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1.
Phenolics’ occurrence in surface water of the Dniester river basin (West Ukraine) with the definition of the natural background is studied. The main attention is given to the Upper Dniester basin and its tributary Stryj as the parts of the Sub-Carpathian oil- and gas province with the numerous objects of oil industry. The total amount of phenolics in water is studied. Phenolics’ concentrations from the first micrograms to the first milligrams per litre have been found in the surface water of the region. The natural background is defined as 0.012 mg l−1 for the areas out of the industrial influence. The anthropogenic part of phenolics is caused mainly by oil industry. The oil-producing objects provide the main phenolics’ releases in the region, due to the low protection level of mechanical facilities as well as to breach of technological norms on the oil-extracting objects. A man-made pollution of the basin water has a regional character and the natural self-purification processes seem to be insufficient for its neutralisation on the plains in particular.  相似文献   

2.
Research on land use and cover change (LUCC) is an important aspect of the study of global change or global warming. The Qinghai-Tibetan Plateau is a good place to study global change because of its unique natural conditions, so we chose the source region of China’s Yellow River for a case study of the driving forces behind LUCC. We used Landsat images obtained in 1989, 2000, and 2005 to establish databases of land use and cover at these times. We then derived LUCC information by overlaying these layers using GIS software. By studying the processes responsible for LUCC, we analyzed the driving forces, which included climatic change, human activities, animal and insect damage, and the influences of government policies. During the 16-year study period, LUCC occurred slowly in response to two groups of processes: natural and anthropogenic. The main driving forces included climate change (the region is becoming drier and warmer), human activities (especially overgrazing), and animal and insect damage. Although political measures such as key national projects to improve the ecological environment could help to restore the region’s vegetation and slow desertification, the region’s fragile ecosystems and harsh natural conditions will make it extremely difficult to rehabilitate the eco-environment.  相似文献   

3.
Heavy metal distribution patterns in river sediments aid in understanding the exogenic cycling of elements as well as in assessing the effect of anthropogenic influences. In India, the Subernarekha river flows over the Precambrian terrain of the Singhbhum craton in eastern India. The rocks are of an iron ore series and the primary rock types are schist and quartzite. One main tributary, the Kharkhai, flows through granite rocks and subsequently flows through the schist and quartzite layers. The Subernarekha flows through the East Singhbhum district, which is one of India’s industrialised areas known for ore mining, steel production, power generation, cement production and other related activities. Freshly deposited river sediments were collected upstream and downstream the industrial zone. Samples were collected from four locations and analysed in <63-μm sediment fraction for heavy metals including Zn, Pb, Cd and Cu by anodic stripping voltammetry. Enrichment of these elements over and above the local natural concentration level has been calculated and reported. Sediments of the present study are classified by Muller’s geo-accumulation index (I geo) and vary from element to element and with climatic seasons. During pre-monsoon period the maximum I geo value for Zn is moderately to highly polluted and for Cu and Pb is moderately polluted, respectively, based on the Muller’s standard. Anthropogenic, lithogenic or cumulative effects of both components are the main reasons for such variations in I geo values. The basic igneous rock layer through which the river flows or a seasonal rivulet that joins with the main river may be the primary source for lithogenic components.  相似文献   

4.
Hydrochemistry of groundwater is largely determined by both natural processes, such as dissolution, cation exchange, mixing, evaporation; and anthropogenic activities, which can affect the aquifer systems by contaminating them or by modifying their hydrological cycle. Both natural and anthropogenic processes vary in time and space; which is reflected in groundwater hydrochemistry variation. The objective of this study is the determination of the main hydrogeochemical processes that affect the quality of shallow groundwaters in the Grombalia basin, located in the Cap Bon Peninsula, north-eastern Tunisia. In this area, the chemical composition of groundwater is mostly characterized by Na–Cl–NO3–Ca water type which reveals the implication of natural and anthropogenic major factors. Natural factors are dissolution of evaporatic minerals, i.e. halite and gypsum and cation exchange with clays, while anthropogenic factors are pollution with industrial Sr-rich waste water and return flow of irrigation water, highly contaminated by MgSO4 and methyl-bromide fertilizers.  相似文献   

5.
For many years the marble extraction sector of the Greek mining industry has been in conflict with the public, especially in terms of rehabilitation of marble quarry sites. One of the main reasons for that is that the marble extraction sector has been unable to adjust to the existing legislative guidelines for the rehabilitation, such as extensive backfilling and re-vegetation. In the majority of cases these methods fail due to erosion of the backfill soil and adverse climatic conditions. As a result the number of abandoned marble quarry sites is continuously increasing. The present paper suggests a different approach regarding the rehabilitation of marble quarries. More specifically, the paper questions the applicability, the effectiveness, and the social usefulness of the above-mentioned guidelines and suggests the establishment of new land-uses, which are based on an in-depth analysis of the area’s special features, by taking full advantage of its potentials. What is more, the rehabilitation scheme proposes that the new land-uses and the quarrying activity may co-exist and operate simultaneously for a long period of time.  相似文献   

