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1.
Xenon isotopic data were acquired by high resolution step pyrolysis and combined step pyrolysis/combustion of aliquots of size separated nanodiamonds. 129Xe excess (129Xe*) from in situ decay of 129I is preferentially associated with the larger grain size separates. This observation rules out trapping by recoil from surrounding material. The releases of Xe-P3 and 129Xe occur in the same low temperature pyrolysis steps and exhibit similar distributions among the size separates. These observations imply a common site for the components and, in consequence, suggest a common incorporation event.Whether one component or two, our observations require that 129Xe* and Xe-P3 were incorporated into a subpopulation of nanodiamonds before nanodiamonds were mixed and incorporated into parent bodies. Their susceptibilities to loss during heating in the laboratory are similar, but the ratio of 129Xe* to Xe-P3 varies among nanodiamond separates from different meteorites (literature data). We conclude that the 129Xe* we observe today was present as 129I during parent body processing. Furthermore, the range of 129Xe*/132XeP3 ratios across all the separates requires that even nanodiamonds from CI chondrites were at least 5-10× more rich in Xe-P3 during 129I decay than they are today.We present a simple model involving one degassing event per parent body between incorporation of nanodiamonds and final decay of 129I. The observed variations among parent bodies require degassing events separated by several 129I half lives (∼50Ma), consistent with low-temperature processing on parent bodies but longer than expected for nebular processing. In this model, nanodiamonds from ALHA77307 degassed at an unusually early stage, suggesting they alone may retain the signature of processing in the nebula in their P3 and 129Xe* abundances.The isotopic signature associated with Xe-P6 is also found only in the larger size separates. Concentration of Xe-HL increases with increasing grain size, but its relative abundance with respect to Xe-P3 and P6 is higher in smaller grain-size fractions. We argue that Xe-P6 is best seen as a variant of Xe-HL, and that they are both mixtures of a “normal” component akin to solar xenon and a slightly variable exotic component. We show that both current models of Xe-H formation can account for the observed variability, and propose a scenario according to which Xe-HL and P6 were implanted into separate diamond populations before incorporation of Xe-P3 and 129I.  相似文献   

2.
The release kinetics of Xe of the isotopically normal component of noble gases (P3 component) from the coarse-grained fraction of nanodiamonds from the Orgueil (CI) meteorite and the kinetics of 4He release from lunar soil were studied by means of a numerical simulation. It is demonstrated that the release of these gases as a peak with a single pronounced maximum may not correspond to the diffusion model with a single activation energy and can in fact be controlled by a spectrum of activation energies with a number of peaks a number of peaks remaining unresolved at stepped pyrolysis. In particular, the amount of Xe-P3 preserved in nanodiamonds during thermal metamorphism of the Orgueil meteorite calculated using parameters of the diffusion process (activation energy and frequency factor) that were determined in the model with a single activation energy indicates that practically all Xe should be lost during a very short time. These losses are inconsistent with both the duration of thermal metamorphism of the meteorite parent bodies and the Xe-P3 concentrations measured in these meteorites. A much higher preservation of Xe-P3 during thermal metamorphism lasting for hundreds of years follows from calculations based on diffusion with a spectrum of activation energiesa for Xe release. The results of isothermal pyrolysis of a nanodiamonds fraction from Orgueil confirms a presence of several activation energies for Xe-P3 release from the nanodiamonds. The application of the diffusion model with a spectrum of activation energies to He release from lunar soil samples also shows that He can be retained in these samples at 20°C during a much longer time than it follows from the model with a single activation energy (Anufriev, 2010).  相似文献   

3.
Analysis of noble gas proportions and their release kinetics during stepped pyrolysis and oxidation of meteoritic nanodiamonds, as well as their core-shell structure led to the following conclusions: (1) Noble gases of HL component with anomalous isotopic composition were presumably formed prior to implantation in the nanodiamonds owing to mixing of nucleosynthetic products of p- and r- process associated with explosion of type-II supernova with noble gases having “normal” isotopic composition; (2) isotopically normal P3 noble gases in the nanodiamonds grains are confined to the nondiamond (for instance, graphite-like) phase in the surface layer. The “layer” structure of nanodiamonds grains resulted from heating up to 800–900°C. Observed increase in contents of P3 noble gases with increasing grain sizes of meteoritic nanodiamonds is caused by the dependence of the degree of graphitization of the superfical layer at given temperature on the grain size and surface defect density; (3) bimodal release of noble gases during pyrolysis of the meteoritic nanodiamonds from weakly metamorphosed meteorites was caused by P3 and HL components, which are comparable in abundance but sharply differ in their release temperature.  相似文献   

