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1.
I. A. Nemirovskaya 《Oceanology》2010,50(5):716-728
Data are presented on the content of aliphatic and polycyclic aromatic hydrocarbons (AHC and PAH, respectively) in the interstitial
waters and bottom sediments of the Kara Sea compared to the distribution of the particulate matter and organic carbon. It
was found that the AHC concentrations within the water mass (16 μg/l on average) are mainly formed by natural processes. The
AHC distribution represents the variability of the hydrological and sedimentation processes in different regions of the sea.
The widest ranges of the concentrations were registered in the Ob Bay-Kara Sea section: in the water (10–310 μg/l for the
AHC and 0.4–7.2 ng/l for the PAH) and in the surface layer of the bottom sediments (8–42 μg/l for the AHC and 9–94 ng/g for
the PAH). The differentiation of the hydrocarbons (HC) in the different media follows the marginal filter’s regularities;
therefore, no oil and pyrogenic compounds are supplied to the open parts of the sea. In the sediment mass, the HC content
is determined by the variations in the oxidative conditions in the sediment and its material’s composition. 相似文献
2.
The paper summarizes results on the content and composition of aliphatic hydrocarbons (HCs) in suspended particulate matter (SPM) and bottom sediments in the Kara, Laptev, and East Siberian seas obtained in 2015–2018. It was established that the “losses” in HC concentrations in surface waters in the river (Ob, Yenisei, Lena, Khatanga, Indigirka, Kolyma) and seawater mixing zone in some cases exceeded their river removal by 90%. The composition of HCs in surface waters depends on the characteristics of the river catchment area, sampling season. and time of day (high/low tide) and basically coincides with the SPM distribution. In the pelagic zone of the seas, the HC content is close to the background (2–7 μg/L). The influence of anthropogenic input was established only in the Gulf of Ob, where the composition of alkanes is close to oil with a HC content of 86 μg/mg SPM. In bottom sediments, the particle size distribution determines the HCs, and terrigenous n-alkanes play the dominant role in the molecular composition.
相似文献3.
Marine organic geochemistry of the Eastern Mediterranean: 1. Aliphatic and polyaromatic hydrocarbons in Cretan Sea surficial sediments 总被引：1，自引：0，他引：1
As part of a lipid biogeochemical study, aliphatic and polyaromatic hydrocarbons were determined in surficial sediments from the Cretan Sea (South Aegean Sea) in the Eastern Mediterranean. Total concentrations of both aliphatic (AHC) and polyaromatic (PAH) hydrocarbons were low (562–5697 and 14.6–158.5 ng/g, respectively) with respect to other coastal sediments worldwide and compare with concentrations found in open sea areas. The composition of AHC was dominated by unresolved complex mixture (UCM) indicating the presence of petroleum-related hydrocarbon inputs as confirmed by the detection of specific α,β-hopanes. PAH consisted mainly of pyrolytic four- to five-ring compounds. UCM and PAH amounts revealed that Cretan Sea receives low supply of anthropogenic material compared to NW Mediterranean. The spatial distributions of AHC and PAH indicated that urban run-off and transport from the continental self are the major input pathway of anthropogenic and biogenic hydrocarbons from terrestrial sources in the near shore area, whereas atmospheric transport might be the significant source of hydrocarbons in the deep area. 相似文献
4.
Data are presented on the content of hydrocarbons (HC) relative to the concentrations of particulate matter, lipids, Corg, and chlorophyll a in the surface waters and snow-ice cover of the East Antarctic coastal areas. It was shown that the growth of the concentrations
of aliphatic HC (AHC) to 30 μg/l in the surface waters takes place in the frontal zones and under the young ice formation.
The AHC content in the snow increases with the growth of the aerosol content in the atmosphere. In the lower part of the ice
at the boundary with the seawater, despite the low temperatures, the autochthonous processes may provide high AHC concentrations
(up to 289 μg/l). Within the snow-ice cover on fast ice, synchronous content variations of all the compounds considered take
place. 相似文献
5.
