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1.
Summary Reflectance spectra for gold have been determined at temperatures of 25°, 300°, and 500°C between 400 and 700 nm. The extremely steep dispersion curve is significantly flattened by the increase of temperature (higher reflectances in the short wavelengths range, lower reflectances in the middle part of the spectrum and in the long wavelengths range, no temperature dependent reflectances at c. 500 nm). This temperature dependent shifting of the spectral reflectance curve is a reversible process.
Das Reflexionsverhalten von Gold bei Temperaturen bis zu 500°C
Zusammenfassung Die Reflexionsspektren von Gold wurden bei Temperaturen von 25°, 300° und 500°C zwischen 400 und 700 nm bestimmt. Die außerordentlich steile Dispersonskurve verflacht mit steigender Temperatur (höhere Reflexion im kurzwelligen Spektralbereich, niedrigere Reflexion im mittleren und langwelligen Spektralbereich, temperaturunabhängige Reflexion bei etwa 500 nm). Die temperaturabhängige Änderung des Kurvenverlaufs ist ein umkehrbarer Vorgang.

With 2 Figures  相似文献   

2.
The sample interval for the selection of extreme magnitudes plays an important part in the quality of Gumbel model fitting. A short sample interval can produce many observations, which is helpful in obtaining a reliably fitting model. However a short sample interval can bring many dummy ``observations', a condition which adversely biases the fitting. The short sample interval also increases the chance to introduce non-independent observations as well, which violates a basic requirement of the Gumbel model. On the other hand, a large time interval not only reduces the number of observations, but also enlarges the observation error. Thus, for Greece, the most suitable parameters of the third Gumbel extreme model are obtained by using a sample interval which produces minimum error. In consideration of the reliability of the seismic data, earthquakes with magnitude M 5.5 in Greece and its surrounding region after 1900 are used mainly in the present paper. In order to obtain well resolved contour maps with smooth changes a 2°× 2° cell with half-degree overlap strategy was used to scan the region. The most expected largest earthquake for the next fifty, one hundred and two hundred years are estimated for each cell. Likewise, the events with magnitude at a probability of 90\% of non-exceedance over the next fifty, one hundred and two hundred years are estimated for each cell. In parallel to this procedure we also analyze the 67 shallow seismic zones outlined by Papazachos and his colleagues and detail individual zone results where these are obtained. The most perceptible earthquake magnitude for the range of intensities I = {VI}, VII and VIII are also calculated. All results show that the areas around the Hellenic Arc and the Cephalonia Transform Fault for Greece have comparatively high frequency of destructive earthquakes accompanied by a high occurrence probability of moderate earthquakes (M 5.5).  相似文献   

3.
Fission-track ages in apatite are generally accepted as giving a measure of the time over which a sample has been exposed to temperatures below approximately 100° C. A compilation of the lengths of confined fission tracks in a wide variety of apatites from different geological environments has shown that the distribution of confined track lengths can provide unique thermal history information in the temperature range below about 150° C over times of the order of 106 to 109 years. The distribution of confined lengths of freshly produced induced tracks is characterised by a narrow, symmetrical distribution with a mean length of around 16.3 m and a standard deviation of the distribution of approximately 0.9 m. In volcanic and related rocks which have cooled very rapidly, and never been reheated above about 50° C, the distribution is also narrow and symmetric, but with a shorter mean of 14.5 to 15 m, and a standard deviation of the distribution of approximately 1.0 m. In granitic basement terrains which are thought never to have been significantly disturbed thermally, since their original post-emplacement cooling, the distribution becomes negatively skewed, with a mean around 12 or 13 m and a standard deviation between 1.2 and 2 m.This distribution is thought to characterise slow continuous cooling from temperatures in excess of 120° C, to ambient surface temperatures. More complex thermal histories produce correspondingly complex distributions of confined tracks. The continuous production of tracks through time, coupled with the fact that the length of each track shrinks to a value characteristic of the maximum temperature it has experienced, gives a final length distribution which directly reflects the nature of the variation of temperature with time. Most distinctive of the myriad possible forms of the final distribution are the bimodal distributions, which give clear evidence of a two-stage history, including high and low temperature phases. The study of confined length distributions therefore offers invaluable evidence on the meaning of any fission-track age, and bears the potential of providing rigorous constraints on thermal history in the temperature regime below about 150° C. The results of this study strongly suggest that any apatite fission-track age determination should be supported by a confined track length distribution.  相似文献   

