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滨海红树林泥炭沉积物中硫的赋存特点及其控制因素 总被引：4，自引：0，他引：4
海南和厦门两地滨海红树林沉积物和埋藏泥炭中硫的成分分析表明,滨海红树林沉积物和泥炭中的硫以硫化铁硫为主,有机硫次之,硫酸盐硫含量最低。泥炭沉积物中硫的赋存形式和特点与沉积环境密切相关。海南福田地区红树林泥炭沉积物主要形成于红树林潮上坪和泥炭坪,硫含量较高,平均为2.60%,且有机硫含量与有机碳含量呈正相关,而硫化铁硫含量与有机碳含量没有明显的相关性;厦门海沧镇红树林泥炭沉积物形成于红树林潮间坪以及潮道环境,硫含量较低,平均值仅为0.43%,形态硫和有机质的相关性与海南红树林泥炭地沉积物相反。红树林泥炭沉积物中铁的硫化物主要以黄铁矿形式产出,且以莓球状形态为主。研究表明,黄铁矿与次生有机硫的生成与微生物活动密切相关,造成红树林泥炭中硫含量差异最主要的原因不是硫源,而是有机质的供给与沉积微环境的影响。现代滨海红树林泥炭沼泽中硫的赋存特征将对煤中硫成因的研究提供重要的科学依据。 相似文献
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海南岛红树林泥炭中硫及其成因研究 总被引：4，自引：2，他引：4
海南岛红树林泥炭普遍富硫。黄铁矿、硫酸盐和有机硫是泥炭中硫的三种主要赋存形态,其中,以黄铁矿硫高为特征。利用形态硫分析、硫同位素分析等手段结合硫的时空变化特征,研究了泥炭中硫的形成机理。泥炭中硫的富集与泥炭坪环境具紧密的成因联系,全硫和形态硫的时空变化受微环境的控制;潮坪水介质中的硫酸盐是泥炭中硫的最初来源;泥炭中硫的加入,主要发生于准同生价段,在加入过程中还原硫细菌起了决定性作用。定量沉积环境分析是查明古代富硫煤田硫分布的主要途径。 相似文献
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通过对贵州东南部雷公坪泥炭进行年代学和有机碳同位素测定,雷公坪泥炭剖面底部150 cm处年龄为13 360±40 a BP,在中部70 cm处年龄为4 570±30 a BP,顶部10 cm处年龄为420±30 a BP,建立了雷公坪泥炭沉积的年代学序列,计算出泥炭层堆积速率由上至下分别为2381 cm·ka-1、1446 cm·ka-1、910 cm·ka-1。获得泥炭层泥炭有机碳同位素δ13C分别为-275‰、-288‰、-285‰,结合其他区域气候记录推断,说明研究区泥炭发育于相对温暖湿润的气候环境。 相似文献
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由刘焕杰、桑树勋、施健等著,中国矿业大学出版社出版的 成煤环境的比较沉积学研究--海南岛红树林潮坪与红树林泥炭(Comparative Sedimentology Rescarch on Coal-forming Environments--Mangrovetidal flats and mangrove peats in The Hainan Island ofThe South China Sea, China)是我国红树林潮坪与红树林泥炭领域第一部多学科系统研究专著,被列为国家教委“九五”重点图书,是国家自然科学基金资助项目的研究成果。 相似文献
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淄博地区本溪期—石千峰期沉积环境经历了障壁岛—泻湖—台地环境，三角洲环境，曲流河环境体系的演替。相应的泥炭形成环境有不稳定的局限泻湖泥炭坪，较开阔泻湖泥炭坪，中等稳定的开阔泻湖泥炭坪，三角洲平原分流河道两侧的泥炭沼泽，洪泛平原上的泥炭沼泽。成煤植物上，本溪期以Ｃｏｒｄａｉｔｅｓ，Ｌｅｐｉｄｏｄｅｎｄｒａｌｅｓ，Ｎｅｕｒｏｐｔｅｒｉｓ为主，太原期华夏植物群发展，Ｌｅｐｉｄｏｄｅｎｄｒｏｎ，Ｃｏｒｄａｉｔｅｓ继续发育，真蕨纲和种子蕨纲占越来越重要的地位。山西期以Ｏｄｏｎｔｏｐｔｅｒｉｓｓｐ．，Ａｎｎｕｌａｒｉａｏｒｉｅｎｔａｌｉｓ，Ｐｅｃｏｐｔｅｒｉｓｏｒｉｅｎｔａｌｉｓ，Ｐ．ｎｏｒｉｎｉ为主。自煤系形成至今，本区经历了海西印支期的普遍沉降埋藏、燕山期的普遍抬升局部断陷、喜山期的剥蚀、新构造运动期的差异沉降等阶段。古构造、古气候对本区成煤环境有重要的控制作用。 相似文献
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根据成因地层分析和沉积环境分析的方法,在永城煤田石炭二叠纪煤系识别出三种沉积体系、11个生长层序。重点分析了陆表海潮下碳酸盐岩沉积和碎屑潮坪沉积特征,认为灰岩在微观特征、微相类型上由上而下的有规律变化,符合向上变浅的缓坡型陆表海沉积模式。潮坪沉积物以潮道发育、砂泥混合坪标志明显为特征。三角洲则表现为浅水沉积性质。有价值的煤层形成于废弃碎屑潮坪泥炭沼泽和下三角洲平原泥炭沼泽。泥炭沼泽几乎不受咸水和活动碎屑体系的影响是主要煤层低硫低灰的原因。 相似文献
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黄河北煤田煤系广泛发育潮坪沉积体系,通过对其沉积特征及沉积模式的研究,认为潮坪沉积体系主要包括潮道（潮沟或潮渠）、泥坪、沙坪、砂泥混合坪及潮坪沼泽和潮坪泥炭沼泽相等沉积相类型,其特征是砂泥比值较高,沉积厚度大,为含煤地层发育提供物质基础;在沉积环境演化方面与整个鲁西南地区沉积特征相似,整体为海水逐渐衰退的过程;在潮坪沼泽和潮坪泥炭沼泽中形成含硫量相对较高的煤层与海平面的变化密不可分,潮坪沉积物中发育的10煤、8煤、7煤、6煤等与潮坪泥炭沼泽沉积在该区分布特点具有一致性,由此可知,潮坪沉积体系的沉积物与煤层形成特点和形成规律有着密切关系,为研究区成煤作用研究提供了理论依据。 相似文献
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The lignin component of humic substances: Distribution among soil and sedimentary humic,fulvic, and base-insoluble fractions 总被引：1，自引：0，他引：1
Vanillyl, syringyl and cinnamyl phenols occur as CuO oxidation products of humic, fulvic and base-insoluble residual fractions from soils, peat and nearshore marine sediments. However, none of these lignin-derived phenols were released by CuO oxidation of deepsea sediment or its base-extractable organic fractions. Lignin analysis indicated that peat and coastal marine sediments contained significantly higher levels of recognizable vascular plant carbon (20–50%) than soils and offshore marine sediments (0–10%).Although accounting for less than 20% of the total sedimentary (bulk) lignin, lignin components of humic acid fractions compositionally and quantitatively resembled the corresponding bulk samples and baseinsoluble residues. Recognizable lignin, presumably present as intact phenylpropanoid