首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 15 毫秒
1.
Pre-Cretaceous metasedimentary rocks occurring in the Inner Zone of the Southwest Japan Arc can be divided into three major groups, namely, high P/T metamorphic (Renge and Suo belts), low P/T metamorphic (Hida-Oki, Ryoke and Higo belts), and accretionary terranes (Akiyoshi, Maizuru, Mino-Tamba, and Ashio belts). Major and trace element compositions of most of the sedimentary rocks are typical of relatively mature sedimentary rocks, although abundances of ferromagnesian elements also suggest the presence of a significant mafic to intermediate igneous component. The sedimentary rocks with older Nd model ages (> 2.0 Ga) have high εSr values and major and trace element geochemical signatures typical of mature sediments, whereas those with younger model ages (< 1.45 Ga) have low εSr values and immature geochemical characteristics. With the exception of Hida samples, the sedimentary rocks from other districts have geochemical and isotopic features intermediate between the rocks with old and young Nd model ages. Some of the Hida samples have old Nd model ages, but others are influenced by younger rock fragments and have immature geochemical features. Based on combined isotopic and geochemical evidence, Inner Zone sedimentary rocks with older Nd model ages are interpreted to have been derived from felsic upper continental crustal materials such as Sino-Korean or northwest Yangtze craton granitoids. Compositions of rocks with younger Nd model ages reflect addition of mafic to intermediate detritus, such as island arc basalts and andesites. The rocks with intermediate Nd model ages may have formed in and around the Asian continental margin. The Hida metasedimentary rocks may have been derived from several terranes of varying age and geochemical composition.  相似文献   

2.
泥岩埋藏成岩过程中绿泥石的演化途径及意义   总被引：1，自引：0，他引：1       下载免费PDF全文
粘土矿物是泥质沉积岩重要的组成部分。在温度、压力、阳离子及水/岩比值等多种因素的共同作用下,埋藏成岩过程常常伴随着不同粘土矿物间的相互转化:蒙脱石、伊利石、高岭石和磁绿泥石等矿物均可发生绿泥石化。但各种矿物发生绿泥石化条件及反应机制不同,形成的绿泥石在化学成分及构型方面也有很大差异,通过X-射线衍射(XRD)、电子探针(EMPA)和高分辨率透射电子显微镜(HRTEM)等测试手段可识别出不同类型的绿泥石,区分不同转化序列并分析其转化机制。不同转化序列形成的绿泥石,不仅受温度的控制,还受阳离子类型和浓度的控制,在利用绿泥石作为地温计时需慎重;不同转化序列绿泥石化过程中都有水的参与,并伴有氢离子释放或消耗,这将会对有机质生烃产生影响。因此,关注泥岩埋藏成岩过程中绿泥石演化途径的差异,对拓宽绿泥石化的地质应用领域,特别是粘土矿物—有机质的协同作用具有重要的意义。  相似文献   

3.
Abstract

The characteristics and distribution of clay minerals and their effects on reservoir quality in the Huagang sandstones in the Xihu Sag, East China Sea Basin were studied by using X-ray diffraction, casting thin-sections, scanning electron microscopy, electron microprobe analysis, fluid inclusion analysis, constant-rate mercury injection and nuclear magnetic resonance. Clay minerals consist of kaolinite, chlorite, illite and illite–smectite mixed layer (I/S); kaolinite forms from dissolved feldspars, chlorite occurs as clay coatings that are transformed from clay precursors owing to the flocculation of suspended detrital clays or the crystallisation of pore fluids, and illite forms from the illitisation of detrital smectite, authigenic kaolinite and K-feldspars. Clay distribution is controlled by sedimentary environments, burial history and lithologies. Typical reservoirs in the western sub-sag are thin and developed in braided river facies at relatively shallow burial depths with clays dominated by kaolinite. However, typical reservoirs in the central inversion tectonic zone are thicker and developed in a braided delta front facies at deeper burial depths with clays mainly consisting of chlorite, illite and I/S. High-quality reservoirs are characterised by coarse granularity, high quartz content and low clay content with widespread development of chlorite coatings that inhibit quartz cements at low temperatures. At higher temperatures, the high-quality reservoirs develop more pores providing growth space for quartz cements and result in the coexistence of chlorite coatings and quartz cements. The high-quality reservoirs are controlled by their lithological characteristics rather than chlorite coatings. Illite and I/S clays create severe damage to reservoirs by reducing the size and connectivity of pore-throats.  相似文献   

