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1.
Coarse-grained whiteschist, containing the assemblage: garnet+kyanite+phengite+talc+quartz/coesite, is an abundant constituent of the ultrahigh-pressure metamorphic (UHPM) belt in the Kulet region of the Kokchetav massif of Kazakhstan. Garnet displays prograde compositional zonation, with decreasing spessartine and increasing pyrope components, from core to rim. Cores were recrystallized at T=380°C (inner) to 580°C (outer) at P<10 kbar (garnet–ilmenite geothermometry, margarite+quartz stability), and mantles at T=720–760°C and PH20=34–36 kbar (coesite+graphite stability, phengite geobarometer, KFMASH system reaction equilibria). Textural evidence indicates that rims grew during decompression and cooling, within the Qtz-stability field. Silica inclusions (quartz and/or coesite) of various textural types within garnets display a systematic zonal distribution. Cores contain abundant inclusions of euhedral quartz (type 1 inclusions). Inner mantle regions contain inclusions of polycrystalline quartz pseudomorphs after coesite (type 2), with minute dusty micro-inclusions of chlorite, and more rarely, talc and kyanite in their cores; intense radial and concentric fractures are well developed in the garnet. Intermediate mantle regions contain bimineralic inclusions with coesite cores and palisade quartz rims (type 3), which are also surrounded by radial fractures. Subhedral inclusions of pure coesite without quartz overgrowths or radial fractures (type 4) occur in the outer part of the mantle. Garnet rims are silica-inclusion-free. Type 1 inclusions in garnet cores represent the low-P, low-T precursor stage to UHPM recrystallization, and attest to the persistence of low-P assemblages in the coesite-stability field. Coesites in inclusion types 2, 3, and 4 are interpreted to have sequentially crystallized by net transfer reaction (kyanite+talc=garnet+coesite+H2O), and were sequestered within the garnet with progressively decreasing amounts of intragranular aqueous fluid. During the retrograde evolution of the rock, all three inclusion types diverged from the host garnet P–T path at the coesite–quartz equilibrium, and followed a trajectory parallel to the equilibrium boundary resulting in inclusion overpressure. Coesite in type 2 inclusions suffered rapid intragranular H2O-catalysed transformation to quartz, and ruptured the host garnet at about 600°C (when inclusion P27 kbar, garnet host P9 kbar). Instantaneous decompression to the host garnet P–T path, passed through the kyanite+talc=chlorite+quartz reaction equilibrium, resulting in the dusty micro-assemblage in inclusion cores. Type 3 inclusions suffered a lower volumetric proportion transformation to quartz at the coesite–quartz equilibrium, and finally underwent rupture and decompression when T<400°C, facilitating coesite preservation. Type 4 coesite inclusions are interpreted to have suffered minimal transformation to quartz and proceeded to surface temperature conditions along or near the coesite–quartz equilibrium boundary. 相似文献
2.
Scapolite–wollastonite–grossular bearing calc-silicate rocks from the Vellanad area in the Kerala Khondalite Belt (KKB) of Southern India preserve a number of reaction textures which help to deduce their P– T–fluid history. Textures include calcite+plagioclase±quartz symplectites after scapolite, grossular+quartz coronas between wollastonite and plagioclase, grossular coronas between wollastonite and plagioclase+calcite that replace former scapolite, and grossular blebs replacing anorthite+calcite+quartz pseudomorphs of scapolite. Garnet coronas are also observed between clinopyroxene and wollastonite or scapolite or plagioclase. The reactions, apart from those involving clinopyroxene, can be modelled in the simple CaO–Al 2O 3–SiO 2–CO 2 system and interpreted using partial reaction grids constructed for the activities of end-members in the analysed phases. The reaction topologies produced are good approximations for the peak as well as retrograde mineral assemblages and reaction textures. For the compositions of the phases present in this study, the medium pressure calc-silicate assemblages are defined by the stable pseudo-invariant points [Qtz], [Mei] and [Grs]. The textural features interpreted using these activity-corrected grids indicate a phase of isobaric cooling from about 835°C to 750°C at 6 kbar in the Vellanad area. This is inconsistent with earlier studies on other lithologies from the KKB, most of which imply a post-peak P– T path involving near-isothermal decompression. However, as the temperatures obtained for the KKB from the calc-silicates are higher than those previously deduced from metapelites and garnet–orthopyroxene assemblages, the phase of near-isobaric cooling reported here is inferred to have proceeded prior to the onset of the decompression documented from studies of other rock types. 相似文献
3.
