7 Ma and 318.0 ± 2.0 Ma, respectively. These new ages, in combination with published data can be used to subdivide magmatism of the Bailingshan intrusive complex into three phases at ca. 329–323 Ma, ca. 318–313 Ma and ca. 308–297 Ma. Of the analyzed rocks of this study, the Shuanglong diorite enclave, diorite and andesitic tuff show calc-alkaline affinities, exhibiting LILE enrichment and HFSE depletion, with negative Nb and Ta anomalies. They have high MgO contents and Mg# values, with depleted εHf(t) and positive εNd(t) values, similar crustal-derived Nb/Ta and Y/Nb ratios, low Th/Yb and Th/Nb, and high Ba/La ratios, which are consistent with them being sourced from a depleted mantle wedge metasomatized by slab-derived fluids and crustal contamination. However, the monzogranite and granodiorite are metaluminous with characteristics of low- to high-K calc-alkaline I-type granites. The granitic rocks are enriched in LILE, depleted in HFSE and have significant Eu anomalies, with high Y contents and low Sr/Y ratios, resembling typical of normal arc magmas. Depleted εHf(t) and positive εNd(t) values with corresponding young TDMC ages of zircons, as well as Nb/Ta, Y/Nb, Th/U and La/Yb ratios suggest that the granitic rocks were probably formed by re-melting of juvenile lower crust or pre-existing mantle-derived mafic–intermediate igneous rocks. Integrating published data, we conclude that the Bailingshan granitoids (excluding the Shuanglong diorite and diorite enclave) were derived from re-melting of juvenile lower crust and mantle-derived mafic–intermediate igneous rocks, with mantle components playing a more prominent role in the formation of the younger and more felsic rocks. A comprehensive review, including our new data, suggests that the Aqishan-Yamansu belt formed as a fore-arc basin during the Carboniferous (ca. 350–300 Ma) when the Kangguer oceanic slab subducted beneath the Yili-Central Tianshan block. The ongoing southward subduction of the slab resulted in the closure of the Aqishan-Yamansu fore-arc basin (ca. 320–300 Ma), due to slab steepening and rollback followed by slab breakoff and rebound. During the Aqishan-Yamansu fore-arc basin inversion, the main phase of the Bailingshan granitoids emplaced in the Aqishan-Yamansu belt, accompanied by contemporary Fe and Fe-Cu mineralization.  相似文献   

18.
Garnet–clinopyroxene ultra‐high‐pressure (UHP) rocks from the northern Bohemian Massif contain zircon with micro‐diamond inclusions. Trace element concentrations, oxygen and hafnium isotopic composition and U–Pb age of distinct textural domains in zircon characterize their growth conditions and temporal evolution. Diamond‐bearing zircon mantle domains with relicts of oscillatory zoning have uniform Th/U ratios (~0.1–0.2), high‐Ti contents (110–190 ppm, corresponding to temperatures of at least 1100 °C), and some (two of 17 mantle analyses) preserve steep heavy rare earth element (HREE) patterns with YbN/GdN = 10–11, with a weak negative Eu anomaly. These signatures are consistent with crystallization from a melt under UHP/ultra‐high‐temperature (UHT) conditions. Some of the bright‐cathodoluminscence (CL) rims preserve Th/U and Ti values characteristic of the zircon mantles, but others show elevated Th/U ratios of ~0.3–0.4 and lower Ti contents (20–40 ppm; only 13 ppm in a rare low‐CL outer rim). As they feature flat HREE patterns and negative Eu anomalies and commonly make embayments and truncate the mantle zoning, we suggest that they have formed through recrystallization in the solid state during exhumation of the rock, when both garnet and plagioclase were stable. The three zircon domains, that is, cores, mantles and rims, yield U–Pb concordia ages of 340.9 ± 1.5, 340.3 ± 1.5 and 341.2 ± 3.4 Ma respectively. When linked to the previously reconstructed P–T path of the rock, the error limits of the zircon mantle and rim ages constrain the exhumation of the rocks from depth of ~140 km (UHP) to ~80 km (HP) to a minimum rate of 1.5 cm yr?1. The zircon cores are heterogeneous in terms of Th/U ratio (below 0.1 but also above 0.2) and REE characteristics, and their εHf values scatter between ?15.7 and +4.8 with similar values for individual domains within a single zircon grain suggesting a very localized control on hafnium isotope composition on a grain scale. The non‐equilibrated εHf values as well as a large range of the Hf‐depleted mantle model ages possibly reflect the presence of a heterogeneous population of old zircon. Consequently, the uniform and young 238U/206Pb ages may represent (near‐)complete resetting of the U–Pb geochronometer during the UHP–UHT event at c. 340 Ma through dissolution–reprecipitation process. In contrast to Hf, the oxygen isotope composition of zircon is homogeneous, ranging between 7.8‰ and 9.6‰ VSMOW, reflecting a source containing upper crustal material and homogenization at UHP–UHT conditions. Our study documents that continental crust was subducted to mantle depths at c. 340 Ma during the Variscan orogeny and was subsequently very rapidly exhumed, implying that the sequence of events was faster than can be resolved by the secondary ion mass spectrometry technique.  相似文献   

