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1.
Clay-mineral, heavy-mineral, and elemental distributions in sediments from the Arctic Ocean and the adjacent Laptev and Kara seas can be attributed to the geology of the hinterland and the transport of terrigenous material by rivers onto the shelves. Kara Sea sediments are characterized by increased contents of smectite and elevated Ni/Al-, Ti/Al-, and Cr/Al ratios. In the western Laptev Sea sediments are enriched in smectite and clinopyroxene and increased in Ti/Al-, Cr/Al-, and Ca/Al ratios. The composition of the sediments reflects suspended matter input from the large trap basalt of the Putoran Mountains. The eastern Laptev Sea sediments display increased illite and amphibole contents as well as a chemical composition similar to average shale. This composition is due to the discharge from the Lena and Yana rivers, which drain a large catchment area consisting of sedimentary Mesozoic and Paleozoic rocks. Material from the eastern Laptev Sea is transported by ocean currents and sediment-laden sea ice along the Transpolar Drift into the central Arctic Ocean. This is indicated by similar values of Ti/Al-, Cr/Al-, Rb/Al-, and K/Al ratios as well as increased concentrations of amphibole and illite, determined in sediments from the Lomonosov Ridge. A minor input from the Beaufort Sea into the central Arctic Ocean is suggested from increased Ca/Al ratios and increased contents of opaque minerals.  相似文献   

2.
The REE distribution was studied in the bottom sediments of the East Arctic shelf of Russia. It is established that sediments of the Laptev and western East Siberian seas are significantly enriched in REEs, the contents of which are much higher than those of other near-continental basins. The main REE sources are runoff of the Lena River, the basin of which comprises ancient crystalline shields and magmatic rocks enriched in LREEs with significant contribution from the coastal erosion of the ice complex from the Laptev Sea and western East Siberian Sea. The terrigenous flux with a specific REE composition is supplied to the Chukchi Sea through the Bering Strait.  相似文献   

3.
The aim of this study was to identify pathways and processes of modern sediment transport from the Siberian hinterland to the Laptev Sea and further to the Arctic Ocean. Clay mineral analyses were performed on riverine suspended particulate material (SPM), surface sediments of the Laptev Sea shelf, and sea-ice sediments (SIS). Material collected during seven expeditions was included in this study. Clay mineral assemblages are used to decipher the distribution of riverine sediments on the shallow Laptev Sea shelf, the entrainment of fine particles into newly forming ice, and the transport of SIS from the Laptev Sea towards the ablation areas. A cluster analysis of our data set shows that the clay mineral assemblages of Laptev Sea shelf sediments and SIS are controlled mainly by the input of riverine SPM supplied by the Khatanga, Lena, and Yana Rivers. Whereas the western shelf clay-mineral province is characterized by enhanced smectite concentrations supplied by the Khatanga River, the eastern Laptev Sea is dominated by illite discharged through the Lena and Yana Rivers. The SIS smectite concentration serves as an indicator for sediment source areas on the circum-Arctic shelves. Subsequently, the Transpolar Drift can be distinguished into a Siberian Branch fed from the eastern Kara Sea and the western Laptev Sea, and a Polar Branch originating from the eastern Laptev Sea.  相似文献   

4.
Concentration, distribution, and sources of 16 polycyclic aromatic hydrocarbons (PAHs) were investigated in surface sediments of Laizhou Bay, China. Total PAH concentrations ranged from 97.2 to 204.8 ng/g, with a mean of 148.4 ng/g. High concentrations of PAHs were found in the fine-grained sediments on both sides of the Yellow River estuary (YRE). In contrast, low levels of PAHs were observed in relatively coarse grain sediments, suggesting hydrodynamics influence the accumulation of sedimentary PAHs. The YRE and its adjacent area is the main sink for Yellow River-derived PAHs. Both PAH isomer ratios and principal component analysis (PCA) with multivariate linear regression (MLR) were applied to apportion sources of PAHs. Results indicated that both pyrogenic and petrogenic PAH sources were important. Further PCA/MLR analysis showed that the contributions of coal combustion, petroleum combustion and a combined source of spilled oil and biomass burning were 41, 15 and 44%, respectively. From an ecotoxicological viewpoint, the studied area appears to have low levels of PAH pollution.  相似文献   