In the Pulur complex, NE Turkey, a heterogeneous rock sequence ranging from quartz-rich mesocratic gneisses to silica- and alkali-deficient, Fe-, Mg- and Al-rich melanocratic rocks is characterized by granulite-facies assemblages involving garnet, cordierite, sillimanite, ilmenite, ±spinel, ±plagioclase, ±quartz, ±biotite, ±corundum, rutile and monazite. Textural evidence for partial melting in the aluminous granulites, particularly leucosomes, is largely absent or strongly obliterated by a late-stage hydrothermal overprint. However, inclusion relations, high peak P– T conditions, the refractory modes, bulk and biotite compositions of the melanocratic rocks strongly support a model of partial melting. The melt was almost completely removed from the melanocratic rocks and crystallised within the adjacent mesocratic gneisses which are silica-rich, bear evidence of former feldspar and show a large range in major element concentrations as well as a negative correlation of most elements with SiO 2. Peak conditions are estimated to be ≥800 °C and 0.7–0.8 GPa. Subsequent near-isothermal decompression to 0.4–0.5 GPa at 800–730 °C is suggested by the formation of cordierite coronas and cordierite–spinel symplectites around garnet and in the matrix. Sm–Nd, Rb–Sr and 40Ar/ 39Ar isotope data indicate peak conditions at 330 Ma and cooling below 300 °C at 310 Ma. 相似文献
4.
Because of late metamorphic and tectonic overprints, the reconstruction of prograde parts of P– T paths is often difficult. In the SW Variscan French Massif Central, the Thiviers-Payzac Unit (TPU) is the uppermost allochthon emplaced above underlying units. The TPU experienced a Barrovian metamorphism coeval with a top-to-the-NW ductile shearing (D2 event) in Early Carboniferous times ( ca. 360–350 Ma). The tectonic setting of the D2 event, compression or synconvergence extension, remains unclear. Using the THERMOCALC software and the model system MnNCKFMASH, the peak P– T conditions are estimated from garnet rims and matrix minerals and the prograde evolution is deduced from garnet core compositions. The combination of these two approaches demonstrates that the TPU experienced pressure and temperature increases before reaching peak conditions at 6.6–9.0 +/− 1.2 kbar and 615–655 +/− 35 °C. This kind of P– T path shows that the regional D2 event corresponds to crustal thickening. 相似文献
5.
The high pressure mafic granulites of the Bacariza Formation outcrop in the two uppermost structural units of the Cabo Ortegal Complex (La Capelada unit and Cedeira unit) were separated by a Variscan thrust. In both cases, they appear as heterogeneous metabasites in normal contact between ultramafic rocks and other more homogeneous and less differentiated metabasic rocks, also affected by catazonal metamorphism. The main difference between the mafic granulites in the two units is the degree of deformation, which is higher in the underlying Cedeira unit. Petrologic and mineralogical data indicate that the high-pressure (HP) granulites (Gt-Cpx±Amp-Pl±Qtz±Scp-Rt±Ilm-Czo) are already retrograde (M2 Stage), post-dating an earlier eclogite facies metamorphism (M1 Stage) characterised by the mineral associations: Gt-Cpx±Amp±Ky±Qtz-Rt and Gt-Cpx±Amp±Qtz±Zo-Rt. The main structure related to the exhumation processes is the development of a general mylonitic foliation that, although initiated in granulite facies conditions, was mainly equilibrated in amphibolite facies (M3 Stage). This foliation was affected by isoclinal folds, which led to the formation of the Variscan thrusts responsible for the present stacking position. Thrust conditions were transitional between amphibolite and greenschist facies (M4 Stage). Thermobarometric data point to different P– T exhumation paths in the two units. Estimated P– T conditions were higher in La Capelada unit during M1 ( P≥13 kbar; 860°C) and M2 (15 kbar; 800°C) than in the Cedeira unit (M1: P≥11 kbar, 770°C; M2: 12 kbar; 750°C). Temperatures for the M3 stage were comparable (720°C) in both units but rocks from the Cedeira unit show a much bigger drop in pressure. This resulted in an isothermal decompression type path for the Cedeira unit, while both P and T decreased more steadily in La Capelada rocks. These were always located at deeper level than the Cedeira rocks before the Variscan stacking. The difference in the two paths is related to different exhumation rates; higher in rocks from the Cedeira unit than in those from La Capelada. Exhumation processes coeval with underthrusting, and a different location of the rocks with respect to the main shear zone responsible for the exhumation would account for the distinct paths. 相似文献
6.
