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1.
The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag) deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in 87Rb/86Sr and 87Sr/86Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial 87Sr/86Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust. 相似文献
2.
The RbSr and UPb methods were used to study gneisses in the Lake Helen quadrangle of the Big Horn Mountains, Wyoming. Two episodes of magmatism, deformation and metamorphism occurred during the Archean. Trondhjemitic to tonalitic orthogneisses and amphibolite of the first episode (E-1) are cut by a trondhjemite pluton and a calc-alkaline intrusive series of the second episode (E-2). The E-2 series includes hornblende-biotite quartz diorite, biotite tonalite, biotite granodiorite and biotite granite.A RbSr whole-rock isochron for E-1 gneisses indicates an age of 3007 ± 34 Ma (1 sigma) and an initial 87Sr/86Sr of 0.7001 ± 0.0001. UPb determination on zircon from E-1 gneisses yield a concordia intercept age of 2947 ± 50 Ma. The low initial ratio suggests that the gneisses had no significant crustal history prior to metamorphism, and that the magmas from which they formed had originated from a mafic source.A RbSr whole-rock isochron for E-2 gneisses gives an age of 2801 ± 31 Ma. The 87Sr/86Sr initial ration is 0.7015 ± 0.0002 and precludes the existence of the rocks for more than 150 Ma prior to metamorphism. The E-2 magmas may have originated from melting of E-1 gneisses or from a more mafic source. 相似文献
3.
The Newer Volcanics Province of Victoria and South Australia consists of a major region of mainly alkaline basalts within which are two restricted areas containing strongly differentiated flow‐rocks. Typical alkalic basalts from this widespread province have K‐Ar ages from 4.5 to 0.5 m.y. and initial 87Sr/86Sr ratios from 0.7038 to 0.7045. Contrastingly, in the Macedon area of differentiated lavas, flow compositions range from limburgite to soda trachyte, with K‐Ar ages from 6.8 to 4.6 m.y. and initial 87Sr/86Sr ratios from 0.7052 to 0.7127. These differentiated rocks therefore are older, and some of them may have been contaminated by reaction with more radiogenic basement rocks during differentiation. Alternatively, the variation in initial Sr‐isotope composition may have resulted from varying isotopic composition of partial melts from the immediate source rocks. The most felsic of the differentiated rocks, soda trachyte, is extremely enriched with Rb relative to Sr; one of the three restricted outcrops of this rock (Camel's Hump) yields a total‐rock Rb‐Sr isochron age of 6.3 ± 0.6 m.y. with an initial 87Sr/86Sr ratio of 0.7127. K‐Ar sanidine ages reported for the three outcrops of trachyte are identical to each other and to the Rb‐Sr isochron result. 相似文献
4.
The geochemistry and evolution of early precambrian mantle 总被引：1，自引：0，他引：1
Seven high-purity cumulate clinopyroxenes from 2.7 b.y. maficultramafic rock associations from the Abitibi belt, Superior Province, Canada, have been analyzed for major elements and K, Rb, Cs, Ba, Sr and 87Sr/86Sr ratio. Attempts to reconstruct the trace element patterns of the original parent magmas were partially successful; Sr contents (140 ppm), K/Rb (470) and K/Ba (16) ratios are similar to those of modern low-K island arc tholeiites. K/Cs ratios (2700) are significantly lower than island arc tholeiites (17,000) or oceanic island and oceanic ridge basalts (> 30,000); the presentday mantle seems to be more depleted in Cs than in Archean times. Initial Sr isotope ratios of the 7 Archean clinopyroxenes average 0.70114±13(2σ) with relatively little variation; this value is in good agreement with initial ratios published for felsic and mafic rocks of the same age, though the latter show much larger variations and uncertainties. The pyroxene Sr isotope data, in conjunction with data for rocks of other ages, defines the following simple model for mantle evolution:
- starting with primordial Sr, a short period of relatively rapid 87Sr/86Sr growth, followed by Rb depletion;
- a period between ≧ 3.5 b.y. and ～ 1.7 b.y. when closed-system Sr isotope evolution occurred (with Rb/Sr ～ 0.023);
- development of large-scale Rb/Sr heterogeneities in the mantle at ～ 1.7 b.y., leading to a present-day mantle with 87Sr/86Sr ranging from 0.7023 to 0.7065 and Rb/Sr ranging from ～ 0 to 0.065.