units, accounted for up to 5% of the carbon in peat and coastal humic acids but less than 1% in soil humic acids. Fulvic acid fractions uniformly yielded less lignin-derived phenols in mixtures that were depleted in syringyl and cinnamyl phenols relative to the corresponding humic acid fractions.Within the vanillyl and syringyl families the relative distribution of acidic and aldehydic phenols is a sensitive measure of the degree of oxidative alteration of the lignin component The high acid/aldehyde ratios and the low phenol yields of soils and their humic fractions compared to peat and coastal sediments indicate extensive degradation of the lignin source material. Likewise, the progressively higher acid/aldehyde ratios and lower phenol yields along the sequence: plant tissues (plant debris)-humic acids-fulvic acids suggest that this pattern represents the diagenetic sequence for the aerobic degradation of lignin biopolymers. 相似文献
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A comparative study of lignin and neutral carbohydrate compositions, combined with C, N and δ13C analyses, was carried out on sedimentary cores, and on various vascular plant species collected in mangrove swamps of French Guiana. The main purpose of this study was to assess the diagenesis of carbohydrates and lignin in brackish to hypersaline fine-grained mangrove sediments characterized by great changes in redox conditions. Distribution of carbohydrates in sediments reflects both the lability of these compounds and their efficient recycling. They are subject to selective degradation, cellulosic glucose and xylose appearing to be the two most labile neutral sugars. In contrast a relative increase in arabinose, rhamnose, fucose and hemicellulosic glucose between plants and sediments, suggests that they may be more refractory and/or that they also derive from microbial synthesis. The total carbon from lignin-derived phenols is higher in sediments than in mangrove plants as a consequence of their rather refractory character. Nevertheless, evidence of lignin decomposition was found to be independent of local environmental conditions. The various redox processes that occur in mangrove sediments depend on plant species, stages in forest development and season. Different redox conditions induce different mechanisms for the decomposition of lignin and thus induce changes in phenol distributions. At depth, in most mangroves, an increase in (Ad/Al)v ratios and in deoxy sugars (fucose and rhamnose) content was significantly correlated with increased proportions of oxidized allochthonous organic debris deriving from the Amazonian detrital discharge, thus suggesting a specific source effect rather than a diagenesis induced change. Therefore, this study illustrates that both lignin and cellulose, derived from vascular plant debris, can be degraded in waterlogged mangrove sediments, and that their distribution depends on environmental conditions. 相似文献
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S.I. Arbuzov L.P. Rikhvanov S.G. Maslov V.S. Arhipov A.M. Belyaeva 《International Journal of Coal Geology》2006,68(3-4):127-134