The 558-m-deep ZK703 drillhole located near Donghai in the southern part of the Sulu ultrahigh-pressure metamorphic belt, eastern China, penetrates alternating layers of eclogites, gneisses, jadeite quartzites, garnet peridotites, phengite–quartz schists, and kyanite quartzites. The preservation of ultrahigh-pressure metamorphic minerals and their relics, together with the contact relationship and protolith types of the various rocks indicates that these are metamorphic supracrustal rocks and mafic-ultramafic rock assemblages that have experienced in-situ ultrahigh-pressure metamorphism. The eclogites can be divided into five types based on accessory minerals: rutile eclogite, phengite eclogite, kyanite–phengite eclogite, quartz eclogite, and common eclogite with rare minor minerals. Rutile eclogite forms a thick layer in the drillhole that contains sufficient rutile for potential mining. Two retrograde assemblages are observed in the eclogites: the first stage is characterized by the formation of sodic plagioclase+amphibole symplectite or symplectitic coronas after omphacite and garnet, plagioclase+biotite after garnet or phengite, and plagioclase coronas after kyanite; the second stage involved total replacement of omphacite and garnet by amphibole+albite+epidote+quartz. Peak metamorphic P– T conditions of the eclogites were around 32 to 40 kbar and 720°C to 880°C. The retrograde P– T path of the eclogites is characterized by rapidly decreasing pressure with slightly decreasing temperature. Micro-textures and compositional variations in symplectitic minerals suggest that the decompression breakdown of ultrahigh-pressure minerals is a domainal equilibrium reaction or disequilibrium reaction. The composition of the original minerals and the diffusion rate of elements involved in these reactions controlled the symplectitic mineral compositions. 相似文献
7.
The Thor-Odin dome region of the Shuswap metamorphic core complex, British Columbia, contains migmatitic rocks exhumed from the deep mid-crust of the Cordilleran orogen. Extensive partial melting occurred during decompression of the structurally deepest rocks, and this decompression path is particularly well recorded by mafic boudins of silica-undersaturated, aluminous rocks. These mafic boudins contain the high-temperature assemblages gedrite+cordierite+spinel+corundum+kyanite/sillimanite±sapphirine±högbomite and gedrite+cordierite+spinel+corundum+kyanite/sillimanite+garnet±staurolite (relict)±anorthite. The boudins are interlayered with migmatitic metapelitic gneiss and orthogneiss in this region. The mineral assemblages and reaction textures in these rocks record decompression from the kyanite zone (P>8–10 kbar) to the sillimanite–cordierite zone (P<5 kbar) at T750 °C, with maximum recorded temperatures of 800 °C. Evidence for high-temperature decompression includes the partial replacement of garnet by cordierite, the partial to complete replacement of kyanite by corundum+cordierite+spinel (hercynite)±sapphirine±högbomite symplectite, and the replacement of some kyanite grains by sillimanite. Kyanite partially replaced by sillimanite, and sillimanite with coronas of cordierite±spinel are also observed in the associated metapelitic rocks. Partial melt from the surrounding migmatitic gneisses has invaded the mafic boudins. Cordierite reaction rims occur where minerals in the boudins interacted with leucocratic melt. When combined with existing structural and geochronologic data from migmatites and leucogranites in the region, these petrologic constraints suggest that high-temperature decompression was coeval with partial melting in the Thor-Odin dome. These data are used to evaluate the relationship between partial melting of the mid-crust and localized exhumation of deep, hot rocks by extensional and diapiric processes. 相似文献
8.
