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1.
Monte-Carlo simulations were used to assess the extent of shortterm alkalinity depressions occuring in Sierra Nevada lakes due to acidic deposition events. The Episodic Event Model (EEM) was used to simulate spring snowmelt events. Snow course data, precipitation data and lake acidification surveys were used to derive values for the EEM parameters. Spring snowmelt events were shown to have great impacts on the water quality of Sierran lakes. Lakes are likely to be most affected by the early-spring snowmelt event because the epilimnion depth is at a minimum, which indicates minimum dilution. Under annual average loading conditions, no Sierran lake has been reported as acidic although 29% of the lakes have alkalinities less than 40 µeq/L indicating a sensitivity to acidification. In simulations of early-spring snowmelt events, using present-day acidic loading conditions, it was estimated 79% ± 9% of the lakes would experience shortterm lake alkalinity depressions to levels less than 40 µeq/L. The results provided by the model simulations are valuable in establishing upper and lower limits on the extent of possible episodic acidification to lake-resources-at-risk. The most critical parameters controlling the magnitude of lake alkalinity depressions during snowmelt episodic events are a) the lake area to watershed area ratio — a measure of input loading, and b) the epilimnion volume — a measure of dilution and mixing.  相似文献   

2.
Climate variability during the Mid‐Late Holocene has influenced the activity of geomorphic processes in the current periglacial belt of the Sierra Nevada. We studied two types of sedimentary records that reveal a synchronous timing for slope instability in this high semi‐arid massif: solifluction landforms and mountain lake sediments. Lithological and sedimentological properties of both records have recorded numerous cycles of different magnitude of slope processes in the massif. Solifluction deposits record seven phases of solifluction activity and soil development during the last 7 ka bp and lake sediments show evidence of eight periods with increased geomorphic activity in the catchments over the last 6 ka bp . Although present‐day climate conditions do not promote active solifluction processes in the Sierra Nevada, colder and wetter periods during the Holocene triggered solifluction and transported coarse‐grained sediments into the lakes. By contrast, warm phases favoured soil formation and spread an incipient vegetation cover over the headwaters of the highest valleys, diminishing the grain size of the particles reaching the lakes. Lake sediments record an aridification trend in the massif intensifying since 4·2 ka bp that has conditioned solifluction activity to shift gradually to higher elevations. During major cooler phases such as the Little Ice Age active solifluction was recorded back down to 2500 m altitude. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

3.
Understanding the extent to which local factors, including bedrock and structure, govern catchment denudation in mountainous environments as opposed to broader climate or tectonic patterns provides insight into how landscapes evolve as sediment is generated and transported through them, and whether they have approached steady-state equilibrium. We measured beryllium-10 (10Be) concentrations in 21 sediment samples from glaciated footwall and hanging wall catchments, including a set of nested catchments, and 12 bedrock samples in the Puga and Tso Morari half-grabens located in the high-elevation, arid Zanskar region of northern India. In the Puga half-graben where catchments are underlain by quartzo-feldspathic gneissic bedrock, bedrock along catchment divides is eroding very slowly, about 5 m/Ma, due to extreme aridity and 10Be concentrations in catchment sediments are the highest (~60–90 × 105 atoms/g SiO2) as colluvium accumulates on hillslopes, decoupled from their ephemeral streams. At Puga, 10Be concentrations and the average erosion rates of a set of six nested catchments demonstrate that catchment denudation is transport-limited as sediment stagnates on lower slopes before reaching the catchment outlet. In the Tso Morari half-graben, gneissic bedrock is also eroding very slowly but 10Be concentrations in sediments in catchments underlain by low grade meta-sedimentary rocks, are significantly lower (~10–35 × 105 atoms/g SiO2). In these arid, high-elevation environments, 10Be concentrations in catchment sediments have more to do with bedrock weathering and transport times than steady-state denudation rates. © 2020 John Wiley & Sons, Ltd.  相似文献   

