首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 344 毫秒
1.

The composition of fluid inclusions (FI) often represents the initial geochemical characteristics of palaeo-fluid in reservoir rock. Influence on composition and carbon isotopic composition of gas during primary migration, reservoir-forming and subsequent secondary alterations are discussed through comparing fluid inclusion gas with coal-formed gas and natural gas in present gas reservoirs in the Ordos Basin. The results show that primary migration of gas has significant effect on the molecular but not on the carbon isotopic composition of methane. Migration and diffusion fractionation took place during the secondary migration of gas in Upper Paleozoic gas reservoir according to carbon isotopic composition of methane in Fls. Composition and carbon isotopic composition of natural gas were nearly unchanged after the gas reservoir forming through comparing the FI gases with the natural gas in present gas reservoir.

  相似文献   

2.
During two sampling seasons we analyzed on weekly basis fatty acid (FA) composition of seston fraction <130 μm and zooplankton fraction >130 μm, and compared them using a multivariate canonical correlation analysis (CCA). Besides, we evaluated a possible impact of water temperature and inorganic nutrients on FA composition of the seston and the zooplankton.In spite of significant differences in percentages of several individual FAs, we found very strong canonical correlation (cross-correlation, 1-week lag) between FA composition of the seston and the zooplankton. The most important factor, providing the overall canonical cross-correlation between FA profiles of the seston and the zooplankton fractions was eicosapentaenoic acid (20:5ω3, EPA). FA composition of the zooplankton fraction had comparatively poor correlations with taxonomic composition of the zooplankton. Thus, seasonal variations of FA composition of the zooplankton were determined primarily by seasonal changes in FA composition of the seston, rather than by taxonomic differences of FA profiles between rotifers, cyclopoids and cladocerans. FA composition of the seston was strongly affected by its taxonomic composition, namely by that of phytoplankton. According to CCA, the highest factor loadings pertained to diatoms interacting with their marker acids, including EPA, and cyanobacteria and greens, interacting with their marker acids. Ciliates and small rotifers composed considerable and sometimes major part of the seston biomass, but according to CCA their contributions to seasonal variations of the total FA profile of the seston were insignificant. This finding indirectly support the conclusion of the other authors, that the main source of FAs presented in ciliates and rotifers must be sought in algae and that they do not modify FA composition of food consumed, apart from repackaging it.Water temperature was the principal environmental parameter which drove the overall variations of FA composition. Factor loadings for the inorganic nutrients were comparatively negligible. The main contribution in the seasonal variation of FA composition of the seston was given by negative interaction between water temperature and percentage of EPA in the seston.  相似文献   

3.
We have developed a generic dynamic model of extension of the lithosphere, which predicts major element composition and volume of melt generated from initial extension to steady state seafloor spreading. Stokes equations for non-Newtonian flow are solved and the mantle melts by decompression. Strengthening of the mantle due to dehydration as melting progresses is included. The composition is then empirically related to depletion. Using a crystallisation algorithm, the predicted primary melt composition was compared with mean North Atlantic mid-ocean ridge basalt (MORB). At steady state, using half spreading rates from 10 to 20 mm yr− 1 and mantle potential temperatures of 1300 to 1325 °C we predict a major element composition that is within the variation in the mean of North Atlantic MORB.

This model is applied to the Southeast Greenland margin, which has extensive coverage of seismic and ODP core data. These data have been interpreted to indicate an initial pulse of magmatism on rifting that rapidly decayed to leave oceanic crustal thickness of 8 to 11 km. This pattern of melt production can be recreated by introducing an initial hot layer of asthenosphere beneath the continental lithosphere and by having a period of fast spreading during early opening. The hot layer was convected through the melt region giving a pulse of high magnesian and low silica melt during the early rifting process. The predicted major element composition of primary melts generated are in close agreement with primary melts from the Southeast Greenland margin. The observed variations in major element composition are reproduced without a mantle source composition anomaly.  相似文献   


