共查询到19条相似文献，搜索用时 125 毫秒
1.
北京、郑州和深圳三城市空气中气溶胶单颗粒特征的扫描电镜分析 总被引：1，自引：0，他引：1
分别采集北京、深圳和郑州3个城市气溶胶样品,使用场发射扫锚电镜-能谱仪观察气溶胶单颗粒的显微形貌和元素组成,并利用图像分析系统对PM2.5的粒径进行了分析。结果表明,城市气溶胶单颗粒类型以矿物颗粒、烟尘和球形颗粒(飞灰和二次粒子)为主。对比3个城市气溶胶中不同颗粒类型数量百分比发现,矿物颗粒数量最多的城市是北京,飞灰和烟尘数量最多的城市是郑州,而规则矿物颗粒数量最多的城市是深圳。3个城市气溶胶单颗粒的数量-粒径分布均呈单峰分布。深圳气溶胶中颗粒物的粒径相对较小,其次为郑州、北京。3个城市气溶胶中颗粒物来源不同程度上都受到交通污染源影响,而燃煤源对北京和郑州气溶胶中颗粒物来源影响仍然不容忽视。 相似文献
2.
综述了大气气溶胶颗粒物的特征、颗粒物的界面反应与矿物协同演化意义;重点介绍了大气颗粒物粒径分布和矿物成分,以及常见有毒有害气体的界面反应产物特征与关键化学过程;总结了矿物颗粒在大气气溶胶形成过程中汇聚、调控、催化的作用,以及颗粒物与大气中SO2、NOx的协同反应机制;分析了微纳米颗粒对二次有机气溶胶形成的影响,以及大气矿物相颗粒界面反应产物组合及协同演化作用.可为进一步研究大气颗粒物与大气中痕量污染气体反应形成二次气溶胶进而影响大气化学组成的过程提供指导,对深入探讨大气矿物颗粒表面特性在复合污染物中多介质反应的微界面化学过程,矿物尘-污染物气溶胶体系在雾-霾形成、转换、新生粒子和阻断行为的复合作用具有重要的环境学意义. 相似文献
3.
大气气溶胶密度观测研究进展 总被引：1，自引：0，他引：1
大气气溶胶的气候效应、环境效应、健康效应均与其物理化学性质密切相关,其中,密度是大气气溶胶重要的物理性质之一。密度影响着粒子的输送过程和在人体肺部的沉积过程。密度可以分别将电迁移率粒径和空气动力学粒径,数浓度和质量浓度联系起来。密度的变化可为气溶胶的形成和老化过程提供信息,细粒子分粒径的密度还可为大气过程和化学组分的演化提供参考依据。因此,研究大气气溶胶密度对了解气溶胶化学组分,评估气溶胶形成过程以及探究气溶胶在人体内的沉积效率具有重要的意义。由于国内在该领域研究总体较少,对大气气溶胶密度的定义、研究方法、国内外研究进展以及影响因素和变化特征等进行较为系统的总结,对未来开展大气气溶胶密度的观测和研究十分必要。 相似文献
4.
《地球化学》2020,(3)
基于2017年1月4日至7日成都市一次重霾污染过程的系留汽艇探测的低层大气气象要素和大气颗粒物垂直探空加密观测资料,分析了大气边界层结构及气溶胶垂直分布。结果表明,此次重霾污染期间,大气边界层昼夜变化特征基本消失。稳定边界层结构出现25次,对流边界层结构仅出现3次,大气边界层结构趋于稳定,边界层高度普遍在700 m以下。霾污染发生、维持及消散阶段大气边界层气溶胶垂直结构具有明显差异。霾污染发生阶段,大气边界层气溶胶粗、细粒子主要集中在300m高度以下,近地面层大气气溶胶粒子累积触发霾污染事件;霾维持阶段,大气颗粒物粒子浓度数垂直方向趋于一致,大气边界层稳定结构中存在强的大气垂直混合作用;在霾消散阶段,较高处的气溶胶粒子浓度最先下降,且下降幅度最大,表明对流层自由大气作用对霾污染消散具有影响。大气边界层风速的增大加剧了大气传输扩散。温度与大气颗粒物浓度在近地层呈负相关关系,在100m高度以上呈正相关关系。大气边界层低层偏冷,高层偏暖的稳定大气热力层结减弱了大气污染物的垂直扩散。相对湿度的增加有利于气溶胶粒子的吸湿增长和液相化学反应,加剧了霾污染。 相似文献
5.
