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1.
Euganean trachyte is a subvolcanic porphyritic rock extracted in northern Italy with an age-old tradition of use as dimension stone, historically linked, in particular, to the fervent building activity brought by the Roman Empire and, later on, the Republic of Venice Serenissima. The results of a comprehensive petrophysical and mechanical characterization of Euganean trachyte from the most representative quarries are discussed here, involving the following properties: density, porosity, water absorption, capillary water uptake, hygroscopic water adsorption, hydric/hygric dilatation, water vapor diffusion, thermal expansion, and resistance to salt attack and abrasion. The different trachyte varieties, although belonging to the same quarry basin, exhibit a relatively wide array of technical performances, which are strongly dependent on pore volume, size, size distribution, shape, and degree of interconnection, controlling modes and rates of water transport and retention. Therefore, indications are provided for evaluating durability performance of the stone, with stress on water-driven weathering. Complementary information is finally given on the possible criteria followed in the antiquity for properly selecting the trachyte quarries to be exploited, and by a comparison with the properties of the most important trachytes extracted in Europe.  相似文献   

2.
Most studies dealing with material properties of sandstones are based on a small data set. The present study utilizes petrographical and petrophysical data from 22 selected sandstones and ~300 sandstones from the literature to estimate/predict the material and weathering behaviour of characteristic sandstones. Composition and fabric properties were determined from detailed thin section analyses. Statistical methods applied consist of data distributions with whisker plots and linear regression with confidence regions for the petrophysical and weathering properties. To identify similarities between individual sandstones and to define groups of specific sandstone types, principal component and cluster analyses were applied. The results confirm an interaction between the composition, depositional environment, stratigraphic association and diagenesis, which leads to a particular material behaviour of sandstones. Three different types of pore radii distributions are observed, whereby each is derived from different pore space modifications during diagenesis and is associated with specific sandstone types: (1) bimodal with a maximum in capillary and micropores, (2) unimodal unequal with a maximum in smaller capillary pores and (3) unimodal equable with a maximum in larger capillary pores. Each distribution shows specific dependencies to water absorption, salt loading and hygric dilatation. The strength–porosity relationship shows dependence on the content of unstable lithic fragments, grain contact and type of pore radii distribution, cementation and degree of alteration. Sandstones showing a maximum of capillary pores and micropores (bimodal) exhibit a distinct hygric dilatation and low salt resistance. These sandstones are highly immature sublitharenites–litharenites, characterized by altered unstable rock fragments, which show pointed-elongated grain contacts, and some pseudomatrix. Quartz arenites and sublitharenites–litharenites which are strongly compacted and cemented, show unimodal unequal pore radii distributions, low porosity, high strength and a high salt resistance. The presence of swellable clay minerals in sublitharenites–litharenites leads to a medium to high hygric dilatation, whereas quartz arenites show little hygric dilatation. Sandstones with unimodal equal pore radii distribution mostly belong to weakly compacted and cemented mature quartz arenites. These are characterized by high water absorption and high porosity, low to medium strength and a low salt resistance. The data compiled in this study are used to create a sandstone quality catalogue. Since material properties are dependent on many different parameters of influence, the transition between different lithotypes is fluent.  相似文献   

3.
Pouragha  Mehdi  Eghbalian  Mahdad  Wan  Richard  Wong  Tai 《Acta Geotechnica》2021,16(4):1147-1160

Water retention of clayey soils with wide particle size distributions involves a combination of capillary and adsorbed layers effects that result into suction–saturation relations spanning over multiple decades of matric suction values. The present study provides a physics-based analysis to reproduce the water retention curve of such soils based solely on particle size distribution and porosity. The distribution of inter-particle pore sizes is inferred through a probabilistic treatment of the particle size distribution, which is then used, together with an assigned pore entry pressure, to estimate the inter-particle water volume at a given suction. The contribution to water content from adsorbed layers is also taken into account by considering the balance of electrochemical forces between water and clay material. The total water content is therefore found by summing up the contribution of inter-particle water, as well as adsorbed layers that form around clay particles and around the individual clay platelets. Comparisons with experimental results on nine different soil samples verify the capability of the model in accurately predicting the wide water retention curves without any prior calibration. Additional to capturing the essential features of the water retention curve with remarkable detail, the analytical model also provides insights into the relative contributions of capillary and adsorbed waters to the overall saturation at different suction regimes. Being based upon easily accessible information such as particle size distribution and void ratio, the model can therefore be considered as a substitute for costly and lengthy laboratory and in situ measurements of water retention curve.