4.
Phosphorus (P) concentrations in sediments and in surface and interstitial water from three gravel bars in a large river (Garonne River, southern France) were measured daily, downstream of a wastewater treatment plant for a city of 740 000 inhabitants (Toulouse). Measurements were made of vertical hydraulic gradient (VHG), total dissolved phosphorus (TDP), soluble reactive phosphorus (SRP) and total phosphorus (TP) in water and of three extractable forms of phosphorus (water extractable, NaOH extractable and H2SO4 extractable) in hyporheic sediments from the gravel bars. Dissolved phosphorus was the major contributor to TP (74–79%) in both interstitial and surface waters on all sampling dates, and in most cases surface water P concentrations were significantly higher than interstitial concentrations. Hyporheic sediment TP concentrations ranged between 269 and 465 µg g?1 and were highest in fine sediment fractions. Acid‐extractable P, a non‐bioavailable form, represented at least 95% of sediment TP. A positive relationship was observed between VHG and TP in two of the gravel bars, with wells that were strongly downwelling having lower TP concentrations. These results suggest that in downwelling zones, hyporheic sediments can trap surface‐derived dissolved P, and that much of this P becomes stored in refractory particulate forms. Bioavailable P is mainly present in dissolved form and only occupies a small fraction of total P, with particulate P comprising the majority of total P. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

5.
Three shallow basins in Huizhou West Lake, China, were compared with respect to phosphorus (P) cycling between sediment and water, binding forms of P in sediment, and macrophyte biomass. The basins had similar sediments and similar depths, but two of the basins were restored by carp fish removal and macrophyte transplantation. These two basins have had clear water, low Chl.a and high macrophyte coverage for seven and ten years, whilst the unrestored control basin had turbid water and higher Chl.a. Judged by diffusive ammonium efflux, sediments in restored basins had higher mineralization rates than the unrestored basin, but the release of total dissolved P were more similar. However, sediments of restored basins released primarily dissolved organic P, while the sediment from the unrestored basin only released dissolved inorganic P. One third of the P release in the unrestored basin occurred from resuspended sediment, while this pathway contributed less than 3% in restored basins where resuspension rates were 10 times lower and the surface sediments affinity for phosphate higher. Besides from the presence of carps in the unrestored basin, the main differences were a large pool of P (700–850 mg P m−2) in macrophyte biomass and a smaller pool (∼150 mg m−2) as loosely adsorbed P in the sediment of restored basins than in the unrestored (0 in macrophytes and 350 mg P m−2 as loosely adsorbed). Also, a tendency of higher concentrations of oxidized iron was observed in the surface sediment from restored basins. The study underlines the potential of trophic structure changes to alter internal nutrient cycling in shallow lakes.  相似文献   

6.
Two expeditions (October 1989 and May 1992) were carried out to two points of the main Amazon River channel and four tributaries. The Solimões and Madeira rivers, taking their origin in the Andes, are whitewater rivers. The Negro River is a typical acid, blackwater river. The Trombetas River flows through bauxite‐rich areas, and is characterized by low concentrations of dissolved humic substances. The 238U, 234U, 232Th and 230Th activities were recorded from dissolved, suspended particulate phases and river bank sediments. The latter were analysed for their 226Ra, 228Ra and 210Pb contents, and also subjected to leaching with 0·2 M hydroxylamine–hydrochloride solution to determine the concentrations of radionuclides bound to amorphous Fe hydroxides and Mn oxides and hydroxides. The dissolved U average concentration in the Amazon system is ten times lower than the mean world river concentration. The uranium concentration observed at Óbidos in the lower Amazon (0·095 µg L?1), where the U content in the river bank sediments and suspended matter is lowest, suggests U release from the solid phase during river transport. About 485 t of U are transported annually to the Amazon delta area in dissolved form, and 1943 t bound to suspended particulate matter. Total U and Th concentrations in the river bank sediments ranged from 1·59 to 7·14 µg g?1 and from 6·74 to 32 µg g?1, respectively. The highest concentrations were observed in the Trombetas River. The proportion extracted by means of the hydroxylamine solution (HL) was relatively high for U in the Trombetas river bank sediment (31%) and for Th in the Solimões sediment (30%). According to the alpha recoil effects, the 234U/238U activity ratios of the Andean river waters and downstream Amazon water (Óbidos) were >1, but were <1 in the Negro River (at Manaus). The activity ratios of dissolved U correlate with pH and also with the U activity ratios in the river bank sediment hydroxylamine extracts. As expected, the 234U/238U activity ratios in river bank sediments were <1 in the Andean rivers and in the downstream Amazon, but they were >1 in the Trombetas and Negro rivers. Such ratios probably result from the binding of dissolved uranium to solid sediment. The 228Th/232Th ratios of river bank sediments were close to unity (except for the Negro River, where it is lower), suggesting no significant Th exchanges between the river water and the sediment. The 226Ra/232Th activity ratios were <1, and the 226Ra/228Ra activity ratios generally were significantly higher than the activity ratios of their respective parents. This perhaps is the result of easier leaching of the 226Ra parent, 230Th, from solid material (owing to the alpha recoil effect) than of the 228Ra parent. Uranium and thorium isotopes were used as tools to evaluate the chemical weathering rate of rocks in the Amazon system, which was estimated to be 2·7 cm 1000 year?1 s?1. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

