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1.
Abundant Lower Cretaceous (Berriasian–Hauterivian) paleosols have been recognized in the Sichuan Basin, along with the preserved pedogenetic features, e.g., soil horizons, soil structure, root traces and pedogenic nodules. Chemical, geochemical and mineralogical analyses were used to examine the paleosols. These paleosols were classified as Entisols, Inceptisols, Aridisols and Alfisols in terms of the modern soil taxonomic system. Early Cretaceous paleoprecipitation and paleotemperature in the Sichuan Basin were estimated from the degree of chemical weathering for non-calcareous paleosols, and from the depth to the calcic horizon and stable oxygen isotopic composition of pedogenic carbonates in calcareous paleosols, respectively. A temperate semi-arid climate generally prevailed in the Sichuan Basin as a part of the South China Block (SCB) and was controlled by subtropical high-pressure and a rain-shadow effect because the humid air masses from the Paleo-Pacific were impeded by the highlands of the South China Block. Further, several intervals of sub-humid paleoclimate occurred due to strengthened monsoonal circulation in the Early Cretaceous. Using the paleosol barometer, the paleoatmospheric CO2 levels of the Early Cretaceous are estimated to range from ∼120 to ∼520 ppmv, with a mean of 305 ppmv. Regional temperature is generally coupled with atmospheric CO2 concentration and is roughly consistent with the sea level fluctuation. 相似文献
2.
The Early Cretaceous was a time with super-greenhouse conditions and episodic global oceanic anoxic events. However, relative timing of atmospheric CO2 emissions and oceanic anoxic events, and their causal relationships remain matters of debate. Using the stomatal index approach, well-preserved fossil cuticles of Ginkgo from the Lower Cretaceous Changcai Formation, eastern Jilin, and from the Lower Cretaceous Yingcheng Formation, central Jilin, Northeast China, were investigated to reconstruct atmospheric CO2 concentrations during the Aptian and earliest Albian (Early Cretaceous). The results indicate that the CO2 concentrations reached 1098–1142 ppmv (Carboniferous standardization) or 970–1305 ppmv (regression function) during the Aptian and earliest Albian. Our estimates of palaeoatmospheric CO2 concentrations during the earliest Albian (OAE 1b) are slightly higher than the data between the early Aptian Selli (OAE 1a) and the middle Aptian Fallot OAEs; this may indicate the absence of any great emissions of CO2 during the latest Aptian and earliest Albian. 相似文献
3.
The palaeo-atmospheric CO_2 concentration(pCO_2) variation in the Yumen, Gansu Province during the middle Cretaceous has been reconstructed using the newly established plant photosynthetic gas exchange mechanistic model, and the results show that the p CO_2 values are in the range of about 550–808 ppmv. The present pCO_2 values are higher than the p CO2 results(531–641 ppmv) of the previous study according to the Recent standardization of the stomatal ratio method, and much lower than the pCO_2 results(882–1060 ppmv) according to the Carboniferous standardization of the stomatal ratio method. The present pCO_2 variation is not only within the error range of GEOCARBⅡ and GEOCARB Ⅲ but also is similar to the reconstructed results based on the biochemistry and carbon isotope models. Besides, the present Brachyphyllum specimens were collected from four consecutive horizons of the upper Zhonggou Formation of the Hanxia Section, and the reconstructed pCO_2 exhibits the reconstructed pCO_2 exhibits a decline trend during the late Aptian to early Albian. This decline variation is probably associated with the Oceanic Anoxic Events(OAE1 b) and the Cold snap event. With the combination of p CO_2 during the Albian to Cenomanian recovered by the plant photosynthetic gas exchange mechanistic model, the pCO_2 showed a prominent increase during the late Aptian to early Cenominian, which indicates a response to the greenhouse warming during the middle Cretaceous. Therefore, the mechanical model of the plant photosynthetic gas exchange shows a relatively strong accuracy in the reconstruction of the pCO_2 and can reflect a strong relation between the atmospheric CO_2 concentrations and climatic events. 相似文献
4.