4.
On the basis of the systematic variation and the appearance and disappearance of some metamorphic minerals in metapelitic assemblages, the metamorphic terrain of Leros can be divided into chlorite, biotite, garnet and staurolite-kyanite zones of progressive regional metamorphism. The matapelites are interbedded with blueschists containing magnesioriebeckite in Fe3+-rich mafic assemblages in the chlorite zone and more normal greenschist and amphibolite facies in higher grade zones. Combining the observed mineral assemblages in pelitic and mafic schists with the available experimental or calculated relevant phase equilibria, one can deduce temperature conditions of metamorphism ranging from about 350° C up to about 700° C and pressures ranging between a minimum value defined by the pressure of the triple point of the Al2SiO5 polymorphs and a possible minimum around 7 kb.The observed metamorphic sequence may be interpreted as the result of progressive transportation of the original sediments and the interbedded mafic rocks from a regime typified by low temperatures and relatively high pressures, to regimes characterized by higher temperature and medium pressures.  相似文献   

5.
Kriging with imprecise (fuzzy) variograms. I: Theory   总被引：2，自引：0，他引：2  
Imprecise variogram parameters are modeled with fuzzy set theory. The fit of a variogram model to experimental variograms is often subjective. The accuracy of the fit is modeled with imprecise variogram parameters. Measurement data often are insufficient to create good experimental variograms. In this case, prior knowledge and experience can contribute to determination of the variogram model parameters. A methodology for kriging with imprecise variogram parameters is developed. Both kriged values and estimation variances are calculated as fuzzy numbers and characterized by their membership functions. Besides estimation variance, the membership functions are used to create another uncertainty measure. This measure depends on both homogeneity and configuration of the data.  相似文献   

6.
In order to understand the formation mechanisms of gold-bearing arsenopyrites, hydrothermal experiments have been performed. Needle-shaped gold-rich (up to 1.7 wt % as compared to 1.6 wt % in some natural occurrences) zoned arsenopyrites were obtained at 400 °C and 500 °C under 1 and 2 kbar PH2O. Comparisons with natural needle-like gold-rich arsenopyrite from the Le Châtelet deposit (Creuse, France) revealed analogous zoning of As/S ratio, with similar gold content and zonations. Fluid inclusion studies carried out in the host quartz of the latter indicate high formation temperatures and variable redox conditions. Compared with the neighbouring Villeranges gold deposit, where arsenopyrite was formed at about 200 °C with gold being mainly trapped within its structure, it appears that temperature is not likely to be the major factor for such an incorporation. Alternatively, it is suggested that non-equilibrium rapid crystallization may induce gold trapping under an extended range of T-P-fO2 conditions. The practical importance of the needle-like habit of arsenopyrite in areas where geochemical gold anomalies are known without visible gold being detected, is emphasized.  相似文献   

7.
The pseudobinary section Al2SiO5-Cr2SiO5 of the system Al2O3-Cr2O3-SiO2 has been investigated at 20 and 30 kb pressure in the temperature range 1,000–1,600° C. The solubility of Cr2SiO5 in kyanite (Al2SiO5) extends up to 24 mole % Cr2SiO5 at 20 kb and 31 mole % at 30 kb. The extent of this solid solution is not notably dependent on temperature in the range studied. The stability of kyanite is increased by the substitution Cr Al by about 80° C at 20 kb as compared to Cr-free kyanite. Cr-poor sillimanite and Cr-rich kyanite can stably coexist in a temperature interval of up to 80° C at 20 kb and about 150° C at 25 kb.  相似文献   

