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1.
Abstract— The trapped noble gas record of 57 enstatite chondrites (E chondrites) has been investigated. Basically, two different gas patterns have been identified dependent on the petrologic type. All E chondrites of type 4 to 6 show a mixture of trapped common chondritic rare gases (Q) and a subsolar component (range of elemental ratios for E4–6 chondrites: 36Ar/132Xe = 582 ± 270 and 36Ar/84Kr = 242 ± 88). E3 chondrites usually contain Q gases, but also a composition with lower 36Ar/132Xe and 36Ar/84Kr ratios, which we call sub‐Q (36Ar/132Xe = 37.0 ± 18.0 and 36Ar/84Kr = 41.7 ± 18.1). The presence of either the subsolar or the sub‐Q signature in particular petrologic types cannot be readily explained by parent body metamorphism as postulated for ordinary chondrites. We therefore present a different model that can explain the bimodal distribution and composition of trapped heavy noble gases in E chondrites. Trapped solar noble gases have been observed only in some E3 chondrites. About 30% of each group, EH3 and EL3 chondrites, amounting to 9% of all analyzed E chondrites show the solar signature. Notably, only one of those meteorites has been explicitly described as a regolith breccia.  相似文献   

2.
Abstract The 244Pu-fission-136Xe retention ages of howardites, eucrites, and diogenites (HEDs) show that these meteorites have retained Xe since they were formed about 4500 Ma ago. For the Garland diogenite and the Millbillillie eucrite, we obtain fission Xe ages of 4525 ± 40 Ma and 4486 ± 40 Ma, respectively. If Xe isotope data reported by other workers are also considered, we conclude that the monomict equilibrated eucrites Camel Donga, Juvinas, and Millbillillie formed about 40 Ma later than Pasamonte, a polymict unequilibrated eucrite. Stannern, a monomict equilibrated brecciated eucrite, yields a 244Pu-136Xe age of 4442 Ma. The 40K-40Ar retention ages fall, for most HEDs, into the 1000–4000 Ma age range, indicating that 40Ar is generally not well retained. The good retentivity for Xe of HEDs allows us to study primordial trapped Xe in these meteorites. Except for Shalka, in which other authors found Kr and Xe from terrestrial atmospheric contamination only, we present for the first time Kr and Xe isotopic data for diogenites. We studied Ellemeet, Garland, Ibbenbühren, Shalka, and Tatahouine. We show that Tatahouine contains two types of trapped Xe: a terrestrial contamination acquired by an irreversible adsorption process and released at pyrolysis temperatures up to 800 °C, and indigenous primordial Xe released primarily between 800 °C and 1200 °C. The isotopic composition of this primordial Xe is identical to that proposed earlier to be present in primitive achondrites and termed U-Xe or “primitive” Xe, but it has not been directly observed in achondrites until now. This type of primitive Xe is important for understanding the evolution of other Xe reservoirs in the Solar System. Terrestrial atmospheric Xe (corrected for fission Xe and radiogenic Xe from outgassing of the Earth) is related to it by a mass dependent fractionation favoring the heavier Xe isotopes. This primitive Xe is isotopically very similar to solar Xe except for 134Xe and 136Xe. Solar Xe appears to contain an enrichment of unknown origin for these isotopes relative to the primitive Xe.  相似文献   