Andrzej Pszczółkowski Ryszard Myczyński 《Journal of South American Earth Sciences》2010,29(2):225-253
In the Guaniguanico Mountains of western Cuba, the Late Jurassic–Early Cretaceous limestones occur in three stratigraphic successions, which have accumulated along the proto-Caribbean margin of North America. The Late Jurassic subsidence and shallow-water carbonate deposition of the Guaniguanico successions have no counterpart on the northeastern Maya block, but some distant similarities with the southeastern Gulf of Mexico may exist. Four facies types have been distinguished in the Tithonian–Lower Valanginian deposits of the Guaniguanico tectonic units. Drowning of the Late Jurassic carbonate bank of the Sierra de los Organos occurred at the Kimmeridgian/Tithonian boundary. During this boundary interval, sedimentation in the west Cuban area and southwestern margin of the Maya block (Mexico) has evolved in a similar way in response to a major second-order transgression.The Lower Tithonian ammonite assemblages of the Guaniguanico successions indicate, in general, the neritic zone. Presence of juvenile gastropods and lack of adult specimens suggest unfavorable environment for these molluscs, probably related to low oxygenation levels. The Early Tithonian transgressive phase terminated about the lower boundary of the Chitinoidella Zone. The Late Tithonian “regressive” phase is weakly marked, whereas the latest Tithonian–earliest Berriasian strata were deposited during a deepening phase. The latter transgressive phase has ended in the Late Berriasian Oblonga Subzone. We correlate the bioturbated pelagic biomicrites of the Tumbitas Member of the Guasasa Formation with a significant fall of the sea level during the latest Berriasian–Early Valanginian. The average sedimentation rate for the Tumbitas Member biomicrites was about three times faster than for the Berriasian Tumbadero Member limestones. Sedimentation rates for the Tumbitas Member and the Valanginian limestones at the DSDP Site 535 in the southeastern Gulf of Mexico were similar. In the Los Organos succession, the Late Valanginian transgressive interval is associated with radiolarian limestones and black chert interbeds in the lower part of the Pons Formation. In the Southern Rosario succession, the pelagic limestones pass into the radiolarian cherts of the Santa Teresa Formation indicating a proximity of CCD during Late Valanginian–Hauterivian times. 相似文献
5.
内蒙古平庄─元宝山盆地群晚中生代地层 总被引：2，自引：0，他引：2
平庄─元宝山盆地的晚中生代地层可划分为下白垩统黑水组、元宝山组和杏园组，上侏罗统上那不打组与那不打组。杏园组和元宝山组中含有丰富的植物化石，属于ＲｕｆｆｏｒｄｉａＯｎｙｃｈｉｏｐｓｉｓ植物群的中部组合，可与邻区的主要含煤沉积的植物组合进行对比，时代属早白垩世Ｂｅｒｒｉａｓｉａｎ期至早Ａｐｔｉａｎ期。 相似文献
6.
7.
黑龙江东部侏罗—白垩系界线附近地层研究新进展 总被引：30，自引：7，他引：23
<正> 近年来,随着饶河东安镇具国际性对比标准的海相侏罗—白垩系界线的确定及其相关生物组合带的建立(孙革等,1989),黑龙江省东部地区的海相—海陆交互相—陆相的侏罗—白垩系界线及其附近地层的研究,不断取得新的进展。研究成果之一是,鸡西盆地城子河组时代属早白垩世。在其典型剖面(穆棱河北岸路堑剖面)的城子河组下部,发现含早白垩世凡兰吟—戈特里夫期(Valanginian-Hauterivian)沟鞭藻的海相层(孙学坤、 相似文献
8.