4.
In this contribution, we considered the character of carbon nanoparticle formation in the cosmos and during volcanic eruptions of a certain type and compared it with existing methods of synthesis in nanotechnology. Using the methods of electron diffraction and Raman spectroscopy, we investigated nanodiamond samples synthesized by hydrodynamic cavitation in various hydrocarbon liquids. Different forms of nanometer-sized carbon were distinguished, including complex fullerenes, nanodiamonds, and a face-centered cubic (fcc) carbon phase. The synthesized nanodiamonds were doped with silicon, their photoluminescence spectra were analyzed, and application of the results for geochemistry and cosmochemistry were discussed.  相似文献   

5.
Rock fragments from the deepest parts of a buried hydrothermal system belonging to the Mesozoic Tethys Ocean entered as xenoliths in a Miocenic diatreme,hence brought to the surface,in the Hyblean Plateau(Sicily).Some xenoliths consist of strongly serpentinized ultramafic rocks bearing blebs of abiotic organic matter,where clusters of amorphous carbon nanoparticles,including nanodiamonds,are immersed.Such an occurrence conjures up established hypotheses that diamond surfaces are suitable catalytic platforms stimulating the assemblage of complex bio-organic molecules relevant to the emergence of life on Earth.The appearance of bio-organic molecules under primitive Earth conditions is one of the major unsolved questions on the origin of life.Here we report new micro-Raman spectra on blebs of abiotic organic matter from a selected xenolith.Diamond bands were related to hydrogenated nanocrystalline diamonds,with size of nearly 1-1.6 nm,formed from organics at low pressures and temperatures.In particular,diamond surfaces can give rise to crystalline interfacial water layers that may have played a fundamental role in the early biosphere evolution as a good medium for rapidly transporting positive charges in the form of hydrated protons.Nowadays,proton gradients in alkaline hydrothermal vents along oceanic ridges are generally viewed as key pre-biotic factors.In general,serpentinites span the entire geological record,including prebiotic times.These hydrous ultramafic rocks often display evidence of abiotic carbon species,both organic and inorganic,including nanodiamonds,being also capable to give rise to chemiosmotic processes and proton gradients necessary to the organisms,such as the"Last Universal Common Ancestor"(LUCA),in the prebiotic Earth.  相似文献   

6.
The results of spectroscopic and structural studies of phase composition and defects in nanodiamonds from Efremovka (CV3) and Orgueil (CI) chondrites indicate that nitrogen atomic environment in meteoritic nanodiamonds (MND) is similar to that observed in synthetic counterparts produced by detonation and by the Chemical Vapor Deposition (CVD)-process. Most of the nitrogen in MND appears to be confined to lattice imperfections, such as crystallite/twin boundaries and other extended defects, while the concentration of nitrogen in the MND lattice is low. It is suggested that the N-rich sub-population of MND grains may have been formed with high growth rates in environments rich in accessible N (i.e., N in atomic form or as weakly bonded compounds). For the first time the silicon-vacancy complex (the “silicon” defect) is observed in MND by photoluminescence spectroscopy.  相似文献   

7.
Scour holes often form in shallow flows over sand on the beach and in morphodynamic scale experiments of river reaches, deltas and estuarine landscapes. The scour holes are on average 2 cm deep and 5 cm long, regardless of the flow depth and appear to occur under similar conditions as current ripples: at low boundary Reynolds numbers, in fine sand and under relatively low sediment mobility. In landscape experiments, where the flow is only about 1 cm deep, such scours may be unrealistically large and have unnatural effects on channel formation, bar pattern and stratigraphy. This study tests the hypotheses that both scours and ripples occur in the same conditions and that the roughness added by sediment saltation explains the difference between the ripple–dune transition and the clear‐water hydraulic smooth to rough transition. About 500 experiments are presented with a range of sediment types, sediment mobility and obstructions to provoke scour holes, or removal thereof to assess scour hole persistence. Most experiments confirm that ripples and scour holes both form in the ripple stability field in two different bedform stability diagrams. The experiments also show that scours can be provoked by perturbations even below generalized sediment motion. Moreover, the hydraulic smooth to rough transition modified with saltation roughness depending on sediment mobility was similar in magnitude and in slope to ripple–dune transitions. Given uncertainties in saltation relations, the smooth to rough transitions modified for movable beds are empirically equivalent to the ripple–dune transitions. These results are in agreement with the hypothesis that scours form by turbulence caused by localized flow separation under low boundary Reynolds numbers, and do not form under generalized flow separation over coarser particles and intense sediment saltation. Furthermore, this suggests that ripples are a superposition of two independent forms: periodic bedforms occurring in smooth and rough conditions plus aperiodic scours occurring only in hydraulic smooth conditions.  相似文献   

