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1.
An igneous intrusion of 94m thick was discovered intruding into the Silurian sandstone from Tazhong 18 Well. The petroleum
previously preserved in the Silurian sandstone reservoir was altered into black carbonaceous bitumen by abnormally high heat
stress induced by the igneous intrusion. The reflectance of the carbonaceous bitumen reaches as high as 3.54%, indicating
that the bitumen had evolved into a high thermal evolution level. Similar to the Silurian samples from the neighboring Tazhong
11, Tazhong 12, Tazhong 45 and Tazhong 47 wells, the distribution of C 27, C 28 and C 29 steranes of the carbonaceous bitumen is still “V”-shaped and can still be employed as an efficient parameter in oil source
correlation. The “V”-shaped distribution indicates that the hydrocarbons from the Tazhong 18 and the neighboring wells were
all generated from the Middle-Upper Ordovician hydrocarbon source rocks. However, the oil source correlation parameters associated
with and terpanes had been changed greatly by the high heat stress and can no longer be used in oil source correlation. The
δ
13C values of the petroleum from the neighboring wells are between −32.53%. and −33.37%., coincident with those of the Paleozoic
marine petroleum in the Tarim Basin. However, the δ
13C values of the carbonaceous bitumen from the Tazhong 18 Well are between −27.18%. and −29.26%., isotopically much heavier
than the petroleum from the neighboring wells. The content of light hydrocarbons ( nC 14− nC 20) of the saturated hydrocarbon fraction in the carbonaceous bitumen is extremely higher than the content of heavy hydrocarbons.
The light/heavy hydrocarbon ratios (Σ nC 21
−/Σ nC 22
+ are between 4.56 and 39.17. In the saturated fraction, the even numbered hydrocarbons are predominant to the odd numbered,
and the OEP (Odd to Even Predominance) values are between 0.22 and 0.49. However, the content of light hydrocarbons in the
petroleum from the neighboring wells is relatively low and the content of the even numbered hydrocarbons is almost equal to
that of the odd numbered. Compared with the samples from the neighboring wells, the abundance of non-alkylated aromatic hydrocarbons,
such as phenanthrenes, and polycyclic aromatic hydrocarbons (PAHs), such as fluoranthane, pyrene, benzo[a]anthracene and benzofluoranthene,
are relatively high.
Supported by the National Key Basic Research and Development Project (Grant No. 2005CB422103) 相似文献
2.
The results of studying the composition of hydrocarbon gases (C 1–C 5) and organic matter in bottom sediments of the Ivankovo Reservoir in 1995, 2004, and 2005 are given. The methods used in the study include vapor-phase gas chromatography, instrumental pyrolysis gas chromatography, and mass-spectrometry for determining organic carbon δ 13C org. The gas field of bottom sediments in different regions of the reservoir varies widely in terms of gas saturation and the spectrum of hydrocarbon gases. This suggests the heterogeneous composition of organic matter in the sediments and different conditions of its input and transformation processes. The gases were found to contain saturated hydrocarbons from methane to pentane C 1–C 5, including isomers i-C 4 and i-C 5 and unsaturated compounds C 2–C 4. A correlation was found to exist between methane distribution and the distribution of its more high-molecular homologues, which confirms their genetic relationship in bottom sediments. The obtained results show an increase in the rate of microbiological processes and organic matter transformation for most regions in the Ivankovo Reservoir. The only exceptions are the zones of Moshkovichskii Bay and the sections at Gorodnya and Konakovo, where technogenic organic matter is being accumulated. The high information value of hydrocarbon gases as biogeochemical markers of the sources of organic matter and the rates of its transformation is demonstrated. The isotopic composition of organic-matter carbon in the bottom sediments of the Ivankovo Reservoir δ 13C varies from ?26.21 to ?30.86‰. 相似文献
3.