5.
Initial 87Sr/86Sr ratios down a 2,315 foot-long core (DDH-295) through the Partridge River Troctolite are lower in the depth range 710–1,410
feet (0.70443±22) than in the underlying and overlying rocks (0.70500±18). These initial ratio variations define three zones
(I, II, and III) thought to be three intrusive units within the troctolite. The best estimate of the Rb-Sr age of the troctolite
is 1,050±105 m.y. The olivine compositions and the abundances of the incompatible trace elements Zr, Y, and Rb show identical
variations down the core, with downward repetitions of olivine iron-enrichment and incompatible trace element enrichments.
Discontinuities in the olivine compositions and incompatible trace element abundances match the initial 87Sr/86Sr ratio discontinuities in the core.
The strontium isotope data imply that involatile components of the Proterozoic Virginia Formation and other Archaean rocks
were not significantly assimilated by the troctolites, for only three out of the twenty-three initial 87Sr/86Sr ratios depart from normal magmatic values. These three anomalous ratios are not systematically related to the Cu-Ni sulphide
mineralization and may be the result of secondary calcite in the troctolite. The strontium isotope systematics of the Virginia
Formation xenoliths and underlying hornfelses are highly disturbed as a result of Rb loss.
The apparently inverted fractionation sequences in the troctolites are interpreted in terms of downward increases in intercumulus
liquid in repeated magma batches and controlled by plagioclase flotation. The amount of intercumulus liquid is estimated to
range from 7 to 61 weight per cent.
The Cu-Ni sulphides are concentrated in the lower 250 feet of zone I (immediately above the Virginia Formation) and through
400 feet of core across the contact between zones I and II, more than 750 feet above the base. Because the sulphide-bearing
troctolites are not systematically related to disturbances in the magmatic initial 87Sr/86Sr ratios, the mineralization probably involved the volatile transfer of sulphur derived from dehydration reactions in the
underlying Virginia Formation. 相似文献
6.
W. Compston 《Australian Journal of Earth Sciences》2013,60(4):403-411
The Table Hill Volcanics of the Officer Basin were first dated as approximately 1100 m.y. from Rb‐Sr model ages for total‐rock samples of basalt from the Yowalga No. 2 bore. Later regional mapping, however, places the Volcanics as Marinoan (very late Precambrian) or younger, and receives support from discordant K‐Ar ages ranging from 330 m.y. to 445 m.y. New total‐rock analyses confirm the original Rb‐Sr data, but analyses of separated minerals do not confirm the low value for the initial 87Sr/86Sr that had been assumed to calculate the 1100 m.y. model age. Instead, apparently‐unaltered primary pyroxenes indicate that the initial 87Sr/86Sr could be as high as 0.718. Combined with the total‐rock results, this yields an apparent age for the basalt of 575 ± 40 m.y. It is possible in principle that the high 87Sr/86Sr in the pyroxenes could be due to Sr isotope exchange during a Palaeozoic metamorphism, but there is absolutely no field or petrological evidence for such an event. Consequently, and in view of the stratigraphic evidence for their age, the Rb‐Sr data are best interpreted as signifying an original extrusion of the basalts at 575 ± 40 m.y., together with a prehistory of the magma that includes contamination with radiogenic Sr and alkalis from Precambrian crustal material. 相似文献
7.
The wadi Kid pluton of Iqna Granite, Southern Sinai, which was intruded during the last Precambrian magmatic phase, yields
a Rb-Sr total rock isocrhon age of 580±23 m.y., and an initial 87Sr/ 86Sr ratio of 0.7028±0.0028. The magma of the Iqna Granite was derived from a low Rb/Sr source shortly before its crystallization.
Partial resetting of biotite ages is detected by both Rb-Sr and K-Ar methods. Mineral isochrons yield higher initial values
(0.7045–0.7065) as a result of Sr isotopic redistribution within a closed total rock system.
The Rb-Sr resetting of the biotites is expressed by radiogenic Sr loss accompanied by a proportional enrichment of common
Sr. The Rb content was unaffected by this process. Oxidation of the iron within the biotite indicates the opening of the biotite
interlayer space, thus making the Sr exchange possible. These effects are attributed to a thermal event some 510–540 m.y.
ago. 相似文献
8.