3.
Abstract— This work reports on the noble gas inventory of 3 new acapulcoites, 3 brachinites, 2 new eucrites from the Dar al Gani region in Libya, the unique achondrite Dar al Gani (DaG) 896 from the same locality, the new eucrite‐like achondrite Northwest Africa (NWA) 011, and the controversial sample Tafassasset. We determined cosmic ray exposure and gas retention ages, evaluated shielding conditions, and discuss the trapped noble gas component of the specimens. All exposure ages are within the known range of stony meteorites and partly confirm previously established age clusters. Shielding conditions vary, suggesting substantial shielding for all 3 brachinites and Tafassasset. We cannot exclude, however, that the Mg‐rich composition of brachinites simply simulates heavy shielding. Regarding the trapped component, we found Q‐like compositions only for the acapulcoite Thiel Mountains (TIL) 99002. The brachinite Elephant Moraine (EET) 99402 yields a high, subsolar 36Ar/132Xe ratio of ?400 along with a slightly elevated 84Kr/132atio, indicating minor atmospheric contamination. All the other samples, particularly the eucrite DaG 983, are characterized by clearly elevated Ar/Kr/Xe ratios due to significant terrestrial alteration. Tafassasset exhibits noble gas parameters that are different from those of CR chondrites, including a relatively high cosmic ray exposure age, the absence of a solar component, low 132Xe concentrations, a low trapped 36Ar/132Xe ratio of ?30, and a noticeable amount of radiogenic 129Xe. Similar attributes have been observed for some primitive achondrites. These attributes are also consistent with the metamorphic character of the sample. We, therefore, consider Tafassasset's noble gas record to be inconclusive as to its classification (primitive achondrite versus metamorphosed CR chondrite).  相似文献   

4.
Abstract— The L/LL5 chondrite Knyahinya had an approximately spherical shape, and as it experienced a single stage exposure history, it represents a very interesting object to study depth profiles of cosmic-ray-produced nuclide concentrations. Such data are required to improve and to validate model calculations of production rates. We report Ne, Ar, Kr and Xe isotopic abundances in five bulk samples. The adopted procedure of noble gas extraction included two pyrolysis steps at 450 °C and 650 °C, respectively, followed by a combustion step in pure O2 at 650 °C before melting the sample. This procedure allows for the separation of a significant fraction of the trapped Kr and Xe, leading to an enrichment of the cosmic-ray produced component, which is released in the melting step. The isotopic composition of the trapped Xe component measured in the combustion step is found to be identical with the OC-Xe composition (Lavielle and Marti, 1992) and supports the suggestion that ordinary chondrites formed in a homogeneous trapped noble gas reservoir. Cosmic-ray produced Kr and Xe components and depth profiles were measured, including for the first time a 81Kr profile. The calculated exposure age of 39.5 ± 1.0 Ma, based on the 81Kr-Kr method, is found to be in excellent agreement with previous determinations. The concentrations of trapped and fissiogenic noble gas components are clearly lower than those generally observed in type 5 ordinary chondrites and may suggest diffusion losses before a meter-sized object was exposed to the cosmic radiation.  相似文献   

5.
Abstract— The noble gases He, Ne, Ar, Kr, and Xe were measured in 27 individual Antarctic micrometeorites (AMMs) in the size range 60 to 250 μm that were collected at the Dome Fuji Station. Eleven of the AMMs were collected in 1996 (F96 series) and 16 were collected in 1997 (F97 series). One of the F97 AMMs is a totally melted spherule, whereas all other particles are irregular in shape. Noble gases were extracted using a Nd‐YAG continuous wave laser with an output power of 2.5‐3.5 W for ?5 min. Most particles released measurable amounts of noble gases. 3He/4He ratios are determined for 26 AMMs ((0.85‐9.65) × 10?4). Solar energetic particles (SEP) are the dominant source of helium in most AMMs rather than solar wind (SW) and cosmogenic He. Three samples had higher 3He/4He ratios compared to that of SW, showing the presence of spallogenic 3He. The Ne isotopic composition of most AMMs resembled that of SEP as in the case of helium. Spallogenic 21Ne was detected in three samples, two of which had extremely long cosmic‐ray exposure ages (> 100 Ma), calculated by assuming solar cosmic‐ray (SCR) + galactic cosmic‐ray (GCR) production. These two particles may have come to Earth directly from the Kuiper Belt. Most AMMs had negligible amounts of cosmogenic 21 Ne and exposure ages of <1 Ma. 40Ar/36Ar ratios for all particles (3.9–289) were lower than that of the terrestrial atmosphere (296), indicating an extraterrestrial origin of part of the Ar with a very low 40Ar/36Ar ratio plus some atmospheric contamination. Indeed, 40Ar/36Ar ratios for the AMMs are higher than SW, SEP, and Q‐Ar values, which is explained by the presence of atmospheric 40Ar. The average 38Ar/36Ar ratio of 24 AMMs (0.194) is slightly higher than the value of atmospheric or Q‐Ar, suggesting the presence of SEP‐Ar which has a relatively high 38Ar/36Ar ratio. According to the elemental compositions of the heavy noble gases, Dome Fuji AMMs can be classified into three groups: chondritic (eight particles), air‐affected (nine particles), and solar‐affected (eight particles). The eight AMMs classified as chondritic preserve the heavy noble gas composition of primordial trapped component due to lack of atmospheric adsorption and solar implantation. The average of 129Xe/132Xe ratio for the 16 AMMs not affected by atmospheric contamination (1.05) corresponds to the values in matrices of carbonaceous chondrites (?1.04). One AMM, F96DK038, has high 129Xe/132Xe in excess of this ratio. Our results imply that most Dome Fuji AMMs originally had chondritic heavy noble gas compositions, and carbonaceous chondrite‐like objects are appropriate candidate sources for most AMMs.  相似文献   