The retrograde chemical zonal structure of amphibole in hematite-bearing basic and quartz schists from the higher grade zone in the Saruta-gawa area of the Sanbagawa belt was studied to investigate the relationships between the prograde and retrograde P– T paths of the Sanbagawa metamorphism. This amphibole coexists with chlorite, epidote, muscovite, albite, quartz and hematite, and is composed of Al-rich core and Al-poor mantle. The core is fairly homogeneous and has a barroisitic composition. In the mantle part, [B]Na increases with decreasing [4]Al towards the margins, which have winchite–magnesioriebeckite compositions. The barroisite–winchite–magnesioriebeckite composite crystal is sometimes rimmed by actinolite and/or winchite with low [4]Al and [B]Na. The Al-rich core and Al-poor mantle are regarded as prograde and retrograde products, respectively. The retrograde mantle in the Saruta-gawa area: (1) is systematically richer in [B]Na [0.40–1.73 per formula unit (pfu; for O=23)] than that from the same grade zone in the Asemi-gawa area (0.19–0.78 pfu), about 8 km south of the studied area; (2) tends to be [B]Na-poorer (less than 1.73 pfu) than prograde sodic amphibole (up to 1.93 [B]Na pfu) produced in the peak temperature stage from the lower grade zone in the same and other areas; and (3) extends its compositional range towards higher [B]Na and lower [4]Al than prograde-formed amphibole from the same grade zone in the same area. These zonal characteristics imply that (1) the Saruta-gawa samples experienced retrograde metamorphism under higher P/ T conditions than the Asemi-gawa samples, (2) the retrograde P– T path of the Saruta-gawa area passes on the lower pressure side of the metamorphic field gradient, and (3) the Saruta-gawa samples underwent retrograde metamorphism under higher P/ T conditions than the prograde metamorphism. The higher P/ T conditions of the retrograde metamorphism suggests an increasing d P/d T of the geotherm during exhumation. Retrograde P– T conditions during the formation of magnesioriebeckite can be roughly estimated at 7–8 kbar, 400–450°C based on semi-quantitative phase relations of actinolite–winchite–magnesioriebeckite–barroisite series associated with chlorite, epidote, muscovite, albite, quartz and hematite. 相似文献
9.
In the Pointe Géologie area (66°40 S; 140°00 E; Terre Adélie, East Antarctica), the Paleoproterozoic basement consists in a migmatitic complex of metasedimentary origin. Metasediments underwent a thermal event, leading to the high-grade amphibolite facies assemblages biotite–cordierite–sillimanite and to dehydration melting reactions at 4–6 kbar and 700±50 °C, followed by retrogression in greenschist facies. In most of the archipelago, K-feldspar gneisses (KFG) are characterized by a Sil+Crd+Kfs+Bt assemblage and many K-feldspar-rich leucosomes. Locally, a spectacular rock type occurs as North dipping bands of about 10 m thick and consists in nodular gneisses (NG) that display less abundant, K-feldspar-poor leucosomes. Commonly, the retrograde imprint facies is quite weak in KFG and only expressed by sporadic Bt–Ms±And equilibrium assemblage, whereas it developed more extensively in NG. A pseudosection calculated at constant P=4 kbar shows that the differences between NG and KFG assemblages can be considered to be mainly driven by difference in H2O proportions and much less by differences in FeO/MgO or K2O/MgO ratios. The hydrated assemblage (Bt–Ms nodules) in NG requires at least 10–20% more H2O than the Crd+Kfs+Sil/And assemblage does in KFG. Parageneses and mineral compositions indicate that this difference in H2O occurred early in the history, at least as early as the anatectic stage. Therefore, differences between NG and KFG are related to the variation in partial melting features (water distribution, proportion of melt extraction), which appears to be spatially controlled by cryptic tectonic structures. The particular shape and orientation of NG bands are interpreted as a complex history of melt extraction in the Pointe Géologie area which could involve a two stage melting process. 相似文献
10.
In the present study from the southern margin of the Central Indian Tectonic Zone, it is demonstrated how the metamorphic P– T path of ultrahigh-temperature granulite terranes can be reconstructed using the metamorphic transition in corundum granulites from early biotite melting to later FMAS solid–solid reaction. The extreme metamorphism in these rocks caused two-stage biotite melting, resulting in initial porphyroblastic garnet 1 and later sapphirine–spinel 1 incongruent solid mineral assemblages. During this process, the leucocratic and melanocratic layers in the corundum granulites evolved from an initial silica-oversaturated to a later silica-undersaturated domain. In the melanocratic layer, this allowed localized concentration of sapphirine-spinel 1 and residual sillimanite 1, producing an extremely restitic assemblage, at the culmination of peak metamorphism, BM 1. BM 1 is constrained at 1000 °C at relatively deep crustal levels ( P 9 kbar) from the stability of ferroaugite in a co-metamorphosed Iron Formation granulite. During subsequent metamorphism (BM 2), the reaction path and history in the corundum granulites shifted to the restitic domain allowing reacting sapphirine, spinel 1 and sillimanite to produce coronal garnet 2–corundum assemblage via a FMAS univariant reaction. In the final stages of reaction history, biotite 2–sillimanite 2–spinel 2 assemblage was produced after garnet 2–corundum due to localized melt–crystal interaction. The metamorphic sequence, when interpreted with the help of a newly constructed, qualitative KFMASH petrogenetic grid, reveals successive stages of heating, increasing pressure and cooling around the KFMASH invariant point, [Opx,Crd], which is consistent with a counterclockwise metamorphic P– T path. The near isobaric nature of post-peak cooling (Δ T 250–300 °C) is also evident from multistage pyroxene exsolution and by the appearance of lamellar and coronal garnets in the Iron Formation granulites. This study provides the first tight constraint for ultrahigh- T metamorphism along a counter clockwise P– T trajectory in the Central Indian Tectonic zone, and has important bearing for terrane correlations in this part of East Gondwanaland. In addition, the new KFMASH grid allows evaluation of metamorphic phase relations in ultrahigh- T, corundum-bearing and corundum-absent aluminous granulites. 相似文献
11.