4.
This paper reports the results of a detailed isotopic (Sm–Nd, Pb–Pb, and δ34S) and geochemical studies of Neoproterozoic metasedimentary rocks from the Patom and Bodaibo domains of the Baikal–Patom belt (northern Transbaikalia). It was shown that the metasedimentary rocks of these domains are strongly variable in their geochemical and isotope geochemical characteristics. Regular variations in these characteristics were observed, and their correlation with the main stages of the evolution of the sedimentary paleobasin in the Neoproterozoic was established.  相似文献   

5.
Bangladesh is situated in a subtropical to tropical climatic zone. A recently weathered crust has developed on sedimentary bedrock (sandstone, siltstone, shale and claystones) of Tertiary–Quaternary age. Weathered samples were collected from 16 sections totaling 68 samples and were analyzed mineralogically. The main primary minerals identified in the weathered crust of sedimentary rocks are quartz, plagioclase, K-feldspar, biotite, muscovite, sparse carbonate and epidote. The secondary minerals are kaolinite, illite, chlorite, gibbsite and goethite. Weathering initiated along the grain boundaries and cleavage planes of the minerals, forming small cloudy materials which were very difficult to identify. In the advanced stage of weathering, these cloudy materials have turned into secondary minerals. In region 1, high rain fall (7100 mm/yr) and monsoonic climate resulted in a kaolinite–gibbsite–goethite suite through the weathering of feldspars and biotite. The occurrence of gibbsite in the relatively elevated lands of Sylhet and Fe-kaolinite throughout the study areas is indicative of a humid–tropical climate during formation of the weathered crust.  相似文献   

6.
Cretaceous sedimentary and volcanosedimentary rocks from northwestern Kamchatka are considered. The stadial analysis has revealed variable impacts of three major provenances upon the Cretaceous Penzhina sedimentary basin. The provenances were composed of volcanic and volcanosedimentary rocks (Uda–Murgal island arc and Okhotsk–Chukotka volcanic belt) and granitic–metamorphic rocks (the mature Asian continental margin). Sediments were largely accumulated owing to the erosion of island-arc volcanics during reactivation of the Uda–Murgal island arc (Hauterivian–Barremian) or the Okhotsk–Chukotka volcanic belt (middle Albian–Cenomanian). Eroded granitic–metamorphic rocks of the mature Asian continental margin (Berriasian–Valanginian) or Asian metamorphic–volcanic rocks (Santonian–Campanian) were supplied to the basin during tectonically quiet periods (Berriasian–Valanginian and late Cenomanian–Campanian). Compositional changes in provenances were related to active tectonic processes at the continental margin, including evolution and closure of the Uda–Murgal island-arc system and origin of the Okhotsk–Chukotka volcanic belt. The postsedimentary modification of Cretaceous rocks deposited in forearc trough beyond the tectonically active accretionary prism is characterized by a low degree of clastic component alteration.  相似文献   

7.
Laterite occurs extensively over the crystalline and sedimentary rocks in the midland and lowland areas of south Kerala, India. Two lateritization cycles are identified in this area. Large, good-quality kaolin deposits, composed mostly of kaolinite, are characteristic of the sedimentary sequence in south Kerala. These deposits were formed on deposition of the weathering materials of the khondalites towards the first cycle of lateritization. After deposition and uplift of the sedimentary rocks, another lateritization cycle affected these, as well as the khondalites during pre-Quaternary times with the formation of a planation surface at 25–125 m above sea level having thick laterite profiles. The laterite profiles over the kaolin deposits show higher concentration of Fe-oxides (mostly in the form of hematite) and titania, compared to their concentration in the kaolins. Higher contents of Cr and Ni are also characteristic of the laterite over kaolin deposits. Recrystallization of the kaolinite, appearance of Al, Fe and Si amorphous phases in the kaolin clays and partial removal of Fe and Ti from them are attributed to the second lateritization cycle.  相似文献   