8.
《地学前缘(英文版)》2018,9(6):1849-1858
There are four main types of natural diamonds and related formation processes. The first type comprises the interstellar nanodiamond particles. The second group includes crustal nano-and micron-scale diamonds associated with coals, sediments and metamorphic rocks. The third one includes nanodiamonds and microndiamonds associated with secondary alteration and replacing of mafic and ultramafic rocks.The fourth one includes macro-, micron-and nano-sized mantle diamonds which are associated with kimberlites, mantle peridotites and eclogites. Each diamond type has its specific characteristics. Nanosized diamond particles of lowest nanometers in size crystallize from abiotic organic matter at lower pressures and temperatures in space during the stages of protoplanetary disk formation. Nano-sized diamonds are formed from organic matter at P-T exceeding conditions of catagenesis stage of lithogenesis. Micron-sized diamonds are formed from fluids at P-T exceeding supercritical water stability.Macrosized diamonds are formed from metal-carbon and silicate-carbonate melts and fluids at P-T exceeding 1150℃ and 4.5 GPa. Nitrogen and hydrocarbons play an important role in diamond formation.Their role in the formation processes increases from macro-sized to nano-sized diamond particles.Introduction of nitrogen atoms into the diamond structure leads to the stabilization of micron-and nanosized diamonds in the field of graphite stability.  相似文献   

9.
该区枯水径流分析和预测可用自回归模型进行。从自相关系数及枯水径流形成的条件,可将该区分为五个类型区。在自相关系数高、多年变化小的地区应用灰色残差模型预测枯水径流量能保证一定精度而又较简便。  相似文献   

10.
The origin of large subsidence in intracratonic basins is still under debate. We propose a new and self‐consistent model for the formation of those basins, where lithospheric shortening/buckling triggers metamorphism and densification of crustal mafic heterogeneities. We use a forward thermo‐mechanical finite element technique to evaluate this mechanism for the typical example of the East Barents Sea basin (EBB) where a very large and compensated subsidence, accommodating an up to 20‐km‐thick sediment succession, is observed. The lower crust in the dynamic model is modelled with petrologic‐consistent densities for a wet mafic gabbroic composition that depend on pressure and temperature taking into account dehydration at high PT conditions. The model successfully explains the main characteristics of the EBB, notably the large anomalous and fast subsidence during the Late Permian–Early Triassic, its present‐day geometry and the absence of a significant gravity anomaly.  相似文献   

11.
The analysis of excess 129Xe in meteoritic nanodiamonds and the kinetics of its release during stepwise pyrolysis allow to suggest that (1) in the solar nebula 129I atoms were adsorbed onto nanodiamond grains and (or) chemisorbed by forming covalent bonds with carbon atoms. Most 129I atoms existed in a surface connected state, but a minor amount of them was in nanopores of the grains. At radioactive decay of 129I the formed 129Xe (129Xe∗) was trapped by diamond grains due to nuclear recoil. (2) During thermal metamorphism or aqueous alteration, the surface-sited 129I atoms were basically lost. On the basis of these assumptions and calculated concentrations of 129Xe∗ in meteoritic nanodiamonds it is shown that the minimum closing time of the I-Xe system for meteorites of different chemical classes and low petrologic types may be about one million years relative to the minimally thermally metamorphized CO3 meteorite ALHA 77307. With increasing metamorphic grade the closing time of the I-Xe system increases and can range up to several ten millions years. This tendency is in agreement with an onion-shell model of structure and cooling history of meteorite parent bodies where the temperature increases in the direction from surface to center of the asteroids.  相似文献   

12.
A thermomagnetic analysis has been performed for 737 picroilmenite samples from the cores of eight boreholes in the N-S-striking drilling profile of the Zarnitsa kimberlite pipe in the Daldyn kimberlite field, Yakutia. Based on the shapes of thermomagnetic curves and the Curie points, 29 samples were chosen for detailed microprobe studies of chemical composition and elucidation of the dependence of their thermomagnetic parameters on the content of the hematite end-member in the picroilmenites. The thermomagnetic curves of most of the studied picroilmenite samples are approximated by a two-component model for the hematite end-member distribution: the main and supplementary distribution. The average hematite end-member content in the main distribution coincides with the probe microanalysis data and is always lower than the average content in the supplementary distribution. The relative hematite end-member contents in the main and supplementary distributions within the picroilmenite grains are indicators of the dynamics of mineral formation in different parts of the Zarnitsa pipe. The data obtained testify to the multistage formation of the pipe under unstable thermodynamic conditions, which explains the intricate distribution pattern of picroilmenite.  相似文献   