Using relevant geothermobarometric methods, P– T-data were collected for the reconstruction of the metamorphic evolution of 34 eclogite samples taken from small lenses and boudins within the ultrahigh-pressure (UHP) metamorphic coesite-bearing Brossasco-Isasca Unit (BIU) of the Dora-Maira Massif. The mineral phases used (clinopyroxene, garnet, phengite), or growth zones thereof, were identified as being coexistent for different stages of metamorphism on the basis of careful petrographic studies. Of several published geothermobarometers, the garnet–clinopyroxene thermometer of Powell [Powell, R., 1985. Regression diagnostics and robust regression in geothermometer/geobarometer calibration: the garnet–clinopyroxene geothermometer revisited. J. Metamorph. Geol., 3, pp. 231–243.] combined with the garnet–clinopyroxene–phengite barometer after Waters and Martin [Waters, D., Martin, H.N., 1993. The garnet–clinopyroxene–phengite barometer. Terra Abstr., 5, pp. 410–411.] was chosen here, because it provided the most reliable results. Nevertheless, the scatter of P– T-data points for the prograde (stage I), peak metamorphic (stage II), and retrograde (stage III) development of the eclogites is still considerable. Among the many possible reasons for this inconsistency discussed, a partial lack of equilibration of some of the eclogites during their metamorphic history should be taken into account. Despite the data scatter, an average P– T-path could be estimated, which includes the following coordinates: for stage I: 15 kbar/500°C; 25 kbar/570°C; 32 kbar/650°C; for stage II: 36 kbar/720°C; and for stage III: 24 kbar/680°C and 14 kbar/620°C. This is in fair agreement with P– T-paths derived earlier for other rock types of the BIU on the basis of other geothermobarometers. 相似文献
12.
A new occurrence of the rare corundum + quartz assemblage and magnesian staurolite has been found in a gedrite–garnet rock from the Central Zone of the Neoarchean Limpopo Belt in Zimbabwe. Poikiloblastic garnet in the sample contains numerous inclusions of corundum + quartz ± sillimanite, magnesian staurolite + sapphirine ± orthopyroxene, and sapphirine + sillimanite assemblages, as well as monophase inclusions. Corundum, often containing subhedral to rounded quartz, occurs as subhedral to euhedral inclusions in the garnet. Quartz and corundum occur in direct grain contact with no evidence of a reaction texture. The textures and Fe–Mg ratios of staurolite inclusions and the host garnet suggest a prograde dehydration reaction of St → Grt + Crn + Qtz + H 2O to give the corundum + quartz assemblage. Peak conditions of 890–930 °C at 9–10 kbar are obtained from orthopyroxene + sapphirine and garnet + staurolite assemblages. A clockwise P– T path is inferred, with peak conditions being followed by retrograde conditions of 4–6 kbar and 500–570 °C. The presence of unusually magnesian staurolite (Mg / [Fe + Mg] = 0.47–0.53) and corundum + garnet assemblages provides evidence for early high-pressure metamorphism in the Central Zone, possibly close to eclogite facies. The prograde high-pressure event followed by high- to ultrahigh-temperature metamorphism and rapid uplifting of the Limpopo Belt could have occurred as a result of Neoarchean collisional orogeny involving the Zimbabwe and Kaapvaal Cratons. 相似文献
13.