Rocks of the northeast portion of the Colorado mineral belt form two petrographically, chemically and geographically distinct rock suites: (1) a silica oversaturated granodiorite suite; and (2) a silica saturated, high alkali monzonite suite. Rocks of the granodiorite suite generally have Sr contents less than 1000 ppm, subparallel REE patterns and initial 87Sr/ 86Sr ratios greater than 0.707. Rocks of the monzonite suite are restricted to the northeast part of the mineral belt, where few rocks of the granodiorite suite occur, and generally have Sr contents greater than 1000 ppm, highly variable REE patterns and 87Sr/86Sr initial ratios less than 0.706.Despite forming simple, smooth trends on major element variation diagrams, trace element data for rocks of the granodiorite suite indicate that they were not derived from a single magma. These rocks were derived from magmas having similar REE patterns, but variable Rb and Sr contents, and Rb/Sr ratios. The preferred explanation for these rocks is that they were derived by partial melting of a mixed source, which yielded pyroxene granulite or pyroxenite residues.The monzonite suite is chemically and petrographically more complex than the granodiorite suite. It is subdivided here into alkalic and mafic monzonites, and quartz syenites, based on the textural relations of their ferromagnesian phases and quartz. The geochemistry of these three rock types require derivation from separate and chemically distinct magma types. The preferred explanation for the alkalic monzonites is derivation from a heterogeneous mafic source, leaving a residue dominated by garnet and clinopyroxene. Early crystallization of sphene from these magmas was responsible for the severe depletion of the REE observed in the residual magmas. The lower Sr content and higher Rb/Sr ratios of the mafic monzonites requires a plagioclase-bearing source.The Sr-isotope systematics of the majority of these rocks are interpreted to be largely primary, and not the result of crustal contamination. The positive correlation of Rb/Sr and 87Sr/86Sr ratios for the least fractionated samples indicate that the sources from which parent magmas of both the granodiorite and monzonite suites were derived are Precambrian in age. 相似文献
9.
《Journal of Asian Earth Sciences》2000,18(5):585-594
The results of a Sr isotopic study of coexisting alkaline silicate rocks and carbonatites of two Cretaceous alkaline complexes of India, Amba Dongar (Deccan Flood Basalt Province) and Sung Valley (Rajmahal–Bengal–Sylhet Flood Basalt Province) are reported. The overlapping nature of initial Sr isotopic ratios of alkaline rocks and carbonatites of both the complexes is consistent with a magmatic differentiation model. Modelling of initial 87Sr/86Sr variation in alkaline rocks of Amba Dongar is consistent with a process of crustal assimilation by the parent magma undergoing simultaneous fractional crystallization of silicate rocks and silicate–carbonate melt immiscibility. A maximum of ∼5% crustal contamination has been estimated for the parent magma of Amba Dongar, the effect of which is not seen in the Sr isotope ratio of carbonatites generated by liquid immiscibility. A two point Rb–Sr isochron of the Sung Valley carbonatites, pyoxenite and a phlogopite from a carbonatite yielded an age of 106±11 Ma, which is identical to the 40Ar–39Ar age of this complex. The same age for the carbonatites and the alkaline silicate rocks, similar initial Sr ratios and the higher Sr concentration in the former than the latter favour the hypothesis of liquid immiscibility for the generation of the Sung Valley. The higher initial 87Sr/86Sr ratio for these complexes than that of the Bulk Earth indicates their derivation from long-lived Rb/Sr-enriched sources. 相似文献
10.