V. N. Lukashin A. P. Lisitzin O. M. Dara N. V. Kozina A. A. Klyuvitkin A. N. Novigatsky 《Oceanology》2016,56(6):852-862
Data on the mineral composition of sedimentary matter and its fluxes in the sediment system of the Caspian Sea are presented. River runoff, aerosols, particulate matter from sediment traps, and the upper layer (0–1 cm) of bottom sediments are considered. The contents of detrital minerals (quartz, albite, and K-feldspar), clay minerals (illite, chlorite, and kaolinite), and carbonates (calcite, Mg-calcite, dolomite, aragonite, and rhodochrosite) are determined. Gypsum was found in bottom sediments but is absent in the other object of the sediment system. 相似文献
6.
A. V. Maslov N. V. Kozina A. A. Klyuvitkin A. N. Novigatsky A. S. Filippov V. P. Shevchenko 《Oceanology》2016,56(4):552-563
The features of the distribution of some rare and trace elements in modern bottom sediments of the Caspian Sea have been studied from samples collected during cruises 35, 39, and 41 of the R/V Rift and the cruise of the R/V Nikifor Shurekov in 2013. It was established that bottom sediments in different areas of the Caspian Sea vary to some degree in the contents of Zr, Hf, Th, V, Cr, Co, Ni, Cu, Sr, and Ba in comparison to suspended matter discharged by the Volga River and rivers originating in the Caucasus. As follows from the results of a comparison of the geochemical features of modern bottom sediments of the Volga River delta and different sedimentary subsystems of the Caspian Sea with the chemical composition of Middle Archean granitoids and Paleozoic and Mesozoic–Cenozoic basalts, which are regarded as geochemical images of such provenance areas as the basement of East European Platform, Urals, and Caucasus, none of these regions is considered the dominant provenance area for all sedimentary subsystems of the Caspian Sea region. Here, the revealed similarity between modern bottom sediments of the northern, central and southern Caspian Sea regions, the Volga River delta, and Post-Archean average Australian shale (PAAS) in some parameters, including REE spectra, assumes that the Volga River discharge plays a dominant role in the formation of the geochemical image of Caspian Sea subsystems. The role of clastics, including the fine-grained fraction, which is supplied to the Caspian Sea from the Caucasus region and Elburz Mountains, is insignificant already in the coastal area, which is determined both by influence of the marginal filter (MF) and large-scale cholestatic current circulation. 相似文献
7.
Geochemistry of polycyclic aromatic hydrocarbons in the bottom sediments of the eastern Arctic shelf
V. I. Petrova G. I. Batova A. V. Kursheva I. V. Litvinenko V. M. Savinov T. N. Savinova 《Oceanology》2008,48(2):196-203
Sources and pathways of supply of polycyclic aromatic hydrocarbons (PAH) in the surface sediments of the Laptev and East Siberian seas were identified based on an analysis of the lithological-geochemical characteristics and distribution of organic matter (OM). The distribution of organic carbon, humic acids, bitumoids, and hydrocarbons demonstrates the determining role of the riverine runoff in the formation of the recent sediments. The total average content of PAH in the sediments of this region approximates 37 ng/g, not exceeding 80 ng/g of dry sediment. The biogenic components of the PAH (alkylphenanthrenes, alkylchrysenes, perylene) dominate in the estuarine-shelf and coastal-shelf sediments enriched with plant detritus and significantly decrease in the pelagic zone. The anthropogenic influence is observed in sediments of the port of Tiksi, where the total content of PAH with dominant pyrogenic components is two orders of magnitude higher as compared with the background values in the study region. 相似文献
8.
三峡截流后长江口秋季TSM、POC和PN的分布特征 总被引：2，自引：0，他引：2
基于2004年11—12月长江口56个站位的悬浮体调查资料,分析了长江口区悬浮体总量(TSM)、颗粒有机碳(POC)和颗粒氮(PN)质量浓度的平面分布特征,探讨该区TSM及颗粒有机质的物质来源和三峡截流对长江三角洲的影响。结果表明,表、底层TSM与POC、PN质量浓度之间存在显著的正线性相关关系并都呈现出南高北低的格局,说明了长江悬浮颗粒物入海后主要沿东南方向输运。POC、PN质量分数与POC、PN的质量浓度不同,它们与TSM质量浓度对数有负相关关系。由于河口区底质再悬浮作用显著,TSM和POC、PN质量浓度呈现表层低、底层高的特点。长江口悬浮体主要来自长江径流和底质沉积物的再悬浮。与三峡截流前数据的对比表明,截流对目前长江口区的TSM和POC尚未造成明显的影响。 相似文献
9.