One hundred twenty-two samples of Jurassic and Paleogene brown coals and 1254 peat samples from the south-eastern region of the Western-Siberian platform were analyzed for gold by the neutron-activation method. Mean content of Au in Jurassic coals is 30 ± 8 ppb, in Paleogene coals is 10.6 ± 4.8 ppb, and in peat is 6 ± 1.4 ppb. Concentrations of gold as high as 4.4 ppm were found in coal ash and 0.48 ppm in the peat ash. Coal beds with anomalous gold contents were found at Western-Siberian platform for the first time.Negative correlation between gold and ash yield in coals and peat and highest gold concentrations were found in low-ash and ultra-low-ash coals and peat. Primarily this is due to gold's association with organic matter.For the investigation of mode of occurrence of Au in peat the bitumen, water-soluble and high-hydrolyzed substances, humic acids, cellulose and lignin were extracted from it. It was determined that in peat about 95% of gold is combined with organic matter. Forty to sixty percent of Au is contained in humic acids and the same content is in lignin. Bitumens, water-soluble and high-hydrolyzed substances contain no more than 1% of general gold quantity in peat.The conditions of accumulation of high gold concentrations were considered. The authors suggest that Au accumulation in peat and brown coals and the connection between anomalous gold concentrations and organic matter in low-ash coals and peat can explain a biogenic–sorption mechanism of Au accumulation. The sources of formation of Au high concentration were various Au–Sb, Au–Ag Au–As–Sb deposits that are abundant in the Southern and South-Eastern peripheries of the coal basin. 相似文献
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Sources of sedimentary humic substances: vascular plant debris 总被引：1，自引：0，他引：1
A modern Washington continental shelf sediment was fractionated densimetrically using either an organic solvent, CBrCl3, or aqueous ZnCl2. The resulting low density materials (<2.06 g/ml) account for only 1% of the sediment mass but contain 25% of the sedimentary organic carbon and 53% of the lignin. The C/N ratios (30–40) and lignin phenol yields () and compositions indicate that the low density materials are essentially pure vascular plant debris which is slightly enriched in woody (versus nonwoody) tissues compared to the bulk sediment. The low density materials yield approximately one-third of their organic carbon as humic substances and contribute 23% and 14% of the total sedimentary humic and fulvic acids, respectively. Assuming that the lignin remaining in the sedimentary fraction is also contained in plant fragments that yield similar levels of humic substances, then 50% and 30% of the total humic and fulvic acids, respectively, arise directly from plant debris.Base-extraction of fresh and naturally degraded vascular plant materials reveals that significant levels of humic and fulvic acids are obtained using classical extraction techniques. Approximately 1–2% of the carbon from fresh woods and 10–25% from leaves and bark were isolated as humic acids and 2–4 times those levels as fulvic acids. A highly degraded hardwood yielded up to 44% of its carbon as humic and fulvic acids. The humic acids from fresh plants are generally enriched in lignin components relative to carbohydrates and recognizable biochemicals account for up to 50% of the total carbon. Humic and fulvic acids extracted directly from sedimentary plant debris could be responsible for a major fraction of the biochemical component of humic substances. 相似文献
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通过对贵州盘县上二叠统钻井资料的研究分析,基于沉积岩石学、沉积学、古生物地史学及沉积地球化学等相标志识别出潮坪沉积以陆源碎屑沉积为主,可细分为砂坪、混合坪、泥坪、泥炭坪和潮沟等5种微相。分析认为:潮坪沉积发育海退型进积层序,沉积物粒度整体较细,分选性较好,发育潮汐层理;混合坪、泥坪、泥炭坪微相泥岩中V/(V+Ni)、Sr/Ba、U/Th、V/Cr、Ni/Co、Ceanom等地球化学参数指示了各微相沉积水体的缺氧-贫氧-氧化状态、贫氧-氧化状态和还原-贫氧-缺氧-氧化状态,与地质背景吻合性好。 相似文献