《International Geology Review》2012,54(16):1975-1991
Late Palaeozoic granites are widely distributed in the southeastern Beishan area, which is located in the central part of the southern Central Asian Orogenic Belt (CAOB). U–Pb zircon dates of five late Palaeozoic granitic plutons from the southeastern Beishan area yield Permian ages: 285 ± 2 Ma (Shuwojing and Western Shuwojing plutons), 269 ± 3 Ma (Jianquanzi and Jiuquandihongshan plutons), and 260 ± 1 Ma (Jiujing pluton). The early Permian Shuwojing pluton, an unfractionated calc-alkaline biotite monzogranite with slightly positive εNd(t) (+0.7 and +0.6) and low initial 87Sr/86Sr (0.70722 and 0.70712), and the early Permian Western Shuwojing pluton, a high-K calc-alkaline biotite granite with slightly negative εNd(t) (?0.2 and ?0.1) and low initial 87Sr/86Sr (0.70390 and 0.70919), are likely derived from a mixture of depleted (juvenile) mantle and upper continental crustal (or sedimentary) material. The mid-Permian Jianquanzi and Jiuquandihongshan monzogranites have highly fractionated potassium-rich calc-alkaline characteristics with negative εNd(t) (?4.3) and very high initial 87Sr/86Sr (0.71949), reflecting a continental crustal component. The compositionally diverse Jiujing pluton and the granodiorite and high-Sr monzogranite phases display adakite-like compositions with relatively low εNd(t) (?0.1 and ?2.2) and high initial 87Sr/86Sr (0.70822 and 0.70913). The Jiujing low-Sr monzogranite has higher initial 87Sr/86Sr (0.73464) and lower εNd(t) (?2.8), indicating a significant continental crustal component in its genesis. This work, combined with the regional geology and previous studies, suggest that the early to middle Permian southern Beishan plutons formed in a post-collisional environment, probably an intracontinental rift environment linked to asthenospheric upwelling in response to the break-off of a subducted slab. In the late Permian, the southern Beishan area was in a compressive tectonic regime and thickening of the continental crust resulted in the formation of the Jiujing adakite-like granite. 相似文献
11.
K-Ar dating on a suite of volcanic rocks from the island of Principe gives the following chronology.
- Basal palagonite breccia (30.6 ± 2.1 Ma).
- Older Lava Series (OLS) basalt (23.6±0.7 Ma) and hawaiite (19.1±0.5 Ma).
- Younger Lava Series (YLS) nephelinite (5.60±0.32 Ma) and basanite (3.51 ±0.15).
- Intrusive phonolite (5.32±0.17 Ma, 5.48±0.19 Ma), tristanite (4.89±0.15 Ma) and trachyphonolite (6.93±0.68 Ma) plugs.
12.
O. van Breemen J. Hutchinson P. Bowden 《Contributions to Mineralogy and Petrology》1975,50(3):157-172
Sixty-four Rb-Sr and two K-Ar isotopic measurements from seven ring complexes in central Nigeria provide evidence for a systematic age trend along a 200 km zone ranging from 174±5 m.y. in the north to 154±4 m.y. in the south. A peak of anorogenic magmatism occurred in the Jos Plateau region about 164±4 m.y. ago. Although a small syenitetrachyte complex at Zaranda, near Bauchi, gives an age of 190±15 m.y., unpublished ages of 290–330 m.y. for the southern Niger ring complexes confirm the existence of an overall southerly decreasing age trend in the Niger-Nigeria province of West Africa. Isotopic measurements on two small, oversaturated syenite intrusions at Zaranda and Pankshin suggest that syenitic liquids had initial 87Sr/86Sr ratios of 0.7048—not significantly different from the mantle range of values, but that related peralkaline silicic variants from the same complexes are depleted in total Sr and have higher 87Sr/86Sr initial ratios characteristic of the earth's crust. This variation of initial 87Sr/86Sr ratios in syenite-related granitic liquids of the peralkaline spectrum has also been noted at the Shere Hills, near Jos, and at Liruei, near Kano, and may be representative for all syenite-granite occurrences in the Nigerian Younger Granite province. Such isotopic variations in the initial 87Sr/86Sr ratio may be attributed to “crustal enrichment” of syenitic liquids whose source lies in the mantle. Coarse-grained, peraluminous biotite granites have consistently low initial 87Sr/86Sr ratios in the range 0.706–0.709 (similar to the ca. 600 m.y. Pan-African granites of the basement), and may represent further modifications of originally syenitic liquids in the crust, or the granites may have originated from an independent source within a “dioritio” lower crust. Although the magmatic trends show small variations in the initial 87Sr/86Sr ratio, much higher initial ratios are recorded in granites which have been modified within their roof zone by deuteric (autometamorphic) and/or metasomatic processes. 相似文献
13.
Strontium isotope data are presented from 28 rock samples representing four distinct episodes of late Cenozoic volcanism in southeastern Papua. Eocene tholeiitic basalts have initial 87Sr/86Sr ratios (0.7037) which are higher than those in chemically comparable basalts and are thought to have been enhanced by rock-sea water interaction. Late Cenozoic are trench type volcanoes in the Papuan islands have initial 87Sr/86Sr ratios which show little variation (0.7041±2) in contrast to those from the contiguous Papua New Guinea mainland (0.7036-0.7054). This isotopic discontinuity does not appear to be due to contamination by immediately underlying sialic metamorphics. High-K trachytes in the Lusancay Islands north of the late Cenozoic are have comparable initial 87Sr/86Sr ratios. Wide variation (0.703-0.710) in the initial ratios measured in a group of apparently closely related rocks ranging in composition from transitional basalt to peralkaline rhyolite cannot be explained by differences in age or by late magmatic fractionation and continue to pose an enigma. 相似文献
14.