Data on the contents and compositions of the hydrocarbons (HCs)—aliphatic (AHCs) and polycyclic aromatic (PAHs)—are provided
in comparison with the contents of the total organic carbon (Corg), the lipids in the particulates, and the Corg in bottom sediments. Particular attention has been paid to the distribution of the HCs in the water area of the Kravtsov
oil field. It has been established that the concentrations of AHCs in the water are governed by the content of particulates,
and the elevated AHC concentrations are confined to the coastal areas. In the water area of platform D-6, the sandy bottom
sediments were notable for the great variability of the HC concentrations, both laterally and from year to year. In the summer
of 2010, the content of AHCs averaged 40 μg/g (19% in the Corg), and that of PAHs, 23 ng/g. Natural seepage from the sediment mass is considered to be a source of HCs along with oil contamination. 相似文献
10.
Variation of reactivity of particulate and sedimentary organic matter along the Zhujiang River Estuary 总被引：3，自引：0，他引：3
To investigate organic matter source and reactivity in the Zhujiang River (Pearl River)Estuary and its adjacent areas, particulate organic carbon (POC), particulate hydrolysable amino acids (PHAA), and Chl a during two cruises in July 1999 and July 2000 were measured. The highest POC and PHAA concentration was observed in the waters with maximum Chl a. The spectra distribution,relative content (dry weight in milligram per gram), PHAA-C% POC and other indicators such as the ratios of amino acids vs. amino sugars (AA/AS) and glucosamine vs. galactosamine (Glum/Gal) suggested that particulate amino acids in the water column and sediments in the Zhujiang River Estuary were mainly derived from biogenic processes rather than transported from terrestrial erosion. In inner estuary where high turbidity was often observable, organic matter was mainly contributed by re-suspension of bottom sediments with revealed zooplankton, microbial reworked characteristics, which suggest that these organic matters were relatively “old“. In the estuarine brackish region, organic matter in water column is mainly contributed by relatively fresh, easily degradable phytoplankton derived organic matter.During physical - biological processes within the eastuary, organic matter derived from phytoplankton was subjected to alteration by zooplankton grazing and bacterial reworking. 相似文献
11.
A method is presented to study the carbohydrate composition of marine objects involved into sedimento- and diagenesis (plankton,
particulate matter, benthos, and bottom sediments). The analysis of the carbohydrates is based upon the consecutive separation
of their fractions with different solvents (water, alkali, and acid). The ratio of the carbohydrate fractions allows one to
evaluate the lability of the carbohydrate complex. It is also usable as an indicator of the biogeochemical processes in the
ocean, as well of the genesis and the degree of conversion of organic matter in the bottom sediments and nodules. The similarity
in the monosaccharide composition is shown for dissolved organic matter and aqueous and alkaline fractions of seston and particulate
matter. 相似文献
12.
Yu. S. Dolotov N. N. Filatov V. P. Shevchenko M. P. Petrov A. V. Tolstikov R. E. Zdorovennov A. V. Platonov A. S. Filippov K. L. Bushuev I. P. Kutcheva N. V. Denisenko R. Stein C. Saukel 《Oceanology》2008,48(2):255-267
The distribution of the temperature and salinity, current velocities, suspended particulate matter, bottom sediments, bottom morphology, and planktonic and benthic organisms during the summer period are studied in the estuary of the large Onega River and the coastal areas of Onega Bay (White Sea) influenced by interacting marine and riverine factors. 相似文献
13.
Lukashin V. N. Kravchishina M. D. Klyuvitkin A. A. Novigatsky A. N. Politova N. V. 《Oceanology》2019,59(3):381-391
Oceanology - The first data on a long-term study of the Volga River marginal filter are reported. The concentrations of suspended particulate matter, particulate chemical elements, and trace... 相似文献
14.