4.
The chemical composition of suspended particulate material (SPM) in the Tamar Estuary and its response to tidal sediment resuspension at the turbidity maximum have been investigated. The results discriminate four regions: (1) the outer estuary where spatial changes in the composition of SPM reflect the dispersal of estuarine particles modified by in situ generation of organic particles, (2) the middle estuary where the composition of SPM is mainly determined by hydrodynamic mixing although there is some evidence of in situ chemical reactivity, (3) the upper estuary where sharply distinct and temporally variable SPM compositions are centred at the turbidity maximum; these are largely the result of particle-selective accumulation, sedimentation and resuspension processes rather than of local particle-water chemical exchanges, and (4) the fluvial estuary where the SPM composition reflects the influx of riverine particles.  相似文献   

5.
The oxygen isotopic composition of modern soil carbonate is well correlated with the isotopic composition of local meteoric water. The carbon isotopic cycle for CO2 in soils can be described in terms of the proportion of biomass using the C4 photosynthetic pathway and the CO2 respiration rate of the soil; at low soil respiration rates significant atmospheric CO2 mixing can occur. In general, the carbon isotopic composition of soil carbonate is related to the proportion of C4 biomass present in soil, but soils that freeze to the depth of carbonate formation often have a significant atmospheric component. This suggests that freezing of the soil solution should be considered as another important mechanism for soil carbonate formation. Because of these relationships, the isotopic composition of soil carbonate may be a paleoclimatic and paleoecologic indicator in cases in which diagenetic alteration has not occurred.  相似文献   

6.
Stable carbon and oxygen isotope composition of fossilized brachiopod shells serves as an important source to delineate Earth's paleoenvironmental evolution in the Phanerozoic. However, the original isotopic composition is potentially modified by various kinds of diagenesis. To evaluate the extent to which the original isotopic composition of fossilized brachiopod shells is modified by meteoric diagenesis, microstructure, cathodoluminescence (CL) images, and carbon and oxygen isotope composition of fossilized Kikaithyris hanzawai (rhynchonellate brachiopod) shells were examined. The shells were collected from Pleistocene shallow marine carbonates exposed on the Ryukyu Islands, southwestern Japan. The extent of diagenetic alteration is quantitatively evaluated here as both the preservation state of the original shell microstructure and the luminescence/non‐luminescence of shells. Although altered fibers were commonly observed in the brachiopod shells, the original isotopic composition was almost retained. There are no significant differences in the isotopic composition between the luminescent and non‐luminescent shells. There is no direct relationship between the preservation state of the original shell microstructure and the luminescence/non‐luminescence of shells at three of four horizons, indicating that CL images are not necessarily useful for the detection of diagenetic alteration of shells or shell portions. Applying multiple criteria to assessing diagenetic alteration and cross‐checking them are required to distinguish between diagenetically altered and unaltered brachiopod shells.  相似文献   

7.
The textures of chondrules have been reproduced by crystallizing melts of three different compositions at 1 atm with cooling rates ranging from 400 to 20°C/min under 10?9 to 10?12 atmPO2. A porphyritic olivine texture has been formed from a melt of olivine-rich composition (SiO2 = 45 wt.%), a barred-olivine texture from melt of intermediate composition (SiO2 = 47 wt.%), and radial-olivine texture from melt of pyroxene-rich composition (SiO2 = 57 wt.%). The cooling rate for producing barred olivine is most restricted; the rate ranges from 120 to 50°C/min. Other textures can be formed with wider ranges of cooling rate. The results of the experiments indicate that some of the major types of textures of chondrules can be formed with cooling rate of about 100°C/min. With this cooling rate, the texture varies depending on the composition of melt.  相似文献   

