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1.
Water column samples have been collected in the outer channel of the Ferrol Ria (NW Spain) during four occasions over a tidal cycle. The objective was to study the exchange of dissolved and particulate Cd, Cu, Pb and Zn and particulate Al, Fe and Si between the ria and the adjacent coastal waters. This study provides the first extensive dataset on dissolved and particulate metal concentrations in the water column of a Galician ria. Typical concentrations of dissolved Cd (96 ± 31 pM), Cu (8 ± 4 nM), Pb (270 ± 170 pM) and Zn (21 ± 10 nM) were similar than in other European Atlantic shelf and coastal waters. The fraction of metals in the particulate phase followed the trend: Pb > Cu Zn > Cd. The outgoing water from the ria was enriched in dissolved and particulate Cu, Pb and Zn compared with incoming waters, whereas Cd concentrations were similar for both waters. The suspended particulate matter was composed of a mixture of marine and continental material. The latter end-member was found to arise from the metal-rich ria bed sediments, which is diluted by the dominant metal-poor marine end-member. The net output flux of Cu from the channel is balanced by the freshwater inputs to the ria, and the net Zn flux gave a positive output to coastal waters. For Pb, the net flux to the coastal waters is less than that input from the rivers, as a result of its particle reactivity and deposition in sediments. On the contrary, a net input flux of dissolved Cd from coastal waters was observed, highlighting the oceanic source of this metal in the Galician rias. Results from the budget calculations are in agreement with the differential geochemical behavior of these elements in coastal waters.  相似文献   

2.
《Marine Chemistry》2002,79(1):1-26
This study investigates the relative importance of processes that affect trace metal (TM) cycling in the upper water column at the shelf edge of the Celtic Sea on the western European continental margin. The examined processes include external inputs (by atmosphere and river), physical factors (upwelling, winter mixing and water mass advection) and biological processes (in situ uptake, regeneration and export to deep waters). The concentrations of dissolved Cd, Cu, Ni and Pb were measured with this aim in January 1994 and June 1995 at vertical stations across slope, including stations with upwelling, and in the surface waters along the Celtic Sea shelf. Additionally, deep sea (from sediment trap data) and atmospheric fluxes were estimated. The metal profiles over the slope off the Celtic Sea are quite similar to open ocean profiles already described in the northeast Atlantic, and the concentrations in surface waters are only slightly enriched compared to the nearby open ocean (1.2–1.3× for Cd and Ni). The external sources to the system appear to be of weak influence: the fluvial input is locally strong at the coast and then “diluted” along the large continental shelf; the atmospheric deposition is not significant at the annual scale in comparison to the metal content in the upper waters of the shelf edge (at least for Cd, Ni and Cu). In the upwelling zone, a significant increase in concentrations was observed in the summer surface mixed layer (×2 for nitrate and Cd and ×1.5 for Ni) in comparison to the non-upwelling zone. In winter, concentrations of bioreactive metals increased significantly in the surface waters in comparison to the low summer levels (×5 for nitrate and Cd). Our results suggest that upwelling and winter mixing act as regenerated sources that lead to the resupply of the bioreactive elements above the permanent thermocline with a low export to deeper waters. The tracing of the Mediterranean intermediate waters (MIW) from Gibraltar to the studied area shows indeed that its elemental content at the Celtic shelf edge is mainly due to the conservative mixing of the three “end-member” component waters which are thought to make up the MIW. The remineralization of organic matter within this water mass during its transport to the north would contribute only 20% of the nutrients and Cd concentrations recorded at the Celtic Sea shelf edge. According to the correlation found with nutrients in the 10–200-m layer, dissolved Pb would also be subjected to biological uptake and regeneration within the seasonal thermocline. Particulate scavenging removal of Pb would take place below the permanent thermocline throughout the water column.  相似文献   