生物气溶胶对全球气候、空气质量、大气过程和人体健康均具有重要影响。每年爆发的沙尘事件,使得生物气溶胶可借助沙尘进行长距离输运,从而影响到下风向地区生物气溶胶的浓度和性质。综述了沙尘天气下生物气溶胶中微生物的浓度、特性和分布特征的研究现状。已有研究显示,沙尘发生时,生物气溶胶中不同类别微生物的组成比例会有显著变化,细菌和真菌相对贡献随之改变。可培养细菌、真菌和总微生物浓度,均在沙尘天气下显著增加,但不同地区不同种类微生物在沙尘天气下的增加幅度相差很大。生物气溶胶中微生物主要分布于粗粒子中,其粒径分布受到沙尘天气的较大影响,而且不同种类微生物粒径分布的变化并不相同。沙尘发生时,生物气溶胶中的微生物群落结构与优势微生物也会发生明显改变。沙尘天气对生物气溶胶浓度、粒径分布、群落结构和活性的影响程度和影响机制,还需要进一步深入研究。 相似文献
6.
气溶胶在雪面干沉积作用的量化描述一般采用其干沉降速度,它是指气溶胶从大气中消失之前的沉降末速度.估算气溶胶干沉降速度是评价气溶胶在大气中滞留时间长短的重要依据,而气溶胶在大气中滞留时间的长短会对气候造成影响.回顾了气溶胶在冰雪环境下干沉降速度的理论研究,重点阐述了近年来气溶胶在冰雪面上干沉降速度的研究进展,并指出了气溶胶在冰雪面上干沉降速度测量的难点和模型方面的缺陷.在冰雪界面上,以气溶胶沉降到冰雪面为例的设计模型认为,融化冰雪面存在液泡水膜与否会对化学元素的干沉降速度造成影响. 相似文献
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8.
临安一次沙尘暴过程影响气溶胶物理化学特性演变的初步分析 总被引：16，自引：4，他引：12
文章利用2002年3月29日～4月4日在浙江临安大气本底污染监测站观测的气溶胶粒子质量谱、离子与元素成分的数据,结合TOMS卫星的气溶胶指数资料和轨迹模式,重点分析在北方沙尘暴输送影响期间临安气溶胶质量浓度尺度分布的演变特点以及气溶胶化学成分与不同空气来源的关系。初步分析结果显示,受北方沙尘暴天气影响,临安气溶胶质量浓度、离子、元素浓度有明显的尺度分布演变。这种演变与污染物来源和大气污染物的气粒转化有关。沙尘影响前和结束后临安地区气溶胶主要以细粒子为主(<2.1μm),峰值粒径0.65～2.1μm,而受北方地区的沙尘暴影响,峰值粒径偏移到2.1～3.3μm,且在7～11μm间出现另一个峰值,同时临安气溶胶粗粒子中矿物元素显著增加。从离子成分看,在整个观测期间SO2-4与NH+4在细粒子段有很好的一致性,而SO2-4,NO-3与Ca2+在粗粒子段有很好的相关,尤其是沙尘影响期间NO-3与Ca2+有很好的对应关系,表现出较明显的表面非均相反应特征 相似文献
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应用场发射扫描电镜(FESEM)对青藏高原纳木错综合观测站和香格里拉本底站2011年7～8月份不同天气情况下收集的气溶胶样品进行研究。结果表明,区域内气溶胶单颗粒类型主要包括烟尘集合体、球形颗粒(焦油球、燃煤飞灰)、似球形颗粒、矿物颗粒、生物颗粒等,香格里拉的球形颗粒中出现了飞灰颗粒,而纳木错样品中没有。纳木错气溶胶颗粒的数量-粒度峰值和体积-粒度峰值分别出现在0.2～0.3 μm和1～2.5 μm,矿物颗粒数量和体积最多,分别占44.4%和61.7%。香格里拉气溶胶颗粒的数量-粒度峰值和体积-粒度峰值都呈现双峰分布,主峰均分布在>2.5 μm范围,矿物颗粒数量和体积最多,分别占51.7%和58.7%。细粒子和粗粒子分别为纳木错和香格里拉气溶胶的主要类型。纳木错气溶胶中矿物颗粒最多,数量百分比为44.4%,其次为烟尘集合体(29.5%)和球形颗粒(26.1%),香格里拉气溶胶中矿物颗粒数量百分比为51.7%,其次为球形颗粒(29%)和烟尘集合体(19.3%);纳木错气溶胶总颗粒物主要分布在0.2～0.3 μm粒径范围中,数量百分比为32.59%,其中矿物颗粒最多(15%),其次为球形颗粒(11.5%)和烟尘集合体(6.1%)。香格里拉气溶胶颗粒物主要分布在>2.5 μm粒径范围中,数量百分比为37.5%,其中矿物颗粒最多(17.9%),其次为球形颗粒(10%)和烟尘集合体(9.6%)。 相似文献
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《Sedimentology》2018,65(2):335-359
Predominantly fine‐grained strata were deposited in the Smith Bank Formation (Early Triassic) in the Central North Sea area of the Northern Permian Basin. Previously regarded as monotonous red claystone, examination of continuous core reveals abundant stratification, significant variation in colour, siltstone as the prevalent average grain size, and claystone is rare. Loessite occurs beyond the north‐western lacustrine margin, and aerosol dust has inundated clay pellets derived from aeolian reworking of the desiccated lake floor. The loessite has limited evidence of pluvial reworking but rare fossil roots testify to sufficient moisture to sustain plants. Loessite has not previously been differentiated successfully from other fine‐grained strata in the subsurface, but