The stable carbon isotope compositions and the stomatal parameters (stomatal density and stomatal index) of four Cheirolepidiaceae species, Brachyphyllum ningxiaensis, Brachyphyllum obtusum, Pseudofrenelopsis dalatzensis and Pseudofrenelopsis gansuensis, were analyzed to recover the late Early Cretaceous atmospheric CO2 levels. The fossil plants were collected from 5 consecutive sedimentary members of the uppermost Zhonggou Formation. Based on the stomatal data, the estimated palaeo-atmospheric CO2 concentrations in the Jiuquan Basin during the late Early Cretaceous were 1060–882 ppmv based on the carboniferous standardization and were 641–531 ppmv based on the recent standardization; the pCO2 values present at first a decreasing and then an increasing trend within the sedimentary time of the five members. The δ13Cp values based on the 21 Brachyphyllum specimens showed a large variation, which ranged from −20.98‰ to −25.69‰, with an average of −24.2‰. The values also identified a C3 photosynthetic pathway for the Brachyphyllum specimens. The predicted δ13Ca values varied from −2.1‰ to −6.38‰, with an average of −5.03‰. These two proxies were irregular within the different members; therefore, the correlation with the change in atmospheric CO2 concentrations was not significant. Moreover, a water-stressed environment was proposed based on the δ13C values of the present fossil plants, a proposal that was also supported by the previous palaeobotanical, palynological and stratigraphical evidence. In the present study, an inconsistent relationship between the stable carbon isotope and the stomata values was apparent, which most likely indicated that the stomata numbers of the plant were more sensitive to the variation in the concentration of the atmospheric CO2, whereas the δ13C values were sensitive to the moisture conditions. 相似文献
9.
The Valanginian carbon isotope event: a first episode of greenhouse climate conditions during the Cretaceous 总被引：1，自引：0，他引：1
Lower Cretaceous pelagic carbonates outcropping along the Southern Alps of northern Italy provide a record of Tethyan palaeoceanography as well as of low frequency fluctuations in the global carbon cycle. The carbonate C-isotope stratigraphy established at five selected localities in the Southern Alps allows an accurate picture to be drawn of the duration and amplitude of the Valanginian C-isotope event. δ13 C values near 1.25–1.50% determined in Berriasian and lower Valanginian sediments are replaced by more pdsitive δ13 C values near 3% in the late Valanginian. The carbonate C-isotope excursion ends in the early Hauterivian with values fluctuating between 1.5% and 2%. The carbonate C-isotope excursion is accompanied by a positive excursion in the total organic carbon C-isotope curve. The Valanginian C-isotope excursion identified in Tethyan sediments correlates with a C-isotope excursion recorded in the western North Atlantic, in the Gulf of Mexico, and in the Central Pacific (DSDP Sites 534,391,535 and 167). By analogy with the Aptian stage, also marked by a significant positive C-isotope excursion, the time of positive δ13 C values is regarded as a time of accelerated carbon cycling coupled with increased burial rates of organic carbon and detrital material in oceanic sediments. A warm and humid climate, possiblycoupled with a high atmospheric CO2 content and a high global sea-level, may have triggered the acceleration of the global carbon cycling. In this case the Valanginian C-isotope event would reflect a first episode of Greenhouse Earth conditions during the Cretaceous. 相似文献
10.
Pedogenic goethites in each of two Early Permian paleosols appear to record mixing of two isotopically distinct CO2 components—atmospheric CO2 and CO2 from in situ oxidation of organic matter. The δ13C values measured for the Fe(CO3)OH component in solid solution in these Permian goethites are −13.5‰ for the Lower Leonardian (∼283 Ma BP) paleosol (MCGoeth) and −13.9‰ for the Upper Leonardian (∼270 Ma BP) paleosol (SAP). These goethites contain the most 13C-rich Fe(CO3)OH measured to date for pedogenic goethites crystallized in soils exhibiting mixing of the two aforementioned CO2 components. δ13C measured for 43 organic matter samples in the Lower Leonardian (Waggoner Ranch Fm.) has an average value of −20.3 ± 1.1‰ (1s). The average value yields a calculated Early Permian atmospheric Pco2 value of about 1 × PAL, but the scatter in the measured δ13C values of organic matter permits a calculated maximum Pco2 of 11 × PAL (PAL = present atmospheric level). Measured values of the mole fraction of Fe(CO3)OH in MCGoeth and SAP correspond to soil CO2 concentrations in the Early Permian paleosol profiles of 54,000 and 50,000 ppmV, respectively. Such high soil CO2 concentrations are similar to modern soils in warm, wet environments.The average δ13C values of pedogenic calcite from 9 paleosol profiles stratigraphically