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4.
Won  Jongmuk  Lee  Junghwoon  Burns  Susan E. 《Acta Geotechnica》2021,16(2):421-432

Understanding particle transport in porous media is critical in the sustainability of many geotechnical and geoenvironmental infrastructure. To date, the determination of the first-order rate coefficients in the advection–dispersion equation for simulating attachment and detachment of particles in saturated porous media typically has been relied on the result of laboratory-scale experiments. However, to determine attachment and detachment coefficients under varied hydraulic and geochemical variables, this method requires a large experimental matrix because each test provides only one set of attachment and detachment coefficients. The work performed in this study developed a framework to upscale the results obtained in pore-scale modeling to the continuum scale through the use of a pore network model. The developed pore network model incorporated variables of mean particle size, the standard deviation of particle size distribution, and interparticle forces between particles and sand grains. The obtained retention profiles using the pore network model were converted into attachment coefficients in the advection–dispersion equation for long-term and large-scale simulation. Additionally, by tracking individual particles during and after the simulation, the pore network model introduced in this study can also be employed for modeling the clogging phenomenon, as well as fundamental investigation of the impact of particle size distribution on particle retention in the sand medium.

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5.
In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N2 adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals.  相似文献   

6.
The huge sculptures placed outdoors in the Valley of the Fallen Memorial Park (El Escorial, Madrid) made with blocks of Black-Limestone from Calatorao-Zaragoza, Spain (BLCZ) and disposed on a concrete core exhibit weathering traces, flaking, saline efflorescence and falling fragments, currently represent a danger for visitors. Frost action is important in the Valley of the Fallen by the large number of freeze–thaw cycles produced during Sculptures‘live under a temperate Mediterranean climate with severe seasonality. The formation of fissures facilitates the water transport within the rock and the salt- and ice-induced deterioration. Temperate climates with frequent freezing and thawing cycles can be the most effective drivers of the visible physical weathering. In order to propose a suitable weathering model, collected black-limestones from sculptures and Calatorao quarries were analyzed by optical microscopy, environmental scanning electron microscopy with energy dispersive spectrometry (ESEM-EDS), inductively coupled mass spectrometry (ICP-MS) and X-ray diffraction. Mercury intrusion porosimetry (MIP), nitrogen absorption and helium pycnometry techniques were used for pore analyses of the BLCZ micro-blocks (10 × 10 × 10 cm) described in terms of pore size distribution, pore volume and specific surface area. The appreciable amount of organic matter was isolated by solvent extraction, acid treatment, flotation and perborate degradation followed by Gas Chromatography–Mass Spectrometry (GC–MS), Analytical Pyrolysis (Py-GC/MS), Fourier Transformed Infrared Spectroscopy and Raman techniques. Both weathered and fresh BLCZ samples contained more than 90 % calcite shells with circa 10 % of pyrite (fresh samples) or iron hydroxides (weathered samples), quartz grains, claystone and fossil organic matter consisting of a condensed matrix with polyalkyl chains and polycyclic methoxyl-lacking aromatic structures. The petrophysical analyses revealed volumes of pores, sized <0.025 μm obtained by N2 adsorption, of 3.18 × 10?3 cm3 g?1 while the measured porosity by MIP in the pore range from 0.005 to 200 μm was 3.30 × 10?3 cm3 g?1. These data could be explained by the existence of clay minerals and organic matter in the pore system less than 50 nm of diameter. Concerning BLCZ deterioration it was found that the porous framework of BLCZ was filled with sulphates formed from artificial cement observed in the sculptures inside trough a testing hole and from its intrinsic pyrite. The results suggested that although biological processes were not major agents in rock deterioration, there was also weak compatibility between sculptures‘constituents, (limestone, concrete and oxidized iron clamps) which under, continental Mediterranean conditions, were continuously releasing weathering compounds accelerating disruption of the cut-stone sculptures.  相似文献   

7.
The paper offers an analytical determination of the hydraulic properties of an unsaturated soil with reference to its retention curve, which describes the relationship between the volumetric water content and capillarity through matric suction. The analysis combines a particulate approach focused on the physics at the pore scale, including microstructural aspects, with a probabilistic approach where the void space and grain size are considered as random variables. In the end, the soil water characteristic curve of an unsaturated granular medium along a drying path can be derived analytically based on the sole information of particle size distribution. The analysis hinges on the tessellation of a wet granular system into an assemblage of tetrahedral unit cells revealing a pore network upon which capillary physics are computed with respect to pore throat invasion by a non-wetting fluid with evolving pendular capillary bridges. The crux of the paper is to pass from particle size probability distribution to a matching void space distribution to eventually reveal key information such as void cell and solid volume statistics. Making reasonable statistically based assumptions to render calculations tractable, the water retention curve can be readily constructed. Model predictions compare quite favourably with experimental data available for actual soils, especially in the high saturation range. Having a sound scientific basis, the model can be made amenable to address a variety of soils with a wider range of particle sizes.  相似文献   