7.
Lead (Pb) concentrations and isotope ratios of two different geochemical archives are compared; lake sediment cores and lichens (Hypogymnia physodes, naturally growing and transplanted) from a ca. 80 km-long transect centred on the Cu smelter and former mining town of Karabash, Ural Mountains, Russia. Lead concentrations in sediment cores from 10 lakes were generally low near their base and show an abrupt increase in their upper portions interpreted to coincide with the onset of large-scale smelting operations in 1910. Lead isotope ratios derived from 204Pb, 206Pb, 207Pb, 208Pb of the bottom layers differed significantly from those of the top. The top sediments have isotope ratios that show distinct end members, one of which was the stack dust from the Karabash smelter, which is similar to the Pb derived from ores from Sibay, a major mine in the Urals. The composition of the bottom sediment layers generally fall slightly off a mixing line between the top sediments and average Earth’s upper crust. Lichens transplanted from a reference site, as well as naturally growing lichens, sampled from southwest of the smelter have isotope ratios similar to those of the stack dust. Lichens to the northeast contained Pb from the smelter, but are increasingly influenced by other sources probably leaded petrol and local soils, and a signature derived from a source enriched in 207Pb. Vegetables collected from local kitchen gardens contained Pb from an additional atmospheric source, possibly coal. Our work confirms that: (1) Pb isotopes in lake sediments provide a long-term record of inputs and allows the characterisation of natural and anthropogenic sources; (2) Pb isotopes in lichens provide a short-term record of local and long-range atmospheric deposition at high spatial resolution and short time scales as they replace their Pb content within a few months; (3) determination of all four stable Pb isotopes is necessary for the identification of the sources of Pb and is extremely sensitive for discerning minor source signatures, even in an area with a dominant source such as a smelter. Particularly significant for the Karabash area is that ore-smelter-derived airborne Pb is a major component in the lake sediments and lichens but its contribution reaches insignificant levels ca. 40 km from the smelter.  相似文献   

8.
The ‘Chicken Creek’ artificial catchment area, Welzow-South, E Germany, created to study processes and structures of initial ecosystem development, discharges into a small experimental lake (A=3805 m2, V=3992 m3, zmax=2.4 m). This lake was man-made in 2005 and filled by natural surface runoff until January 2006. In summer 2006 and 2008, the actual development of sediments and the evolution of the phosphorus (P) cycle were studied. 19.7% of the original lake volume was filled by sediment within the first 3 years. A fine-grained sediment representing silt (6.3-63 μm) accumulated at high accretion rates at the deepest point (200 mm a−1, 0-24 mm week−1) due to massive erosion in the catchment. The sediment is low in organic matter (2.5-5.2%) and total P (TP, 0.31-0.97 mg g−1). Low amounts of P associated with degradable organic matter and surplus of metal hydroxides (Fe:P∼40, Al:P∼20) favor an efficient P binding and low dissolved P concentrations in pore water (1-107 μg l−1). Hence, the mineral sediment quality and the low rates of P release (0.06 mg m−2 d−1) revealed that a lake at an initial stage of development has essentially no sedimentary P cycle compared to eutrophic shallow lakes. However, the increasing emersed and submersed macrophyte growth will control further lake succession by intensifying the internal nutrient cycling. The macrophytes drive the evolution of a sedimentary P cycle by mobilizing and translocating P, by accumulating carbon and thus by stimulating microbial and redox processes.  相似文献   