Oils, condensates and natural gases in the Kekeya Field, southeast depression of the Tarim Basin were studied for their geochemical characteristics. According to the distribution analysis of the C2/C3 values with C1/C2 values, C2/C3 values with C1/C3 values, as well as C2/C3 values with dryness index, there are two different types of natural gases in the studied field, which are spatially regularly distributed. One is the oil cracking gas, located on shallow reservoirs over X
25
reservoir, namely Upper oil legs; the other is kerogen cracking gas, located on X
27
reservoirs, X8 reservoirs and E2
k reservoirs, namely Lower oil legs. In addition, the distribution patterns of molar concentration of oils and condensates with different carbon numbers of the n-alkanes in the Kekeya Field indicate that the crude oils have experienced several kinds of secondary alterations, which were closely related to the charging of gaseous hydrocarbons after petroleum accumulation. These results indicate that, based on the research of δ
13C values of individual hydrocarbons, heptane values and isoheptane values of light hydrocarbons and aromatic maturity parameters for oils, condensates and natural gases, oils and gases were charged at different geological time in the Kekeya Field. 相似文献
4.
Hydrocarbon samples taken from bottom sediments of the Barents Sea in summer 2010 in two grounds near the Shtokman Gas Condensate Field were studied. The concentration of hydrocarbons was found to increase with sampling depth along with a decrease in C org concentration. The composition of alkanes had mixed genesis: autochthonous homologues ( n-C 16-C 17) dominated in the low-molecular domain, while oil ones dominated in the high-molecular domain; light polyarenes dominated in the composition of polycyclic aromatic hydrocarbons. The seepage of hydrocarbons from the sedimentary stratum and their transformation in the surface layer of bottom sediments are considered as their major source. The relatively low hydrocarbon concentrations converted to dry mass and in the composition of C org are supposed to be due to a decrease in the intensity of fluid flows, since the hydrocarbon reservoirs of the Shtokman Field are firmly capped by an impermeable stratum of mostly clay rocks. 相似文献
5.
The presented results have been obtained in a study of the concentrations and composition of aliphatic and polycyclic hydrocarbons in bottom sediments of Volga delta branches and in its shallow zone (2009–2010), as well as the Caspian Sea proper (2010–2013). Oil hydrocarbon pollution has been found to manifest itself mostly in Volga delta branches, which, despite the low concentrations (up to 54.5 μg/g), showed higher hydrocarbons share in C org (up to 33.8%), while the composition of alkanes suggested their oil genesis. The geochemical barrier the Volga–the Caspian Sea prevents anthropogenic hydrocarbons from entering the open parts of the Caspian. Bottom sediments in the shallow zone of the Northern Caspian, represented by coarse-grained material, are now polluted by oil hydrocarbons to a lesser extent compared with other areas. The highest concentrations of aliphatic hydrocarbons (up to 178 μg/g) were recorded in the deepsea bottom sediments of Derbent Depression and in depressions of the Middle and Southern Caspian. These areas show a higher concentration of C org (up to 9.884%) and a low concentration of hydrocarbons in C org (up to 0.16%), while odd high-molecular homologues ( n-C 25–C 31) dominate in the composition of alkanes. 相似文献
6.
Concentrations of total hydrocarbons within the boiling point range of the alkanes n-C 14 and n-C 32 were determined in oysters, Pinctada margaratifera, from coastal waters of Kuwait. Levels of petroleum-derived hydrocarbons were highest in an area adjacent to the major oil loading facilities. Whether the use of dispersants to treat minor spills increases levels of incorporation of petroleum compounds into the food webs could not be concluded from the data of this study. Levels of total petroleum-type hydrocarbons in the oysters at this site were equivalent to those in mussels, Mytilus sp., from harbours, bays and urban coastal areas of California. The Kuwaiti oysters lacked a C 28 pentacyclic triterpane that was present in extracts of mussels from southern California that had been recently exposed to a minor spill or to a natural seepage. Levels of DDE and PCB were comparable to those in relatively unpolluted areas of North America. 相似文献
7.