8.
Abstract Cordierite-anthophyllite rocks and related cordierite-rich, talc-rich and chlorite-rich rocks occur in the Rosebud Syncline, north-west Queensland, Australia, as part of a Proterozoic metasedimentary sequence. Field relations and rock compositions attest the sedimentary origin of these rather unusual metamorphic rocks. Their chemical composition is comparable to that of unmetamorphosed, alkali- and Ca-poor pelites, which are associated with some evaporite deposits. Other occurrences of cordierite-anthophyllite rocks have commonly been interpreted as metamorphosed chloritic alteration products derived from mafic or felsic volcanics. A comparative chemical study, using analyses of cordierite-anthophyllite rocks from such alteration zones and analyses of unmetamorphosed magnesian pelites, demonstrates the general chemical similarity between these two rock groups of entirely different origin. However, distinct differences in major element relations help to distinguish these two genetic groups. Particularly useful are Al2O3–FeO–MgO plots, in which evaporitic pelites occupy the Fe-poor side. The highly magnesian metamorphic rocks from the Rosebud Syncline fall entirely into the compositional field of evaporitic clays and shales. Furthermore, analyses of relatively immobile trace elements give supporting evidence for the sedimentary origin of these cordierite-anthophyllite rocks. The correlation with trace element ranges of clays and shales is very good. However, the correlation with trace element ranges of mafic and felsic volcanics is poor, and major discrepancies occur with Cr, Ni, Co, Nb, Sc, Th and Ti. Thus, the magnesian metamorphics of the Rosebud Syncline appear to be derived from evaporitic clays rich in magnesian clay minerals, such as palygorskite, sepiolite, chlorite or corrensite. The complete metamorphic rock assemblage of interlayered calcareous, aluminous and magnesian rocks is interpreted as a metamorphosed carbonate-evaporite-pelite sequence.  相似文献   

9.
We have studied the petrography and the bulk-rock geochemistry of arenites and mudstones of the Cenomanian Peruc–Korycany Formation to characterize their provenance and sedimentary history, as well as the influence of weathering, hydraulic sorting, and recycling of the source rocks. The Peruc–Korycany Formation contains sedimentary facies reflecting both meandering- and braided-river systems and shallow-marine systems. Differences in the three depositional settings did not cause distinctly different modifications of the framework compositions of the arenites. The sand from the fluvial systems is very mature (Qm98F0Lt2). These fluvial arenites were subsequently modified by shallow-marine processes; reworking produced very slight decreases in the abundance of lithic fragments and polycrystalline quartz grains. The Cenomanian strata of the Bohemian Cretaceous Basin were derived dominantly from metasedimentary and crystalline rocks of the Palaeozoic Teplà-Barrandian and Cadomian Moldanubian units, respectively. Periods of low tectonic activity resulted in the deposition of arenites with quartzose framework compositions, indicating that climatic and/or transport/depositional-environmental controls overwhelmed factors such as source-rock compositions. Ultrastable dense minerals are useful indicators of sedimentary recycling within the Peruc–Korycanytarenites. Mudstone samples are characterized by abundant kaolinite, illite, chlorite, and quartz but by negligible amounts of goethite and gypsum. Concentrations normalized to the post-Archaean Australian shale (PAAS) show that the sediments are strongly depleted of Na, K, Ca, Sr, and Ba, probably because of the mobility of these elements during weathering. Chemical indices of alteration (CIA, CIW, and PIA) show that the degree of weathering of the source area was high. The data fall closer to the compositional fields of highly weathered minerals such as kaolinite, gibbsite, and chlorite on an A-CN-K diagram. The indices of compositional variability of the studied samples are much less than 1, suggesting that the samples are compositionally mature and were likely dominated by recycling. The elemental ratios critical of provenance (La/Sc, Th/Sc, Th/Co, Th/Cr, and Cr/Th) are similar to fine fractions derived from the weathering of mostly granitoids rather than mafic rocks.  相似文献   