6.
The Paris carbonaceous chondrite represents the most pristine carbonaceous chondrite, providing a unique opportunity to investigate the composition of early solar system materials prior to the onset of significant aqueous alteration. A dual origin (namely from the inner and outer solar system) has been demonstrated for water in the Paris meteorite parent body (Piani et al. 2018 ). Here, we aim to evaluate the contribution of outer solar system (cometary‐like) water ice to the inner solar system water ice using Xe isotopes. We report Ar, Kr, and high‐precision Xe isotopic measurements within bulk CM 2.9 and CM 2.7 fragments, as well as Ne, Ar, Kr, and Xe isotope compositions of the insoluble organic matter (IOM). Noble gas signatures are similar to chondritic phase Q with no evidence for a cometary‐like Xe component. Small excesses in the heavy Xe isotopes relative to phase Q within bulk samples are attributed to contributions from presolar materials. CM 2.7 fragments have lower Ar/Xe relative to more pristine CM 2.9 fragments, with no systematic difference in Xe contents. We conclude that Kr and Xe were little affected by aqueous alteration, in agreement with (1) minor degrees of alteration and (2) no significant differences in the chemical signature of organic matter in CM 2.7 and CM 2.9 areas (Vinogradoff et al. 2017 ). Xenon contents in the IOM are larger than previously published data of Xe in chondritic IOM, in line with the Xe component in Paris being pristine and preserved from Xe loss during aqueous alteration/thermal metamorphism.  相似文献   

7.
Abstract— We have carried out noble gas measurements on graphite from a large graphite‐metal inclusion in Canyon Diablo. The Ne data of the low‐temperature fractions lie on the mixing line between air and the spallogenic component, but those of high temperatures seem to lie on the mixing line between Ne‐HL and the spallogenic component. The Ar isotope data indicate the presence of Q in addition to air, spallogenic component and Ar‐HL. As the elemental concentration of Ne in Q is low, we could not detect the Ne‐Q from the Ne data. On the other hand, we could not observe Xe‐HL in our Xe data. As the Xe concentration and the Xe/Ne ratio in Q is much higher than that in the HL component, it is likely that only the contribution of Q is observed in the Xe data. Xenon isotopic data can be explained as a mixture of Q, air, and “El Taco Xe.” The Canyon Diablo graphite contains both HL and Q, very much like carbonaceous chondrites, retaining the signatures of various primordial noble gas components. This indicates that the graphite was formed in a primitive nebular environment and was not heated to high, igneous temperatures. Furthermore, a large excess of 129Xe was observed, which indicates that the graphite was formed at a very early stage of the solar system when 129I was still present. The HL/Q ratios in the graphite in Canyon Diablo are lower than those in carbonaceous chondrites, indicating that some thermal metamorphism occurred on the former. We estimated the temperature of the thermal metamorphism to about 500–600 °C from the difference of thermal retentivities of HL and Q. It is also noted that “El Taco Xe” is commonly observed in many IAB iron meteorites, but its presence in carbonaceous chondrites has not yet been established.  相似文献   