19.
Both oceanic and continental HP rocks are juxtaposed in the Huwan shear zone in the western Dabie orogen, and thus provide a window for testing the buoyancy‐driven exhumation of dense oceanic HP rocks. The HP metamorphic age of the continental rocks in this zone has not been well constrained, and hence it is not known if they are of the same age as the exhumation of the HP oceanic rocks. In situ laser ablation (multiple collector) inductively coupled plasma mass spectrometry (LA‐(MC‐)ICP‐MS), U–Pb, trace element and Hf isotope analyses were made on zircon in a granitic gneiss and two eclogites from the Huwan shear zone. U–Pb age and trace element analysis of residual magmatic zircon in an eclogite constrain its protolith formation at 411 ± 4 Ma. The zircon in this sample displays εHf (t) values of +6.1 to +14.4. The positive εHf (t) values up to +14.4 suggest that the protolith was derived from a relatively depleted mantle source, most likely Palaeotethyan oceanic crust. A granitic gneiss and the other eclogite yield protolith U–Pb ages of 738 ± 6 and 700 ± 14 Ma, respectively, which are both the Neoproterozoic basement rocks of the Yangtze Block. The zircon in the granitic gneiss has low εHf (t) values of ?14.2 to ?10.5 and old TDM2 ages of 2528–2298 Ma, suggesting reworking of Palaeoproterozoic crust during the Neoproterozoic. The zircon in the eclogite has εHf (t) values of ?1.0 to +7.4 and TDM1 ages of 1294–966 Ma, implying prompt reworking of juvenile crust during its protolith formation. Metamorphic zircon in both eclogite samples displays low Th/U ratios, trace element concentrations, relatively flat heavy rare earth element patterns, weak negative Eu anomalies and low 176Lu/177Hf ratios. All these features suggest that the metamorphic zircon formed in the presence of garnet but in the absence of feldspar, and thus under eclogite facies conditions. The metamorphic zircon yields U–Pb ages of 310 ± 3 and 306 ± 7 Ma. Therefore, both the oceanic‐ and continental‐type eclogites share the same episode of Carboniferous eclogite facies metamorphism. This suggests that high‐pressure continental‐type metamorphic rocks might have played a key role in the exhumation and preservation of oceanic‐type eclogites through buoyancy‐driven uplift.  相似文献   

20.
《International Geology Review》2012,54(15):1941-1958
The Qiarbahete complex in NW China consists of gabbroic diorite, granodiorite, and late-stage quartz diorite porphyry veins. Zircon sensitive high-resolution ion microprobe (SHRIMP) U–Pb analyses show that the gabbroic diorite and granodiorite formed at 368 ± 5.2 Ma and 354 ± 4.1 Ma, respectively, indicating that the complex was emplaced in the Late Devonian–Early Carboniferous. The gabbroic diorites, characteristic of Sanukitoids, exhibit high Mg# (62 average), MgO (6.84% average), Cr (195 ppm average), and Ni (61.4 ppm average) contents. The rocks show moderately fractionated rare earth element (REEs) patterns and weak negative Eu anomalies (δEu: 0.83–0.89), enrichment of large ion lithophile elements (LILEs), and depletion of high field strength elements (HFSEs), with low ?Nd(t) values (1.46–1.73). The gabbroic diorites originated from partial melting of a hydrous mantle wedge followed by assimilation of crust during ascent. The granodiorites show a geochemical affinity with adakitic rocks, e.g. SiO2 (64.95–67.87%) > 56%, Al2O3 (15.88–16.56%) > 15%, MgO (1.79–2.31%) < 3%, Sr (315–375 ppm) > 300 ppm, and Yb (1.84–2.06 ppm). They are enriched in light rare earth elements (LREEs) and LILEs and depleted in HFSEs, with weak negative Eu anomalies (δEu: 0.78–0.87). The granodiorites were mainly derived by the partial melting of a subducted oceanic slab, followed by subsequent melt–mantle interaction and crustal rocks contamination. All these indicate that the Qiarbahete complex was emplaced in a continental arc setting attending the southward subduction of the Junggar Ocean during the Late Devonian–early Carboniferous, generating the lateral accretion of continental crust in NW Tianshan.  相似文献   

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