associated with MCGoeth (Waggoner Ranch Fm.) range from −6.5‰ to −4.4‰, with a mean δ13C value for all profiles of −5.4‰. Thus, the value of Δ13C between the pedogenic calcite data set and MCGoeth is 8.1 (±0.9)‰, which is in reasonable accord with the value of 7.7‰ expected if atmospheric Pco2 and organic matter δ13C values were the same for both paleosol types. Furthermore, the atmospheric Pco2 calculated for the Early Permian from the average measured carbon isotopic compositions of the paleosol calcite and organic matter is also analytically indistinguishable from 1 × PAL, with a maximum calculated atmospheric Pco2 (permitted by one standard deviation of the organic matter δ13C value) of ∼5 × PAL.If, however, measured average δ13C values of the plant organic matter are more positive than the original soil organic matter as a result of diagenetic loss of 13C-depleted, labile organic compounds, calculated Permian atmospheric Pco2 using these 13C-enriched organic values would underestimate the actual atmospheric Pco2 using either goethite or calcite. This is the first stratigraphically constrained, intrabasinal study to compare ancient atmospheric CO2 concentrations calculated from pedogenic goethite and calcite. These results demonstrate that the two different proxies record the same information about atmospheric CO2.The Fe(CO3)OH component in pedogenic goethite from a Triassic paleosol in Utah is significantly enriched in 13C relative to Fe(CO3)OH in goethites from soils in which there are mixtures of two isotopic CO2 components. Field-relationships and the δ13C value (−1.9‰) of the Triassic goethite indicate that this ancient paleosol profile experienced mixing of three isotopically distinct CO2 components at the time of goethite crystallization. The three components were probably atmospheric CO2, CO2 from in situ oxidation of organic matter and CO2 from in situ dissolution of preexisting calcite. Although mixing of three isotopically distinct CO2 components, as recorded by Fe(CO3)OH in goethite, has been described in modern soil, this is the first example from a documented paleosol. Its preservation affirms the need for careful, case-by-case assessment of ancient paleosols to establish that goethite in any particular soil is likely to be a valid proxy of atmospheric Pco2. 相似文献
11.
The Valanginian is a period of global environmental change as illustrated by sedimentary, palaeontological, geochemical and climatic perturbations. A production crisis in most of the carbonate platforms suggests important changes in palaeoenvironmental conditions. During the same time interval, a major positive excursion in δ13C, the Weissert Event, suggests perturbations of the carbon cycle from the latest Early Valanginian to the Early Hauterivian. In order to better understand the link between these changes, sea‐level fluctuations have been reconstructed in detail from the Middle Berriasian to the earliest Hauterivian. Sections from the Peri‐Vocontian Zone (South‐east France) have been investigated because of the good quality of outcrops on the carbonate platforms, their margins and in the Vocontian Basin. Sections ranging from the most proximal zone (Swiss Jura) to the basin were interpreted in terms of sequence stratigraphy and cyclostratigraphy, and correlated at high resolutions. Using the identified small, medium and large‐scale sequences as well as depositional geometries, sea‐level fluctuations were reconstructed. Two main trends are evidenced during the studied interval: (i) the peak amplitude (magnitude) of the sea‐level fluctuations increased gradually from the Middle Berriasian to the Early Valanginian, and reached a maximum (more than 50 m) from the middle Early Valanginian to the Valanginian/Hauterivian boundary; and (ii) sea‐level variations were quite symmetrical during the Late Berriasian, slightly asymmetrical during the Early Valanginian and strongly asymmetrical (fast sea‐level rise, slow fall) from the latest Early Valanginian to the earliest Hauterivian. Moreover, three orders of sea‐level fluctuations were recognized in the sedimentary rocks of the Peri‐Vocontian Zone. Platform‐basin correlations and cyclostratigraphic interpretations of the basinal sections evidence an astronomical control on the sea‐level variations, mainly by the two eccentricity cycles of 100 and 400 kyr. The increase in the amplitude of the sea‐level fluctuations and their change from symmetrical to asymmetrical can be related to the onset of a major cooling event in the Early Valanginian. Fast transgressions followed by slower regressions would correspond to waxing and waning of high‐latitudinal ice during most of the Valanginian, especially from the latest Early Valanginian to the latest Late Valanginian. Glacio‐eustatic sea‐level fluctuations in tune with the 100 and 400 kyr eccentricity cycles are in agreement with glaciations during the Valanginian. 相似文献
12.