this study defines the presence of random grain‐fabric orientation as an intrinsic unequivocal characteristic of loessite that formed during air‐fall deposition of aerosol dust. Comparison with outcrop data verifies the utility of grain fabric to differentiate loessite. Tosudite, an aluminous di‐octahedral regularly ordered mixed‐layer chlorite/smectite, which is rare in sedimentary rock, forms a significant proportion (10 to 21%) of the clay mineral fraction of loessite along with a similar quantity of kaolinite. In all other samples, only illite and chlorite are identified, which is typical of fine‐grained Triassic strata. In a location, close to the southern lake margin, lacustrine strata are characterized by fining‐upward couplets of very fine‐grained sandstone into siltstone and mudstone, with occasional desiccated surfaces. Small sand injections and associated sand extrusions are common and indicate periodic fluidization of sand. Precise stratigraphic location of the Smith Bank Formation is problematic because of extremely sparse fossil preservation; however, there is no sedimentological evidence for a period of hyperaridity known from the early Olenekian in continental Europe, which may mean that the North Permian Basin was never hyperarid or that the Smith Bank Formation is restricted to the Induan. 相似文献
12.
对2006年4月17日北京降尘的粒度和磁学性质进行深入分析,提出降尘磁化率相对黄土样品较高是现代降尘磁化率的特点,源区表土磁化率普遍较高是本次降尘磁化率值高的主要原因,污染产生的磁性物质对其也有一定的影响。同时通过对比几次降尘的粒度特征和传输方式提出粒度可以有效地指示源区的变化。结合降尘的粒度、磁化率分析与沙尘暴的监测信息和卫星云图,认为此次降尘粒度为0.8～20.0μm的组分可能是来自内蒙古西部的物质;20～70μm与>70μm的组分可能是来自距离北京较近的河北北部和内蒙古中部发生强烈沙尘暴的地区。 相似文献
13.
G. I. Gorchakov A. V. Vasiliev K. S. Verichev E. G. Semoutnikova A. V. Karpov 《Doklady Earth Sciences》2016,471(1):1158-1163
It is shown that the absorption capacity of smoke aerosol during mass forest and forest–peat fires is determined to a considerable degree by light absorbing organic compounds or brown carbon. According to the data from the AERONET global network of stations [1], the absorption spectra of smoke aerosol vary significantly if airborne particulate matter is contained in brown carbon. It is established that in several cases, the absorption spectra of smoke aerosol are approximated with satisfactory accuracy by exponents. It is shown that the finely dispersed (submicron) fraction of the smoke aerosol makes a major contribution to its optical characteristics in the 0.44–1.02 μm spectral region. Strong variation in the single scattering albedo is discovered in the presence of brown carbon in the smoke aerosol. It is shown that the optical characteristics of coarsely dispersed and finely dispersed fractions of smoke aerosol differ considerably. 相似文献
14.