8.
Among hygric properties of stone material, the sorption behaviour is of essential importance because of the permanence of the processes involved. New results from static sorption experiments performed by standard techniques and by a new tool are reported for six different building stones. Furthermore, an example of dynamic sorption behaviour under continuously changing humidity is presented. For the static equilibrium sorption measurements a close relation to the stone type, its pore properties, such as specific inner surface, pore volume, pore size distribution as well as capillary water uptake and water saturation, is drawn. The comparison of the different data allows us to retrieve correlations between material features that are crucial for weathering processes. The sorption–desorption processes respond spontaneously on even small humidity changes as shown by the dynamic sorption experiment. A permanent breathing-process of the material is imposed.  相似文献   

9.
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10.
The composition of river water, sediments, and pore waters (down to 30 cm below the bed) of Las Catonas Stream was studied to analyze the distribution of trace elements in a peri-urban site. The Las Catonas Stream is one of the main tributaries of Reconquista River, a highly polluted water course in the Buenos Aires Province, Argentina. The semi-consolidated Quaternary sediments of the Luján Formation are the main source of sediments for Las Catonas Stream. The coarse-grained fraction in the sediments is mainly composed of tosca (calcretes), intraclasts, bone fragments, glass shards, quartz, and aggregates of fine-grained sediments together with considerably amounts of vegetal remains. The clay minerals are illite, illite–smectite, smectite, and kaolinite. For the clay-sized fraction, the external surface area values are mostly between 70 and 110 m2g?1, although the fraction at 15 cm below the bottom of the river shows a lower surface area of 12 m2g?1. The N2 adsorption–desorption isotherms at 77 K for this sample display a behavior indicative of non-porous or macroporous material, whereas the samples above and below present a typical behavior of mesoporous materials with pores between parallel plates (slit-shaped). As, Cr, Cu, and Cd concentrations increase down to 15 cm depth in the sediments, where the highest trace element and total organic carbon (TOC) concentrations were found, and then decrease toward the bottom of the core. Except for As, the levels of the other heavy metals show higher concentration in surficial waters than in pore waters. Distribution coefficients between the sediments, pore water, and surficial water phases indicate that As is released from the sediments to the pore and surficial waters. Cu content strongly correlates with TOC (mainly from vegetal remains), suggesting that this element is mainly bound to the organic phase.  相似文献   

11.
非饱和粘土孔隙弹性压力理论   总被引：2，自引：0，他引：2  
非饱和粘土因存在气体、液体和固体相, 使非饱和土孔隙压力问题变得复杂。一般来说,气体压缩性大,体积变化对土体变形的贡献起主要作用。在简单介绍现在常用的孔隙压力理论后,基于非饱和粘土孔隙压力平衡关系,由混合物理论导出Bishop公式系数X的表达式;以弹性理论为基础,由质量守恒导出非饱和粘土孔隙压力的一般公式,由此得出Skempton公式A,B系数的表达式;还将其各向同性压缩和侧向约束压缩两种情况作了试验证实。  相似文献   

12.
Consolidation of sensitive clays: a numerical investigation   总被引：1，自引：1，他引：0  
Consolidation of sensitive clay layers, which have significant compressibility at different stress states, is investigated via a nonlinear one-dimensional consolidation approach with a piecewise linear e ~ log10σ′ model. The behaviour of sensitive clays during consolidation and the limitations of conventional consolidation theory are addressed. It is shown that (1) the sensitive clay layer can be divided by the preconsolidation pressure into two zones, that is, high- and low-compressibility zones. The progressive destruction of particle cementation bonding through the soil layer is shown by the moving front of the interface between these two zones; (2) the excess pore pressure dissipation primarily takes place in the low-compressibility zone, which results in a small settlement during the early stages of consolidation; (3) conventional consolidation theory highly overestimates the settlement and gives a poor prediction of effective stress distribution.  相似文献   

13.
The transport and filtration behaviour of fine particles (silt) in columns packed with sand was investigated under saturated conditions by using step-input injections. Three samples of different particle size distributions (coarse medium, fine medium and a mixture of both) were used in order to highlight the influence of the pore size distribution on particle retention and size selection of recovered particles. The main parameters of particle transport and deposition were derived from the adjustment of the experimental breakthrough curves by an analytical model. The higher particle retention occurs in the mixture medium, owing to its large pore size distribution, and the filtration coefficient decreases with increasing flow velocity. Particle size distribution of recovered particles shows a thorough size selection: (i) the first recovered particles are the coarser ones; (ii) the size of the recovered particles increases with increasing flow velocity and enlarger pore distribution of the medium.  相似文献   