3.
The distributions of the trace metals iron (Fe), copper (Cu) and cadmium (Cd) along with hydrological parameters (salinity, temperature and reactive phosphate) across the New Zealand continental shelf near Otago Peninsula have been studied. This is a region in which the Subtropical Convergence (STC), a major oceanic front separating subtropical and subantarctic waters, is uniquely located close to land, permitting an examination of the influence of terrestrial sources of Fe and Cu on oceanic waters containing excess micronutrients. Acid-soluble (110 nmol kg−1) and dissolved (6.3 nmol kg−1) Fe concentrations were highest over the central shelf, and decreased rapidly across the mixing zone of the STC to about 5 nmol kg−1 for both forms. The distribution of acid-soluble and dissolved Cu were similar to their counterparts for Fe. Depth-concentration profiles for acid-soluble Fe and Cu suggest resuspension of shelf sediments is the main source. The ratio of oxine-labile to acid-soluble Fe varied from 0.03 to 0.26, with the highest values found in the near surface waters. Oxine-labile Fe and Cu also decreased in concentration in a seawards direction, and with depth, indicating the influence of near surface processes on the reactivity of these elements. Cd concentrations across the continental shelf were very low (<200 pmol kg−1) and exhibited no clear spatial trend and no correlation with phosphate. Comparison of the Cd/P ratio across the shelf indicated that the waters in this region were strongly depleted in Cd relative to P. Phosphate concentrations were lowest in neritic water and increased in the seawards direction because of mixing with nutrient-rich Subantarctic Surface Water.  相似文献   

4.
Concentrations of dissolved Ni, Cu, Zn, Cd and Pb were measured in water samples collected during a cruise with R.V Pelagia (29-6/14-7-1993) in the northern North Sea and N.E. Atlantic Ocean. At least six depths (0–90 m) were sampled with modified Go-Flo samplers from a rubber zodiac. In the study area, the first 25 m were well mixed and stratification occurred below this depth. The local bloom of Emiliania huxleyi hardly affected the trace metals concentration, except for some removal of Cd as seen from its correlation with nitrate. The mean dissolved concentrations were for Ni (3.66 nM), Cu (1.61 nM), Zn (4.5 nM), Cd (48 pM) and Pb (108 pM). These concentrations are among the lowest reported for the North Sea and are of similar magnitude to those found in the eastern North Atlantic at the same latitude. Zn was the only exception with values 10 times higher compared to those in the Atlantic Ocean, suggesting external inputs, mainly atmospheric and possibly from surrounding land masses. The observed ratio Zn:Cd in the North Sea and estuaries is in between the high ratio 600–900 for continental sources and the low ratio 5–10 for oceanic waters. Latter low ratio is consistent with the 21-fold stronger inorganic complexation of Cd in seawater which, in combination with the preferential biological uptake of Zn, may lead to the observed about hundredfold fractionation of Zn versus Cd in the marine system. Other processes may play a role but would need further investigation. The dissolved Pb values tend to be lower than found before in the North Sea, indicating decreasing inventories due to reduced anthropogenic emissions.  相似文献   

5.
The influence of the Columbia River plume on the distributions of nitrate and iron and their sources to coastal and shelf waters were examined. In contrast to other large estuaries, the Columbia River is a unique study area as it supplies very little nitrate (5 μM) and iron (14–30 nM) at salinities of 1–2 to coastal waters. Elevated nitrate and dissolved iron concentrations (as high as 20 μM and 20 nM) were observed, however, in the near field Columbia River plume at salinities of 20. Surface nitrate concentrations were higher than observed in the Columbia River itself and therefore must be added by entrainment of higher nitrate concentrations from subsurface coastal waters. Tidal flow was identified as an important factor in determining the chemical constituents of the Columbia River plume. During the rising flood tide, nitrate and iron were entrained into the plume waters resulting in concentrations of 15 μM and 6 nM, respectively. Conversely, during the ebb tide the concentrations of nitrate and total dissolved iron were reduced to 0.3–3 μM and 1–2 nM, respectively, with a concomitant increase in chlorophyll a concentrations. As these plume waters moved offshore the plume drifted directly westward, over a nitrate depleted water mass (< 0.2 μM). The plume water was also identified to move southwards and offshore during upwelling conditions and nitrate concentrations in this far field plume were also depleted. Iron concentrations in the near-field Columbia River plume are sufficient to meet the biological demand. However, due to the low nitrate in the Columbia River itself, nitrate in the plume is primarily dependent on mixing with nitrate rich, cold, high salinity subsurface waters. Without such an additional source the plume rapidly becomes nitrate limited.  相似文献   