9.
The artificial reservoir Lagoa da Pampulha in central Brazil has been increasingly affected by sediment deposition and pollution from urban and industrial sources. This study investigates water chemistry and heavy metal concentrations and their fractionation in the lake sediment using ICP-OES, ICP-MS, and XRD analyses. Fractionation analysis was done by sequential extraction under inert gas as well as after oxidation. The lake exhibits a permanent stratification with an oxygen-free hypolimnion below 2 m depth. Nutrient concentrations are enriched for phosphorous components (SRP, PO4). In the sediment it was not possible to detect oxygen. Carbon, sulfur, and most of the analyzed heavy metals are enriched in the top sediment layer with a pronounced downward decrease, indicating the presence of an anthropogenic influence. Statistical analysis, including correlations and a Principal Component Analysis (PCA) of depth-related total concentration data, helps to distinguish presumably anthropogenic heavy metals from geogenic components. Some samples with high element concentrations in the sediment also show elevated concentrations in their pore water. Analyses of element distribution between sediment and pore water suggest a strong bonding of heavy metals to the anoxic sediment. The trend towards elevated solubility in the pore water of oxidized samples is clear for most of the analyzed elements. Fractionation analysis reveals characteristic associations of selected elements to specific mineral bonding forms. In addition, it indicates that the behavior of heavy metals in the sediment is strongly influenced by organic substances. These substances provide buffering against oxidation, acidification, and metal release. The high nutrient loading causes reducing conditions in the lake sediment. These conditions trigger the accumulation of sediments rich in S2−, which stabilizes the fixation of heavy elements. In the future, care must be taken to reduce the supply of contaminants and to prevent the release of heavy metals from sediments dredged for remediation purposes.  相似文献   

10.
Sedimentary phosphorus species and sedimentation flux in the East China Sea   总被引：1，自引：0，他引：1  
《Continental Shelf Research》2007,27(10-11):1465-1476
Core sediment samples were collected from the middle shelf of the East China Sea (ECS) to study the phosphorus forms, P accumulation rate (PAR), P burial efficiency and the burial flux in the ECS. The sediment samples were sequentially extracted and directly extracted to analyze different forms of sedimentary P: lossely sorbed P and iron-bound P (PCDB); inorganic P associated with francolite (carbonate fluorapatite, CFA), biogenic hydroxyapatite, smecite, and CaCO3 (PCFA); detrital P (PDetrital); organic P (POrganic); and total P. In addition, the Fe contents in the citrate-dithionite-bicarbonate (CDB) extracted solution were also measured.The total concentrations of P in the surface sediments in the study area ranged from 13.5 to 22.3 μmol g−1. Inorganic P was the major form and accounted for 72–93% of the total P pool. The average percentage of each fraction of P followed the sequence: PDetrital (70%)>POrganic (15.5%)>PCDB (8.4%)>PCFA (5.8%). The distribution pattern of total P in the surface sediment was similar to that of PDetrital and POrganic, but different from that of PCDB and PCFA. The profile variation of POrganic was the most significant among the phosphorus forms at the study stations. The concentrations of PCDB and PCFA showed minor variation with depth. These results may suggest that transformations of POrganic, PCFA and PCDB occurred at the study stations during sedimentary P burial.Based on the concentrations of total P, PCDB and FeCDB obtained in the present study and the mass accumulation rate (MAR) reported in the literature, the values of the PAR, the P diffusion flux (JPFe) supplied by reducible iron hydroxides and the P burial efficiency were calculated. The calculated results for PAR and JPFe in the study area ranged from 1.02 to 24.23 μmol cm−2 yr−1 and from 0.1 to 2.11 μmol cm−2 yr−1, respectively. The phosphorus burial efficiency (PBE) was approximately 90%. The ECS is a phosphorus sink, and the average annual P burial flux has been reasonably estimated to be in the range of 20–25×109 mol yr−1.  相似文献   

11.
Identifying aquifer vulnerability to climate change is of vital importance in the Sierra Nevada and other snow‐dominated basins where groundwater systems are essential to water supply and ecosystem health. Quantifying the component of new (current year's) snowmelt in groundwater and surface water is useful in evaluating aquifer vulnerability because significant annual recharge may indicate that streamflow will respond rapidly to annual variability in precipitation, followed by more gradual decreases in recharge as recharge declines over decades. Hydrologic models and field‐based studies have indicated that young (<1 year) water is an important component of streamflow. The goal of this study was to utilize the short‐lived, naturally occurring cosmogenic isotope sulfur‐35 (35S) to quantify new snowmelt contribution to groundwater and surface waters in Sagehen Creek Basin (SCB) and Martis Valley Groundwater Basin (MVGB) located within the Tertiary volcanics of the central Sierra Nevada, CA. Activities of 35S were measured in dissolved sulfate (35SO42?) in SCB and MVGB snowpack, groundwater, springs, and streamflow. The percent of new snowmelt (PNS) in SCB streamflow ranged from 0.2 ± 6.6% during baseflow conditions to 14.0 ± 3.4% during high‐flow periods of snowmelt. Similar to SCB, the PNS in MVGB groundwater and streamflow was typically <30% with the largest fractions occurring in late spring or early summer following peak streamflow. The consistently low PNS suggests that a significant fraction of annual snowmelt in SCB and MVGB recharges groundwater, and groundwater contributions to streamflow in these systems have the potential to mitigate climate change impacts on runoff.  相似文献   