8.
This study tested the hypothesis that the community composition of Chironomidae will change according to the duration of the exposure of plant leaves in a subtropical stream. In addition, we expected the chemical quality of the detritus to affect the association of Chironomidae with decaying plant materials. The chironomid colonisation of leaf litter from Campomanesia xanthocarpa and Sebastiania brasiliensis was assessed in a subtropical Atlantic forest stream. Litter bags containing leaves from these two species were incubated in the stream for 22 days. We identified 7245 invertebrates associated with the leaf detritus of both plant species (5110 were Chironomidae, 70.7% of the total). Thirteen genera of Chironomidae were identified, with Rheotanytarsus, Thienemanniella and Corynoneura the most abundant (94% of all Chironomidae collected). Chironomidae assemblages changed with the duration of incubation in the stream. The dissimilarity and the functional composition of the Chironomidae communities were related to the chemical composition of the detritus. The chemical components that best explained the composition of the fauna were tannins, the C:N ratio, calcium, and magnesium. However, the functional feeding groups were explained by the chemical variables organic matter and C:N. This study found that the exposure time of the detritus and therefore its level of degradation and chemical composition are important factors determining the characteristics of the Chironomidae assemblage in subtropical streams.  相似文献   

9.
A new model is proposed for the structure of the Kaapvaal craton lithosphere. Based on chemical thermodynamics methods, profiles of the chemical composition, temperature, density, and S wave velocities are constructed for depths of 100–300 km. A solid-state zone of lower velocities is discovered on the S velocity profile in the depth interval 150–260 km. The temperature profiles are obtained from absolute values of P and S velocities, taking into account phase transformations, anharmonicity, and anelastic effects. The examination of the sensitivity of seismic models to the chemical composition showed that relatively small variations in the composition of South African xenoliths result in lateral temperature variations of ～200°C. Inversion of some seismic profiles (including IASP91) with a fixed bulk composition of garnet peridotites (the primitive mantle material) leads to a temperature inversion at depths of 200–250 km, which is physically meaningless. It is supposed that the temperature inversion can be removed by gradual fertilization of the mantle with depth. In this case, the craton lithosphere should be stratified in chemical composition. The depleted lithosphere composed by garnet peridotites exists to depths of 175–200 km. The lithospheric material at depths of 200–250 km is enriched in basaltoid components (FeO, Al2O3, and CaO) as compared with the material of garnet peridotites but is depleted in the same components as compared with the fertile substance of the underlying primitive mantle. The material composing the craton root at a depth of ～275 km does not differ in its physical and chemical characteristics from the composition of the normal mantle, and this allows one to estimate the thickness of the lithosphere at 275 km. The results of this work are compared with data of seismology, thermal investigations, and thermobarometry.  相似文献   

10.
Variation in habitat structure provided by macrophytes is regarded as one of the determinants of macroinvertebrate species composition in lentic ecosystems, but mechanisms underlying this relationship appear to be confounded with site-specific factors, such as physicochemical factors, epiphyton and composition of the vegetation. To better understand the relationship between structural complexity of a macrophyte stand and its macroinvertebrate assemblage composition, it is essential to determine the ecological role of different components of habitat structure for the phytomacrofauna. Using artificial structures as macrophyte mimics, representing three growth forms (stems, broad-leaved, finely dissected) and three structure surface areas (0.1, 0.2, 0.3 m2), a full factorial field experiment was conducted in a series of drainage ditches. We investigated if macroinvertebrate assemblages colonizing the structures were affected by an increase in macrophyte structure surface area, structural complexity, or by a combination of both, and if the observed patterns were consistent among sites differing in physicochemical and habitat characteristics. Assemblages were characterized both in terms of taxonomic and functional composition, because we expected that non-taxonomic aggregation of species into functional categories would give a different insight in habitat complexity-macroinvertebrate relationships in comparison to approaches based on the taxonomic assemblage composition. Ditch intrinsic factors, in part reflected in the periphyton on the structures, explained the major proportion of the variance in both the taxonomical macroinvertebrate assemblages and functional groups among structures. Contrary to our expectation, patterns in the taxon-based and functional dataset resembled each other. Only a minor contribution of growth form to the explained variance was observed in the taxonomical dataset, whilst differences in functional composition were unrelated to habitat structure. In conclusion, processes operating on larger spatial scales overrode the micro-scale effects of habitat structural complexity and surface area on macroinvertebrates.  相似文献   