10.
The quantitative mineral composition estimated using the Rietveld method and some geochemical features are considered for bulk samples of the ice-rafted sediments (IRS) from some Arctic regions. Layer silicates in the studied samples vary from ~20 to ~50%. They are dominated by micas and their decomposition products (illite and likely some part of smectites) at significant contents of kaolinite, chlorite, and transformation/decomposition products of the latter. A significant content of illite and muscovite among layer silicates in most IRS samples suggests that sources of the sedimentary material were mainly mineralogically similar to modern bottom sediments of the East Siberian and Chukchi seas, as well as presumably sediments of the eastern Laptev Sea. It is suggested that a significant kaolinite fraction in IRS samples from the North Pole area can be caused by the influx of ice-rafted fine-grained sedimentary material from the Beaufort or Chukchi seas, where kaolinite is supplied from the Bering Sea. Positions of IRS data points in the (La/Yb)N–Eu/Eu*, (La/Yb)N–(Eu/Sm)N, and (La/Yb)N–Th diagrams show that the studied samples contain variable proportions of erosion products of both mafic and felsic magmatic rocks and/or sufficiently mature sedimentary rocks. This conclusion is confirmed by localization of IRS data points in the Th/Co–La, Si/Al–Ce, and Si/Al–Sr diagrams.  相似文献   

11.
Clays associated with the Precambrian unconformity-related (sensu lato) uranium mineralization that occur along fractures of Rohini carbonate, Bandai sandstone and clay-organic rich black carbonaceous Gorakalan shale of the Sonrai Formation from Bijawar Group is significant. Nature and structural complexity of these clays have been studied to understand depositional mechanism and palaeoenvironmental conditions responsible for the restricted enrichment of uranium in the Sonrai basin. Clays (<2 μm fraction) separated from indurate sedimentary rocks by disaggregation, chemical treatment and centrifugation were examined using X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). Presence of tv-1M type illite is inferred from the Rohini and Bandai Members of the Sonrai Formation, indicative of high fluid/rock interaction and super-saturation state of the fluids available in proximity with the uranium mineralization. It is observed that the Sonrai Formation is characterized by kaolinite > chlorite > illite > smectite mineral assemblages, whereas, Solda Formation contains kaolinite > illite > chlorite clays. It has been found that the former mineral assemblage resulted from the alteration process is associated with the uranium mineralization and follow progressive reaction series, indicating palaeoenvironmental (cycles of tropical humid to semi-arid/arid) changes prevailed during maturation of the Sonrai basin. The hydrothermal activity possibly associated with Kurrat volcanics is accountable for the clay mineral alterations.  相似文献   

12.
The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca++, Mg++ and K+ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006).  相似文献   