5.
To determine the degree of hydrocarbon contamination and the contribution of local petroleum industries to contaminant loadings in sediments from the Beiluohe River, China, 12 surface sediment samples were collected for geochemical analysis in 2005. Sediment samples were extracted by organic solvents, separated by silica gel column chromatography and the profiles of n-alkanes, biomarkers and polycyclic aromatic hydrocarbons (PAHs) in sediments were analyzed by gas chromatography with flame ionization detector and gas chromatography/mass spectroscopy. Concentrations of total hydrocarbons in the sediments varied from 12.1 to 3,761.5 μg g−1 dry wt, indicating that most sediments in Beiluohe River was only slightly to moderately contaminated by hydrocarbons. Concentrations of PAHs for six samples (sum of 16 isomers) varied from 17.7 to 407.7 ng g−1 dry wt and at present low levels of PAHs did not cause adverse biological effects in Beiluohe River sedimentary environment. PAH compositions, n-alkanes and biomarker profiles all suggested that there were different sources of contaminations in studied areas. n-Alkanes reflect two distinct sources: a fossil n-alkane series from crude oil at sites S40, S43, S87 and plantwax n-alkanes at sites S39 and S45. Judged by their PAH ratios, the sediments at site S15 were pyrolytic, sediments at S17 and S43 were petrogenic, and sediments at S39, S40 and S64 had a mixture source of pyrolytic and petrogenic.  相似文献   

6.
Concentrations, spatial distribution and sources of 16 polycyclic aromatic hydrocarbons (PAHs) listed by the United States Environmental Protection Agency as priority pollutants were investigated in surface sediments of Bohai Bay, North China. Total concentrations of PAHs were in the range of 140.6–300.7 ng/g (dry wt), with an average of 188.0 ng/g. The three predominant PAHs were phenanthrene, acenaphthene and naphthalene. Sedimentary PAH concentrations of the north and central Bohai Bay were higher than those of the southern side of this bay. PAHs source analysis suggested that PAHs in most of the sediments were mainly from grass, wood and coal incomplete combustion. At other stations near the estuaries (Luanhe River Estuary and Chaohe River Estuary) or the oil drilling platform, both petrogenic and pyrogenic inputs were significant. The pyrogenic PAHs close to the oil drilling platform were mainly from petroleum combustion.  相似文献   

7.
The distribution and genesis of polycyclic aromatic hydrocarbons (PAHs) were studied in a 40-m core from a lagoon of the Laptev Sea that appeared during the Holocene resulting from the flooding of seawater into a freshwater lake in the area of the Buor-Khaya Gulf. The bulk of the core is constituted of permafrost rocks, thawed partially in their upper layers and covered with recent sediments (mainly by the products of intense thermoabrasion). The ratio of petrogenic and pyrogenic PAHs was evaluated.  相似文献   

8.
Clay-mineral distributions in the Arctic Ocean and the adjacent Eurasian shelf areas are discussed to identify source areas and transport pathways of terrigenous material in the Arctic Ocean. The main clay minerals in Eurasian Arctic Ocean sediments are illite and chlorite. Smectite and kaolinite occur in minor amounts in these sediments, but show strong variations in the shelf areas. These two minerals are therefore reliable in reconstructions of source areas of sediments from the Eurasian Arctic. The Kara Sea and the western part of the Laptev Sea are enriched in smectite, with highest values of up to 70% in the deltas of the Ob and Yenisey rivers. Illite is the dominant clay mineral in all the investigated sediments except for parts of the Kara Sea. The highest concentrations with more than 70% illite occur in the East Siberian Sea and around Svalbard. Chlorite represents the clay mineral with lowest concentration changes in the Eastern Arctic, ranging between 10 and 25%. The main source areas for kaolinite in the Eurasian Arctic are Mesozoic sedimentary rocks on Franz-Josef Land islands. Based on clay-mineral data, transport of the clay fraction via sea ice is of minor importance for the modern sedimentary budget in the Arctic basins.  相似文献   

9.
Sediment samples collected from the Core Area, Experimental Area and Buffer Area of Yellow River Delta National Nature Reserve (YRDNNR), China, were analyzed by GC-MS in order to determine the degree of hydrocarbon contamination, and identify the sources of aliphatic hydrocarbons and PAHs. The total petroleum hydrocarbon contents of sediments were relatively low or moderate compared to world-wide locations reported to be chronically contaminated by oil. On the whole, the degree of petroleum contamination in the Core Area and Buffer Area in YRDNNR is weaker than that of the Experimental Area. The potential ecosystem risk assessment indicated that PAHs will not cause immediate adverse biological effects in the YRDNNR. Besides oil-related hydrocarbon inputs in this region, aliphatic hydrocarbon analysis showed the presence of hydrocarbons of terrestrial origin at some sampling sites, characterized by high CPI values. Based on PAH ratios and principal component analysis, pyrolytic input may be a major source of PAHs in YRDNNR sediment, while petrogenic inputs were more apparent at some sites in the Experimental Area due to oil exploration in the Shengli Oilfield.  相似文献   