6.
Dissolved copper concentrations in surface waters of the Bering Sea ranged from 106 to 882 ngl–1. Higher concentrations were found in continental shelf waters. In the northwestern North Pacific dissolved copper ranged from 54 to 140 ngl–1. Particulate copper concentrations varied regionally and seasonally from 6 to 79 ngl–1. Regionally averaged particulate copper concentrations decreased from 175 to 33g g–1 against an increase in suspended materials because of the dilution effects of biological fractions. Apparent sporadic increases in copper concentrations were found in the mixing area of the Kuroshio and the Oyashio waters. The feature is attributed to the lateral distribution of different water types rather than to the upwelling of deeper waters by eddies. In the same area west of 160E, waters with high concentrations of dissolved copper (96±9 ngl–1) were found. Their origin appears to be the continental shelf of the Bering Sea. In spite of intensive biological activity, a considerable fraction of copper added to shelf waters was transported to the area off Japan via the circulation in the Bering Sea and the Oyashio current.  相似文献   

7.
《Marine Chemistry》2005,93(2-4):81-103
Surface water transects and vertical profiles for dissolved iron, macronutrients, chlorophyll a (Chl a), and hydrographic data were obtained in the Peru upwelling regime during August and September 2000. The supply of the micronutrient iron, relative to that of the macronutrients nitrate, phosphate and silicic acid, is shown to play a critical role in allowing extensive diatom blooms to develop in the Peru upwelling system. The extremely high-chlorophyll “brown waters of Peru” (with Chl a concentrations between 20 and 45 μg/l) result from massive diatom blooms with maximal photochemical efficiencies (Fv/Fm >0.6) occurring in the iron-rich upwelling region observed over the broad continental shelf off northern and central Peru. The source of the upwelled water in this region is the nutrient-rich subsurface countercurrent in contact with the organic-rich shelf sediments. This subsurface shelf water is suboxic and has extremely high concentrations of dissolved Fe (>50 nM) in the near-bottom waters. In marked contrast, relatively low-chlorophyll “blue waters” (Chl a <2 μg/l) with low concentrations of dissolved Fe (<0.1 nM) and high unutilized macronutrient concentrations are observed in the coastal upwelled waters along the southern coast of Peru and in the offshore regions of the Peru Current. Southern Peru is a region without a wide shelf to serve as a source of iron and, as a result, dissolved Fe concentrations in the near-bottom suboxic waters of this region are an order-of-magnitude lower than observed off northern and central Peru. In addition, the offshore Peru Current is a broad, Fe-limited, high-nitrate, lower than expected chlorophyll region extending hundreds of kilometers offshore into the northeast region of the South Pacific subtropical gyre and northwestward into the South Equatorial Pacific.  相似文献   

8.
The Portuguese margin in front of the Tagus and Sado rivers is characterized by a narrow shelf incised by numerous canyons and by a large mud deposit. The two estuaries that feed this continental margin have distinct impact. The suspended particulate matter concentration values in the mouth of the Tagus are four times higher than in the Sado. During the summer the surface nepheloid layer is always larger than during the winter when it is restricted near the mouth of the estuary. This nepheloid layer may reach 30 km in length extending westward. The bottom nepheloid layer usually shows higher nephelometer values, and has a typical distribution: it is usually diverted southward in the direction of the Lisbon Submarine Canyon. We estimate the amount of suspended matter being discharged annually from the Tagus estuary to be between 0.4 and 1×106 t. The area covered by fine deposits is about 560 km2. Hence the thickness of sediments deposited annually should be between 0.07 and 0.18 cm. The sedimentation rates calculated from the 210Pb excess vary between 0.16 and 2.13 cm y−1 which correspond to the maximum rate. For a layer of 1 cm thick, 81,000 t of particulate organic carbon (POC) should be trapped. That would represent, with a minimum sedimentation rate between 0.07 and 0.18 cm y−1, an entrapment of 6000–15,000 t POC y−1. The trace metals content of box core samples clearly shows the anthropogenic impact in the uppermost level (5 cm thick) in the Tagus estuary and in all the sedimentary deposits (15 cm thick) on the shelf muddy area. Despite the narrowness of the shelf, a significant part of continental fluxes fails to reach the deep ocean.  相似文献   