13.
Precambrian psammitic rocks of the Patom Highland as constituents of metasedimentary groups belong to the quartz-polymictic family, which is divided in each group into the following five petrochemical types: (A) highly silicic quartz sandstones, (B) silicic quartz sandstones, (C) alkali silicic quartz sandstones, (D) Fe-Si polymictic sandstones, and (E) Fe-Al-Si polymictic sandstones. The mineralogic-petrographic classification elaborated by Shutov (1967) may be applied to the calculated quantitative mineral and component compositions of metasandstone protoliths. According to this classification, the petrochemical types A–E may be correlated with monomictic (A′), oligomictic (B′), and mesomictic (C′) sandstones, feldspar-quartz graywacke (D′) and graywacke proper (E′), respectively.Quartz-polymictic sandstones make up the direct petrographic (mineralogic-petrographic) series A′-B′-C′-D′-E′ and the almost mirror inverse series E′-D′-C′-B′. The direct series A′-E′ represent the transgressive branches of sedimentary cycles that begin with the crustal redeposited products of chemical weathering, including high-Al schists and monomictic (A′) and oligomictic (B′) quartz sandstones. As the humid climate became arid, the sandstones gave way to the mesomictic sandstones C′ and to the polymictic sandstones D′ and E′ in the middle sections of sedimentary cycles. The polymictic sandstones mark culminations of tectonic activity that led to the formation of high mountains. The inverse series E′-B′ begin from the periods of mountainous topography and characterize regressive branches of sedimentary cycles that mark the decreasing tectonic activity. Polymictic sandstones E′ and D′ are replaced by oligomictic sandstones B′ in these branches. Thus, petrographic or mineralogic-petrographic series reflect the compositional evolution of psammitic rocks between epochs of peneplanation. The termination of these epochs and resumption of orogenic movements are documented by deposition of the Teptorgo-Mama, Kadalikan, and Bodaibo sedimentary groups. The onset of tectonic events fell on the terminal Paleoproterozoic, Early Riphean, and the Middle-Late Riphean. The composition of sedimentary rocks underwent progressive changes during the tectonic evolution of the continental margin of the Siberian Craton and the concomitant variation of paleoclimate.  相似文献   

14.
The Warchha Sandstone of the Salt Range of Pakistan is a continental succession that accumulated as part of a meandering, fluvial system during Early Permian times. Several fining-upward depositional cycles are developed, each of which is composed of conglomerate, cross-bedded sandstone and, in their upper parts, bioturbated siltstone and claystone units with distinctive desiccation cracks and carbonate concretions. Clast lithologies are mainly of plutonic and low-grade metamorphic origin, with an additional minor sedimentary component. Textural properties of the sandstone are fine- to coarse-grained, poorly to moderately sorted, sub-angular to sub-rounded, and with generally loose packing. Based on modal analyses, the sandstone is dominantly a feldspathoquartzose (arkose to sub-arkose). Detrital constituents are mainly composed of monocrystalline quartz, feldspars (more K-feldspar than plagioclase) and various types of lithic clasts. XRD and SEM studies indicate that kaolinite is the dominant clay mineral and that it occurs as both allogenic and authigenic forms. However, illite, illite-smectite mixed layer, smectite and chlorite are also recognised in both pores and fractures. Much of the kaolinite was likely derived by the severe chemical weathering of previously deposited basement rocks under the influence of a hot and humid climate. Transported residual clays deposited as part of the matrix of the Warchha Sandstone show coherent links with the sandstone petrofacies, thereby indicating the same likely origin. Illite, smectite and chlorite mainly occur as detrital minerals and as alteration products of weathered acidic igneous and metamorphic rocks. Based primarily on fabric relationship, the sequence of cement formation in the Warchha Sandstone is clay (generally kaolinite), iron oxide, calcareous and siliceous material, before iron-rich illite and occasional mixed layer smectite–illite and rare chlorite. Both petrographic analysis and field characteristics of the sandstone indicate that the source areas were characterised by uplift of a moderate to high relief continental block that was weathered under the influence of hot and humid climatic conditions. The rocks weathered from the source areas included primary granites and gneisses, together with metamorphic basement rocks and minor amounts of sedimentary rocks. Regional palaeogeographic reconstructions indicate that much of the Warchha Sandstone detritus was derived from the Aravalli and Malani ranges and surrounding areas of the Indian Craton to the south and southeast, before being transported to and deposited within the Salt Range region under the influence of a semi-arid to arid climatic regime.  相似文献   