10.
Heavy mineral studies of East Siberian river sediments, Laptev Sea surface sediments, and a sediment core of the western Laptev Sea were carried out in order to reconstruct the pathways of modern and ancient sediment transport from the Siberian hinterland to the Laptev Sea. The modern heavy mineral distribution of Laptev Sea surface sediments reflects mainly the riverine input. While the eastern and central part of the Laptev Sea is dominated by amphibole, which is supplied by the Lena River, the western part is dominated by pyroxene imported from the Siberian Trap basalts by the Khatanga River. The distribution of garnet and opaque minerals is additionally influenced by hydrodynamic processes. As a consequence of their high density, these minerals are predominantly deposited close to the river mouths. Heavy mineral and sedimentological studies of a sediment core of the western Laptev Sea were applied to reconstruct the postglacial history of the shelf area during the last 11 ka. In the lowermost interval of the core (> c. 10 ka), high accumulation rates and a heavy mineral composition similar to that of the modern Khatanga river indicate fluvial conditions. Additionally, the high mica content in this interval may indicate meltwater inflow from the Byrranga mountains. Strong variations in accumulation rates, grain-size distribution, and heavy mineral composition are observed in the time interval between c. 10 and 6 ka, which represents the main transgression of the Laptev Sea shelf. During the uppermost interval (<6 ka), rather stable conditions similar to the modem situation prevailed.  相似文献   

11.
Surface sediments from the Outer Continental Shelf of Alaska were analyzed for hydrocarbons as part of an environmental survey sponsored by NOAA/BLM. Sediments were collected from the proposed oil lease areas of Beaufort Sea, southeastern Bering Sea, Norton Sound, Navarin Basin, Gulf of Alaska, Kodiak Shelf and lower Cook Inlet. Data on normal and branched alkanes and di- and triterpenoids from capillary gas chromatography (GC) and gas chromatography-mass spectrometry (GC/ MS) indicate that the area displays little evidence of petroleum hydrocarbons (i.e., seeps) except at a few isolated stations. Beaufort Sea sediments have the highest hydrocarbon budget, whereas Kodiak Shelf sediments have the lowest. The molecular markers of the hydrocarbons are of a mixed marine autochthonous and terrestrial allochthonous origin. Norton Sound and Cook Inlet sediments contain the highest levels of terrigenous lipids and Kodiak Shelf the lowest. The abundance of alkenes implies that relatively low oxidizing conditions exist in some of the depositional areas studied, suggesting that extraneous petroleum hydrocarbons introduced into these sediments would be expected to have a relatively long residence time. The distribution of polynuclear aromatic hydrocarbons (PAH) is complex and shows a pyrolytic origin. The data on perylene strongly favor the hypothesis that it is “performed” from terrigenous precursors and transported into the marine environment with no apparent in situ generation. Polynuclear aromatic hydrocarbons of diagenetic origin are probably dominant in Gulf of Alaska and Kodiak Shelf sediments.Two stations, north of Kalgin Island, in lower Cook Inlet and one in southeastern Bering Sea show typical weathered petroleum distribution of n-alkanes and triterpenoids. Probable pathways of transport and fate of petroleum hydrocarbons in case of an oil spill are also briefly discussed.  相似文献   

12.
The International Ocean Discovery Program (IODP) Expedition 367/368 reported massive Upper Miocene deep-sea turbidite in the northern South China Sea basin. The Upper Miocene turbidite sand-bodies at Site U1500 were examined with detrital zircon U-Pb dating to conduct the source-to-sink analysis. This study shows that the U-Pb age spectrums of Site U1500 sample are similar to those detrital zircons from the Miocene Qiongdongnan Basin and the Pearl River Mouth Basin. Multidimensional scaling (MDS) plot also shows that the turbidite sand-bodies at Site U1500 are closely related to the sediments in the Pearl River Mouth Basin and Qiongdongnan Basin. It is likely that the thick deep-sea turbidite succession in the deep-water basin of northern South China Sea was formed by a mixed provenance pattern during the late Miocene. On the one hand, terrigenous sediments from the west of the South China Sea were transported along the Central Canyon to the eastern South China Sea deep-sea basin in the form of turbidity current. On the other hand, terrigenous sediments were also transported from the Pearl River through the slope canyon system to the northern South China Sea in the form of gravity flow . Those mixed sediments from two different source areas have collectively deposited at the deep-sea basin and thus, give rise to turbidite sequence of hundred meters. Provenance analysis of the thick turbidites sand-bodies in the deep-sea basin is of great significance to the profound understanding of the tectonic evolution, filling processes, provenance evolution, and the palaeogeographic characteristics of the Cenozoic basins of the South China Sea.  相似文献   