8.
Abstract– We have determined the elemental abundances and the isotopic compositions of noble gases in a bulk sample and an HF/HCl residue of the Saratov (L4) chondrite using stepwise heating. The Ar, Kr, and Xe concentrations in the HF/HCl residue are two orders of magnitude higher than those in the bulk sample, while He and Ne concentrations from both are comparable. The residue contains only a portion of the trapped heavy noble gases in Saratov; 40 ± 9% for 36Ar, 58 ± 12% for 84Kr, and 48 ± 10% for 132Xe, respectively. The heavy noble gas elemental pattern in the dissolved fraction is similar to that in the residue but has high release temperatures. Xenon isotopic ratios of the HF/HCl residue indicate that there is no Xe‐HL in Saratov, but Ne isotopic ratios in the HF/HCl residue lie on a straight line connecting the cosmogenic component and a composition between Ne‐Q and Ne‐HL. This implies that the Ne isotopic composition of Q has been changed by incorporating Ne‐HL (Huss et al. 1996) or by being mass fractionated during the thermal metamorphism. However, it is most likely that the Ne‐Q in Saratov is intrinsically different from this component in other meteorites. The evidence of this is a lack of correlation between the isotopic ratio of Ne‐Q and petrologic types of meteorites (Busemann et al. 2000). A neutron capture effect was observed in the Kr isotopes, and this process also affected the 128Xe/132Xe ratio. The 3He and 21Ne exposure ages for the bulk sample are 33 and 35 Ma, respectively.  相似文献   

9.
Abstract– Noble gas isotopic compositions were measured for a eucritic pebble and bulk material of a silicate–metal mixture from the Vaca Muerta mesosiderite as well as pyroxene and plagioclase separated from the eucritic pebble by total melting and stepwise heating methods. Trapped noble gases were degassed completely by a high‐temperature thermal event, probably at the formation of the Vaca Muerta parent body (VMPB). The presence of fissiogenic Xe isotopes from extinct 244Pu in the bulk samples might be a result of rapid cooling from an early high‐temperature metamorphism. High concentrations of cosmogenic noble gases enabled us to determine precise isotopic ratios of cosmogenic Kr and Xe. Spallogenic Ne from Na and unique Ar isotopic compositions were observed. The 81Kr‐Kr exposure age of 168 ± 8 Myr for the silicate pebble is distinctly longer than the age of 139 ± 8 Myr for the bulk samples. The precursor of the pebble had been irradiated on the surface of the VMPB for more than 60 Myr (first stage irradiation), with subsequent incorporation into bulk materials approximately 4 Gyr ago. The Vaca Muerta meteorite was excavated from the VMPB 140 Myr ago (second stage irradiation). Relative diffusion rates among the cosmogenic Ar, Kr, and Xe based on data obtained by stepwise heating indicate that Kr and Xe can be partially retained in pyroxene and plagioclase under the condition that resets the K‐Ar system. This result supports the presence of fission Xe and of excess concentration of cosmogenic Kr, which could have survived the thermal event approximately 3.8 Gyr ago.  相似文献   