8.
Summary Secondary minerals of a 91 meters-thick sequence of pillow basalts cored during ODP Leg 195 (Site 1201, West Philippine Basin) were investigated to reconstruct the hydrothermal alteration history and regime. The basement was first buried by red clays, and then by a thick turbidite sequence, thereby isolating it from seawater. The basalts are primitive to moderately fractionated, texturally variable from hypocrystalline and spherulitic to intersertal, sub-ophitic and intergranular. Relic primary minerals are plagioclase, clinopyroxene and opaques. Hydrothermal alteration pervasively affected the basalts, generating secondary clay minerals (mostly glauconite, minor Al-saponite and Fe-beidellite), iddingsite, Ca–Na-zeolites, minor alkali-feldspar and calcite. The secondary mineral paragenesis and mutual relationships suggest that the hydrothermal alteration occurred under zeolite-facies conditions, at temperatures <100–150°C. The main phase of alteration occurred under oxidizing conditions, with a high seawater/rock ratio, in an open-circulation regime, at temperatures of 30–60°C, with precipitation of abundant glauconite and iddingsite. A later stage of alteration occurred at ca. 70°C, with precipitation of abundant Ca–Na-zeolites and minor calcite, in a more restricted circulation regime as a consequence of basement burial under the sedimentary cover, which supplied an altered, Ca-rich and Mg–K-sulfate-poor water causing precipitation of almost pure calcite.  相似文献   

9.
Granitic rocks deformed by cataclasis and mylonitization on macro- (a few meters) and micro- (thin section) scales are found at depths down to 6.6km in the Siljan impact structure in central Sweden. Granites near fault planes exhibit: (1) fracturing, kinking, fragmentation, and recrystallization of feldspars into pure K and Na endmember varieties, (2) fragmentation, polygonization and development of undulose extinction in quartz, and (3) kinking, appearance of wavy extinction and alteration of biotite, chlorite, amphibole, and alteration of ilmenite and magnetite. Whole-rock chemical analyses of deformed and undeformed rocks show that deformed rocks are enriched in SiO2 (by about 5 wt.%) and depleted in other oxides by variable percentages. Apart from Rb and Co, the concentrations of other trace elements (including Ba, Sr, Zn, Zr, Pb, Cd, Cu, Cr, Ni, V, U, Th, La, and Li) are lower in deformed relative to undeformed rocks. Mass-balance calculations for a 1000 cm3 model granite which were based on modal mineralogy, whole-rock chemistry, and mineral analyses suggest that the break down of primary biotite, chlorite, and amphibole in deformed zones released elements to circulating fluids. These calculations also indicate liberation of water and a doubling of porosity (from 1 to 2%) during the deformation episodes. Later precipitation of minerals in shear and tension fractures reduced this porosity. Within the upper 2000 m of the Gravberg-1 well, the formation of fracture-filling minerals (smectite, calcite, hematite, chlorite, and albite) is impact-related, and was favored by active circulation of meteoric water. Fracture-filling minerals in the upper 2000 m of the borehole formed at temperatures of 70° to 200°C. Between depths of 2000 and 3500 m, fracture-filling mineral assemblages (dominated by Fe–Mg chlorite, sphene and epidote) suggest formation temperatures in the range of 150° to 300°C. Occurrence of pumpellyite and prehnite in some altered biotite and chlorite of the deformed zones between 3500 and 5500 m suggest preimpact metamorphism and formation temperature above 150°C. Below 5500 m, the mineral assemblages in the fractures are dominated by quartz, sphene, epidote, and some muscovite and chlorite, indicating a temperature range between 300° and 450°C. One of the possible origins for the CH4 and H2 gases detected in the Gravberg-1 well is a combination of hydrogen ions released by decomposition of hydrated silicates (biotite, chlorite, hornblende) with carbon. The presence of iron in the deformed granitic rocks prevented the resulting CH4 from being oxidized.  相似文献   