Christopher Brooks 《Australian Journal of Earth Sciences》2013,60(2):457-469
Rb‐Sr isotopic age measurements relate emplacement of the Pieman and Meredith Granites (356 ± 9 and 353 ± 7 m.y., respectively), and the Bischoff and Renison Bell Porphyries (349 ±4 and 355 ± 4 m.y., respectively) to the Tabberabberan Orogeny. The genetic relationship of the Bischoff Porphyry to mineralization and the agreement between the age of this porphyry and the age of the adjacent Meredith Granite, strongly suggests that the Bischoff mineralization resulted from granite intrusion. The Pieman Granite is closely similar to the white Heemskirk Granite in displaying a high initial 87Sr/86Sr ratio (0.7354 ± 0.0018), feldspar discordance patterns and open system total‐rock behaviour. The high initial 87Sr/86Sr ratio is attributed to contamination during intrusion by Precambrian metasediments containing appreciable radiogenic strontium. A basic intrusion (McIvors Hill Gabbro) gave a pre‐Tabberabberan age (518 ±133 m.y.) and a high initial 87Sr/86Sr ratio (0.7132 ± 0.0031). 相似文献
15.
M.H. Dodson 《Lithos》1982,15(3):215-219
A general null hypothesis for isotope geochemistry states that the isotopic composition of an element is independent of its concentration or any other geochemical property of the population. ‘Spurious’ correlations between the ratios 87Sr/86Sr and 87Rb/86Sr (orRb/Sr), due to the common denominator effect, may be ruled out because they contradict this null hypothesis. Mixing processes may be regarded as geochemical counterparts of the common denominator effect. In geochronological systems which satisfy the basic assumptions of the Rb-Sr isochron method observed correlations between Sr isotope abundance and Sr concentration must be secondary to the direct causal dependence of 87Sr/86Sr upon Rb/Sr ratios. 相似文献
16.
Joshua D. Cocker 《Australian Journal of Earth Sciences》2013,60(1-2):139-158
Biotite igneous ages and well‐defined isochron ages of plutons from the composite Blue Tier Batholith and the Coles Bay area in northeastern Tasmania range from 395 to 370 Ma. The older limit of this range, for the George River granodiorite, is considerably older than any age previously recorded for NE Tasmania. The ages of the youngest plutons (Mt Paris and Anchor granites), which host cassiterite ores, record pervasive hydrothermal alteration events. The initial 87Sr/80Sr ratios of the granitoids range from 0.7061 to 0.7136 and suggest different protolith compositions, consistent with mineralogical and geochemical characteristics of each pluton. The S‐type garnetbiotite granites (Ansons Bay and Booby alia granites) have initial ratios greater than 0.7119, indicative of enriched, high Rb/Sr ratio, crustal source‐rocks of Proterozoic age (1700–800 Ma). The S‐type biotite granites (Poimena and Pearson granites) have relatively high initial 87Sr/86Sr ratios (0.7070, 0.7105) but overlap with those of the I‐type granodiorites (George River, Scamander Tier, Pyengana and Coles Bay granodiorites) which are in the range of 0.7061 to 0.7073. The initial ratios of the enriched altered plutons are poorly constrained, and on both hand‐specimen and thin‐section scales, reveal open‐system Sr isotopic patterns. Isochron ages for the arenite‐lutite and lutite sedimentary associations of the Mathinna Beds, which are intruded by the granitoids, reflect an approach to Sr isotopic equilibrium during regional metamorphism. The metamorphic age (401 ± 7 Ma) of the early Pragian arenite‐lutite association indicates a relatively small time interval between deposition, regional metamorphism and granitoid intrusion. The isotopic age for the lutite sedimentary association (423 ± 22 Ma) is tentatively correlated with a Benambran‐age burial metamorphic event that has not previously been recorded in Tasmania. 相似文献
17.