In three sections in the Kara Sea, the contents of the dissolved and particulate organic carbon (the DOC and POC, respectively),
as well as of the organic carbon of the bottom sediments (Corg) were determined. The contents of varied from 6.3 to 2400 μg/l for the DOC and from 0.84 to 12.2 mg of C/l for the POC. The
average concentrations for all the samples tested amounted to 200 μg/l for the DOC (n = 78, σ = 368) and 2.7 mg/l for the POC (n = 92, σ = 2.7). The concentrations of Corg in the samples of the upper layer of the bottom sediments of the area treated
varied from 0.13 to 2.10% of the dry substance at an average value of 0.9% (n = 21, σ= 0.49%). It is shown that the distribution of the different forms of organic matter (OM) is an indicator of the supply
and spreading of the particulate matter in the Kara Sea and that the DOC and POC of the Kara Sea are formed under the impact
of the runoff of the Ob and Yenisei river waters. It is found that the distribution of the OM of the bottom sediments in the
surveyed area of the Kara Sea is closely related to their grain-size composition and to the structure of the currents in the
area studied. The variations in the Corg content in the bottom sediment cores from the zone of riverine and marine water mixing
represent the variability of the OM burial. 相似文献
15.
The anthropogenic contribution of trace metals to settling particulate matter (SPM) and surficial sediments was determined on the high-energy continental shelf adjacent to Sydney, Australia. Settling particulate matter and surficial sediment was collected in the vicinity of a major sewage outfall and at five control sites on the middle shelf (80-100 m water depth). Sediment traps were deployed on 10 occasions for up to 2 weeks during the summer and winter of 1995 and SPM was analyzed for Ag, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn. Cobalt, Fe, Mn and Ni act conservatively in SPM and in sediments regionally and are used as normalizing elements to determine anthropogenic enrichment. Surficial sediments and SPM are enriched in Ag, Cr, Cu, Pb and Zn near a major ocean outfall and at four of the five control sites, although sewage particles contribute < 5% of trace metals in the total sample. Silver is the most sensitive trace metal tracer for establishing the presence of sewage particulate matter. Sewage particulate matter flux near the outfall was estimated using a two end-member mixing model and is below 0.5 g m(-2) day(-1) during all deployment periods. The mean sewage particulate matter flux at sampling locations 30 km and 60 km north of the outfall are <0.13 g m(-2) day(-1) and <0.01 g m(-2) day(-1), respectively, indicating an efficient dispersal of anthropogenic material on this high energy continental shelf. 相似文献
16.
甘油二烷基甘油四醚(glycerol dialkyl glycerol tetraethers,GDGTs)作为一种重要的膜脂化合物,广泛存在于海洋水体和沉积物中。基于GDGTs对温度的敏感性, TEX86(Tetra Etherinde Xoftetraethers consisting of 86 carbons)指标被广泛用于海洋古温度重建。然而,研究表明GDGTs母源生物古菌也会受到环境中溶解氧(DO)变化的影响,进而影响其膜脂组成,但边缘海DO对GDGTs组成的影响仍不清楚。本文研究了夏季长江口及其邻近海域颗粒物与表层沉积物中GDGTs的含量与组成,探讨了表层沉积物中GDGTs的来源及其组成对底层DO的响应。结果表明,长江口及其邻近海域颗粒物GDGTs的含量随水深的增加而增加,同时表层沉积物中的GDGT-2/GDGT-3和GDGT-0/Cren比值均与底层颗粒物相近,表明沉积物中GDGTs主要来源于底层颗粒物的沉降输入。进一步对受陆源有机质输入影响较小的站位研究发现有机质来源BIT(Branched and Isoprenoid Tetractter)指... 相似文献
17.
Composition of the organic matter of the water,suspended matter,and bottom sediments in Nha Trang Bay in Vietnam in the South China Sea 总被引：1，自引：0，他引：1
V. I. Peresypkin A. V. Smurov N. A. Shulga E. S. Safonova T. G. Smurova Ch. V. Bang 《Oceanology》2011,51(6):959-968
Research has been conducted in Nha Trang Bay (Southern Vietnam, the South China Sea) at the section from the estuary of the
Cai River to the marine part of the bay, as well as in the area of coral reefs. The objects of the studies are the river and
sea waters, the suspended matter, and the bottom sediments. Data on the dissolved organic carbon and the total nitrogen in
the water are obtained. The organic carbon content is estimated in the suspended matter; the organic carbon and the molecular
and group composition of the n-alkanes are determined in the bottom sediments. The molecular and group composition of the n-alkanes in the bottom sediments of the landfill have made it possible to identify three types of organic matter (OM): marine,
mixed, and of mainly terrigenous origin. All the types of OM are closely related to the specificity of the sedimentation and
the hydrodynamics of the waters in this water area. 相似文献
18.