6.
Small islands groundwater are often exposed to heavy pumpings as a result of high demand for freshwater consumption. Intensive exploitation of groundwater from Manukan Island’s aquifer has disturbed the natural equilibrium between fresh and saline water, and has resulted increase the groundwater salinity and leap to the hydrochemical complexities of freshwater–seawater contact. An attempt was made to identify the hydrochemical processes that accompany current intrusion of seawater using ionic changes and saturation indices. It was observed that the mixing between freshwater–seawater created diversity in geochemical processes of the Manukan Island’s aquifer and altered the freshwater and seawater mixture away from the theoretical composition line. This explained the most visible processes taking place during the displacement.  相似文献   

7.
Based on the factor analysis of chemical elements determined in topsoil (0–5 cm) and attic-dust, two natural and two man-made (anthropogenic) geochemical associations were discovered in the Meza valley, an old mining and metallurgic area. The natural geochemical association (Al-Ce-Co-K-La-Li-Nb-Rb-Sc-Th-Ti-V) is influenced mainly by weathering of metamorphic rocks, while the anthropogenic association (Ca-Mg) was determined in an area of carbonate rock outcrops. The man-made associations are a result of lead production (Ag-As-Cd-Mo-Pb-S-Sb-Sn-Zn) and iron production (Co-Cr-Mo-Ni-W).  相似文献   

8.
The Vaal River Basin is an economically significant area situated in the interior of South Africa (SA), where mining, industrial, domestic and agricultural activities are very intense. The purpose of the study was to assess the influence of geology and anthropogenic activities on groundwater chemistry, and identify the predominant hydrochemical processes in the basin. Data from seventy groundwater sites were retrieved from the national database, and attention was paid to fifteen water quality parameters. Groundwater samples were clustered into seven hydrochemically distinct groups using Hierarchical Cluster Analysis (HCA), and three samples treated independently. A Piper plot revealed two major water types, Ca–Mg–HCO3 and Ca–Mg–SO4-Cl, which were linked to dissolution of the underlying geology and mine pollution. The Ca?+?Mg vs HCO3?+?SO4 plot indicated that reverse ion exchange is an active process than cation exchange in the area. Principal component analysis (PCA) was used to identify the main natural and anthropogenic processes causing variation in groundwater chemistry. Four principal components were extracted using PCA that explains 82% of the total variance in the chemical parameters. The PCA results can be categorized by four components: (1) evaporites and silicates weathering enrichment of Na, K, Cl, SO4 and F, and anthropogenic Cl; (2) dissolution of dolomite, limestone and gypsum; (3) agricultural fertilizers (4) wastewater treatment. This study reveals that both natural and anthropogenic activities are the cause of groundwater variation in the basin.  相似文献   

9.
Chemical compositions and stable isotope ratios of water and sulphate were used to characterise sources and processes responsible for elevated concentrations of sulphate and other constituents in groundwater from aquifers at Colima State along Mexico’s Pacific Coast. The δ18O and δ2H values of the groundwater were similar to those of precipitation indicating a meteoric origin, and recharge processes are relatively uniform in large parts of the study area with only slight local evaporation effects. δ34Ssulphate and δ18Osulphate analyses indicated that high sulphate concentrations of up to 1,480 mg/l are mainly due to dissolution of evaporites and volcanic exhalations. Chloride is largely related to sources other than seawater. The Marabasco sub basin is affected by anthropogenic contamination through manganese and iron ore mining activities. The obtained knowledge regarding sources and areas of contamination will be essential for the development and design of a water quality monitoring program in the study area.  相似文献   

10.
This report gives the conceptual approaches to the development of the theory of the formation of natural water composition in view of the primary properties of aquatic ecosystems: the “principle of uncertainty” in the estimation of the conditions, the “continuity” of the changes proceeding, and the “plurality” of water’s natural structure and components (biotic and abiotic), as well as their interaction processes. The importance and features of each of these basical criteria for characterizing the conditions of an aquatic ecosystems are substantiated in theory.  相似文献   