10.
The stability relations of lawsonite, CaAl2Si2O7(OH)2H2O, have been investigated at pressures of 6 to 14 GPa and temperatures of 740 to 1150°C in a multi-anvil apparatus. Experiments used the bulk composition lawsonite+H2O to determine the maximum stability of lawsonite. Lawsonite is stable on its own bulk composition to a pressure of 13.5 GPa at 800°C, and between 6.5 and 12 GPa at 1000°C. Its composition does not change with pressure or temperature. All lawsonite reactions have grossular, vapour and two other phases in the system Al2O3-SiO2-H2O (ASH) on their high-temperature side. A Schreinemakers analysis of the ASH phases was used to relate the reactions to each other. At the lowest pressures studied lawsonite breaks down to grossular+kyanite+coesite+vapour in a reaction passing through 980°C at 6 GPa and 1070°C at 9 GPa. Above 9 GPa the reactions coesite=stishovite and kyanite+vapour=topaz-OH are crossed. The maximum thermal stability of lawsonite is at 1080°C, at 9.4 GPa. At higher pressures the lawsonite breakdown reactions have negative slopes. The reaction lawsonite=grossular+topaz-OH+stishovite+vapour passes through 1070°C at 10 GPa and 1010°C at 12 GPa. At 14 GPa, 740–840°C, lawsonite is unstable relative to the assemblage grossular+diaspore+vapour+a hydrous phase with an Al:Si ratio of 1:1. Oxide totals in electron microprobe analyses suggest that the composition of this phase is AlSiO3(OH). Two experiments on the bulk composition lawsonite+pyrope [Mg3Al2Si3O12] show that at 10 GPa the reaction lawsonite=Gr-Pyss+topaz-OH+stishovite+vapour is displaced down temperature from the end-member reaction by 200°C for a garnet composition of Gr20Py80. Calculations suggest similar temperature displacements for reaction between lawsonite and Gr-Py-Alm garnets of compositions likely to occur in high-pressure eclogites. Temperatures in subduction zones remain relatively low to considerable depth, and therefore slab P-T paths can be within the stability field of lawsonite from the conditions of its crystallisation in blueschists and eclogites, up to pressures of at least 10 GPa. Lawsonite contains 11.5 wt% H2O, which when released may trigger partial melting of the slab or mantle, or be incorporated in hydrous phases such as the aluminosilicates synthesised here. These phases may then transport H2O to an even greater depth in the mantle.  相似文献   

11.
The syenitic layered series in the Klokken intrusion is surrounded by a zone (500 m thick) of nearly structureless unlaminated syenite followed outwards by a zone of vertically banded gabbro (200 m thick) at the outer rim. The unlaminated syenite is intrusive into the gabbro and develops a thin (2 m) transition zone of syenodiorite at the contact. A traverse across the vertical transition zone and inwards towards the layered series was sampled with a portable drill. Mafic silicates (olivine, clinopyroxene, biotite) show inward evolution in Fe/(Fe+Mg) across the syenodiorite-unlaminated syenite zones. Feldspars change rapidly across the syenodiorite zone from rocks dominated by plagioclase, in some cases together with two alkali feldspars, one a mesoperthite or cryptomesoperthite, the other a cryptoperthite, to rocks in which plagioclase is seen only rarely as cores to cryptomesoperthitic alkali feldspar crystals. Plagioclase is absent from the layered series.Alkali feldspars occurring in pairs have bulk compositions on solvus isotherms in the Or-Ab-An ternary system, estimated at 950° C in a syenogabbro and 910° C in a syenodiorite, at 1 kbar. The more calcic liquids from which they crystallized fractionated on paths that intersected the two- feldspar surface, whereas the more syenitic members crystallized from liquids which terminated crystallization in the one- feldspar field at 900° C. Plagioclases evolve from calcic andesine in syenodiorites, to very rare sodic oligoclase in the most evolved unlaminated syenites. The boundaries between plagioclase cores and alkali feldspar rims, which are usually optically abrupt, involve complex mixed zones on the m -scale, consistent with arrested reaction between plagioclase primocrysts and crystallizing syenitic liquid. Ternary liquidus-solidus relationships are in qualitative agreement with this interpretation. The syenodiorites are cumulates produced during sidewall crystallization of a trachytic magma against a gabbroic chamberlining. This magma changed little in bulk composition as it evolved, giving rise to the unlaminated syenites by further sidewall crystallization. Water build- up in this liquid probably caused a change in style of chamber filling, giving rise to the layered series by bottom accumulation. Microtextures in the zoned feldspars are described in an accompanying paper.CRPG contribution 729  相似文献   