Natural gases discovered up to now in Lishui Sag, the East China Sea Basin, differ greatly in gaseous compositions, of which hydrocarbon gases amount to 2%–94% while non-hydrocarbon gases are dominated by CO2. Their hydrocarbon gases, without exception, contain less than 90% of methane and over 10% of C2
+ heavier hydrocarbons, indicating a wet gas. Carbon isotopic analyses on these hydrocarbon gases showed that δ
13C1, δ
13C2 and δ
13C3 are basically lighter than −44‰, −29‰ and −26‰, respectively. The difference in carbon isotopic values between methane and ethane is great, suggesting a biogenic oil-type gas produced by the mixed organic matter at peak generation. δ
13
\( C_{CO_2 } \)
values of nonhydrocarbon gases are all heavier than −10‰, indicating a typical abiogenic gas. The simulation experiment on hydrocarbon generation of organic matter in a closed gold-tube system showed that the proportion of methane in natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit is obviously higher than that in natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit, consequently the proportion of heavier hydrocarbons of the former is remarkably lower than that of the latter. Moreover, δ
13C1 values of natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit are about 5‰ heavier than those of natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit while δ
13C2 and δ
13C3 values of the former are over 9‰ heavier than those of the latter. Currently the LS36-1 oil-gas pool is the only commercial oil-gas reservoir in Lishui Sag, where carbon isotopic compositions of various hydrocarbon components differ greatly from those of natural gases produced by the Lingfeng Formation organic matter but are very similar to those of natural gases derived from the Yueguifeng Formation organic matter, therefore, natural gases in the LS36-1 oil-gas pool are mainly derived from the Yueguifeng Formation lacustrine source rock rather than the Lingfeng Formation marine or Mingyuefeng Formation coal-measures source rocks. 相似文献
8.
The composition of crude oil in a surficial aquifer was determined in two locations at the Bemidji, MN, spill site. The abundances of 71 individual hydrocarbons varied within 16 locations sampled. Little depletion of these hydrocarbons (relative to the pipeline oil) occurred in the first 10 years after the spill, whereas losses of 25% to 85% of the total measured hydrocarbons occurred after 30 years. The C 6‐30 n‐alkanes, toluene, and o‐xylene were the most depleted hydrocarbons. Some hydrocarbons, such as the n‐C 10–24 cyclohexanes, tri‐ and tetra‐ methylbenzenes, acyclic isoprenoids, and naphthalenes were the least depleted. Benzene was detected at every sampling location 30 years after the spill. Degradation of the oil led to increases in the percent organic carbon and in the δ 13C of the oil. Another method of determining hydrocarbon loss was by normalizing the total measured hydrocarbon concentrations to that of the most conservative analytes. This method indicated that the total measured hydrocarbons were depleted by 47% to 77% and loss of the oil mass over 30 years was 18% to 31%. Differences in hydrocarbon depletion were related to the depth of the oil in the aquifer, local topography, amount of recharge reaching the oil, availability of electron acceptors, and the presence of less permeable soils above the oil. The results from this study indicate that once crude oil has been in the subsurface for a number of years there is no longer a “starting oil concentration” that can be used to understand processes that affect its fate and the transport of hydrocarbons in groundwater. 相似文献
9.
Oils, condensates and natural gases in the Kekeya Field, southeast depression of the Tarim Basin were studied for their geochemical characteristics. According to the distribution analysis of the C 2/C 3 values with C 1/C 2 values, C 2/C 3 values with C 1/C 3 values, as well as C 2/C 3 values with dryness index, there are two different types of natural gases in the studied field, which are spatially regularly distributed. One is the oil cracking gas, located on shallow reservoirs over X 5 2 reservoir, namely Upper oil legs; the other is kerogen cracking gas, located on X 7 2 reservoirs, X 8 reservoirs and E 2 k reservoirs, namely Lower oil legs. In addition, the distribution patterns of molar concentration of oils and condensates with different carbon numbers of the n-alkanes in the Kekeya Field indicate that the crude oils have experienced several kinds of secondary alterations, which were closely related to the charging of gaseous hydrocarbons after petroleum accumulation. These results indicate that, based on the research of δ 13C values of individual hydrocarbons, heptane values and isoheptane values of light hydrocarbons and aromatic maturity parameters for oils, condensates and natural gases, oils and gases were charged at different geological time in the Kekeya Field. 相似文献
10.