13.
IODP367/368航次在南海北部深海盆地多个站位发现上中新统厚达数百米的大规模深海浊积岩。采用碎屑锆石U-Pb年龄谱系分析方法对U1500站上中新统浊积砂体进行源汇对比分析。研究结果表明U1500站上中新统浊积岩碎屑锆石年龄谱系与其西侧琼东南盆地和北侧珠江口盆地中新世沉积物特征类似。多维排列分析(MDS)结果也显示,该站位样品与珠江口盆地、琼东南盆地沉积物关系密切,表明南海北部深海盆地内厚达数百米的上中新统浊积砂体为南海北部物源和南海西部物源混合堆积形成。南海西部陆源输入物质以浊流搬运的方式,沿中央峡谷从西到东搬运至南海东部深海盆地;南海北部珠江物源以重力流的形式,经南海北部陆坡峡谷搬运至深海盆地中,两种来源的沉积物在深海盆地发生混合沉积,形成U1500站厚达数百米的浊积砂体。南海北部深海盆地厚层浊积砂体物质来源的准确识别,对深刻理解南海新生代盆地的构造演化、沉积物充填过程、物源演变以及古地理特征均具有重要意义。  相似文献   

14.
Concentrations and sources of polycyclic aromatic hydrocarbons (PAHs) were investigated in surface sediments of the Yellow River Estuary (YRE). The isobath-parallel tidal and residual currents play important roles in the variation of PAH distribution, such that the contamination level of PAHs in fine-grained sediments is significantly higher than in the relatively coarse grain size sediments. Both diagnostic ratios and principal component analysis (PCA) with multivariate linear regression (MLR) were used to apportion sources of PAHs. The results revealed that pyrogenic sources are important sources of PAHs. Further analysis indicated that the contributions of coal combustion, traffic-related pollution and mixed sources (spills of oil products and vegetation combustion) were 35, 29 and 36 %, respectively, using PCA/MLR. Pyrogenic sources (coal combustion and traffic-related pollution) contribute 64 % of anthropogenic PAHs in sediments, which indicates that energy consumption could be a predominant factor in PAH pollution of YRE. Acenaphthylene and acenaphthene are the two main species of PAHs with more ecotoxicological concern in YRE.  相似文献   

15.
Coastal erosion vs riverine sediment discharge in the Arctic Shelf seas   总被引：8，自引：0，他引：8  
This article presents a comparison of sediment input by rivers and by coastal erosion into both the Laptev Sea and the Canadian Beaufort Sea (CBS). New data on coastal erosion in the Laptev Sea, which are based on field measurements and remote sensing information, and existing data on coastal erosion in the CBS as well as riverine sediment discharge into both the Laptev Sea and the CBS are included. Strong regional differences in the percentages of coastal erosion and riverine sediment supply are observed. The CBS is dominated by the riverine sediment discharge (64.45᎒6 t a-1) mainly of the Mackenzie River, which is the largest single source of sediments in the Arctic. Riverine sediment discharge into the Laptev Sea amounts to 24.10᎒6 t a-1, more than 70% of which are related to the Lena River. In comparison with the CBS, the Laptev Sea coast on average delivers approximately twice as much sediment mass per kilometer, a result of higher erosion rates due to higher cliffs and seasonal ice melting. In the Laptev Sea sediment input by coastal erosion (58.4᎒6 t a-1) is therefore more important than in the CBS and the ratio between riverine and coastal sediment input amounts to 0.4. Coastal erosion supplying 5.6᎒6 t a-1 is less significant for the sediment budget of the CBS where riverine sediment discharge exceeds coastal sediment input by a factor of ca. 10.  相似文献   