The studies of past climatic changes form the basis for predicting our future anthropogenic world and are among the most prominent topics in current Earth sciences. Although the Cretaceous is generally considered as a greenhouse period in Earth's history, a number of significant cooling events based on an array of climatic proxies have been identified. Here we present the first data on Berriasian (Ryazanian) glendonite findings from the paleontologically well dated Lower Cretaceous succession of northeastern Siberia. Based on well calibrated Buchia and ammonite biostratigraphy, the stratigraphic interval across which the glendonites occur is restricted to the late Berriasian. Stable carbon isotope (δ13C) values of the studied glendonites clearly suggest the precipitation of ikaite from marine water without any significant contamination from biogenic methane. Our results, when integrated with other available paleoclimatic proxies from elsewhere in the high latitudes, suggest a revision of the initiation of Early Cretaceous cooling in the high latitudes from the Valanginian to the late Berriasian. All known occurrences of Lower Cretaceous glendonites in both the northern and southern hemispheres are reviewed. 相似文献
13.
The Younger Dryas stadial (11 000-10 000 yr BP) was an abrupt return to a glacial climate during the termination of the last glaciation. We have reconstructed atmospheric CO2 concentrations from a high-resolution sequence of fossil Salix herbacea leaves through this climatic oscillation from Kråkenes, western Norway, using the relationship between leaf stomatal density and atmospheric CO2 concentration. High Allerød CO2 values (median 273 ppmv) decreased rapidly during 130–200 14C-years of the late Allerød to ca. 210 ppmv at the start of the Younger Dryas. They then increased steadily through the Younger Dryas, reaching typical interglacial values once more (ca. 275 ppmv) in the Holocene. The rapid late Allerød decrease in CO2 concentration preceded the Younger Dryas temperature drop, possibly by several decades. This striking pattern of changes has not so far been recorded unambiguously in temporally coarse measurements of atmospheric CO2 from ice cores. Our observed late-glacial CO2 changes have implications for global modelling of the ocean-atmosphere-biosphere over the last glacial-interglacial transition. 相似文献
14.
黑龙江省东部中侏罗世至早白垩世沟鞭藻组合序列 总被引：5，自引：0，他引：5
对近二十年来黑龙江省东部海相侏罗纪—白垩纪沟鞭藻地层资料进行了综合研究 ,首次为该地区建立起侏罗纪—白垩纪沟鞭藻地层序列 ,主要包含 7个组合带 (含 3个高峰带 ) ,其中绥滨地区 Callovian— Valanginian期有 4个带 ;鸡西盆地早白垩世也有 4个带 (其中包括与绥滨地区早白垩世早期同时异相的一个 )。它们自下而上为 :1)绥滨组的 Pareodinia ceratophora- N annoceratopsispellucida组合带 ; 2 )东荣组下部的 Gonyaulacysta jurassica组合带 (高峰带 ) ; 3)东荣组上部的 Amphorula delicata组合带 ; 4 )东荣组最上部的海相 Oligosphaeridium pul-cherrimum组合带 (高峰带 )或鸡西盆地滴道组的微咸水—半咸水的 Vesperopsis didaoensis- L agenorhytis granoru-gosa组合带 ,两者为同时异相关系 ; 5 )城子河组下部海相层的 Odontochitina operculata- Muderongia tetracantha组合带 (该带可进一步划分出 2个亚组合带 ) ; 6 )城子河组上部海相层的 Canningia reticulata组合带 ; 7)穆棱组下段的 Cribroperidinium ?parorthoceras组合带 (高峰带 )。 相似文献
15.