P. Sivaprasad C. A. Babu A. A. Samah P. R. Jayakrishnan 《Arabian Journal of Geosciences》2017,10(19):422
The paper addresses influence of dust particles on the aerosol loading over the major deserts in the northern hemisphere. The role of dust aerosols in the total aerosol concentration and size distribution of the particles are analysed. It is observed that the aerosol loading is high in the northern hemisphere of which the deserts and adjoining areas in Asia and Africa play a leading role. Over the entire oceanic region, except some parts of the Atlantic Ocean near to the West coast of Africa and the Arabian Sea, aerosol loading is less. The Sahara Desert is the prominent source of dust aerosols throughout the year. The deserts of Asia are also prominent sources of dust aerosols on a global basis. Above 70% of the total aerosol optical depth (AOD) is contributed by the dust particles, reaching to around 90% during spring months March, April and May over the Sahara Desert, which is the major source of dust aerosols. Goddard Chemistry Aerosol Radiation and Transport model is used to estimate the dust aerosol concentration over the deserts of Asia and Africa. The model output almost agrees with the regions of dust loading obtained from the Envisat/SCIAMACHY. Hence, the model is reliable in estimating the dust aerosol loading over the major dust aerosol sources. The major portion of the total dust loading belongs to coarse mode particles. 相似文献
15.
K. Niranjan V. Sreekanth B. L. Madhavan T. Anjana Devi B. Spandana 《Journal of Earth System Science》2008,117(1):421-427
Realizing the importance of aerosol physical properties at the adjoining continental and coastal locations in the airmass pathways onto the oceanic region, extensive measurements of aerosol physical properties were made at Visakhapatnam (17.7°N, 83.3°E), an eastern coastal location in peninsular India during the ICARB period. The temporal variations of aerosol optical depth, near surface aerosol mass size distributions and BC mass concentrations show significantly higher aerosol optical depth and near surface mass concentrations during the first and last weeks of April 2007. The mean BC mass fraction in the fine mode aerosol was around 11%. The aerosol back scatter profiles derived from Micro Pulse Lidar indicate a clear airmass subsidence on the days with higher aerosol optical depths and near surface mass fraction. A comparison of the temporal variation of the aerosol properties at Visakhapatnam with the MODIS derived aerosol optical depth along the cruise locations indicates a resemblance in the temporal variation suggesting that the aerosol transport from the eastern coastal regions of peninsular India could significantly affect the aerosol optical properties at the near coastal oceanic regions and that the affect significantly reduced at the farther regions. 相似文献
16.
R. Khondoker D. Weiss T. van de Flierdt M. Rehkämper K. Kreissig B.J. Coles S. Strekopytov E. Humphreys-Williams S. Dong A. Bory V. Bout-Roumazeilles P. Smichowski P. Cid-Agüero M. Babinski R. Losno F. Monna 《Chemie der Erde / Geochemistry》2018,78(3):372-384
Improving the geochemical database available for characterising potential natural and anthropogenic aerosol sources from South America and Southern Africa is a critical precondition for studies aimed at understanding trace metal controls on the marine biogeochemical cycles of the South Atlantic Ocean. We here present new elemental and isotopic data for a wide range of sample types from South America and Southern Africa that are potentially important aerosol sources. This includes road dust from Buenos Aires and lichen samples from Johannesburg, soil dust from Patagonia, volcanic ash from the Andean volcanic belt, and aerosol samples from São Paulo. All samples were investigated for major (Al, Ca, Fe, Mg, Na, K, Mn) and trace element (Cd, Co, Cr, Cu, Ni, Pb, REE, Sc, Th, Y, V, Zn) concentrations and Nd and Pb isotopic compositions. We show that diagrams of 208Pb/207Pb vs. εNd, 208Pb/207Pb vs. Pb/Al, 1/[Pb], Zn/Al, Cd/Al, Cu/Al, and εNd vs. Pb/Al, and 1/[Nd] are best suited to separate South American and South African source regions as well as natural and anthropogenic sources. A subset of samples from Patagonia and the Andes was additionally subjected to separation of a fine (<5?μm) fraction and compared to the composition of the bulk sample. We show that differences in the geochemical signature of bulk samples between individual regions and source types are significantly larger than between grain sizes. Jointly, these findings present an important step forward towards a quantitative assessment of aeolian trace metal inputs to the South Atlantic Ocean. 相似文献
17.