12.
Indicator kriging (IK) is extended to analyze three-dimensional random unit vectors and evaluate the local probability distribution of rock joint orientations in geological formations. The pole vector representing joint orientations is regionalized and projected on a plane normal to the mean attitude of the joint family and centered at the mean. A two-dimensional cutoff system is developed to define the indicator variable, and corresponding indicator variograms and indicator kriging. The cutoff system defines probability regions similar to those of a bivariate distribution, concentric rings sliced into radial sectors. A case study made on an open pit mine proved positively the efficiency of IK and encourages its applications to localized probabilistic structural modeling for geotechnical or geohydrological analysis and oil and gas reservoir analysis.  相似文献   

13.
High-grade iron mineralisation (>65%Fe) in the North Deposit occurs as an E-W trending synclinal sheet within banded iron formation (BIF) of the Early Proterozoic Dales Gorge Member and consists of martite-microplaty hematite ore. Three hypogene alteration zones between unmineralised BIF and high-grade iron ore are observed: (1) distal magnetite-siderite-iron silicate, (2) intermediate hematite-ankerite-magnetite, and (3) proximal martite-microplaty hematite-apatite alteration zones. Fluid inclusions trapped in ankerite within ankerite-hematite veins in the hematite-ankerite-magnetite alteration zone revealed mostly H2O–CaCl2 pseudosecondary and secondary inclusions with salinities of 23.9±1.5 (1, n=38) and 24.4±1.5 (1, n=66) eq.wt.% CaCl2, respectively. Pseudosecondary inclusions homogenised at 253±59.9°C (1, n=34) and secondary inclusions at 117±10.0°C (1, n=66). The decrepitation of pseudosecondary inclusions above 350°C suggests that their trapping temperatures are likely to be higher (i.e. 400°C). Hypogene siderite and ankerite from magnetite-siderite-iron silicate and hematite-ankerite-magnetite alteration zones have similar oxygen isotope compositions, but increasingly enriched carbon isotopes from magnetite-siderite-iron silicate alteration (–8.8±0.7, 1, n=17) to hematite-ankerite-magnetite alteration zones (–4.9±2.2, 1, n=17) when compared to the dolomite in the Wittenoom Formation (0.9±0.7, 1, n=15) that underlies the deposit. A two-stage hydrothermal-supergene model is proposed for the formation of the North Deposit. Early 1a hypogene alteration involved the upward movement of hydrothermal, CaCl2-rich brines (150–250°C), likely from the carbonate-rich Wittenoom Formation (13C signature of 0.9±0.7, 1, n=15), within large-scale folds of the Dales Gorge Member. Fluid rock reactions transformed unmineralised BIF to magnetite siderite-iron silicate BIF, with subsequent desilicification of the chert bands. Stage 1b hypogene alteration is characterised by an increase in temperature (possibly to 400°C), depleted 13C signature of –4.9±2.2 (1, n=17), and the formation of hematite-ankerite-magnetite alteration and finally the crystallisation of microplaty hematite. Late Stage 1c hypogene alteration involved the interaction of low temperature (~120°C) basinal brines with the hematite-ankerite-magnetite hydrothermal assemblage leaving a porous martite-microplaty hematite-apatite mineral assemblage. Stage 2 supergene enrichment in the Tertiary resulted in the removal of residual ankerite and apatite and the weathering of the shale bands to clay.Editorial handling: B. Lehmann  相似文献   

14.
The pressure temperature stability of the phase Mn-cordierite hitherto not recorded as a mineral has been determined at temperatures ranging from 400° C up to the melting mainly using standard hydrothermal techniques at the oxygen fugacities provided by the buffering power of the bomb walls. Manganocordierite is a pronounced low-pressure phase with a maximum pressure stability of about 1 kb near 400° C and decreasing pressure limits at higher temperatures. Throughout the temperature range investigated the stable high-pressure breakdown assemblage of Mn-cordierite is spessartine, an Al-silicate, and a SiO2-polymorph. Due to the variable water contents of Mn-cordierite and spessartine there is a pronounced curvature in the negative dP/dT-slope of the requisite upper pressure breakdown curve of Mn-cordierite. Only theoretical deductions were possible concerning the stable hydrous low-temperature breakdown assemblage of Mn-cordierite below about 400° C.The manganocordierites synthesized are orthorhombic low-cordierites with distortion indices increasing with temperature, water pressure, and duration of heating. Their mean refractive indices increase with rising contents of absorbed water in the structural channels. Based on experiments with natural material the upper temperature stability limit of the mineral carpholite must lie at temperatures below about 400° C for water pressures up to 2.5 kb.The absence of Mn-cordierite from natural rocks studied thus far cannot be explained on chemical grounds, but must be due to its narrow pressure temperature stability range. The phase may yet be discovered as a mineral in manganiferous metasediments formed by lowpressure contact metamorphism.  相似文献   