Hawaiian streams are flashy in nature because watersheds are small and steep and receive intense and unevenly distributed rainfall. As a result, stream chemistry is characterized by considerable spatiotemporal variability. To examine how rainfall and streamflow affect the solute content of the Manoa River in Hawaii, time-series geochemical data collected during 17 sampling campaigns in spring-fall of 2010 were evaluated in a coupled δ13CDIC/major ion inversion model. Spatially, the stream is characterized by a distinct shift from a low HCO3 (43 mg/L), low pCO2 (3760 ppmv) and heavy δ13CDIC (−6.5‰) fingerprint in the upper reaches to a high HCO3 (91 mg/L), high pCO2 (8961 ppmv) and light δ13CDIC (−11.7‰) signature in the lowlands. These trends are attributed to (1) progressive weathering of exposed aluminosilicates, and (2) downstream enrichment in CO2 from organic matter decay in the soil zone. Solute (i.e., nitrate) yields from nitric acid weathering are generally low (<1% of TDS), even in the developed lowlands, where runoff of nitrate-enriched urban effluent has historically been documented. Data furthermore indicate a significant positive correlation between δ13CDIC and rainfall rates in the mid-stream section of the river which is consistent with an atmospheric CO2 dilution effect during high rainfall events. This dilution effect needs to be accounted for to reliably describe the role of volcanic island river systems in global assessments of silicate weathering and CO2 degassing. 相似文献
16.
Three-dimensional radiolarian skeletons isolated from rock matrix in HF solution and then studied under scanning electron microscope substantiate the Early Cretaceous age of volcanogenic-cherty deposits sampled from fragmentary rock successions of the East Sakhalin Mountains. Accordingly the Berriasian age is established for jasper packets formerly attributed to the Upper Paleozoic-Mesozoic Daldagan Group; the Valanginian radiolarians are identified in cherty rock intercalations in the Upper Paleozoic (?) Ivashkino Formation; the Berriasian-Barremian assemblage is macerated from cherty tuffites of the Jurassic-Cretaceous Ostraya Formation; and the Aptian-early Albian radiolarians are characteristic of tuffaceous cherty rocks sampled from the Cretaceous Khoe Formation of the Nabil Group. Photographic documentation of radiolarian skeletons specifies taxonomic composition and age of the Berriasian, Valanginian, Berriasian-Valanginian, Barremian, and Aptian-Albian radiolarian assemblages from the East Sakhalin Mountains, and their evolution as related to abiotic events is considered. Coexistence of Tethyan and Pacific species in the same rock samples evidence origin of radiolarian assemblages in an ecotone. Consequently, the assemblages are applicable for intra- and interregional correlations and paleogeographic reconstructions. 相似文献
17.
The distributions of the partial pressure of carbon dioxide (pCO2) and total alkalinity (TA) were examined for a 6-month period in the Wailuku and Wailoa rivers and coastal waters of Hilo
Bay on the west coast of the Island of Hawaii, USA. Main results for the largest and turbulent Wailuku River show in the watershed
an oversaturation in CO2 with respect to atmospheric equilibrium and a CO2 undersaturation in the estuary. In the Wailoa river-estuary system, extremely high pCO2 values ranging from 1500 to 10500 ppm were measured with significant shifts in pCO2 from drought to flood period. In the two rivers, water residence time, groundwater inputs and occasional flood events are
the predominant drivers of the spatial and temporal patterns in the distribution of pCO2. In Hilo Bay, CO2 oversaturation dominates and the bay was a source of CO2 to the atmosphere during the study period. TA is conservative along the salinity gradient, indicating calcification in the
bay is not a significant source of CO2 to the atmosphere. 相似文献
18.
S.O. Zorina 《Russian Geology and Geophysics》2009,50(5):430-437
The generalized eustatic and tectonoeustatic models developed by the author are tested on Lower Cretaceous deposits of the eastern part of the Russian Plate. The models are applicable to facies analysis of sections of epicontinental basins with mainly slope sedimentation. They demonstrate possible variations in section lithology depending on the rate of eustatic changes and the intensity and direction of epeirogenic movements. It has been revealed that the Lower Cretaceous sections in the east of the Russian Platform formed as a result of the synchronous global eustasy and regional epeirogeny. Superposition of the global eustatic curve onto the Lower Cretaceous chronostratigraphic chart of the eastern part of the platform showed that global eustasy, periodically concealed by regional epeirogeny, played a crucial role in the Early Cretaceous history of the study area. Regional epeirogenic and eustatic curves were constructed. The epeirogenic curve demonstrates the contribution of vertical tectonic movements to the overall eustatic-epeirogenic result recorded on a regional eustatic curve. The latter was constructed from the analysis of the spatial and temporal changes in the stratigraphic position of formations and strata and transgressive surfaces ranking. Eustatic cycles of different ranks, from elementary (systems tracts) to regional scale, have been recognized. In the rank of largest lithostratigraphic units, three sequences are revealed: Valanginian (RP-1K), Upper Hauterivian–Upper Aptian (RP-2K), and Albian (RP-3K), which reflect the crucial stages of the Early Cretaceous evolution of the eastern Russian Plate. The eustatic-epeirogenic processes during accumulation of formations and strata from Early Berriasian to Late Albian (145.5–99.6 Ma) are considered. It is shown that the division of the studied composite section into sequences permits precise prediction of diverse solid minerals. 相似文献
19.