9.
Freshwater concentrations confirm the pristine character of the Lena River environment as already pointed-out in a previous study with a limited set of data (Martin et al., 1993). Total dissolved concentrations of the freshwater are 13.8 ± 1.6 nM, Cu, 4.4 ± 0.1 nM, Ni, 0.054 ± 0.047 nM, Cd, 642 ± 208 nM, Fe, 0.2–0.3 nM Pb and 1.2 ± 1.0 nM, Zn. For Zn and Pb, a simple mixing of the Lena River waters with the Arctic waters is observed. Relationships with salinity suggest that for Cu, Ni and Cd, there is a mobilization of the dissolved fraction from the suspended matter, with an increase of the dissolved concentration of 1.5, 3 and 6 times, respectively. For Fe, the total dissolved concentrations follow an exponential decrease in the mixing zone and 80% of the total “dissolved” Fe is removed from the solution. For Cu, Ni, Cd and Fe, the riverine end-members are 20 nM, 12 nM, 0.3 nM and 47 nM, respectively. When considering the input of total dissolved metals to the Arctic Ocean, the fraction attributed to the freshwaters from the Arctic rivers appears to be small (4% of the input of dissolved metal to the Arctic Ocean for Cd, 27% for Cu, 11 % for Ni and 2% for Zn). Metal concentrations in the Laptev Sea and Arctic Ocean are very similar, indicating a generally homogeneous distribution in the areas sampled.  相似文献   

10.
Toxic Gymnodinium catenatum blooms usually occur in the Galician Rias at the end of the upwelling season, which necessitates a ban on harvesting shellfish extraction, with subsequent economic losses for this sector. One of the possible causes cited in the literature is the advection of populations from outside the area but no evidence was available to substantiate this.Oceanographic conditions at the end of the upwelling season in the NW coast of the Iberian Peninsula (39°–43°N) have been studied for the years 1986, 1990, 1995 and 1998. Sea surface temperature data from satellite images, wind data, drifter tracks and in situ oceanic data from the Galician Rias have been combined to clarify the oceanographic structures in the area at the commencement of the blooms. On the inner shelf, an inshore poleward current advecting warm water has been identified after the cessation of upwelling. On the middle and outer shelf, a tongue of cold water as a remnant of the previous upwelling continued to move southward. On the slope and offshore, the poleward counter current reported by several authors was detected carrying warm oceanic water northwards.It is suggested that the inshore poleward current, not previously reported in the literature, could advect initial populations of dinoflagellates to the Rias from northern Portuguese waters. This would explain why blooms such as G. catenatum have been found usually in Portuguese waters several weeks before the Galician Rias, showing an apparent northward movement, but cells of this toxic dinoflagellate species have not been found in waters of the offshore poleward counter current.  相似文献   

11.
Total dissolvable metals (Co, Ni, Cu, Cd, and Pb) in both surface waters and the water columns were acquired in the southern East/Japan Sea during a cruise around the Ulleung Basin in June 2001 to understand the spatial distributions of the metals. Concentrations in offshore surface waters were found to be Co 60 ± 12 pM, Ni 2.16 ± 0.25 nM, Cu 1.85 ± 0.55 nM, Cd 0.134 ± 0.018 nM, and Pb 155 ± 40 pM. Spatial distributions in surface waters showed that metal levels were generally enhanced at coastal sites in both Korea and Japan, where the metal distributions indicated complex patterns due to inputs, biogeochemical processes, and physical factors including upwelling. The Co distributions in the water columns seemed to be influenced predominantly by surface and bottom inputs, scavenged rather than regenerated at depth. For Cd, there was generally good agreement between the Cd and PO4 depth distributions, in agreement with the literature. The Cd/PO4 ratio from the water columns was found to be 0.133–0.203, lower than that in other marginal seas (e.g. the East/South China Seas and the Philippine Sea) of the western Pacific Ocean; this might be a result of the fast ventilation rate in this sea. The vertical Pb profile showed typical scavenged-type behavior with a surface maximum and deep minimum. From a comparison of inputs from the atmosphere and the Tsushima Warm Current, atmospheric deposition is substantial enough that it cannot be ignored, and its role in metal cycling is more significant in the offshore zone.  相似文献   