The Ordos Basin, the second largest sedimentary basin in China, contains the broad distribution of natural gas types. So far, several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin, each having over 1000×108m3 of proven gas reserves, and several gas pools have also been discovered in the Mesozoic. This paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs, and then discussed their origin. For hydrocarbons preserved in the Upper Paleozoic, the elevated δ
13C values of methane, ethane and propane indicate that the gases would be mainly coal-formed gases; the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different maturity. In the Lower Paleozoic, the δ
13C1 values are mostly similar with those in the Upper Paleozoic, but the δ
13C2 and δ
13C3 values are slightly lighter, suggesting that the gases would be mixing of coal-type gases as a main member and oil-type gases. There are multiple reversals in carbon isotopes for gaseous alkanes, especially abnormal reversal for methane and ethane (i.e. δ
13C1>δ
13C2), inferring that gases would be mixed between high-mature coal-formed gases and oil-type gases. In the Mesozoic, the δ
13C values for gaseous alkanes are enriched in 12C, indicating that the gases are mainly derived from sapropelic sources; the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different maturity. In contrast to the Upper Paleozoic gases, the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane, which may be caused by gases generated from different kerogen types. Finally, according to δ
13C1-R
0 relationship and extremely low total organic carbon contents, the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source, bycontrast, the Upper Paleozoic source as a main gas source is contributed to the Lower Paleozoic gases. 相似文献
11.
Long-chain n-alkenes showing a predominance of n-C 25:1 and n-C 27:1 were detected in recent sediment of Lake Lugu, an oligotrophic alpine lake in Yunnan Province, SW China. The abundances of n-C 25:1 and n-C 27:1 alkenes varied considerably in the sediment core, most obviously in showing higher values during the period of 1821–1982, followed by a significant decrease between 1982 and 2012. Such variations were similar to those of long-chain 1,15-alkyl diols, biomarkers of eustigmatophytes, and a significant correlation was observed between n-C 25:1 (or n-C 27:1) alkene and C 32 1,15-alkyl diol in the sediment core. This correlation and the fact that long-chain n-alkenes in some eustigmatophytes (e.g., Nannochloropsis sp.) were dominated by C 25 and C 27 compounds indicates that eustigmatophytes were the most likely contributor of the long-chain n-alkenes (especially the n-C 25:1 and n-C 27:1 alkenes) in Lake Lugu sediment. Chlorophytes, on the other hand, cannot be excluded as a possible contributor of the long-chain n-alkenes because these algae are common in Lake Lugu and they are known to biosynthesize n-C 27:1 alkene. Productivities for some species of eustigmatophytes and chlorophytes considerably decreased when the lake water was heavily influenced by catchment soil erosion and anthropogenic sewage inputs. 相似文献
12.
The compound-specific stable carbon isotope compositions(δ~(13)C) of leaf wax n-alkanes from two short sediment cores recovered off the Pearl River estuary(PRE) were analyzed to check for their capability of indicating decadal scale catchment environmental change. Sedimentary long-chain n-alkanes exhibited an odd-over-even predominance, with a maximum at n-C_(29) or n-C_(31), indicating their leaf wax origin was from vascular plants. The δ~(13)C values of C_(29) and C_(31) n-alkane in all the sediment samples were in the range of -28.8‰ to -31.2‰, consistent with the C_3 plant-dominated vegetation in the Pearl River catchments. The time series of δ~(13)C records from the two cores were comparable and displayed a decreasing trend from the early 20 th century to the end of the 1970s, followed by a reversal in that change leading to continued increase for ca. 15 years. After being corrected for the effect of atmospheric CO_2 rise and δ~(13)C_(atm) decline, the δ~(13)C_(29) records largely retained their raw changing pattern; the post-1980 increase being more conspicuous. The slightly decreasing trend in corrected δ~(13)C records before around 1980 may have been caused by an increase in precipitation, whereas the subsequent increase of δ~(13)C is likely associated with the observed dry climate and/or intensive anthropogenic deforestation. Our results thus demonstrate that leaf wax n-alkanes buried in the sediments off the PRE may well reflect change in the regional climate and/or human activity in the river catchments over the past century. 相似文献
13.