15.
In the Pötürge (Malatya, Turkey) area pyrophyllite occurrences are common in the shear zones, mostly in the form of lenses along faults. Mineralogical investigations (XRD, FTIR and SEM) revealed that pyrophyllite, kaolinite (dickite) and quartz are present in the form of major phases and muscovite (sericite), kyanite, chlorite, and alunite are only present in the form of minor phases. This study revealed that the existence of the kyanite phase points out to high pressure and temperature conditions which the rocks were underwent. On the other hand, the minerals such as pyrophyllite, kaolinite, and alunite are products of a low degree metamorphism (retrograde). The mineral paragenesis in the pyrophyllite deposits suggests that the formation of minerals took place in two ways: (1) the transformation of kyanite into pyrophyllite and quartz through retrograde metamorphism by a high degree temperature, (2) then pyrophyllite and probably muscovite were transformed into kaolinite and alunite through reactions with relatively low temperature hydrothermal fluids. The geochemical data indicate that during the retrograde metamorphism the elements K, Rb, Sr, Ba, S, and Fe were mobile, the elements Si, Al, P moderately mobile to immobile and the HPS elements (Zr, Ti, and Nb) were immobile. It was shown that the formation of pyrophyllite, kaolinite and alunite was associated with depletion in alkalis, Mg, Fe and enrichment of elements including Sr, Ba, and S. Mineralogical and geochemical data suggest that parent rocks (pre-metamorphism) of the Pötürge pyrophyllite were probably kaolinite, Al-rich clays or bauxites.  相似文献   

16.
Metasedimentary and sedimentary rocks that represent the allochthonous Bolkardagi Unit crop out in the Central Taurus Belt. Devonian units include mainly slate, metadolomite, metadolomitic limestone, and metasandstone. Slates with slaty cleavage and chlorite-mica stacks are characterized by phyllosilicate, quartz, calcite, dolomite, feldspar, and goethite. Phyllosilicates consist of 2M1 and lesser amounts of 1M muscovite, IIb chlorite, pyrophyllite, paragonite. PM, C-V, C-S. rectorite, and dickite, and reflect conditions of the low epizone-anchizone. In the Carboniferous-Triassic units, limestone, clayey limestone, dolomitic limestone, marl, shale, and sandstone retaining primary textures are composed of calcite, dolomite, quartz,1Md illite, chlorite, and I-S, and locally smaller quantities of 2M1 muscovite, PM, paragonite, pyrophyllite, and rectorite. In contrast, the Triassic formation is made up of calcite, 1Md illite, I-S, kaolinite, smectite, chlorite, C-S, C-V, dolomite, and quartz. Textural and mineralogical data indicate that development of the diagenetic-metamorphic grade in the Central Taurus was related to sedimentary burial and thrusting; moreover, the metasedimentary rocks were metamorphosed in a typical anticlockwise P-T-t pathway in an extensional setting.  相似文献   

17.
15011993

Abstract

In 1990–1991 the LITHOPROBE project completed 450 km of seismic reflection profiles across the late Archaean crust of the southwestern Superior province. The results define a broad three-fold division of crust: upper crust in the Abitibi greenstone belt is non-reflective and is a 6–8 km veneer of volcanic and plutonic supracrustal rocks, whereas, in the sediment-gneiss dominated Pontiac subprovince, upper crust comprises shallow northwest-dipping turbidite sequences; mid-crust, in both the Abitibi and the Pontiac subprovinces, is interpreted as imbricate sequences of metasedimentary and metaplutonic rocks; lower crust in both subprovinces has a horizontal layer parallel strycture which may represent interleaved mafic-intermediate gneisses. The seismic signature of the northern Abitibi greenstone belt may be represented in an exposed 25 km crustal section in the Kapuskasing stuctural zone.

Preliminary tectonic models based on the seismic data are consistent with a plate-tectonic scenario involving oblique subduction and imbrication of sedimentary, plutonic and volcanic sequences. The northern Abitibi supracrustal sequences either represent an allochthon, or overlie an allochthonous underthrust metasedimentary and plutonic sequence which may be equivalent to a metasedimentary subprovince such as the Pontiac or Quetico.