Oxygen isotopic study of Late Mesozoic cooling of the Mount Barcroft area,central White Mountains,eastern California 总被引：1，自引：0，他引：1
The Middle Jurassic Barcroft mafic granodiorite and Late Cretaceous, ternary-minimum McAfee Creek Granite are important components of the igneous arc sited along the SW North American margin. Bulk-rock analyses of 11 samples of the metaluminous, I-type Barcroft comagmatic suite have an average δ18O value of 7.4±0.6‰ (all values±1σ). Four Barcroft specimens average εNd=?3.6±1.8, 87Sr/86Sr=0.707±0.001. The pluton consists of petrochemically gradational, Ca-amphibole-rich gabbro/diorite, granodiorite, metadiorite, and rare alaskite–aplite; for most of the pluton, oxygen isotope exchange of quartz, feldspar(s), biotite, and Ca-amphibole accompanied local deuteric alteration. Eight specimens of slightly peraluminous granitic rocks of the muscovite-bearing McAfee Creek series have an average δ18O of 8.6±0.5‰. Four McAfee-type samples average εNd=?7.8±1.7, 87Sr/86Sr=0.711±0.004. For both plutons, bulk-rock evidence of exchange with near-surface water is lacking, suggesting ~5–10 km cooling depths. Barcroft minerals exhibit regular oxygen isotopic partitioning from high to low δ18O in the sequence quartz>plagioclase>K-feldspar>>amphibole≥biotite. Along the SE margin of the pluton, quartz and biotite in Lower Cambrian quartzites are higher in δ18O, and show slightly larger fractionations than igneous analogues. Exchange with fluids derived from these heated, contact-metamorphosed country rocks increased bulk 18O/16O ratios of Barcroft border rocks (and constituent plagioclase+subsolidus tremolite–actinolite), especially of granitic dikes transecting the wall rocks. Oxygen isotope thermometry for seven Barcroft pluton quartz–amphibole and six quartz–biotite pairs indicate apparent subsolidus temperatures averaging 519±49 °C. Quartz–plagioclase pairs from two Barcroft granodiorites yield values of 519 and 515 °C. A quartz–biotite pair from a quartzite adjacent to the Barcroft pluton yields an apparent temperature of 511 °C, in agreement with estimates based on contact metamorphic parageneses. Except for its SE margin, Barcroft pluton silicates evidently exchanged oxygen isotopes under local deuteric conditions. Compatible with Ca-amphibole thermobarometric analyses, areal distributions for quartz–plagioclase, quartz–amphibole, and quartz–biotite pairs reveal that putative annealing temperatures are lowest in NE-trending axial portions of the Barcroft body, so it simply cooled inwards. Intrusion ~70 million years later by the McAfee Creek Granite had no discernable effect on δ18O values of Barcroft minerals and bulk rocks. 相似文献
18.
Philip R. Kyle 《Contributions to Mineralogy and Petrology》1980,73(1):89-104
Tholeiitic lava flows (Kirkpatrick Basalts) and dolerite sills and dikes (Ferrar Dolerites) of the Jurassic Ferrar Group from Antarctica and dolerite sills from Tasmania, Australia are characterised by initial strontium isotope ratios ranging from 0.7089 to 0.7153. The mean and standard deviation of 85 analyses is 0.7115±0.0012. Some of the scatter in the initial 87Sr/86Sr ratios can be attributed to sample inhomogeneity, analytical uncertainties and sample alteration. The published major element data show well-defined trends that are consistent with an evolution by fractional crystallization. Recognition of a parental magma is difficult due to the fractionated nature of the rocks. Trace element analyses, particularly the rare earth elements (REE) support a differentiation model. Compared to mid-ocean ridge basalts, Ferrar Group rocks are enriched in light REE. Kirkpatrick Basalts from the central Transantarctic Mountains show significant correlations between initial 87Sr/86Sr ratios and major elements only for SiO2 and CaO. The general lack of strong correlation is the basis for rejecting the possibility of wholesale contamination by sialic material as a possible cause of the high 87Sr/86Sr ratios. Selective contamination of the basaltic magmas is a possibility and cannot be completely discounted. It would probably involve a fluid phase in order to transport and mix the light REE, Rb, 87Sr, and other elements. By analogy with selective contamination of ocean ridge basalts by sea water it is difficult to envisage a similar process acting on magma emplaced in a non-marine environment. Because of the elevated values of the initial 87Sr/86Sr ratios, their similar average value over 2,500 km and the large volume of magma involved (4× 105 km3) a mantle origin for the high Sr ratios is preferred. Models to account for the enrichment of Rb and light REE in the Antarctic mantle during or prior to the Jurassic include:
- addition of continental material from a Palezoic Mesozoic subduction zone;
- metasomatism of volatile elements from the lower mantle; and
- evolution of a mantle with a high Rb/Sr ratio.