11.
Acid mine drainage (AMD) pollution is considered to be the most serious water pollution problem in mining areas. AMD containing iron sulfates and other components can affect the receiving water bodies. Pyrite oxidation and AMD generation can be considered as important processes that may take place in the wastes produced by coal mining and coal washing operations in the Golestan province (northeast Iran). The study area is characterized by appropriate atmospheric conditions that favor pyrite oxidation and the presence of a large amount of water bodies. This study attempts to consider pyrite oxidation and AMD generation in the Azad shahr–Ramian region. The impact of AMD on the quality of the surface water bodies was investigated by taking samples and analyzing them for hydro-geochemical parameters. Stiff and Piper diagrams were used to represent chemical analyses of water samples. The coal samples taken from different depths at four points on two different coal waste dumps were analyzed to find the fraction of pyrite that remained in the waste particles to investigate the pyrite oxidation process. A computational fluid dynamic package called PHOENICS was used to model pyrite oxidation process numerically. The results obtained from the geochemical analyses of water and coal samples and numerical simulation show pyrite oxidation and acid generation in the region. However, the presence of carbonate rocks raised the pH of the water samples. The drainages of the Razi mine may be recognized as natural alkaline mine drainages.  相似文献   

12.
INTRODUCTIONMining activlties have significant envi ronmenta1 inll)ac'l ssuch as visual intrusions, dust, noise, blasting, trafflc and h}'drology (Kwolek, l999; Ripley et al., l996 ). The l)rot'csst'sof mineral extraction, processing, smelting and refinlng;1rt'never approximate to the environmental neutrality, but tht' affected areas can be ameliorated (KwoIek, l999; Klukanov;1;llltlRapant, 1999). The regions, where mining activities are I,r('sent or continuous for a long tlme, are pote…  相似文献   

13.
We investigated the mineral composition and trace element contents of dustfall with different deposited phases at the Minqin Oasis, in China’s Hexi Corridor. The contents of elements such as Pb, Cd, Cu, As, Sb, Se, Rb, Cs, and Ba (believed to be of anthropogenic origin) indicated that the significance of human impacts on dust emissions increased from 1970s to the early 2000s. However, variations in the content of elements including Sc, Mn, Na, Cr, V, Eu, Ce, Nb, Zr, La, and Ce (believed to originate from natural processes such as physical and chemical weathering) show no obvious changes in the major potential dust source areas (PSAs) in this region. In addition, analysis of the assemblage of trace elements in dustfall indicated that the elements assumed to originate from anthropogenic and natural processes appear to be intertwined, leading to difficulties and uncertainties in identifying the PSAs and evaluating the significance of human impacts on dust emissions. Comparisons of the element contents of dustfall collected in Beijing and Minqin with similar data for Beijing show that under different conditions some differences in ranges are permitted; the contents of most trace elements were similar even though the dustfall in the two areas came from different sources. These results suggest that before attempting to identify major PSAs, researchers should perform an integrated analysis that includes the mineral, elemental, geomorphological, vegetation cover, climatic conditions, and other characteristics of the regions being studied.  相似文献   

14.
Results of data analysis, based on measurement of atmospheric concentrations of methane in the shallow part of the East Siberian shelf (ESS) are presented in this work. It was shown that methane emission in the atmosphere is determined not only by natural factors, but is also sensitive to anthropogenic influences, like the engine mode of a ship. It was determined that the hydraulic impact, which occurs when starting a ship’s engine after drifting through a shallow, can induce a great methane outbreak in the atmosphere. The power of these “short-lived” sources can exceed the power of any one deep-water mud volcano. In the shallow parts of the ESS, the anthropogenic factor can be one of the important factors effecting methane outbreaks in the atmosphere.  相似文献   

15.
An investigation was carried out to evaluate the geochemical processes regulating groundwater quality in a coastal region, Barka, Sultanate of Oman. The rapid urban developments in Barka cause depletion of groundwater quantity and deterioration of quality through excessive consumption and influx of pollutants from natural and anthropogenic activities. In this study, 111 groundwater samples were collected from 79 wells and analysed for pH, EC, DO, temperature, major ions, silica and nutrients. In Barka, water chemistry shows large variation in major ion concentrations and in electrical conductivity, and implies the influence of distinguished contamination sources and hydrogeochemical processes. The groundwater chemistry in Barka is principally regulated by saline sources, reverse ion exchange, anthropogenic pollutants and mineral dissolution/precipitation reactions. Due to ubiquitous pollutants and processes, groundwater samples were classified into two groups based on electrical conductivity. In group1, water chemistry is greatly influenced by mineral dissolution/precipitation process and lateral recharge from upstream region (Jabal Al-Akdar and Nakhal mountains). In group 2, the water chemistry is affected by saline water intrusion, sea spray, reverse ion exchange and anthropogenic pollutants. Besides, high nitrate concentrations, especially in group 2 samples, firm evidence for impact of anthropogenic activities on groundwater quality, and nitrate can be originated by the effluents recharge from surface contamination sources. Ionic ratios such as SO4/Cl, alkalinity/Cl and total cation/Cl indicate that effluents recharged from septic tank, waste dumping sites and irrigation return flow induce dissolution of carbonate minerals, and enhances solute load in groundwater. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta, the difference between the actual concentration of each constituent and its theoretical concentration for a freshwater–seawater mix calculated from the chloride concentration of the sample, and proved that this approach is a promising tool to identify and differentiate the geochemical processes in coastal region. Hence, both regular geochemical methods and ionic delta ensured that groundwater quality in Barka is impaired by natural and human activities.  相似文献   