The composition characteristics of light hydrocarbons from crude oil, chloroform bitumen A, saturated hydrocarbon fraction, aromatic hydrocarbon fraction, and asphaltene fraction during cracking have been studied systematically. The results revealed that the content of n-alkanes, branched alkanes and cycloalkanes in light hydrocarbons from the samples gradually decreased as the simulation temperature increased, and finally almost depleted completely, while the abundance of methane, benzene and its homologues increased obviously and became the main products. The ratios of benzene/ n-hexane and toluene/ n-heptane can be used as measures for oil cracking levels. Variation characteristics of maturity parameters of light hydrocarbons, for example, iC 4/ nC 4, iC 5/ nC 5, isoheptane value, 2,2-DMC 4/ nC 6, and 2-MC 6+3-MC 6/ nC 7 for different samples with increasing pyrolysis temperature, are consistent with those in petroleum reservoirs, indicating that these parameters may be efficient maturity index. 相似文献
14.
This paper discusses the kinetic fractionation, composition and distribution characteristics of carbon and hydrogen isotopes for various alkane gases formed in different environments, by different mecha- nisms and from different sources in nature. It is demonstrated that the biodegradation or thermode- gradation of complex high-molecule sedimentary organic material can form microbial gas or thermogenic gas. The δ 13C1 value ranges from -110‰ to -50‰ for microbial gases but from -50‰ to -35‰ (even heavier) f... 相似文献
15.
Aromatic hydrocarbons are generally main distillation of crude oil and organic extract of source rocks. Bicyclic and tricyclic aromatic hydrocarbons can be purified by two-step method of chromatography on alumina. Carbon isotopic composition of individual aromatic hydrocarbons is affected not only by thermal maturity, but also by organic matter input, depositional environment, and hydrocarbon generation process based on the GC-IRMS analysis of Upper Ordovician, Lower Ordovician, and Cambrian source rocks in different areas in the Tarim Basin, western China. The subgroups of aromatic hydrocarbons as well as individual aromatic compound, such as 1-MP, 9-MP, and 2,6-DMP from Cambrian-Lower Ordovician section show more depleted 13 C distribution. The 13 C value difference between Cambrian-Lower Ordovician section and Upper Ordovician source rocks is up to 16.1‰ for subgroups and 14‰ for individual compounds. It can provide strong evidence for oil source correlation by combing the 13 C value and biomarker distribution of different oil and source rocks from different strata in the Tarim Basin. Most oils from Tazhong area have geochemical characteristics such as more negative 13C9-MP value, poor gammacerane, and abundant homohopanes, which indicate that Upper Ordovician source rock is the main source rock. In contrast, oils from Tadong area and some oils from Tazhong area have geochemical characteristics such as high 13C9-MP value, abundant gammacerane, and poor homohopanes, which suggest that the major contributor is Cambrian-Lower Ordovician source rock. 相似文献
16.