12.
Using sediment traps, we aimed to elucidate the temporal and spatial variations in sediment fluxes in large and shallow Lake Peipsi, over the May to October 2011 period, and analyze the factors behind those variations. The effects of weather factors (mean and maximum wind velocity, water level and water temperature) on sediment resuspension and the concentrations of suspended solids (SS), total phosphorus (TP), soluble reactive phosphorus (SRP), and chlorophyll a (Chl a) were investigated. Moreover, the internal loading of TP due to sediment resuspension was determined. The sediment resuspension rates were significantly higher in the shallower waters than in the deeper parts of the lake. Resuspension was a major factor in sedimentation dynamics of the lake, which is presently subject to eutrophication. The rates of sediment resuspension followed the same pattern as gross sedimentation during the study period, and their respective values differed significantly between sampling dates. The highest resuspension rates were observed in September (mean 55.4 g dw m?2 day?1), when the impacts of wind events were particularly pronounced. Weather factors that were recorded approximately 2 weeks before water and sediment sampling affected the gross sedimentation and sediment resuspension. The water quality variables of SS, TP, SRP, Chl a were similarly affected. During the study, TP concentrations of the water were mainly determined by the resuspension of sediments containing a large pool of organic material. Although internal loading of TP due to resuspension was several times greater than external loading, external loading determines the amount of phosphorus that enters the lake and can be resuspended.  相似文献   

13.
Surface sediments (n = 17) were collected from 6 sites located in the coasts of the Bushehr Peninsula. ∑16PAH concentrations were in the range of 285.9–1288 ng g? 1 dw and the sediments were moderately polluted. Py, Ph, B(a)A and Flu showed > 70% of the detected values in order of the mentioned rank. 4-ring PAHs were the dominant compounds and the molecular ratios presented the dominant pyrolytic source. The toxicity of PAHs for sediment dwelling life was averagely equivalent to occurrence of 0.08 ng g? 1 of Dioxin in dw of the examined sediments. The evaluated narcotic potential (confidence level of 99%) was 0.027–3.04 and upper part of the Bushehr Peninsula, where the human population is more concentrated, showed more narcotic potential. ∑ n-alkane concentrations (n-C15 ? n-C32) were in the range of 3.10–35.6 μg g? 1 dw. The dominant distribution of even carbon number n-alkanes was traced back to a possibly autochthonous source.  相似文献   

14.
湖泊水华存在复杂的生消过程,然而目前较多研究聚焦在水华持续阶段对湖泊生态系统的影响,却较少关注水华生消过程对湖泊水体和沉积物理化性质的影响.以巢湖为对象,根据历史资料确定水华区和非水华区,在相同位点分别于水华形成前期、形成期、持续期和消亡期采集水体和沉积物样品,分析水华生消过程对湖泊水体和沉积物理化指标及营养盐的影响.结果表明,巢湖研究区域水华形成期为5月中旬至6月中旬,持续期为6月中旬至9月上旬,之后进入水华消亡期.水体透明度、p H值和溶解氧在水华区与非水华区大部分时间存在显著差异,且随水华生消过程呈现不同的变化趋势,但水温、氧化还原电位和电导率在水华区和非水华区无显著差异,并随水华生消过程呈现相同的变化趋势.非水华区水体和沉积物中各形态氮、磷浓度明显低于水华区,且随时间变化幅度相对较小.在水华区,水体氮、磷浓度(总溶解性氮、硝态氮、氨氮、总氮、总溶解性磷、磷酸盐)在水华形成期和水华持续前期呈下降趋势,但在水华持续后期和水华消亡期呈增加趋势;沉积物氮、磷浓度(总氮、总磷)和总有机质含量显著高于非水华区,三者在水华区和非水华区随水华生消过程呈现不同的变化趋势.研究表明,水华生消过程对湖泊营养盐和水体及沉积物性质有不同的影响,这对湖泊富营养化治理和水华防治具有重要意义.  相似文献   