12.
Copper concentrations were measured in the sediments and dissolved phase of the water column in the Lérez Estuary (Pontevedra Ria, Galicia), NW Spain, and in the freshwater-sewage inputs to the estuary. Dissolved copper fluxes in the estuary were quantified. Results show that the freshwater end-member in the Lérez Estuary has minimal copper contamination ([Cu](Dissolved)=7+/-4 nM, Sediment Enrichment Factor=1) and the source of dissolved copper inputs is localized in the saline end-member ([Cu](Dissolved)=20-55 nM, Sediment Enrichment Factor=6-7). A non-conservative behaviour of dissolved copper showing a net addition during estuarine mixing was observed. The budgetary calculations and the copper sediment distribution suggest that the major copper input to the estuary-ria system is located at the Marín-Placeres transect, playing an important role in the net addition of copper within the estuarine mixing. The importance of upwelling in the renewal of the Galician coastal waters and dilution of continental inputs is discussed.  相似文献   

13.
The distributions of iodide, iodate and total iodine were determined along a transect from the Sargasso Sea and across the Gulf Stream to the continental shelf of the South Atlantic Bight during November 1990. The western boundary of the Gulf Stream at the outer shelf-upper slope was characterized by steeply sloping isotherms and isopleths of iodide and iodate, resulting from a dome of cold water that was rich in iodate and nearly devoid of iodide at the slope. Both the mid and the inner shelf were relatively well mixed vertically. The concentration of iodate in the surface waters decreased shoreward from >0.3 μM in the Sargasso Sea/Gulf Stream/outer shelf, to 0.29 μM in the midshelf, 0.19 μM in the outer-inner shelf and 0.11 /IM in the inner-inner shelf. Concomitantly, the concentration of iodide increased from <161 nM to 175 nM, 257 nM and 300 nM. The concentration changes were more abrupt in the inner-inner shelf within about 30 km from the shore. There was no evidence of significant concentrations of organic iodine. These distributions of iodide and iodate suggest that the South Atlantic Bight may act as a geochemical processor of dissolved iodine. Iodate is added to the shelf during topographically induced upwelling and frontal exchange with the Gulf Stream. In the shelf waters, iodate is reduced to iodide in situ. Iodide is exported from the shelf to the Gulf Stream which may eventually further transport it to the ocean interior. A ☐ model calculation suggests that 28% and 43% of the iodate added to the Bight and the inner shelf, respectively, are converted to another form in these waters, almost all of which is iodide. About a third of the reduction of iodate to iodide in the Bight occurs in the inner shelf. Thus, the inner shelf may be the most geochemically active zone within the Bight. The residence times of iodide relative to its production and that of iodate relative to its removal are 3.1 and 3.6 months in the Bight and 0.9 and 1.8 months in the inner shelf.  相似文献   

14.
A linear decrease in dissolved organic carbon and nitrogen with increasing salinity offshore from the Georgia coast suggests that organic nitrogen compounds contributed to coastal waters by rivers are stable during the period (2–3 months) of their transfer over the continental shelf. While the C/N ratio decreased with distance from shore, total dissolved organic nitrogen (DON), total amino nitrogen, and primary amino nitrogen showed similar relative decreases, suggesting that nitrogen is associated with refractory organic compounds. Measured amino nitrogen accounted for about 20% of the total DON, leaving about 80% of the organic nitrogen undefined.  相似文献   