Seismic velocities have yet to be defined. However, crustal thicknesses are relatively constant at 35–40 km. The thinnest crust is adjacent to the Grenville Front where Moho is very well defined.  相似文献   


18.
Geostructural setting, as well as mineral and isotopic compositions, of separate apatite deposits and occurrences in the Aldan Shield composed of Precambrian metasedimentary apatite–carbonate rocks are considered. In terms of carbon and oxygen isotopic compositions, they differ from other carbonate rocks of the Aldan Shield, including carbonatites and Ca–Mg metasomatites, and resemble Phanerozoic and Precambrian metasedimentary carbonates. They formed in oxidizing conditions. The contribution of evaporite processes at different stages of their formation is supported by the carbonate enrichment in 13C and the presence of sulfates. It was established that apatite–carbonate rocks represent the product of complex alternation of sedimentary processes at different values of salinity in the basins occasionally characterized by the decomposition of older sediments under subaerial conditions.  相似文献   

19.
The clay mineralogy of the Newark Supergroup (Upper Triassic/Lower Jurassic) in the Connecticut Valley was studied by X-ray diffraction analysis. Clay minerals identified in 126 samples are illite, chlorite, smectite, kaolinite, vermiculite, expandable chlorite, mixed-layer illite/smectite, mixed-layer chlorite/smectite, and mixed-layer chlorite/vermiculite. In general, the rocks are illitic with subordinate amounts of chlorite. However, the various lithofacies in the Newark Supergroup are characterized by distinct clay-mineral assemblages. Red beds of floodplain origin contain clays mainly of detrital nature with 2M illite most abundant. Subordinate amounts of chlorite, smectite, vermiculite, kaolinite and mixed-layer illite/smectite are also present. An interstratified chlorite/vermiculite occurs in red mudstone underlying basalt flows. Lacustrine gray beds are generally characterized by the clay-mineral assemblage 1Md illite + chlorite with minor amounts of smectite ane expandable chlorite. An interstratified chlorite/smectite predominates in gray mudstone associated with perennial lake cycles in the East Berlin Formation. Black shales of deeper lacustrine origin contain the assemblage 1Md ifillite + trioctahedral smectite and traces of chlorite. Illite and smectite also occur as mixed-layer phases.In many respects, the distribution of clay minerals in the Connecticut Valley can be likened to the general scheme proposed for the Permo-Triassic basins of Europe and Africa. These display both vertical and horizontal variations in clay-mineral assemblages that reflect the chemical and spatiotemporal evolution of intrabasin depositional and diagenetic environments. Chemical data indicate that magnesium, especially, was concentrated in the black muds of large perennial lakes that intermittently occupied the Connecticut rift valley. Pore waters derived from these sediments played an important role in the development of Mg-rich 2 : 1 and interstratified clay minerals during early diagenesis.  相似文献   

20.
The Guarguardz Complex, basement of the Cordillera Frontal, included in the proposed Chilenia Terrane, consists of metasedimentary rocks deposited in clastic and carbonatic platforms. Turbiditic sequences point out to slope or external platform environments. According to geochemical data, the sedimentary protoliths derived through erosion of a mature cratonic continental basement. Volcanic and subvolcanic rocks with N and E-MORB signature were interbeded in the metasedimentary rocks during basin development. A compressional stage, starting with progressive deformation and metamorphism, followed this extensional stage. Continuing deformation led to the emplacement of slices of oceanic crust, conforming an accretionary prism during Late Devonian. The Guarguardz Complex and equivalent units in western Precordillera and also in the Chilean Coastal Cordillera share common evolutional stages, widely represented along the western Gondwana margin. These evidences imply that Chilenia is not an allochthonous terrane to Gondwana, but a portion of its Early Paleozoic margin. Regional configuration indicates that the Guarguardz Complex and equivalent units represent the accretionary prism of the Famatinian arc (Middle Ordovician-Late Devonian).  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号