15.
Twenty-six subcalcic diopside megacrysts (Ca/(Ca+ Mg)) = 0.280–0.349, containing approximately 10 mol% jadeite, from 15 kimberlite bodies in South Africa, Botswana, Tanzania, and Lesotho, have been characterized by electron microprobe analysis, X-ray-precession photography, and transmission electron microscopy. Significant exsolution of pigeonite was observed only in those samples for which Ca/(Ca+Mg)0.320. The exsolution microstructure consists of coherent (001) lamellae with wavelengths ranging from 20 to 31 nm and compositional differences between the hosts and lamellae ranging from 10 to 30 mol% wollastonite. These observations suggest that the exsolution reaction mechanism was spinodal decomposition and that the megacrysts have been quenched at various stages of completion of the decomposition process.Annealing experiments in evacuated SiO2 glass tubes at 1,150° C for 128 hours failed to homogenize microstructure, whereas, at 5 kbar and 1,150° C for only 7.25 hours, the two lattices were homogenized. This pressure effect suggests that spinodal decomposition in the kimberlitic subcalcic diopside megacrysts can only occur at depths less than 15 km; the cause of the effect may be the jadeite component in the pyroxene. Apparent quench temperatures for the exsolution process in the megacrysts range from 1,250° C to 990° C, suggesting that decomposition must have commenced at temperatures of more than 1,000° C.These P–T limits lead to the conclusion that, in those kimberlites where spinodal decomposition has occurred in subcalcic diopside megacrysts, such decomposition occurred at shallow levels (<15 km) and, at the present erosion level, temperatures must have been greater than 1,000° C.  相似文献   

16.
Microthermometric, stable isotope (D/H, 18O/16O), and Raman spectroscopic data are given for four different mineralization events located beneath a Triassic unconformity. These events include the Pb-Zn-bearing KII mineralization which fills geodes and fractures in the main karstic mineralization KI and the F mineralization which fills fractures in the Cambrian carbonates and shales. Post-KI, pre-KII, and F mineralization fluids were hot (150°C), moderately saline (10 equiv. wt% NaCl), and precipitated red dolomite. Subsequently, equally hot but more saline (20 equiv. wt% NaCl) fluids deposited white dolomite and then sphalerite of the F mineralization; they were followed by another generation of dolomite at about 70°C from fluids with about 15 equiv. wt% NaCl and, even later, barites (165°C, 10 equiv. wt% NaCl). Variation in the homogenization temperature with salinity for the different dolomite generations suggests that the hot saline fluids were repeatedly diluted by a cooler, less-saline fluid. The fluids are interpreted to be of formation-water origin having possibly developed in the deep levels of the Rhone basins to the southeast, which was at least 3 km thick at the time of mineralization (post-Hetangian). The inferred metal-bearing hot brines were probably episodically expulsed during the dewatering of the basin, depositing their mineralization in the more permeable fault and karstic zones associated with the uplift of the St. Bresson horst. Cold surface waters probably invaded the mineralized zones between the pulses of hydrothermal solutions. This hydrothermal model with the introduction of sulfides can account for the precipitation and dissolution textures associated with the hydrothermal mineralizations.  相似文献   