13.
In the area of the magnesite deposits of Eugui (Navarra, Spain) studies on illite crystallinity, the degree of graphitization of carbonaceous material, measurements of vitrinite reflectivity, and fluid inclusions have been carried out on dolomites, magnesites, schists, and carbonaceous matter. These rocks have suffered metamorphism of very low to low grade.The magnesite appears generally concordant with the Namurian dolomitic rocks showing a typically banded structure. The genetic model proposed involves an early Mg concentration during sedimentation (syndiagenetic dolomitization), lateral circulation of saline solutions, and formation of diagenetically crystallized rhythmites (DCR), and final compaction. The formation of magnesite took place under the conditions of low pressure and temperatures close to 150°C, very similar to all strata-bound ore deposits. Deformation and regional metamorphism only caused minor removal, recrystallization, and transformation of the clay minerals and carbonaceous matter.  相似文献   

14.
铀的沉淀、富集与还原剂种类、含量有密切关系.还原剂主要包括有机质、黄铁矿、油气等.白城-开鲁地区新近系有机炭、黄铁矿含量总体较低,有机质腐殖化程度弱,但深部油气上升可进入新近系下部的大安组砂体,在某种程度上弥补岩石还原物质的不足.从后生氧化类型看,大安组具有层间氧化特点,具有形成铀矿床的前提,但从砂岩的黏土化蚀变成分看,高岭石含量比伊犁盆地成矿地层明显偏低,说明含氧化水相对较弱,铀成矿条件略差.这从某种程度解释了松辽盆地西南部新近系找矿无重大突破的原因.  相似文献   

15.
Palygorskite is a fibrous, magnesium‐bearing clay mineral commonly associated with Late Mesozoic and Early Cenozoic dolomites. The presence of palygorskite is thought to be indicative of warm, alkaline fluids rich in Si, Al and Mg. Palygorskite has been interpreted to form in peritidal diagenetic environments, either as a replacement of detrital smectite clay during a dissolution–precipitation reaction or solid‐state transformation, or as a direct precipitate from solution. Despite a lack of evidence, most diagenetic studies involving these two minerals posit that dolomite and palygorskite form concurrently. Here, petrological evidence is presented from the Umm er Radhuma Formation (Palaeocene–Eocene) in the subsurface of central Qatar for an alternative pathway for palygorskite formation. The Umm er Radhuma is comprised of dolomitized subtidal to peritidal carbonate cycles that are commonly capped by centimetre‐scale beds rich in palygorskite. Thin section, scanning electron microscopy and elemental analyses demonstrate that palygorskite fibres formed on both the outermost surfaces of dissolved euhedral dolomite crystals and within partially to completely dissolved dolomite crystal cores. These observations suggest that dolomite and palygorskite formed sequentially, and support a model by which the release of Mg2+ ions and the buffering of solution pH during dolomite dissolution promote the formation of palygorskite. This new diagenetic model explains the co‐occurrence of palygorskite and dolomite in the rock record, and provides valuable insight into the specific diagenetic conditions under which these minerals may form.  相似文献   

16.
Characteristics of ribbed moraines, the dominating moraine type in southern Finnish Lapland, have been studied in detail. The ridges are composed of several till units, of which the bottommost units consist of mature basal tills and the surficial parts are enriched with local, short‐transport rock fragments and boulders in till and at the surface of ridges. As a result of this re‐examination a two‐step model of the formation process of ribbed moraines is presented. In the first stage, while cold‐based conditions prevailed, both the bottommost part of the ice sheet and the frozen, substrate fractured under compressive ice flow. Following glacial transport of fractured blocks and formation of the transverse ridge morphology, erosion between the ridges continued owing to freeze–thaw process under variable pressure conditions. In the areas with a low pre‐existing till sheet, the process caused quarrying of the bedrock surface and subsequent deposition of rock fragments and boulders under high pressure on the next ridge. The most suitable conditions for ribbed moraine formation existed during Late Weichselian deglaciation, after the Younger Dryas when the climate warmed very quickly, leading to an imbalance between a warm glacier surface and a cold base. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