10.
Abstract– Aubrites exhibit a wide range of highly siderophile element (HSE—Re, Os, Ir, Ru, Rh, Pt, Pd, Au) concentrations and 187Os/188Os compositions. Their HSE concentrations are one to three orders of magnitude less than chondrites, with the exception of the Shallowater and Mt. Egerton samples. While most aubrites show chondritic HSE abundance ratios, significant enrichments of Pd and Re relative to Os, Ir, and Ru are observed in 12 of 16 samples. Present‐day 187Os/188Os ratios range from subchondritic values of 0.1174 to superchondritic values of up to 0.2263. Half of the samples have 187Os/188Os ratios of 0.127 to 0.130, which is in the range of enstatite chondrites. Along with the brecciated nature of aubrites, the HSE and Re‐Os isotope systematics support a history of extensive postaccretion processing, including core formation, late addition of chondritic material and/or core material and potential breakup and reassembly. Highly siderophile element signatures for some aubrites are consistent with a mixing of HSE‐rich chondritic fragments with a HSE‐free aubrite matrix. The enrichments in incompatible HSE such as Pd and Re observed in some aubrites, reminiscent of terrestrial basalts, suggest an extensive magmatic and impact history, which is supported by both the 187Re‐187Os isotope system and silicate‐hosted isotope systems (Rb‐Sr, K‐Ar) yielding young formation ages of 1.3–3.9 Ga for a subset of samples. Compared with other differentiated achondrites derived from small planetary bodies, aubrites show a wide range in HSE concentrations and 187Os/188Os, most similar to angrites. While similarities exist between the diverse groups of achondrites formed early in solar system history, the aubrite parent body(ies) clearly underwent a distinct evolution, different from angrites, brachinites, ureilites, howardites, eucrites, and diogenites.  相似文献   

11.
Abstract— Several solar gas rich lunar soils and breccias have trapped 40Ar/36Ar ratios >10, although solar Ar is expected to yield a ratio of <0.01. Radiogenic 40Ar produced in the lunar crust from 40K decay was outgassed into the lunar atmosphere, ionized, accelerated in the electromagnetic field of the solar wind, and reimplanted into lunar surface material. The 40Ar loss rate depends on the decreasing abundance of 40K. In order to calibrate the time dependence of the 40Ar/36Ar ratio in lunar surface material, the period of reimplantation of lunar atmospheric ions and of solar wind Ar was determined using the 235U‐136Xe dating method that relies on secondary cosmic‐ray neutron‐induced fission of 235U. We identified the trapped, fissiogenic, and cosmogenic noble gases in lunar breccia 14307 and lunar soils 70001‐8, 70181, 74261, and 75081. Uranium and Th concentrations were determined in the 74261 soil for which we obtain the 235U‐136Xe time of implantation of 3.25+0.38‐0.60 Ga ago. On the basis of several cosmogenic noble gas signatures we calculate the duration of this near surface exposure of 393 ± 45 Ma and an average shielding depth below the lunar surface of 73 ± 7 g/cm2. A second, recent exposure to solar and cosmic‐ray particles occurred after this soil was excavated from Shorty crater 17.2 ± 1.4 Ma ago. Using a compilation of all lunar data with reliable trapped Ar isotopic ratios and pre‐exposure times we infer a calibration curve of implantation times, based on the trapped40 Ar/36Ar ratio. A possible trend for the increase with time of the solar 3He/4He and 20Ne/22Ne ratios of about 12%/Ga and about 2%/Ga, respectively, is also discussed.  相似文献   

12.
Abstract— Ar‐rich noble gases, the so‐called “subsolar” noble gases, are a major component of heavy primordial noble gases in unequilibrated ordinary chondrites and some classes of anhydrous carbonaceous chondrites, whereas they are almost absent in hydrous carbonaceous chondrites that suffered extensive aqueous alteration. To understand the effects of aqueous alteration on the abundance of Ar‐rich noble gases, we performed an aqueous alteration experiments on the Ningqiang type 3 carbonaceous chondrite that consists entirely of anhydrous minerals and contains Ar‐rich noble gases. Powdered samples and deionized neutral water were kept at 200 °C for 10 and 20 days, respectively. Mineralogical analyses show that, during the 10‐day alteration, serpentine and hematite formed at the expense of olivine, low‐Ca pyroxene, and sulfide. Noble gas analyses show that the 10‐day alteration of natural Ningqiang removed 79% of the primordial 36Ar, 68% of the 84Kr, and 60% of the 132Xe, but only 45% of the 4He and 53% of the primordial 20Ne. Calculated elemental ratios of the noble gases removed during the 10‐day alteration are in the range of those of Ar‐rich noble gases. These results indicate that Ar‐rich noble gases are located in materials that are very susceptible to aqueous alteration. In contrast, heavy primordial noble gases remaining in the altered samples are close to Q gas in elemental and isotope compositions. This indicates that phase Q is much more resistant to aqueous alteration than the host phases of Ar‐rich noble gases. In the 20‐day sample, the mineralogical and noble gas signatures are basically similar to those of the 10‐day sample, indicating that the loss of Ar‐rich noble gases was completed within the 10‐day alteration. Our results suggest that almost all of the Ar‐rich noble gases were lost from primitive asteroids during early, low‐temperature aqueous alteration.  相似文献   