11.
In a study of the origin of basalt magma, peridotite has been partially fused and the composition of the liquid phases determined. Peridotite was chosen because it is thought to be the most likely material of the upper mantle. Geological evidence suggests that the upper mantle is not of basaltic composition and eclogitic mineralogy but that it is of ultrabasic composition. Although under some conditions an ultrabasic mantle may be within the field of eclogite stability, the comparative rarity of high-pressure phases such as garnet in ultrabasic nodules suggests that normal basalts are derived from non-eclogitic regions. The peridotite composition selected for experimental work was that of average peridotite (Nockolds). Charges of the synthetic peridotite were held at constant temperature (±1/2°C) in a non-oxidising atmosphere for one week. After quenching, the glass was extracted and analysed. The glass content varied from 4% at 1250°C to 26% at 1355°C. Its composition ranged from a basalt more or less saturated in normative silica at a temperature of 1310°C (15% fusion) and below, to picrite basalt at higher temperatures. The results confirm the general assumption that basalts can be the product of the partial fusion of peridotite. To date, the experimental work has been under anhydrous conditions at atmospheric pressure.  相似文献   

12.
Q. He  D. E. Walling 《水文研究》1998,12(7):1079-1094
River floodplains have been widely recognized as important sinks for storing suspended sediment and associated contaminants transported by river systems. The grain size composition of floodplain deposits exerts an important influence on contaminant concentrations, and commonly exhibits significant spatial variability in response to the dynamic nature of overbank flow and sediment transport. Information on the spatial variability of the grain size composition of overbank deposits is therefore essential for developing an improved understanding of the processes controlling sediment transport on floodplains, and for investigating the fate of sediment-associated contaminants. Such information is also important for validating existing floodplain sedimentation models. This paper reports the results of a study aimed at investigating the spatial variability of the grain size composition of floodplain sediments at different spatial scales, through analysis of surface sediment samples representative of contemporary floodplain deposits collected from frequently inundated floodplain sites on five British lowland rivers. Significant lateral and downstream variations in the grain size composition of the sediment deposits have been identified in the study reaches. An attempt has been made to relate the observed spatial distribution of the grain size composition of the overbank deposits to the local floodplain geometry and topography. The importance of the particle size characteristics of the suspended sediment transported by the rivers in influencing the spatial variability of the grain size composition of the overbank sediments deposited on these floodplains is also considered. © 1998 John Wiley & Sons, Ltd.  相似文献   

13.
If surface anomalies in the composition of the metallic-line A stars (Am stars) are due to a precipitation of planet-like bodies (planetoids) on them, then one should expect a correlation to exist between the overabundance of heavier-than-iron elements on these stars and their “standard” abundances in the solar system (since chondrites provide the “standard” level for these elements). However, an anticorrelation was revealed.Nevertheless, this fact supports the original suggestion on the origin of the metallicism of A stars, and can easily be explained within the author's hypothesis on the formation of the Sun from matter escaping from the proto-Jupiter. During the terminal stages of mass transfer, the matter was strongly depleted in refractories (forming the rocky core of Jupiter). Therefore the composition of the meteorites formed should not coincide with the primary composition of the matter. Thus the Sun's outer layers may also have a distorted composition. The author concludes that it is desirable to revise the “standard” abundances of elements heavier than iron.From a comparison of the surface composition of Am stars with the composition of lunar anorthosites and that of rocks in the upper zones of the Skaergaard intrusion (Greenland), the Am phenomenon may be seen to result from a precipitation of large geochemically differentiated planetoids onto a star. Such planetoids (including the Moon) condense in the cooled envelope of the primary component of a close binary stellar system.  相似文献   