14.
This study aims to quantify the effect of heating and freezing temperatures on the pore size distribution of saturated clays. Three kaolinite clay specimens were subjected to different temperatures: 20, 70, and ? 10 °C. Upon achieving the desired temperature for each specimen, the specimens were flash frozen in liquid nitrogen to preserve their microstructure. Each specimen was, then, freeze-dried for 24 h after which consecutive two-dimensional (2-D) SEM images were taken using a dual focused ion beam/scanning electron microscope. The produced 2-D images of each specimen were used to reconstruct three-dimensional tomographies of the specimens, which were analyzed to determine the pore size distribution at each temperature. Compared to the specimen at room temperature, the pores in the specimen subjected to ? 10 °C were larger; this is believed to be due to the formation of ice lenses inside the pores upon freezing and potential merging between initial pores to form larger pores. On the other hand, the heated specimen showed an increase in the volume of the smaller pores and a decrease in the volume of the larger pores compared to the specimen at room temperature. This opposite behavior between the small and large pores in the heated specimen is justified considering (1) the easier flow of water out of the larger pores compared to that in the smaller pores and (2) the anisotropic nature of the thermal expansion of the clay particles.  相似文献   

15.
This study was carried out to determine the flux of nutrients and heavy metals from the Melai sub-catchment into Lake Chini through the process of erosion. Melai River is one of the seven feeder rivers that contributed to the present water level of Lake Chini. Three properties of soils, such as particle size, organic matter content, and soil hydraulic conductivity and three chemical soil properties, such as available nutrients, dissolved nutrients, and heavy metals, were analyzed and interpreted. Potential soil loss was estimated using the revised universal soil loss equation model. The results show that the soil textures in the study area consist of clay, silty clay, clay loam, and sandy silt loam. The organic matter content ranges from 3.40 to 9.92 %, while the hydraulic conductivity ranges from 5.2 to 25.3 cm/h. Mean values of available P, K, and Mg amount was 8.5 ± 3.7 μg/g, 24.5 ± 3.4 μg/g, and 20.7 ± 18.6 μg/g, respectively. The highest concentration of soluble nutrients was SO 4 ?2 (815.8 ± 624.1 μg/g), followed by NO3 ?-N (295.5 ± 372.7 μg/g), NH4 +-N (24.5 ± 22.1 μg/g) and PO4 3? (2.0 ± 0.8 μg/g). The rainfall erosivity value was 1658.7 MJ mm/ha/h/year. The soil erodibility and slope factor ranges from 0.06 to 0.26 ton h/MJ/mm and 7.63 to 18.33, respectively. The rate of soil loss from the Melai sub-catchment in the present condition is very low (0.0028 ton/ha/year) to low (18.93 ton/ha/year), and low level flow of nutrients and heavy metals, indicating that the Melai River was not the contaminant source of sediments, nutrients, and heavy metals to the lake.  相似文献   

16.
A simple cutoff approach based on the capillary bundle model has become an industrial standard method to quickly obtain the irreducible water saturation from NMR T2 distribution. However this approach is not always valid. To overcome the shortcoming of the capillary bundle model that ignores pore-pore connectivity, we have conducted a two-phase flow simulation in a CT-based pore network. The CT -based pore network is a representation of a real rock pore structure that is described by a binary X-ray tomographic data set. Simulation on such network mimics a process of the porous plate measurement. The generated capillary curve is quite reasonable. The oil accession distributions at different water saturations plotted as a function of pore size provide an insight for the immiscible displacement process in the real rock pore structure. Water is trapped not only in dead ends but also in the well-connected pores due to a pore level by-pass mechanism. At the capillary end point pressure, a plot of the trapped water distribution as a function of pore size has the same lognormal distribution as the pore size distribution, which is much different from what the simple capillary bundle model suggests.  相似文献   