13.
Abstract– Enstatite chondrites (ECs) were subjected to noble gas analyses using stepped crushing and pyrolysis extraction methods. ECs can be classified into subsolar gas‐carrying and subsolar gas‐free ECs based on the 36Ar/84Kr/132Xe ratios. For subsolar gas‐free ECs, elemental ratios, and Xe isotopic compositions indicate that Q gas is the dominant trapped component, the Q gas concentration can be correlated with the petrologic type, reasonably explained by gas release from a common EC parental material during subsequent heating. Atmospheric Xe with sub‐Q elemental ratios is found in Antarctic E3s at 600–800 °C and through crushing. The 132Xe released in these fractions accounts for 30–60% of the bulk concentrations. Hence, the sub‐Q signature is generally due to contamination of elementally fractionated atmosphere. Subsolar gas is mainly released (up to 78% of the bulk 36Ar) at 1300–1600 °C and through crushing, suggesting that enstatite and friable phases are the host phases. Subsolar gas is isotopically identical to solar gas, but elementally fractionated. These observations are consistent with a previous study, which suggested that subsolar gas could be fractionated solar wind having been implanted into chondrule precursors ( Okazaki et al. 2001 ). Unlike subsolar gas‐free ECs, the primordial gas concentrations of subsolar gas‐carrying ECs are not simply correlated with the petrologic type. It is inferred that subsolar gas‐rich chondrules were heterogeneously distributed in the solar nebula and accreted to form subsolar gas‐carrying ECs. Subsequent metamorphic and impact‐shock heating events have affected noble gas compositions to various degrees.  相似文献   

14.
Abstract— Noble gases in two ureilites, Kenna and Allan Hills (ALH) 78019, were measured with two extraction methods: mechanical crushing in a vacuum and heating. Large amounts of noble gases were released by crushing, up to 26.5% of 132Xe from ALH 78019 relative to the bulk concentration. Isotopic ratios of the crush‐released Ne of ALH 78019 resemble those of the trapped Ne components determined for some ureilites or terrestrial atmosphere, while the crush‐released He and Ne from Kenna are mostly cosmogenic. The crush‐released Xe of ALH 78019 and Kenna is similar in isotopic composition to Q gas, which indicates that the crush‐released noble gases are indigenous and not caused by contamination from terrestrial atmosphere. In contrast to the similarities in isotopic composition with the bulk samples, light elements in the crush‐released noble gases are depleted relative to Xe and distinct from those of each bulk sample. This depletion is prominent especially in the 20Ne/132Xe ratio of ALH 78019 and the 36Ar/132Xe ratio of Kenna. The values of measured 3He/21Ne for the gases released by crushing are significantly higher than those for heating‐released gases. This suggests that host phases of the crush‐released gases might be carbonaceous because cosmogenic Ne is produced mainly from elements with a mass number larger than Ne. Based on our optical microscopic observation, tabular‐foliated graphite is the major carbon mineral in ALH 78019, while Kenna contains abundant polycrystalline graphite aggregates and diamonds along with minor foliated graphite. There are many inclusions at the edge and within the interior of olivine grains that are reduced by carbonaceous material. Gaps can be seen at the boundary between carbonaceous material and silicates. Considering these petrologic and noble gas features, we infer that possible host phases of crush‐released noble gases are graphite, inclusions in reduction rims, and gaps between carbonaceous materials and silicates. The elemental ratios of noble gases released by crushing can be explained by fractionation, assuming that the starting noble gas composition is the same as that of amorphous carbon in ALH 78019. The crush‐released noble gases are the minor part of trapped noble gases in ureilites but could be an important clue to the thermal history of the ureilite parent body. Further investigation is needed to identify the host phases of the crush‐released noble gases.  相似文献   