Biodegradation of polycyclic aromatic hydrocarbons (PAHs) in contaminated sediment is an attractive remediation technique and its success depends on biodegradation kinetics, and the optimal condition for the PAH-degrading isolates; however, information on this aspect is still scarce. The effects of multi-factors on biodegradation of phenanthrene, a 3-ring model PAH, in contaminated sediment slurry by Sphingomonas sp. a bacterial strain isolated from surface mangrove sediment, were investigated using the orthogonal experimental design (form L 16(4 5)). The most significant factors were salinity and inoculum size, while the effects of phenanthrene concentrations, nutrient addition and temperatures were insignificant. The optimal biodegradation condition in contaminated mangrove sediment slurry was 30 °C, 15 ppt salinity, a carbon/nitrogen ratio of 100:1 (the background ratio in sediment) and an inoculum size of 10 6 most probable number g −1 sediment. The phenanthrene biodegradation could be best described by the first order rate model, C = C0e −kt, where k (the rate constant) is equaled to 0.1185, under the optimal condition. The kinetic model was verified and its validity in predicting biodegradation by Sphingomonas sp. at various phenanthrene concentrations was proved by experimental data. 相似文献
17.
The Xushen gas field, located in the north of Songliao Basin, is a potential giant gas area for China in the future. Its proved reserves have exceeded 1000×108 m3 by the end of 2005. But, the origin of natural gases from the deep strata is still in debating. Epimetamorphic rocks as a potential gas source are widely spreading in the northern basement of Songliao Basin. According to pyrolysis experiments for these rocks in the semi-confined system, gas production and geochemistry of alkane gases are discussed in this paper. The Carboniferous-Permian epimetamorphic rocks were heated from 300°C to 550°C, with temperature interval of 50°C. The gas production was quantified and measured for chemical and carbon isotopic compositions. Results show that δ
13C1 is less than −20‰, carbon isotope trend of alkane gas is δ
13C1<δ
13C2<δ
13C3 or δ
13C1<δ
13C2>δ
13C3, these features suggest that the gas would be coal-type gas at high-over maturity, not be inorganic gas with reversal trend of gaseous alkanes (δ
13C1>δ
13C2>δ
13C3). These characteristics of carbon isotopes are similar with the natural gas from the basin basement, but disagree with gas from the Xingcheng reservoir. Thus, the mixing gases from the pyrolysis gas with coal-typed gases at high-over maturity or oil-typed gases do not cause the reversal trend of carbon isotopes. The gas generation intensity for epimetamorphic rocks is 3.0×108–23.8×108 m3/km2, corresponding to R
o from 2.0% to 3.5% for organic matter. 相似文献
18.
The composition of hydrocarbons (aliphatic and polycyclic aromatic) is studied in the surface layer of bottom sediments of the Ivankovo Reservoir. Their concentrations are found to be high both per dry mass and in the composition of C org. The concentration range was 0.42 to 28.15% for C org, 141.9 to 3451.8 μg/g for aliphatic hydrocarbons (0.2–51.2% C org), and 28.2–9161 ng/g for polycyclic aromatic hydrocarbons ((0.04–6.58) × 10 ?3 % C org). The distribution of hydrocarbons is shown to be determined not only by the lithologic type of sediments, but also by their input from petroleum and pyrogenic sources. 相似文献
19.
Petroleum mainly comprises carbon and hydrogen elements. The stable carbon isotopic analysis for whole oil was undertaken as early as the 1930s. After decades, the stable carbon isotopic analytical methods have been developed from analysis for whole oil and oil fractions (e.g., saturated, aromatic and polar frac-tions) into compound-specific isotopic analysis with the emergence of the newly developed GC-C-IRMS analytical technique. Especially, by using com-pound-specific isotopic analytical… 相似文献
20.
The general expression for gravity and magnetic anomalies over thin sheets and sloping contacts may be expressed as a polynomial of the form Fx
2+C 1Fx+C 2F+C 3x 3+C 4x 2+C 5x+C 6. The initial parameters of the source are obtained from the coefficients C
1, C 2,..., C 6 which may be solved by inverting a 6×6 matrix. The initial parameters are modified by successive iteration process using the difference formula until the root mean square error between the observed and calculated anomalies is a minimum. The regional background which may be in the form of a polynomial is estimated by the computer itself. This method is applied on a number of field anomalies and is found to yield reliable estimates of depth and other parameters of the source. 相似文献
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