16.
Due to the abundance of mineral deposits associated with the metamorphic rocks of the Sudetes, the area was intensively settled and developed by the end of the Middle Ages. Several centuries later, the first attempts were made to rehabilitate the devastated natural environment. The advent of capitalism brought further damage to the environment, which has remained almost unchanged to this day. Improvements in the context of transfrontier cooperation have arisen out of the economic crisis and the disintegration of the Soviet bloc. However, the Sudetes are still a problem area, and various industries are competing for local resources. The main problem facing the region is the need to rehabilitate its natural environment and create a more balanced local economy. Tourism, forestry, agriculture and ‘clean’ industrial technologies have the greatest potential. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

17.
The lower Liaohe River Plain (LRP) is an economically and ecologically important area situated on an alluvial plain, where anthropogenic activities are very intensive. Field investigations were conducted in the LRP and 15 water quality parameters surveyed at 216 wells during September and October of 2009 and 2010. These showed significant variation in the hydrochemistry of groundwater throughout the plain. A Piper plot was used to identify the major geochemical processes occurring in the entire plain. Principal components analysis (PCA) was used to identify various underlying natural and anthropogenic processes that created these distinct water types. The Stuyfzand classification was used to subdivide and interpret the complex groundwater hydrochemistry of the Liaohe River delta. Five principal components (PCs) were extracted in terms of PCA, which can be invoked to explain 82% of the total variance in water quality parameters. The PCA results can be categorized by five major factors: (1) Holocene transgression and mixing; (2) surface water infiltration; (3) multi-factor processes; (4) rainfall and agricultural fertilizer contamination; and (5) Geogenic F enrichment. This study demonstrates that the great variation of groundwater hydrochemistry in the LRP should be attributed to both natural and anthropogenic processes.  相似文献   

18.
This study was conducted to evaluate factors regulating groundwater quality in an area with agriculture as main use. Thirty groundwater samples have been collected from Razan area (Hamadan, Iran) for hydrochemical investigations to understand the sources of dissolved ions and assess the chemical quality of the groundwater. The chemical compositions of the groundwater are dominated by Na+, Ca2+, HCO3 , Cl and SO4 2−, which have been derived largely from natural chemical weathering of carbonate, gypsum and anthropogenic activities of fertilizer’s source. The production of SO4 2− has multiple origins, mainly from dissolution of sulphate minerals, oxidation of sulphide minerals and anthropogenic sources. The major anthropogenic components in the groundwater include Na+, Cl, SO4 2− and NO3 , with Cl and NO3 being the main contributors to groundwater pollution in Razan area.  相似文献   

19.
The Ribeira Valley region (State of Sao Paulo, Brazil) hosts the largest Brazilian Atlantic forest reserve. The region was an important mineral district during the ‘60s, from where several tons of lead and other metals were exploited. Residual materials produced by the mining are diffused in the environment until today. The area also encompasses a regional arsenium anomaly associated with unexplored gold deposits. The population presently living in this region performs basic farming activities, from which most of their food is yielded. These features coupled together imply in a complex relationship between natural and anthropogenic factors that are likely to affect the life and health of the local communities. The aim of this paper is to apply digital data integration techniques for environmental risk assessment in the Ribeira Valley using environmental geochemistry. Geochemical, digital elevation and remote sensing data (Landsat Thematic Mapper) were merged and analyzed using a geographical information system. The assumed model considered environmental mobilization through erosion and anomalous As–Pb areas. Data were analyzed through Boolean and fuzzy logic techniques. Fuzzy logic proved superior in this case study as it allowed not only the detection but also the distinction between low, moderate and high environmental risk areas.  相似文献   

20.
NOAA’s National Geophysical Data Center is using state-of-the-art Internet tools for natural hazards education, public outreach, and access to natural hazards data. For example, NGDC acquires, processes, and provides access to geologic hazards event data that are useful in natural hazards risk assessment and hazards-related research. In addition, a collection of natural hazards slides and a teacher’s guide on volcanoes are available online. NGDC also created an online “Kids Hazards Quiz” to test the user’s knowledge of disaster safety information. An online Natural Hazards Data Resources Directory provides access to information and links to organizations that provide natural hazards data and information. Expanded access to these data and information by the public and researchers can increase public awareness of natural hazards, improve hazards research, and ultimately reduce the devastating impacts of natural disasters.  相似文献   

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