马兰黄土平均沉积速率为0.078毫米/年.但又可分为三个沉积速率层段,即上部中等,中部最大,下部最小.沉积速率的变化与黄土颗粒粒径有关.粒度粗,分选好.沉积速率最小.反之.沉积速率则大.更重要的是,沉积速率受控于古气候的演化.气候愈旱干、寒冷.沉降黄土的次数增多.沉积速率就愈大.相反.暖湿气候则不利于黄土沉积.黄土-古土壤系列反映了这期间气候韵律和黄土沉积速率的关系. 相似文献
18.
论述了将气溶胶理论和技术应用于深部隐伏矿找矿的基本问题。深部矿物质能够穿越矿体覆盖层到达地表,主要是通过气体携带质粒向上迁移,这种迁移发生的基本条件是质粒可以稳定悬浮于气体中并随之流动。气溶胶理论表明,直径在0.1~2.5μm的质粒在气体中最稳定,质粒过小或过粗都不可能较长时间悬浮于气体中。气溶胶的另一个理论要点是,直径小于2.5μm的固体质粒不可能通过机械碾磨方式形成。这两个气溶胶理论要点是深部金属矿生成气溶胶级别的质粒并进入气体向上迁移的基础。将气溶胶理论和技术应用于新疆金窝子隐伏金矿床找矿试验,结果表明,在210隐伏矿上方和矿体倾斜面上方有明显的金异常和金伴生元素异常,异常程度高,出露面积大。这一实验证明了通过提取吸附于地表土壤中的地气溶胶质粒,并分析其元素含量的气溶胶找矿方法,具有良好效果。 相似文献
19.
云南高原湖泊表层沉积物粒度特征及环境指示意义 总被引：5，自引：1，他引：4
选取云南15个高原湖泊,利用瑞典产HTH重力采样器提取沉积物短钻,取顶部0~0.5 cm作为湖泊现代沉积物进行粒度分析并利用分析软件对粒度频率曲线进行拟合,探讨各组分的沉积特征和环境指示意义。结果显示,滇池等15个云南湖泊表层沉积物频率曲线呈多峰态,含有2至5个组分,从细到粗分别为黏土组分（C1）、细粉砂组分（C2）、粉砂组分（C3）、细-中砂组分（C4）、粗砂组分（C5）,拟合众数粒径范围为0.6~423.0 μm。C1组分来自大气中长期悬浮的超细粉尘和气溶胶,通过自然沉降和降水进入湖泊水体,反映西南地区大气粉尘背景值;C2和C3是湖泊沉积物中的主要组分,反映流域内降水和水动力大小;C4和C5组分只出现在洱海、滇池、差黑海等部分湖泊湖心沉积物中,且含量非常低,该组分与湖泊水动力密切相关。对于滇池、抚仙湖等大型湖泊而言,粗颗粒进入湖心需两个过程:从流域地表进入湖泊水体的输入过程和从湖滨到达湖心的传输过程。湖心沉积物中粗粒含量主要受第二个过程影响,而该过程的强弱与湖流、水深、湖盆坡度等因素有关。西南地区干旱背景下湖泊快速收缩直至消失时,降水量的大幅减少使得地表径流动力减弱,加之大气环流偏弱以及水生植物覆盖面积比例增大,湖水动力减弱,由湖滨向湖心传输的物质以细粒碎屑为主。位于山地地区的小型湖泊,由于汇水面积有限、地形坡度较大,坡面径流可将地表风化碎屑物带入湖盆甚至湖心位置,这类湖泊沉积物中粗粒物质的增加反映流域内降水量或降水强度增大。 相似文献