Lower Cretaceous successions that crop out in the eastern part of the Getic Carbonate Platform (Southern Carpathians, Romania) preserve records of the Valanginian events in different settings of the platform. The integrated sedimentological, biostratigraphical, geochemical and mineralogical analysis of the upper Berriasian–Valanginian successions reveal successive stages in the evolution of the carbonate platform: (a) pre-drowning stage of the shallow-shelf and slope settings of the platform; (b) subaerial exposure and karstification; and (c) incipient flooding and drowning of the carbonate platform. Following the subaerial exposure, starting in the middle early Valanginian, the eastern part of the Getic Carbonate Platform experienced a drowning phase documented by iron oxyhydroxides, phosphate and glaucony mineralized discontinuity surface and glaucony-rich sediments disposed on the discontinuity surface. Recognition of the diachronous intra-Valanginian discontinuity surface within the studied successions is based on clear evidences (facies contrast, depositional and diagenetic features, biostratigraphic and taphonomic data, and geometrical relations). The negative–positive carbon isotope excursion is correlated with the global perturbations of the carbon cycle related to the Valanginian “Weissert” episode, and it is documented for the first time in the shallowest parts of the Getic Carbonate Platform. Tectonic activity and eustatic sea-level fluctuations were most probably the main factors that led to fault-block tilting, local emersion and subsequent drowning of the eastern part of the Getic Carbonate Platform during the Early Cretaceous. We infer that the eastern part of the Getic Carbonate Platform was affected by late Berriasian–early Hauterivian extensional tectonics that could be related to the Neo-Cimmerian movements with effects generally recognized in the northern peri-Tethyan areas. 相似文献
20.
Crayton J. Yapp 《Geochimica et cosmochimica acta》2004,68(5):935-947
Measured mole fractions (X) and δ13C values of the Fe(CO3)OH component in pedogenic goethite from a mid-latitude Oxisol of Early Eocene age (≈52 Ma B.P.) range from 0.0014 to 0.0064 and −20.1 to −15.4‰, respectively. These values of X imply that concentrations of CO2 gas in the paleosol were ≈7400 to ≈34,000 ppm. δ13C and 1/X are correlated and define a linear, soil-CO2 diffusive mixing line with a positive slope. Such positive slopes are characteristic of mixing of two isotopically distinct CO2 endmembers (atmospheric CO2 and CO2 from oxidation of soil organic matter). From the intercept of the mixing line, it is calculated that the δ 13C value of organic matter in the ancient soil was ≈−28.0‰. The magnitude of the slope implies an Early Eocene atmospheric CO2 concentration of ≈2700 ppm.A simple model for forest soils suggests that a “canopy effect” may cause atmospheric CO2 concentrations deduced from pedogenic minerals to underestimate the actual concentrations of atmospheric CO2. If a significant forest canopy were present at the time of formation of pedogenic goethite in the Ione Fm, the concentration of 2700 ppm calculated for atmospheric CO2 could be slightly low, but the underestimate is expected to be < ≈300 ppm (i.e., less than the analytical uncertainty). The relatively high concentration of 2700 ppm inferred for atmospheric CO2 at ≈52 Ma B.P. would have been coincident with the Early Eocene climatic optimum. This result seems to support the case for an important role for variations of atmospheric CO2 in the modification of global paleoclimate. 相似文献