15.
Abstract— We have measured Ne, Ar, Kr and Xe in Si2O3 “smokes” that were condensed on Al substrates, vapor-deposited with various mixtures of CH4, NH3, H2O and noble gases at 10 K and subsequently irradiated with 1 MeV protons to simulate conditions during grain mantle formation in interstellar clouds. The noble gases were analyzed using conventional stepwise heating and static noble gas mass spectrometry. Neither Ne nor Ar is retained by the samples upon warming to room temperature, but Xe is very efficiently trapped and retained. Kr is somewhat less effectively retained, typically depleted by factors of about 10–20 relative to Xe. Isotopic fractionation favoring the heavy isotopes of Xe and Kr of about 5–10‰/amu is observed. Correlations between the specific chemistry of the vapor deposition and heavy noble gas retention are most likely the result of competition by the various species for irradiation-produced trapping sites. The concentration of Xe retained by some of these smokes exceeds that observed in phase Q of meteorites and, like phase Q, they do not seem to be carriers of the light noble gases. Such artificially prepared material may, therefore, offer clues concerning the incorporation of the heavy planetary noble gases in meteoritic material and the nature of phase Q.  相似文献   

16.
Abstract— In this paper, we present concentration and isotopic composition of the light noble gases He, Ne, and Ar as well as of 84Kr, 132Xe, and 129Xe in bulk samples of 33 Rumuruti (R) chondrites. Together with previously published data of six R chondrites, exposure ages are calculated and compared with those of ordinary chondrites. A number of pairings, especially between those from Northwest Africa (NWA), are suggested, so that only 23 individual falls are represented by the 39 R chondrites discussed here. Eleven of these meteorites, or almost 50%, contain solar gases and are thus regolithic breccias. This percentage is higher than that of ordinary chondrites, howardites, or aubrites. This may imply that the parent body of R chondrites has a relatively thick regolith. Concentrations of heavy noble gases, especially of Kr, are affected by the terrestrial atmospheric component, which resides in weathering products. Compared to ordinary chondrites, 129Xe/132Xe ratios of R chondrites are high.  相似文献   

17.
Abstract— We performed a comprehensive study of the He, Ne, and Ar isotopic abundances and of the chemical composition of bulk material and components of the H chondrites Dhajala, Bath, Cullison, Grove Mountains 98004, Nadiabondi, Ogi, and Zag, of the L chondrites Grassland, Northwest Africa 055, Pavlograd, and Ladder Creek, of the E chondrite Indarch, and of the C chondrites Hammadah al Hamra 288, Acfer 059, and Allende. We discuss a procedure and necessary assumptions for the partitioning of measured data into cosmogenic, radiogenic, implanted, and indigenous noble gas components. For stone meteorites, we derive a cosmogenic ratio 20Ne/22Ne of 0.80 ± 0.03 and a trapped solar 4He/3He ratio of 3310 ± 130 using our own and literature data. Chondrules and matrix from nine meteorites were analyzed. Data from Dhajala chondrules suggest that some of these may have experienced precompaction irradiation by cosmic rays. The other chondrules and matrix samples yield consistent cosmic‐ray exposure (CRE) ages within experimental errors. Some CRE ages of some of the investigated meteorites fall into clusters typically observed for the respective meteorite groups. Only Bath's CRE age falls on the 7 Ma double‐peak of H chondrites, while Ogi's fits the 22 Ma peak. The studied chondrules contain trapped 20Ne and 36Ar concentrations in the range of 10?6–10?9 cm3 STP/g. In most chondrules, trapped Ar is of type Q (ordinary chondritic Ar), which suggests that this component is indigenous to the chondrule precursor material. The history of the Cullison chondrite is special in several respects: large fractions of both CR‐produced 3He and of radiogenic 4He were lost during or after parent body breakup, in the latter case possibly by solar heating at small perihelion distances. Furthermore, one of the matrix samples contains constituents with a regolith history on the parent body before compaction. It also contains trapped Ne with a 20Ne/22Ne ratio of 15.5 ± 0.5, apparently fractionated solar Ne.  相似文献   