15.
Larval fish community structure was studied in the northeastern Aegean Sea (NEA) over an area influenced by the advection of Black Sea water (BSW). Sampling was carried out in early summer during a period of 4 years (2003–2006). Taxonomic composition and abundance presented high variability in space that remained relatively constant among years. Tow depth and indicators of trophic conditions in the upper water column (i.e., zooplankton displacement volume, fluorescence) explained significantly the structure of larval assemblages during all surveys. The northern continental shelf (Thracian and Strymonikos shelf), where a large amount of enriched, low salinity BSW is retained, was dominated by larvae of epipelagic species, mainly anchovy (Engraulis encrasicolus). Interannual changes in horizontal extension of the BSW seemed to match closely observed changes in the distribution of anchovy larvae. Mesopelagic fish larvae were particularly abundant beyond the continental shelf (over the North Aegean Trough) where a strong frontal structure is created between the low salinity waters of BSW origin and the high salinity waters of the Aegean Sea. Larvae of certain mesopelagic species (e.g., Ceratoscopelus maderensis) may occasionally be transported inshore when the prevailing current meanders towards the coast or feeds anticyclonic gyres over the continental shelf.  相似文献   

16.
Nepheloid layer dynamics in the northern Portuguese shelf   总被引：1，自引：0，他引：1  
A general hydrographic and nephelometric survey of the NW Portuguese continental shelf and upper slope was undertaken, under winter and spring conditions. The nepheloid layer dynamics along the shelf during three cruises were controlled, principally by the following factors: (a) the hydrography of the shelf-slope waters, i.e. the nepheloid layers followed isopycnals and water masses; (b) prevalence of upwelling or downwelling circulation over the shelf; (c) dispersion of material by river discharge (mainly the Douro river); (d) resuspension of mid-shelf fine deposits induced by swell; (e) peculiar morphology with the presence of Porto Canyon and outer shelf rock outcrops.The general circulation controls the seaward extension of the nepheloid layers. In winter, under dominant downwelling conditions, an intense bottom nepheloid layer (BNL) was observed on the shelf, due to river borne particle supply and remobilization of mid-shelf muddy sediments (depth ≈100 m). In this period the BNL increased in thickness to the top of the slope, following the isopycnals. Near the shelf-break the BNL detached to form intermediate nepheloid layers (INL). Small INLs appear deeper in some areas of the slope. A surface nepheloid layer (SNL) appears in the surface water over the shelf and slope. In spring, biological particles mainly contribute to the SNL, which is separated from the BNL by a zone of clear water. In winter the SNL is restricted to the inner shelf where there are high inputs of fluvial particles.Downwelling circulation probably induces transport of shelf particles to deeper waters in the BNL. In spring, the predominant circulation was southward (upwelling), the water column was highly stratified, and dispersion of particles in the SNL was offshore.  相似文献   

17.
Dissolved titanium distributions in the Mid-Atlantic Bight   总被引：1，自引：0，他引：1  
Stephen A. Skrabal   《Marine Chemistry》2006,102(3-4):218-229
Although titanium is abundant in Earth's crust, its sources and distribution in the ocean are poorly understood. To elucidate its behavior, distributions of dissolved (< 0.2 μm) Ti were determined in surface waters and vertical profiles from the Mid-Atlantic Bight (MAB). Concentrations of Ti decreased from 390 pM at the Delaware Bay mouth to < 100 pM across the Delaware continental shelf. In vertical profiles, small increases in bottom waters suggest a possible flux of Ti from shelf sediments, consistent with previous reports of pore water enrichments of dissolved Ti in MAB sediments. Concentrations in surface waters of the outer shelf and slope ranged between 30 and 140 pM, with most values below 90 pM. Concentrations in a 1000 m vertical profile in the eastern Gulf Stream ranged between 110 and 280 pM, and showed a variable distribution attributed to the mixing of water masses in the outer MAB. A simple model of Ti sources to the MAB suggests that atmospheric deposition of dissolved Ti is comparable to net riverine contributions and therefore must be considered in applications of Ti as a tracer of oceanographic processes.  相似文献   