15.
氮是引起湖泊水体富营养化的关键营养元素之一。本次工作从贵州两个重要水库（红枫湖和百花湖）采集了未受扰动的沉积物样品性,分析了分层沉积物样品中的总氮,无机交换性氮和固定铵的含量及垂直剖面分布,研究表明,红枫湖和百花湖沉积物中具有较高的全氮含量,平均含量约为沉积物干重的0.36%～0.40%,其垂直分布在埋藏过程中受到成岩作用改造,沉积物交换性氮在沉积物中的赋存受到全氮含量和埋藏环境的双重控制,红枫湖和百花湖沉积物具有较强的吸持固定铵的能力,沉积物固定铵的绝对含量的平均值分别为434.05mg/kg和416.94mg/kg,分别占全氮的13.53%和12.53%。  相似文献   

16.
This paper presents a field investigation on river channel storage of fine sediments in an unglaciated braided river, the Bès River, located in a mountainous region in the southern French Prealps. Braided rivers transport a very large quantity of bedload and suspended sediment load because they are generally located in the vicinity of highly erosive hillslopes. Consequently, these rivers play an important role because they supply and control the sediment load of the entire downstream fluvial network. Field measurements and aerial photograph analyses were considered together to evaluate the variability of fine sediment quantity stored in a 2·5‐km‐long river reach. This study found very large quantities of fine sediment stored in this reach: 1100 t per unit depth (1 dm). Given that this reach accounts for 17% of the braided channel surface area of the river basin, the quantities of fine sediment stored in the river network were found to be approximately 80% of the mean annual suspended sediment yields (SSYs) (66 200 t year?1), comparable to the SSYs at the flood event scale: from 1000 t to 12 000 t depending on the flood event magnitude. These results could explain the clockwise hysteretic relationships between suspended sediment concentrations and discharges for 80% of floods. This pattern is associated with the rapid availability of the fine sediments stored in the river channel. This study shows the need to focus on not only the mechanisms of fine sediment production from hillslope erosion but also the spatiotemporal dynamics of fine sediment transfer in braided rivers. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

17.
湖泊底泥疏浚环境效应:Ⅰ.内源磷释放控制作用   总被引：9，自引：1，他引：8  
通过为期一年的疏浚模拟试验,在试验室培养疏浚与对照柱样研究了底泥疏浚对内源磷释放的控制效果．结果发现,疏浚表层30cm能够有效的消减沉积物中不f司形态磷含量与孔隙水中PO4^3-P含量．在一年的试验周期内,疏浚和对照柱沉积物-水界面的PO4^3-P通量分别为-143．8至14．4与-237．3至3047．6μg／（m^2&#183;d）,疏浚柱沉积物-水界面的磷通量总体上低于未疏浚对照的磷通量,尤其是在温度较高的月份,从2006年3-10月疏浚柱沉积物-水界面磷释放通量显著低于未疏浚对照柱,疏浚沉积物的磷的释放潜力低于未疏浚对照沉积物．研究结果表明,在外源磷得到有效控制的前提下,底泥疏浚是消减研究区内源磷负荷有效的技术手段．  相似文献   

18.
This paper adopts standard tests developed in temperate catchment research to determine the total phosphorus (TP) and the algal available (base‐extractable) phosphorus (NaOH–P) content of a wide range of glaciofluvial sediments from the Northern Hemisphere. We find that the TP content of these sediments is broadly similar to the P content of major rock types in Earth's crust (230–670 µgP/g) and so the TP yields of glacier basins may be high owing to the efficacy of suspended sediment evacuation by glacial meltwaters. We show that this is best achieved where subglacial drainage systems are present. The NaOH–P pool of the sediments is found to be low (1–23 µgP/g) relative to the TP pool and also to the NaOH–P pool of suspended sediments in temperate, non‐glacierized catchments. This most probably reflects the restricted duration of intimate contact between dilute meltwaters and glacial suspended sediments during the ablation season. Thus, despite the high surface‐area:volume ratio of glacial suspended sediments, the potential for P adsorption to mineral surfaces following release by dissolution is also low. Further, sorption experiments and sequential extraction tests conducted using glacial suspended sediments from two Svalbard catchments indicate that the generation of reactive secondary minerals (e.g. Fe‐ and other hydroxides) with a strong capacity to scavenge P from solution (and thereby promote the continued dissolution of P) may also be limited by the short residence times. Most P is therefore associated with poorly weathered, calcite/apatite‐rich mineral phases. However, we use examples from the Svalbard glacier basins (Austre Brøggerbreen and Midre Lovénbreen) to show that the high sediment yields of glaciers may result in appreciable NaOH–P loading of ice‐marginal receiving waters. Again, the importance of subglacial drainage is highlighted, as it produces a major, episodic release of NaOH–P at Midre Lovénbreen that results in a yield (8·2 kg NaOH–P/km2/year) more than one order of magnitude greater than that at Austre Brøggerbreen (where subglacial drainage is absent and the yield is 0·48 kg NaOH‐P/km2/year). Therefore, as since both detrimental and beneficial effects of sediment‐bound P loading in ice marginal receiving waters are possible (i.e. either reduced primary productivity owing to increased turbidity or P fertilization following desorption) there is a pressing need to assess the ambient P status of such environments and also the capacity for ice‐marginal ecosystems to adapt to such inputs. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