18.
Abstract— A glass separate from the LEW88516 shergottite was analyzed by step-wise combustion for N and noble gases to determine whether it contained trapped gas similar in composition to the martian atmosphere-like component previously observed in lithology C of EETA79001. Excesses of 40Ar and 129Xe were in fact observed in this glass, although the amounts of these excesses are ≤20% of those seen in the latter meteorite, and are comparable to the amounts seen in whole-rock analyses of LEW88516. The isotopic composition of N in LEW88516 does not show an enrichment in 15N commensurate with the amount of isotopically-heavy N expected from the noble gases excesses. One must posit some extreme assumptions about the nature of the N components present in LEW88516 in order to allow the presence of the trapped nitrogen component. Alternatively, the N has somehow been decoupled from the noble gases, and was either never present or has been lost.  相似文献   

19.
Abstract— A fine‐grained dark inclusion in the Ningqiang carbonaceous chondrite consists of relatively pristine solar nebular materials and has high concentrations of heavy primordial rare gases. Trapped 36Ar concentration amounts to 6 times 10?6 cc STP/g, which is higher than that of Ningqiang host by a factor of three. Light HF‐HCl etching of the dark inclusion removed 86, 73, and 64% of the primordial 36Ar, 84Kr, and 132Xe, respectively. Thus, the majority of the noble gases in this inclusion are located in very acid‐susceptive material. Based on the elemental composition, the noble gases lost from the dark inclusion during the acid‐treatments are Ar‐rich, and the noble gases remaining in the inclusion are Q and HL gases. Transmission electron microscopy showed that the acid treatments removed thin Si, Mg, and Fe‐rich amorphous rims present around small olivine and pyroxene grains in the dark inclusion, suggesting that the Ar‐rich gases reside in the amorphous layers. A possible origin of the Ar‐rich gases is the acquisition of noble‐gas ions with a composition fractionated relative to solar abundance favoring the heavy elements by the effect of incomplete ionization under plasma conditions at 8000 K electron temperature.  相似文献   

20.
Abstract— We studied the elemental and isotopic abundances of noble gases (He, Ne, Ar in most cases, and Kr, Xe also in some cases) in individual chondrules separated from six ordinary, two enstatite, and two carbonaceous chondrites. Most chondrules show detectable amounts of trapped 20Ne and 36Ar, and the ratio (36Ar/20Ne)t (from ordinary and carbonaceous chondrites) suggests that HL and Q are the two major trapped components. A different trend between (36Ar/20Ne)t and trapped 36Ar is observed for chondrules in enstatite chondrites indicating a different environment and/or mechanism for their formation compared to chondrules in ordinary and carbonaceous chondrites. We found that a chondrule from Dhajala chondrite (DH‐11) shows the presence of solar‐type noble gases, as suggested by the (36Ar/20Ne)t ratio, Ne‐isotopic composition, and excess of 4He. Cosmic‐ray exposure (CRE) ages of most chondrules are similar to their host chondrites. A few chondrules show higher CRE age compared to their host, suggesting that some chondrules and/or precursors of chondrules have received cosmic ray irradiation before accreting to their parent body. Among these chondrules, DH‐11 (with solar trapped gases) and a chondrule from Murray chondrite (MRY‐1) also have lower values of (21Ne/22Ne)c, indicative of SCR contribution. However, such evidences are sporadic and indicate that chondrule formation event may have erased such excess irradiation records by solar wind and SCR in most chondrules. These results support the nebular environment for chondrule formation.  相似文献   

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