14.
The chemical composition of sediment sampled from a network of ice boreholes contacting the bed of the ablation zone of the Greenland Ice Sheet is compared to the composition of intact bedrock clasts. This sediment is enriched in silica and depleted in reactive cations compared to the underlying bedrock. In order to test whether these differences result from grain size biases either in sample collection or due to natural sorting, sediment samples were analyzed by grain size aliquots. Enrichment of silicon and depletion of cations is consistent across grain size classes and the compositions of bedrock and subglacial sediment are statistically separate. The difference in composition between subglacial sediment and rock aligns closely with the composition of dissolved solutes in waters sampled from the same field sites and is dissimilar to the composition of the sites' suspended sediment. This implies that chemical weathering rather than disproportionate physical removal of friable minerals is responsible for the compositional differences between rock and sediment. Mass balance analysis implies 3–10% of the sediment's mass is lost to solute dissolution, with approximately double that amount precipitated as clay minerals (a large portion of which may have been physically expelled). This result implies that temperate ice sheet subglacial environments may be more chemically active than previously realized. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

15.
Abstract

Studies of the chemical composition of snowpack and stream water were carried out in a catchment having an area of 53km2 (31°03′-30°55′N and 78°40′-78°51′E) in the Garhwal Himalaya, India. The dominant ions in the snowpack and stream water were Ca2+, Na+, NO? 3, SO2- 4 and HCO? 3. Solute patterns in the snowpack show preferential elution. Investigation of the chemical composition of stream water shows that meltwater changes its composition substantially as it passes through soil pathways to the stream. The groundwater flushing perhaps controls the chemical composition of meltwater in the early spring. However, in the period from July to September, the stream water carries the chemical signature of monsoonal precipitation.  相似文献   

16.
This study critically assesses the temporal sensitivity of the steady-state model of erosion that has been applied to chemical and mechanical weathering studies of volcanic islands and the continents, using only one sample from each catchment. The model assumes a geochemical mass balance between the initially unweathered rock of a drainage basin and the dissolved and solid loads of the river.Chemical composition of 178 samples of suspended and dissolved inorganic river constituents, collected in 1998–2002, were studied from five basaltic river catchments in NE Iceland. The Hydrological Service in Iceland has monitored the discharge and the total suspended inorganic matter concentration (SIM) of the glacial rivers for ~ four decades, making it possible to compare modelled and measured SIM fluxes.Concentration of SIM and grain size increased with discharge. As proportion of clay size particles in the SIM samples increased, concentrations of insoluble elements increased and of soluble decreased. The highest proportion of altered basaltic glass was in the clay size particles.The concentration ratio of insoluble elements in the SIM was used along with data on chemical composition of unweathered rocks (high-Mg basalts, tholeiites, rhyolites) to calculate the pristine composition of the original catchment rocks. The calculated rhyolite proportions compare nicely with area-weighted average proportions, from geological maps of these catchments.The calculated composition of the unweathered bedrock was used in the steady-state model, together with the chemical composition of the suspended and dissolved constituents of the river. Seasonal changes in dissolved constituent concentrations resulted in too low modelled concentrations of SIMmod at high discharge (and too high SIMmod at low discharge). Samples collected at annual average river dissolved load yielded SIMmod concentrations close to the measured ones. According to the model, the studied rivers had specific mechanical denudation rates of 1.3–3.0 kg/m2/yr whereas the average measured rates were 0.8–3.5 kg/m2/yr which are among the highest on Earth.This study validates the use of a steady-state model of erosion to estimate mechanical weathering rates at the scale of a river catchment when the collected riverine dissolved load represents the average chemical composition over a mean hydrological year.  相似文献   