16.
Heavy contaminant load released into the Northern Dvina River during flooding increased the concentrations of aliphatic (AHC) and polcyclic aromatic (PAH) hydrocarbons in water and bottom sediments. The composition of hydrocarbons was different from that of the summer low flow season. The concentrations of dissolved and particulate AHC ranged from 12 to 106 and from 192 to 599 μg/l, respectively, and bottom sediments contained from 26.2 to 329 μg/g AHC and 4 to 1785 ng/g PAH. As the transformation of AHC occurred at low spring temperatures, the alkane composition was shown to be dominated by terrigenous compounds, whereas more stable PAH showed elevated contents of petrogenic and pyrogenic compounds. It was also shown that the Northern Dvina-Dvina Bay geochemical barrier prevents contaminant input into the White Sea, i.e., acts as a marginal filter.  相似文献   

17.
《Applied Geochemistry》2001,16(11-12):1429-1445
Polycyclic aromatic hydrocarbons (PAHs) were measured in surface sediments and dated core sediments from the Pearl river and estuary, China, to investigate the spatial and temporal variability of anthropogenic pollutants. The sediments from the sampling stations at the Guangzhou channel have the highest concentrations of PAHs, owing to contributions from the large amount of urban/industrial discharges from the city of Guangzhou. The significant decrease of PAHs concentrations in sediments from the Shiziyang channel is mainly attributed to the increasing degradation and desorption of low molecular weight PAHs and alkyl PAHs, and the dilution by less contaminated water and particles from the East river. The PAH contaminants were concentrated on the western side in the Lingding bay of the Pearl river estuary because of the hydrodynamic and sedimentation conditions. Based on the characteristics of the parent compound distributions (PCDs) and the alkyl homologue distributions (AHDs) of PAHs, the potential source of PAHs in sediments from each sampling station was identified. Results indicated that the pyrogenic (combustion) source, characterized by the abundance of parent PAHs, were predominant in the heavily contaminated station (ZB01) near the aging industrial area, and the petrogenic (petroleum- derived) PAHs were more abundant in the stations (ZB02, ZB03) adjacent to the petrochemical plant and shipping harbor. Sediments from Lingding bay show variable distributions of PAH composition and variety in the proportion of combustion and petrogenic sources for the PAHs in different stations. Perylene, a naturally derived PAH, was found to be highly abundant in less contaminated stations. Analysis of the dated sediments (210Pb) indicates that higher PAH concentrations occurred in the sediments deposited after 1980, and higher fluxes of PAHs discharged to the Pearl river are found after 1990.  相似文献   

18.
This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R 2 = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R 2 = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities.  相似文献   

19.
板块俯冲碰撞拼合带是盆山相互作用最为强烈的地区,发育有弧前、弧间及弧后多种类型的盆地,沉积物的剥蚀搬运作用极为活跃。证据显示,沉积物搬运充填过程在构造—古地理控制型盆地中具有一定的演变规律,伴随盆地演化,沉积物轴向搬运与横向搬运呈此消彼长的互动关系。南海南北两侧均发育了大型板块俯冲拼合带及相关的沉积盆地,在盆地发育早期沉积物沿盆地长轴方向分别形成昆莺琼古河和巽他古河,以轴向搬运的方式分别把越南中部及马来半岛沉积物由西向东输送到南海,形成大型三角洲及前三角洲深水扇沉积,河流发育位置均在板块拼合转折地段。在盆地发育的成熟阶段,沉积物以横向搬运的方式进入盆地,与轴向搬运沉积物形成混合堆积。轴向搬运是洋陆碰撞拼合盆地中一种重要的沉积物搬运途径,主要受盆地形成时的构造古地理控制。  相似文献   

20.
板块俯冲碰撞拼合带是盆山相互作用最为强烈的地区,发育有弧前、弧间及弧后多种类型的盆地,沉积物的剥蚀搬运作用极为活跃。证据显示,沉积物搬运充填过程在构造—古地理控制型盆地中具有一定的演变规律,伴随盆地演化,沉积物轴向搬运与横向搬运呈此消彼长的互动关系。南海南北两侧均发育了大型板块俯冲拼合带及相关的沉积盆地,在盆地发育早期沉积物沿盆地长轴方向分别形成昆莺琼古河和巽他古河,以轴向搬运的方式分别把越南中部及马来半岛沉积物由西向东输送到南海,形成大型三角洲及前三角洲深水扇沉积,河流发育位置均在板块拼合转折地段。在盆地发育的成熟阶段,沉积物以横向搬运的方式进入盆地,与轴向搬运沉积物形成混合堆积。轴向搬运是洋陆碰撞拼合盆地中一种重要的沉积物搬运途径,主要受盆地形成时的构造古地理控制。  相似文献   

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