As is typical of ultra-high pressure (UHP) terrains, the regional extent of the UHP terrain in the Dabieshan of central China is highly speculative, since the volume of eclogites and paragneisses preserving unequivocal evidence of coesite and/or diamond stability is very small. By contrast, the common garnet ( XMn=0.18–0.45)–phengite (Si=3.2–3.35)–zoned epidote (Ps 38–97)–biotite–titanite–two feldspars–quartz assemblages in the more extensive orthogneisses have been previously thought to have formed under low P– T conditions of ca. 400±50°C at 4 kbar. However, certain orthogneiss samples preserve garnets with XCa up to 0.50, rutile inclusions within titanite or epidote and relict phengite inclusions within epidote with Si contents p.f.u. of up to 3.49 — overlapping with the highest values (3.49–3.62) recorded for phengites in samples of undoubted UHP schists. These and other mineral composition features (such as A-site deficiencies in the highest Si phengites, Na in garnets linked to Y+Yb substitution and Al F Ti −1 O −1 substitution in titanites) are taken to be pointers towards the orthogneisses having experienced a similar metamorphic evolution to the associated UHP schists and eclogites. Re-evaluated garnet–phengite and garnet–biotite Fe/Mg exchange thermometry and calculated 5 rutile+3 grossular+2SiO 2+H 2O=5 titanite+2 zoisite equilibria indicate that the orthogneisses may indeed have followed a common subduction-related clockwise P– T path with the UHP paragneisses and eclogites through conditions of Pmax at ca. 690°C–715°C and 36 kbar to Tmax at ca. 710°C–755°C and 18 kbar, prior to extensive re-crystallisation and re-equilibration of these ductile orthogneisses at ca. 400°C–450°C and 6 kbar. The consequential conclusion, that it is no longer necessary to resort to models of tectonic juxtapositioning to explain the spatial association of these Dabieshan orthogneisses with undoubted UHP lithologies, has far-reaching implications for the interpretation of controversial gneiss–eclogite relationships in other UHP metamorphic terrains. 相似文献
14.
The evolution of the pre-Alpine Corio and Monastero metagabbros points to strong chemical and mineralogical similarities with that of other Permian gabbro bodies of the Alps, which are concentrated in the Southalpine and Austroalpine domains. The structural and metamorphic pre-Alpine evolution of these gabbros records a re-equilibration following the emplacement in the deep crust ( P=0.6–0.9 GPa and T=850±70 °C), exhumation through amphibolite facies conditions ( P=0.5–0.35 GPa and T=570–670 °C), followed by a greenschist facies imprint (0.25≤ P≤0.35 GPa and T<550 °C). This retrograde P– T evolution suggests that the exhumation occurred in a high thermal gradient regime, such as that induced by upwelling of an asthenospheric plume during continental rifting. This would be consistent with the crustal thinning known to have occurred in both the Southalpine and Austroalpine domains during Permian times. The gabbros and their country acid granulites are spatially associated with the serpentinised subcontinental mantle of the Lanzo Massif. This lithologic association and the metamorphic evolution is similar to that of the Fedoz gabbro (Austroalpine Domain of the Central Alps) and completely different from that observed in passive margins, where no remnants of the lower crust occur and the upper granitic crust directly overlies the serpentinized lherzolites. The location of Permian gabbro bodies in the Austroalpine and Southalpine domains and their absence in the Helvetic domain is evidence for asymmetric rifting. 相似文献
15.
Petrological analysis, zircon trace element analysis and SHRIMP zircon U–Pb dating of retrogressed eclogite and garnet granulite from Bibong, Hongseong area, SW Gyeonggi Massif, South Korea provide compelling evidence for Triassic (231.4 ± 3.3 Ma) high-pressure (HP) eclogite facies (M1) metamorphisms at a peak pressure–temperature ( P– T) of ca. 16.5–20.0 kb and 775–850 °C. This was followed by isothermal decompression (ITD), with a sharp decrease in pressure from 20 to 10 kb and a slight temperature rise from eclogite facies (M1) to granulite facies (M2), followed by uplift and cooling. Granitic orthogneiss surrounding the Baekdong garnet granulite and the ophiolite-related ultramafic lenticular body near Bibong records evidence for a later Silurian (418 ± 8 Ma) intermediate high-pressure (IHP) granulite facies metamorphism and a prograde P– T path with peak P– T conditions of ca. 13.5 kb and 800 °C. K–Ar ages of biotite from garnet granulites, amphibolites, and granitic orthogneisses in and around the Bibong metabasite lenticular body are 208–219 Ma, recording cooling to about 310 °C after the Early Triassic metamorphic peak. Neoproterozoic zircon cores in the retrogressed eclogite and granitic orthogneiss provide evidence that the protoliths of these rocks were 800 and 900 Ma old, respectively, similar to the ages of tectonic episodes in the Central Orogenic Belt of China. This, and the evidence for Triassic HP/UHP metamorphism in both China and Korea, is consistent with a regional tectonic link within Northeast Asia from the time of Rodinia amalgamation to Triassic continent–continent collision between the North and South China Blocks, and with an eastward extension of the Dabie–Sulu suture zone into the Hongseong area of South Korea. 相似文献
16.