17.
Spatial variability of throughfall (TF) isotopic composition, used as tracer input, influences isotope hydrological applications in forested watersheds. Notwithstanding, identification of the dominant canopy factors and processes that affect the patterns of TF isotopic variability remains ambiguous. Here, we examined the spatio‐temporal variability of TF isotopic composition in a Japanese cypress plantation, in which intensive strip thinning was performed and investigated whether canopy structure at a fine resolution of canopy effect analysis is related to TF isotopic composition and how this is affected by meteorological factors. Canopy openness, as an index of canopy structure, was calculated from hemispherical photographs at different zenith angles. TF samples were collected in a 10 × 10 m experimental plot in both pre‐thinning (from July to November 2010) and post‐thinning (from May 2012 to March 2013) periods. Our results show that thinning resulted in a smaller alteration of input δ18O of gross precipitation, whereas the changes in deuterium excess varied in both directions. Despite the temporal stability of spatial patterns in TF amount, the spatial variability of TF isotopic composition was not temporally stable in both pre‐ and post‐thinning periods. Additionally, after thinning, the isotopic composition of TF was best related to canopy openness calculated at the zenith angle of 7°, exhibiting three different relationships, that is, significantly negative, significantly positive, and nonsignificant. Changes in meteorological factors (wind speed, rainfall intensity, and temperature) were found to affect the relationships between TF δ18O and canopy openness. The observed shifts in the relationships reveal different dominant factors (partial evaporation and the selection), and canopy water flowpaths control such differences. This study provides useful insights into the spatial variability of TF isotopic composition and improves our understanding of the physical processes of interception through canopy passage.  相似文献   

18.
The strontium isotopic geochemistry is given for three Puerto Rican intrusive rocks: the granodioritic Morovis and San Lorenzo plutons and the Rio Blanco stock of quartz dioritic composition. The average calculated initial87Sr/86Sr ratios are 0.70370, 0.70355 and 0.70408, respectively. In addition, the San Lorenzo data establish a whole-rock isochron of71 ± 2m.y., which agrees with the previously reported K-Ar age of 73 m.y. Similarity of most of the intrusive rocks in the Greater Antilles with respect to their strontium isotopic geochemistry regardless of their major element composition indicates that intrusive magmas with a wide range of composition can be derived from a single source material. The most likely source material, in view of the available isotopic data, is the mantle wedge overlying the subduction zone.  相似文献   

19.
Abstract

The potential of stable isotope ratios (2H/1H and 18O/160) of water as a modern tool for palaeoclimatic reconstructions on continents is reviewed. Examples of stable isotope records of palaeo-precipitation preserved in various continental archives (polar ice sheets, mid- and low latitude glaciers, lacustrine deposits, groundwater) are presented, and the methodology of their interpretation in terms of climatic changes is briefly discussed. To interpret quantitatively the isotope records preserved in continental archives, the response of the isotopic composition of precipitation to long-term fluctuations of key climatic parameters (temperature, precipitation amount, relative humidity) over the given area should be known. Further, the transfer functions relating the climate-induced changes of the isotopic composition of precipitation to the isotope record preserved in the given archive should be established. Since the isotopic composition of precipitation has been monitored only for the past three decades, alternatives ways of assessing the long-term climatic sensitivity of the isotopic signature of precipitation are being investigated. The isotope composition of precipitation should be viewed not only as a powerful proxy climatic indicator but also as an additional hydrometeorological parameter which should be explored as a diagnostic tool for the modelling of climate-induced changes in the water cycle, both on a regional and a global scale.  相似文献   

20.
Liquid metal-liquid silicate partitioning of Fe, Ni, Co, P, Ge, W and Mo among a carbon-saturated metal and a variety of silicate melts (magnesian-tholeiitic-siliceous-aluminous-aluminosiliceous basalts) depends modestly to strongly upon silicate melt structure and composition. Low valency siderophile elements, Fe, Ni and Co, show a modest influence of silicate melt composition on partitioning. Germanium shows a moderate but consistent preference for the depolymerized magnesian melt. High valency siderophile elements, P, Mo, and W, show more than an order of magnitude decrease in metal-silicate partition coefficients as the silicate melt becomes more depolymerized. Detailed inspection of our and other published W data shows that polymerization state, temperature and pressure are more important controls on W partitioning than oxidation state. For this to be true for a high and variable valence element implies a secondary role in general for oxidation state, even though some role must be present. Equilibrium core segregation through a magma ocean of ‘ultrabasic’ composition can provide a resolution to the ‘excess’ abundances of Ge, P, W and Mo in the mantle, but the mantle composition alone cannot explain the excess abundances of nickel and cobalt in chondritic proportions.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号