沉积物中重金属的归一化问题——以Al为例 总被引：21，自引：0，他引：21
沉积物的来源、粒度和矿物组成是影响重金属在动力沉积过程中的行为的最显著的因素,用某些参考元素（如Ａｌ、Ｌｉ等）归一化的目的是为了减小沉积物中重金属含量的波动,以揭示人文活动（例如污染）的影响。通过对国内一些河流沉积物中重金属的Ａｌ归一化结果的分析,认为在岩石的风化和变质过程中元素与Ａｌ的相对迁移能力的差异和各种生物过程均可使重金属的Ａｌ归一化值产生显著的变化,在某些情况下Ｍ／Ａｌ值并不一定能准确地描述人类活动对沉积物中重金属的影响。Ａｌ归一化仅能部分地校正粒度分布引起的重金属含量的变化,但不能消除矿物组成的影响。 相似文献
19.
In the summer 2006, integrated geological, geochemical, hydrological, and hydrochemical studies were performed on the relict
anoxic Lake Mogil’noe (down to 16 m depths) located on Kil’din Island in the Barents Sea. The chemical and grain-size composition
of the bottom sediments were compared for the lake (a permanently anoxic basin) and the Baltic Sea Deeps (periodically anoxic
basins). The vertical location of the hydrogen sulfide layer boundary in the lake (9–11 m depths) was practically the same
from 1974 up to now. The concentrations of suspended particulate matter in the lake in June and July 2006 appeared to be close
to its summer concentrations in the seawaters of the open part of the Baltic Sea. The mud from Lake Mogil’noe compared to
those of the Baltic Sea Deeps are characterized by fluid and flake consistency and by pronounced admixtures of sandy and silty
fractions probably of eolic origin. The lacustrine mud contain much plant remains; iron sulfides and vivanite were also found
in ooze. The concentrations of 22 elements determined in the lacustrine bottom sediments were of the same levels as those
found here 33 years ago. The concentrations also appeared to be close to those in the corresponding grain-size types of the
bottom sediments in the Baltic Sea. The low Corg/N value (5% on average) in the mud of Mogil’noe Lake compared to the values for the mud of the Baltic Sea Deeps (10% on average)
points to the considerable planktogenic component in the organic matter composition of the lacustrine mud. No indications
were reveled for anthropogenic contaminations of the lacustrine bottom sediments with toxic metals. 相似文献
20.
Surface sediments from the Saronikos Gulf were analyzed for their aliphatic hydrocarbon (AHC) and polycyclic aromatic hydrocarbon (PAH) content by gas chromatography – mass spectrometry (GC/MS). The concentrations of Fe, Cr, As, Sb, Co and Sc were also determined by neutron activation analysis (NAA). The survey was performed at the beginning of the operation of Athens’ sewage primary treatment unit and the results can be used to monitor the unit's long-term effects in the area. The composition of aliphatic hydrocarbons indicated a chronic oil-pollution in the Saronikos Gulf sediments. The industrially impacted Elefsis Bay sediments suffered from heavy petroleum pollution, while the sediments near the sewage outfall had a moderate degree of pollution. Mixed source patterns of polycyclic aromatic hydrocarbons with dominant pyrolytic inputs have been identified in the sediments. Total concentrations of Fe, As and Sb along with their Sc normalized values presented elevated values in Elefsis Bay sediments. Chromium was found enriched in the sediments near the Athens sewage outfall. Factor analysis results showed that a part of As and Sb in Elefsis Bay sediments could be associated with organic or sulphidic phases. In addition, the lithogenic fraction of the sediments and the Fe oxides/hydroxides were important trace element carriers. Chromium and PAH inputs from the sewage outfall were also detected. Comparison of PAH and trace element concentrations with internationally-used sediment quality guidelines (SQG) revealed that Elefsis Bay sediments had the greatest potential of causing adverse effects in benthic organisms. 相似文献