19.
Porewater profiles often are used to identify and quantify important biogeochemical processes occurring in lake sediments. In this study, multiple porewater profiles were obtained from two eutrophic Swiss lakes using porewater equilibrators (peepers) in order to examine spatial and seasonal trends in biogeochemical processes. Variability in profile shapes and concentrations was small on spatial scales of a few meters, but the uncertainty in calculated diffusive fluxes across the sediment surface was, on average, 35%. Focusing of Fe and Mn oxides toward the lake center resulted in systematic increases in porewater concentrations and diffusive fluxes of Fe2+ and Mn2+ with increasing water depth; these fluxes are postulated to be regulated by the pH-dependent dissolution of reduced-metal phases. Despite higher concentrations of inorganic carbon, NH 4 + , Si and P in pelagic compared to littoral sites, diffusive fluxes of these substances across the sediment surface increased only slightly or not at all with increasing water depth. Porewater profiles did reveal temporal changes in Fe2+, Mn2+, Ca2+ and Mg2+ that were an indirect result of the large, seasonal changes in seston deposition, but no clear seasonal variations were found in diffusive fluxes of nutrients across the sediment surface. The intense mineralization occurring at the sediment surface was not reflected in the porewater profiles nor in the calculated diffusive fluxes. Calculated diffusive fluxes across the sediment surface resulted from decomposition occurring primarily in the top 5–7 cm of sediment. Diffusive fluxes from this subsurface mineralization were equal to the solute release from mineralization occurring at the sediment-water interface. Buried organic matter acts as a memory of previous lake conditons; it will require at least a decade before reductions in nutrient inputs to lakes fully reduce the diffusive fluxes into the lake from the buried reservoir of organic matter.  相似文献   

20.
The mechanisms which controls the fixation and/or release of P in sediment of an extremely acidic lake（pH = 2.0 to 3.0） and its response to the influence of eutrophic urban waste water were investigated.The results,in the chemical composition,in the mineralogy of the sediment and in the material as obtained from sediment traps,show that the lake sediments are mainly volcanic material reflecting volcanic features of the basin.The sedimentation rate calculated for the lake(2.5×10-2 mg m-2 day-1) was higher than that observed in other similar glacial lakes in both Andean Patagonia and also elsewhere in the world.The Total Phosphorus concentration in sediments was higher than figures reported by other authors for mining acid lakes,and the main fraction of P was found associated with organic matter.There was no control by Fe or Al on P,because both are in solution at pH < 3.0.It was concluded that changes in the natural input of nutrients（derivatives of Copahue volcano fluid,the discharge of sewage,or basin run-off） are responsible for a high concentration of SRP and N-NH4+ in the lake.Laboratory experiments showed that sediments have no ability to retain phosphorus and a continuous release of P from the sediments into the water column was observed.The assays where the pH was artificially increased showed that the P still remains in solution until at least pH 7.0.It was concluded that changes in the natural input of nutrients due to:1) the volcanic fluids,2) the increase in sewage charges,or 3) surface runoff upstream,maintain a high trophic state with high concentrations of dissolved P and N-NH4+,although the threshold of neutral pH in the lake is exceeded.This study will enable a better understanding about of the mechanism of release/fixation of phosphorus in acidic sediments in order to assist in making decisions regarding the conservation and management of this natural environment.  相似文献   

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