18.
In July 2002, a combination of underway mapping and discrete profiles revealed significant along-shore variability in the concentrations of manganese and iron in the vicinity of Monterey Bay, California. Both metals had lower concentrations in surface waters south of Monterey Bay, where the shelf is about 2.5 km wide, than north of Monterey Bay, where the shelf is about 10 km wide. During non-upwelling conditions over the northern broad shelf, dissolvable iron concentrations measured underway in surface waters reached 3.5 nmol L−1 and dissolved manganese reached 25 nmol L−1. In contrast, during non-upwelling conditions over the southern narrow shelf, dissolvable iron concentrations in surface waters were less than 1 nmol L−1 and dissolved manganese concentrations were less than 5 nmol L−1. A pair of vertical profiles at 1000 m water depth collected during an upwelling event showed dissolved manganese concentrations of 10 decreasing to 2 nmol L−1, and dissolvable iron concentrations of 12–20 nmol L−1 in the upper 100 m in the north, compared to 3.5–2 nmol L−1 Mn and 0.6 nmol L−1 Fe in the upper 100 m in the south, suggesting the effect of shelf width influences the chemistry of waters beyond the shelf.These observations are consistent with current understanding of the mechanism of iron supply to coastal upwelling systems: Iron from shelf sediments, predominantly associated with particles greater than 20 μm, is brought to the surface during upwelling conditions. We hypothesize that manganese oxides are brought to the surface with upwelling and are then reduced to dissolved manganese, perhaps by photoreduction, following a lag after upwelling.Greater phytoplankton biomass, primary productivity, and nutrient drawdown were observed over the broad shelf, consistent with the greater supply of iron. Incubation experiments conducted 20 km offshore in both regions, during a period of wind relaxation, confirm the potential of these sites to become limited by iron. There was no additional growth response when copper, manganese or cobalt was added in addition to iron. The growth response of surface water incubated with bottom sediment (4 nmol L−1 dissolvable Fe) was slightly greater than in control incubations, but less than in the presence of 4 nmol L−1 dissolved iron. This may indicate that dissolvable iron is not as bioavailable as dissolved iron, although the influence of additional inhibitory elements in the sediment cannot be ruled out.  相似文献   

19.
Trace element concentrations (Pb, Cd, Mn, Fe, and Zn) were measured along four surface water transects across the continental shelf off Baja California, to evaluate the magnitude of heavy metal contamination in the coastal waters along the US-Mexican boundary. These initial measurements of trace elements in Mexican neritic waters revealed offshore concentration gradients, with the highest levels in coastal waters with high salinities and nutrient concentrations. There were also longshore gradients, with lower concentrations in the southern locations. Although the relative enrichment of metals detected at nearshore stations along the US-Mexican border appeared to correspond to wastewater discharges in that area, these trace metal enhancements were found to be primarily associated with physical oceanographic processes (upwelling and advection), rather than anthropogenic inputs. This was demonstrated both by metal-nutrient correlations and multivariate statistical analyses. Mass balance calculations also indicated that about 1% of Cd, 9% of Zn, and 29% of Pb were from urban discharges within the area.  相似文献   

20.
《Oceanologica Acta》1998,21(2):179-190
The annual cycle of temperature, salinity and nutrients of surface waters (up to 100 m depth) was studied from June 1991 to December 1995 in a cross-shelf section over the continental shelf waters off Santander (southern Bay of Biscay). The time series showed that the temperature followed the expected seasonal warming and cooling pattern, which determines a seasonal process of stratification and mixing of the water column. The stratification period occurs annually between May and October in a layer of about 50 m depth from the neritic station beyond to the shelf-break. In the period between November and April the water column remained mixed. During spring and summer low salinity values were found in the surface due to continental runoff and advection from oceanic waters. In late autumn and winter, the salinity pattern was governed by an influx of salty water associated with the poleward current. As in other temperate latitudes, nitrates showed the highest values in winter throughout the water column and the lowest values at the surface during the stratified period. Wind-induced upwelling events were observed mainly in summer, which are characterised by low temperatures (< 12°C), high salinity and nutrient concentrations. The inter-annual variability of temperature showed a warming trend in the upper layers but this sign was not found at 100 m depth. In salinity a decreasing trend was observed throughout the water column, and this feature corresponds to the relaxing of the high salinity anomaly detected in the North Atlantic at the beginning of the 1990s. Both trends were coherent in the cross-shelf section from the coast to the slope.  相似文献   

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