17.
Osumilitess was synthesized as a single phase product in the model system K2O-MgO-Al2O3-SiO2 at 800° C/ 0.5 Kbar water pressure and at 800° to 840° C/1.0 Kbar total pressure with 0.3 in the gas phase. The experimentally determined solid solubility range of synthetic osumilites can be expressed by the formula KMg2(Al3-xMgx) (Al2–xSi10+x)O30 with 0x0.4. A survey of sixteen chemical analyses of natural osumilites from eleven occurrences shows a solid solubility characterized by 0x0.6. Reversed stability experiments for the synthetic osumilite KMg2(Al2.75Mg0.25)(Al1.75Si10.25)O30 determined at water pressure equal to total pressure demonstrate its restriction to water pressures below 0.8 Kbar (at 0.5 Kbar, the stability range is between 765° and 800° C). At the lower thermal stability limit osumilite+H2O vapor break down to cordierite+K feldspar+phlogopitess+quartz, at the higher one to cordierite+K feldspar+phlogopite+liquid. Reduction of water fugacity will expand the stability field largely by shifting the lower and higher thermal stability limits to lower and higher temperatures, respectively. The dependence of osumilite stability on water fugacity makes osumilite a sensitive indicator mineral for dry conditions in rocks formed at total pressures higher than about 0.8 Kbar.  相似文献   

18.
Summary The Etive complex, one of the Caledonian Newer Granites of Scotland, is a ring complex of Devonian age, ranging in composition from pyroxene-diorite to leucogranite. Six samples, representing the major rock units in the southern parts of the Etive complex were chosen for mineral chemical studies and for estimation of the pressure and temperature conditions of magmatic crystallisation. Application of Al- in-hornblende barometry and crossite contents of amphiboles indicates a pressure <3kbar for the intrusion, in good agreement with published independent pressure estimates of 2kbar from mineral equilibria in metasedimentary hornfelses in the Etive thermal aureole. Thermometry, using ternary and binary feldspar systems, yields low temperatures, which probably reflect late-stage, post-magmatic re-equilibration of these minerals. Several geothermometers have been applied to the Quarry Diorite, the outermost intrusion of the complex. The highest temperature for the rocks comes from orthopyroxene–clinopyroxene solvus thermometry, and is 1000°C; this is interpreted to reflect the initial crystallisation of the diorite magma immediately after its emplacement. The maximum temperature from hornblende-plagioclase thermometer is 816°C, which probably reflects late-stage crystallisation of the magma.  相似文献   

19.
In the last few years, an increasing number of practical studies using so-called kriging estimation procedures have been published. Various terms, such as universal kriging, lognormal kriging, ordinary kriging, etc., are used to define different estimation procedures, leaving a certain confusion about what kriging really is. The object of this paper is to show what is the common backbone of all these estimation procedures, thus justifying the common name of kriging procedures. The word kriging (in French krigeage) is a concise and convenient term to designate the classical procedure of selecting, within agiven class of possible estimators, the estimator with a minimum estimation variance (i.e., the estimator which leads to a minimum variance of the resulting estimation error). This estimation variance can be seen as a squared distance between the unknown value and its estimator; the process of minimization of this distance can then be seen as the projection of the unknown value onto the space within which the search for an estimator is carried out.  相似文献   

20.
Sub-potassic nephelines in the system NaAlSiO4(Ne)-KAlSiO4(Ks) were synthesized under a variety of conditions and studied at room temperature and up to 1000 °C using an X-ray powder diffractometer. At low temperatures they do not have the hexagonal structure determined by Hahn and Buerger (1955) for natural nepheline. Samples with 0.7 to 2.5 mole % Ks have an orthorhombic supercell with parameters equivalent to a, 3a, 3c where a and c are Hahn and Buerger structure cell parameters. Nephelines with 0 to 0.7% Ks consist of two phases with different c axes; one of these phases has the orthorhombic supercell.Pure-Na nephelines (NaAlSiO4) invert to a hexagonal phase with the Hahn and Buerger structure at 190 °±10 °C; this inversion temperature decreases with increasing Ks and a sample with 0.5% Ks inverts at 170 °±5 °C. The inversion is reversible and is displacive. Another reversible inversion begins at 875 °±10 °C in pure-Na nepheline; this inversion increases in temperature with increasing Ks and a sample with 1.8% Ks begins to invert at 960 °±10 °C.Superstructures with anomalous low-temperature cell parameters in sub-potassic nephelines are attributed to reversible collapse of the framework about the larger cation sites which must be occupied by small Na in subpotassic nephelines. Superstructures in natural nephelines are also related to framework collapse at a displacive inversion.  相似文献   

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