19.
R. W. Page 《Australian Journal of Earth Sciences》2013,60(3-4):141-164
A detailed Rb‐Sr total‐rock and mineral and U‐Pb zircon study has been made on suites of Proterozoic silicic volcanic rocks and granitic intrusions, from near Mt Isa, northwest Queensland. Stratigraphically consistent U‐Pb zircon ages within the basement igneous succession show that the oldest recognized crustal development was the outpouring of acid volcanics (Leichhardt Metamorphics) 1865 ± 3 m.y. ago, which are intruded by coeval, epizonal granites and granodiorites (Kalkadoon Granite) whose pooled U‐Pb age is 1862 +27 ‐21 m.y. A younger rhyolitic suite (Argylla Formation) within the basement succession has an age of 1777 ± 7 m.y., and a third acid volcanic unit (Carters Bore Rhyolite), much higher again in the sequence, crystallized 1678 ± 1 m.y. ago. All of these rocks are altered in various degrees by low‐grade metamorphic events, and in at least one area, these events were accompanied by, and can be partly related to, emplacement of a syntectonic, foliated granitic batholith (Wonga Granite) between 1670 and 1625 m.y. ago. Rocks that significantly predate this earliest recognized metamorphism, have had their primary Rb‐Sr total‐rock systematics profoundly disturbed, as evidenced by 10 to 15% lowering of most Rb‐Sr isochron ages, and a general grouping of many of the lowered ages (some of which are in conflict with unequivocal geological relationships) within the 1600–1700 m.y. interval. Such isochrons possess anomalously high initial 87Sr/86Sr ratios, and some have a slightly curved array of isotopic data points. Disturbance of the Rb‐Sr total‐rock ages is attributed primarily to mild hydrothermal leaching, which resulted in the loss of Sr (relatively enriched in 87Sr in the Sr‐poor (high Rb/Sr) rocks as compared with the Sr‐rich rocks). 相似文献
20.
Mohamed M. Abu Anbar 《Mineralogy and Petrology》2009,95(1-2):87-103
The Wadi Nesryin gabbroic intrusion is part of the Neoproterozoic Pan-African basement cropping out in southern Western Sinai of Egypt. The intrusion comprises hornblende gabbro, pyroxene–hornblende gabbro, diorite and appinitic varieties. It exhibits chilled margins against the older rocks represented by fine-grained gabbro and dolerite and belongs to what is known throughout Egypt as the “younger gabbro suite”. Mineralogy, mineral chemistry and whole rock geochemistry indicate that these rocks were derived from tholeiitic magmas with minor calc-alkaline affinity. They have chemical signatures of subduction related arc rocks formed at an active convergent plate margin. They were formed by 15–30% of partial melting of a garnet lherzolite and to a minor extent of spinel-garnet lherzolite sources, modified by fluids related to a subducting slab. Pressure estimates using the amphibole geobarometer indicate that the gabbroic rocks crystallized at pressures between 2.8 and 5.6 kbar (average?=?4.3 kbar). Diorites record lower formation pressures between 1.8 and 3.7 kbar (average?=?3.0 kbar). The temperature estimates calculated by several geothermometers yielded crystallization temperatures ranging from 674°C to 961°C, with an average of about 817°C. The whole rock Rb–Sr isochron age of the Nesryin gabbroic intrusion is 617?±?19 Ma with initial 87Sr/86Sr?=?0.70322?±?0.00004. This age indicates that the mafic–ultramafic plutons in the Pan-African belt in southern Sinai belong to the Egyptian younger gabbros and not to the older metagabbro–diorite complexes or ophiolitic suites. The rocks have low 87Sr/86Sr initial ratios ranging from 0.703141 to 0.703338 and negative ? Sr ranging from ?6.34 to ?9.14. The initial 143Nd/144Nd ratios range from 0.511944 to 0.512145 with positive and high ? Nd values (1.93 to 5.86) reflecting a mantle contribution in their petrogenesis. 相似文献