17.
Micro-mechanical failure analysis of wet granular matter   总被引：1，自引：1，他引：0  
We employ a novel fluid–particle model to study the shearing behavior of granular soils under different saturation levels, ranging from the dry material via the capillary bridge regime to higher saturation levels with percolating clusters. The full complexity of possible liquid morphologies Scheel et al. (Nat Mater 7(3):189–193, 2008. doi: 10.1038/nmat2117) is taken into account, implying the formation of isolated arbitrary-sized liquid clusters with individual Laplace pressures that evolve by liquid exchange via films on the grain surface Melnikov et al. (Phys Rev E 92(022):206, 2015. doi: 10.1103/PhysRevE.92.022206). Liquid clusters can grow in size, shrink, merge and split, depending on local conditions, changes of accessible liquid and the pore space morphology determined by the granular phase. This phase is represented by a discrete particle model based on contact dynamics Brendel et al. (Contact dynamics for beginners. Wiley-VCH, Weinheim, 2005. doi: 10.1002/352760362X.ch14), where capillary forces exerted from a liquid phase add to the motion of spherical particles. We study the macroscopic response of the system due to an external compression force at various liquid contents with the help of triaxial shear tests. Additionally, the change in liquid cluster distributions during the compression due to the deformation of the pore space is evaluated close to the critical load.  相似文献   

18.
The effect of grain size distribution on the unconfined compressive strength (UCS) of bio-cemented granular columns is examined. Fine and coarse aggregates were mixed in various percentages to obtain five different grain size distributions. A four-phase percolation strategy was adopted where a bacterial suspension and a cementation solution (urea and calcium chloride) were percolated sequentially. The results show that a gap-graded particle size distribution can improve the UCS of bio-cemented coarser granular materials. A maximum UCS of approximately 575 kPa was achieved with a particle size distribution containing 75% coarse aggregate and 25% fine aggregate. Furthermore, the minimum UCS obtained has applications where mitigation of excessive bulging of stone/sand columns, and possible slumping that might occur during their installation, is needed. The finding also implies that the amount of biochemical treatments can be reduced by adding fine aggregate to coarse aggregate resulting in effective bio-cementation within the pore matrix of the coarse aggregate column as it could substantially reduce the cost associated with bio-cementation process. Scanning electron microscopy results confirm that adding fine aggregate to coarse aggregate provides more bridging contacts (connected by calcium carbonate precipitation) between coarse aggregate particles, and hence, the maximum UCS achieved was not necessarily associated with the maximum calcium carbonate precipitation.  相似文献   

19.
The relationship between composition and physical parameters such as specific surface area, cationic exchange capacity and plasticity is studied with the aim of developing regression models that would permit the prediction of clay properties. These models could be useful for mineralogists and industrial applications. Nineteen representative clay samples were collected from Jebel Ressas in north-eastern Tunisia. Mineralogical data show that clay samples cover a very large variety of minerals. The main clay mineral is illite (50–60 wt%), secondary minerals including quartz, calcite and minor amounts of Na-feldspar. This study reveals that the average amount of silica (SiO2) and alumina (Al2O3) are 51.9 and 19.6 wt%, respectively. The contents of lime (CaO) and iron (Fe2O3) vary between 4 and 8 wt% whereas the amount of alkalis (Na2O + K2O) is on average 4.1 wt%. The grain size data indicates a significant amount of silt fraction, and the fraction <2 µm varies between 23 and 35 wt%. Values for plasticity index range from 16 to 28 wt%. The cation exchange capacity and the specific surface values are 34.1–45.7 meq/100 g of air-dried clay and 302–374 m2/g, respectively. Lastly, regression models are used to correlate the properties with the mineralogical and chemical compositions. The significance and the validity of models were confirmed by statistical analysis and verification experiments. The regression models can be used to select the clay properties (plasticity index, cation exchange capacity and specific surface) in relation with clay minerals proportions and the finer fraction amounts.  相似文献   

20.
This study experimentally investigates the effect of particle size, particle concentration and flow velocity on the migration of suspended particles of size 1.02–47 μm in porous media. The results show that at the same flow velocity, the peak values of the breakthrough curves decrease and corresponding pore volumes increase slightly with increasing particles size. The migration velocity of smaller suspended particles is even greater than water flow velocity, which is attributed to the size exclusion effect. With increase of the injected particle concentration, the deposition coefficients of small single particles increase at first and then tend to a steady state or even decrease slightly, explained by the maximum retention concentration. The dispersivity of small particles decreases with increasing velocity. However, at a high flow velocity, the hydrodynamic dispersivity becomes increasingly dominant with the increase of particle size. The deposition coefficients for large-sized particles are higher than those for small-sized particles, which is attributed to considerable mass removal due to straining. An analytical solution, considering the release effect of sorbed particles, is developed to account for the one-dimensional flow and dispersive effect using a source function method, and then three transport parameters—dispersivity, deposition coefficient and release coefficient—are fitted using the experimental results. Finally, suspended-particle migration is predicted by the proposed model for short-time constant-concentration injection and repeated three-pulse injection. Overall, particle size has a significant effect on the seepage migration parameters of suspended particles in porous media such as the particle velocity, dispersivity and deposition coefficient.  相似文献   

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