Metagranites in the NKFMASH system require external hydration during prograde high-pressure metamorphism in order to equilibrate to ambient HP conditions by producing more siliceous muscovite. Any lack of external fluid or the disappearance of biotite stops re-equilibration and thus prevents recording of high-pressure conditions. The same hydration reactions cause dehydration during exhumation. Orthogneiss from shear zones or adjacent to metapelites and metabasites will take up external fluid during subduction and record the highest P– T conditions, but will also be the first to dehydrate upon exhumation, now hydrating other lithologies and probably refuelling shearzones. The (de)hydration behavior of Ca-bearing metagranitoids is similar to that in the Ca-free system. However, the anorthite component of plagioclase decomposes with increasing pressure to form either (clino)zoisite or a grossular-rich garnet. Both reactions are fluid-consuming. If H2O is supplied from an external source, the garnet-bearing assemblage can record P–T conditions up to very high pressures, but dehydrates again during heating and/or decompression to form a more Fe-rich garnet and Al-rich mica(s). The garnet compositions observed in natural HP-metagranites are mostly too Fe-rich to be formed in the presence of an H2O-rich fluid. N(C)KFMASH metapelites generally have a more complex mineralogy and succession of mineral assemblages along a P–T path. The H2O contained in hydrous silicates like chlorite and chloritoid is only partly released, but partly transferred to other minerals like paragonite, glaucophane or phengite during subduction and further dehydration during exhumation is common. The mineral assemblage preserved by the rock may then record P–T conditions way below those of the actual pressure and temperature peak of the path. Contouring of the P–T pseudosection of a specific metapelite composition with mode isopleths for H2O shows which P–T conditions along a given path are the ones most likely recorded by the rock. 相似文献
17.
Minor granulites (believed to be pre-Triassic), surrounded by abundant amphibolite-facies orthogneiss, occur in the same region as the well-documented Triassic high- and ultrahigh-pressure (HP and UHP) eclogites in the Dabie–Sulu terranes, eastern China. Moreover, some eclogites and garnet clinopyroxenites have been metamorphosed at granulite- to amphibolite-facies conditions during exhumation. Granulitized HP eclogites/garnet clinopyroxenites at Huangweihe and Baizhangyan record estimated eclogite-facies metamorphic conditions of 775–805 °C and ≥15 kbar, followed by granulite- to amphibolite-facies overprint of ca. 750–800 °C and 6–11 kbar. The presence of (Na, Ca, Ba, Sr)-feldspars in garnet and omphacite corresponds to amphibolite-facies conditions. Metamorphic mineral assemblages and P– T estimates for felsic granulite at Huangtuling and mafic granulite at Huilanshan indicate peak conditions of 850 °C and 12 kbar for the granulite-facies metamorphism and 700 °C and 6 kbar for amphibolite-facies retrograde metamorphism. Cordierite–orthopyroxene and ferropargasite–plagioclase coronas and symplectites around garnet record a strong, rapid decompression, possibly contemporaneous with the uplift of neighbouring HP/UHP eclogites. Carbonic fluid (CO2-rich) inclusions are predominant in both HP granulites and granulitized HP/UHP eclogites/garnet clinopyroxenites. They have low densities, having been reset during decompression. Minor amounts of CH4 and/or N2 as well as carbonate are present. In the granulitized HP/UHP eclogites/garnet clinopyroxenites, early fluids are high-salinity brines with minor N2, whereas low-salinity fluids formed during retrogression. Syn-granulite-facies carbonic fluid inclusions occur either in quartz rods in clinopyroxene (granulitized HP garnet clinopyxeronite) or in quartz blebs in garnet and quartz matrices (UHP eclogite). For HP granulites, a limited number of primary CO2 and mixed H2O–CO2(liquid) inclusions have also been observed in undeformed quartz inclusions within garnet, orthopyroxene, and plagioclase which contain abundant, low-density CO2±carbonate inclusions. It is suggested that the primary fluid in the HP granulites was high-density CO2, mixed with a significant quantity of water. The water was consumed by retrograde metamorphic mineral reactions and may also have been responsible for metasomatic reactions (“giant myrmekites”) occurring at quartz–feldspar boundaries. Compared with the UHP eclogites in this region, the granulites were exhumed in the presence of massive, externally derived carbonic fluids and subsequently limited low-salinity aqueous fluids, probably derived from the surrounding gneisses. 相似文献
18.