17.
伽马蜡烷--水体分层的地球化学标志   总被引：48，自引：9，他引：39  
密执安盆地等海相蒸发环境伽马蜡烷的分布表明,伽马蜡烷作为咸水环境的生物标志化合物与高盐度环境并没有绝对的对应关系;松辽盆地淡水－微咸水环境较高含量的伽马蜡烷表明其形成与湖海沟通引起的水体分层事件有关。伽马蜡烷重碳同位素值及微生物学证据均表明了伽马蜡烷的形成与水体分层有关,由于高盐环境往往伴随着密度分层,从而解释了伽马蜡烷经常与高盐环境伴生,但并不仅仅局限于高盐环境的现象。  相似文献   

18.
A model of the formation of the Ulkan trough was specified on the basis of new geochemical and geochronological data. The volcanics of the Ulkan Group exhibit geochemical features typical of the rocks of two modern geodynamic settings: suprasubduction and within-plate ones. The combination of the components derived from the different-depth sources in the magmatic chambers explains the formation of the volcanics with mixed geochemical signatures. The age of the granitoids of three phases of the Ulkan Massif is determined within the range of 1730–1925 Ga. The granites of the first and third phases have positive ɛNd(T) of + 3.5 and + 0.7, respectively. The granites of the first phase of the Ulkan Complex were likely derived from the Paleoproterozoic juvenile crust with an age of 1.84–1.95 Ga. The effusive rocks of the Ulkan Group were presumably formed in a geodynamic setting of a Cordilleran-type transform continental margin. Judging from the model TNd(DM) age, these geodynamic conditions operated >1.84 Ga ago.  相似文献   

19.
Iron-rich smectite is commonly described in the diagenetic fraction of deep-sea sediment, as millimeter to centimeter aggregates dispersed in the sediment, or as a coating on sedimentary particles or nodules. This study examines several factors to elucidate formation mechanisms of a particular iron-rich smectite and its potential transformation to glauconite. The study combines a detailed mineralogical investigation on natural samples and a chemical modeling approach to assess mineralogical reactions and pathways.Transmission electron microscopy (TEM) observations and analytical electron microscopy (TEM-AEM) analyses were conducted on microtomed samples of millimeter- to centimeter-long green grains. These grains are widespread in pelagic calcareous sediment from the Costa Rica margin. They are composed of pyrites that are partially dissolved and are surrounded by amorphous or very poorly crystallized iron-rich particles. Iron-rich montmorillonite grows from an amorphous precursor and its formation requires the input of Si, O, Mg, K, Na and Ca; our results suggest that these inputs are supported by the dissolution of sedimentary phases such as volcanic glasses, siliceous fossils and silicates.Thermodynamic modeling of fluid-sediment interactions was conducted with the geochemical computer code PhreeqC, using mineralogical and pore fluid compositions from sediment samples and calculated estimates for thermodynamic constants of smectites that are not maintained by the computer code. Simulations confirm the possibility that the green grains are the product of pyrite alteration by seawater under oxidizing conditions. The extent of smectite production is controlled by the kinetics of pyrite dissolution and fluid migration. The absence of aluminum in the Costa Rica margin system explains the formation of an iron-rich montmorillonite instead of glauconite, whereas the presence of calcite that buffers the system explains the formation of an iron-rich montmorillonite instead of iron oxides.  相似文献   

20.
Epithermal uranium deposits of the Sierra Pe?a Blanca are classic examples of volcanic-hosted deposits and have been used as natural analogs for radionuclide migration in volcanic settings. We present a new genetic model that incorporates both geochemical and tectonic features of these deposits, including one of the few documented cases of a geochemical signature of biogenic reducing conditions favoring uranium mineralization in an epithermal deposit. Four tectono-magmatic faulting events affected the volcanic pile. Uranium occurrences are associated with breccia zones at the intersection of fault systems. Periodic reactivation of these structures associated with Basin and Range and Rio Grande tectonic events resulted in the mobilization of U and other elements by meteoric fluids heated by geothermal activity. Focused along breccia zones, these fluids precipitated under reducing conditions several generations of pyrite and uraninite together with kaolinite. Oxygen isotopic data indicate a low formation temperature of uraninite, 45–55°C for the uraninite from the ore body and ～20°C for late uraninite hosted by the underlying conglomerate. There is geochemical evidence for biological activity being at the origin of these reducing conditions, as shown by low δ34S values (～?24.5‰) in pyrites and the presence of low δ13C (～?24‰) values in microbial patches intimately associated with uraninite. These data show that tectonic activity coupled with microbial activity can play a major role in the formation of epithermal uranium deposits in unusual near-surface environments.  相似文献   

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