Petrologic data on the paragenesis of (I) kyanite-zoisite marbles and (II) garnet-chloritoid quartz-mica schists are presented with the goal of providing constraints on the pressure-temperature evolution of the Eclogite Zone, Tauern Window, Austria. The peak metamorphic assemblages in the two rock types are: (I) kyanite + zoisite + dolomite + quartz; zoisite + muscovite + dolomite + calcite + quartz; and (II) garnet + chloritoid + kyanite + muscovite + quartz + epidote ± dolomite ± Zn-staurolite. The estimated peak metamorphic conditions are 19 ± 2 kbar, 590 ± 20°C. Secondary alteration of the kyanite-zoisite marbles was accomplished in two stages. The early stage resulted in the production of margarite, paragonite, secondary muscovite and chlorite and the later stage resulted in the formation of sudoite (a di/trioctahedral Mg---Al layer silicate) and kaolinite. The early alteration is bracketed at conditions between 3 and 10 kbar, 450–550°C and the later alteration between 200 and 350°C, P 3 kbar. The P-T path is characterized by maximum burial to approximately 19 kbar (60–70 km) (at≈590°C), followed by nearly isothermal decompression to approximately 10 kbar (30 km), and then more gradual decompression with cooling to approximately 3 kbar (10 km). Alteration was apparently accomplished by the influx of H2O-rich fluids, with the composition of the fluid locally buffered by the mineral assemblage. 相似文献
19.
The Lindås Nappe, Caledonides W-Norway was affected by two major tectonometamorphic events. A Precambrian granulite facies event at T=800–900°C, P<10 kbar was followed by localized Caledonian eclogite facies ( T=650–700°C and P>15 kbar) and localized amphibolite facies reworking. During the granulite–eclogite facies transition, anorthositic rocks were converted from garnet granulites to kyanite eclogites, while phlogopite-bearing spinel lherzolite reacted to garnet lherzolite. The eclogite and amphibolite facies reequilibration took place along shear zones and fluid pathways. In the unhydrated and undeformed parts, the minerals preserved their granulite facies composition with constant Fe/Mg ratios from core to rim, suggesting diffusional reequilibration. Rb/Sr age dating was carried out on relict granulite facies minerals from three lenses of ultramafites (Alvfjellet, Hundskjeften and Kvamsfjellet). Phlogopite from phlogopite lherzolite at Alvfjellet give 857±9 Ma, while clinopyroxene, amphibole, phlogopite and whole rock from a lherzolite at Hundskjeften yield an age of 842±12 Ma (MSWD=1.9). Clinopyroxene, feldspar, orthopyroxene phlogopite and whole rock from websterite, Kvamsfjellet, yield an age of 835±7 Ma (MSWD<1), while clinopyroxene, phlogopite and whole rock from a lherzolite from the same lens gives a result of 882±9 Ma. These results are interpreted as minimum ages for the granulite facies event and only slightly younger than, or overlap with previous U–Pb zircon ages (929±1 Ma) and Sm–Nd garnet–pyroxene ages (890–923 Ma) interpreted to date the end of the granulite facies event. By contrast, ages obtained for the eclogite and amphibolite facies range from 460 (U–Pb, sphene), 440 (Ar–Ar), 419 (U–Pb, zircon) to 410 Ma (Rb/Sr mineral ages). These results demonstrate that the reopening temperature for the Rb/Sr system in phlogopite–biotite under dry and static high-pressure conditions is, in the given mineral assemblages, at least 650°C, considerably higher than the 300–400°C assumed as the closure temperature of this system. We ascribe this elevated reopening temperature to fluid absent conditions that prevented element transport and rehomogenization. 相似文献
20.
In the present study, we describe and discuss the geology of aluminous–magnesian granulites and associated garnet-bearing charnockitic granulite from the Brejões Dome area, located in the Jequié Block, part of the São Francisco Craton in Bahia, Brazil. Investigation of metamorphic mineral assemblages allows the evaluation of P– T conditions for the formation of these rocks, and therefore to obtain constraints for the better understanding of the geological evolution of the area. We conclude that the rocks from the Brejões Dome area were formed under granulite facies conditions of low to intermediate pressure (5–8 kbar). Temperatures determined in samples of aluminous–magnesian granulites collected away from the dome are in the order of 850 °C, similar to those determined elsewhere in the southern part of the Itabuna–Salvador–Curaçá Orogen. However, samples of the same rock type collected close to the Brejões Dome are hercynite + quartz-bearing and record higher temperatures of about 900–1000 °C. It is suggested that the intrusion of the Brejões charnockite diapir was responsible for a local increase in temperature above the peak temperature of regional granulite metamorphism. 相似文献
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